# Honeywell International, Inc. — Hazardous Materials Safety Interpretation

**Citation:** 02-0089  
**Type / status:** guidance / guidance  
**Agency:** Pipeline and Hazardous Materials Safety Administration  
**Effective:** Not stated  
**Published:** 2002-04-15

02-0089 response to Honeywell International, Inc. concerning 171.8, 172.504, 172.505, 172.519.

## Document text

<<<PAGE 1>>>

S. Departmer
f Transportatio
400 Seventh St., S.W
Nashington, D.C. 2059
Special Programs
Research and
APR 15 2002
Administration
Ms. Barbara Konrad
Reference No.: 02-0089
Manager, Transportation Safety
Honeywell International. Inc.
P. O. Box 1057
Morristown, NJ 07962-1057
Dear Ms. Konrad:
This is in response to your letter requesting clarification of the placarding requirements under the
Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180). You state that during an audit
by the Federal Railroad Administration (FRA), disagreement arose over the correct placarding
for a tank car containing hydrogen fluoride, anhydrous. It is your understanding that Division
6.1 (other than Inhalation Hazard Zone A or B) materials must be placarded POISON (see §§
172.504(e) and 171:14(b)) and that § 172.519(b)(4) allows the use of the POISON placard in lieu
of the POISON INHALATION HAZARD placard.
The current HMR requirements for placarding shipments of hydrogen fluoride, anhydrous, are
confusing and will be addressed in an upcoming rulemaking. A tank car containing hydrogen
fluoride, anhydrous, must display CORROSIVE and POISON INHALATION HAZARD placards.
Your understanding of the placarding table in § 172.504 and the transitional provisions in
§ 171.14 is correct. Poisonous by inhalation (PIH) liquids are typically assigned to either Inhalation
Hazard Zone A or B. Hydrogen fluoride, anhydrous, a corrosive liquid which also meets the
definition of a PIH material in § 171.8, is an exception in that it is assigned to Inhalation Hazard
Zone C. The subsidiary placarding requirements in § 172.505(a) require that the transport vehicle
must be placarded with the POISON INHALATION HAZARD placard in addition to any other
required placards. It applies to PIH materials in all hazard zones. Section 172.519(b)(4) does not
apply. This latter provision addresses the display of the hazard class or division number in the
vithout the hazard class or division number in domestic transportation by rail or highway
ower corner of a placard and the transition period that permits continued use of subsidiary placard:
I hope this information is helpful. If you have further questions, please do not hesitate to contact
this office.
Sincerely,
Hotte iz. Mitchel
Hattie L. Mitchell
Chief, Regulatory Review and Reinvention
Office of Hazardous Materials Standards
17|.14
020089

<<<PAGE 2>>>

MAR-22-2002 09:48
P. 01/02
Honeywell
Honeywell
Morristora, NJ 07962-1057
P.O. Box 1057
Corbin
8171.14
March 21, 2002
$172.504
Research and Special Programs Administration
Office of Hazardous Materials Standards (DHM-10)
US Department of Transportation
placardin
400 Seventh Street SW
32-0086
Washington, DC 20590-0001
Subject:
Interpretation on Marking and Placarding Requirements for
Anhydrous Hydrogen Fluoride, 8, UN1052, PG 1(6.1)
Polson Inhalation Hazard Zone C
Dear Sir or Madam:
During a routine Federal Railroad Administration audit, there arose disagreement over
the placarding requirements of a tank car loaded with anhydrous hydrogen fluoride
(AHF).
Honeywell believes that tank cars of AHF are correctly marked and placarded if they
contain the following:
Marks:
Proper Shipping Name - Hydrogen Fluoride, Anhydrous
Identification Number - 1052 (displayed on the primary hazard placard)
Additional Marking - Inhalation Hazard
Placards:
Class 8 Primary Placard
Class 6.1 Subsidiary Placard (not a PIH placard)
We believe this marking and placarding is correct, for the following reasons:
(1)
According to the placard substitution table in both 172.504 and 171.14 only
liquids that meet the criteria or are assigned to zone A or B require the PIF
placard. All other class 6.1 materials, require only the poison placard.
(2)
Even though 172.505(a) requires that materials subject to the PIH shipping
paper requirements (all PH zones whether primary or subsidiary, and thus AHF)
must be placarded with a PIH placard, 172.519(b)(4) authorizes the use of a
regular poison placard.
This section states that "stocks of non-permanently affixed subsidiary placards
in compliance with the requirements in effect on September 30, 2001, may
continue to be used in domestic transportation by rail or highway until October 1,
2005 or until current stocks are depleted, whichever occurs first." On

<<<PAGE 3>>>

MAR-22-2002 09:48
P.02/02
For these reasons, AHF tank cars, displaying both a corrosive and a poison placard,
and showing the marks indicated on page one of this letter, would be in complete
compliance with the Hazardous Materials Regulations until October 1, 2005.
I look forward to hearing your opinion on this matter. If you require any additional
information, or would like to discuss this in greater detail, please do not hesitate to call
me at the number listed below.
Very truly yours,
Barbara Konrad
Manager, Transportation Safety
973-455-4009
Honeywell International Inc.
Cc:
Pat Williams - Honeywell
Jeff Leese - Honeywell
Derek Fletcher - Honeywell
Jim Duncan - FRA
TOTAL P. 02

## Provenance

- Official: Yes
- Source: <https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2002/020089.pdf>
- Source ID: `phmsa`
- SHA-256: `a460836f5df58db074adbb8840a892b9d1154b4b9c002c86c1008820819d3119`
- Retrieved: 2026-08-20T00:59:31.977Z
- Exported: 2026-08-23T07:47:48.048Z
- Document slug: `phmsa-interpretation-02-0089`

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