# 3M Center — Hazardous Materials Safety Interpretation

**Citation:** 13-0221  
**Type / status:** guidance / guidance  
**Agency:** Pipeline and Hazardous Materials Safety Administration  
**Effective:** Not stated  
**Published:** 2014-01-16

13-0221 response to 3M Center concerning 172.313.

## Document text

<<<PAGE 1>>>

U.S. Department
of Transportation
Pipeline and Hazardous
Materials Safety
Administration
1200 New Jersey Avenue, SE
Washington, D.C. 20590
JAN 1 6 2014
Mr. William Gramer
Packaging Engineering, Dangerous Goods
3M Center, 216-02N-08
St. Paul, MN 55144
Ref. No.: 13-0221
Dear Mr. Gramer:
This is in response to your email dated November 14, 2013, requesting clarification of the
Hazardous Materials Regulations (HMR; 49 CPR Parts 171-180) relating to the
§ 172.313(b) requirement that each non-bulk plastic outer packaging used as a single or
composite packaging for materials meeting the definition of Division 6.1 shall be
permanently marked, by embossment or other durable means with the word "POISON."
You present a scenario where solid Division 6.1 poison materials are sealed inside an
impermeable plastic bag. The sealed plastic bag is placed into either a UN 1 H plastic drum
or a UN 6HA composite drum. You contend that since the poisonous materials are
contained within the impermeable plastic bag and do not directly contact the interior of the
lH plastic drum or the liner of the 6HA composite drum that the§ 172.313(b) "POISON"
marking is not required.
You are correct. The described packagings meet the definition of combination packagings.
The marking requirement of§ 172.313(b) does not apply to combination packagings.
Section 171.8 defines a receptacle as a containment vessel for receiving and holding
materials, including any means of closure. It is the opinion of this office that a plastic bag
meets the definition of a plastic receptacle and may be used, where suitable, as the inner
packaging of a combination package.
An authorized single packaging for a hazardous material, such as the UN 6HA composite
drum, may contain inner receptacles, such as the sealed plastic bag, that are compatible with
the lading as long as the inner receptacles would not adversely affect the level of
performance of the packaging. The packaging would remain marked as a single packaging.

<<<PAGE 2>>>

A package consisting of an outer packaging and a separate inner receptacle placed within the
outer packaging is defined as a combination packaging. Therefore, both the UN 1 H plastic
drum and the UN 6HA composite drum containing the separate inner receptacle (the sealed
plastic bag) would meet the definition of a combination packaging.
I trust this information is helpful. If you have further questions, please do not hesitate to
contact this office.
Sincerely,
-~ Ucl--·.« /1' ~~_{
1
Duane A. Pfund
/
International Standards Coordinator
Standards and Rulemak:ing Division
-------~-- --------------~---------~------·-

<<<PAGE 3>>>

Drakeford, Carol
From: INFOCNTR (PHMSA)
Sent:
To:
Subject: Friday, November 15, 2013 4:37PM
Drakeford, Carolyn (PHMSA)
FW: Clarification requested for 49CFR §172.313
Hi Carolyn,
This caller requested we submit this e-mail as a formal letter of interpretation.
Thanks,
Victoria
From: wgramer@mmm.com [mailto:wgramer@mmm.com]
Sent: Thursday, November 14, 2013 6:09 PM
To: INFOCNTR (PHMSA)
Subject: Clarification requested for 49CFR §172.313
Mr. Gramer would like his email submitted for a formal interpretation
Completed by AE via phone on 11/15/13 at 12:48 left vm
Clarification requested for Poison Marking aspect of 49CFR §172.313
USDOT PHMSA:
The text of 172.313 appears consistent with alerting users of Plastics packagings which may have had poison materials
permeate or penetrate the polymeric walls of the package that the plastic is potentially contaminated as a result - thus,
"Poison" is to be Indelibly marked to protect later users from this potential contamination.
Now, Our question has to do with using plastics drums or composite drums which also have an inner impermeable plastic
liner into which toxic solid is placed, sealed and then this bag is placed into a UN 1 H1, 1 H2 with or without a bung
opening, or 6HA 1 drum with or without smaller bung in metal lid, (Any 6H*# really from 178.522), and further, there is
never contact between the poison and the plastic drum wall The liners are disposed of properly not re-used. The drums
can be re-used with new clean liners.
We believe the intent of 172.313 would not require the "Poison" marking on openings of these drums, as it is implict that the
Poison mark is only required when permeation/contamination may have happened due to direct contact with drum wall.
However the letter of the text is not explicit as to that interpretation - thus our Question:
May we use 1 H1 or 2 or 6HXx containers without the 'Poison' mark from 313(b) being applied near the opening(s), when we
use bags/liners to contain poison material and such liners prevent any toxic/poison from ever contacting the the walls of the
packagings?
Again, The text of 172.313 appears consistent with an intent to allow us to do so. As text seems to require clear alert via
the 'Poison' marking to users of Plastics packagings which may have earlier been used for carrying toxic/poison material
and thus had poison materials permeate or penetrate the polymeric walls of the package. Thus the purpose of the text is to
prevent later users from unknowingly use a package where the plastic is potentially contaminated and could affect food for
human or animal consumption. As such, we believe our plastic packages are not contaminated due to liners preventing
contact with the hazardous material and that in this specific scenario we should not have to indelibly mark our packages as
having been contaminated by 'poison'. However, if so, the text seems to require this clarification.
1

<<<PAGE 4>>>

Please let me know if you need further detail before answering.
Bill Gramer
William Gramer I Specialist II, DGSA
Packaging Engineering, Dangerous Goods.
3M Center, 216-02N-08 I St. Paul, MN 55144 USA
Office: US +1651 736 1407
wgramer@mmm.com I www.3M.com I solutions.3m.com/wps/portai/3M/en US/WW3/Country/
(3M Internal Web site)
3msource.mmm.com/wps/myportai/3M/en US/SourcingPackaging/Center/Reference/PkgRegulatory/
49CFR § 172.313 Poisonous hazardous materials.
In addition to any other markings required by this subpart:
(a) A material poisonous by inhalation (see §171.8 ofthis subchapter) shall be marked "Inhalation Hazard" in
association with the required labels or placards, as appropriate, and shipping name when required. The marking
must be on two opposing sides of a bulk packaging. (See § 172.302(b) of this subpart for size of markings on bulk
packages.) When the words "Inhalation Hazard" appear on the label, as prescribed in§§ 172.416 and 172.429, or
placard, as prescribed in §§ 172.540 and 172.555, the "Inhalation Hazard" marking is not required on the package.
(b) Each non-bulk plastic outer packaging used as a single or composite packaging for materials meeting the
definition ofDivision 6.1 (in §173.132 of this subchapter) shall be permanently marked, by embossment or other
durable means, with the word "POISON" in letters at least 6.3 mm (0.25 inch) in height. Additional text or
symbols related to hazard warning may be included in the marking. The marking shall be located within 150 mm
( 6 inches) of the closure of the packaging.
(c) A transport vehicle or freight container containing a material poisonous by inhalation in non-bulk packages
shall be marked, on each side and each end as specified in § 172.332 or § 172.336, with the identification number
specified for the hazardous material in the § 172.101 table, subject to the following provisions and limitations:
(1) The material is in Hazard Zone A orB;
(2) The transport vehicle or freight container is loaded at one facility with 1,000 kg (2,205 pounds) or more
aggregate gross weight of the material in non-bulk packages marked with the same proper shipping name and
identification number; and
(3) If the transport vehicle or freight container contains more than one material meeting the provisions of this
paragraph (c), it shall be marked with the identification number for one material, determined as follows:
(i) For different materials in the same hazard zone, with the identification number of the material having the
greatest aggregate gross weight; and
2

<<<PAGE 5>>>

(ii) For different materials in both Hazard Zones A and B, with the identification number for the Hazard Zone A
material.
(d) For a packaging containing a Division 6.1 PG III material, "PG III" may be marked adjacent to the POISON
label. (See § 172.405( c).)
§ 105.20Guidance and interpretations.
(a) Hazardous materials regulations. You can obtain information and answers to your questions on compliance with the hazardous
materials regulations ( 49 CFR parts 171 through 180) and interpretations of those regulations by contacting PHMSA's Office of
Hazardous Materials Safety as follows:
(1) Call the Hazardous Materials Information Center at 1-800-467-4922 1-800-467-4922 (in Washington, DC, call (202) 366-4488
(202) 366-4488 . The Center is staffed from 9 a.m. through 5 p.m. Eastern time, Monday through Friday except Federal holidays. After
hours, you can leave a recorded message and your call will be returned by the next business day.
(2) E-mail the Hazardous Materials Information Center at in(ocntr@tfot.gov.
(3) Obtain hazardous materials safety information via the Internet at http://www.phmsa.dot.gov.
(4) Send a letter, with your return address and a daytime telephone number, to: Office of Hazardous Materials Standards, Pipeline and
Hazardous Materials Safety Administration, Attn: PHH-10, U.S. Department of Transportation, East Building, 1200 New Jersey
Avenue, SE., Washington, DC 20590-0001.
(b) Federal hazardous materials transportation law and preemption. You can obtain information and answers to your questions on
Federal hazardous materials transportation law, 49 U.S.C. 5101 et seq., and Federal preemption of State, local, and Indian tribe
hazardous material tr2msportation requirements, by contacting PHMSA's Office of the Chief Counsel as follows:
(1) Call the office of the Chief Counsel at (202) 366-4400 (202) 366-4400 from 9 a.m. to 5 p.m. Eastern time, Monday through Friday
except Federal holidays.
(2) Access information from the Office of the Chief Counsel via the Internet at http://www.phmsa.dot.gov.
(3) Send a letter, with your return address and a daytime telephone number, to: Office of the Chief Counsel, Pipeline and Hazardous
Materials Safety Administration, Attn: PHC-10, U.S. Department ofTransportation, East Building, 1200 New Jersey Avenue, SE.,
Washington, DC 20590-0001.
( 4) Contact the Office of the Chief Counsel for a copy of applications for preemption determinations, waiver of preemption
determinations, and inconsistency rulings received by PHMSA before February 1, 1997.
William Gramer I Specialist II, DGSA
Packaging Engine~ering, Dangerous Goods.
3M Center, 216-CI2N-08 I St. Paul, MN 55144 USA
Office: US +1651 736 1407
wgramer@mmm.com 1 www.3M.com 1 solutions.3m.com/wps/portai/3M/en US/WW3/Country/
(3M Internal Web site)
3msource.mmm.com/wps/myportai/3M/en US/SourcingPackaging/Center/Reference/PkgRegulatory/
3M Technology Advancing Every Company - 3M Products Enhancing Every Home - 3M Innovation Improving
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3

## Provenance

- Official: Yes
- Source: <https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2013/130221.pdf>
- Source ID: `phmsa`
- SHA-256: `ed2f89efdd68977b422a685e8c774987d62438dcd47ce9a3042b9ea2cdb634b6`
- Retrieved: 2026-08-20T00:59:31.977Z
- Exported: 2026-08-22T11:14:16.741Z
- Document slug: `phmsa-interpretation-13-0221`

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