# LANXESS Corporation — Hazardous Materials Safety Interpretation

**Citation:** 20-0084  
**Type / status:** guidance / guidance  
**Agency:** Pipeline and Hazardous Materials Safety Administration  
**Effective:** Not stated  
**Published:** 2021-05-06

20-0084 response to LANXESS Corporation concerning 173.124, 173.125.

## Document text

<<<PAGE 1>>>

U.S. Department
of Transportation
Pipeline and Hazardous
Materials Safety
Administration
1200 New Jersey Avenue, SE
Washington, DC 20590
May 6, 2021
Cyndi Fink
Distribution Safety Manager
LANXESS Corporation
111 RIDC Park West Drive
Pittsburgh, PA 15275
Reference No. 20-0084
Dear Ms. Fink:
This letter is in response to your October 29, 2020, letter requesting clarification of the
Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to classifying
organic acid chlorides. Specifically, you seek clarification of the classification criteria for
dangerous when wet (Division 4.3) materials as specified in §§ 173.124(c) and 173.125(d) of the
HMR.
In your letter, you state that your company contracted with a laboratory to conduct testing in
accordance with the United Nations (UN) Test N.5 of the UN Manual of Tests and Criteria and
§ 173.124(c) of the HMR to determine whether some organic acid chlorides should be classed as
a Division 4.3 material. You state that while the UN Test for Division 4.3 materials requires
testing for the emission of flammable gases, § 173.124(c) of the HMR indicates that both
flammable or toxic gases must be considered for classifying a substance as a Division 4.3
material. Additionally, in your letter you state that samples of your material did not emit any
flammable gases during testing; however, they did emit hydrogen chloride, a toxic gas. You ask
for PHMSA to clarify its position for requiring a material to be classed as a Division 4.3 if it
emits a toxic gas during testing, or if this requirement should be harmonized with international
test methods and only be considered a Division 4.3 material if flammable gasses are emitted
during testing.
PHMSA acknowledges that there is a difference between the international regulations and the
HMR pertaining to the criteria for the classification of a Division 4.3 material. The international
regulations do not mention the emission of toxic gases as criteria in assigning a material to
Division 4.3, while the emission of toxic or flammable gas would be the criteria to assign a
material to Division 4.3 in accordance with the HMR. It is the opinion of this Office that water-
reactive materials that produce toxic gases still present a hazard that should be addressed in the

<<<PAGE 2>>>

HMR, and that until this issue is addressed, you may use the same criteria for Packing Group
(PG) assignment currently specified in § 173.125(d) for measuring the emission of flammable
gasses as for measuring the emission of toxic gasses.
I hope this information is helpful. Please contact us if we can be of further assistance.
Sincerely,
T. Glenn Foster
Chief, Regulatory Review and Reinvention Branch
Standards and Rulemaking Division

<<<PAGE 3>>>

Larson
From:
20-0084
Subject:
To:
INFOCNTR (PHMSA)
Dodd, Alice (PHMSA); Hazmat Interps
Date:
FW: Request for letter of interpretation
Attachments:
2020-10-27 Class 4.3 Toxic Gas LOI request.pdf
Friday, October 30, 2020 12:49:52 PM
Hi Alice,
Please see attached for a letter of interpretation request.
Please contact our office with any questions.
Thank you,
Sarah (HMIC)
From: cyndi.fink@lanxess.com [mailto:cyndi.fink@lanxess.com]
Sent: Thursday, October 29, 2020 12:10 PM
To: INFOCNTR (PHMSA) < INFOCNTR.INFOCNTR@dot.gov>
Cc: Ernest Marcel <ernest.marcel@lanxess.com>; sebastian.buchner@lanxess.com
Subject: Request for letter of interpretation
CAUTION: This email originated from outside of the Department of Transportation (DOT). Do not click on links or
open attachments unless you recognize the sender and know the content is safe.
Please see attached request for a letter of interpretation regarding 49CFR173.124(c).
Thank you.
*uit4+t444++444++44444444++4+4444444+4444444444444444444444.4kk
Cyndi Fink, CDGP, DGSA
Distribution Safety Manager
Product Safety & Regulatory Affairs
LANXESS Corporation
111 RIDC Park West Drive | Pittsburgh, PA 15275-1112
Cell: 412-337-2350 | Office: 412-809-4774 | cyndi.fink@lanxess.com

## Provenance

- Official: Yes
- Source: <https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/docs/standards-rulemaking/hazmat/interpretations/75021/200084.pdf>
- Source ID: `phmsa`
- SHA-256: `c0ec0fac22a01e2e685a254bbf6f81580d87198313aa86f006d16c3d5700ae15`
- Retrieved: 2026-08-20T00:59:31.977Z
- Exported: 2026-08-23T00:02:02.351Z
- Document slug: `phmsa-interpretation-20-0084`

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