# ASi International — Hazardous Materials Safety Interpretation

**Citation:** 98-0405  
**Type / status:** guidance / guidance  
**Agency:** Pipeline and Hazardous Materials Safety Administration  
**Effective:** Not stated  
**Published:** 1998-02-26

98-0405 response to ASi International concerning 172.101.

## Document text

<<<PAGE 1>>>

1
-
U.S. Department
of Transportation
400 Seventh Street, SW
Research and
Washington, D.C.
20590
Special Program:
Administration
FEB 26 1998
Mr. Greg Lemley
Sales
ASi International
4595 Van Epps Road
Cleveland, OH 44131
Dear Mr. Lemley:
This is in response to your letter dated November 14, 1997, requesting clarification on the
applicability of the Hazardous. Materials Regulations (HMR; 49 CFR Parts 171-180) to your
product,
"Magnesium Ferro Silicon." Specifically, you are requesting confirmation that your
:
defining criteria in Part 173 of the HMR.
material does not meet the Division 4.3 (Dangerous When Wet Material) hazard class
Under § 173.22, it is the shipper's responsibility to properly classify a hazardous material.
This office does not normally perform this function. However, based on the test results
provided in your letter, your product, "Magnesium Ferro Silicon", meets the Division 4.3
(Dangerous When Wet Material) hazard class guidelines in the UN Manual of Tests and
Criteria. Your test results report the maximum evolution rate of 1.6 liters per kilogram of
substance per hour which exceeds the UN Manual of Tests and Criteria, Part III, Section 33
:
maximum evolution rate of 1 liter per kilogram of substance per hour for Division 4.3
material. Therefore, your product, "Magnesium Ferro Silicon" is subject to the HMR.
I hope this answers your inquiry. If you need additional assistance, do not hesitate to
contact us.
Sincerely,
-
Nih
mas telling
Delmer F. Billings
Chief, Regulations Development
Office of Hazardous Materials Standards

<<<PAGE 2>>>

•
•
..!*
Bootte.
ASi International
:: 13
172.101
SC: 170,174
November 14, 1997
Alan Roberts
Assistant Administrator for Hazardous Materials Safety
Department of Transportation
400 7th Street SW
Washington, DC. 20590-001
FERRO SILICON LETTER OF INTERPRETATION
Our company imports silicon based material (Magnesium Ferro Silicon) from Brazil into the port
of Baltimore. We are currently shipping this material as a hazardous product according to 49
CFR part 173. We have sent this material to an independent testing laboratory to determine if it is
hazardous to ship.
We would like to get this material or a letter stating this material can be shipped as
non-hazardous.
All our tests indicate that this product is not hazardous according to this regulation. We have
included the test results from the independent lab. We deem it not hazardous & will take all
responsibility herein for shipping said material
I have addressed this letter to you as some of the US Ferro silicon producers have said that this is
where they have sent their requests for the same ruling. If you are not the person whom this letter
should be sent to, please return to me so that I can send it to the appropriate individual.
Please notify me if there is anything else that you need from me to process this request.
Key enly.
Sales
4595 Van Epps Road * Cleveland, Ohio 44131 * Phone 216-485-1800 - Fax 216-485-1807

<<<PAGE 3>>>

1.-
RECD JUN 0 9 1997
610 Willow Street
AndrewS. Melreath & Son, Ine.
P.O. Box 1453
Harrisburg, PA 17105-1453
Telephone: (717) 238-9331
ANALYTICAL AND CONSULTING CHEMISTS
Telex: 84-2321
Fax: (717) 238-4843
June 5, 1997
ASI International
4595 Van Epps Road
Cleveland, Ohio 44131
Gentlemen:
The sample received from you on May 22, 1997, identified as: Magnesium Ferro Silicon,
was tested in accordance with DOT Standard 173, Appendix E, Division 4.3 (Dangerous
water wet material. Results are as follows: *
Spontaneous Ignition Test
Division 4.3 a (1)
No Spontaneous Ignition
Division 4.3 a (2)
No Spontaneous Ignition
Division 4.3 a (3)
No Spontaneous Ignition
Gas Evolution Measurement
Total volume in Mi each hour.
Time Interval
Test 1
Test 2
Test3
I Hour
7.00 MI
8.00 MI
5.50 MI
2 Hour
9.50 MI
10.75 MI
7.50 MI
3 Hour
11.00 MI
11.50 MI
8.50 MI
4 Hour
12.25 MI
11.75 MI
9.50 MI
5 Hour
13.50 MI
12.50 MI
10.00 MI
6 Hour
14.50 MI
13.00 MI
10.75 MI
7 Hour
16.00 Ml
13.75 MI
12.00 MI
24 Hour
21.00 MI
15.75 MI
14.00 MI
Total
21.00 MI
15.75 MI
14.00 MI

<<<PAGE 4>>>

weights of
Test Six mples,
Icalled Mo. Leade
far test sample
weiglets 12114184009
$ 25 grands) Domple
sher03 1211797

<<<PAGE 5>>>

77. 7
==
Page No. 2
June 5, 1997
DOT Test
Maximum Rate - 1.6 liter/hour/kilogram
Average Rate
- 0.42 liter/hour/kilogram after 7 hours
Average Rate
- 0.14 liter/hour/kilogram after 24 hours
Note: The evolved gas was flammable.
Yours very truly,
ANDREW S. McCREATH & SON, INC.

## Provenance

- Official: Yes
- Source: <https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/1998/980405.pdf>
- Source ID: `phmsa`
- SHA-256: `fa113ca540dda816107374eee45183e5956ef7057dbc7b38bf051dd606df0672`
- Retrieved: 2026-08-20T00:59:31.977Z
- Exported: 2026-08-22T21:39:25.858Z
- Document slug: `phmsa-interpretation-98-0405`

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