# Spectra Gases, Inc. — Hazardous Materials Safety Interpretation

**Citation:** 98-0560  
**Type / status:** guidance / guidance  
**Agency:** Pipeline and Hazardous Materials Safety Administration  
**Effective:** Not stated  
**Published:** 1998-03-10

98-0560 response to Spectra Gases, Inc. concerning 173.306.

## Document text

<<<PAGE 1>>>

•
U.S. Department
of Transportation
400 Seventh Street, S.W
Research and
Washington, D.C.
20590
Special Programs
Administration
MAR I O 1998
Mr. William Miller
Manager-Environmental Gases
i
Spectra Gases, Inc.
80 Industrial Drive
Alpha, NJ 08865
Dear Mr. Miller:
4
This is in response to your letter dated February 10, 1998, regarding packaging dilute
mixtures of hydrogen chloride (HCI), anhydrous, chlorine (Clz), anhydrous, and hydrogen
flouride (HF), anhydrous with nitrogen, in a DOT-39 aluminum cylinder under the Hazardous
Materials Regulations (HMR; 49 CFR Parts 171-180). Specifically, you ask whether it is
permissible to fill mixtures of Cl, HCI and HF at concentrations of 300 pm or less and at
pressures of 500 to 1,000 p.s.i.g., with balance nitrogen, in DOT-39 aluminum cylinders.
Based on your statement that you have evidence that your dilute concentrations are not
corrosive to aluminum, you may use a DOT-39 cylinder up to 500 p.s.i.g. Section
178.65(b)(2) states that an aluminum DOT-39 cylinder is not authorized for service pressures
for use of a DOT-39 cylinder above 500 p.s.i.g.
in excess of 500 p.s.i.g. However, you may apply for an exemption as provided in § 107.105
I hope this answers your inquiry. If we can be of further assistance, please contact us.
Sincerely,
Silentlling,
Delmer F. Billings
Chief, Standards Development
Office of Hazardous Materials Standards

<<<PAGE 2>>>

02/10/1998
14:40
9084545009
SPECTRA ENV
PAGE 01
.. ...
Alpha, NJ 08865
80 Industrial Drive
Jesse
173306
Fax: (808)454-7784
Phone: (908)454-7455 ext. 227
Spectra Gases, Inc.
;
Fax
To:
USDOT - Office of Hazardous Materiais From: Bill Miller
Standard. Attn: Jodie George
Fax:
202-366-8700
Pages: 1
Phone: 202-366-8553
Dater 02/10/98
Ro:
Phone Conversation of 2/9/98
CC:
• Urgent
X For Reviow
• Ploaso Comment XPlease Rapty
• Plaase Rocycle
Dear Ms. George,
This is to clarfy my request for determination which we discussed by phone yesterday, It relates to the
ruling in 48CFR that halogen gases are not compatible with aluminum cylinders.
The section of 49CFR which you cited in our phone conversation last week (173.308) does not seem to
contain up to 104 liters of gas at pressures of 500 to 1,000psig. The containers are DOT Specification
apply. It cites quantities of less than 4 Fluid ounces at less than 170psig. The containers we wish to use
39NRC, of aluminum alloy construction.
Anhydrous in balance of Nitrogen. Concentrations are normally 300ppm or less. The proper shipping
The products we wish to ship are dilute mixtures of HI, anhydrous, CI2, Anhydrous, and HF,
name for these products is Compressed Gas NOS, Non-Flammable Gas.
We have evidence that these products do not react with or corrode the aluminum cylinder surface, as
we have standards made for internal use, one to three years old, in which the concentration of the
:
the container.
minor component has been almost constant over time, indicating that there has been no reaction with
Further, we have purchased these products, specifically HCL in Nitrogen, 10ppm, and CL2 in Nitrogen
100ppm from two other companies that claim they are not violating DOT regulations, however, would
not offer proof that this complies with 49CFR. Since the passage in question does not seem to indicate
if it applies to only pure halogen gases in aluminum cylinders, or at what dilution it no longer applies, we
are requesting clarification from you.
Thank you very much for your assistance.

## Provenance

- Official: Yes
- Source: <https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/1998/980560.pdf>
- Source ID: `phmsa`
- SHA-256: `5a1c4dd274133e0ed30f3b120a797c0e892f1373df1844b27ee25a4d377f427d`
- Retrieved: 2026-08-20T00:59:31.977Z
- Exported: 2026-08-22T22:30:00.369Z
- Document slug: `phmsa-interpretation-98-0560`

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