{"operation":"document","citation":"01-0120","title":"World Heart, Inc. — Hazardous Materials Safety Interpretation","source_type":"guidance","agency":"Pipeline and Hazardous Materials Safety Administration","status":"guidance","official":true,"published_on":"2001-07-13","effective_on":null,"summary":"01-0120 response to World Heart, Inc. concerning 172.101.","machine_formats":{"json":"https://regulus.evalyn.ai/document/phmsa-interpretation-01-0120.json","markdown":"https://regulus.evalyn.ai/document/phmsa-interpretation-01-0120.md"},"app_url":"https://regulus.evalyn.ai/document/phmsa-interpretation-01-0120","source_url":"https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2001/010120.pdf","body":"<<<PAGE 1>>>\n\nS. Departmer\nTransportatic\n100 Seventh St., Sv\nNashington, D.C. 2059\nJUL 1 3 2001\nMs. Carol McCulley\nExplant Services\nReference No.: 01-0120\nWorld Heart, Inc.\n7799 Pardee Lane\nOakland, CA 94612\nThis is in response to your May 10, 2000 letter requesting clarification of the proper shipping\nname for a Formaldehyde solution containing 10% neutral buffered formalin under the\nHazardous Materials Regulations (HMR; 49 CFR Parts 171-180). Specifically, you ask whether\n\"Aviation regulated liquid, n.o.s.\"\nthe proper shipping name should be \"Environmentally hazardous substances, liquid, n.o.s.\" or\nEither shipping name may be used, however, the preferred proper shipping name is \"Aviation\nregulated liquid, n.o.s.\" The entry \"Aviation regulated liquid, n.o.s.\" was added to the § 172.101\nHazardous Materials Table in a final rule published March 5, 1999 (Docket HM-215C; 64 FR\n10741) for alignment with the ICAO Technical Instructions and the UN Recommendations.\nI trust you find the information helpful.\nSincerely,\nHotle 2. Mittel\nHattie L.Mitchell\nChief, Regulatory Review and Reinvention\nOffice of Hazardous Materials Standards\n\n<<<PAGE 2>>>\n\nCorbin\n$172.101\nWORLDHE RT\nma Proper Shipping hime\n10 May, 2000\nAttention: Edward Mazzulo\nDirector of Hazardous Materials Standards\nDepartment of Transportation\n400 7th Street, SW\nWashington, D.C. 20590\nDear Mr. Mazzulo:\nWe provide a shipping box for our customers to return our Left Ventricular Assist Device when\nit is removed from a patient. The box contains a total amount of approximately 560 ml of 10%\nneutral buffered formalin in five containers when returned to us. We do not provide the 10%\nneutral buffered formalin.\nCurrently, our shipping information is: Environmentally hazardous substances, liquid, 1.o.s.\n(formaldehyde), UN3082, packing group III, hazard class 9. I have MSDS forms from various\nmanufacturers of 10% neutral buffered formalin. They disagree as to the proper shipping name\nand UN classification. I have been informed by the manufacturer of the shipping box we use that\nthe correct information should now be: Aviation regulated liquid, n.o.s. (10% buffered\nformalin), UN3334, no packing group, hazard class 9.\nWe would appreciate confirmation that Aviation regulated liquid, n.o.s. (10% buffered formalin)\nUN3334, no packing group, hazard class 9 is the proper shipping name/description and shipping\ninformation.\nThank you very much.\nRegards,\nCarlie-ally,\nCarol McCulley\nExplant Services\nWorld Heart, Inc.\n(510) 563-4971 (phone)\n(510) 569-4914 (fax)\ncarol.mcculley@worldheart.com (e-mail)\nAttachments: 4 MSDS forms from various manufacturers\n\n<<<PAGE 3>>>\n\n...\nWORLD HEART INC\nWORLDHE RT\nOAKLAND. CA 84821 1SA\n7709 PARDEE LANE\nTEL.\n510-363-5000\nFAX. 310•303•3005\nDepartment of Transportation\nDirector of Hazardous Materials\n\n<<<PAGE 4>>>\n\n...-\nSIGMA-ALDRICH\nMaterial Safety Data Sheet\nDate upated: 0027/2000\nVersion 1,20\nSection 1 - Product and Company Information\nProduct Number\nProduct Name\nFORMALDEHYDE\nBrand\nSigma Chemical\nF1635\nCompany\nStreet Address\nSigma-Aldrich\nTechnical Phone:\nCity, State, Zip, Country\n3050 Spruce Street\nSt. Louls, MO 63103 US\nFax:\n314 771 5765\n800 325 5052\nEmergency Phone:\n414 273 3850 Ext.5996\nSection 2 - Composition/Information on Ingredient\nFORMALDEHYDE\nSubstance Name\n60-00-0\nSARA 313\nYes\nFormula\nSynonyms\nCH2O\nAldehyde formique (French), Aldehyd mravenci (Czech), Aldeide formica (Italian), BFV, Fannofom\n-ormaldehyde (ACGIH:OSHA), Formaldehyd (Czech, Polish), Formaldehyde, gas, Formalin,\nSection 3 - Hazards Identification\nToxic.\nEmergency Overview\nToxic by Inhalation, in contact with skin, and if swallowed. Causes bums. May cause sensitizaton by inhalation and skin contact.\nPotential cancer hazard. Contains formaldehyde. Readily absorbed through skin. Lachrymator. Combustible liquid. Target organ(s):\nPossible risk of irreversible effects. May cause heritable genetic damage.\nHealth: 3*\nHMIS Rating\n•Flammability: 2\nReactivity: 1\nHealth: 3\nNFPA Rating\nFlammability: 2\nReactivity: 1\n*additional chronic hazards present. For additional information on toxicity, please refer to Section 11.\nSection 4 - First Aid Measures\nIf swallowed, wash out mouth with water provided person is conscious. Call a physician immediately.\nOral Exposure\nInhalation Exposure\nIf inhaled, remove to fresh air. It not breathing give artificial respiration. if breathing is difficult, give oxygen.\n-\n•\n\n<<<PAGE 5>>>\n\n•\nIn case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a\nDermal Exposure\nphysician.\nin case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the\nEye Exposure\neyelids with fingers. Call a physician.\nSection 5 - Fire Fighting Measures\nFlash Point:\n147.2°F\n64 °C\nExplosion Limits:\n- NoT Chan!\nLower: 7%\nUpper: 73%\nAutoignition Temp:\n300 °C\nClass 3! castiar\nExtinguishing Media\nSuitable\nCarbon dioxide, dry chemical powder, or appropriate foam.\nFirelighting\nProtective Equipment\nWear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.\nSpecific Hazard(8)\nSpecific Method(8) of Fire Fighting\nCombustible lIquid. Emits toxic fumes under fire conditions,\nUse water spray to cool fire-exposed containers.\nSection 6 - Accidental Release Measures\nEvacuate area.\nProcedure to be Followed in Case of Leak or Spill\n/ear self-contained breathing apparatus, rubber boots, and heavy rubber glove\nrocedure(s) of Personal Precaution(t\nCover with dry lime or soda ash, pick up, keep in a closed container, and hold for waste disposal. Ventilate area and wash spill site\nMethods for Cleaning Up\nafter material pickup is complete.\nSection 7 - Handling and Storage\nHandling\nUser Exposure\nDo not breathe vapor. Do not get in eyes, on skin, on clothing. Avold prolonged or repeated exposure.\nStorage\nSuitable\n• man\nKeep tightly closed. Keep away from heat and open flame. Store in a cool dry place.\nSection 8 - Exposure Controls / PPE\nEngineering Controls\n:\nUse only in a chemical fume hood, Safety shower and eye bath.\nPersonal Protective Equipment\nRespiratory\nHand\nNIOSH/MSHA-approved respirator.\nCompatible chemical-resistant gloves.\nPage 2\nSigma Chemical - F1635\nSigma-Aldrich Corporation\nwww.oigma-aldrich.com\n-\n\n<<<PAGE 6>>>\n\n•\nChemical safety goggles.\nEye\nOther\nFaceshield (8-inch minimum).\nash Contamient eating before reus. Discard conkaminated shoes. Wash thoroughly after handling.\nExposure Limits, RTECS\nUSA\nCountry\nACGIH\nSource\nLYDE\nCelllry\nValue\nUSA\nMSHA Standard\nconcentration\n0.37 MG/M3 (0.3 PPM)\nRemarks\nCelling\n2 PPM (3 MG/M3)\n•\nNew Zealand\nUSA\nOEL\nOSHA.\npercentration\nSEE 1910.1048\nUSA\nNIOSH\nTWA Celling\nconcentration\n0.016 PPM 0.1 PPM/15M\ncheck ACGIH TLV\nSection 9 - Physical/Chemical Properties\nAppearance\nLiquid\nPhysical State\nColor\nColoress\nClear liquid\nForm\nMolecular Weight:\n30.03 AMU\nProperty\nValue\nAt Temperature or Pressure\npH\nMP/MP Range\nBP/BP Range\nN/A\nN/A\nFreezing Point\nN/A\nN/A\nVapor Pressure\nVapor Density\n1.03 g/l\n52 mmHg\n37 °C\nSG/Density\nSaturated Vapor Conc.\nN/A\nBulk Density\nN/A\n1.016 g/cm3\nVolatile%\nOdor Threshold\nN/A\nWater Content\nVOC Content\nN/A\nN/A\nEvaporation Rate\nSolvent Content\nN/A\nN/A\nViscosity\nN/A\nPartition Coefficient\nN/A\nN/A\nBeen Pointion Temp.\nN/A\nFlash Point °C\n147.2 °F\nExplosion Limite\nLower: 7%\n64 °C\nRefractive Index\nAutoignition Temp\nUpper: 73%\n300 °C\nSolubility\n1.339\nN/A\nSigma Chemical - F1635\nPage 3\nSigma-Aldrich Corporation\n:\nwww.sigma-aldrich.com\n\n<<<PAGE 7>>>\n\n•\nSection 10 - Stability and Reactivity\nStability\nStable\nStable.\nMaterials to Avoid\nPeroratible with aniline, phenol, locyanates, anhydrides, Strong acids, Strong bases, Strong oxidizing agents, Amines,\nHazardous Decomposition Products\nHazardous Decomposition Products\nCarbon monoxide, Carbon dioxide.\nHazardous Polymerization\nWill not occur.\nHazardous Polymerization\nSection 11 - Toxicological Information\noute of Exposur\nkin Contac\nCauses burns.\nSkin Absorption\nReadily absorbed through skin. Toxic if absorbed through skin.\nCauses burns.\nEye Contact\nInhalation\nIngestion\nToxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract.\naffecting the ability to breathe, circulatory shock, and convulsions. Toxic if swallowed.\nIngestion can cause immediate burning pain in the mouth, throat, abdomen; severe swelling of the larynx and skeletal paralysis\nSensitization\nSensitization\nMay cause allergic respiratory and skin reactions\nEyes, Kidneys, Liver. Heart.\nTarget Organ(s) or Systems)\nMaterial is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result\nSigns and Symptoms of Exposure\nin spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure\ncause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. May cause convulsions. To the best of our\nmay include buming sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting, Exposure can\nknowledge, the chemical, physical, and toxicological properties have not been thoroughly Investigated.\nRECS Number: LP8925000\n...... Toxicity Data\nOral - Woman: 108 mg/kg (LDLO)\n-\n••\nOral - Woman: 1 ML/KG (LDLO)\nRemarks: Behavioral:Coma.\nGastrointestinal:Alteration in gastric secretion.\nCardiac:Other changes.\nOral - Rat: 100 mg/kg (LD50)\nPage 4\nSigma Chemical - F1635\nSigma-Aldrich Corporation\nwww.sigma-aldrich.com\n\n<<<PAGE 8>>>\n\n•.\nSubcutaneous - Rat: 420 MG/KG (LD50)\nRemarks: Lungs, Thorax, or Respiration:Acute pulmonary edema.\nLungs, Thorax, or Respiration:Broncholar constriction.\nIntravenous - Rat: 87 MG/KG (LD50)\nOral - Mouse: 42 mg/kg (LD50)\nRemarks: Behavioral:Somnolence (general depressed activity).\nBehavioral:Convulsions or effect on seizure threshold.\nBehavioral:Excitement.\nInhalation - Mouse: 454,000 mg/m3 (LC50)\nSubcutaneous - Mouse: 300 MG/KG (LD50)\nRemarks: Lungs, Thorax, or Respiration:Acute pulmonary edema.\nLungs, Thorax, or Respiration:Bronchiolar constriction,\nSkin - Rabbit: 270 UL/KG (LD50)\nOral - Guinea pig: 260 mg/kg (LD50)\nIrritation Data\nSkin - Human: 0.15 mg 3D |\nRemarks: Mild irritation effect\nEyes - Human: 4 ppm 5M\nEyes - Human: 1 ppm SM\nRemarks: Mild irritation effect\nSkin - Rabbit: 2 mg 24H\nRemarks: Severe irritation effect\nSkin - Rabbit: 540 mg\nRemarks: Open irritation test\nSkin - Rabbit: 50 mg 24H\nRemarks: Moderate irritation effect\nEyes - Rabbit: 0.75 mg 24H\nRemarks: Severe Irritation effect\nEyes - Rabbit: 0.75 mg\nRemarks: Severe imitation effect\nEyes - Rabbit: 10 mg\nRemarks: Severe irritation effect\nChronic Exposure Carcinogen\nResult: This product is or contains a component that has been reported to be possibly carcinogenic based on its ARC,\nACGIH, NTP, or EPA classification.\nRat - Oral: 109 GM/KG 2Y C\nResult: Tumorigenic: Carcinogenic by RTECS criteria, Gastrointestinal:Tumors. Blood:Leukemia\nRat - Inhalation: 14300 PPB 6H/2Y 1\nHes: Tumorge:Carcingenle by RECS criteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste): Olfaction: Tumors.\n-.. un... Result: Tumorigenic: Equivocal tumorigenic agent, by. RECS criteria. Tumorigenic: Tumors at site or application.\nRat - Subcutaneous: 1170 MG/KG 65W 1\nMouse - Inhalation: 14300 PB 6H/2Y |\nResult: TumorigencEquivocal tumorigenic agent by RTECS criteria, Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste): Olfaction: Tumors.\nRat Inhalation: 15 PM 64/78W 1\nTaste):Olfaction:Tumors.\nResult: Tumorigenic:Carcinogenic by RECS cnteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nRat Subtaneous: 350 MG/ 78W |\nResult: Tumorigenic:Equivocal tumorigenic agent by RTECS criteria, Skin and Appendages: Other: Tumors.\nTumorigenic:Tumors at site or application.\nPage 5\nSigma Chemical - F1635\nSigma-Aldrich Corporation\nwww.sigma-aldrich.com\n-\n•\n\n<<<PAGE 9>>>\n\n..\nRat - Inhalation: 6 PPM 6H/2Y |\nResult: Tumorigenic:Equivocal tumorigenic agent by RTECS criterla. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste):Olfaction:Tumors.\nRat - Inhalation: 15 PM 6H/86W 1\nResuit: Tumorigenic:Carcinogenic by RTECS criteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste): Olfaction: Tumors.\nRat - Inhalation: 14 PPM 6H/84W |\nResult: Tumorigenic: Carcinogenic by RTECS criteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste):Olfaction:Tumors,\nRat - Inhalation: 18750 UG/M3 2Y- |\nResult: Tumorigenic: Equivocal tumorigenic agent by RECS criteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste):Olfaction:Tumors.\nMouse - Inhalation: 15 PM 6H/104W 1\nResult: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste): Olfaction: Tumors.\nRat - Inhalation: 15 PPM 6H/2Y |\nResult: Tumorigenic: Carcinogenic by RTECS criteria, Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste):Olfaction:Tumors.\nRat - Inhalation: 5600 PB HRY |\nResult: Tumorigenic: Equivocal tumorigenlc agent by RTECS criteria. Sense Organs and Special Senses (Nose, Eye, Ear, and\nTaste):Olfaction:Tumors.\nOSHA Carcinogen List\nPatential cancer hazard.\nLARC Carcinogen List\nRating\nGroup 2A\nNTP Carcinogen List\nRating\nAnticipated to be a carcinogen.\nACGIH Carcinogen List\nRating\nA2\nChronic Exposure - Teratogen\nSpecies\nRat\nRoute of Application\nExposure Time\nRosul-Specie Development Abnormies Headilary system.\n(1-21D PREG)\nRat\nResut lets on My relus: Cylogic lange induting somalie el genetie materia.\n1 MG/3/24H\nRat\n500 UG/M3/4H\n(1-19D PREG)\nRat\nResult:Specific Developmental Abnormalities: Hepatobiliary system.\n168 MG/KG\nOral\n(1-21D PREG)\nMouse\n(7-14D PREG)\nSpect Desomena porales raid a prince su on gu.\nMouse\nSpecific Developmental Abnormalities: Musculoskeletal system.\nResult: Effects on Embryo or Fetus: Fetal death.\n240 MG/KG\nIntraperitoneal\n(7-14D PREG)\nMouse\nResultSpectic DeVelopmental Abnormalities: other developmental abnomil PREG)\n160 MG/KG\nIntraperitoneal\nPage 6\nSigma Chemical - F1635\nSigma-Aldrich Corporation\nwww.sigme-aldrich.com\n-\n\n<<<PAGE 10>>>\n\n•\nSpecies\nChronic Exposure - Mutagen\nResult: May aer genetic materialute\nExposure Time\nCell Type\nMutation test\n-\nSigma Chemical - F1635\nPage 7\nigma-Aldrich Corporatic\nww.sigma-aldrich.cr\n\n<<<PAGE 11>>>\n\n•\nDNA damage\nlung\nDNA damage\nDNA damage\nDNA damage\nUnscheduled DNA synthesis\nDNA inhibition\nDNA inhibition\nOther mutation test systems\nCytogenetic analysis\nOther mutation test systems\nCytogenetic analysis\n•\nSister chromatid exchange\nOral\n30H\nMicronucieus test\nMutation In mammalian somatic cells.\n• -\n3Н\nInhalation\nliver\nDNA damage\nMorphological transformation.\nOral\nDNA damage\nDNA damage\nDNA damage\nDNA damage\nOral\nUnscheduled DNA synthesis\nSiver\nUnscheduled DNA synthesis\nUnscheduled DNA synthesis\nDNA inhibition\n500\nInhalation\nCytogenetic analysis\nOther mutation test systems\nInhalation\nIntraperitoneal\n5D\nIntraperitoneal\nOral\n5D\nDominant lethal test\nCytogenetic analysis\n5D\nspem\nsperm\nMutation In microorganisms\nDNA damaga\nMorphological transformation.\nOral\nCytogenetic analysis\nDNA damage\nIntraperitoneal\nMutation in mammalian somatic cells.\nCytogenetic analysis\nMorphological transformation.\nHost-medlated assay\nMorphological transformation.\nDNA damage\nCytogenetic analysis\nPhage inhibition capacity\nCytogenetic analysis\nSister chromatid exchange\nSister chromatid exchange\nDNA damage\nMutation In mammalian somatic cells.\nIntratesticular\nsperm\n-\n-\nФ\nDNA\nDNA damage\nSigma Chemical - F1635\nPage 8\nSigma-Aldrich Corporation\nwww.sigma-aldrich.com\n-\n\n<<<PAGE 12>>>\n\n..\nChronic Exposure - Reproductive Hazard\nSpecies\nRat\nDose\n200 MG/KG\nRoute of Application\nOral\nExpasure Time\n(1D MALE)\nRat\nResult: Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count).\nResult: Effects on Newborn: Biochemical and metabolic.\n168 MG/KG\n(1-21D PREG)\nRat\n12 UG/M3/24H\ninhalation\nPREG)\n(15D PRE/1-22D\neffects.\nResult: Effects on Newborn: Growth statistics (e.g., reduced weight gain). Effects on Newborn: Other postnatal measures or\nRat\n12 UG/M3/24H\nInhalation\n(1-22D PREG)\nRat\nResult: Effects on Newborn: Biochemical and metabolic.\nResult: Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count), Paternal\n35 UG/M3/8H\nInhalation\n(BOD MALE)\nRat\nEffects: Other effects on male.\nInhalation\nPREG)\n(20D PRE/1-22D\nRat\nResult: Effects on Newborn: Biochemical and metabolic.\n80 MG/KG\nResult: Pateral Elects: Testes, epididymis, sperm duct. Paternal Effects: Prostate, seminal vessicle, Cowper's gland,\nIntraperitoneal\n(10D MALE)\nRat\naccessory glands.\nResult: Patemal Effects: Testes, epicidymis, sperm duct.\n46243 MG/KG\nSubcutaneous\n(20D MALE)\nRat\nResult: Effects on Merily: Male fertily die a t males imprep ating males per it males exposed to fertile nonpregnant\nfemales).\nResult: Paternal Effects: Spermatogenesis (including genetic material, sperm morphology, motility, and count).\n500 MG/KG\nResult: Effects on Feiny: Post implantation oraly (a g, dead and or resorbed implanka per total number of Implants).\nDog\nEffects on Embryo or Fetus: Fetal death.\nResult: Paternal Effects: Testes, epididymis, sperm duct.\n7 MG/KG\nIntratesticufar\n(1D MALE)\nMonkey\n4 MG/KG\nIntratesticular\n(1D MALE)\nDomestic\nResult: Paternal Effects: Spermatogenesis (Including genetic material, sperm morphology, motility, and count).\nAnimals\n6687 UG/KG\nIntratesticular\n(1D MALE)\nResult: Paternal Effects: Spermatogenesis (Including genetic material, sperm morphology, motility, and count). Patemal\nEffects: Testes, epididymis, sperm duct.\nSection 12 - Ecological Information\nSection 13 - Disposal Considerations\nAppropriate Method of Disposal of Subetance or Preperation\ncontact a licensed professional waste disposal service to dispose of this material.\n•. Observe all,tederal, state, and local environmental regulations.\nDissolve or mix the material with a combustible solvent and burn in a chemical Incinerator equipped with an afterburner and scrubber\nSection 14 - Transport information\n\"DOT—\nUN#: 1198\nProper Shipping Name: Formaldehyde, solutions, flammable\nClass: 3\npa face 472F\nPIH: Not PIH\nPacking Group: Packing Group Ill\n• Not Class 3!\nLATA\nProper Shipping Name: Formaldehyde solution, flammable\nHazard Class: 3\nIATA Number: 1198\nPacking Group: III\nPage 9\nSigma Chemical - F1635\nSigma-Aldrich Corporation\nwww.sigma-aldrich.com\n\n<<<PAGE 13>>>\n\nSection 15 - Regulatory Information\nEU Directives Classification\nIndication of Danger\nSymbol of Danger: T\nToxic.\nRick Statements\nToxic by inhalation, in contact with skin, and if swallowed. Causes burns. Possible risk of irreversible effects. May cause\nR: 23/24/25 34 40 43\nSafety Statements\nIn case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and\ngloves. Wear eye/ace protection. in case of accident or if you feel unwell, seek medical advice Immediately (show the label where\npossible). Use only in well ventilated areas.\nUS Classification and Label Text\n. Toxic.\nIndication of Danger\nRisk Statements\nToxic by inhalation, in contact with skin, and If swallowed. Causes burns. May cause sensitization by inhalation and skin contact.\nPossible risk of Irreversible effects. May cause heritable genetic damage.\nSafety Statements\nIn case or coat ire in ran ay with or you we rand e neil dice maritaly her the take who.\nUS Statements\npossible). Use only in well ventilated areas.\nPotential cancer hazard. Contains formaldehyde, Readily absorbed through skin. Lachrymator. Combustible liquid. Target organ(s):\nEyes. Kidneys.\nListed: Yes\nUnited States Regulatory Information\nDeminimis: 0.1 %\nNotes: This product is subject to SARA section 313 reporting requirements.\nTSCA Inventory Item: Yes\nCalifornia Prop - 65\nUnited States - State Regulatory Information\nProposition 65: This product is or contains chemical(s) known to the state of California to cause cancer.\nCalifornia Proposition 65: This product is or contains chemical(s) known to the state of California to cause cancer. Califomia\nSection 16 - Other Information\nunlimited paper copies for internal use only.\n•\nSigma Chemical - F1635\nPage 10\nSigma-Aldrich Corporation\nwww.sigma-eldrich.com\n-\n\n<<<PAGE 14>>>\n\nEmergency Tacon: 420 350 54.065\nSIGMA-ALDRICH\nwww.sigma-aidrich.com\nFax: 800 325 5052\n4/18/01\nSigma-Aldrich MSDS\nThe MSDS that surpasses them all.\nThe MSDS for more than 85,000 Sigma, Aldrich, Fluka, Supelco, and Riedel-de Haen chemicals on compact\ndisc or magnetic tape. MSDS are arranged in 16 chapter format and are available in six languages:\n• English\n• Dutch\n* German\n• French\nItalian\n• Spanish\nupdated safety information. The CD-ROM includes versions for Microsoft Window...etc.\nSubscribers receive quarterly updates on a new CD-ROM or magnetic tape that includes new products and\nTo order call your local Sigma-Aldrich office or visit www.sigma-aldrich.com\nwww.sigma-aldrich.com has a new look!\nWe have made some exciting upgrades to our website as well as given it a new look. Some of the things\nfamiliarize yourself with our new, more unified, navigation system.\nyou've been familiar with are improved upon and have possibly been relocated. Please take some time to\n•\nWeare Committed to the Succees of our Customers; Employees and Shareholdera through Life Sclence, Technology and Service.\n\n<<<PAGE 15>>>\n\n•\nSt. Louis, MO 63103 U\n3050 Spruce Stree\nTechnical Phone: 314 771 5765\nSIGMA-ALDRICH\nEmergency Phone: 414 273 3850 Ex. 5096\nwww.sigma-aidrich.com\nFax: 800 325 5052\n7799 PARDEE LN\nCAROL MCCULLEY\n4/18/01\nUS\nOAKLAND, CA 94621\nPhone number: 5105634971\nFax: 5105694914\nDear Sigma-Aldrich Customer\nWe recently reorganized our MSDS to better serve you, our valued customer. In addition to an updated look, our sheets\nnow feature a revision date, NFPA/HMIS ratings, and transportation Information.\nyou have any questions or comments\nAs always, customer service is our top priority. Please contact the MSDS department toll-free at 800-521-8956 ext. 2143 i\nMSDS Reference Number: P10515789\nAttached please find the Material Safety Data Sheets you requested.\nMaterial: Sigma Chemical - F1635 FORMALDEHYDE\nSubstance: 50-00-0 FORMALDEHYDE SARA 313: Yes\n-\nWe are Committed to the Success of our Customers, Employees and Shareholders through Life Sclence, Technology and Sorvice.\n\n<<<PAGE 16>>>\n\n-\nMaterial Safety Data Sheet\n10 % Buffered Formalin\nACC# 41129\nSection 1 - Chemical Product and Company Identification\nMSDS Name: 10 % Buffered Formalin\nSynonyms: None.\nCatalog Numbers: SF99 20, SF99 4, SF9920, SF994\n-\nCompany Identification:\nFisher Scientific\nFair Lawn, NJ 07410\n1 Reagent Lane\nFor information, call: 201-796-7100\nEmergency Number: 201-796-7100\nFor CHEMTREC assistance, call: 800-424-9300\nFor International CHEMTREC assistance, call: 703-527-3887\nSection 2 - Composition, Information on Ingredients\nCAS#\nChemical Name\n50-00-0\nPercent\nEINECS/ELINCS\nFormaldehyde\n67-56-1\n3.9-4.0\nMethyl Alcohol\n200-001-8\n2.0 %\n127-09-3\n200-659-6\nSodium Acetate\n7732-18-5\n1.2-2.0\nWater\nBalance\n204-823-8\n231-791-2\nSection 3 - Hazards Identification\nEMERGENCY OVERVIEW\nAppearance: not available, Flash Point: > 194 deg F. Danger! May cause allergic respiratory\nfetal effects in animals. May cause central nervous system depression. Causes eye and skin\nreaction. May cause allergic skin reaction. This substance has caused adverse reproductive and\nirritation. Causes digestive and respiratory tract irritation. Contains formaldehye. Potential\nTarget Organs: Central nervous system.\nPotential Health Effects\nEye: Causes eye irritation.\nSkin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes\nevident upon re-exposure to this material.\nIngestion: Cannot be made non-poisonous. May cause central nervous system depression,\nkidney damage, and liver damage. Causes gastrointestinal irritation with nausea, vomiting and\ndiarrhea.\nInhalation: Causes respiratory tract irritation. May cause allergic respiratory reaction.\nChronic: May cause cancer according to animal studies. May cause reproductive and fetal\neffects.\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 17>>>\n\n-\nSection 4 - First Aid Measures\nthe upper and lower eyelids. Get medical aid.\nEyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting\nSkin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while\nremoving contaminated clothing and shoes.\nIngestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or\nInhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial\nwater. Never give anything by mouth to an unconscious person. Get medical aid.\nrespiration. If breathing is difficult, give oxygen. Get medical aid.\n• Notes to Physician: Treat symptomatically and supportively.\nSection 5 - Firefighting Measures\nGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-\nand highly toxic gases may be generated by thermal decomposition or combustion.\ndemand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating\nExtinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-\nresistant foam. Cool containers with flooding quantities of water until well after fire is out.\nSection 6 - Accidental Release Measures\nGeneral Information: Use proper personal protective equipment as indicated in Section 8.\nSpills/Leaks: Absorb spill with inert material, (e.g., dry sand or earth), then place into a\nEquipment section.\nchemical waste container. Clean up spills immediately, observing precautions in the Protective\nSection 7 - Handling and Storage\n.._Handling: Wash thoroughly after handling. Wash hands before eating. Use only in a well-\ningest or inhale.\nventilated area. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not\nincompatible substances.\nStorage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from\nSection 8 - Exposure Controls, Personal Protection\nEngineering Controls: Use adequate general or local exhaust ventilation to keep airborne\nconcentrations below the permissible exposure limits.\nExposure Limits\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 18>>>\n\n•\n-\nChemical Name\nACGIH\nNIOSH\nOSHA - Final PELs\n0.016 ppm TWA; NIOSH\nFormaldehyde\nC 0.3 ppm\nPotential Occupational\nAppendix A Potential\nCarcinogen - see\nppm STEL; 0.5 ppm TWA\n0.75 ppm TWA PEL; 2\nNIOSH carcinogen.\naction leve\nMethyl Alcohol\n200 ppm; 250 ppm STEL;\ncutaneous absorption\nskin - potential for\n200 ppm TWA; 260\nmg/m3 TWA 6000 ppm\n200 ppm TWA; 260\nSodium Acetate\n.IDLH\nmg/m3 TWA\nThone listed\nnone listed\nnone listed\nWater\n/none listed\nnone listed\nnone listed\nOSHA Vacated PELs: Formaldehyde: 3 ppm TWA (unless specified in 1910.1048) Methyl\nPersonal Protective Equipment\nOSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.\nSkin: Wear appropriate protective gloves to prevent skin exposure.\nClothing: Wear appropriate protective clothing to prevent skin exposure\nnecessary.\nSection 9 - Physical and Chemical Properties\nPhysical State: Liquid\nOdor: None reported\nAppearance: not available\npH: Not available.\nVapor Pressure: Not available.\nVapor Density: Not available.\nEvaporation Rate:Not available.\nViscosity: Not available.\nBoiling Point: Not available.\nFreezing/Melting Point:Not available.\nDecomposition Temperature:Not available.\nAutoignition Temperature: Not applicable.\nFlash Point: > 194 deg F (> 90.00 deg C)\nNFPA Rating: Not published.\nExplosion Limits, Lower:Not available.\nUpper: Not available.\nSolubility: Soluble in water.\nSpecific Gravity/Density:Not available.\nMolecular Formula: Mixture\nMolecular Weight:Not applicable.\nSection 10 - Stability and Reactivity\n• rai -Chemical Stability: Stable under normal temperatures and pressures.\nConditions to Avoid: Incompatible materials, excess heat.\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 19>>>\n\n-\nincompatibilities with Other Materials: Strong oxidants.\nlazardous Decomposition Products: Irritating and toxic gases\nlazardous Polymerization: Has not been reported\nSection 11 - Toxicological Information\nRTECS#:\nCAS# 50-00-0: LP8925000\nCAS# 67-56-1: PC1400000\nCAS# 7732-18-5: ZC0110000\nCAS# 127-09-3: A14300010\nLD50/LC50:\nCAS# 50-00-0:\nInhalation, mouse: LC50 =400 mg/m3/2H;\nInhalation, rat: LC50 =203 mg/m3;\nOral, mouse: LD50 = 42 mg/kg;\nOral, rat: LD50 = 100 mg/kg;\nSkin, rabbit: LD50 = 270 mg/kg;\nCAS# 67-56-1:\nInhalation, rat: LC50 =64000 ppm/4H;\nOral, mouse: LD50 = 7300 mg/kg;\nOral, rabbit: LD50 = 14200 mg/kg;\nOral, rat: LD50 = 5628 mg/kg;\nSkin, rabbit: LD50 = 15800 mg/kg;\nCAS# 127-09-3:\nOral, mouse: LD50 = 6891 mg/kg;\nOral, rat: LD50 = 3530 mg/kg;\nCAS# 7732-18-5:\nOral, rat: LD50 = >90 mL/kg;\nCarcinogenicity:\nCAS# 50-00-0:\nACGIH: A2 - suspected human carcinogen\nCalifornia: carcinogen; initial date 1/1/88\nNIOSH: occupational carcinogen\nNTP: Suspect carcinogen\nOSHA: Possible Select carcinogen\nTARC: Group 2A carcinogen CAS# 67-56-1: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.\nCAS# 127-09-3: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed\n...\nby ACGIH, IARC, NIOSH, NTP, or OSHA.\nEpidemiology: No information available.\nbiochemical/metabolic and reduced weight gain, ihl-rat TCLo=12 ug/m3/24H. Embryo or Fetus:\nTeratogenicity: Formaldehyde effects on Newborn: behavioral, ihl-rat TCLo=50 ug/m3/4H;\ncytological changes, ihl-rat TCLo=1 mg/m3/24H; stunted fetus and death, ipr-mouse TDLo=240\nmg/kg. Specific Developmental Abnormalities: craniofacial and musculoskeletal, ipr-mouse\nTDLo=240 mg/kg.\nReproductive Effects: Formaldehyde effects on Fertility: male index, itt-rat TDLo=400 mg/kg;\npost- implantation mortality, ims-mouse TDLo=259 mg/kg. Paternal Effects: spermatogenesis,\nNeurotoxicity: No information available.\norl-rat TDLo=200 mg/kg; testes/sperm duct/epididymis, ipr-rat TDLo=80 mg/kg.\nMutagenicity: Formaldehyde DNA Damage: human fibroblast 100 umol/L DNA Inhibition:\nhuman cell types 210 umol/L. Unscheduled DNA Synthesis: rat cell types 50 umol/L. Gene\nOther Studies: No data available.\nMutation in Mammalian Cells: human lymphocyte 130 umol/L.\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 20>>>\n\nSection 12 - Ecological Information\nEcotoxicity: Atlantic salmon LC50=173 uL/L/96H; Catfish (fresh water) TLm=32ppm/24H;\nFlounder (salt water) TLm=100-330 ppm/48H; Fathead minnowLC50=10-100 uL/L/96H;\nRainbow trout LC50= 168mg/L/48H; Zebrafish LC50=41mg/L/96H; Water flea LC50=52\n(96Hr.) fathead minnow = 24.1 mg/L; flowthrough conditions; LC50 (96Hr.) bluegill = 0.10\nmg/L/24H.Cas# 50-00-0: LC50(96Hr.) rainbow trout = 0.12 mL/L; flowthrough bioassay; LC50\nphotobacterium phospherum = 3.00-10.2 mg/L; Microtox.\nmg/L; Flow-through conditions;EC50 (96Hr.) water flea = 20 mg/L; EC50 (30 min)\nEnvironmental Fate: No information found.\nPhysical/Chemical: No information found.\nOther: Not available.\nSection 13 - Disposal Considerations\nnazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR\nChemical waste generators must determine whether a discarded chemical is classified as a\nregulations to ensure complete and accurate classification.\nParts 261.3. Additionally, waste generators must consult state and local hazardous waste\nRCRA P-Series: None listed.\nRCRA U-Series: CAS# 50-00-0: waste number U122. CAS# 67-56-1: waste number U154;\n(Ignitable waste).\nSection 14 - Transport Information\nUS DOT\nIATA\nRID/ADR\nIMO\nCanada\nTDG\nAVIATION\nShipping Name:\nLIQUID,N.O.S.\nREGULATED\nNo\nFORMALIN)\n(10%\ninformation\navailable.\nHazard Class:\n9\nUN Number:\nUN3334\nPäcking Group!\nSection 15 - Regulatory Information\nUS FEDERAL\nTSCA\nCAS# 50-00-0 is listed on the TSCA inventory.\nCAS# 67-56-1 is listed on the TSCA inventory.\nCAS# 127-09-3 is listed on the TSCA inventory.\nCAS# 7732-18-5 is listed on the TSCA inventory.\nNone of the chemicals are on the Health & Safety Reporting List.\nHealth & Safety Reporting List\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 21>>>\n\nLaguvul l\nChemical Test Rules\nNone of the chemicals in this product are under a Chemical Test Rule.\nSection 12b\nNone of the chemicals are listed under TSCA Section 12b.\nTSCA Significant New Use Rule\nSARA\nNone of the chemicals in this material have a SNUR under TSCA.\nSection 302 (RQ)\nCAS# 50-00-0: final RQ = 100 pounds (45.4 kg) CAS# 67-56-1: final RQ = 5000 pounds (2270\nkg)\nSection 302 (TPQ)\nCAS# 50-00-0: TPQ = 500 pounds; RQ = 100 pounds (does not meet toxici ty criteria but\nSARA Codes\nbecause of high production volume and recognized toxic ity is considered a chemical of concern)\nCAS # 50-00-0: acute, chronic. CAS # 67-56-1: acute, flammable.\nSection 313\nThis material contains Formaldehyde (CAS# 50-00-0, 3 9 4 0%), which is subject to the\nreporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. This material\nSection 313 of SARA Title III and 40 CFR Part 373.\ncontains Methyl Alcohol (CAS# 67-56-1, 2 0%),which is subject to the reporting requirements of\nClean Air Act:\nCAS# 50-00-0 is listed as a hazardous air pollutant (HAP). CAS# 67-56-1 is listed as a\nhazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This\nClean Water Act:\nmaterial does not contain any Class 2 Ozone depletors.\nCAS# 50-00-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this\nlisted as Toxic Pollutants under the CWA.\nproduct are listed as Priority Pollutants under the CWA. None of the chemicals in this product are\nOSHA:\nCAS# 50-00-0 is considered highly hazardous by OSHA.\nSTATE\nFlorida, Pennsylvania, Minnesota, Massachusetts.\nCAS# 50-00-0 can be found on the following state right to know lists: California, New Jersey,\nCAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey,\nFlorida, Pennsylvania, Minnesota, Massachusetts.\nCAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.\nCAS# 127=09-3. is not present on. state lists from CA, PA, MN, MA, FL, or NJ.\nThe following statement(s) is(are) made in order to comply with the California Safe\nstate of California to cause cancer. California No Significant Risk Level: CAS# 50-00-0: no\nDrinking Water Act: WARNING: This product contains Formaldehyde, a chemical known to the\nsignificant risk level = 40 ug/day European/International Regulations\nEuropean Labeling in Accordance with EC Directives\nHazard Symbols:\nRisk Phrases:\nNot available.\nSafety Phrases:\nWGK (Water Danger/Protection)\nCAS# 50-00-0: 2\nCAS# 67-56-1: 1\nCAS# 127-09-3: 1\nCAS# 7732-18-5: No information available.\nCanada\nCAS# 50-00-0 is listed on Canada's DSL/NDSL List.\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 22>>>\n\nrage / OI /\nCAS# 67-56-1 is listed on Canada's DSL/NDSL List.\nCAS# 127-09-3 is listed on Canada's DSL/NDSL List.\nCAS# 7732-18-5 is listed on Canada's DSL/NDSL List.\nThis product has a WHMIS classification of D1B, D2A.\nCAS# 50-00-0 is not listed on Canada's Ingredient Disclosure List.\nCAS# 67-56-1 is not listed on Canada's Ingredient Disclosure List.\nCAS# 127-09-3 is not listed on Canada's Ingredient Disclosure List.\nExposure Limits\nCAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.\nSTRALIA:TWA 1 ppm (1,5 mg/m3);STEL 2 ppm (3 mg/m3);CAR OEL-BELGIUM:TW\nCAS# 50-00-0: OEL-ARAB Republic of Egypt:TWA 2 ppm (3 mg/m3) OEL-AU\nA 1 ppm (1.2 mg/m3);STEL 2 ppm (2.5 mg/m3); CAR OEL-CZECHOSLOVAKIA:TWA\n0.5 mg/m3;STEL 1 mg/m3 OEL-DENMARK:STEL 0.3 ppm (0.4 mg/m3); Carcinog\nen OEL-FINLAND:STEL 1 ppm (1.3 mg/m3); Skin OEL-FRANCE:STEL 2 ppm (3\nmg/m3) OEL-GERMANY:TWA 0.5 ppm (0.6 mg/m3); Carcinogen OEL-HUNGARY:ST\nEL 0.6 mg/m3;Carcinogen OEL-JAPAN: TWA 0.5 ppm (0.61 mg/m3);Carcinogen\nTHE PHILIPPINES: TWA 5 ppm (6 mg/m3) OEL-POLAND:TWA 2 mg/m3 OEL-RUSSI\nDEL-IHE NETHERLANDS:TWA 1 ppm (1.5 mg/m3);STEL 2 ppm (3 mg/m3) OEL-\nA:TWA 0.5 ppm;STEL 0.5 mg/m3;Skin OEL-SWEDEN: TWA 0.5 ppm (0.6 mg/m3);\nSTEL 1 ppm (1. mg/m3) OEL-SWITZERLAND:TWA 0.5 ppm (0.6 mg/m3);STEL 1\nPP (1.2 mg/m3) OEL-THAILAND: TWA 3 ppm;STEL 5 ppm OEL-TURKEY: TWA 5 pp\nm (6 mg/m3) OEL-UNITED KINGDOM:TWA 2 ppm (2.5 mg/m3);STEL 2 ppm (2.5\nIN NEW ZELAND, SINGAPORE, VIETNAM check ACGI TLV\nmg/m3) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL\nCAS# 67-56-1: OEL-ARAB Republic of Egypt: TWA 200 ppm (260 mg/m3);Ski\nn OEL-AUSTRALIA: TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL-BELGIU\nM: TWA 200 ppm (262 mg/m3);STEL 250 ppm;Skin OEL-CZECHOSLOVAKIA:TWA 10\n0 mg/m3;STEL 500 mg/m3 OEL-DENMARK: TWA 200 ppm (260 mg/m3); Skin OEL-\nFINLAND: TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL-FRANCE:TWA 200\nppm (260 mg/m3);STEL 1000 ppm (1300 mg/m3) OEL-GERMANY:TWA 200 ppm (2\n-JAPAN: TWA 200 ppm (260 mg/m3);Skin OEL-THE NETHERLANDS: TWA 200 ppm (\n60 mg/m3);Skin OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN9 OEL\n260 mg/m3);Skin OEL-THE PHILIPPINES:TWA 200 ppm (260 mg/m3) OEL-POLA\nND: TWA 100 mg/m3 OEL-RUSSIA:TWA 200 ppm;STEL 5 mg/m3;Skin OEL-SWEDEN\n:TWA 200 ppm (250 mg/m3);STEL 250 ppm (350 mg/m3);Skin OEL-SWITZERLAN\nD: TWA 200 ppm (260 mg/m3);STEL 400 ppm;Skin OEL-THAILAND: TWA 200 ppm\n(260 mg/m3) OEL-TURKEY:TWA 200 ppm (260 mg/m3) OEL-UNITED KINGDOM:TW\nRDAN, KOREA check ACGIH TLV OEL IN NEW ZELAND, SINGAPORE, VIETNAM ch\nA 200 ppm (260 mg/m3); STEL 250 ppm;Skin OEL IN BULGARIA, COLOMBIA, JO\neck ACGI TLV\nSection 16 - Additional Information\nMSDS Creation Date: 7/12/1999\nRevision #3 Date: 8/02/2000\nhttps://fscimage.fishersci.com/msds/41129.htm\n4/18/01\n\n<<<PAGE 23>>>\n\n•\nMaterial Safety Data Sheet\nFormalin Neutral Buffered 10% w/v\nACC# 41127\nSection 1 - Chemical Product and Company Identification\nMSDS Name: Formalin Neutral Buffered 10% w/v\nCatalog Numbers: SF100 20, SF100 200, SF100 4, SF10020, SF100200, SF1004\nSynonyms: None\ncompany Identification:\nFisher Scientific\n1 Reagent Lane\nFor information, call: 201-796-7100\nFair Lawn, NJ 07410\nEmergency Number: 201-796-7100\nFor International CHEMTREC assistance, call: 703-527-3887\nFor CHEMTREC assistance, call: 800-424-9300\nSection 2 - Composition, Information on Ingredients\nCAS#\nChemical Name\nPercent\n50-00-0 /\nEINECS/ELINCS\nFormaldehyde\n4.0\n200-001-8\n67-56-1\nMethyl alcohol\n1.0-2.0\n200-659-6\n7558-79-4\nSodium phosphate dibasic\n0.65\n231-448-7\n7732-18-5\nWater\n10049-21-5\n91.9-92.\n231-791-2\nSodium phosphate, Monobasic, Monohydrate\n0.4\nunlisted\nSection 3 - Hazards Identification\nEMERGENCY OVERVIEW\nAppearance: clear. Danger! May cause allergic skin reaction. This substance has caused\n•..adverse reproductive. and fetal effects. in animals. May cause centraL nervous system depression.\nformaldehye. Respiratory sensitizer. Potential cancer hazard.\nCauses eye and skin irritation. Causes digestive and respiratory tract irritation. Contains\nTarget Organs: Central nervous system.\nPotential Health Effects\nEye: Causes eye irritation. Contact may cause ulceration of the conjunctiva and cornea.\nSkin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes\nevident upon re-exposure to this material.\nIngestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause\ndizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness,\ncentral nervous system depression, characterized by excitement, followed by headache,\ncoma and possible death due to respiratory failure. May cause systemic toxicity including central\nnervous system depression, convulsions, coma, and possible death due to respiratory failure.\nhttps://fscimage.fishersci.com/msds/41127.htm\n4/18/01\n\n<<<PAGE 24>>>\n\n-\nInhalation: May cause asthmatic attacks due to allergic sensitization of the respiratory tract.\nChronic: Formaldehyde has been associated with nasal and nasopharyngeal cancers. Repeated\nexposure may cause skin discoloration and thickening and nail decay.\nSection 4 - First Aid Measures\nEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and\nl","truncated":true,"body_characters":69159}