# U.S. Geological Survey — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 02-0292
- **title:** U.S. Geological Survey — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2003-04-10
- **effective on:** Not available
- **summary:** 02-0292 response to U.S. Geological Survey concerning 172.101, 173.134.
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- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2002/020292.pdf
**body:**

<<<PAGE 1>>>

•
U.S. Department
of Transportation
400 Seventh St., S.W.
Washington, D.C. 20590
APR 10 2003
Dr. Stephen R. Moulton, II
Ref. No.: 02-0292
Biological Operations Manager
United States Department of Interior
National Water-Quality Assessment Program
U.S. Geological Survey
Reston, Virginia 20192
Dear Dr. Moulton:
This responds to your letter regarding whether biological samples from streams, preserved with
Parts 171-180). We apologize for the delay in responding and hope it has not caused any
Formalin, are regulated for transportation under the Hazardous Materials Regulations (HMR; 49 CFR
inconvenience.
Your agency collects biological samples from streams to determine the identification and abundance of
algae and invertebrates (e.g., insects, crustaceans, worms, clams) for use in water-quality studies. For
each sample, the stream bottom material (consisting of organisms and debris) is preserved with either
3-5% formalin (algae samples) or 10% formalin (invertebrate samples). A single sample container
ranges from 60 mL to a maximum of 1L. These samples are shipped to a central laboratory for
analysis.
Section 172.101(c)(11) provides, in part, that a shipper may assign a tentative shipping name, hazard
class and identification number to a material sent for testing, based on the shipper's tentative
determination according to defining criteria in the HMR, hazard precedence prescribed in § 173.2, and
the shipper's knowledge of the material. Based on the information you provided, it is this Office's
opinion that these samples do not meet the definition of an infectious substance in § 173.134 because
there is no reason to know or suspect they contain an infectious substance.
Although you did not provide sufficient information, such as a Material Safety Data Sheet, the acute
effects of Formaldehyde solutions has been well documented. Formalin (10% formaldehyde solution),
used to preserve the biological samples, meet the definition for a Class 9 material in § 173.140 and is
subject to regulation when transported domestically by air. The appropriate shipping description is
"Other Regulated Substances, liquid, n.o.s. (formaldehyde), 9, NA3082, II." Generally, solutions of
less than 10% formaldehyde mixed with non-hazardous materials do not meet the definition of a Class 9
hazardous material and, provided they do not meet any other hazard class, are not subject to the HMR.
172.101,
173.134
020292

<<<PAGE 2>>>

As provided by § 173.22 of the HMR, it is the shipper's responsibility to properly class a hazardous
material. Manufacturers, generally, have the knowledge to properly class the materials and products
they produce, although it may be necessary to enlist an outside laboratory to assist in the classification
process as testing may have to be conducted to see how a product compares to the criteria for the
various hazard classes.
I hope this satisfies your inquiry. If we can be of further assistance, please contact us.
Sincerely,
1
dich
Delmer F. Billings
Chief, Standards Division
Office of Hazardous Materials Standards

<<<PAGE 3>>>

United States Department of the Interior
Engrum
U.S. GEOLOGICAL SURVEY
Reston, Virginia 20192
§172.101
National Water-Quality Assessment Program
MS 413
$173.134
Classification
October 30, 2002
02-02926
Director of the Office of Hazmat Standards
Edward Mazzullo
400 7th Street, NW
US DOT/RSPA DHM-10
Washington, DC 20590-0001
Dear Mr. Mazzullo,
My agency collects biological samples from streams to determine the identification and
quality studies. For each sample, the stream bottom material (consisting of the organisms and
abundance of algae and invertebrates (e.g., insects, crustaceans, worm, clams) for use in water-
samples). A single sample container ranges from 60 mL to a maximum of 1 L depending on the
debris) is preserved with either 3-5% formalin (algae samples) or 10% formalin (invertebrate
laboratory for analysis.
amount of sample material. These samples are shipped from across the country to a central
We have been experiencing considerable confusion over the interpretation of shipping regulations
of interpretation for the proper classification and shipping requirement for these samples?
for these samples preserved with either 3-5% or 10% formalin. Can you provide us with a letter
Thank you. I look forward to your response.
Sincerely,
Stephen R. Moulton II, Ph.D
Biological Operations Manager
703-648-6874
smoulto@usgs.gov
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