# NRS America Inc. — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 03-0091
- **title:** NRS America Inc. — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2003-08-05
- **effective on:** Not available
- **summary:** 03-0091 response to NRS America Inc. concerning 171.12, 176.83.
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- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-03-0091
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2003/030091.pdf
**body:**

<<<PAGE 1>>>

*
of Transportation
U.S. Department
400 Seventh St., S.W.
Special Programs
Research and
Washington, D.C. 20590
AUG
5 2003
Administration
NRS America Inc.
Mr. Domenico Masi
Ref. No. 03-0091
Suite 110
10 Bank Street
White Plains, NY 10606
Dear Mr. Masi:
This responds to your letter requesting clarification of the
Regulations (HMR; 49 CFR Parts 171-180)
segregation requirements under the Hazardous Materials
Maritime Dangerous Goods Code. (IMDG Code) .
and the International
inquire whether Dichlorosilane, Division 2.3, UN2189, may be
Specifically, you
container.
loaded with other Division 2.1 materials in the same
You state that because dichlorosilane
has
freight
risks of Division 2.1 and Class 8, the container is rejected
secondary
and 7.2.1.16 of the IMDG Code requirina Class 8 materials be
›ased on the general segregation tables. in S 176.83 of the HMF
stowed "away from" Division 2.1 materials.
dichlorosilane in the same freight container with other Division
Under both the HMR and the IMDG Code, it is permissible to stow
2.1 materials.
dichlorosilane is not considered for the purpose of segregation
The Class 8 secondary hazard assigned to
under both the HMR and the IMDG Code.
column (10B) of the § 172.101 Hazardous Materials Table for
In the HMR, the specific segregation requirements specified in
dichlorosilane is stowage
code "17."
$ 176.84, states "segregation same as for flammable gases but
Code. 17, as
set forth in
"away from" dangerous when wet."
HMR requires that all secondary labels be taken into account when
Although S 176.83 (a) (6) of the
"where a code in column (10B) of the § 172.101 Hazardous
determining segregation, paragraph (a) (10) of that section states
Materials Table specifies that "segregation as for ..." applies,
the segregation requirements applicable to that class in the
$ 176.83 (b) General Table must be applied." (Emphasis
Therefore, for segregation purposes, dichlorosilane is treated
solely as
a Division 2.1 material.
provisions for materials having more than two hazards are given
Paragraph 7.2.1.6.2 of the IMDG Code states the segregation
in the Dangerous Goods List (DGL).
of the DGL states "segregation as
for class 2.1 but "away from"
For dichlorosilane, column 16
111.12,
17683
030091

<<<PAGE 2>>>

in the case of conflicting provisions,
class 4.3." Furthermore, paragraph 7.2.1.16 states that the DGL,
takes precedence over the
general provisions contained in the segregation table. Therefore,
again, dichlorosilane is treated solely as a class 2.1 material.
be of further assistance.
I trust this satisfies your inquiry. Please contact us if we can
Sincerely,
Hithe x. Mikell
Hattie I. Mitchell
Chief, Regulatory Review and Reinvention
Office of Hazardous Materials Standards

<<<PAGE 3>>>

:
Suite 1110
Head Office:
Branch Office:
White Plains, NY 10606
10 Bank Street
363 N. Sam Houston Pkwy. East
Suite 1730
Fax: (914)422-3414
Phone: (914)422-3400
Phone: (281)820-1993
Houston, TX 77060
E-mail: info@nrsa.com
AMERICA INC.
Fax: (281)820-2399
FMC License No. 3563
Stevens
Friday, March 14, 2003
$171.12
Mr. Ed Mazullo
US Dept. Of Transportation / RSPA
$ 176.83
Washington, DC 20590
400 Seventh St., S.W.
Vessel
Dear Ed:
03-0091
Subject: Dichlororosilane
currently handling the export of hazardous gases packaged in DOT approved cylinders from both the West Coast
NRSA America is a licensed and bonded transportation company operating in the state of New York. We are
we then segregate and load these cylinders into intermodal containers. The below listed product has presented
and East Coast. These commodities are delivered to our contracted warehouse's located within the port city where
problems in that this commodity is regularly rejected by the pier operators and in some instances the steamship line.
Listed below is the product and a summary of the problem we have face in shipping this product.
Product
Classified as
Dichlorosilane
Dichlorosilane, class 2.3, UN2189, Toxic Inhalation Hazard, Zone B, (2.1), (8)
rejected by the pier because they only check product compatibility tables which shows class 8 incompatible with
When our containers are loaded with Dichlorosilane and another class 2.1 material, the entire container is often
than 2 hazards are listed in the Dangerous Goods List. Entry for Dichlorosilane indicates segregate as 2.1.
another 2.1 material. Per IMDG (amdt 31-02) Code 7.2.1.6.2, segregation requirements for materials having more
DOT 49 CFR entry column 10B indicates segregation provision 17, "segregate as flammable gas but away from
dangerous when wet".
We respectfully request your clarification on the above issue.
Sincerely,
Amenico Masi
Domenico Masi
Enclosure (1)
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