# Fisher Scientific Company, LLC — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 03-0321
- **title:** Fisher Scientific Company, LLC — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2004-01-30
- **effective on:** Not available
- **summary:** 03-0321 response to Fisher Scientific Company, LLC concerning 173.136.
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- **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-03-0321.md
- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-03-0321
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2003/030321.pdf
**body:**

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U.S. Department
of Transportation
400 Seventh St., S.W.
Research and
Washington, D.C. 20590
Administration
Special Programs
JAN 3 0 2004
Mr. John G. Mayfield
Ref. No. 03-0321
Manager, Dangerous Goods Transportation
Fisher Scientific Company, LLC
2000 Park Lane
Pittsburgh, PA 15275-1126
Dear Mr. Mayfield:
This is in response to your letter dated December 17, 2003 requesting clarification on the classification
of Bouin's Solution under the Hazardous Materials Regulations (HMR: 49 CFR Parts 171-180).
Specifically, you would like a letter confirming your conclusions that a mixture consisting of 1.5% picric
acid, 97 acetic acid, 19% formaldehyde, < 1% coloring agent, and approximately 79% water should
be classified as "Corrosive liquid, acidic, organic, n.o.s. (formaldehyde, acetic acid), 8, UN3266, III."
Under § 173.22 of the HMR, it is the shipper's responsibility to properly classify a hazardous material.
This office generally does not perform this function. The definition of a corrosive material is found in
§ 173.136 of the HMR and procedures for packing group selection are found in § 173.137. Assuming
that you have reviewed those sections and determined that your Bouin's Solution meets the definition of
a corrosive material in packing group I and is assigned to the Corrosive liquid hazard class then the
proper shipping name "Corrosive liquid, acidic, organic, n.o.s. (formaldehyde, acetic acid)" would be
appropriate. However, the identification number that you provided in your letter, UN3266, is not
consistent with the proper shipping name that you selected. UN3266 is the identification number for
the proper shipping name "Corrosive liquid, basic, inorganic, n.o.s.". If your conclusions are accurate,
then it is our opinion that the actual description would be "Corrosive liquid, acidic, organic, n.o.s.
(formaldehyde, acetic acid), 8, UN3265, III."
If you determine that a particular mixture of Bouin's Solution does not meet the definition of a corrosive
material or any other hazard class, but it does present a risk during transportation, specifically air
transportation, then it is our opinion that the basic description "Aviation regulated liquid, n.o.s.
(formaldehyde), 9, UN3334, III" would be acceptable. However, if the acetic acid or picric acic
contribute in any way to the hazards of the material they may be required to be included in basic
173.13%
030321
L23C

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description as part of the technical name (i.c., Aviation regulated liquid, n.o.s. (formaldehyde, acetic
acid), 9, UN3334, III ot Aviation regulated liquid, n.o.s. (formaldehyde, picric acid), 9, UN3334, I).
I hope this satisfies your request.
Sincerely,
Thas Arly
Susan Gorsky
Senior Transportation Regulations Specialist
Office of Hazardous Materials Standards …

<<<PAGE 3>>>

DEC-17-2003
17:39
FROM-FISHER SCIENTIFIC QA
+4124808605
T-148 P.002/003 F-363
Supko
2000 Park Lane
Fisher Scientific Company L.L.C.
Fisher Scientific
§ 172.101
Jonn.Mayfield@fisharsci.com
Pittsburgh, PA 15275-1126
Tel: 412-490-8449
Classification
Fax: 412-490-8930
December 17; 2003...
Dr. Charles Ke
03-0321
fishersci.. "
Office of Hazardous Materials Fechnology
US Department of Transportation
400 Seventh Street S.W.
Research and Special Programs Administration
Washington; ĐC 20590-.
Re:
Bouins Solution Classification
Dear Dr. Ke:
Thank you for taking our call of this morning: In response to our conversation regarding the classification for
primary as a tissue fixative: Fisher Scientific purchases this material from various vendors for resale. While
Bouins Solution. we offer the following information. Bouins Solution is a product used in the medical industry
maximum percentages are picric acid (trinitrophenol) at 1.5%, acetic acid at 9%, formaidehyde at 19%, one
the various producers' exact percentages and components may vary, the primary ingredients with their
requested; we have enclosed a copy of Mr. Mazzullo's Memorandum to Mr. William G. Wilkening dated June 2.
coloring agent (which varies by supplier) at < 1% and water as the balance or approximately 79%. As
2000, which specifically states that mixtures of picric acid (1.3%) and water (98.7%) are not subject to the
trinitrophenal wetred with not less than 30% water. We do not feel that the addition of the formaldehyde or
We believe that the Bouins Solution mixtures should not be regulated as a 4.1, as is the classification for
acetic acid would contribute to the activity of the trinitrophenol. The final product should not be classified as
percentages of formaldenyde and acetic acid, we propose the classification for transporation as:
either explosive or reactive:" However, we do think that the materials would fall under the HMR. Due to the
Corrosive Liquid; Acidic; Organic; N:O:S: (formaldenyde, acetic acid).
8, UN3266, Ill
to meet the definition of corrosive, we propose that the alternative classification for materials tested and found
Given the possibility that some of these Bouins Solutions may not contain enough acetic acid or formaldehyde
to be non-corrosive be:
Aviation Regulated Liquid, N.O.S. (formaldehyde), 9, UN3334, III
Do you agree with our classifications?
Thank you for your time. If you have any other questions, please do not hesitate to contact me.
Respectfully.
lotS haull
Manager, Dangérous Goods Transportation...
Enclosure: 1
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