# Sandia National Laboratories — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 05-0210
- **title:** Sandia National Laboratories — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2006-02-06
- **effective on:** Not available
- **summary:** 05-0210 response to Sandia National Laboratories concerning 173.1, 173.476.
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- **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-05-0210.md
- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-05-0210
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2005/050210.pdf
**body:**

<<<PAGE 1>>>

FEB 6 2006
Mr. Leighton Ford
Ref. No. 05-0210
Sandia National Laboratories
7011 East Avenue MS9221
Livermore, CA 94550
Dear Mr. Ford:
This is in response to your electronic mail requesting clarification of the Hazardous
Materials Regulations (HMR; 49 CFR Parts 171-180) pertaining to the classification of
hazardous materials. You state that you cannot recall the classification of the materials
when received by Sandia National Laboratories (SNL) and that SNL plans to transport
the materials for disposal. Specifically, you ask whether the materials meet the definition
for a Class 1 (explosive) or Class 3 (flammable) material and you request assistance in
assigning proper shipping names. You also ask whether the materials are allowed any
exceptions under the HMR based on the small amount of explosive material in each
composition, and whether there is a percentage threshold of diluent that would allow SNL
to reclassify the materials without submitting an approval request to the U.S. Department
of Transportation (DOT).
All new compositions containing any amount of explosive material must be classed by
DOT, including compositions of diluted (desensitized) explosives. Prior to transport, a
written approval and an assigned EX number must be obtained from DOT. If you do not
have access to the EX number or documentation of the DOT classification for the
material that you received, or if a change in the formulation, design, or process alters the
properties of the material, the material is considered to be a new explosive and must be
tested. If you determine that the material may not meet the definition for Class 1
(explosive) under Subpart C of Part 173, you may include the data with your written
request for classification, as specified in §173.56(i), to the Associate Administrator, U.S.
173.1
173:476
050210

<<<PAGE 2>>>

DOT, Pipeline and Hazardous Materials Safety Administration, Office of Special Permits
and Approvals, PHH-32, 400 Seventh St., S.W., Washington, DC 20590.
I hope this information is helpful. Please contact this office if you have additional
questions.
Sincerely,
Hattie L. Mitchell
Chief, Regulatory Review and Reinvention
Office of Hazardous Materials Standards

<<<PAGE 3>>>

The InfoCenter received that following Interp request via
e-mail.
Thank you!
05.0210
Jessica
-----Original Message-- - - -
From: 1ford@sandia.gov
[mailto:lford@sandia.gov]
Sent: Friday, August 26, 2005 2:22 PM
Subject: Information Center Comments/Questions
To: INFOCNTR < PHMSA>
Below
is the result of your feedback form.
Leighton Ford (1ford@sandia.gov) on Friday, August 26, 2005 at
It was submitted by
14:21:46.
Email: lford@sandia.gov
Name:
Leighton Ford
Category:
Shippers-General Requirements for Shipments and Packagings (Sections 173.1 -
173.476)
Organization:
Sandia National Laboratories
Street: 7011 East Avenue MS9221
City:
Livermore
State: California
Zip Code:
Phone:
925-294-4506
Fax:
925-294-3418
Comments: Mr. Edward T. Mazzullo
Director, Office of Hazardous Materials Standards
U.S. DOT/PHMSA (PHH-10)
400 7th Street S.W.
Washington, D.C. 20590-0001
'Dear Mr. Mazzullo,
that we would like :o dispose of.
The intent of this letter is to request a proper shipping name for the following material
I am getting all kinds of advice fru? across the
the following material
country as to whether or not the material these standards to be used as a baseline
there is no explosive characteristic but rather just a flammable solution per se.
reference for analysis meets the definition of an explosive or because of the percentages,
sercentages,
light of all of the advice that I find invaluable; i.e., 10% rule,
...what happens if the

<<<PAGE 4>>>

RDX, Trinitrobenzene solution (.018) in Acetonitrile (99.9%).
ampoule in one box.
5) 2,4,6-Trinitrotoluene (.01%) in Acetonitrile (99.9%).
1- 1 ml ampoule with no box.
6) Tetryl (.01%) in Acetontitrile (99.9%).
2- 1ml ampoules with no box.
How we classify these materials for disposal will dictate how we are able to handle them
at our facility and how we
are to transport them in accordance with all applicable DOT
regulations. I Considering the quantities involved are we provided relief from any of the
HMR requirements? Is there a percentage threshold of diluent in the standard that would
allow us to reclassify the material under a different shipping name without the need to
seek an EX letter should the material be classified as an explosive? 3 When SNL/CA received
the material I cannot recall that the material was shipped to us as an explosive material.
Rather,
With
this in mind, is there
I am under the impression that the standard came to us as a flammable liquid.
shipping standards such
as these.
Thank you ahead of time for your time and consideration.
Sincerely,
jeighton Ford
vaste Management
3NL/ CA
livermore.
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- **body characters:** 4822
