# Hawkins, Inc. — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 08-0216
- **title:** Hawkins, Inc. — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2008-10-07
- **effective on:** Not available
- **summary:** 08-0216 response to Hawkins, Inc. concerning 173.21, 177.848.
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- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-08-0216
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretation%20Files/2008/080216.pdf
**body:**

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U.S. Department
of Transportation
Pipeline and Hazardous Materials
Safety Administration
1200 New Jersey Ave., SE
Washington, DC 20590
Mr. Chris W. Gibson
EHS&R Manager
Hawkins, Inc.
3 100 East Hennepin Avenue
Minneapolis, MN 554 13
Ref. No.: 08-02 16
Dear Mr. Gibson:
This responds to your letter dated August 20,2008, regarding the segregation requirements
of the Hazardous Materials Regulations (HMR: 49 CFR Parts 17 1 - 1 80). Specifically, you
ask if § 177.848(c) applies to the transport of "Hydrochloric Acid, 8, UN 1789, PG 11", and
an unregulated material (i.e., Ferric Ferro cyanide) that can produce hydrogen cyanide when
it comes into contact with acids.
Paragraph (c) of 9 177.848 prohibits cyanides and cyanide mixtures or solutions to be stored,
loaded or transported in the same transport vehicle with "acids" if a mixture of the materials
would generate hydrogen cyanide. Further, Division 4.2 materials may not be stored, loaded
and transported with Class 8 (Corrosive) liquids. This requirement does not address cyanides
and cyanide mixtures or solutions transported on the same transport vehicle with unregulated
materials. However, 9 173.2 l(e) of the HMR prohibits a material in the same packaging,
freight container, or overpack with another material, the mixing of which is likely to cause a
dangerous evolution of heat, or flammable or poisonous gases or vapors or to produce
corrosive materials. Therefore, the transport of "Hydrochloric Acid, 8, UN 1789, PG 11" and
an unregulated material (i.e., Ferric Ferro cyanide) that can produce hydrogen cyanide gases
or vapors when it comes into contact with acids is forbidden.
I hope this information is helpful. If we can be of further assistance, please contact us.
Sincerely,
1.
' Susan Gorsky
Acting Chief, Standards Development
Office of Hazardous Materials Standards

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Aug. 20, 2 0 0 8 8 : 5 3 A M Hawkins, I n c . No. 2 6 4 1 P. 1 / 1
Corpomte g%cc
3100 East Hennepin Avenue
Minneapolis, Minnesota 55413
Phone: (612) 331 -691 0
FOX: (612) 331-5304
August 20,2008
Mr. Edward T. Mazzullo
Director, Office of Hazardous Materials Standards
U.S. DOTIPHMSA (PHH-10)
400 7th Street S.W.
Washington, D,C, 20590-0001
REQUEST FOR INTERYRETATION
RE: 49 CFR 177.8481~)
Dear Mr. Mazzullo:
Scenario:
There are 2 products to be shipped via truck (1 shipment)
Product #1 is a 500# drm of Hydrochloric Acid (UN1789, Hazard Class 8, PGII)
Product #2 i s Manox Blue Dye 1 SOD, which is a Non-DOT regulated material, which
contains Ferric ferrocyanide (CAS#14038-43-8). The Material Safety Data Sheet for this
product indicates that Hydrogen Cyanide gas can be evolved when it comes into contact
with acids.
49 CFR 177.848(c) states: "In addition to the provisions of paragraph (d) of this section
and except as provided in 9 173.1 2(e) of this subchapter, cyanides, cyanide mixtures or
solutions may not be stored, loaded and transported with acids if a mixture of the materials
would generate hydrogen cyanide, and Division 4.2 materials may not be stored, loaded
and transported with Class 8 liquids."
As Product #l is regulated, but Product #2 is not, does 177.848(c) apply?
If you have any questions, 1 can be reached at 6 12-33 1-6910, x855 1 or at
chris.Gibson@hawkinsinc.com
Sincerely,
Chris W. Gibson
EBS&R Manager
Hawkins, Inc.
An Equal Opportunig Employer
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