# Thermo Fisher Scientific — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 09-0037
- **title:** Thermo Fisher Scientific — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2009-10-21
- **effective on:** Not available
- **summary:** 09-0037 response to Thermo Fisher Scientific concerning 171.1, 172.101.
- **machine formats:** - **json:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0037.json
- **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0037.md
- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0037
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretations/2009/090037.pdf
**body:**

<<<PAGE 1>>>

U.S. Department of Transportation
Pipeline and Hazardous Materials
Safety Administration
OCT 2 1 2009
1200 New Jersey Ave, SE
Washington, D.C. 20590
Mr. Gene Sanders, DGSA
Senior Dangerous Goods Transportation Specialist
Thermo Fisher Scientific, Customer channel Group
2000 Park Lane
Pittsburg, Pennsylvania 15275
Ref. No. 09-0037
Dear Mr. Sanders:
This responds to your e-mail regarding the classification of hydrogen gas at low pressure
under the Hazardous Materials Regulations (HMR; 49 CFR Parts 17 1 - 180). Specifically,
you ask whether the HMR apply to the transportation of a small quantity of hydrogen inside a
glass tube or sphere if the hydrogen is shipped at a reduced pressure, rather than compressed.
According to the information provided with your email, the hydrogen gas is shipped within a
glass tube with a total capacity of 1.7 ml. The gas is shipped at a pressure lower than
atmospheric pressure (75 tom). In the event that the glass tube or sphere were to break, the
amount of hydrogen released (0.17 ml) would be insufficient to ignite (i.e., in a 1 -inch
diameter tube or sphere, the concentration of the hydrogen would be below the 4% LEL).
It is the opinion of this office that when packaged as described in your e-mail, the hydrogen
is not shipped in a quantity and form that poses an unreasonable risk to health and safety or
property and, therefore, is not subject to regulation under the HMR.
I hope t h s satisfies your inquiry. If we can be of further assistance, please contact us.
Sincerely,
Charles E. Betts
Standards Development
of Hazardous Materials Standards

<<<PAGE 2>>>

Spectrum tubes with Hydrogen Page 1 of 1
Drakeford, Carolyn <PHMSA>
w."-..-.-e-* .""",*-- "--- .."-*---- "- e m - -.
From: Gorsky, Susan <PHMSA>
Sent: Wednesday, February 18,2009 7:20 AIM
To: Drakeford, Carolyn <PHMSA>
Subject: FW: Spectrum tubes with Hydrogen
From: Sanders, Gene [mailto:gene.sanders@thermofisher.com]
Sent: Tuesday, February 17, 2009 4:41 PM
To: Gorsky, Susan <PHMSA>
Cc: Mayfield, John
Subject: Spectrum tubes with Hydrogen
Dear Ms. Gorsky,
Thermo Fisher has a product that includes 1.7 mL of hydrogen gas at low pressure, 75 Torr, approximately
1110 of an atmosphere, inside a glass tube. In the event that the glass tube were to be broken, the hydrogen
would return to atmospheric pressure, and its volume would become 0.17 mL, approximately one half of 1% of an
ounce. As the hydrogen diffuses into air in a sphere 1 inch across, it becomes too dilute to ignite, (i.e., in a 1 inch
diameter sphere, the concentration of that much hydrogen would be below the 4% LEL).
Because of the extremely small quantity of hydrogen in this article, and because it is shipped at a reduced
pressure rather than compressed, we do not believe that it poses an unreasonable risk to health, safety, or
property when shipped in commerce, and therefore is not a hazardous material for transport. Does PHMSA
disagree with this classification?
Thank you.
Cheers,
Gene Sanders, DGSA
Senior Dangerous Goods Transportation Specialist
Thermo Fisher Scientific, Customer Channels Group
2000 Park Lane
Pittsburgh, Pa. 15275 USA
Gene.Sanders@ThermoFisher.com
41 21490-8934, cell 4121498-2458, fax 41 21490-8930
www.thermofisher.com
The world leader in serving science
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