# Hazmat, Inc. — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 09-0201
- **title:** Hazmat, Inc. — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2009-10-01
- **effective on:** Not available
- **summary:** 09-0201 response to Hazmat, Inc. concerning 172.203, 172.505, 173.29.
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- **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0201.md
- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0201
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretations/2009/090201.pdf
**body:**

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U.S. Department
of Transportation
Pipeline and Hazardous Materials
Safety Administration
1200 New Jersey Ave., SE
Washington, DC 20590
Mr. Paul J. Dambek
Hazmat, Inc.
12 Kimball Hill Road
Hudson, NH 0305 1-391 5
Ref. No.: 09-0201
Dear Mr. Dambek:
This responds to your August 14,2009 letter requesting clarification of the placarding
requirements under the Hazardous Materials Regulations (HMR; 49 CFR Parts 17 1-1 80).
Your questions are paraphrased and answered below.
Ql. A shipper offers for transportation two cylinders of Chlorine, UN1017,2.3 (5.1, 8). The
gross weight of this shipment is 800 pounds. Must the vehicle be placarded with the poison
gas, oxidizer, and corrosive placards?
Al. No. The required placard for "UN 10 17, Chlorine, 2.3" is the POISON GAS placard.
See 5 172.504(e), Table 1. Placarding for the subsidiary 5.1 and 8 hazards is not required, but
is permissible as specified in 5 172.505. The HMR do not specify how to display the primary
and subsidiary placards in relation to each other; however, each placard must be clearly
visible from the direction it faces.
Q2. A shipper offers for transportation two cylinders containing residual amounts of
Chlorine, UN1017,2.3 (5.1,8). Is the shipment required to be placarded?
A2. Yes. As specified in 9 173.29, empty packagings containing the residue of a hazardous
material must be offered and transported in the same manner as when they previously
contained a greater quantity of the hazardous material unless the packagings are sufficiently
cleaned of residue and purged of vapors to remove any potential hazard, or are refilled with a
material that is not subject to the HMR.
Q3. A shipper offers for transportation a drum of Chlorosulfonic acid, UN 1754, 8 (6. I), PG I
for transportation by highway. The gross weight of the material is 450 pounds. Is the
shipment required to be placarded?
A3. Yes. In accordance with 9 172.505(a), a poisonous material subject to the "Poison
Inhalation Hazard" shipping description requirements in 9 172.203(m) must be placarded with
a POISON INHALATION HAZARD or POISON GAS placard. Chlorosulfonic acid meets

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-2- October 1, 2009
the definition for a material that is poisonous by inhalation (see Special Provision 2 as
indicated in Column 7 for the entry for Chlorosulfonic acid in the Hazardous Materials Table
in tj 172.1 01) and, therefore, is subject to the shipping description requirements in
172.203(m) and the placarding requirements in 5 172.505(a).
I trust this satisfies your inquiry. Please contact us if we can be of further assistance.
Sincerely,
&Hattie L. Mitchell
Chief, Regulatory Review and Reinvention
Office of Hazardous Materials Standards

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HAZMATEAM, ZNC.
12 Kimball Hill Rd.
Hudson, NH 0305 1-391 5
Telephone (603) 882- 1 1 12
Fax (603) 882-65 12
E-Mail: hazmateam@earthlink.net
www.hazmatearn.com
IATA
DANGEROUS GOODS
ACCREDITED SCHOOL
August 14,2009
Office of Hazardous Materials Standards
Pipeline and Hazardous Materials Safety Administration
ATTN: PHH-10
U.S. Department of Transportation
466 yth Srree~
Washington, D.C. 20590
Dear Sirs:
I have a question concerning the applicability 49 CFR 172.505, subsidiary placarding. Consider the following
scenarios:
#1) A shipper offers for transportation two cylinders of chlorine gas (UN 101 7, Chlorine, 2.3 (5.1, 8)) on one
truck. The aggregate gross weight of this shipment is 800 pounds. Must the vehicle be placarded with the
poison gas AND oxidizer & corrosive placards?
#2) Consider scenario #1 above, but the cylinders only have residual amounts of gas in the cylinders. Which
placards must be affixed to the truck?
#3) One drum of UN 1754, Chlorosulfonic acid, 8 (6.1), PG I is offered for transportation on a truck.
Chlorosulfonic acid is a PIH, Zone B chemical. The gross weight of the drum is 450 pounds. must be affixed to the truck?
Which placards
Your assistance is greatly appreciated.
Sincerely,
Paul J. ~ a m b e k
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