# Thermo Fisher Scientific — Hazardous Materials Safety Interpretation - **operation:** document - **citation:** 09-0233 - **title:** Thermo Fisher Scientific — Hazardous Materials Safety Interpretation - **source type:** guidance - **agency:** Pipeline and Hazardous Materials Safety Administration - **status:** guidance - **official:** true - **published on:** 2009-12-15 - **effective on:** Not available - **summary:** 09-0233 response to Thermo Fisher Scientific concerning 172.101, 173.22. - **machine formats:** - **json:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0233.json - **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0233.md - **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-09-0233 - **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretations/2009/090233.pdf **body:** <<>> U.S. Department of Transportation Pipeline and Hazardous Material Safety Administration DEC 15 2009 1200 New Jersey AI/e, S.E. Washington. D.C. 20590 Mr. Gene Sanders Senior Dangerous Goods Transportation Specialist Thenno Fisher Scientific 2000 Park Lane Pittsburgh, PA 15275 USA Ref. No. 09-0233 Dear Mr. Sanders: This responds to your October 15, 2009 request for clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180). Specifically, you ask for assistance in detennining the hazard class for your alcohol mixture. According to your letter, your product (Fast Orange G ; Pigment Orange 13, Pyrazolone Orange, C.1. 21110, CAS#3520-72-7) has a chemical structure that, according to Appendix 6 to the United Nations Manual of Tests and Criteria, fourth revised edition, may result in unintended explosive or self-reactive properties. You do not have test data that indicates whether this material meets the definition of a Class 1 ( explosive) or a Di vision 4.1 (selfreactive) material. You state that the Fast Orange G is diluted to less than 1 % with common alcohols, water, and less than 1 % Phosphotungstic acid. You suggest that at this concentration, even if pure Fast Orange G met the definition for a Class 1 (explosive) material, it has been sufficiently desensitized that it no longer exhibits explosive characteri sties. Section 173.22 requires a shipper to properly class and describe a hazardous material for transportation in commerce. This Office does not perfonn that function. However, based on the infonnation provided in your letter and the MSDS enclosed in your letter, it is the opinion of this Office that your product should be described as "UN 1993, Flammable liquid solution, n.o.s., 3, 11." I hope this answers your inquiry. If you need further assistance, please contact this Office. Sincerly, .tJ 71ft 6'124!-ib Charles E. Betts Chief, Standards Development Office of Hazardous Materials Standards <<>> Transport classification verification requested Page 1 of 1 Drakeford, Carolyn (PHMSA) From: Gorsky, Susan (PHMSA) Sent: Friday, October 16, 2009 7:41 AM To: Drakeford, Carolyn (PHMSA) ~112. 101 Subject: FW: Transport classification verification requested QJCl!)Si ~ Co.n;YI Attachments: Pigment Orange 13.pdf; OG-6 MSDS.pdf OQ-OZ3'3 Boo+h~' From: Sanders, Gene [mailto:gene.sanders@thermofisher.com] Sent: Thursday, October 15, 2009 5:52 PM To: Gorsky, Susan (PHMSA); Gorsky, Susan (PHMSA); Watson, Spencer (PHMSA); Watson, Spencer (PHMSA) Cc: Mayfield, John; Kosarich, Kathy Subject: Transport classification verification requested Dr. Watson and Ms. Gorsky, Fast Orange G (Pigment Orange 13, Pyrazolone Orange, C.1. 21110, CAS# 3520-72-7), chemical structure attached, has a chemical structure which Appendix 6 to the United Nations Manual of Tests and Criteria, fourth revised edition, suggests may cause it to have some unintended explosive or self-reactive properties. No test data has been found to indicate whether or not this material might meet the definition of a Class 1 or a Division 4.1 self-reactive. In a product known as OG-6, Fast Orange G is diluted to less than 1 % in some common alcohols, water, and less than 1% Phosphotungstic acid, MSDS attached, At this concentration, even if pure Fast Orange G were to be a Class 1 material, it seems reasonable to believe that it has been adequately desensitized. Does PHMSA find anything non-compliant with using the following transport classifications for OG-6? 49CFR: UN1987, Alcohols, n.o.s., 3, II ICAO: UN1987, Alcohols, n.o.s. (Ethanol, Methanol, Isopropanol), 3, II IMO: UN1987, Alcohols, n.o.s. (Ethanol, Methanol, Isopropanol), 3, II Thank you for your review and evaluation. Cheers, Gene Sanders, DGSA Senior Dangerous Goods Transportation Specialist Thermo Fisher Scientific 2000 Park Lane Pittsburgh, Pa. 15275 USA Gene.Sanders@ThermoFisher.com 412/490-8934, cell 412/498-2458, fax 412/490-8930 www.thermofisher.com The world leader in serving science WORLDWIDE CONFIDENTIALITY NOTE: Dissemination, distribution or copying of this e-mail or the information herein by anyone other than the intended recipient. or an employee or agent of a system responsible for delivering the message to the intended recipient, is prohibited. If you are not the intended recipient. please inform the sender and delete all copies. -_...:==;< «Pigment Orange 13.pdf» «OG-6 MSDS.pdf» 10116/2009 <<>> Pigment Orange 13, C.I. 21110, 4,4'-[(3,3'-Dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[... Page 1 of 1 ~1!r~ Online Database of Chemicals from Around the World ~11E!m6Iink» Chemical Listing » P» Pigment Orange 13 Pigment Orange 13 M~ !btGoogl~ pigmeot CIJ!lmi.QrQj:lw:;!§ Ch!!Jl1iQ!lL~!!lQgYt;! Ada by GooogIt Qr.fNnjc. Qye~tllffs C.Q.!lL Your source for dyes, pigments and colorants for all industries. www.OrganicDye.com QvalityQrgani.:: ~gmen.ts Pigments for inks,coatings,plastics Call Aceto 516-6276000 www.aceto.com fi"~Chl,\!!mh:;ills state-of-the-art, modern producer good prices & service, Check now www.jhchem.com ~llljl!JtPeilri Search Thousands of Catalogs for Pigment Pearl www.globalspec.com Identification Name Pigment Orange 13 C.L 21110; 4,4'·[(3,3'·Oichloro[l,l'-biphenylj-4,4'-diyl)bis Synonyms (azo)]bis[2,4-dihydro·5-methyl·2·phenyl-3H-pyrazol-3-one] Learp A.bout Chapter 7 Free Online Evaluation & Chapter 7 Infonnation. Lawyers Nationwide \V, .. ,\ T()t:llBan~nlpt~~ (lIm Purcb~~.e Ch~rnk!ll$ T()d~y Rare and Unusual Chemicals Organic, Inorganic & Patina U"q\ Clt,ChcmlCal com Molecular Structure Molecular Formula C3zHz4ClzNaOz Molecular Weight 623.49 CAS Registry Number 3520-72·7 EINECS 222-530-3 R~\jabll,\!!(:hemk:als List of Suppliers The CompleteList of Suppliers for Pigment OranQ.e 13 Market Analysis Reports l,.istQf Reports~l,Iailiilblefor Pigment Orange 13 i"~A Methylbenzothiazole, Carbazates, Diethyl Maleate, Hydrazides www.AIDchemlcal.com Phlhalhydrazide Phthailc anhydride Phthallde O·Phthailmide 4-(Phthajlmlde)cyclohexanol 2·12-(2-Phthallmidoethoxy)ethoxyjacetJc aCid 2.Phthallmldo·3·methylbutanoic aCId 6(Phlhalimidomethylj.8.11-dihydro-5H-dibenz[b.elazepme 3·Phthalimldopropionaldehyde 2·Phthallmldoproplonlc aCid 3·Phthalimldopropionlc aCid alpha-Phthalimldoproplophenone Phthalon;lrlle Phthaloyl amlodlplne Phthaloyl dichloride N-Phthaloylglyclne Phthalylglycyl chlonde Phthalylsulfathiazole Physclon Phytase Phytlc aCId Plberaline Plcloram 2· Picollne 3-Picoltne 4·Plcollne·N·oXlde 2·Plcoline·N-{)xide 3·Plcollne·N·oxide Plcolinlc aCid 2,Plcolylamlne 3·Plcolyl chlonde hydrochlonde 2-P,colyl chlonde hydrochloride Picoplalin Picotamide P,coxystrobin Plcramlc aCld Plcnc aCld Picroside I P,croslde II Pidoltmod Pigment Blue 1 Pigment Blue 15'2 Pigment BI~e 27 PIgment 81~e 29 Pigment Blue 61 Pigment Geen 7 Pigment Green 18 Pigment Green 36 Pigment Orange 16 Copyright 2009 @) chemBlink. All rights reserved. Content Dis.clalmer I""bout chemelink I Conll!CI http://www.chemblink.com/products/3520-72-7.htm 10/15/2009 <<>> Print Date: 8/01/08 ACC# 93611 Therl110 Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 MSDS Name: OG-6 Catalog Numbers: 75204, 75204E, 75211, 75211E, 75225 Synonyms: None Known. Company Identification: Richard Allan Scientific 4481 Campus Drive Kalamazoo, MI 49008 Company Phone Number: 800-522-7270 Emergency Phone Number: 800424-9300 CHEMTREC Phone Number, US: (800) 424-9300 CHEMTREC Phone Number, Europe: (202) 483-7616 64-17-5 Ethyl alcohol 7732-18-5 Water 67-63-0 Isopropyl alcohol 67-56-1 Methyl alcohol 3520-72-7 Orange G 12067-99-1 Phosphotungstic acid 75-78 200-578-6 F 11 12-14 231-791-2 4-5 200-661-7 FXI 113667 4-5 200-659-6 FT 11 23/24/25 39/23/24/25 <1.0 222-530-3 <1.0 235-087-6 Page 1 <<>> Print Date: 8/01/08 ACC# 93611 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 EMERGENCY OVERVIEW Appearance: Orange liquid Danger! Poison! Flammable liquid and vapor. May be fatal or cause blindness if swallowed. Harmful if swallowed, inhaled, or absorbed through the skin. Vapor harmful. Causes eye, skin, and respiratory tract irritation. This substance has caused adverse reproductive and fetal effects in humans. May cause central nervous system depression. May cause liver, kidney and heart damage. Cannot be made non-poisonous. Flash Point: 16.5°C. Target Organs: Kidneys, Heart, Liver, Eyes, Nervous system, Optic nerve Potential Health Effects Eye: Causes severe eye irritation. May cause painful sensitization to light. May cause visual impairment. May cause chemical conjunctivitis and corneal damage. Skin: Causes moderate skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May cause cyanosis of the extremities. Methanol can be absorbed through the skin, producing systemic effects that include visual disturbances. Ingestion: May be fatal or cause blindness if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. Methanol is toxic and can very readily form extremely high vapor concentrations at room temperature. Inhalation is the most common route of occupational exposure. At first, methanol causes CNS depression with nausea, headache, vomiting, dizziness and incoordination. A time period with no obvious symptoms follows (typically 8-24 hrs). This latent period is followed by metabolic acidosis and severe visual effects which may include reduced reactivity and/or increased sensitivity to light, blurred, doubl and/or snowy vision, and blindness. Depending on the severity of exposure and the promptness of treatment, survivors may recover completely or may have permanent blindness, vision disturbances and/or nervous system effects. Chronic: Prolonged or repeated skin contact may cause dermatitis. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage. Chronic exposure may cause effects similar to those of acute exposure. Eyes: Get medical aid immediately. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid. Page 2 <<>> Print Date: 8/01/08 ACC# 93611 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Effects may be delayed. Treat symptomatically and supportively. Persons with skin or eye disorders or liver, kidney, chronic respiratory diseases, or central and peripheral nervous sytem diseases may be at increased risk from exposure to this substance. Antidote: Ethanol may inhibit methanol metabolism. Replace fluid and electrolytes. " ·:~~!i~~~'S·l'Ei:r~·~lghting·Nt~a'.·"· General Information: Replace fluid and electrolytes. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHAINIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Autoignition Temperature: Not available Explosion Limits: Lower: 3.3 Upper: 19.0 Flash Point: 16.5°C (61.70°F) NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 0 General Information: Use proper personal protective equipment as indicated in Section 8. Page 3 <<>> Print Date: 8/01/08 ACC# 93611 Therl110 Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG·6 Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. ~.9n/l.~i~~~;dlipg.~n~;'~tQl(a)g~;£~~·~;~Z>;;.;; ....•~ Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Storage: Keep away from sources of ignition. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Do not store near perchlorates, peroxides, chromic acid or nitric acid. Q~;~r~;CQntfPJ$;.r:e~s~llfl~I·\'fti~t~·~l~··' Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Chemical Name: ACGIH NIOSH OSHA Ethyl alcohol 1000 ppm TWA 1000 ppm TWA; 1900 1000 ppm TWA; 1900 mg/m3 TWA 3300 ppm mg/m3 TWA; IDLH (10% LEL) Water None listed None listed None listed Isopropyl alcohol 200 ppm TWA:400 ppm 400 ppm TWA; 980 400 ppm TWA; 980 STEL mg/m3 TWA 2000 ppm mg/m3TWA; IDLH (10% LEL) Methyl alcohol 200 ppm TWA;250 ppm 200 ppm TWA; 260 200 ppm TWA; 260 STEL;Skin - potential mg/m3 TWA 6000 ppm mg/m3 TWA; significant contribution IDLH to overall exposure by the cutaneous route Orange G None listed None listed None listed Phosphotungstic acid 1 mg/m3 TWA (as W) 1 mg/m3 TWA (as W) None listed (listed under Tungsten, (listed under Tungsten, soluble compounds); 3 soluble compounds) mg/m3 STEL (as W) (listed under Tungsten, soluble compounds) OSHA Vacated PELs Ethyl alcohol: 1000 ppm TWA; 1900 mg/m3 TWA Isopropyl alcohol: 400 ppm TWA; 980 mg/m3 TWA Methyl alcohol: 200 ppm TWA; 260 mg/m3 TWA Page 4 <<>> Print Date: 8/01/08 ACC# 93611 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 Phosphotungstic acid 1 mg/m3 TWA (as W) (listed under Tungsten, soluble compounds) Persona) Protective Equipment Eyes: Skin: Clothing: Respirators: Wear chemical splash goggles. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI 288.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Physical State: Liquid Color: Orange Odor: Alcohol-like pH: No information found Vapor Pressure: 40 mm Hg Vapor Density: 1.5 (air=1 ) Evaporation Rate: 1.4 (Butyl acetate= 1 ) Viscosity: No information found Boiling Point: 76.1-89-4°C Freezing/Melting Point: No information found Decomposition Temperature: No information found Solubility in water: Soluble. Specific Gravity/Density: 0.789 @ 21°C Molecular Formula: Solution Molecular Weight: No information found Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: High temperatures, ignition sources, excess heat, oxidizers, confined spaces Incompatibilities with Other Materials Strong oxidizing agents, strong acids, acids, alkali metals, ammonia, hydrazine, peroxides, sodium, acid anhydrides, calcium hypochlorite, chromyl chloride, nitrosyl perchlorate, bromine pentafluoride, perchloric acid, silver nitrate, mercuric nitrate, potassium tert-butoxide, magnesium perchlorate, acid chlorides, platinum, uranium hexafluoride, powdered aluminum, silver oxide, iodine heptafluoride, acetyl bromide, disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride, powdered magnesium, permanganic acid, ruthenium (VIII) oxide, uranyl perchlorate, potassium dioxide Page 5 <<>> ACC# 93611 Print Date: 8/01/08 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 Hazardous Decomposition Products Carbon monoxide, carbon dioxide, formaldehyde Hazardous Polymerization Has not been reported RTECS: CAS# 64-17-5: KQ6300000 CAS#7732-18-5: ZC0110000 CAS# 67-63-0: NT8050000 CAS# 67-56-1: PC1400000 CAS# 3520-72-7: GE4455000 CAS# 12067-99-1: TH5650000 Page 6 <<>> Print Date: 8/01/08 ACC# 93611 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 LD50/LC50: CAS# 64-17-5: Oraize test, rabbit, eye: 500 mg Severe Oraize test, rabbit, eye: 500 mg/24H Mild Oraize test, rabbit, skin: 20 mg/24H Moderate Inhalation, mouse: LC50 = 39 gm/m3/4H Inhalation, rat: LC50 = 20000 ppm/10H Oral, mouse: L050 = 3450 mg/kg Oral, rabbit: L050 =6300 mg/kg Oral, rat: L050 =7060 mg/kg Oral, rat: L050 =9000 mg/kg. CAS# 7732-18-5: Oral, rat: L050 = >90 mUkg. CAS# 67-63-0: Oraize test, rabbit, eye: 100 mg Severe Oraize test, rabbit, eye: 10 mg Moderate Oraize test, rabbit, eye: 100 mg/24H Moderate Oraize test, rabbit, skin: 500 mg Mild Inhalation, mouse: LC50 =53000 mg/m3 Inhalation, rat: LC50 = 16000 ppm/8H Inhalation, rat: LC50 =72600 mg/m3 Oral, mouse: L050 = 3600 mg/kg Oral, mouse: L050 = 3600 mg/kg Oral, rabbit: L050 =6410 mg/kg Oral, rat: L050 = 5045 mg/kg Oral, rat: L050 = 5000 mg/kg Skin, rabbit: L050 = 12800 mg/kg. CAS# 67-56-1 : Oraize test, rabbit, eye: 40 mg Moderate Oraize test, rabbit, eye: 100 mg/24H Moderate Oraize test, rabbit, skin: 20 mg/24H Moderate Inhalation, rabbit: LC50 = 81000 mg/m3/14H Inhalation, rat: LC50 =64000 ppm/4H Oral, mouse: L050 = 7300 mg/kg Oral, rabbit: L050 = 14200 mg/kg Oral, rat: L050 = 5600 mg/kg Skin, rabbit: LD50 = 15800 mg/kg. CAS# 3520-72-7: Oral, rat: L050 = >5 gm/kg. CAS# 12067-99-1 : Oral, rat: L050 =3300 mg/kg. Carcinogenicity: CAS# 64-17-5 ACGIH: Not listed California: Not listed NTP: Not listed fARC: Group 1 carcinogen CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. CAS# 67-63-0: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. CAS# 67-56-1: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. CAS# 3520-72-7: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. CAS# 12067-99-1: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Page 7 <<>> Print Date: 8/01/08 ACC# 93611 Therl110 Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 Epidemiology: Ethanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have collectively been termed the "fetal alcohol syndrome". Teratogenicity : There is no human information available. Methanol is considered to be a potential developmental hazard based on animal data. In animal experiments, methanol has caused fetotoxic or teratogenic effects without maternal toxicity. Reproductive: See actual entry in RTECS for complete information. Mutagenicity: See actual entry in RTECS for complete information. NeurotoxiCity: No information found Other: Standard Draize Test(Skin, rabbit) = 20 mg124H (Moderate) Standard Draize Test: Administration into the eye (rabbit) = 500 mg (Severe). :?~~~i~l#c;l~ ~~co:I()gical InfQfiliatf9~~~~[' Ecotoxicity: Fish: Fathead Minnow: 29.4 gIL; 96 Hr; LCSO (unspecified) Fish: Goldfish: 250 ppm; 11 Hr; resulted in death Fish: Rainbow trout: 8000 mg/L; 48 Hr; LCSO (unspecified) Fish: RainbOW trout: LCSO =13-68 mg/L; 96 Hr.; 12 degrees C Fish: Fathead Minnow: LCSO = 29400 mg/L; 96 Hr.; 25 degrees C, pH 7.63 Fish: Rainbow trout: LCSO =8000 mglL; 48 Hr.; Unspecified Bacteria: Phytobacterium phosphoreum: ECSO =51,000-320,000 mg/L; 30 minutes; Microtox test Fish: Rainbow trout: LCSO = 12900-15300 mg/L; 96 Hr; Flow-through @ 24-24.3°C Fish: Rainbow trout: LCSO =11200 mg/L; 24 Hr; Fingerling (Unspecified) Bacteria: Phytobacterium phosphoreum: ECSO = 34900 mg/L; 5-30 min; Microtox test When spilled on land it is apt to volatilize, biodegrade, and leach into the ground water, but no data on the rates of these processes could be found. Its fate in ground water is unknown. When released into water it will volatilize and probably biodegrade. It would not be expected to adsorb to sediment or bioconcentrate in fish. Environmental: When released to the atmosphere it will photodegrade in hours (polluted urban atmosphere) to an estimated range of 4 to 6 days in less polluted areas. Rainout should be significant. Physical: No information found Other: No information found Page 8 <<>> Print Date: ~8/01/08 ACC# 93611 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Part 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P Series Wastes None of the components are on this list. RCRA U Series Wastes CAS# 67-56-1: waste number U154 (Ignitable waste). USOOT Proper Shipping ALCOHOLS, Name: N.O.S. Hazard Class: 3 UN Number: UN1987 Packing Group: II USA RQ: CAS# 67-56-1: 5000 Ib final RQ; 2270 kg final RQ Canadian TOG ALCOHOLS, N.O.S. 3 UN1987 II US Federal TSCA CAS# 64-17-5 is listed on the TSCA Inventory. CAS# 7732-18-5 is listed on the TSCA Inventory. CAS# 67-63-0 is listed on the TSCA Inventory. CAS# 67-56-1 is listed on the TSCA Inventory. CAS# 3520-72-7 is listed on the TSCA Inventory. CAS# 12067-99-1 is listed on the TSCA Inventory. Health and Safety Reporting List CAS# 67-63-0: Effective 12/15/86, Sunset 12/15/96 Chemical Test Rules CAS# 67-63-0: 40 CFR 799.2325 TSCA Section 12b None of the components are on this list. TSCA Significant New Use Rule (SNUR) None of the components are on this list. CERCLA Hazardous Substances and corresponding RQs CAS# 67-56-1: 5000 Ib final RQ; 2270 kg final RQ Page 9 <<>> Print Date: 8/01/08 ACC# 93611 Thermo Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 SARA Section 302 Extremely Hazardous Substances None of the components are on this list. SARA Hazard Categories CAS# 64-17 -5: immediate, delayed, fire. CAS# 67-63-0: immediate, delayed, fire. CAS# 67-56-1: immediate, fire. CAS# 12067-99-1: immediate, fire. SARA Section 313 This material contains Isopropyl alcohol {CAS# 67-63-0, 4-5%}, which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 372. This material contains Methyl alcohol (CAS# 67-56-1, 4-5%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 372. Clean Air Act - Hazardous Air Pollutants (HAPs) CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). Clean Air Act - Class 1 Ozone Depletors None of the components are on this list. Clean Air Act - Class 2 Ozone Depletors None of the components are on this list. Clean Water Act - Hazardous Substances None of the components are on this list. Clean Water Act - Priority Pollutants None of the components are on this list. Clean Water Act - Toxic Pollutants None of the components are on this list. OSHA - Highly Hazardous None of the components are on this list. OSHA· Specifically Regulated Chemicals None of the components are on this list. US State State Right to Know Ethyl alcohol can be found on the following state Right-to-Know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. Isopropyl alcohol can be found on the following state Right-to-Know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. Methyl alcohol can be found on the following state Right-to-Know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. No information found California Prop 65 None of the components are on this list. California No Significant Risk Level None of the components are on this list. None of the components are on this list. None of the components are on this list. None of the components are on this list. None of the components are on this list. None of the components are on this list. Page 10 <<>> Thermo Print Date: 8/01/08 ACC# 93611 Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Material Safety Data Sheet OG-6 EuropeanlInternational Regulations European Labelling in Accordance with EC Directives: Hazard Symbols: F XN Risk Phrases: R 11 Highly flammable. R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Safety Phrases: S 7 Keep container tightly closed. S 9 Keep container in a well-ventilated place. S 16 Keep away from sources of ignition No smoking. S 33 Take precautionary measures against static discharges. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) No information found United Kingdom Occupational Exposure Limits No information found United Kingdom Maximum Exposure Limits No information found Canadian DSUNDSL CAS# 64-17-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 67-63-0 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 3520-72-7 is listed on Canada's DSL List. CAS# 12067-99-1 is listed on Canada's DSL List. Canadian WHMIS Classifications This product has a WHMIS classification of B2, D2A, D1 B, D2B. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List. CAS# 67-63-0 is listed on the Canadian Ingredient Disclosure List. CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List. CAS# 12067-99-1 is not listed on the Canadian Ingredient Disclosure List. iti)Il;i.(i·i.f.()tller'Infg"qfati~ij),;; No information found MSDS Creation Date: July 21, 2005 Revision Date: August 1, 2008 Page 11 <<>> ACC# 93611 Print Date: 8/01/08 Therl110 Revision Date: 8/01/2008 SCIENTIFIC Version: 2 Materia I Safety Data Sheet OG-6 This MSDS is intended for review and guidance in the receipt, storage, handling, use and disposal of product purchased from us, and for no other purpose. Use this product only as directed and in accordance with applicable instructions and warnings provided with the product. Please consult your institution's policies regarding use of this product. Ifyou have obtained this MSDS other than in connection with the supply of this product from us, this MSDS should be consulted for general information only, and should not be relied upon for any purpose. As with the use of all hazardous materials, you should in all instances follow the guidance of the MSDS provided or available with the specific product purchased. Page 12 - **truncated:** false - **body characters:** 28892