# Sandia National Laboratories, New Mexico — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 12-0058
- **title:** Sandia National Laboratories, New Mexico — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2012-04-05
- **effective on:** Not available
- **summary:** 12-0058 response to Sandia National Laboratories, New Mexico concerning 173.22.
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- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/legacy/interpretations/Interpretations/2012/120058.pdf
**body:**

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U.S. Department
of Transportation
Pipeline and Hazardous
Materials Safety
Administration
1200 New Jersey Avenue, SE
Washington, D.C. 20590
APR 0 s 2312
Mr. David Castillo
Sandia National Laboratories, New Mexico
Regulated Waste and Pollution Prevention Department, 04144
P.O. Box 5800, MS1112
Reference No.: 12-0058
Dear Mr. Castillo:
This responds to your February 21, 2012 letter requesting clarification of the Hazardous
Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to proper shipping names.
Specifically, you note that a manufacturer's documentation for the chemical
1-Hydroxybenzotriazole hydrate indicates it contains 14% water by mass. You add that the
stoichiometric calculation of water contained in the 1-Hydroxybenzotriazole, monohydrate
is 13.3% by mass. You ask which of the two Proper Shipping Name entries in the HMR
table apples: UN0508, 1-Hyrdroxybenzotriazole, anhydrous, dry or wetted with less than
20% water by mass, or UN3474, 1-Hydroxybenzotriazole, monohydrate?
Under§ 173.22, it is the shipper's responsibility to classify a hazardous material. This Office
does not normally perform this function. However, because the 1-Hydroxybenotriazole hydrate
contains less than 20% water by mass, it is the opinion of this Office that UN0508,
1-Hydroxybenzotrizole, anhydrous, d1y or wetted with less than 20% water by mass, would be
the proper shipping name.
I hope this satisfies your inquiry. Please contact us if we can be of further assistance.
Sincerely,
T. Glenn Foster
Chief, Regulatory Review and Reinvention Branch
Standards and Rulemaking Division

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From: Castillo, Dave H [mailto:DHCASTI@sandia.gov]
Sent: Tuesday, February 21, 2012 5:17PM
To: Lawson, Eleanor (PHMSA)
Cc: Schade, A Carl; Krauss, Maryann; Tetreault, Kenneth J
Subject: Interpretation
Importance: High
Eleanor,
Per our phone discussion today, I have the following question:
If the manufacture's documentation for the chemicai1-Hydroxybenzotriazole hydrate indicates it
contains 14% water by mass, which of the two Proper Shipping Name entries in the November 1, 2011
Hazardous Materials Table applies: 1-Hydroxybenzotriazole, anhydrous, dry or wetted with less than
20% water by mass, (UN0508) or 1-Hydroxybenzotriazole, monohydrate (UN3474)?
It should be noted that the stoichiometric calculation of water contained in 1-Hydroxybenzotriazole,
monohydrate is 13.3% by mass. Therefore, it is not clear if the hydrate/monohydrate forms should be
regarded as the anhydrous form when the total water is below 20%. Please let me know if you need any
other information. Thanks.
David Castillo
Sandia National Laboratories, New Mexico
Regulated Waste and Pollution Prevention Department, 04144
P.O. Box 5800, MS1112
Albuquerque, NM 87185-1112
Office (505) 284-4192
Cell (505) 269-1705
Pager(505)951-6340
Fax(505)284-4034
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