{"operation":"document","citation":"17-0067","title":"Public Works - Naval Station Everett — Hazardous Materials Safety Interpretation","source_type":"guidance","agency":"Pipeline and Hazardous Materials Safety Administration","status":"guidance","official":true,"published_on":"2017-11-16","effective_on":null,"summary":"17-0067 response to Public Works - Naval Station Everett concerning 173.22.","machine_formats":{"json":"https://regulus.evalyn.ai/document/phmsa-interpretation-17-0067.json","markdown":"https://regulus.evalyn.ai/document/phmsa-interpretation-17-0067.md"},"app_url":"https://regulus.evalyn.ai/document/phmsa-interpretation-17-0067","source_url":"https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/docs/standards-rulemaking/hazmat/interpretations/69891/170067.pdf","body":"<<<PAGE 1>>>\n\nPublic Works\nNaval Station Everett\n2000 W Marine View Drive\nEverett, WA 98207\nReference No. 17-0067\nDear Mr. Roley:\nThis letter is in response to your June 14, 2017, e-mail requesting clarification of the Hazardous\nMaterials Regulations (HMR; 49 CFR Parts 171-180) applicable to classification. Specifically,\nyou ask whether the products listed in the Material Safety Data Sheets (MSDS) you provided\nwould be considered hazardous materials under the HMR.\nIn accordance with § 173.22 of the HMR, it is the shipper's responsibility to classify a hazardous\nmaterial. This Office does not normally perform this function. However, based on the\ninformation provided in your e-mail, it is the opinion of this Office that both the \"All Purpose\nSAE 10W-40 Four Stroke Engine Oil\" and \"TGMO SN 5W-30\" oil have flash points above\n200 °F and are not considered to be a flammable or combustible liquid under the HMR.\nTherefore, provided these oils do not meet any other hazard classes, they would not be subject to\nthe requirements of the HMR.\nI hope this information is helpful. Please contact us if we can be of further assistance.\nSincerely,\nT. Glenn Foster\nChief, Regulatory Review and Reinvention Branch\nStandards and Rulemaking Division\n\n<<<PAGE 2>>>\n\nHi Shante/Alice,\nPlease submit this as a letter of interpretation. Mr. Roley spoke with Eamonn.\nPlease let me know if you have any questions.\nThanks,\nJordan\n-----Original Message----\nFrom: Roley, Andrew BLT NAVFAC NW, PRE2 [mailto:andrew.roley@navy.mil]\nSent: Wednesday, June 14, 2017 2:27 PM\nTo: INFOCNTR (PHMSA) < INFOCNTR.INFOCNTR@dot.gov>\nSubject: Request for Interpretation\n[resending attachments]\nGood morning, PHMSA.\nI was speaking with Eamonn in your office earlier today, who assisted with some informal guidance over the phone. He\nsuggested sending this request via email for formal guidance when I requested a written response.\nBackground: 1 am in the United States Navy and recently moved from Naval Station Guantanamo Bay, Cuba, to Everett,\nWA. As part of my orders, I am entitled to movement of household goods. This excludes any hazardous material. I had\nattempted to \"offer\" two types of motor oil for shipment, and classified them as being non-hazardous based on their\nSDSs (attached). The Naval Supply Systems Command (NAVSUP), who utilized a contractor to pack and move my goods,\noverrode my classification, saying it was flammable, specifically a \"petroleum product\" (The Defense Transportation\nRegulation lists \"Petroleum products\" as an example of prohibited flammable materials). They made this determination\nwithout viewing the SDSs and did not change it after I provided the SDSs (I do not believe they were read, though). I\nthen mailed it through the military postal service agency (which NAVSUP manages a portion of) with the SDSs attached\nwith no issues, and submitted for reimbursement. NAVSUP again said it was a hazardous material not allowable to be\nreimbursed for shipment.\nQuestions:\n1) Are either of these materials classifiable as petroleum products?\n2) Are either of these materials classifiable as a flammable or combustible liquid?\n3) Would these materials be regulated in any other way under Hazardous Material Regulations?\nI apologize if these seem to be very easy and straight forward questions based on the SDS contents. However, I believe\nyour expert formal opinion may be needed to convince NAVSUP of the answers and to receive reimbursement.\n1\n\n<<<PAGE 3>>>\n\n425-304-3637\n\n<<<PAGE 4>>>\n\nProduct Name:\nYama lube Performance All Purpose SAE 10W-40 Four Stroke Engine Oil\n\"Distributed by Yamaha Motor Corporation, U.S.A.\"\nIdentification of the\nJ Nippon Oil & Energy USA Inc.\nsupplier:\nAddress:\n20 N. Martingale., Suite 325, Schaumburg, IL 60173\nCharge section:\n(TEL: +1-847-413-2188)\n2. Hazards identification\nhazard category\nCategory\nFlammable liquids\nNo Classification\nAcute toxicity (oral)\nNo Classification\nAcute toxicity (dermal)\nNo Classification\nSpecific target organ systemic toxicity\nNo Classification\nfollowing single exposure\nSpecific target organ systemic toxicity\nNo Classification\nAspiration hazard\nfollowing repeated exposure\nNo Classification\nLABEL ELEMENTS\nPrecautionary pictograms:\nNot applicable\nSignal word:\nNot applicable\nHazard Statement\nNot applicable\nrecautionary Statements\nPrevention Do not handle until all safety precautions have been read and\nunderstood.\nWear protective gloves/protective clothing/eye protection/face\nprotection.\nDo not allow the eyes to become exposed to the product. Do not\nswallow the product.\nWash hands thoroughly after handling.\nDo no eat, drink or smoke when using this product.\nResponse IF SWALLOWED: Immediately call a POISON CENTER or\ndoctor/physician.\nIF SWALLOWED: rinse mouth. Do NOT induce vomiting.\nIf the eyes are exposed to the product: Rinse the eyes with\nIF ON SKIN: Wash with plenty of soap and water.\nON SKIN: Wash with plenty\nwater and immediately contact a physician.\nStorage The product must be stored in a cool, well-ventilated locatior\nhere it will not be exposed to direct sunlight\nContainers that have been opened must be tightly sealed.\nDisposal Dispose of contents/container in accordance with\nlocal/regional/national/international regulations.\nIf there are any doubts about proper methods of handling the\nproduct, contact the point of purchase before proceeding with\nusage.\n\n<<<PAGE 5>>>\n\nSubstance/Mixture:\nMixture\nIngredients and Concentration\nIngredient Name\nConcentrationwt. %\nBase Oil (s)\n80-90\nAdditives\nK20\n4. First-aid measures\nInhalation:\nIF INHALED: Remove victim to fresh air and keep at rest in a\nposition comfortable for breathing.\nCover the body with blankets to keep warm and quiet. If you feel\nlersathi keep warm and quiet. If you feel\nunwell, seek medical advice.\nSkin Contact:\nImmediately flush skin with\nlarge amounts\nof water.\nWash contaminated clothing before reuse.\nIf skin irritation occurs: Get medical\nadvice/attention.\nEye Contact:\nRinse with clean water\ncarefully for several minutes.\ncontact lenses if present and if removal\nrinsinto inse for 15 minutes zt a mininun and seek medical\nIngestion:\ncontrol\nDo not induce vomiting. Drink water. Call a physician or poison\ncenter immediately.\n5. Fire-fighting measures\nSuitable Extinguishing Media:\nMist of loaded liquid, dry chemicals, carbon dioxide, fire foam,\nand dry sand are effective.\nExtinguishing Media to Avoid:\nUse of\nstraight steam of water can cause a risk of spreading\nfire.\nSpecific hazards arising from the\nIn some cases of fire, may release irritant gases.\nchemical:\nWhen burnt, may generate carbon monoxide and other toxic gases.\nFire Fighting:\nSpray water to the surrounding facilities for cooling.\nleep unauthorized persons off the site of occurrence of fire and\nEven after extinction, cool containers thoroughly with plenty of\nthe surroundings\nwater.\npecial protective equipment an\nWear fire/flame resistant/retardant clothing.\nrecautions for fire fighters\nFight fire from windward direction while wearing protective\nequipment. If contact with skin is expected, wear impervious\nUse air-breathing apparatus and protective clothing whenever\nprotective equipment and gloves.\nnecessary.\n\n<<<PAGE 6>>>\n\nPersonal precautions, protective\nWear protective equipment when working.\nequipment and emergency procedures:\nRemove nearby potential ignition sources immediately.\nWhen mist is generated, use respiratory equipment to prevent\ninhalation of mist.\nDo not touch or walk through spillage.\nPay attention to the site of spillage, which is slippery.\nEnvironmental precautions:\nPrevent spreading of oil spill with earth and sand, sandbags,\nother proper materials and use care not to allow the oil spill\nto all on the oil spill\nto flow to street drains, sewer systems, and rivers.\nAt sea, install oil spill containment booms to prevent spreading\nof spills and absorb with absorption mat or other proper\none arg spreading\nmaterials.\nMethods and materials for\nIn case of spillage in small quantity, collect spillage by\ncontainment and cleaning up:\nabsorbing with earth, sand, sawdust, waste, or other proper\nmaterials.\nIn case of spillage in large quantity, enclose with\nto prevent spreading of spillage and collect spillage in empty\nembankment\ncontainers to the\nextent possible.\nPrevention of second accident:\nIn case of spillage,\nimmediately\ninform the organizations\nconcerned of the spillage to prevent possible accidents and\nspreading of spillage.\nRemove nearby potential ignition sources immediately and make\nand ventilate and clean the site and the surroundings.\nfire-extinguishing agents available. Remove spillage completely,\n7. Handling and storage\nHandling\nTechnical Measures:\nKeep away from any possible contact with sparks, open flames,\nand high-temperature materials, and do not allow release of\nvapor without justification.\nUse pumps or other proper equipment for taking out from\ncontainers. Do not siphon with your mouth using a tube. Do not\ndrink.\nWhen mist is generated, use respiratory equipment to prevent\ninhalation of mist.\nIn case of vapor/mist dispersion, install a closed system, local\nventilation system, and/or other proper equipment for the\nsources of vapor/mist generation.\nAvoid rough handling of containers such as falling, dropping,\nVentilation\nexposing to shock, and dragging.\nMaintain adequate ventilation when handling indoors.\nrequirements:\nPrecautions:\nWash hands and face thoroughly after handling.\nBe careful with fire.\nandling\nrecautions for saf\nAvoid falling, dropping, exposing to shock, or dragging of\ncontainers.\n\n<<<PAGE 7>>>\n\nStorage\nStorage Conditions:\nStore in a well ventilated, cool, dry, dark place, protecting\nfrom direct sunlight and keeping away from any potential\nignition sources and high-temperature materials.\nStore tightly stopped after use to prevent possible\nreferably store locked up in a proper storage area\nontamination with dust and moisture\nSafety adequate\nUse spill-proof containers that are free of damage/corrosion.\ncontainer materials:\n8. Exposure controls/personal protection\nAppropriate engineering controls:\nIn case of mist generation, enclose the source of mist\ngeneration,\nor install a ventilation system.\nInstall eye cleaning and body cleaning equipment near the\nhandling site.\nControl parameters\nJapan Society for\nIngredient Name\nOccupational\nACGIH\nOccupational\nExposure Limits\nTLV-STEL\nTLV-TWA\nBase Oil (s)\nNone established\nNone established\nNone established\n3mg/m3 (Mineral Oil None\nppm,\nppm,\nppm,\nMist)\n5mg/m3 (Mineral Oil\nestablishedmg/m3\n(Mist)\nPersonal Protective Equipment\nRespiratory Protection: Not needed under normal conditions, but wear a gas mask (against\norganic gases) whenever required\nHand protection:\nIn case of prolonged or repeated exposure, wear oil-resistant\nEye/face protection:\nSkin Protection:\nIn case of exposure to splashes, wear ordinary type goggles.\nIn case of handling over a prolonged period of time or in case\nPle of co tell eat ol red at loraler torte rouse.\nHygiene Measures:\nWash hands thoroughly after handling.\n9. Physical and chemical properties\nProduct\nPhysical state:\nLiquid\nForm:\nLiquid\nColor:\nYellow\nSlight odor\n\n<<<PAGE 8>>>\n\nFlash point:\n224 (°C) Cleveland Open Cup\nAuto-ignition\nEstimate200-410 (°C)\ntemperature:\nVapour density:\nNo data.\nDensity (g/cm3) :\n0. 86(15°C)\nSolubility:\nwater: Insoluble.\nPartition coefficient: n-No data.\noctanol/water:\nDecomposition\nNo data.\ntemperature:\n10. Stability and reactivity\nChemical stability:\nStable when stored or preserved in a dark place at room temperature.\nPossibility of hazardous\nKeep away from any possible contact with strong oxidizing agents.\nreactions:\nConditions to avoid:\nContact with incompatible hazard substances\nProlonged heating, open flames, and ignition sources\nIncompatible materials:\nIse care to keep away from any possible contact with halogens, strong\nHazardous decomposition\nWhen burnt, may release carbon monoxide and other gases.\nproducts:\n11. Toxicological information\nProduct\nAcute toxicity (oral):\nFor mixtures, hazard category was identified based on\nthe\nclassification criteria for mixtures.\nAcute toxicity (dermal):\nFor mixtures,\nhazard category was identified based on\nthe classification criteria for mixtures.\nAcute toxicity (inhalation):\nFor mixtures, hazard category was identified based on\nthe classification criteria for mixtures.\nSkin corrosion/irritation:\nthe classification criteria for mixtures.\nFor mixtures, hazard category was identified based\nSerious eye damage/irritation:\nFor mixtures,\nhazard category was identified based on\nthe\nclassification criteria for mixtures.\nRespiratory sensitization:\nFor mixtures, hazard category was identified based on\nthe\nclassification criteria for mixtures.\nSkin sensitization:\nFor mixtures,\nhazard category was identified based on\nthe\nclassification criteria for mixtures.\nMutagenicity:\nFor mixtures, hazard category was identified based on\nthe\nclassification criteria for mixtures.\nCarcinogenicity:\nFor mixtures,\nhazard category was\nidentified based on\nthe classification criteria for mixtures.\nReproductive\ntoxicity:\nFor mixtures, hazard category was identified based on\nthe classification criteria for mixtures.\nTarget organ effect/Single\nFor mixtures, hazard category was identified based\non\nexposure:\nthe classification criteria for mixtures.\n\n<<<PAGE 9>>>\n\nRespiratory toxic:\nFor mixtures, hazard category was identified based on\nthe classification criteria for mixtures.\nIngredient\nBase Oil (s)\nAcute toxicity (oral):\nLD50: ≥ 5000 mg/kg[rat]\nAcute toxicity (dermal):\nLD50: ≥ 5000 mg/kg[rat]\nSerious eye damage/irritation:\nPractically None [rabbit]\nSkin sensitization:\nNone\nBuehler method [guinea pig]\nMutagenicity:\nAmes Test: Negative\nCarcinogenicity:\nEU: Category 2 : R45 need not apply. (NOTE L is\nApplicable), IARC:3\n12. Ecological information\nProduct\nEcotoxicity\nFish acute toxicity:\nFor mixtures, hazard category was identified based on\nAlgae acute toxicity:\nthe classification criteria for mixtures.\nFor mixtures, hazard category was identified based on\nFish chronic toxicity:\nthe classification criteria for mixtures.\nFor mixtures, hazard category was identified based on\nAlgae chronic toxicity:\nclassification criteria for mixtures.\nFor mixtures, hazard category was identified based on\nthe classification criteria for mixtures.\nIngredient\nBase Oil(s)\nEcotoxicity\nFish acute toxicity:\n96hLC50: > 5000 mg/L[Oncorhynchus mykiss]\nDaphnia acute toxicity:\n48hEC50: > 1000 mg/L[Daphnia magna]\n13. Disposal considerations\nDisposal\nDispose of contents/container in accordance with local/regional/national/international\nmethods:\nregulations.\nEvery customer/user of the product should dispose of industrial waste on its own\nresponsibility, otherwise it must rely on a company authorized by prefectural governor\nfor treating industrial waste or a local public body involved in the disposal of\nindustrial waste for proper disposal.\nBefore disposal of used container, remove contents completely.\n14. Transport information\nIMDG\nUN classification:\nNot applicable\n\n<<<PAGE 10>>>\n\n15. Regulatory information\nKorea (KECL) :\nAll components are listed or exempted.\nAustralia (AICS) :\nCanada (DSL) :\nAll components are listed or exempted.\nAll components are listed or exempted\nChina (IECSC) :\nAll components are listed or exempted.\nEU (REACH) :\nlisted, in the case\nIn the case where one or more components are not listed or, even if\napplication or notification is required.\nof importing to the country or area concerned, an\nNew Zealand (NZIoC) :\nAll components are\nUSA (TSCA):\nlisted or exempted.\nPhilippines (PICCS):\nAll components are listed or exempted.\nAll components are listed or exempted\nTaiwan:\nIn the case where one or more components are not listed or, even if\napplication or notification is required.\nlisted, in the case of importing to the country or area concerned, an\n16. Other information\nDisclaimer\nNe at JX Nippon Oil & Energy Corporation have prepared the copyrighter\nSafety Data Sheet to provide reference information on the hazardous\nchemical product of interest for our customers/users to ensure secure and\nse would like every customer/user of the product to refer to the\ninformation and understand the necessity of taking appropriate measures\nfor the actual handling conditions on their own responsibilities for\noptimum practical application of the product of interest.\nConsequently,\nthe Safety Data Sheet is not intended to guarantee the\nof the product referenced to herein.\n\n<<<PAGE 11>>>\n\nPRODUCT\nProduct Name: TGMO SN 5W-30\nProduct Description:\nBase Oil and Additives\nProduct Code:\n20201030C056,\n477547-00,\n97Z831\nEngine oil\nCOMPANY IDENTIFICATION\nSupplier:\nEXXON MOBIL CORPORATION\n22777 Springwoods Village Parkway\nSpring, TX. 77389\nUSA\n24 Hour Health Emergency\n609-737-4411\n800-424-9300 or 703-527-3887 CHEMTREC\n800-662-4525\nhttp://www.exxon.com, http://www.mobil.com\n[SECTION 2\nHAZARDS IDENTIFICATION\nThis material is not hazardous according to regulatory guidelines (see (M)SDS Section 15).\nOther hazard information:\nHAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200.\nPHYSICAL / CHEMICAL HAZARDS\nNo significant hazards.\nHEALTH HAZARDS\nor ies pirats erition under skin may cause serious damage. Excessive exposure may result in eye, skin,\nENVIRONMENTAL HAZARDS\nNo significant hazards.\nNFPA Hazard ID:\nHealth:\nFlammability:\nReactivity:\nHMIS Hazard ID:\nHealth:\nFlammability:\nReactivity:\nNOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert\nfrom person to person.\nadvice. Health studies have shown that chemical exposure may cause potential human health risks which may vary\n\n<<<PAGE 12>>>\n\nHazardous Substances or complex substance s) required for disclosure\nName\nCAS#\nConcentration*\nGHS Hazard Codes\nSEVERELY HYDROTREATED HEAVY PARAFFINIC\n64742-54-7\n1 - < 5%\nH304\nDISTILLATE\nSOLVENT DEWAXED HEAVY PARAFFINIC DISTILLATE\n64742-65-0\n1 - < 5%\nH304\n* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.\nAs per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and\nexact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact\npercentage composition will be provided to health professionals, employees, or designated representatives in\naccordance with applicable provisions of paragraph (i).\nSECTION 4\nFIRST AID MEASURES\nINHALATION\nRemove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use\nadequate respiratory protection. It respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek\nimmediate medical assistance.\nIf breathing has stopped, assist ventilation with a mechanical device or use\nmouth-to-mouth resuscitation.\nSKIN CONTACT\nWash contact areas with soap and water. If product is injected into or under the skin, or into any part of the\na physician as a surgical emergency. Even though initial symptoms from high pressure injection may be\nbody, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by\nminimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent\nEYE CONTACT\nFlush thoroughly with water. If irritation occurs, get medical assistance.\nINGESTION\nFirst aid is normally not required. Seek medical attention if discomfort occurs.\nSECTION 5\nFIRE FIGHTING MEASURES\nEXTINGUISHING MEDIA\nAamepriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish\nInappropriate Extinguishing Media: Straight Streams of Water\nFIRE FIGHTING\n\n<<<PAGE 13>>>\n\noxides, Oxides of carbon\nFLAMMABILITY PROPERTIES\nFlash Point [Method]: >200°C (392°F) [ASTM D-92]\nFlammable Limits (Approximate volume % in air): LEL: 0.9\nUEL: 7.0\nAutoignition Temperature: N/D\nSECTION 6\nACCIDENTAL RELEASE MEASURES\nNOTIFICATION PROCEDURES\nIn the event of a spill or accidental release, notify relevant authorities in accordance with all applicable\nregulations. Us regulations require reporting releases of this material to the environment which exceed the\napplicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The\nNational Response Center can be reached at (800)424-8802.\nPROTECTIVE MEASURES\nAvoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification\nSection for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum\nrequirements for personal protective equipment. Additional protective measures may be necessary, depending\non the specific circumstances and/or the expert judgment of the emergency responders.\nFor emergency responders: Respiratory protection: respiratory protection will be necessary only in special\ncases, e.g., formation of mists. Half-face or full-face respirator with filters) for dust/organic vapor or Self\nburganic apor or sel\nContained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of\nexposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible\nor anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended.\nGloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use.\nChemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic\nwork clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is\nrecommended\nSPILL MANAGEMENT\nLand Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.\nWater Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other\nshipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist\nbefore using dispersants.\nWater spill and land spill recommendations are based on the most likely spill scenario for this material;\nhowever, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction\nand speed may greatly influence the appropriate action to be taken. For this reason, local experts should be\nconsulted. Note: Local regulations may prescribe or limit action to be taken.\nENVIRONMENTAL PRECAUTIONS\nLarge Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,\n\n<<<PAGE 14>>>\n\nHANDLING\nAvoid contact with used product. Prevent small spills and leakage to avoid slip hazard.\naccumulate static charges which may cause an electrical spark (ignition source). When the material is handlec\nin bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g.,\nduring switch-loading operations).\ngrounds may not eliminate the hazard from static accumulation. Consult local applicable standards for\nguidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions\nArising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended\nPractice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance\nof hazards due to static electricity.\nStatic Accumulator:\nThis material is a static accumulator.\nThe container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store\nin open or unlabelled containers.\nSECTION 8\nEXPOSURE CONTROLS / PERSONAL PROTECTION\nEXPOSURE LIMIT VALUES\nExposure limits/standards (Note: Exposure limits are not additive)\nSubstance Name\nForm\nLimit / Standard\nNOTE\nSource\nSEVERELY HYDROTREATED HEAVY\nInhalable\nTWA\n15 mg/m3\nN/A\nACGIH\nPARAFFINIC DISTILLATE\nfraction\nSEVERELY HYDROTREATED HEAVY\nMist.\nTWA\n5 mg/m3\nN/A\nACGIH\nPARAFFINIC DISTILLATE\nSOLVENT DEWAXED HEAVY\nTWA\nPARAFFINIC DISTILLATE\nMist.\n5 mg/m3\nN/A\nOSHA Z1\nSOLVENT DEWAXED HEAVY\nTWA\nPARAFFINIC DISTILLATE\n2000\n500 ppm\nN/A\nOSHA Z1\nmg/m3\nSOLVENT DEWAXED HEAVY\nMist.\nTWA\n15 mg/m3\nN/A\nACGIH\nPARAFFINIC DISTILLATE\nExposure limits/standards for materials that can be formed when handling this product: When mists/aerosols\ncan occur the following are recommended: 5 mg/m - ACGIH TLV (inhalable fraction), 5 mg/m - OSHA PEL.\nNOTE: Limits/standards shown for guidance only. Follow applicable regulations.\nNo biological limits allocated.\nENGINEERING CONTROLS\nThe level of protection and types of controls necessary will vary depending upon potential exposure conditions.\nControl measures to consider:\n\n<<<PAGE 15>>>\n\nwith this material, as provided below, is based upon intended, normal usage.\nBabul re select protective equipment for use\nRespiratory Protection:\nIf engineering controls do not maintain airborne contaminant concentrations at a\nlevel which is adequate to protect worker health, an approved respirator may be appropriate.\nRespirator\nselection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of\nrespirators to be considered for this material include:\nNo special requirements under ordinary conditions of use and with adequate ventilation.\nFor high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.\nSupplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,\ngas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded\nHand Protection:\nAny specific glove information provided is based on published literature and glove\nmanufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.\nContact the glove manufacturer for specific advice on glove selection and breakthrough times for your use\nconditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material\ninclude:\nNo protection is ordinarily required under normal conditions of use.\nEye Protection: If contact is likely, safety glasses with side shields are recommended.\nSkin and Body Protection:\nmanufacturer data.\nAny specific clothing information provided is based on published literature or\nThe types of clothing to be considered for this material include:\nNo skin protection is ordinarily required under normal conditions of use. In accordance with good\nindustrial hygiene practices, precautions should be taken to avoid skin contact.\nSpecific Hygiene Measures:\nAlways observe good personal hygiene measures, such as washing after\nhandling the material and before eating, drinking, and/or smoking.\nRoutinely wash work clothing and protective\nequipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.\nPractice good housekeeping.\nENVIRONMENTAL CONTROLS\nComply with applicable environmental regulations limiting discharge to air, water and\nsoil. Protect the environment by applying appropriate control measures to prevent or limit\nemissions.\nSECTION 9\nPHYSICAL AND CHEMICAL PROPERTIES\nNote: Physical and chemical properties are provided for safety, health and environmental considerations only\nand may not fully represent product specifications. Contact the Supplier for additional information.\nGENERAL INFORMATION\nPhysical State:\nLiquid\nColor: Amber\nOdor:\nCharacteristic\n\n<<<PAGE 16>>>\n\nFlammable Limits (Approximate volume % in air): LEL: 0.9\nUEL: 7.0\nAutoignition Temperature: N/D\nBoiling Point / Range:\n> 316°C (600°F)\nDecomposition Temperature: N/D\nVapor Density (Air = 1):\n> 2 at 101 kPa\nVapor Pressure:\n< 0.013 kPa (0.1 mm Hg) at 20 °C\nEvaporation Rate (n-butyl acetate = 1): N/D\nLog Pow (n-Octanol/Water Partition Coefficient): > 3.5\nSolubility in Water:\nNegligible\nViscosity:\n61.9 cSt (61.9 mm2/sec) at 40 °C | 10.5 cSt (10.5 mm2/sec) at 100°C\nOxidizing Properties: See Hazards Identification Section.\nOTHER INFORMATION\nFreezing Point: N/D\nMelting Point: N/A\nPour Point:\n-27°C (-17°F)\nDMSO Extract (mineral oil only), IP-346:\n< 3 %wt\nSECTION 10\nSTABILITY AND REACTIVITY\nREACTIVITY: See sub-sections below.\nSTABILITY: Material is stable under normal conditions.\nCONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.\nMATERIALS TO AVOID:\nStrong oxidizers\nHAZARDOUS DECOMPOSITION PRODUCTS:\nMaterial does not decompose at ambient temperatures.\nPOSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.\nSECTION 11\nTOXICOLOGICAL INFORMATION\nINFORMATION ON TOXICOLOGICAL EFFECTS\nHazard Class\nConclusion / Remarks\nInhalation\nAcute Toxicity: No end point data for\nmaterial.\nMinimally Toxic. Based on assessment of the components.\nIrritation: No end point data for material.\nNegligible hazard at ambient/normal handling temperatures.\nIngestion\nAcute Toxicity: No end point data for\nmaterial.\nMinimally Toxic. Based on assessment of the components.\n\n<<<PAGE 17>>>\n\nSerious Eye Damage/Irritation: No end point\nMay cause mild, short-lasting discomfort to eyes. Based on\ndata for material.\nassessment of the components.\nSensitization\nfor material.\nRespiratory Sensitization: No end point data\nNot expected to be a respiratory sensitizer.\nSkin Sensitization: No end point data for\nNot expected to be a skin sensitizer. Based on assessment of the\nmaterial.\ncomponents.\nAspiration: Data available.\nNot expected to be an aspiration hazard. Based on\nGerm Cell Mutagenicity: No end point data\nphysico-chemical properties of the material.\nfor material.\nNot expected to be a germ cell mutagen. Based on assessment of\nCarcinogenicity: No end point data for\nNot expected to cause cancer. Based on assessment of the\nReproductive Toxicity: No end point data\nNot expected to be a reproductive toxicant. Based on assessment\nLactation: No end point data for material.\nof the components.\nNot expected to cause harm to breast-fed children.\nSpecific Target Organ Toxicity (STOT)\nSingle Exposure: No end point data for\nNot expected to cause organ damage from a single exposure.\nNot expected to cause organ damage from prolonged or repeated\nexposure. Based on assessment of the components.\nOTHER INFORMATION\nFor the product itself:\nDiesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any\ncarcinogenic effects in chronic mouse skin painting studies.\nOils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in\nanimal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds\n(PAC) from combustion products of gasoline and/or thermal degradation products.\nBase oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames\ntest, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of\nimmune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals\nThe following ingredients are cited on the lists below: None.\n-REGULATORY LISTS SEARCHED--\n1 = NTP CARC\n3 = IARC 1\n2 = NTP SUS\n5 = IARC 2B\n4 = IARC 2A\n6 = OSHA CARC\n\n<<<PAGE 18>>>\n\nMaterial -- Not expected to be harmful to aquatic organisms.\nMOBILITY\nExpected to partition to sediment and wastewater solids.\nBase oil component - Low solubility and floats and is expected to migrate from water to the land.\nPERSISTENCE AND DEGRADABILITY\nBiodegradation:\nBase oil component -- Expected to be inherently biodegradable\nBIOACCUMULATION POTENTIAL\nBase oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may\nreduce the bioconcentration or limit bioavailability.\nSECTION 13\nDISPOSAL CONSIDERATIONS\nDisposal recommendations based on material as supplied. Disposal must be in accordance with current applicable\nlaws and regulations, and material characteristics at time of disposal.\nDISPOSAL RECOMMENDATIONS\nProduct is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised\nincineration at very high temperatures to prevent formation of undesirable combustion products. Protect the\nbrake fluids or coolants.\nenvironment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents,\nREGULATORY DISPOSAL INFORMATION\nRCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous\nwaste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It\ndoes not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with\ncontaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used\nproduct may be regulated\nEmpty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and\ncan be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be\ncompletely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken\nfor recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with\ngovernmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE\nSUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION\nTHEY MAY EXPLODE AND CAUSE INJURY OR DEATH.\n\n<<<PAGE 19>>>\n\nLAND (TDG):\nNot Regulated for Land Transport\nSEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code\nMarine Pollutant: No\nAIR (IATA): Not Regulated for Air Transport\nSECTION 15\nREGULATORY INFORMATION\nOSHA HAZARD COMMUNICATION STANDARD:\nThis material is not considered hazardous in accordance with\nOSHA HazCom 2012, 29 CFR 1910.1200.\nListed or exempt from listing/notification on the following chemical inventories:\nDSL, KECI, PICCS, TSCA\nEPCRA SECTION 302: This material contains no extremely hazardous substances.\nSARA (311/312) REPORTABLE HAZARD CATEGORIES: None.\nSARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification\nrequirements of the SARA 313 Toxic Release Program.\nThe following ingredients are cited on the lists below:\nChemical Name\nCAS Number\nList Citations\nDIPHENYLAMINE\n122-39-4\nZINC ALKYLDITHIOPHOSPHATE\n18\n68649-42-3\nZINC DITHIOPHOSPHATE\n15,19\n68649-42-3\nI 15, 19\n-REGULATORY LISTS SEARCHED.-\n1 = ACGIH ALL\n6 = TSCA 5a2\n11 = CA P65 REPRO\n16 = MN RTK\n2 = ACGIH A1\n7 = TSCA 5e\n12 = CA RTK\n3 = ACGIH A2\n17 = NJ RTK\n8 = TSCA 6\n13 = IL RTK\n18 = PA RTK\n4 = OSHA Z\n9 = TSCA 12b\n14 = LA RTK\n19 = RI RTK\n5 = TSCA 4\n10 = CA P65 CARC\n15 = MI 293\n\n<<<PAGE 20>>>\n\nND No termed, NA - Not applicable\nKEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):\nH304: May be fatal if swallowed and enters airways; Aspiration, Cat 1\nTHIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:\nUpdates made in accordance with implementation of GHS requirements.\nThe information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate\nand reliable as of the date issued.\navailable from ExxonMobil. The information and recommendations are offered for the user's consideration and\nexamination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use.\nrepackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is\nincluded with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to\nhandlers and users. Alteration of this document is strictly prohibited.\nExcept to the extent required by law,\nre-publication or retransmission of this document, in whole or in part, is not permitted. The term, \"ExxonMobil\" is used\nfor convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any\naffiliates in which they directly or indirectly hold any interest.\nInternal Use Only\nМНС: ов, Ов, 0, 0, 0, 0\nPPEC: A\nDGN: 7010885XUS (1018590)\nCopyright 2002 Exxon Mobil Corporation, All rights reserved","truncated":false,"body_characters":36109}