# ACA International LLC — Hazardous Materials Safety Interpretation - **operation:** document - **citation:** 19-0099 - **title:** ACA International LLC — Hazardous Materials Safety Interpretation - **source type:** guidance - **agency:** Pipeline and Hazardous Materials Safety Administration - **status:** guidance - **official:** true - **published on:** 2019-10-08 - **effective on:** Not available - **summary:** 19-0099 response to ACA International LLC concerning 177.834. - **machine formats:** - **json:** https://regulus.evalyn.ai/document/phmsa-interpretation-19-0099.json - **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-19-0099.md - **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-19-0099 - **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/docs/standards-rulemaking/hazmat/interpretations/72581/190099.pdf **body:** <<>> U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration OCT O 8 2019 1200 New Jersey Avenue, SE Washington, DC 20590 Tim Farrell ACA International LLC 129 Newbury Street Boston, MA 02116 Reference No. 19-0099 Dear Mr. Farrell: This letter is in response to your August 6, 2019, email and subsequent phone call requesting clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to transportation of a cargo tank motor vehicle (CTMV) on a removeable gooseneck (RGN) trailer. Specifically, you ask whether the HMR prohibits the transportation of a filled or partially filled CTMV on a RGN trailer. The answer is no, the HMR does not prohibit the transportation of a filled or partially filled CTMV on a RGN trailer. Please note that all applicable HMR requirements, including hazard communication such as markings and placards, continue to apply when the filled or partially filled CTMV is the object of carriage, rather than the actual vehicle used to transport the hazardous material cargo. Also, please be aware that§ 177.834(a) requires that the CTMV be secured against shifting during transportation while loaded on the RGN trailer. I hope this information is helpful. Please contact us if we can be of further assistance. Smc, ~_/4 2, ~ ei:7' Chief, Standards Development Branch Standards and Rulemaking Division <<>> Dodd, Alice (PHMSA) From: Sent: To: Subject: Attachments: INFOCNTR (PHMSA) Tuesday, August 06, 2019 10:42 AM Hazmat Interps FW: REQUEST FOR LETTER OF INTERPRETATION: QUO0000024 Request regarding bulk movement of UN1202 and UN1978 Foster Fuels SOS Deisel.pdf; Foster Fuels SOS Propane.pdf Hi Alice and lkeya, Please see the attached request for a letter of interpretation. Thanks, Kathryn, HMIC NOTE: Spoke with requester and he verified the bulk containers are approved for his specific materials. From: Tim Farrell [mailto:tim@aca-int.com] Sent: Tuesday, August 6, 2019 9:52 AM To: INFOCNTR (PHMSA) Subject: REQUEST FOR LETTER OF INTERPRETATION: QUO0000024 Request regarding bulk movement of UN1202 and UN1978 Hello: We had sent a question in about the movement of bulk fuel vehicles by RGN trailer while filled with DG fuels. Robert from the DOT customer service center contacted us to advise it would be allowable as long as the vehicles are approved bulk fuel containers. In order to confirm to the carriers this is true, we are asking to be sent an official letter of interpretation on the matter. To restate our question: We are looking to move fuel trucks that are filled with fuel by loading them onto RGN trailers. During the shipment they would be filled with DG fuels such as UN1202 and UN1978 (SDS's attached). The vehicles we would be moving are DOT approved as bulk containers. We would use them as single packaging on the RGN trailer to carry the fuel to destination. We would like an official letter of interpretation to state that this is allowable under DOT /PHMSA guidelines. Requesting Party: ACA International LLC DOT# 3107313 MC #80822 129 Newbury Street 2nd Floor Boston, MA 02116 646-843-0700 Please let me know if you have any questions or if I can further clarify what we are looking for in our letter. 1 <<>> Thank you! Best Regards, Tim Farrell ACA International LLC "The Charter and Logistics Specialist" Aviation • Logistics • Consulting T +l.646.843.0700 F + 1.646.381.3629 M +l.203.525.3100 Tim@aca-int.com www.aca-int.com Charter Requests: charters@aca-int.com On Tue, Jul 30, 2019 at 2:05 PM Portia Corsetti wrote: Hello Info center. I have a customer who owns a fuel company and they are looking for assistance to move their fuel tankers from the east to the west coast over the road. The vehicles are currently DOT certified for carrying the bulk DG but we were wondering if the trucks themselves could be considered single packaging if we wanted to load out multiple full trucks onto an RGN. Do you have any insight into the possibility of this or any suggestions on where to get more information? Please see sample SOS sheets for these commodities attached. Please let me know if you have any questions. Thank you, Portia Jensen Corsetti ACA International LLC Aviation • Logistics • Consulting T +1.646.843.0700 C +1.508.904.3995 F +1.646.381.3629 Portia@aca-int.com www.aca-int.com charter requests: charters@aca-int.com 2 <<>> ¥- VALERO 1. Identification Product identifier Other means of identification SOS number Synonyms SAFETY DATA SHEET DIESEL FUELS 102-GHS Recommended use Recommended restrictions Diesel Fuels All Grades, Diesel Fuel No.2, Fuel Oil No.2, High Sulfur Diesel Fuel, Low Sulfur Diesel Fuel, Ultra Low Sulfur Diesel Fuel, CARB (California Air Resource Board) Diesel Fuel, Off-Road Diesel Fuel, Dyed Diesel Fuel, X Grade Diesel Fuel, X-1 Diesel Fuel, R5 ULSD, B5 ULS D See section 16 for complete information. Motor Fuel Refinery feedstock. None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Valero Marketing & Supply Company and Affiliates One Valero Way San Antonio, TX 78269-6000 General Assistance E-Mail Contact Person Emergency Telephone 210-345-4593 CorpHSE@valero.com Industrial Hygienist 24 Hour Emergency 866-565-5220 1-800-424-9300 (CHEMTREC USA) 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable liquids Acute toxicity, inhalation Skin corrosion/irritation Carcinogenicity Reproductive toxicity Specific target organ toxicity, repeated exposure Aspiration hazard Hazardous to the aquatic environment, long-term hazard Not classified. Category 3 Category 4 Category 2 Category 2 Category 2 Category 2 Category 1 Category 2 Signal word Hazard statement Precautionary statement Prevention Danger Flammable liquid and vapor. Harmful if inhaled. Causes skin irritation. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs (blood, thymus, liver) through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heaUsparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Do not breathe misUvapors/spray. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well-ventilated area. DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 1 / 11 <<>> Response Storage Disposal Hazard(s) not otherwise classified (HNOC) If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If exposed or concerned: Get medical advice/attention. If swallowed: Immediately call a poison center/doctor. Take off contaminated clothing and wash before reuse. In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Fuels, diesel, no. 2 68476-34-6 85 - 100 Biodiesel - Fatty acid methyl esters 67762-38-3 0 - 10 Fuels, diesel, C9-18-alkane branched and linear 1159170-26-9 0-5 n-Nonane 111-84-2 1 - 3 Octane (All isomers) 111-65-9 1 - 2 Hexane (Other isomers) 96-14-0 0 - 1 Naphthalene 91-20-3 0 - 1 n-Heptane 142-82-5 0 - 1 n-Hexane 110-54-3 0 - 1 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Get medical attention if irritation develops or persists. Wash clothing separately before reuse. Destroy or thoroughly clean contaminated shoes. If high pressure injection under the skin occurs, always seek medical attention. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Do not give mouth-to-mouth resuscitation. If vomiting occurs, keep head low so that stomach content does not get into the lungs. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention immediately. Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation. Unconsciousness. Corneal damage. Narcosis. Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice. Conjunctivitis. Proteinuria. Defatting of the skin. Rash. The toxicological properties of this product have not been thoroughly investigated. Use appropriate precautions. Hydrogen sulfide, a highly toxic gas, may be present. Signs and symptoms of overexposure to hydrogen sulfide include respiratory and eye irritation, dizziness, nausea, coughing, a sensation of dryness and pain in the nose, and loss of consciousness. Odor does not provide a reliable indicator of the presence of hazardous levels in the atmosphere. In case of shortness of breath, give oxygen. Keep victim warm . Keep victim under observation. Symptoms may be delayed. The toxicological properties of this material have not been fully investigated. If exposed or concerned: get medical attention/advice. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re-use. 5. Fire-fighting measures Suitable extinguishing media DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). 2 / 11 <<>> Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Do not use a solid water stream as it may scatter and spread fire. The product is flammable, and heating may generate vapors which may form explosive vapor/air mixtures. Thermal decomposition or combustion may liberate toxic gases or fumes. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Water runoff can cause environmental damage. Use compatible foam to minimize vapor generation as needed. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Keep unnecessary personnel away. Local authorities should be advised if significant spills cannot be contained . Keep upwind. Keep out of low areas. Ventilate closed spaces before entering. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. See Section 8 of the SOS for Personal Protective Equipment. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Local authorities should be advised if significant spillages cannot be contained. Stop leak if you can do so without risk. This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas. Use non-sparking tools and explosion-proof equipment. Small Spills: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination. This material and its container must be disposed of as hazardous waste. Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent product from entering drains. Do not allow material to contaminate ground water system. Should not be released into the environment. Clean up in accordance with all applicable regulations. If facility or operation has an "oil or hazardous substance contingency plan", activate its procedures. Stay upwind and away from spill. Wear appropriate protective equipment including respiratory protection as conditions warrant. Do not enter or stay in area unless monitoring indicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew. Flammable. Review Firefighting Measures, Section 5, before proceeding with clean up. Keep all sources of ignition (flames, smoking, flares, etc.) and hot surfaces away from release. Contain spill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stop leak if it can be done without risk. Use water spray to disperse vapors. Use compatible foam to minimize vapor generation as needed. Spilled material may be absorbed by an appropriate absorbent, and then handled in accordance with environmental regulations. Prevent spilled material from entering sewers, storm drains, other unauthorized treatment or drainage systems and natural waterways. Contact fire authorities and appropriate federal , state and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, contact the National Response Center at 1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300. 7. Handling and storage Precautions for safe handling Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Wear personal protective equipment. Avoid breathing mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Use only with adequate ventilation. Wash thoroughly after handling. The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. When using, do not eat, drink or smoke. Avoid release to the environment. DIESEL FUELS 91 3579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 3 / 11 <<>> Conditions for safe storage, including any incompatibilities Flammable liquid storage. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. The pressure in sealed containers can increase under the influence of heat. Keep container tightly closed in a cool, well-ventilated place. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Naphthalene (CAS 91-20-3) PEL n-Heptane (CAS 142-82-5) PEL n-Hexane (CAS 110-54-3) PEL Octane (All isomers) (CAS PEL 111-65-9) US. ACGIH Threshold Limit Values Components Type Fuels, diesel, no. 2 (CAS TWA 68476-34-6) Hexane (Other isomers) STEL (CAS 96-14-0) TWA Naphthalene (CAS 91 -20-3) STEL TWA n-Heptane (CAS 142-82-5) STEL TWA n-Hex~ne (CAS 110-54-3) TWA n-Nonane (CAS 111-84-2) TWA Octane (All isomers) (CAS TWA 111 -65-9) US. NIOSH: Pocket Guide to Chemical Hazards Components Hexane (Other isomers) (CAS 96-14-0) Type Ceiling Value 50 mg/m3 10 ppm 2000 mg/m3 500 ppm 1800 mg/m3 500 ppm 2350 mg/m3 500 ppm Value Form 100 mg/m3 lnhalable fraction and vapor. 1000 ppm 500 ppm 15 ppm 10 ppm 500 ppm 400 ppm 50 ppm 200 ppm 300 ppm Naphthalene (CAS 91-20-3) TWA STEL TWA n-Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) n-Nonane (CAS 111 -84-2) Octane (All isomers) (CAS 111-65-9) Ceiling TWA TWA TWA Ceiling TWA Value 1800 mg/m3 510 ppm 350 mg/m3 100 ppm 75 mg/m3 15 ppm 50 mg/m3 10 ppm 1800 mg/m3 440 ppm 350 mg/m3 85 ppm 180 mg/m3 50 ppm 1050 mg/m3 200 ppm 1800 mg/m3 385 ppm 350 mg/m3 75 ppm DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 4 / 11 <<>> Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time n-Hexane (CAS 110-54-3) 0.4 mg/I 2,5-Hexanedio Urine * n, without hydrolysis 0.4 mg/I 2,5-Hexanedi - on, without hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation n-Hexane (CAS 110-54-3) US ACGIH Threshold Limit Values: Skin designation Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n-Hexane (CAS 110-54-3) Appropriate engineering controls Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof equipment. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear chemical-resistant, impervious gloves. Suitable gloves can be recommended by the glove supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Full body suit and boots are recommended when handling large volumes or in emergency situations. Flame retardant protective clothing is recommended. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workplace exposure limits for product or components are exceeded, NIOSH approved equipment should be worn. Proper respirator selection should be determined by adequately trained personnel, based on the contaminants, the degree of potential exposure and published respiratory protection factors. This equipment should be available for nonroutine and emergency use. Wear appropriate thermal protective clothing , when necessary. Consult supervisor for special handling instructions. Avoid contact with eyes. Avoid contact with skin. Keep away from food and drink. Wash hands before breaks and immediately after handling the product. Provide eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Liquid (may be dyed red). Physical state Liquid. Form Liquid. Color Clear. Straw. Odor Kerosene (strong). Odor threshold Not available. pH Melting poinUfreezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Not available. -60.07 °F (-51 .15 °C) Estimated 325- 700 °F (162.78 -371 .11 °C) > 100.0 °F (> 37.8 °C) Closed Cup 0.02 Not available. DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 5 / 11 <<>> Upper/lower flammability or explosive limits Flammability limit - lower 0.4 % (%) Flammability limit - upper 8 % (%) Explosive limit - lower(%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Vapor density Relative density < 1 mm Hg (20°C) 3 (Air = 1) 0.82 - 0.87 Relative density temperature 60 °F (15.56 °C) Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Decomposition temperature 494.96 °F (257.2 °C) Not available. Viscosity 2 - 4.5 mm2/s 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Stable at normal conditions. Stable under normal temperature conditions and recommended use. Hazardous polymerization does not occur. Incompatible materials Hazardous decomposition products Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Strong oxidizing agents. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion May be fatal if swallowed and enters airways. Inhalation Harmful if inhaled. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Skin contact Causes skin irritation. Eye contact Symptoms related to the physical, chemical and toxicological characteristics May cause eye irritation. Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation. Unconsciousness. Corneal damage. Narcosis. Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice. Conjunctivitis. Proteinuria. Defatting of the skin. Rash. The toxicological properties of this product have not been thoroughly investigated. Use appropriate precautions. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful: may cause lung damage if swallowed. The toxicological properties of this material have not been fully investigated. Components Species Fuels, diesel, no. 2 (CAS 68476-34-6) Acute Inhalation LC50 Rat Test Results 4.1 mg/I, 4 hours DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print dale: 23-May-2014 Prepared by 3E Company 6 / 11 <<>> Components Naphthalene (CAS 91-20-3) Acute Dermal LD50 Oral LD50 n-Heptane (CAS 142-82-5) Acute Inhalation LC50 n-Hexane (CAS 110-54-3) Acute Oral LD50 n-Nonane (CAS 111-84-2) Acute Inhalation LC50 Octane (All isomers) (CAS 111-65-9) Acute Inhalation LC50 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Species Test Results Rabbit > 2 g/kg Rat 490 mg/kg Rat 103 mg/I, 4 Hours Rat 28710 mg/kg Rat 3200 mg/I, 4 Hours Rat 118 mg/I, 4 Hours Causes skin irritation. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Suspected of causing cancer. International Agency for Research on Cancer (IARC): Whole diesel engine exhaust - IARC Group 1. Exposure may cause lung cancer and also noted a positive association with an increased risk of bladder cancer. Diesel exhaust has been reported to be an occupational hazard due to NIOSH-reported potential carcinogenic properties. IARC Monographs. Overall Evaluation of Carcinogenicity Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) 3 Not classifiable as to carcinogenicity to humans. 2B Possibly carcinogenic to humans. NTP Report on Carcinogens Naphthalene (CAS 91-20-3) Reproductive toxicity Reasonably Anticipated to be a Human Carcinogen. Suspected of damaging fertility or the unborn child. Napthalene interferes with embryo development in experimental animals at dose levels that cause maternal toxicity. In humans, excessive exposure to this agent may cause hemolytic anemia in the mother and fetus. Based on available data, the classification criteria are not met. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects May cause damage to the following organs through prolonged or repeated exposure: Blood. Liver. Thymus. May be fatal if swallowed and enters airways. Contains organic solvents which in case of overexposure may depress the central nervous system causing dizziness and intoxication. Repeated exposure to naphthalene may cause cataracts, allergic skin rashes, destruction of red blood cells, and anemia, jaundice, kidney and liver damage. Danger of serious damage to health by prolonged exposure. Prolonged or repeated overexposure may cause central nervous system, kidney, liver, and lung damage. DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 7 / 11 <<>> Further information Symptoms may be delayed. Hydrogen sulfide, a highly toxic gas, may be present. Signs and symptoms of overexposure to hydrogen sulfide include respiratory and eye irritation, dizziness, nausea, coughing, a sensation of dryness and pain in the nose, and loss of consciousness. Odor does not provide a reliable indicator of the presence of hazardous levels in the atmosphere. Toxicological properties of this material have not been fully investigated. 12. Ecological information Ecotoxicity Components Fuels, diesel, no. 2 (CAS 68476-34-6) Aquatic Acute Crustacea EL50 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Species Test Results Fish LL50 Daphnia magna Oncorhynchus mykiss 68 mg/I, 48 hours 65 mg/I, 96 hours Naphthalene (CAS 91 -20-3) Aquatic Crustacea EC50 Fish LC50 Water flea (Daphnia magna) 1.09 - 3.4 mg/I, 48 hours Pink salmon (Oncorhynchus gorbuscha) 0.95 - 1.62 mg/I, 96 hours n-Heptane (CAS 142-82-5) Aquatic Fish LC50 Western mosquitofish (Gambusia aftinis) 4924 mg/I, 96 hours n-Hexane (CAS 110-54-3) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/I, 96 hours Persistence and degradability Not available. Bioaccumulative potential Not available. Partition coefficient n-octanol / water (log Kow) Hexane (Other isomers) (CAS 96-14-0) Octane (All isomers) (CAS 111 -65-9) n-Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) n-Nonane (CAS 111 -84-2) Mobility in soil Not available. Other adverse effects Not available. 3.6 5.18 4.66 3.9 5.46 13. Disposal considerations Disposal instructions Dispose in accordance with all applicable regulations. This material and its container must be disposed of as hazardous waste. Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Hazardous waste code D001 : Waste Flammable material with a flash point <140 °F US RCRA Hazardous Waste U List: Reference Naphthalene (CAS 91-20-3) U165 Waste from residues / unused Dispose of in accordance with local regulations. products Contaminated packaging Ofter rinsed packaging material to local recycling facilities. 14. Transport information DOT UN number UN1202 UN proper shipping name Diesel fuel Transport hazard class(es) Class Combustible Liquid Subsidiary risk Packing group Ill DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 8 I 11 <<>> Environmental hazards Marine pollutant Yes Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk 150 203 242 Read safety instructions, SOS and emergency procedures before handling. 144, B1 , IB3, T2, TP1 IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1202 Diesel fuel 3 3 Ill Yes 3L Special precautions for user Read safety instructions, SOS and emergency procedures before handling. IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant UN1202 DIESEL FUEL 3 3 Ill Yes EmS F-E, S-E Special precautions for user Read safety instructions, SOS and emergency procedures before handling. Transport in bulk according to Not applicable. However, this product is a liquid and if transported in bulk covered under Annex II of MARPOL 73/78 and MARPOL 73/78, Annex I. the IBC Code 15. Regulatory information US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) n-Nonane (CAS 111-84-2) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Hexane (Other isomers) (CAS 96-14-0) Naphthalene (CAS 91-20-3) n-Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (CAS 111-65-9) LISTED LISTED LISTED LISTED LISTED LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. 1.0 % One-Time Export Notification only. SARA 311/312 Hazardous Yes chemical DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 9 / 11 <<>> SARA 313 (TRI reporting) Chemical name CAS number % by wt. 0 - 1 Naphthalene 91-20-3 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Naphthalene (CAS 91-20-3) n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SOWA) US state regulations WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Hexane (Other isomers) (GAS 96-14-0) Naphthalene (CAS 91-20-3) n-Heptane (GAS 142-82-5) n-Hexane (GAS 110-54-3) n-Nonane (GAS 111-84-2) Octane (All isomers) (CAS 111 -65-9) US. New Jersey Worker and Community Right-to-Know Act . Fuels, diesel, no. 2 (GAS 68476-34-6) Naphthalene (CAS 91-20-3) n-Heptane (GAS 142-82-5) n-Hexane (GAS 110-54-3) n-Nonane (GAS 111-84-2) Octane (All isomers) (CAS 111-65-9) US. Pennsylvania Worker and Community Right-to-Know Law Fuels, diesel, no. 2 (GAS 68476-34-6) Hexane (Other isomers) (GAS 96-14-0) Naphthalene (GAS 91-20-3) n-Heptane (GAS 142-82-5) n-Hexane (GAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (GAS 111-65-9) US. Rhode Island RTK Naphthalene (GAS 91-20-3) n-Hexane (GAS 110-54-3) US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Benzene (CAS 71-43-2) Toluene (CAS 108-88-3) International Inventories Country(s) or region Australia Canada Canada China Europe Europe Japan Korea New Zealand Philippines Inventory name Australian Inventory of Chemical Substances (AICS) Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) · Existing Chemicals List (EGL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PIGGS) On inventory (yes/no)* No No No No No No No No No No DIESEL FUELS 913579 Version#: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 10 / 11 <<>> Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 13-May-2013 Revision date 23-May-2014 Version# 04 Further information HMIS® is a registered trade and service mark of the NPCA. NFPA Ratings Disclaimer This material Safety Data Sheet (SDS) was prepared in accordance with 29 CFR 1910.1200 by Valero Marketing & Supply Co., ("VALERO"). VALERO does not assume any liability arising out of product use by others. The information, recommendations, and suggestions presented in this SOS are based upon test results and data believed to be reliable. The end user of the product has the responsibility for evaluating the adequacy of the data under the conditions of use, determining the safety, toxicity and suitability of the product under these conditions, and obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is made as to the effects of such use , the results to be obtained, or the safety and toxicity of the product in any specific application. Furthermore, the information herein is not represented as absolutely complete, since it is not practicable to provide all the scientific and study information in the format of this document, plus additional information may be necessary under exceptional conditions of use, or because of applicable laws or government regulations. DIESEL FUELS 913579 Version #: 04 Revison date: 23-May-2014 Print date: 23-May-2014 Prepared by 3E Company 11 / 11 <<>> SAFETY DATA SHEET Propane an Air Liquide company I Section 1. Identification GHS product identifier Chemical name Other means of identification Product type Product use Synonym SDS# Supplier's details 24-hour telephone Propane propane Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state; propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. Liquefied gas Synthetic/Analytical chemistry. Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state; propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. 001045 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 I Section 2. Hazards identification OSHA/HCS status Classification of the substance or mixture This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). FLAMMABLE GASES - Category 1 GASES UNDER PRESSURE - Liquefied gas GHS label elements Hazard pictograms Signal word Hazard statements Danger Extremely flammable gas. May form explosive mixtures with air. Contains gas under pressure; may explode if heated. May cause frostbite. May displace oxygen and cause rapid suffocation. Precautionary statements General Prevention Response Read and follow all Safety Data Sheets (SDS'S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction . Always keep container in upright position. Approach suspected leak area with caution. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. <<>> Propane I Section 2. Hazards identification Disposal Hazards not otherwise classified Not applicable. : Liquid can cause burns similar to frostbite. I Section 3. Composition/information on ingredients Substance/mixture Substance Chemical name Other means of identification Product code propane Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state; propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. 001045 CAS number/other identifiers CAS number 74-98-6 Ingredient name Propane % CAS number 100 74-98-6 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. I Section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband . Skin contact Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Get medical attention if symptoms occur. In case of contact with liquid, warm frozen tissues slowly with lukewarm water and get medical attention. Do not rub affected area. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if adverse health effects persist or are severe. Ingestion of liquid can cause burns similar to frostbite. If frostbite occurs, get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in - **truncated:** true - **body characters:** 64827