{"operation":"document","citation":"19-0133","title":"Dangerous Goods SME — Hazardous Materials Safety Interpretation","source_type":"guidance","agency":"Pipeline and Hazardous Materials Safety Administration","status":"guidance","official":true,"published_on":"2020-04-28","effective_on":null,"summary":"19-0133 response to Dangerous Goods SME concerning 172.203.","machine_formats":{"json":"https://regulus.evalyn.ai/document/phmsa-interpretation-19-0133.json","markdown":"https://regulus.evalyn.ai/document/phmsa-interpretation-19-0133.md"},"app_url":"https://regulus.evalyn.ai/document/phmsa-interpretation-19-0133","source_url":"https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/docs/standards-rulemaking/hazmat/interpretations/73731/190133.pdf","body":"<<<PAGE 1>>>\n\nU.S. Department\nof Transportation\nPipeline and Hazardous\nMaterials Safety\nAdministration\n1200 New Jersey Avenue, SE\nWashington, DC 20590\nWilliam Canterbury\nDangerous Goods SME\nAlbemarleCongress Street Suite 900\nCharlotte, NC 28209\nApril 28, 2020\nReference No. 19-0133\nDear Mr. Canterbury:\nThis letter is in response to your December 12, 2019, email requesting clarification of the\nHazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the proper\nshipping name for a compound containing a mixture of hydrocarbons. You state that the safety\ndata sheet (SDS) you included in your email lists the technical names as “(Lithium\nDiisopropylamide, Heptane (C7 hydrocarbon mixture)).” Specifically, you ask whether the\nwords “C7 hydrocarbon mixture” must appear as a part of the hazmat shipping description on the\nshipping paper.\nThe answer is no. The addition of “C7 hydrocarbon mixture” is not required because it is\nredundant with the listed technical name Heptane. Note that technical names must be included in\nparentheses with the hazardous material shipping description and generally, at least two\ncomponents which most predominantly contribute to the hazard(s) of the mixture or solution\nmust be entered on the shipping paper. See § 172.203(k).\nI hope this information is helpful. Please contact us if we can be of further assistance.\nSincerely,\nDirk Der Kinderen\nChief, Standards Development Branch\nStandards and Rulemaking Division\n\n<<<PAGE 2>>>\n\nJanuary, Ikeya CTR (PHMSA)\nCasey -19-0133\nFrom:\nINFOCNTR (PHMSA)\nSent:\nTo:\nHazmat Interps\nThursday, December 12, 2019 2:28 PM\nSubject:\nFW: Hazmat Interpretation request - Technical name for UN 2924 Flammable liquids,\ncorrosive, n.o.s\nAttachments:\nSDS SKU 10000280.PDF; Canterbury_LOl.docx\nHello Alice and ikeya,\nPlease see below for interpretation request, as well as attached notes document.\nPlease contact our office with any questions.\nThank you,\nKathryn, HMIC\nFrom: William Canterbury [mailto:william.canterbury@albemarle.com]\nSent: Thursday, December 12, 2019 11:20 AM\nTo: INFOCNTR (PHMSA) <INFOCNTR.INFOCNTR@dot.gov>\nSubject: Hazmat Interpretation request - Technical name for UN 2924 Flammable liquids, corrosive, n.o.s\nDOT / PHMSA Team\nWe have a difference of opinion within our team here at Albemarle as to how to list the technical name for this\ncompound and respectively submit this request for your advice.\nThe attached SDS list the technical name as (Lithium diisopropylamide, Heptane(C7 hydrocarbon mixture))\nAnother option being considered is (Tetrahydrofuran, Lithium Diisopropylamide, Heptane)\nPlease let me know if you need any additional information and note my contact info and mailing address are below.\nThank you and have a great day!\nJust some notes for my personal ref\n49 CFR 171.8\nTechnical name means a recognized chemical name or microbiological name currently used in scientific and\nthey readily identify the general chemical group, or microbiological group. Examples of acceptable generic chemical\ntechnical handbooks, journals, and texts. Generic descriptions are authorized for use as technical names provided\ndescriptions are organic phosphate compounds, petroleum aliphatic hydrocarbons and tertiary amines. For\nproficiency testing only, generic microbiological descriptions such as bacteria, mycobacteria, fungus, and viral\nsamples may be used. Except for names which appear in subpart B of part 172 of this subchapter, trade names may\nnot be used as technical names.\n172.203 (K)(1)\n1\n\n<<<PAGE 3>>>\n\nat least two components most predominately contributing to the hazards of the mixture or solution must be entered\n(1) If a hazardous material is a mixture or solution of two or more hazardous materials, the technical names of\non the shipping paper as required by paragraph (k) of this section. For example, \"UN 2924, Flammable liquid,\ncorrosive, n.o.s., 3 (8), II (contains Methanol, Potassium hydroxide)\".\nWilliam Canterbury | I ALBEMARLE | Dangerous Goods SME, US DOT PHMSA, IATA, IMO/IMDG\nCertified 4250 Congress Street, Suite 900, Charlotte NC 28209 | 2: Office: 704-417-0135| 2: Cell:\n704-287-7177 | X: William.canterbury@albemarle.com\n\n<<<PAGE 4>>>\n\nHello Alice and Ikeya,\nThe requester spoke with Lynsey in the HMIC. She pointed him to the guidance in 172.101(c)(10) about\nusing the two components most predominantly contributing to the hazard and that it is the shipper's\nresponsibility to properly classify. He insisted on moving forward with a LOl. After looking at his LOI, I\ngave him a call to clarify exactly what his question was and to provide him with letters 14-0244 and 03-\n0189 essentially, he still wants to verify his letter but I got a better idea for what he is looking for.\nIn the request, he lists the two options for technical names, his main question is on the inclusion of \"C7\nhydrocarbon mixture\" after heptane. The SDS places it after the heptane in section 14 but he is unsure if\nhe is required to include that because C7 hydrocarbon mixture is basically synonymous with heptane.\nPlease contact our office with any questions.\nThank you,\nKathryn, HMIC\n\n<<<PAGE 5>>>\n\nSAFETY DATA SHEET\nI ALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nSECTION 1. IDENTIFICATION\nProduct name\n: Lithium Di-isoproplyamide abt. 27% in THF/ Heptane/\nEthylbenzene\nManufacturer or supplier's details\nCompany name of supplier\n: Albemarle Corporation\nAddress\n: 4250 Congress Street, Suite 900\nUnited States of America (USA)\n, NC 28209\nTelephone\n: 980.299.5700\nTelefax\n: 980.299.5512\nEmergency telephone\n: +32 (0) 70-233-201 (EUROPE)\n(+1)225-344-7147 (US and WORLDWIDE)\n+65-6733-1661 (ASIA PACIFIC)\n+86-532-8388-9090 (CHINA)\n+61 2 8014 4558 or 18000 74234 (Australia)\nContact person product safe- : DEPARTMENT OF PRODUCT SAFETY\nE-mail address\n: PRODUCTSAFETY@ALBEMARLE.COM\nRecommended use of the chemical and restrictions on use\nRecommended use\n: Reagent for organic synthesis.\nTransported isolated intermediate\nRestrictions on use\nUse only in closed systems.\nSECTION 2. HAZARDS IDENTIFICATION\nGHS classification in accordance with 29 CFR 1910.1200\nFlammable liquids\n: Category 2\nSkin corrosion\n:\nCategory 1A\nSerious eye damage\n:\nCategory 1\n1/29\n\n<<<PAGE 6>>>\n\nSAFETY DATA SHEET\nI ALBEMARLE®\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nCarcinogenicity\n: Category 2\nsystemic toxicity - single\nSpecific target organ\nCategory 3 (Respiratory system, Central nervous system)\nexposure\nSpecific target organ\nsystemic toxicity - repeated\n: Category 2\nexposure\nAspiration hazard\nCategory 1\nAcute aquatic toxicity\nCategory 2\nChronic aquatic toxicity\n:\nCategory 2\nGHS label elements\nHazard pictograms\n:\n!\n·2\nSignal Word\n: Danger\nHazard Statements\n: H225 Highly flammable liquid and vapor.\nH314 Causes severe skin burns and eye damage.\nH304 May be fatal if swallowed and enters airways.\nH335 May cause respiratory irritation.\nH336 May cause drowsiness or dizziness.\nH351 Suspected of causing cancer.\nrepeated exposure.\nH373 May cause damage to organs through prolonged or\nH411 Toxic to aquatic life with long lasting effects.\nPrecautionary Statements\n:\nPrevention:\nP202 Do not handle until all safety precautions have been read\nP201 Obtain special instructions before use.\nand understood.\nP210 Keep away from heat/sparks/open flames/hot surfaces.\nNo smoking.\nP240 Ground/bond container and receiving equipment.\nP233 Keep container tightly closed.\nP241 Use explosion-proof electrical/ ventilating/ lighting/ equip-\nment.\nP242 Use only non-sparking tools.\nP260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.\nP243 Take precautionary measures against static discharge.\n2/29\n\n<<<PAGE 7>>>\n\nSAFETY DATA SHEET\nI ALBEMARLE\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nP264 Wash skin thoroughly after handling.\n271 Use only outdoors or in a well-ventilated area\n273 Avoid release to the environment.\nP280 Wear protective gloves/ protective clothing/ eye protection/\nface protection.\nResponse:\nP301 + P310 IF SWALLOWED: Immediately call a POISON\nP301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT\nCENTER/doctor.\nP303 + P361 + P353 IF ON SKIN (or hair): Take off immediately\ninduce vomiting.\nP304 + P340 + P310 IF INHALED: Remove person to fresh air\nall contaminated clothing. Rinse skin with water/shower.\nCENTER/doctor.\nand keep comfortable for breathing. Immediately call a POISON\nwater for several minutes. Remove contact lenses, if present\nP305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with\nCENTER/doctor.\nand easy to do. Continue rinsing. Immediately call a POISON\nattention.\nP308 + P313 IF exposed or concerned: Get medical advice/\nP378 In case of fire, use extinguish media on basis of NaCl or\npulverized limestone. Never use water.\nStorage:\ntightly closed\nP403 + P233 Store in a well-ventilated place. Keep container\nP403 + P235 Store in a well-ventilated place. Keep cool.\nP405 Store locked up.\nDisposal:\nP501 Dispose of contents/ container to an approved waste dis-\nposal plant.\nOther hazards\nThe information required is contained in this Material Safety Data Sheet.\nSECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS\nSubstance / Mixture\n: Mixture\nChemical nature\n: Organoamide\nHazardous ingredients\nChemical name\nNaphtha (petroleum), hydrotreated light\nCAS-No.\n64742-49-0\nConcentration (% w/w)\n>= 30 - < 50\n(Heptane (C7 hydrocarbon mixture))\n3/29\n\n<<<PAGE 8>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nlithium disopropylamide\n|4111-54-0\n>= 20 - < 30\ntetrahydrofuran\n109-99-9\n>= 20 - < 30\ndiisopropylamine\n100-41-4\n>= 10 - < 20\n1108-18-9\n>= 3-<5\n* Note: The exact concentrations of the above listed chemicals are being withheld as a trade se-\ncret.\nSECTION 4. FIRST AID MEASURES\nGeneral advice\n: First Aid responders should pay attention to self-protection\nMove out of dangerous area.\nand use the recommended protective clothing\nTake off contaminated clothing and shoes immediately.\nKeep warm and in a quiet place.\nIf inhaled\n: Move to fresh air.\nIf not breathing, give artificial respiration.\nCall a physician immediately.\nKeep the victim calm and in a semi-upright position.\nIn case of skin contact\n: Wash off immediately with plenty of water for at least 15\nminutes.\nCall a physician immediately.\nIn case of eye contact\n: Rinse immediately with plenty of water, also under the eyelids,\nfor at least 15 minutes.\nCall a physician immediately.\nIf swallowed\n: Clean mouth with water and drink afterwards plenty of water.\nDo NOT induce vomiting.\nNever give anything by mouth to an unconscious person.\nCall a physician immediately.\nMost important symptoms\nand effects, both acute and\n: Headache\ndelayed\nNausea\nVomiting\nTiredness\nDrowsiness\nDizziness\nUnconsciousness\nRisk of serious damage to the lungs (by aspiration).\nIf ingested, severe burns of the mouth and throat, as well as a\nRisk of product entering the lungs on vomiting after ingestion.\ndanger of perforation of the esophagus and the stomach.\nNotes to physician\n: Treat symptomatically.\nFor specialist advice physicians should contact the Poisons\nInformation Service.\n4/29\n\n<<<PAGE 9>>>\n\nSAFETY DATA SHEET\nMALBEMARLE™\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nSECTION 5. FIRE-FIGHTING MEASURES\nSuitable extinguishing media : Dry extinguishing media based on NaCl or pulverized\nlimestone.\nUnsuitable extinguishing\nmedia\n: Water\nFoam\nCarbon dioxide (CO2)\nfighting\nSpecific hazards during fire\n: Vapors may form explosive mixtures with air.\nVapors are heavier than air and may spread along floors.\nFlash back possible over considerable distance.\nHazardous decomposition products formed under fire\nconditions.\nucts\nHazardous combustion prod- : Carbon monoxide\nCarbon dioxide (CO2)\nFurther information\n: Use a water spray to cool fully closed containers.\nBe aware of a dangerous reaction with water, if the container\nis ruptured.\nCollect contaminated fire extinguishing water separately. This\nmust not be discharged into drains.\nbe disposed of in accordance with local regulations.\nFire residues and contaminated fire extinguishing water must\nSpecial protective equipment: Wear full protective clothing and self-contained breathing\nfor fire-fighters\napparatus.\nSECTION 6. ACCIDENTAL RELEASE MEASURES\ntive equipment and emer-\nPersonal precautions, protec- : Remove all sources of ignition.\ngency procedures\nEnsure adequate ventilation.\nAvoid contact with skin, eyes and clothing.\nWear personal protective equipment.\nKeep people away from and upwind of spill/leak.\nDo not breathe dust/ fume/ gas/ mist/ vapors/ spray.\nEnvironmental precautions\n: Do not flush into surface water or sanitary sewer system.\nAvoid subsoil penetration.\nMethods and materials for\n: Do not allow contact with water.\ncontainment and cleaning up\nCover spilled material with limestone powder.\nPick up and transfer to properly labeled containers.\nNon-sparking tools should be used.\nAdequate disposal\n5 / 29\n\n<<<PAGE 10>>>\n\nSAFETY DATA SHEET\nM ALBEMARLE\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nPrint Date:\nDate of first issue: 03/04/2019\n12/09/2019\nSECTION 7. HANDLING AND STORAGE\nAdvice on protection against: Vapors may form explosive mixtures with air.\nfire and explosion\nFlash back possible over considerable distance.\nVapors are heavier than air and may spread along floors.\nUse only explosion-proof equipment.\nTake precautionary measures against static discharge.\nKeep away from open flames, hot surfaces and sources of\nUncleaned empty containers can contain product gases,\nignition.\nwhich form explosive mixtures with air.\nAdvice on safe handling\n: Handle under inert gas. Protect from moisture.\nUse product only in closed system.\nProvide exhaust ventilation close to floor level.\nProvide sufficient air exchange and/or exhaust in work rooms.\nAvoid formation of aerosol.\nHandle in accordance with good industrial hygiene and safety\nWear personal protective equipment.\nin general, emissions are controlled and prevented by\npractice.\nimplementing an appropriate management system, including\nregular informing and training workers.\nConditions for safe storage\n: Keep under inert gas.\nventilated place.\nKeep containers tightly closed in a dry, cool and well-\nKeep away from heat.\nKeep away from direct sunlight.\nProtect from moisture.\nDo not allow contact with air.\nProtect from frost.\nMaterials to avoid\n: Never allow product to get in contact with water during\nstorage.\nIncompatible with oxidizing agents.\nDo not store near acids.\nFurther information on stor-: Keep at temperatures between 0°C and 15°C.\nage stability\nSECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION\nIngredients with workplace control parameters\nIngredients\nCAS-No.\n| Value type\nControl parame-\n(Form of\nters / Permissible\nBasis\n6/29\n\n<<<PAGE 11>>>\n\nSAFETY DATA SHEET\naccording to OSHA Hazard Communication Standard 29CFR\nI ALBEMARLE®\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n10/09/2019\nRevision Date:\nDate of first issue: 03/04/2019\nDate of last issue: 03/04/2019\nPrint Date:\n12/09/2019\nNaphtha (petroleum),\n(C7 hydrocarbon mixture))\nhydrotreated light (Heptane\n64742-49-0\nexposure)\nconcentration\nTWA\n2,000 mg/m3\n500 ppm\nOSHA Z-1\nTWA\n400 ppm\nOSHA PO\n1,600 mg/m3\ntetrahydrofuran\n109-99-9\nTWA\nSTEL\n50 ppm\nACGIH\nST\n100 ppm\nACGIH\n250 ppm\nNIOSH REL\nTWA\n735 mg/m3\n200 ppm\nNIOSH REL\nTWA\n590 mg/m3\n200 ppm\nOSHA Z-1\nTWA\n590 mg/m3\n590 mg/m3\n200 ppm\nOSHA PO\nSTEL\n250 ppm\nOSHA PO\nethylbenzene\n100-41-4\n735 mg/m3\nTWA\nTWA\n20 ppm\nACGIHR\n100 ppm\nNIOSH REL\nST\n435 mg/m3\n545 mg/m3\n125 ppm\nNIOSH REL\nTWA\n435 mg/m3\n100 ppm\nOSHA Z-1\nTWA\n100 ppm\nOSHA PO\nSTEL\n435 mg/m3\n545 mg/m3\n125 ppm\nOSHA PO\ndiisopropylamine\n108-18-9\nTWA\nTWA\n5 ppm\nACGIHR\n20 mg/m3\n5 ppm\nNIOSH REL\nTWA\n5 ppm\n20 mg/m3\nOSHA Z-1\nTWA\n20 mg/m3\n5 ppm\nOSHA PO\nBiological occupational exposure limits\n[Ingredients\nCAS-NO. Control\nBiological\nTSam-\n[Permissible Basis\nparameters\nspecimen\npling\ntime\nconcentra-\ntetrahydrofuran\n109-99-9\nTetrahydrof\nUrine\nEnd of\ntion\nuran\nshift (As\n2 mg/l\nACGIH\nsoon as\nBEI\npossible\nexposure\nafter\n7/29\n\n<<<PAGE 12>>>\n\nSAFETY DATA SHEET\nIl ALBEMARLE\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nethylbenzene\n100-41-4\nSum of\n(ceases)\nmandelic\nUrine\nshift (As\nEnd of\n0.15 g/g\nACGIH\ncreatinine\nBEI\nacid and\nsoon as\nphenyl,\npossible\nglyoxylic\nacid\nExposure\nafter\nceases)\nEngineering measures\n: Use product only in closed system.\nrooms.\nProvide sufficient air exchange and/or exhaust in work\nProvide exhaust ventilation close to floor level.\nTake precautionary measures against static discharge.\nstandard.\nElectrical equipment should be protected to the appropriate\nPersonal protective equipment\nRespiratory protection\n: In case of inadequate ventilation wear respiratory protection.\nABEK-P2-filter\nRecommended Filter type:\nWhen prolonged exposure is expected:\nWear full protective clothing and self-contained breathing\napparatus.\nHand protection\nMaterial\n: Wear suitable gloves.\nMaterial\n: Flame retardant gloves\nRemarks\n: Protective gloves and\nProtective gloves against thermal risks The choice of an\nappropriate glove does not only depend on its material but\nalso on other quality features and is different from one\nproducer to the other. The exact break through time can be\nobtained from the protective glove producer and this has to\nbe observed. Protective gloves have to be replaced at the\nfirst sign of deterioration.\nEye protection\n: Tightly fitting safety goggles\nFace-shield\nSkin and body protection\n: Flame retardant antistatic protective clothing.\nComplete suit protecting against chemicals\nProtective measures\n: Handle in accordance with good industrial hygiene and safety\npractice.\n8/29\n\n<<<PAGE 13>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nEnsure that eye flushing systems and safety showers are\nlocated close to the working place.\nHygiene measures\n: Take off contaminated clothing and shoes immediately.\nAvoid contact with skin, eyes and clothing.\nDo not breathe dust/ fume/ gas/ mist/ vapors/ spray.\nSmoking, eating and drinking should be prohibited in the\nKeep away from food, drink and animal feedingstuffs.\nWash hands before breaks and at the end of workday.\nSECTION 9. PHYSICAL AND CHEMICAL PROPERTIES\nAppearance\n: liquid\nColor\n: slight, yellow, to, red brown\nOdor\n: solvent\nOdor Threshold\nNo data available\nрн\n: alkaline\nCrystallization temperature\n: < 32 °F/ < 0°C\nBoiling point/boiling range\n: 151 °F / 66 °C\nTetrahydrofuran\nFlash point\n: -6.2 °F/ -21.2 °C\n(1,013 hPa)\nMethod: closed cup\nTetrahydrofuran\nEvaporation rate\n: No data available\nFlammability (solid, gas)\n: No data available\nFlammability (liquids)\n: Flammability (liquids)\nRemarks: Highly flammable liquid and vapor.\nSelf-ignition\n: not auto-flammable\nflammability limit\nUpper explosion limit / Upper : 12 %(V)\nTetrahydrofuran\nLower explosion limit / Lower: 1.5 %(V)\nflammability limit\nTetrahydrofuran\n9/29\n\n<<<PAGE 14>>>\n\nSAFETY DATA SHEET\nMALBEMARLE™\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nVapor pressure\n: No data available\nRelative vapor density\n: No data available\nRelative density\n: No data available\nDensity\n: ca. 0.80 g/cm3 (68 °F / 20 °C)\nSolubility(ies)\nWater solubility\n: Not applicable, Reacts violently with water.\nSolubility in other solvents\n: No data available\noctanol/water\nPartition coefficient: n-\n:\nNo data available\nAutoignition temperature\n419 °F / 215 °C\nHeptane\nDecomposition temperature\n> 104 °F / > 40 °C\nTo avoid thermal decomposition, do not overheat.\nViscosity, dynamic\n: No data available\nViscosity, kinematic\nNo data available\nExplosive properties\n: Vapors may form explosive mixtures with air.\nSECTION 10. STABILITY AND REACTIVITY\nReactivity\n: Risk of violent reaction.\nChemical stability\n: Sensitive to air.\nDecomposes on heating.\n•ated by heating\nDecomposition under influence of moisture is highly acceler-\nPossibility of hazardous reac- : Reacts violently with water.\ntions\nMay form explosive peroxides.\nVapors may form explosive mixture with air.\nConditions to avoid\n: Keep away from open flames, hot surfaces and sources of\nignition.\nProtect from moisture.\nDo not allow contact with air.\nTake action to prevent static discharges.\nProtect from frost, heat and sunlight.\n10 / 29\n\n<<<PAGE 15>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nIncompatible materials\n: Water\nAcids\nOxidizing agents\nHazardous decomposition\nproducts\n: Decomposes in contact with water.\nLithium hydroxide\nDisopropylamine\nSECTION 11. TOXICOLOGICAL INFORMATION\nAcute toxicity\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (CZ hydrocarbon mixture)):\nAcute oral toxicity\n: LD50 (Rat): > 5,840 mg/kg\nMethod: OECD Test Guideline 401\nTest substance: Read-across (Analogy)\nAcute inhalation toxicity\n: LC50 (Rat): > 23.3 mg/l\nExposure time: 4 h\nMethod: OECD Test Guideline 403\nTest atmosphere: vapor\nGLP: yes\nTest substance: Read-across (Analogy)\nAcute dermal toxicity\n: LD50 (Rat): > 2,800 mg/kg\nMethod: OECD Test Guideline 402\nTest substance: Read-across (Analogy)\ntetrahydrofuran:\nAcute oral toxicity\n: LD50 (Rat, male and female): 1,650 mg/kg\nAcute inhalation toxicity\n: LC50 (Rat, male and female): > 14.7 mg/l\nExposure time: 6 h\nTest atmosphere: vapor\nliterature.\nRemarks: Information taken from reference works and the\nAcute dermal toxicity\n: LD50 (Rat, male and female): > 2,000 mg/kg\nGLP: yes\nMethod: OECD Test Guideline 402\nRemarks: Limit Test\nethylbenzene:\nAcute oral toxicity\n: LD50 (Rat): 3,500 mg/kg\n11 / 29\n\n<<<PAGE 16>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLehtame Etsyronzymide abt. 27% in THFI\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nAcute inhalation toxicity\n: LC50 (Rat): 17.2 mg/l\nTest atmosphere: vapor\nExposure time: 4 h\nAcute dermal toxicity\n: LD50 (Rabbit): 15,354 mg/kg\ndiisopropylamine:\nAcute oral toxicity\n: LD50 (Rat, male and female): 420 mg/kg\nMethod: US EPA Test Guideline OPP 81-1\nAcute inhalation toxicity\n: LC50 (Rat, male and female): 5.35 mg/l\nExposure time: 4 h\nTest atmosphere: vapor\nMethod: OECD Test Guideline 403\nSkin corrosion/irritation\nProduct:\nRemarks\n: Causes severe burns.\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nSpecies\nMethod\nExposure time\nCEcO Test Guideline 40s\nTest substance\nResult\n: Skin irritation\n: Read-across (Analogy)\nlithium disopropylamide:\nResult\n: Causes severe burns.\ntetrahydrofuran:\nSpecies\nExposure time\nRabbit\n72 h\nResult\nMethod\n: Draize Testation\nDraize Test\ndiisopropylamine:\nSpecies\nMethod\nExposure time\nResult\nOECD Test Guideline 404\nCauses severe burns.\n12/29\n\n<<<PAGE 17>>>\n\nSAFETY DATA SHEET\nMALBEMARLE\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THFI\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nGLP\n: yes\nSerious eye damage/eye irritation\nProduct:\nRemarks\n: Causes serious eye damage.\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nSpecies\nResult\n: Rabbit\nTest substance\n: Read-across (Analogy)\nNo eye irritation\nlithium diisopropylamide:\nResult\n: Risk of serious damage to eyes.\ntetrahydrofuran:\nResult\nRemarks\nIntaring ton taes\nInformation taken from reference works and the literature.\ndisopropylamine:\nSpecies\nExposure time\nResult\n:Rabbit\nIrreversible effects on the eye\nMethod\nDECD Test Guideline 405\nRespiratory or skin sensitization\nProduct:\nRemarks\n: No data available\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nTest Type\nRoutes of exposure\nMaximization Test\nSpecies\nSkin contact\nMethod\nGuinea pig\nResult\nOECD Test Guideline 406\nTest substance\nDid not cause sensitization on laboratory animals.\n13 / 29\n\n<<<PAGE 18>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\ntetrahydrofuran:\nTest Type\nMethod\nSpecies\nLocal lymph node assay (LLNA)\nMouse\nResult\nGLP\ndiisopropylamine:\nTest Type\nRoutes of exposure\nMain contion Test\nSkin contact\nSpecies\nMethod\nOECD Test Guideline 406\nGuinea pig\nGLP\nResult\nDoes not cause skin sensitization.\nGerm cell mutagenicity\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nGenotoxicity in vitro\n: Test Type: reverse mutation assay\nTest system: Salmonella typhimurium\nMetabolic activation: with and without metabolic activation\nMethod: OECD Test Guideline 471\nResult: negative\nTest substance: Read-across (Analogy)\nTest Type: reverse mutation assay\nTest system: Escherichia coli\nMetabolic activation: with and without metabolic activation\nMethod: OECD Test Guideline 471\nResult: negative\nTest substance: Read-across (Analogy)\ntetrahydrofuran:\nGenotoxicity in vitro\n: Test Type: In vitro mammalian cell gene mutation test\nMetabolic activation: with and without metabolic activation\nTest system: Chinese hamster ovary cells\nResult: negative\nMethod: OECD Test Guideline 476\nGLP: yes\nTest Type: reverse mutation assay\nTest system: Salmonella typhimurium\nMetabolic activation: with and without metabolic activation\nMethod: OECD Test Guideline 471\nResult: negative\n14/29\n\n<<<PAGE 19>>>\n\nSAFETY DATA SHEET\nMALBEMARLE\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nGLP: yes\nGenotoxicity in vivo\n: Test Type: In vivo micronucleus test\nSpecies: Mouse (male and female)\nStrain: B6C3F1\nApplication Route: inhalation (vapor)\nMethod: OECD Test Guideline 474\nResult: negative\nethylbenzene:\nGenotoxicity in vitro\n: Test Type: In vitro Mammalian Cell Gene Mutation Test\nTest system: mouse lymphoma cells\nMethod: OECD Test Guideline 476\nResult: negative\nTest Type: Ames test\nMethod: OECD Test Guideline 471\nTest system: Salmonella typhimurium\nResult: negative\nGenotoxicity in vivo\n: Species: Mouse (male and female)\nApplication Route: Inhalation\nMethod: OECD Test Guideline 474\nResult: negative\ndiisopropylamine:\nGenotoxicity in vitro\n: Test Type: reverse mutation assay\nMetabolic activation: with and without metabolic activation\nTest system: Salmonella typhimurium\nResult: negative\nMethod: OECD Test Guideline 471\nGLP: yes\nCarcinogenicity\nIngredients:\ntetrahydrofuran:\nApplication Route\nSpecies\ninhalation (vapor)\nExposure time\nrean adorate\nGroup\n2 Years\nNOAEC\nFrequency of Treatment\nGLP\nCarcinogenicity - Assess-\n: Limited evidence of carcinogenicity in animal studies\n15 / 29\n\n<<<PAGE 20>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\n12/09/2019\nPrint Date:\nment\nIARC\n109-99-9\nGroup 2B: Possibly carcinogenic to humans\nNot Assigned\n004128; Possibly carcinogenic to humans\nNot Assigned\nOSHA\nNo component of this product present at levels greater than or equal to 0.1% is\non OSHA's list of regulated carcinogens.\nNTP\nidentified as a known or anticipated carcinogen by NTP.\nNo ingredient of this product present at levels greater than or equal to 0.1% is\nReproductive toxicity\nIngredients:\ntetrahydrofuran:\nEffects on fertility\n: Test Type: Two-generation study\nStrain: wistar\nSpecies: Rat, male and female\nApplication Route: Oral\nGeneral Toxicity F1: NOAEL: 305 mg/kg body weight\nGeneral Toxicity Parent: NOAEL: 305 mg/kg bw/day\nMethod; OECD Test Guideline 416\nFertility: NOAEL: 782 mg/kg bw/day\nGLP: yes\nEffects on fetal development : Test Type: Pre-natal\nSpecies: Rat\nStrain: Sprague-Dawley\nApplication Route: inhalation (vapor)\nGeneral Toxicity Maternal: NOAEL: 1,800 ppm\nFrequency of Treatment: 7 days/week\nMethod: OECD Test Guideline 414\nDevelopmental Toxicity: NOAEL: 1,800 ppm\nResult: Animal testing did not show any effects on fetal\ndevelopment.\nGLP: yes\nSTOT-single exposure\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nAssessment\nRoutes of exposure\nThe suion\nThe substance or mixture is classified as specific target organ\ntoxicant, single exposure, category 3 with narcotic effects.\n16 / 29\n\n<<<PAGE 21>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THFI\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n1.1\nRevision Date:\n10/09/2019\nDate of first issue: 03/04/2019\nDate of last issue: 03/04/2019\nPrint Date:\n12/09/2019\ntetrahydrofuran:\nRoutes of exposure\nAssessment\nThe suit.\nThe substance or mixture is classified as specific target organ\ntoxicant, single exposure, category 3 with respiratory tract\nirritation.\ndiisopropylamine:\nAssessment\n: The substance or mixture is classified as specific target organ\nirritation., May cause respiratory irritation.\ntoxicant, single exposure, category 3 with respiratory tract\nSTOT-repeated exposure\nIngredients:\nethylbenzene:\nAssessment\n: The substance or mixture is classified as specific target organ\ntoxicant, repeated exposure, category 2.\nRepeated dose toxicity\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nNOAEL\nSpecies\nRat, male and femal\nMethod\nExposure time\nTest atmosphere\nApplication Route\n12.35 mg/\nInhalation\nvapor\n90 d\nTest substance\nOECD Test Guideline 413\nRead-across (Analogy)\ntetrahydrofuran:\nNOAEL\nSpecies\nRat, male and female\nExposure time\nApplication Route\n1,000 mg/l\nOral\nMethod\nGroup\n28 d\nOECD Test Guideline 407\nyes\nNOAEC\nSpecies\nRat, male and female\nTest atmosphere\nApplication Route\nInhalation\n1800 ppm\nExposure time\n90 d\nvapor\n17/29\n\n<<<PAGE 22>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\n1910.1200 (HCS 2012)\naccording to OSHA Hazard Communication Standard 29CFR\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nPrint Date:\nDate of first issue: 03/04/2019\n12/09/2019\nGroup\nMethod\nGLP\nSub-chronic toxicity study (90-day)\nethylbenzene:\nSpecies\nLOAEL\nNOAEL\n: Rat, male and female\n75 mg/kg\nApplication Route\n250 mg/kg\nMethod\nExposure time\n90 d\nOral\nOECD Test Guideline 408\ndiisopropylamine:\nSpecies\nNOAEL\nExposure time\nApplication Route\n50 mg/kg bw/day\nOral\nMethod\n33 d\n: Regulation (EC) No. 440/2008, Annex, B.7\nSpecies\nNOAEL\n:\nRat, male and female\nExposure time\nApplication Route\n>150 mg/kg bw/day\nSkin contact\nMethod\nNumber of exposures\n5 d/wk\n28 d\nGLP\nOECD Test Guideline 410\n: yes\nAspiration toxicity\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\ngarded as if it causes a human aspiration toxicity hazard.\nThe substance or mixture is known to cause human aspiration toxicity hazards or has to be re-\nethylbenzene:\ngarded as if it causes a human aspiration toxicity hazard.\nThe substance or mixture is known to cause human aspiration toxicity hazards or has to be re-\nFurther information\nProduct:\nRemarks\n: If ingested, severe burns of the mouth and throat, as well as a\ndanger of perforation of the esophagus and the stomach.\nEvaporation of solvents may cause irritation to eyes and mu-\n18/29\n\n<<<PAGE 23>>>\n\nSAFETY DATA SHEET\nMALBEMARIE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nInhalation of high vapor concentrations may cause symptoms\ncous membranes.\nlike headache, dizziness, tiredness, nausea and vomiting.\nSECTION 12. ECOLOGICAL INFORMATION\nEcotoxicity\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nToxicity to fish\n: LL50 (Oncorhynchus mykiss (rainbow trout)): > 13.4 mg/l\nEnd point: mortality\nTest Type: semi-static test\nExposure time: 96 h\nMethod: OECD Test Guideline 203\nToxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 3 mg/l\naquatic invertebrates\nExposure time: 48 h\nEnd point: Immobilization\nTest substance: Read-across (Analogy)\nTest Type: static test\nMethod: OECD Test Guideline 202\nGLP: yes\nToxicity to algae\n: EL50 (Pseudokirchneriella subcapitata (green algae)): 10 mg/l\nExposure time: 72 h\nEnd point: Growth rate\nTest Type: static test\nTest substance: Read-across (Analogy)\nMethod: OECD Test Guideline 201\nGLP: yes\nToxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.017 mg/l\nic toxicity)\naquatic invertebrates (Chron-\nExposure time: 21 d\nTest Type: static test\nAnalytical monitoring: yes\nTest substance: Read-across (Analogy)\nGLP: yes\nMethod: OECD Test Guideline 211\nToxicity to microorganisms\n: EL50 (Tetrahymena pyriformis): 26.8 mg/l\nExposure time: 48 h\nEnd point: Growth rate\nMethod: QSAR\nGLP:\n19/29\n\n<<<PAGE 24>>>\n\nSAFETY DATA SHEET\nI ALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\n10/09/2019\nRevision Date:\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\ntetrahydrofuran:\nToxicity to fish\n: LC50 (Pimephales promelas (fathead minnow): 2, 160 mg/l\nExposure time: 96 h\nEnd point: mortality\nTest Type: flow-through test\nAnalytical monitoring: yes\nMethod: OECD Test Guideline 203\nToxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 3,485 mg/l\naquatic invertebrates\nEnd point: mortality\nTest Type: static test\nExposure time: 48 h\nMethod: OECD Test Guideline 202\nToxicity to algae\n: TTC (Scenedesmus quadricauda (Green algae)): 3,700 mg/l\nEnd point: Growth rate\nTest Type: static test\nExposure time: 8 d\nRemarks: Information taken from reference works and the\nliterature.\nicity)\nToxicity to fish (Chronic tox-\n: NOEC (Pimephales promelas (fathead minnow)): 216 mg/l\nExposure time: 33 d\nEnd point: Growth inhibition\nAnalytical monitoring: yes\nTest Type: flow-through test\nliterature.\nRemarks: Information taken from reference works and the\nToxicity to microorganisms\n: IC50 (activated sludge): 460 mg/l\nEnd point: Respiration inhibition\nExposure time: 3 h\nTest Type: static test\nMethod: OECD Test Guideline 209\nethylbenzene:\nToxicity to algae\n: IC50 (Selenastrum capricornutum (green algae)): 4.6 mg/l\nMethod: OECD Test Guideline 201\nToxicity to microorganisms\n: EC50 (Photobacterium phosphoreum): 9.68 mg/l\nExposure time: 30 min\ndiisopropylamine:\nToxicity to fish\n: LC50 (Leuciscus idus (Golden orfe)): 26 mg/l\nEnd point: mortality\nTest Type: static test\nExposure time: 96 h\n20 / 29\n\n<<<PAGE 25>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nMethod: DIN 38412\nToxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 110 mg/l\naquatic invertebrates\nEnd point: Immobilization\nExposure time: 48 h\nToxicity to algae\n: EC50 (Selenastrum capricornutum (green algae)): 20 mg/l\nEnd point: Growth rate\nExposure time: 96 h\nTest Type: static test\nToxicity to microorganisms\n: EC50 (activated sludge): > 100 mg/l\nEnd point: Respiration inhibition\nExposure time: 3 h\nMethod: OECD Test Guideline 209\nTest Type: static test\nPersistence and degradability\nProduct:\nBiodegradability\n: Remarks: No data available\nity\nPhysico-chemical removabil- : Remarks: No data available\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nBiodegradability\n: aerobic\nInoculum: activated sludge\nConcentration: 100 mg/l\nBiodegradation: 98%\nResult: Readily biodegradable.\nMethod: OECD Test Guideline 301F\nExposure time: 28 d\nTest substance: Read-across (Analogy)\nGLP: yes\ntetrahydrofuran:\nBiodegradability\n: aerobic\nInoculum: activated sludge\nConcentration: 100 mg/l\nResult: Biodegradable\n21/29\n\n<<<PAGE 26>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\naccording to OSHA Hazard Communication Standard 29CFR\n1910.1200 (HCS 2012)\nLithium Di-isoproplyamide abt. 27% in THF/\nHeptane/ Ethylbenzene\nSDS Number: RS_000001280\nVersion\nRevision Date:\n10/09/2019\nDate of last issue: 03/04/2019\nDate of first issue: 03/04/2019\nPrint Date:\n12/09/2019\nGLP: yes\nethylbenzene:\n(COD)\nChemical Oxygen Demand\n1,780 mg/g\nBioaccumulative potential\nProduct:\nBioaccumulation\n: Remarks: Bioaccumulation is unlikely.\nIngredients:\nNaphtha (petroleum), hydrotreated light (Heptane (C7 hydrocarbon mixture)):\nBioaccumulation\n: Remarks: No data available\nlithium disopropylamide:\nBioaccumulation\n: Remarks: Bioaccumulation is unlikely.\ntetrahydrofuran:\nBioaccumulation\n: Remarks: No bioaccumulation is to be expected (log Pow <=\n4).\nPartition coefficient: n-\noctanol/water\n: log Pow: 0.45 (77 °F / 25 °C)\nMethod: OECD Test Guideline 107\nethylbenzene:\noctanol/water\nPartition coefficient: n-\n: log Pow: 3.15\ndiisopropylamine:\nPartition coefficient: n-\noctanol/water\n: log Pow: 0.4 (68 °F / 20 °C)\nMethod: OECD Test Guideline 107\npH: 12\nMobility in soil\nIngredients:\nethylbenzene:\nmental compartments\nDistribution among environ-\n: log Koc: 2.31\nRemarks: The product is insoluble and floats on water.\n22/29\n\n<<<PAGE 27>>>\n\nSAFETY DATA SHEET\nMALBEMARLE®\n19","truncated":true,"body_characters":53158}