# Entegris — Hazardous Materials Safety Interpretation

- **operation:** document
- **citation:** 24-0046
- **title:** Entegris — Hazardous Materials Safety Interpretation
- **source type:** guidance
- **agency:** Pipeline and Hazardous Materials Safety Administration
- **status:** guidance
- **official:** true
- **published on:** 2024-09-25
- **effective on:** Not available
- **summary:** 24-0046 response to Entegris concerning 176.83.
- **machine formats:** - **json:** https://regulus.evalyn.ai/document/phmsa-interpretation-24-0046.json
- **markdown:** https://regulus.evalyn.ai/document/phmsa-interpretation-24-0046.md
- **app url:** https://regulus.evalyn.ai/document/phmsa-interpretation-24-0046
- **source url:** https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/2024-10/240046.pdf
**body:**

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U.S. Department
of Transportation
Pipeline and Hazardous
Materials Safety
Administration
1200 New Jersey Avenue, SE
Washington, DC 20590
September 25, 2024
Shelley Stampfler
Logistics Specialist IV
Entegris
7 Commerce Drive
Danbury, CT 06810
Reference No. 24-0046
Dear Ms. Stampfler:
This letter is in response to your May 22, 2024, letter requesting clarification of the Hazardous
Materials Regulations (HMR; 49 CFR Parts 171-180) and the International Maritime Dangerous
Goods (IMDG) Code applicable to the segregation of hazardous materials transported by vessel.
We have paraphrased and answered questions as follows:
Q1: You ask whether a Division 2.3 gas poisonous by inhalation (with a subsidiary hazard of
Class 8 corrosive) and a Division 2.3 gas poisonous by inhalation (with a subsidiary
hazard of Division 2.1 flammable gas) require segregation.
A1: The answer is no, provided the Division 2.3 gases poisonous by inhalation are shipped in
accordance with the applicable provisions detailed in § 176.83 of the HMR and section
7.2.6.1 of the IMDG Code. Multiple Division 2.3 gases poisonous by inhalation may be
stowed in the same container for vessel transportation without regard to the subsidiary
hazards, provided the different gases are not capable of reacting dangerously with each
other and causing any of the conditions listed in § 176.83(a)(8), or section 7.2.6.1 of the
IMDG Code. Specifically, as provided in § 176.83(a)(8) and in section 7.2.6.1, and
notwithstanding the requirements of paragraphs § 176.83(a)(6) and (a)(7) and sections
7.2.3.3 and 7.2.3.4 of the IMDG Code, hazardous materials of the same class may be
stowed together without regard to segregation required by secondary hazards (subsidiary
risk label(s)), provided the substances do not react dangerously with each other and
cause: (1) a combustion and/or evolution of considerable heat; (2) an evolution of
flammable, toxic, or asphyxiant gases; (3) the formation of corrosive substances; or
(4) the formation of unstable substances.
Q2: You ask whether a Division 2.3 gas poisonous by inhalation (with a subsidiary hazard of
Class 8 corrosive) and a Division 2.3 gas poisonous by inhalation (with a subsidiary

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hazard of Division 2.1 flammable gas) can be stowed in the same transport unit when
transported by vessel.
A2: The answer is yes, as provided in answer A1.
I hope this information is helpful. Please contact us if we can be of further assistance.
Sincerely,
Dirk Der Kinderen
Chief, Standards Development Branch
Standards and Rulemaking Division

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Jones, Jessie Jane CTR (PHMSA)
From: INFOCNTR (PHMSA)
Sent: Friday, June 7, 2024 2:20 PM
To: Dodd, Alice (PHMSA)
Cc: Hazmat Interps
Subject: FW: Request for DOT Letter of Interpretation
Attachments: USDOT-PHMSA Interpretation-Segregation of 2.3 Gases (002).pdf
Follow Up Flag: Follow up
Flag Status: Flagged
Hi Alice,
Please see the below interpretation request and supporting documents attached.
Let us know if you need anything,
-Breanna
From: Shelley Stampfler <Shelley.Stampfler@entegris.com>
Sent: Monday, June 3, 2024 3:53 PM
To: INFOCNTR (PHMSA) <INFOCNTR.INFOCNTR@dot.gov>
Subject: Request for DOT Letter of Interpretation
CAUTION: This email originated from outside of the Department of Transportation (DOT). Do not click on links
or open attachments unless you recognize the sender and know the content is safe.
From: Shelley Stampfler
Sent: Wednesday, May 22, 2024 12:27 PM
To: infocntr@dot.gov
Subject: Stowage of Class 2 Gases for Vessel regarding segregation
I have a question regarding stowage of the same types of gases in the same ocean container . The ocean carriers
are consistently questioning the use of provision 7.2.6.1 of the IMDG code and 176.83 (a) (8) of the DOT 49
CFR regulations to co-load class 8 sub risk with class 2.1 sub risk with Primary Hazard class 2.3
Would it be possible to get a letter from the DOT in the form of a Competent Authority Approval that confirms the
use of this provision .
So the question would be
Can a Class 2.3 Toxic Gas with a Sub risk of Class 8 be coloaded with a Class 2.3 Toxic Gas with a sub risk of class
2.1 provided Entegris meets the requirements as written
In 7.2.6.1 of the IMDG code and 176.83 (a) (8) of the DOT 49 CFR regulations
1

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I have attached a reference to an older interpretation letter from December 2012 showing ATMI as the company .
ATMI was aquired by Entegris in 2014 and would like to request a simliar letter to submit to the carriers that
question the use of this provision .
Thank you for your assistance
Regards,
Shelley Stampfler
Logistic Specialist IV
SCEM
T +1 203 739 1432
entegris.com
Danbury Technology Center
7 Commerce Drive
Danbury, CT 06810 USA
ENTEGRIS PROPRIETARY AND CONFIDENTIAL – INTERNAL
2

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of Transportation
U.S. Department
1200 New Jersey Avenue, SE
Washington, D.C. 20590
Materials Safety
Pipeline and Hazardous
Administration
Mr. James McManus
ATMI, Inc.
DEC 2 O 2012
7 Commerce Drive
Danbury, CT 06810
Ref. No.: 12-0239
Dear Mr. McManus:
This responds to your October 23, 2012 letter requesting clarification of the Hazardous
Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the segregation of
hazardous materials when transported by vessel. Your questions are paraphrased and
answered below.
Q1: You ask if a Division 2.3 gas (with a subsidiary hazard of Division 2.1) and a Division
2.3 gas (with a subsidiary hazard of Class 8) require segregation?
A1: The answer is no, provided the Division 2.3 gases are shipped in accordance with the
applicable provisions detailed in § 176.83. Multiple Division 2.3 gases may be stowed
in the same container for vessel transportation without regard to the subsidiary
hazards, provided the different poison gas materials are not capable of reacting
dangerously with each other and causing any of the conditions listed below.
Specifically, as provided in § 176.83(a)(8) and notwithstanding the requirements of
paragraphs (a)(6) and (a)(7), hazardous materials of the same class may be stowed
together without regard to segregation required by secondary hazards (subsidiary risk
label(s)), provided the substances do not react dangerously with each other and cause:
(1) a combustion and/or evolution of considerable heat; (2) an evolution of flammable,
toxic or asphyxiant gases; (3) the formation of corrosive substances; or (4) the
formation of unstable substances.
02: You ask if a Division 2.3 gas (with a subsidiary hazard of Division 2.1) and a Division
2.3 gas (with a subsidiary hazard of Class 8) can be stowed in the same transport unit
when transported by vessel?
A2: The answer is yes, as provided in Al.
I trust this satisfies your inquiry. Please contact us if we can be of further assistance.
Sincerely,
Henn saster
T. Glenn Foster
Chief, Regulatory Review and Reinvention Branch
Standards and Rulemaking Division
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