RegulusPipeline research66 FR 33316
Passage 1[Federal Register Volume 66, Number 120 (Thursday, June 21, 2001)] [Rules and Regulations] [Pages 33316-33454] From the Federal Register Online via the Government Publishing Office [www.gpo.gov] [FR Doc No: 01-13836] ----------------------------------------------------------------------- ----------------------------------------------------------------------- Research and Special Programs Administration ----------------------------------------------------------------------- Harmonization with the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions; Final Rule Federal Register / Vol. 66, No. 120 / Thursday, June 21, 2001 / Rules and Regulations ----------------------------------------------------------------------- Research and Special Programs Administration 49 CFR Parts 171, 172, 173, 175, 176, 177, 178, 179 and 180 [Docket No. RSPA-2000-7702 (HM-215D)] RIN 2137-AD41 Harmonization with the United Nations Recommendations,International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions AGENCY: Research and Special Programs Administration (RSPA), DOT. ----------------------------------------------------------------------- SUMMARY: This final rule amends the Hazardous Materials Regulations (HMR) to maintain alignment with international standards by incorporating various changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. In addition, this final rule revises the requirements for intermediate bulk containers and UN portable tanks for alignment with international requirements. Because of recent changes to the International Maritime Dangerous Goods Code (IMDG Code), the International Civil Aviation Organization's Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), and the United Nations Recommendations on the Transport of Dangerous Goods (UN Recommendations), these revisions are necessary to facilitate the transport of hazardous materials in international commerce.#
Passage 2DATES: Effective Date: The effective date of these amendments is October 1, 2001. Voluntary Compliance Date: With the exceptions of the ICAO Technical Instructions, 2001-2002 Edition and the International Atomic Energy Agency's (IAEA) Regulations for the Safe Transport of Radioactive Material, No. TS-R-1, which are authorized for use on July 1, 2001, RSPA is authorizing immediate voluntary compliance. However, persons voluntarily complying with these regulations should be aware that petitions for reconsideration may be received and as a result of RSPA's evaluation of those petitions, the amendments adopted in this final rule could be subject to further revision. Delayed Compliance Date: Unless otherwise specified, compliance with the amendments adopted in this final rule is required beginning on October 1, 2002. Incorporation by Reference Date: The incorporation by reference of publications listed in these amendments in Sec. 171.7 has been approved by the Director of the Federal Register as of October 1, 2001. FOR FURTHER INFORMATION CONTACT: Joan McIntyre, Office of Hazardous Materials Standards, telephone (202) 366-8553, or Bob Richard, Assistant International Standards Coordinator, telephone (202) 366- 0656, Research and Special Programs Administration, U.S. Department of Transportation, 400 Seventh Street, SW., Washington, DC 20590-0001.#
Passage 3On October 23, 2000, the Research and Special Programs Administration (RSPA) (hereafter, ``we'' and ``our'' means ``RSPA'') published a notice of proposed rulemaking (NPRM) (65 FR 63294) under Docket HM-215D. The NPRM proposed changing the Hazardous Materials Regulations (HMR), 49 CFR parts 171-180, based on the UN Recommendations, the IMDG Code and the ICAO Technical Instructions with respect to hazard communication, classification, and packaging requirements. The intended effect of the rule was to facilitate the international transportation of hazardous materials by ensuring a basic consistency between the HMR and international regulations, while at the same time ensuring the safe transportation of hazardous materials. On February 1, 2001, we published a final rule under Docket HM-215D (66 FR 8644) authorizing the use of the updated editions of the IMDG Code, the UN Recommendations and the UN Recommendations Manual of Tests and Criteria as proposed in the October 23, 2000 NPRM. This final rule addresses all other proposals published in the NPRM. The UN Recommendations are not regulations, but are recommendations issued by the UN Committee of Experts on the Transport of Dangerous Goods. These recommendations are amended and updated biennially by the UN Committee of Experts. They serve as the basis for national, regional, and international modal regulations (specifically, the IMDG Code, issued by the International Maritime Organization (IMO), and the ICAO Technical Instructions, issued by the ICAO Dangerous Goods Panel). In 49 CFR 171.12, the HMR authorize hazardous materials shipments prepared in accordance with the IMDG Code if all or part of the transportation is by vessel, subject to certain conditions and limitations. In Sec. 171.11, subject to certain conditions and limitations, the HMR authorizes the offering, acceptance and transport of hazardous materials by aircraft, in conformance with the ICAO Technical Instructions, and by motor vehicle either before or after being transported by aircraft. On December 21, 1990, we published a final rule based on the UN Recommendations (Docket HM-181; 55 FR 52402) which comprehensively revised the Hazardous Materials Regulations (HMR), 49 CFR parts 171 to 180, for harmonization with international standards. Since publication of the 1990 final rule, we have issued three additional international harmonization final#
Passage 4rules, (Dockets HM-215A, 59 FR 67390; HM-215B, 62 FR 24690; and HM-215C, 64 FR 10742). The rules provided additional harmonization with international air and sea transportation requirements by more fully aligning the HMR with the corresponding biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions. The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. According to the American Chemistry Council, exports of chemicals totaled almost $80 billion in the year 2000, while imports totaled nearly $74 billion. Harmonization serves to facilitate international transportation and at the same time ensures the safety of people, property and the environment. While the intent of the harmonization rulemakings is to align the HMR with international standards, we review and consider each amendment on its own merit. Each amendment is considered on the basis of the overall impact on transportation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without sacrificing the current HMR level of safety and without imposing undue burdens on the regulated public. In our efforts to continue the alignment of the HMR with international requirements, this final rule makes changes to the HMR based on the eleventh revised edition of the UN Recommendations, Amendment 30 to the IMDG Code, which became effective January 1, 2001; and, the 2001-2002 ICAO Technical Instructions which becomes effective July 1, 2001. Petitions for rulemaking pertinent to harmonization with international standards and the facilitation of international transportation are also addressed in this final rule and serve as the basis of certain amendments. Other amendments are based on feedback from the regulated industry, other DOT modal administrations and our initiative. Included are a few editorial clarifications. Certain commenters raised nonregulatory issues, issues that are beyond the scope of this rulemaking or suggested revisions that are now impractical (such as correcting the spelling of an entry that we removed). Such comments will not be addressed. Unless otherwise stated, the revisions are for harmonization with international standards.#
Passage 5II. Overview of Changes in This Final Rule (See specific section for discussion of comments.) Amendments to the HMR in this final rule include:#
Passage 6--Incorporation by reference of the updated ICAO Technical Instructions and addition of incorporation by reference of five current standards which include an International Atomic Energy Agency (IAEA) safety standard, three International Organization for Standardization (ISO) standards and one American Society for Testing Materials (ASTM) standard. --Amendments to the Hazardous Materials Table (HMT) which add, revise or remove certain proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, bulk packaging requirements, and passenger and cargo aircraft maximum quantity limitations. Proper shipping name amendments include replacing the word ``inhibited'' with ``stabilized.'' Entry removals include certain domestic entries for which corresponding UN entries are currently included in the HMT. --Revision of vessel stowage category definitions and codes for Class 1 (explosive) materials. --Revision of shipping paper requirements for sea transport. --Addition, removal and revision of certain entries to the List of Marine Pollutants. --Addition, removal and revision of special provisions, including removal of current T codes and IBC bulk provisions, and addition of UN portable tank codes and IBC special packing provisions consistent with those in the UN Recommendations. --Removal of the requirement to distinguish between primary and subsidiary risk labels and placards. --Addition and revision to the list of organic peroxides and the list of self-reactive substances. --Revision of the requirements pertaining to the transportation of samples. --Revision of intermediate bulk container (IBC) requirements including amendments to the IBC commodity sections in Secs. 173.240, 173.241, 173.242, 173.243 and 173.247, and addition of UN IBC packing instructions and special IBC packing provisions in part 172. --Incorporation of the design, construction and use requirements for UN portable tanks. --Consolidation of current portable tank maintenance, approval and use requirements. --Inclusion of flexible grandfather provisions for the continued use of IM 101, IM 102, DOT 51, DOT 57 and DOT 60 portable tanks. --Removal of specifications for DOT 52 and 53 portable tanks and the provisions for their continued use. --Incorporation of a provision for the use of the ``W'' mark for IBCs. --Revision of minimum thickness requirements for metal IBC#
Passage 7s. --Revision of several explosive packing methods to allow a broader selection of authorized packagings. --Revision of provisions for cigarette lighters and alcoholic beverages carried aboard aircraft. --Revision of the segregation table for hazardous materials stowed on aircraft. --Allowance of the display of only one placard when certain explosive compatibility groups are transported together. --Revision of lithium battery requirements. III. Summary of Regulatory Changes by Section#
Passage 8Section 171.7. We are updating the incorporation by reference for the ICAO Technical Instructions, and adding an ASTM standard, the current edition of the IAEA safety standard and three ISO standards as specified below. Amendment 30 to the IMDG Code, the eleventh revised edition of the UN Recommendations and the third revised edition of the UN Recommendations Manual of Tests and Criteria were incorporated into the HMR in a final rule under Docket HM-215D published February 1, 2001 (66 FR 8644) with a voluntary compliance date authorized as of January 1, 2001. One commenter opposed incorporation by reference of ASTM's E- 112-96 Standard for Test Methods for Determining Average Grain Size,'' and ISO's 1496-3 ``Series 1 freight containers--Specification and testing,'' 1996 edition; 4126-1 ``Safety valves-Part 1: General Requirements,'' 1991 edition, and 6892 ``Metallic materials--Tensile testing,'' 1984 edition. According to the commenter, the industry supports the use of voluntary consensus standards in commercial applications, however, because of the ``frequency of change'' and because industry does not adopt the standards verbatim, the commenter suggests that these standards be used as guidance. We disagree. The ``National Technology Transfer and Advancement Act of 1995'' directs agencies to use voluntary consensus standards. According to the Office of Management and Budget (OMB), Circular A-119, ``Federal Participation in the Development and Use of Voluntary Consensus Standards and in Conformity Assessment Activities,'' government agencies must use voluntary consensus standards wherever practical in the development of regulations. Agency adoption of industry standards promotes productivity and efficiency in government and industry, expands opportunities for international trade, conserves resources, improves health and safety and protects the environment. Furthermore, requirements in the industry consensus standards are not required to be applied on a mandatory basis unless specifically referenced as such. When incorporating standards in the HMR, we typically specify the specific requirements in the standard that must be met. Requirements that are not mandated in adopted standards are rarely imposed on a mandatory basis in RSPA rulemaking initiatives. On this basis, we are incorporating the standards as proposed. For international shipments of radioactive ma#
Passage 9terial, we are adopting the International Atomic Energy Agency (IAEA) safety standards, ``Regulations for the Safe Transport of Radioactive Material, No. TS-R-1'' with restrictions for its use for the domestic portion of the transport. Additionally, we are retaining Safety Series No. 6 with the same restrictions. As explained previously, TS-R-1 is the updated edition of the current Safety Series No. 6. Under this final rule, domestic shipments remain subject to the HMR requirements which are based on Safety Series No. 6. For domestic use, a proposal to adopt some or all of the TS-#
Passage 10R-1 standards will be addressed under a separate rulemaking, Docket HM- 230, which will provide discussion and opportunity for comment. As discussed in the final rule under Docket HM-215D published on February 1, 2001, we received comments supporting and opposing the incorporation by reference of TS-R-1 into the HMR. We received several comments from industry supporting the incorporation of TS-R-1 including requests for expedited publication of this final rule. Shippers will be required to comply with the TS-R-1 standards for export shipments and failure to comply would result in foreign authorities refusing to accept hazardous materials shipments prepared in accordance with the HMR. Several commenters stressed the importance of a timely compliance date to allow for a reasonable period to implement the TS-R-1 standards and the ICAO Technical Instructions, which both become effective on July 1, 2001. One commenter pointed out that not only does the time element greatly inhibit the preparation of packagings when nearing the July 1, 2001 effective date, but it will also have an impact on packagings already in transit. One commenter stated that failure to adopt TS-R-1 for international shipments will result in serious health treatment implications because radioisotope pharmaceutical products that are necessary for such treatment would be frustrated in transportation. As discussed in the February 1, 2001 final rule, we received many comments from private citizens and local citizen groups opposing the incorporation of TS-R-1. Some of these commenters also opposed the adoption of the updated editions of the IMDG Code and the ICAO Technical Instructions because both incorporate TS-R-1. (The IMDG Code was adopted in the February 1, 2001 final rule.) Most of the commenters stated that TS-R-1 lowers the level of safety for the transportation of radioactive materials and thereby poses hazards to the public, however many of these commenters did not provide any technical basis for their opposition. The comments included claims that the TS-R-1 standards for Type B packagings are ``weakened.'' As discussed in the February 1, 2001 final rule, the commenters are incorrect. The TS-R-1 standards strengthen Type B packagings by adding immersion and crush testing to the previously required performance tests. Furthermore, the standards also add limits on the contents of Type B pac#
Passage 11kaging when being transported by aircraft. Some commenters claimed that uranium hexafluoride packaging requirements are ``weakened'' in TS-R-1. These commenters are also incorrect. The criticality requirements for packages containing uranium hexafluoride did not change. Many of the commenters stated that TS-R-1's revised definition of radioactive material lowers the level of safety by changing the 70Bq/g activity concentration threshold. The revised radioactive material definition will be addressed under Docket HM-230 and is not adopted in this final rule. We are adding a paragraph to Secs. 171.11 and 171.12 to clarify that only the current definition of radioactive material applies. In addition, we are maintaining the current provisions in Secs. 171.11 and 171.12, including the values for Type A packaging contents. Shippers using TS-R-1 under the ICAO Technical Instructions or the IMDG Code must conform to the provisions and restrictions as set forth in Secs. 171.11 and 171.12, respectively. Based on the above, the incorporation by reference materials adopted in this final rule are as follows: --The ICAO Technical Instructions--2001-2002 edition. --ASTM's ``E 112-96 Standard for Test Methods for Determining Average Grain Size'' is added to define ``fine grain steel'' as included in the proposed incorporation of the UN portable tank specifications in Sec. 178.274. --IAEA's current ``Regulations for the Safe Transport of Radioactive Material, No. TS-R-1,'' 1996 edition is added while retaining the previous edition entitled, ``Regulations for the Safe Transport of Radioactive Material, Safety Series No. 6.'' The TS-R-1 requirements were incorporated into the IMDG Code which became effective on a voluntary basis on January 1, 2001 and the ICAO Technical Instructions which will be effective July 1, 2001. --Finally, we are adding three ISO standards to coincide with the incorporation of the UN portable tank requirements. The standards are as follows: ``ISO 1496-3 Series 1 freight containers--Specification and testing,'' 199 edition; ``ISO 4126-1 Safety valves-Part 1: General Requirements,'' 1991 edition; and, ``ISO 6892 Metallic materials-- Tensile testing,'' 1984 edition.#
Passage 12In the NPRM, we proposed to add IMO'S current ``International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships' (INF Code). Because the IMO Maritime Safety Committee adopted the INF Code for incorporation into the 2000 edition of the IMDG Code, which we authorized under Docket HM-215D (66 FR 8644) on February 1, 2001, we are not adding the INF Code separately under Sec. 171.7. Also see Secs. 176.2 and 176.720. Section 171.8. We are adding four new definitions to Sec. 171.8. ``Large packaging'' is added to correspond with the addition of an approval provision that allows the use of large packagings which comply with requirements in the UN Recommendations (see Sec. 178.801(i)). Large packagings are UN-marked bulk packagings which are very similar to IBCs, with the exception that they contain inner packagings. In the NPRM, we proposed to add a definition for ``Liner.'' After reconsideration, we believe that this definition is overly restrictive because it would preclude the use of liners such as those used in portable tanks, (for example, lead or rubber liner materials), bulk bins, IBCs and other types of packagings and the proposed definition would limit liners to bags and tubes. Plastic sheeting, rotationally molded rubber lining and other types of liners that are not bags or tubes would be excluded because the proposed definition limited liners to bags and tubes. On this basis, we are not incorporating the definition for ``Liner.'' ``Stabilized'' is added in conjunction with the proposal to replace the word ``inhibited'' with ``stabilized'' in proper shipping names (see Sec. 172.101). Finally, ``UN portable tank'' is added in conjunction with the requirements for the design, construction and use of UN portable tanks (see Secs. 178.274, 178.275, 178.276 and 178.277). Section 171.10. To correspond with the incorporation of the UN portable tank specifications, we are adding the unit of measure for ``Newton'' into the Table of Conversion Factors in paragraph (c)(2). Section 171.11. We are adding a new paragraph (d)(6)(vi) to limit the radioactive material definition to Sec. 173.403. We are also adding a new paragraph (d)(17) to ensure conformance with the current approval provision in Sec. 173.128(d) which requires an approval from the Associate Administrator for the offering for transport#
Passage 13ation or transport of organic peroxides that are not identified by technical name in the Sec. 173.225(b) Organic Peroxide Table. Section 171.12. In the NPRM, we proposed to revise paragraph(b)(3) by adding a limitation to the use of the IMDG Code, 2000 edition that became effective January 1, 2001. The limitation which regulates certain viscous flammable liquids that are excepted from the IMDG Code was incorporated#
Passage 14into the HMR on February 1, 2001 (66 FR 8646). One commenter stated that we should revise paragraph (b)(5) by removing the reference to Section 26 of the General Introduction to the IMDG Code because it will become obsolete January 1, 2002 (66 FR 8645) due to the extensive reformatting. We agree and are making the revision accordingly. We are also revising the paragraph to allow for the use of IBCs and UN portable tanks intended for liquids and solids that conform to the requirements of the IMDG Code. We are adding a new paragraph (b)(19) to ensure conformance with the current approval provision in Sec. 173.128(d), which requires an approval from the Associate Administrator for the offering for transportation or transport of organic peroxides that are not identified by technical name in the Sec. 173.225(b) Organic Peroxide Table. In addition, we are revising paragraph (d) to reflect the addition of the current edition of the IAEA ``Regulations for the Safe Transport of Radioactive Material, No. TS-R-1,'' 1996 edition. (See Sec. 171.7 for discussion concerning the addition of the updated TS-R-1 standards) to ensure that radioactive material is defined in accordance with Sec. 173.403. Section 171.12a. We are adding a new paragraph (b)(18) to ensure conformance with the current approval provision in Sec. 173.128(d) which requires an approval from the Associate Administrator for the offering for transportation or transport of organic peroxides that are not identified by technical name in the Sec. 173.225(b) Organic Peroxide Table. Section 171.14. We are revising paragraphs (d) and (d)(1) to authorize a delayed implementation date for the amendments adopted in the HM-215D final rule. The effective date of this final rule is October 1, 2001. However, we are authorizing immediate voluntary compliance. This authorization will allow shippers to prepare their international shipments in accordance with the new ICAO Technical Instructions, the IMDG Code and the HMR provisions. We also are authorizing a delayed mandatory compliance date of October 1, 2002 which is comparable to the transition provision provided in the final rule under Docket HM-215C. The delayed mandatory compliance date will offer sufficient time to implement the new provisions and deplete current stocks of shipping papers, labels, placards and packagings affected by the new requirements. We are revisin#
Passage 15g paragraph (d)(2) to permit intermixing of old and new (HM-215D) hazard communication requirements until October 1, 2002. We are adding a new paragraph (d)(4) to allow the use of the T code special provisions (assigned to certain hazardous materials in Column (7) of the HMT) in effect on December 31, 2000 until January 1, 2010 for hazardous materials offered for transportation in IM, DOT Specification 51 and IMO portable tanks. This amendment is consistent with the IMDG Code grandfather provisions for portable tank requirements and will minimize any undue regulatory burden. We are adding a new paragraph (d)(5) to allow continued display of proper shipping names with the word ``inhibited'' on packagings until October 1, 2005. (See Sec. 172.101, HMT for further discussion.)#
Passage 16Section 172.101. Paragraph (b)(1) is being revised for clarification of the use of the plus (+) sign. (See preamble discussion later in this section under the Hazardous Materials Table (HMT). We are revising paragraph (c)(11) for materials transported as samples which are assigned a tentative proper shipping name, hazard class, identification number and packing group. We are adding provisions based on the eleventh revised edition of the UN Recommendations to include requiring the word ``SAMPLE'' to appear in the proper shipping name, requiring a combination packaging, limiting the packaging size to 2.5 kg and allowing an exception from including the technical name when the constituents are not known. We also are adding a new paragraph (c)(16) to allow for the inclusion of the qualifying words ``liquid,'' ``solid'' or ``molten,'' as applicable, to a proper shipping name. We received several comments concerning our proposal to revise hazardous materials transported as samples. Some commenters stated that prohibiting samples from being packed together with other hazardous materials would be overly restrictive and impose an undue burden. Commenters presented examples to demonstrate their argument, including one scenario in which a hazardous material is transported on dry ice. Our intention for revising this paragraph is to prevent the dangerous mixing of materials as prohibited in Sec. 173.24 and to prevent the production of a mixture that would result in violation of Sec. 173.21. Because the HMR requires samples to meet the requirements in Secs. 173.21, 173.24, 173.24a and 173.24b, we agree that it is not necessary to prohibit samples from being shipped in the same packaging with other hazardous materials and are revising the paragraph accordingly. We are also removing proposed paragraph (c)(11)(i) in response to commenters' objections to the proposal prohibiting an explosive, infectious substance or radioactive material from being shipped as a sample. Provisions for transporting samples of such materials are currently authorized in the HMR and we agree that incorporation of the proposed paragraph (c)(11)(i) would be contrary to the current provisions. It was not our intention to remove the authorization to transport these materials as samples. As a result of these changes, certain proposed paragraphs are renumbered. One commenter requested that the word ``SAMP#
Passage 17LE'' be allowed to be shown on the shipping paper in association with the basic description. That is our intent, and although we proposed to require the word ``SAMPLE'' to appear in association with the basic description in the NPRM's preamble, the regulatory text wording required the ``SAMPLE'' to be shown before the basic description. The commenter is correct and we are revising the regulatory text accordingly. One commenter requested that we change the term ``hazardous waste'' to ``waste'' because in accordance with Sec. 171.8 the term ``hazardous waste'' applies only to those materials subject to the EPA manifest requirements under 40 CFR part 262. The commenter is concerned that generators of waste not subject to the EPA manifest requirements would be restricted from transporting their materials as samples. The commenter is incorrect by misapplying the use of the term ``generators of waste'' and ``hazardous waste.'' Under the CFR, the term ``hazardous waste'' does not apply to hazardous materials that are not subject to the EPA manifest requirements. Such materials are considered ``a sample of material'' in the context of paragraph (c)(11) and are not considered ``waste'' under the 49 CFR. Finally, based on comments recommending various revisions to clarify the intent of the paragraph (c)(11), we made certain editorial amendments, including clarifying that technical descriptions do not apply when the primary constituents for which the tentative classification is based are not known. In paragraph (k) for vessel stowage requirements in Column (10) of the HMT, we are adding new paragraphs (k)(6) through (k)(20) to include the IMDG Code vessel stowage category definitions for Class 1 (explosive) materials. This action is consistent with the new stowage categories and terminology contained in Amendment 30 of the IMDG Code. (Also see preamble discussion under ``The Hazardous Materials Table'' and Sec. 176.63.) The Hazardous Materials Table (HMT). Amendments to the HMT include the following:#
Passage 18--Several commenters noted minor editorial errors in the HMT and we made the appropriate changes to correct these entries. --For the entries, ``Other regulated substances, liquid, n.o.s.'' and ``Other regulated substances, solid, n.o.s.,'' we are adding the letter ``G'' to Column (1). The letter ``G,'' which denotes the n.o.s. and generic proper shipping names which are required to be supplemented with the technical names of the hazardous material (in parentheses and in association with the basic description), was inadvertently omitted in Docket HM-215C (64 FR 10742). One commenter requested that we allow marine pollutants to alternatively be described using the proper shipping names ``Other regulated substances, liquid, n.o.s.'' or ``Other regulated substances, solid, n.o.s,'' as appropriate. We are not adopting this requested amendment because the shipping names ``Environmentally hazardous substances, liquid, n.o.s.'' and ``Environmentally hazardous substances, solid, n.o.s'' more accurately describe marine pollutants as posing an environmental risk and are, therefore, more appropriate proper shipping names as required by the HMR.#
Passage 19--We are adding the following new entries: ``Nitroglycerin mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin by mass,'' UN3357; ``Propellant, solid,'' UN0501; ``Refrigerating machines containing flammable, non-toxic, liquefied gas,'' UN3358; ``Rockets with inert head,'' UN0502; and ``1H-Tetrazole,'' UN0504. --We are revising the entry, ``Dangerous Goods in Machinery or Dangerous Goods in Apparatus'' by replacing the identification number NA8001 with UN3363, designating a Class 9 assignment and revising Special Provision 136 (see Sec. 172.102). These changes reflect the adoption of the entry by the UN Committee of Experts and amendments agreed to by the ICAO Dangerous Goods Panel. The entry was added to the HMT under Docket HM-215C as NA8001 and assigned Special Provision 136 to prescribe the appropriate hazard class assignment. As explained in HM-215C, the entry was adopted in the ICAO Technical Instructions to provide an exception from the UN packaging performance tests for equipment, machinery or apparatus containing small quantities of hazardous materials. For machinery or apparatus not specifically listed in the HMT, the entry provides a practical means of describing and transporting machinery or apparatus containing small quantities of hazardous materials. In HM-215C, we stated that upon the assignment of a UN identification number, we would revise the entry accordingly. This was accomplished in the eleventh revised edition of the UN Recommendations in which UN3363 was assigned and this entry was assigned to Class 9. The ICAO Technical Instructions were amended consistent with this UN decision. Therefore, based on the above discussion, we are revising the entry, ``Dangerous Goods in Machinery or Dangerous Goods in Apparatus'' by assigning it to Class 9, replacing the domestic identification number with an international identification number, and revising Special Provision 136. --We are adding the entry ``Air bag inflators, pyrotechnic or Air bag modules, pyrotechnic or seat-belt pretensioners, pyrotechnic,'' UN0503 for air bags that are classified as Division 1.4G. We inadvertently omitted this entry in the NPRM. While we are not considering changing our policy or procedures for the classification of air bags as articles of Class 9, on the basis of the UN Manual of Tests and Criteria, 6c test, we believe that other competent aut#
Passage 20horities may assign a classification of 1.4G for some air bags. Incorporation of this entry is necessary to preclude the potential for frustrated shipments, the need to re-mark certain packagings or to change shipping papers for these air bags, when they are classified as 1.4G by other competent authorities and are being transported to or from the United States. --We are revising all proper shipping names containing the word ``inhibited'' by replacing ``inhibited'' with the word ``stabilized.'' (Also, see the added definition for ``stabilized'' in Sec. 171.8.) One commenter opposed the proposal to replace the word ``inhibited'' with ``stabilized'' and suggested that, instead, we clarify that monomers can be properly inhibited through means other than the addition of an inhibitor. The commenter stated that the words ``inhibited'' and ``stabilized'' have the same meaning for the purpose of transportation and expressed concern that we do not understand the distinction between the two words. The commenter also requested that we add several generic n.o.s. entries that include the word ``inhibited'' in the proper shipping names. We are not convinced of the merits of either request. The word ``stabilized'' introduces internationally accepted and standardized hazard communication wording and conveys that the addition of a stabilizing compound or other means of stabilization such as temperature control measures, have been implemented to prevent an unwanted reaction of a hazardous material. The word ``stabilized'' conveys a broader meaning of inhibiting uncontrolled reaction of a hazardous material (see Sec. 171.8) by different methods. The continued use of the word ``inhibited'' would lead to a dual system of hazard communication that would be burdensome to shippers and carriers. In addition, the word ``stabilized'' is more adequately descriptive from the emergency responders' perspective. Adopting the word ``stabilized'' will also alleviate the necessity of issuing numerous exemptions for the variety of methods or combination of methods used to inhibit uncontrolled reactions without the use of inhibiting chemicals. Based on these reasons, we are adopting the amendment as proposed.#
Passage 21One commenter requested that we extend the proposed transition period for this amendment to provide sufficient relief from remarking all affected bulk packagings. The commenter stated that an extended transition period would allow the remarking to be accomplished during routine maintenance and periodic inspection cycles. In the NPRM, we proposed a transition period until October, 2002. We agree that a longer transition period for domestic transportation would help relieve any undue burden associated with this amendment without having a significant impact on safety. We are including a transitional provision in Sec. 171.14 to allow the use of the word ``inhibited'' to be shown on packagings until October 1, 2005. The allowance of additional means of stabilization and the removal of certain domestic entries from the HMT (see domestic entry removals later in this section) also addresses a petition for rulemaking (P- 1304) requesting that we add a new domestic entry, ``Methyl methacrylate monomer, uninhibited,'' Class 3, NA1247, PG II to the HMT. As we stated, with respect to the request that we add generic n.o.s. entries that include the word ``inhibited,'' such an action would also be contrary to the intent of global harmonization and would be beyond the scope of this rule. We are not adopting the request. Commenters having an interest in developing generic names for inclusion into the UN Recommendations should provide more specific information and examples of materials that require stabilization and are not covered by existing entries.#
Passage 22--We are revising the following proper shipping names: ``Lithium hypochlorite, dry or Lithium hypochlorite mixtures, dry,'' UN1471; ``Printing ink, flammable,'' UN1210; and ``Nitrocellulose membrane filters,'' UN3270. --For the entry, ``Methacrylic acid, stabilized,'' UN2531, we are replacing Packing Group III with Packing Group II. --We are removing various domestic entries that have ``NA'' identification number assignments. As discussed in the NPRM, after reviewing the domestic entries, we determined that the HMR includes ``UN'' identification numbers assigned to entries that are equally appropriate in a number of instances, and in these instances the NA numbers are no longer necessary. In the NPRM, the revision of ``Diesel fuel'' with the identification number NA1883 was a printing error which we are correcting in this final rule. ``Diesel fuel,'' NA1993 is retained and we are adding ``Diesel fuel, UN1202.'' This amendment will allow flexibility of choice in the use of proper shipping names for domestic transportation. In addition, for the convenience of the HMT users, we are separating the entry ``Gas oil or Diesel fuel or Heating oil, light'' by giving each name a separate line entry in appropriate alphabetical order. In response to comments requesting that we reconsider the proposed removal of ``Gasohol,'' we are not removing the entry from the HMT. One commenter recommended that we provide T codes and IBC codes (see Sec. 172.102, Special Provisions) for the entry ``Combustible liquid, n.o.s.,'' NA 1993. We agree with the commenter and are adding portable tank instruction T1, portable tank Special Provision TP1 and IBC code IB3. However, we did not assign IB6 to this entry, as requested by the commenter, because Sec. 173.150(f) currently allows for the use of non-specification bulk packagings. Included in the proposed removals are seven domestic pesticide proper shipping names identified by the pesticide industry as no longer being used. These entries are: ``Aldrin, liquid,'' NA2762; ``Aldrin, solid,'' NA2761; ``Dieldrin,'' NA2761; ``Methyl parathion liquid,'' NA3018; ``Methyl parathion solid, NA2783; ``Parathion,'' NA2783 and ``Tetraethyl pyrophosphate solid,'' NA3018.#
Passage 23--We are adding radioactive material (Class 7) entries consistent with new entries introduced in the UN Recommendations and IAEA's ``Regulations for the Safe Transport of Radioactive Material, No. TS-R- 1.'' In addition, we are revising the current radioactive material entries in the HMR to indicate that these entries may be used for domestic shipments, but may be inappropriate for international transportation. --For Class 1 (explosive) entries, we are revising Columns (10A) and (10B) to reflect the vessel stowage codes as they are presented in Amendment 30 to the IMDG Code. (See Sec. 172.101(k) and Sec. 176.63.) --For the international entry ``Methanol,'' we proposed adding a plus sign (+) in Column (1) of the HMT to indicate that this entry is classified with a subsidiary hazard of Class 6.1 on the basis of human experience consistent with the UN Recommendations. One commenter objected to this proposal by stating that the action would unnecessarily restrict the shipment of dilute solutions of methanol. The commenter presented diluted methanol meeting the criteria for PG III as an example. In previous preamble discussions (see HM-215C Final Rule--Federal Register: March 5, 1999 (Volume 64, Number 43)) we indicated that a mixture or solution containing a hazardous material where the hazard is significantly different from that of the pure material should be evaluated on the basis of classification criteria. If such a mixture or solution does not meet the corresponding hazard class, a different proper shipping name may be used. Our position remains that when a mixture or solution of a material that is assigned a plus sign in column 1 of the HMT, no longer exhibits a hazard to humans, the material need not be described using a proper shipping name with a plus sign assignment. We recognize the need to clarify the intent of the plus sign in paragraph (b)(1). We are adding a sentence to paragraph (b)(1) to clarify the applicable requirements when the plus (+) sign is assigned to a proper shipping name. --We are removing the entry ``Isobutyric anhydride,'' UN2530. --For the entry ``Morpholine,'' UN2054, we are replacing Class 3 with Class 8, replacing Packing Group III with Packing Group I , and adding Class 3 as the subsidiary hazard. --For ``Organic peroxide type F, solid, temperature controlled,'' (UN3120), we are removing the Packing Group III entry that was du#
Passage 24e to a printing error in 49 CFR. The PG II entry remains. --For approximately 14 Zone A and B toxic-by-inhalation entries, we are revising the quantity limits for transport by air to ``forbidden.'' These revisions are consistent with other toxic-by-inhalation entries in the HMT and with the requirements of the ICAO Technical Instructions. --For the entry ``Fire extinguishers containing compressed or liquefied gas'' we are adding Special Provision 110 to Column (7). --We received a comment stating that our proposal to add Special Provisions 128 and B115 to the entry, ``Magnesium granules, coated, particle size not less than 149 microns,'' UN2950 (PG III only) was not reflected in the HMT and should also apply to ``Water-reactive solid, n.o.s,'' UN2813. After re-evaluation, we do not consider that it is appropriate to apply Special Provision 128 to ``Magnesium granules, coated,'' UN2950, because we are not convinced that these materials pose a Class 8 risk. As explained in the NPRM, this action is based on a petition for rulemaking (P-1338) that we received from the Aluminum Company of America (Alcoa). Special Provision 128 allows material meeting the Class 8 definition to be classed as a Division 4.3 with a Class 8 subsidiary hazard. Special Provision B115 authorizes the use of certain non-specification sift-proof bulk packagings when the material is loaded dry, precautions are taken to prevent liquid from reaching the hazardous materials and the bulk packagings are appropriately vented. However, UN2950 is assigned to bulk packaging Sec. 173.240 which already allows non-specification bulk packagings and, therefore, we are not applying Special Provision 128 or B115 to UN2950 in this final rule. In response to the comment that Special Provisions 128 and B115 should apply to ``Water-reactive solid, n.o.s.'' UN2813, we note that exemption DOT E-11602 only applies to one specific material containing magnesium or magnesium nitrides that is described using a technical name in association with ``Water reactive solid, n.o.s.'' We do not agree that broad application of Special Provisions 128 and B115 to all#
Passage 25PG II or III water-reactive solids is appropriate or necessary. --We received a comment stating that we did not include IBC and portable tank assignments for the PG II entry for ``Extracts, flavoring, liquid,'' UN1197. The oversight is corrected in this final rule. --Several commenters noted minor editorial errors in the HMT and we made the changes as appropriate. --For approximately 1,600 entries, we are revising Column (7) by harmonizing the HMR authorizations for IBCs with those contained in the UN Recommendations. As dicussed in the NPRM, in most cases the UN Recommendations provide for greater flexibility in the use of different types of IBCs. However, for certain hazardous materials, the incorporation of the UN IBC requirements further restricts the types of IBCs that were authorized prior to this final rule for certain hazardous materials. For example, some Packing Group II liquid hazardous materials of Class 3, Division 6.1 and Class 8 that were previously authorized to be transported in composite IBCs with flexible inner receptacles (such as 31HZ2) are no longer authorized. For the benefit of the reader and to facilitate a review of the proposed amendments, in the NPRM, we included a table identifying all of the affected hazardous materials and indicated the current bulk assignments and the proposed IBC assignments.#
Passage 26The IBC packaging requirements are included in a newly-created IBC Table under the Special Provisions section in Sec. 172.102(c)(4). The table consists of IBC Codes (using the designations IB1-IB99) corresponding to the UN IBC packing instructions, and BB Codes corresponding to the UN IBC special packing provisions. We assigned the IBC packing instructions and the BB codes to specific hazardous materials in Column (7) of the Sec. 172.101 HMT consistent with assignments in the UN Recommendations. In addition, we believe that consolidating the IBC requirements into one table makes it easier for readers to identify the authorized IBCs for specific hazardous materials. As a result of this amendment, we are revising the bulk special provisions in Sec. 172.102(c)(3) to remove the previously authorized bulk codes relevant to the use of IBCs. We are also revising the current IBC packaging authorizations under Secs. 173.240(d), 173.241(d), 173.242(d) and 173.243(d). This revision also addresses a petition we received from the Rigid Intermediate Bulk Container Association (RIBCA) (P-1395) requesting that we amend the HMR to expand the use of IBCs consistent with new UN provisions. Specifically, the petitioner requested that we allow the use of rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle for certain liquids. We agree with RIBCA's request, however, as discussed in the NPRM, in the interest of harmonization, we believe it is more beneficial to adopt the UN Recommendations' IBC packing instructions in totality, and, as such, are amending the HMR accordingly. One commenter stated that under the new IBC packing instructions, sodium cyanide and potassium cyanide would no longer be permitted in fiberboard or flexible IBCs. The commenter states that they are currently shipped this way according to B69. Although the UN Recommendations do not allow these types of IBCs for such materials, we are maintaining authorization for the use of fiberboard IBCs in domestic transportation. We will pursue the amendment to IB7 to allow the use of fiberboard (11G) IBCs through a proposal to the UN Transport Committee. However, we do not agree that flexible IBCs should be authorized for these hazardous materials. The commenter also stated that large packagings should be authorized for sodium cyanide and potassium cyanide. Assignment of large packaging authorizati#
Passage 27ons to specific substances is beyond the scope of this final rule. Currently, the UN Recommendations do not authorize large packagings for these substances. Large packagings are limited primarily to Packing Group III hazardous materials in the UN Recommendations. We plan to work through the UN Transport Subcommittee to address the commenter's concerns and depending on the outcome, we will address this issue in a future rulemaking. Appendix B to Sec. 172.101. In Appendix B to 172.101, List of Marine Pollutants, we are revising paragraph ``1'' by referencing Sec. 171.4, which contains the applicability and exceptions for offering for transportation or transporting marine pollutants. We are revising paragraph ``2'' to reflect the IMDG Code's provision for the use of two Class 9 proper shipping names when a marine pollutant is not listed by name in the HMT and does not meet the definitions of Class 1 through 8. In addition, a number of materials are added, removed or amended in the List of Marine Pollutants. The entry ``EPTC (ISO)'' is removed. The entry was also the subject of a petition for rulemaking (P-1360) requesting removal of the entry based on its removal from the IMDG Code. Various other entries no longer identified as marine pollutants are also removed. Consistent with the proper shipping name revisions to replace the word ``inhibited'' with ``stabilized,'' we are making the change to five entries in the List of Marine Pollutants. All of the amendments to the List of Marine Pollutants are consistent with the marine pollutants provided in Amendment 30 of the IMDG Code. (Also see Sec. 172.101, HMT for comment on use of proper shipping names for certain marine pollutants.) One commenter stated that the proposal to remove the entry ``Dichlorobenzenes (meta, ortho and para)'' from Appendix B and replace it with the entry ``Dichlorobenzene (para)'' will result in an inappropriate listing of entries in Appendix B of the HMT for dichlorobenzene isomers. The commenter stated that the changes in Amendment 30 of the IMDG Code only delist ``1,2 Dichlorobenzene (ortho)'' as a marine pollutant and that the appropriate dichlorobenzene entry, in addition to existing ``1,3 Dichlorobenzene,'' and ``1,4 Dichlorobenzene,'' should be ``Dichlorobenzene (meta; para).'' We agree with the commenter and are revising the entry accordingly. Section 172.102. We are revising, addi#
Passage 28ng and removing special provisions as follows: --Special Provision 43 is revised to include a provision which excepts ``Nitrocellulose membrane filters,'' UN3270 from the HMR requirements if shown not to meet the criteria for a Division 4.1 hazardous material, according to burn rate tests in Subsection 33.2.1. of the UN Manual of Tests and Criteria, Part III. --Special Provision 110 is revised to more fully identify fire extinguishers that may be assigned to certain proper shipping names. The revision also provides for harmonization with the ICAO Technical Instructions. (We also are adding the special provision to the entry, ``Fire extinguishers containing compressed or liquefied gas.'' See Sec. 172.101 HMT amendments.) --Special Provision 128 is revised based on the amendment to assign it to ``Magnesium granules, coated, particle size not less than 149 microns.'' (See Sec. 172.101 HMT changes.) --Special Provision 136 is revised to reflect the changes adopted by the UN Committee of Experts and the ICAO Dangerous Goods Panel for the entry ``Dangerous Goods in Machinery or Dangerous Goods in Apparatus.'' (Also see Sec. 172.101 HMT changes.)#
Passage 29We are revising the special provision by removing the text specific to the determination of the hazard class based on the UN Committee of Experts' decision that items under this entry should be assigned to Class 9. --A new Special Provision 139 is added for two new entries, ``Radioactive material, transported under special arrangement, fissile'' and ``Radioactive material, transported under special arrangement non-fissile or fissile-excepted.'' The special provision requires international shipments using the two entries to be made under an IAEA Certificate of Competent Authority to be issued by the U.S. Competent Authority. Domestic shipments transported under the two entries would be allowed only under a DOT exemption. --A new Special Provision 142 is assigned for the new entry ``Nitroglycerin mixture, desensitized, liquid, n.o.s.'' The special provision requires the material to be approved by the Associate Administrator. --A new Special Provision 143 is added for the entry ``Life-saving appliances, not self-inflating, containing dangerous goods as equipment.'' The special provision clarifies which articles may be transported under this entry. --A new Special Provision A53 is added for the entry ``Refrigerating machines,'' UN2857 and contains the exceptions from the HMR for certain refrigerating machines. The exceptions are currently in Sec. 173.307. --In conjunction with the amendment to revise and consolidate the IBC requirements (see Sec. 172.101, Column (7) changes), we are adopting the following changes: revising the special provisions for bulk packagings in paragraph (c)(3) to exclude IBCs by revising Special Provisions B53 and B69 and removing Special Provisions B100, B101, B103 through B106 and B108 through B110, adding a new paragraph (c)(4) for special provisions specific to IBCs (IP Codes). IP codes are used to describe the IBC packing instructions. We redesignated the term ``BB'' Codes, as named in the NPRM, to ``IP'' Codes in this final rule in order to make it easier for the HMR user to locate the Special Provisions. By redesignating the ``BB'' Codes, the IB the IP Codes will be listed together in alphabetical order in Sec. 172.102. --The current T codes in paragraph (c)(7) are revised to reflect the incorporation of requirements for UN portable tanks and apply to hazardous materials of Classes 2 through 9. The revised T codes are consistent w#
Passage 30ith those in the UN Recommendations and the IMDG Code and supersede the current HMR IM portable tank T codes. The T code provisions are required in addition to the requirements in part 178. The codes specify the types of authorized portable tanks according to the specific hazardous material transported in the portable tank. Portable tank assignments for Zone A and Zone B toxic-by-inhalation liquids remain consistent with their current assignments in the HMR. In instances where the UN requires a competent authority approval for transportation in portable tanks (such as when TP9 is assigned in the UN Recommendations), we have removed the approval provision. A transition period is provided for the continued use of the existing T codes for IM and DOT 51 portable tanks (see Sec. 171.14(d)(5)). One commenter stated that we did not provide for filling limits for portable tanks used to transport refrigerated liquefied gases. To correct this oversight, we are including filling limits that are similar to those applicable to cryogenic cargo tanks authorized under the HMR to transport refrigerated liquified gases. The filling limits will be contained in new Special Provision TP5 which was previously reserved. TP5 is assigned to all refrigerated liquified gases with a tank code T75 assignment. A commenter stated that fittings were not defined for TP22 which states that lubricants for portable tank fittings must be oxygen compatible. We do not believe that it is necessary to define ``fittings'' other than to require that they must be oxygen compatible. Our basic intent is that no incompatible materials or lubricants be used on fittings such as fasteners, valves, gauges, pipe thread or other fittings that may come into contact with the oxygen and cause an unsafe condition in transport.#
Passage 31-- We are removing proposed TP47 because it is not currently necessary. It is not assigned to any entries and the present requirements are addressed in the applicable packaging sections. -- In paragraph (c)(7)(iv), we are adding definitions for ``small,'' bare,'' ``sunshield'' and ``insulated'' as they apply to T50. --A new Special Provision W7 is added for seven new Class 7 entries and assigned the vessel stowage category ``D,'' as defined in Sec. 172.101(k)(4), to uranyl nitrate hexahydrate solution. -- A new Special Provision W8 is added for four new Class 7 entries and assigned the vessel stowage category ``D,'' as defined in Sec. 172.101(k)(4), to pyrophoric thorium metal or pyrophoric uranium metal. -- Finally, a new Special Provision W9 is added for assignment to the entries, ``Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen,'' UN1748; ``Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures with not less than 5.5 percent but not more than 10 percent water,'' UN2880; and ``Calcium hypochlorite mixtures, dry, with more than 10 percent but not more than 39 percent available chlorine.'' UN2208. This action aligns the packaging requirements for these entries with those contained in Amendment 30 to the IMDG Code by authorizing certain packagings only when approved by the Associate Administrator.#
Passage 32Section 172.202. We are revising paragraph (a)(4) based on a comment requesting that we eliminate the shipping paper requirement for inclusion of the packing group (PG II) for Class 1 (explosives) because the requirement conflicts with the UN Recommendations, the ICAO Technical Instructions and the IMDG Code, all of which do not require the inclusion of PG II on shipping papers. We agree with the commenter. The packing group does not indicate the degree of risk for explosives and does not aid emergency responders and we are providing an exception from this requirement. Based on the same reasoning, we are including in paragraph (a)(4) an exception from the packing group notation for organic peroxides and self-reactive materials. Section 172.203. We are revising paragraphs(d)(11), (i) and (n). In paragraph (d)(11), we are allowing an exception from the requirement to add the appropriate group notation to the shipping description for a shipment of low specific activity material or surface contaminated objects provided the group notation is contained in the proper shipping name. Based on a commenter's request for clarification, we are making editorial revisions to this paragraph to improve the clarity of the additional description requirements applicable to low specific activity (LSA) materials and surface contaminated objects (SCO). We are changing the wording ``unless these symbols are'' to ``unless the group notation is,'' and adding the wording ``as described in the Sec. 172.101 Hazardous Materials Table'' after the wording ``proper shipping name.''#
Passage 33In paragraph (i), we are adding two shipping paper description requirements for transportation by vessel. The first amendment is added as new paragraph (i)(5) and requires the flash point for a liquid hazardous material with a flash point of 61 deg.C or below to be included on shipping papers when transported by water. One commenter objected to the proposed requirement that for materials having a flash point of 61 deg.C or less (closed cup c.c.), the flash point must be included on shipping papers. The commenter questioned the value of this requirement. We submit that knowledge of the flash point of a material is a requirement for vessel operators under the requirements of SOLAS Chapter II-2, Regulation 54. The SOLAS requirement imposes cargo hold, electrical, ventilation, fire protection and bilge pump requirements on hazard classes 3, 6.1 and 8, having a flash point of 61 deg.C or less. In order to ensure that vessel operators have this information, the IMDG Code requires a shipper to include the flash point of such materials on shipping papers. Although for most hazardous materials this information may be derived from the classification and packing group, for some hazardous materials this is not possible. To ensure that the flash point information is readily available, and to harmonize the HMR with the IMDG Code, we are adopting the requirement as proposed. As discussed in the NPRM, we received a petition (P-1402) from the Vessel Operators Hazardous Materials Association (VOHMA) requesting that we add an additional shipping paper description requirement to include the minimum flash point in degrees Celsius for Class 3 (flammable) or combustible liquid hazardous materials. VOHMA stated that the amendment would help support compliance with the current stowage requirements in Sec. 176.305(c) and the segregation requirements (Code 22 and 23, see Sec. 176.84) as designated in Column (10B) of the Sec. 172.101 Hazardous Materials Table. We agree with the petitioner's reasoning, however, for consistency with the IMDG Code, we are adding the requirement to specify the flash point when it is 61 deg.C or below for all such liquid hazardous materials whether or not the primary hazard is Class 3. The second amendment to the shipping paper description requirements for transportation by vessel is added as new paragraph (i)(6) and is based on comments from the USCG regar#
Passage 34ding further harmonization with the IMDG Code. The amendment requires subsidiary risks of a hazardous material that are not reflected in the proper shipping name to be included on shipping papers. In paragraph (n), we are clarfiying that the shipping paper requirement for the word ``HOT'' to be placed immediately preceding the proper shipping names of hazardous materials that are transported as elevated temperature materials, is not required for proper shipping names containing the words ``Molten'' or ``Elevated temperature.'' Section 172.330. Consistent with the proper shipping name revisions that replace the word ``inhibited'' with ``stabilized'' (see Sec. 172.101), we are revising three such proper shipping names in paragraph (a)(1)(ii). Sections 172.402, 172.405 and 172.411. We received several comments concerning the proposal to remove the requirement to differentiate between primary and subsidiary labels. One commenter opposed the requirement with no elaboration. A second commenter stated that it would lower the level of safety. A third commenter opposed the adoption of the requirement stating that as an emergency responder, vital information necessary to respond to an incident would be lost. We disagree with this commenter. When a hazardous material has two or more hazards, each hazard must be considered in determining the appropriate response to an incident. The commenter also pointed out that the subsidiary risk is not required on shipping papers which would be another method for emergency responders to obtain the information. Under a separate rulemaking and consistent with the 12th edition of the UN Recommendations, we plan to propose a requirement to identify the subsidiary risks on shipping papers for all modes. In addition, for vessel only, we are adopting a requirement in this final rule for mandatory notation of subsidiary hazards on shipping papers, unless the subsidiary hazard is reflected in the proper shipping name. Consistent with the eleventh revised edition of the UN Recommendations, we are removing the requirement to differentiate between primary and subsidiary labels. Prior to this final rule, primary labels were required to display the hazard class or division number in the lower corner of the label, while subsidiary labels could not display these numbers. We believe the display of the hazard class and division on all labels will enh#
Passage 35ance safety and hazard communication. We are amending the requirement which provides for two label specifications (one for primary hazards and one for subsidiary hazards) by removing the subsidiary hazard label specification. This change also provides relief by eliminating the need for shippers to stock two sets of labels. Another commenter stated that the proposed 5 year transition period for continued use of subsidiary risk label requirements in effect prior to this final rule, is too lengthy and could cause problems in domestic transportation for multimodal shipments. The commenter stated that the proposed transition period is not necessary because the ICAO Technical Instructions and the IMDG Code have much shorter transition periods in place, and that it seems unlikely that shippers would stock 5 year supplies of subsidiary risk labels. Based on feedback from industry, we believe that a 5 year transition period is warranted to allow sufficient time for filled packagings that are pre-labeled to complete their cycle out of transportation. We are not convinced that the 5 year transition period will cause problems in domestic transportation. Also, based on feedback from industry, we maintain that many shippers stock 5 year supplies of subsidiary risk labels. Therefore, in order to provide a reasonable transition period, we are allowing labels meeting the label specifications in place prior to this final rule to continue to be displayed until October 1, 2005, at which time labels used to convey both primary and subsidiary hazards must display the appropriate hazard class or division number at the bottom of the label. (See Sec. 171.14 for transition provisions.) The same amendment also applies to placards (see Sec. 172.519). Section 172.502. In paragraph (b), we are correcting an error that was published in the February 1, 2001 final rule under Docket HM-215D. Based on a request from the Federal Register, we added a reference to ``see Sec. 171.7.'' During the typesetting process, the ICAO Technical Instructions were mistakenly added and the TDG Regulations were mistakenly omitted. We are correcting this error by removing the ICAO Technical Instructions and reinstating the TDG Regulations. Section 172.504. Based on comments and our own initiative, we are revising paragraph (g) by allowing the display of only one placard bearing one compatibility letter when cer#
Passage 36tain Class 1 materials (explosives) of different compatibility groups are transported together in a single transport vehicle or container. This amendment is consistent with the mixed packaging provisions in Sec. 173.61. Section 172.519. Consistent with the amendment to eliminate the distinction between primary and subsidiary labels, we are revising paragraph (b)(4) to eliminate the requirement to distinguish between primary and subsidiary placards. In addition, we are incorporating a new paragraph (b)(4)(i) to permit subsidiary placards meeting the current placarding specifications (such as placards without the hazard class or division number displayed in the lower corner of the placard) to continue to be displayed in domestic transportation provided they were permanently affixed before October 1, 2001. Non- permanently affixed subsidiary placards meeting the current placarding specifications are allowed to be displayed until October 1, 2005. (See Sec. 171.14 for transition provisions.)#
Passage 37Section 173.2a. Consistent with the eleventh revised edition of the UN Recommendations, in the paragraph (b) Precedence of Hazard Table, we are revising Footnote 2 to exclude liquid and solid desensitized explosives. In addition, we are adding the revised Footnote 2 to Class 3, PG I, II and III in the paragraph (b) Precedence of Hazard Table. Section 173.4. Based on a request for clarification, we are revising paragraph (a) to clarify that the small quantity exceptions apply to packagings containing articles, as well as inner receptacles. Section 173.24b. We are adding a new paragraph (e) to address acceptance of foreign manufactured UN portable tanks that conform to the applicable provisions in the UN Recommendations on the Transport of Dangerous Goods and are manufactured in countries that provide reciprocal treatment for UN portable tanks manufactured in the United States. Section 173.29. One commenter requested that two petitions for rulemaking be addressed in this final rule. The petitions request that IBCs meeting the Environmental Protection Agency's empty container rule in 40 CFR 261.7 be allowed to be transported without vehicle placarding and shipping papers. We are not addressing this issue under HM-215D because it is beyond the scope of this rulemaking. Section 173.31. Consistent with the proper shipping name revisions that replace the word ``inhibited'' with ``stabilized'' (see Sec. 172.101), we are revising one such proper shipping name in Sec. 173.31(b)(2)(ii). Section 173.32. One commenter stated that the consolidation of Secs. 173.32, 173.32b and 173.32c would impose requirements for DOT Specification 57 portable tanks that previously did not apply. The commenter provided specific recommendations for ensuring that new requirements for the maintenance and continued use of DOT Specification 57 portable tanks are not introduced. We did not intend to impose new requirements for DOT Specification 57 portable tanks. We considered the recommendations of the commenter and revised Sec. 173.32(d), (f) and (h) to address these recommendations. One commenter suggested that we incorporate certain editorial changes in Sec. 173.32 and part 180, subpart G, to clarify that not all portable tanks have a maximum allowable working pressure (MAWP) and that some requirements do not apply to all portable tanks, such as DOT Specification 56 and 57 portable tanks. T#
Passage 38he commenter stated that DOT Specification 57 portable tanks, for example, have a design pressure, but not a MAWP. The commenter also noted that when we consolidated the repair, inspection, test and maintenance requirements for portable tanks in the NPRM, we applied requirements to DOT Specification portable tanks that currently are not applicable under the HMR. We agree with the commenter's suggestions and are incorporating the suggested editorial corrections. One commenter stated that one of its members maintains and operates a large fleet of ICC Specification portable tanks and they requested that we maintain the current grandfather provisions for these portable tanks. As stated in the NPRM, our intent with removing the provisions was based on whether these portable tanks were being used. With receipt of this comment, we are retaining the provisions currently in 173.32(b) and (c) of the HMR by incorporating them into Sec. 173.32(c)(4) and (c)(5) in this final rule. The commenter also stated that DOT Specification 60 and marine portable tanks were not addressed in the NPRM and requested that these portable tanks be authorized for continued use. We did not propose any changes in the NPRM that would prevent continued use of these portable tanks. Another commenter expressed concern regarding our proposal to allow UN portable tanks to be designed and constructed to pressure vessel design codes other than the ASME Code. The commenter asked which codes would be acceptable and expressed concern that we would allow codes that are ``less stringent'' than the ASME Code. In response to this comment, we wish to advise the commenter that codes other than ASME will only be authorized if approved by the Associate Administrator for Hazardous Materials Safety, and only for UN portable tanks intended for the transport of liquid and solid hazardous materials. No approval provision was proposed for use of alternative design codes for portable tanks intended for the transport of liquefied gases. Because alternative codes are only allowed if approved by the Associate Administrator, applications for use of other design codes will be reviewed on a case by case basis. It is not our intention to allow the use of design codes that will not provide an equivalent level of safety as afforded in the ASME Code. We did not include a list of potential alternative codes because we have not#
Passage 39considered which codes we will accept and because other factors, in addition to the design code, will be considered in each case. One commenter stated that it is unclear whether the grandfather provision for DOT Specification 56 and 57 portable tanks manufactured after October 1, 1996 provides for such portable tanks to continue in service. We note that DOT Specification 56 and 57 portable tanks were not authorized to be manufactured after October 1, 1996. On October 1, 1996, the UN IBC requirements were introduced which replaced DOT Specification 56 and 57 portable tanks. Because paragraphs (c)(3) and (g) concerning pressure relief valves for DOT specification portable tanks are duplicative, we are removing paragraph (g). With this action the paragraphs following the removed paragraph (g) are renumbered. As proposed in the NPRM, we are revising Sec. 173.32 to provide requirements for all portable tanks by consolidating the requirements for the use of IM portable tanks currently in Sec. 173.32c into a single section and moving them to part 180, subpart G, with the qualification and maintenance requirements for IBCs, cargo tanks and tank cars. We are also including a grandfather clause in Sec. 173.32 to allow IM 101, 102 and DOT 51 portable tanks to continue to be constructed in accordance with the HMR until January 1, 2003. IM 101, 102 and DOT 51 portable tanks which are certified and approved prior to this date are authorized for continued use provided they meet the applicable periodic inspection and test requirements in part 180, subpart G. These requirements were previously in Sec. 173.32b. On January 1, 2003, all newly manufactured portable tanks will be required to conform to the requirements for the design, construction and approval of UN portable tanks (see Secs. 178.274, 178.275, 178.276 and 178.277). Finally, we are removing the provisions for the continued use of DOT Specification 52 and 53 portable tanks based on our view that these portable tanks are no longer#
Passage 40in use and the lack of comments to the contrary. Section 173.32a. We are removing Sec. 173.32a and moving its approval requirements for specification portable tanks to Sec. 178.273. We believe that part 178 is a more appropriate location for these requirements and that the new section will prove to be more convenient for users of the HMR. We also are including similar requirements for the incorporation of requirements for UN portable tanks. Section 173.32b. We are removing Sec. 173.32b and relocating the test requirements to part 180, subpart G, as discussed in Sec. 173.32. Section 173.32c. We are removing Sec. 173.32c. The requirements for the use of all specification portable tanks are now included in Sec. 173.32, thereby precluding the need for Sec. 173.32c. Section 173.34. Consistent with the proper shipping name revisions that replace the word ``inhibited'' with ``stabilized'' (see Sec. 172.101), we are revising two such proper shipping names in Sec. 173.34(e)(13). Section 173.61. Based on our own initiative, for Class 1 (explosives) mixed packaging requirements, we are revising paragraph (e)(3) to allow explosives of compatibility group S that are allowed to be packaged with explosives of all other compatibility groups, except A and L, to be treated as belonging to any of the packaged compatibility groups except S. In addition, we are adding a new paragraph (e)(8) to allow explosive articles in compatibility group G, except for fireworks and articles requiring special packaging, to be packaged with articles of compatibility groups C, D and E, and the combined package may be treated as belonging to compatibility group E. This revision corresponds with the previous allowance contained in Sec. 177.848(g). Section 173.62. Consistent with adding the entries ``Rockets with inert head,'' UN0502 and ``1H-Tetrazole,'' UN0504 to the Sec. 172.101 Table, we are adding them to the paragraph (b) Explosives Table which specifies the Packing Instructions assigned to each explosive. In paragraph (c), we are revising the Explosives Packing Instructions Table to authorize additional types of outer packagings in the following packing instructions: 112(a), 112(b), 112(c), 113, 115, 116, 130, 131, 134, 135, 136, 138, 140, 141,142 and 144. Section 173.150. We are revising paragraph (d) by clarifying that alcoholic beverages containing over 24% alcohol by volume are not excep#
Passage 41ted from regulation when transported by a passenger or crewmember on passenger-carrying aircraft except as provided in Sec. 175.10(a)(17). (See preamble discussion under Sec. 175.10.) Section 173.162. We are revising paragraph (a)(1) by clarifying that the types of packagings specified in the paragraph are combination packagings and that the glass, earthenware or rigid plastic packagings are authorized as inner packagings only. In addition, for these packagings, we are increasing the net mass of 10 kg (22 pounds) for each packaging to15 kg (33 pounds). This is consistent with Packing Instruction 800 in the UN Recommendations. Section 173.185. We are revising Sec. 173.185 to include a definition for equivalent lithium content for lithium ion cells and batteries and to provide the applicable aggregate lithium quantities relevant to excepting lithium ion cells and batteries from the requirements of the HMR consistent with the eleventh edition of the UN Recommendations. The definition of lithium content was revised in this final rule to make it consistent with a minor editorial clarification adopted by the Committee of Experts in its report of the 21st session (see section 38.3.2.2 in the amendments to the UN Manual of Tests and Criteria, report number ST/SG/AC.10/27/Add.2). This clarification was included based on a comment that we received. We adopted this clarification in order to prevent possible confusion about the lithium- equivalent content of lithium-ion battery packs that are currently used in many portable devices. For the readers' information, we plan to issue an NPRM under a separate rulemaking initiative to address the 12th edition amendments to the UN Recommendations that require all lithium batteries, regardless of the lithium content, to be subject to the lithium battery tests in Section 38 of the UN Manual of Tests and Criteria. The lithium battery amendments and revised test methods are available in the report of the UN Committee of Experts and may be downloaded at http://www.unece.org/trans/main/dgdb/dgcomm/ac10rep.html. Several commenters stated that we did not include the revised requirements applicable to large lithium batteries used for electric and hybrid vehicles and requested that we make the correction in the final rule. Although we discussed the amendment in the NPRM's preamble, the revised requirements were inadvertently omitted from#
Passage 42the regulatory text. This error is corrected in this final rule. Section 173.224. Consistent with the UN Recommendations, we are adding the entry ``2,2'-Azodi(isobutyronitrile) as a water-based paste'' to the Self-Reactive Substances Table for substances that are not subject to the approval provisions of Sec. 173.124(a)(2)(iii), provided all applicable provisions in the table are met. Finally, we are revising paragraph (b)(4) and removing paragraph (d) to allow Type F self-reactive substances to be transported in portable tanks under conditions specified in Sec. 173.225(e) (see preamble discussion under Sec. 173.225). Section 173.225. We are amending the paragraph (b) Organic Peroxide Table by making various changes, such as revising several technical names, packing method authorizations and control temperatures. These changes are consistent with the UN Recommendations. We are removing Notes ``7'' and ``10'' consistent with the adoption of UN IBC 520 and adding Note ``26'' to specify the available oxygen content limitation for certain new organic peroxide formulations. We are revising paragraph (e) to incorporate the requirements from the eleventh revised edition of the UN Recommendations relevant to the emergency venting devices for portable tanks and IBCs used for the transportation of organic peroxides and self-reactive substances. This responds to NTSB recommendation (I-92-2) that asked us to ``revise the requirements for pressure relief venting on DOT Specification 57 portable tanks used to transport dicumyl peroxides and other products with similar rapid decomposition characteristics to ensure that the pressure relief systems prevent overpressure rupture of tanks from a rapid product decomposition reaction.'' We are applying the recommended venting requirements to all portable tanks and IBCs, rather than just DOT Specification portable tanks. Additionally, the types of portable tanks authorized for type F organic peroxide and self-reactive substances are expanded to include UN portable tanks. We are adopting the requirements in Portable Tank Instruction T23 and IBC Special Provision, IBC 520. A commenter brought to our attention that Note 26 as proposed would conflict with the Sec. 173.21 restriction for ketone peroxides which limits oxygen content to 9% or less. We agree and are removing the proposed Note 26 text and renumbering the proposed Note 27#
Passage 43to Note 26. In addition, based on a comment, we are adding an organic peroxide formulation for 2,5 Dimethyl 2,5 di-2-ethylhex anoylperoxy hexane, UN3113. The entry was adopted in the UN Recommendations and inadvertently omitted in the NPRM.#
Passage 44We understand that the current Organic Peroxide Table includes a number of formulations that are no longer used. We encourage users of the Organic Peroxide Table to provide us with comments in this regard, as well as suggestions for improving the Organic Peroxide Table. Sections 173.240, 173.241, 173.242 and 173.243. In each section's paragraph (c), we are removing Specification DOT 52 and 53 portable tanks as authorized packagings (see Sec. 173.32 ) because we believe that these portable tanks are no longer used. In addition, we are authorizing UN portable tanks. In conjunction with the revision to the requirements for IBCs, for alignment with international standards, we are revising paragraph (d) which specifies authorized IBCs in Secs. 173.240, 173.241, 173.242 and 173.243 to reflect the proposed incorporation of IBC packing instructions and IP codes (see Sec. 172.101, Column (7)). Based on a comment that we received, we are not requiring temperature sensing devices or reclosing pressure relief devices for DOT Specification 57 portable tanks. We agree with the commenter that such portable tanks have limited use and are very similar to IBCs. We also received a comment stating that Sec. 173.240 should be amended to allow the use of non-specification flexible (``supersacks'') IBCs for hazardous materials such as ``Environmentally hazardous substances, solid, n.o.s.'' Specifically, the commenter requested that we authorize the use of non-specification ``supersacks'' in Sec. 173.240. The commenter questioned the omission by asking why we do not authorize non-specification IBCs, yet we provide for the use of other non-specification bulk packagings. While it is our intent at this time to maintain authorization for use of non-specification portable tanks and bulk bins in Sec. 173.240(c), we do not agree that non- specification IBCs should be authorized. The only non-specification bulk packagings authorized in Sec. 173.240 are portable tanks and bulk bins which are rigid packagings of a higher integrity when compared to a 2,000 pound non-specification bag. Neither the current HMR nor the UN Recommendations authorize the use of non-specification IBCs for environmentally hazardous substances. We believe that authorization of the non-specification ``supersacks'' would be detrimental to safety and, therefore, we are not incorporating it into the HMR. Section 173.247.#
Passage 45In paragraph (c), we are removing Specification DOT 52 and 53 portable tanks as authorized packagings (see Sec. 173.32). Sections 173.301, 173.304, 173.314, 173.315 and 172.330. Consistent with the proper shipping name revisions that replace the word ``inhibited'' with ``stabilized'' (see Sec. 172.101), we are revising all such proper shipping names in these sections. Section 173.306. Consistent with Packing Instruction P201 in the UN Recommendations, we are amending the paragraph (a)(4)(iii) conditions for transporting flammable, non-pressurized gas samples by revising the inner packagings limit from 2.5 L (0.66 gallons) to 5 L (1.3 gallons). Sections 173.314 and 173.315. Consistent with the proper shipping name revisions that replace the word ``inhibited'' with ``stabilized'' (see Sec. 172.101), we are revising one such proper shipping name in Sec. 173.314(c) and (g) and two such proper shipping names in Sec. 173.315(a), (b) and (h). Section 173.315. As proposed in the NPRM, we are revising paragraphs (a) and (i)(1)(iii) to incorporate provisions for the use of UN portable tanks for the transportation of liquefied compressed gases and the requirements for DOT Specification 51 portable tanks. In paragraph (a), we are incorporating a reference to new tank instruction T50 (see UN T Codes under Sec. 172.102) for the transportation of liquefied compressed gases in UN portable tanks. In paragraph (i)(1)(iii), we are including the pressure relief device requirements applicable to UN portable tanks. We received a comment questioning the intent in paragraph (a)(1)(iii) concerning the insulation requirements. The commenter was concerned that the paragraph prevents the use of mylar, other low melting films and aluminum for jacket materials. We note that the paragraph does not prohibit the use of jackets constructed of materials other than steel, except in the case when the portable tank manufacturer is attempting to lower the required relieving capacity of the relief devices by taking into account the thermal protection afforded by the insulation. The UN portable tank requirements intentionally restrict the jacketing material to steel when using the insulation as a means for reducing the required relieving capacity of the pressure relief devices, because jacket materials with lower melting temperatures, such as aluminum, would not provide adequate fire damage protect#
Passage 46ion for the inner vessel, or for the vacuum insulation in the case of a vacuum insulated tank to justify allowing a lower overall relieving capacity for the pressure relief system. We agree with the UN reasoning for limiting jacket material to steel, and, therefore, we are adopting the paragraph as proposed. Section 173.320. For transportation by air for cryogenic liquids exceptions, we are making an editorial clarification in paragraph (c) to refer readers to the specific cites in the ICAO Technical Instructions rather than stating ``see Sec. 171.11 of this subchapter.''#
Passage 47Section 175.10. For consistency with the ICAO Technical Instructions, we are revising paragraph (a)(10) to clarify that lighters containing ``unabsorbed liquid fuel'' are prohibited on one's person or in checked or carry-on baggage. We are revising exclusions for alcoholic beverages as carry-on and checked baggage to impose a per passenger quantity limit and to restrict the exceptions to alcoholic beverages in retail packagings containing not more than 70% alcohol. We are revising paragraph (a)(16) to exclude alcoholic beverages. Also, we are adding new paragraph (a)(17) to specify that alcoholic beverages containing more than 24% and not more than 70% alcohol by volume, when carried by passengers or crew in checked or carry-on baggage, are not subject to the HMR if in retail packagings not exceeding 5 liters (1.3 gallons) with a total net quantity per person of 5 liters (1.3 gallons). These changes are consistent with the ICAO Technical Instructions. Section 175.33. For harmonization with the ICAO Technical Instructions, we are revising paragraph (a) introductory text to add a requirement that the written pilot notification must be accurate and legible. Section 175.78. We are revising this section to update and align segregation requirements with recent changes adopted in the ICAO Technical Instructions which were based on a UN decision to remove the distinction between primary and subsidiary risk labels. Separate rows and columns are provided for Divisions 5.1 and 5.2. We are adding a new provision to clarify that packages with multiple risks do not need to be segregated from other packages bearing the same UN number. The ICAO Technical Instructions currently require segregation of Divisions 5.1 and 4.3 hazardous materials and we have revised the entry to reflect the change. Section 175.85. Consistent with a new provision adopted in the ICAO Technical Instructions, we are revising paragraph (a) to authorize use of main deck Class C cargo compartments for the transport of hazardous materials. Prior#
Passage 48to this final rule, hazardous materials were allowed to be carried in a main deck cargo compartment of a passenger aircraft provided the compartment was inaccessible to passengers and it met certification requirements for a Class B cargo compartment. (Class C cargo compartments differ from Class B cargo compartments in that Class C compartments are required to have a built-in fire extinguishing system, in addition to smoke or fire detection systems.)#
Passage 49Section 176.2. In conjunction with incorporating a requirement for vessel cargo to be in compliance with the INF Code (see Sec. 176.720), we are adding a definition for ``INF cargo'' under the Sec. 176.2 definitions. Section 176.63. For the stowage of Class 1 (explosive) materials on board a vessel, we are adding a stowage location definition for ``closed cargo transport unit.'' This addition coincides with the addition of the vessel stowage category definitions contained in Amendment 30 to the IMDG Code. (See Sec. 172.101(k).) Section 176.84. Consistent with the IMDG Code we are revising paragraph (b) Table of provisions and paragraph (c)(2) stowage provisions. In the paragraph (b) Table of provisions, we are adding two new stowage provisions for assignment to the entries: ``Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen),'' ``Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not less than 5.5 percent but not more than 10 percent water,'' and ``Calcium hypochlorite mixtures, dry with more than 10 percent but not more than 39 percent available chlorine.'' In the paragraph (c)(2), we are revising the list of notes for the stowage of Class 1 (explosive) material provisions. Section 176.128. We are making an editorial change in Sec. 176.128(c) by correcting an identification number. Section 176.136. We are making an editorial change in Sec. 176.136 by removing the word ``portable.'' Section 176.142. Based on a comment from the National Cargo Bureau, Inc., in Sec. 176.142, paragraph (a), we are revising the list of hazardous materials that may not be transported in a vessel carrying Class 1 (explosive) materials to reflect the most current proper shipping names and add one extremely flammable material, ``Methyl phosphonous dichloride, pyrophoric liquid,'' NA2845. Section 176.720. We are adding a new section to require a vessel carrying INF cargo in international transportation to comply with the ``International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships,'' (INF Code, 2000, English edition). The INF Code was adopted by the International Maritime Safety Committee and became effective January 1, 2001 in the IMDG Code.#
Passage 50Section 177.848. In paragraph (g)(3)(vi), we inadvertently added the terms ``special stowage'' and ``stowed'' from the corresponding vessel section of the HMR (Sec. 174.81) under HM-215C (64 FR 10742). We are correcting the wording by removing ``special stowage,'' which is not applicable to this section, and replacing ``stowed'' with ``loaded, transported and stored.'' We received a joint petition from the American Trucking Associations (ATA) and the Institute of Makers of Explosives (IME) (P-1396) requesting additional clarification of this paragraph. Prior to this rule, the paragraph read: ``(vi) ``6'' means explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with other explosive articles of compatibility groups C, D and E, provided no explosive substances (for example, those not contained in articles) are carried in the same vehicle.'' In this paragraph and the corresponding paragraph in Sec. 174.81, the petitioners request that the words ``other explosives'' be inserted before the wording ``explosive substances.'' The petitioners are incorrect in their interpretation of the wording of this paragraph. Explosive articles in compatibility group G may be stowed with certain other explosive articles (C, D and E compatibility groups), provided no explosive substances that are not contined within articles are carried in the same vehicle. We point out that there is a distinction between the words ``articles'' and ``substances.'' To take advantage of this paragraph, explosive substances that are not contained in articles may not be carried on the vehicle. We are revising the paragraph to clarify that substances are prohibited when not contained in articles.#
Passage 51Section 178.273. We are adding a new section by moving the current requirements for the approval of portable tanks from Sec. 173.32a to Sec. 178.273. This new section will include approval provisions for all portable tanks, including ``UN portable tanks.'' These current approval provisions will precede the requirements for UN portable tanks (Secs. 178.274 through 178.277). Approval agencies that have an interest in approving UN portable tanks must send a request to DHM-32, Office of Hazardous Materials Approvals, in accordance with the requirements in part 107, subpart E of this subchapter. Sections 178.274, 178.275, 178.276 and 178.277. Based on the eleventh revised edition of the UN Recommendations, we are incorporating four new sections into the HMR for the UN portable tank requirements. This action is based on our own initiative and a petition for rulemaking (P-1373) and is consistent with our international harmonization objectives. The requirements apply to the design and construction of portable tanks. The IMO Dangerous Goods, Solid Cargoes and Containers (DSC) Sub-Committee incorporated the new harmonized UN multimodal portable tank requirements into the reformatted IMDG Code, Amendment 30. The reformatted IMDG Code became effective on January 1, 2001. The IMDG Code also includes a provision to allow for the continued use of portable tanks designed and constructed under the current requirements (those in Amendment 29 or previous amendments to the IMDG Code as applicable, depending on the date of construction). The IMO allows construction under the new requirements on January 1, 2001, on a voluntary compliance basis, with a mandatory compliance date of January 1, 2003. On January 1, 2003, all new portable tanks will be required to be manufactured in accordance with the new requirements. For purposes of harmonization, we are incorporating the corresponding design, construction and use requirements for UN portable tanks in the HMR. In addition, in Sec. 173.32 we are providing for the continued use of IM 101, 102 and DOT Specification 51 portable tanks, which is consistent with the provisions adopted in the IMDG Code. The design and construction requirements for UN portable tanks do not differ significantly from the previous IM 101 and 102 portable tanks and the DOT Specification 51 requirements. In general, the UN requirements are less restrictive. For e#
Passage 52xample, 6 mm (0.2 inches) minimum thickness is required for most portable tanks, as opposed to the current minimum thickness of 6.35 mm (0.3 inches) for IM 101 and 102 portable tanks. As discussed in the NPRM, while the majority of the changes involve relaxations of the regulatory requirements, there will be implications for portable tank manufacturers, shippers and operators who transport hazardous materials in portable tanks. For example, we are requiring UN portable tanks used for the transportation of liquefied compressed gases to be approved by a DOT- designated approval agency, and we are requiring all UN portable tanks to meet a 4 g impact test. In addition to portable tanks for liquids and liquefied compressed gases, we are incorporating requirements for portable tanks that are used to transport refrigerated liquified gases (cryogenic liquids). Previous to this final rule, requirements for portable tanks used for refrigerated liquefied gases were not specified in the HMR, and we authorized their use only under DOT exemptions. The differences between UN portable tanks and the previous portable tank requirements include, but are not limited to the following:#
Passage 53--The new definition for portable tank includes multimodal tanks with a capacity of more than 450 liters (118.9 gallons). --The new design temperature range is defined as -40 deg.C to 50 deg.C (-40 deg.F to 122.0 deg.F). This final rule includes the requirement that design temperatures must be considered for portable tanks subjected to severe climatic conditions. Previous to this final rule, regulations specified a range of -20 deg.C to 50 deg.C (-4.0 deg.F to 122.0 deg.F). --The new UN leakage test for portable tanks intended for the transport of liquids specifies a test pressure not less than 25% of Maximum Allowable Working Pressure (MAWP). The previous HMR requirements specified an internal pressure equivalent to MAWP, but not less than 0.2 bar (20.0 kPa) for liquids. --The new test requires that the design and construction of portable tanks must take into account the effects of fatigue during normal conditions of transport. Previously, this was not required in the HMR. --The new requirements specify an absolute minimum thickness of 3 mm (0.1 inches), regardless of the material used and regardless of whether additional protection is provided. --Under the new requirements, a rail impact test of 4 g is required for all portable tanks meeting the definition of ``Container'' in the International Convention for Safe Containers (CSC). --The new requirements specify that the test pressure be 1.3 times the design pressure for portable tanks intended for the transport of liquefied gases. Previously, under the HMR, DOT 51 portable tanks used for the transportation of liquefied gases were required to have a test pressure of 1.5 times the design pressure; however, this is based on the vapor pressure of the hazardous material at 115 deg.F (46.1 deg.C), whereas the UN calculates the vapor pressure at 65 deg.C (149 deg.F). The differences between 1.5 at 46 deg.C and 1.3 at 65 deg.C, therefore, would not be significant. (Although one commenter stated that they disagreed with this statement, our view is explained further in the preamble discussion under Sec. 178.274.) --The new requirements include a figure for thermal conductance for the thermal insulation systems of shells intended for the transport of liquefied compressed gases. --The new requirements include a definition for ``Holding time'' relevant to portable tanks used for the transportation of refrigerated lique#
Passage 54fied gases. This is consistent with current HMR requirements in Sec. 178.338-9 for cargo tanks. --The new requirements specify the effectiveness of the insulation system (heat influx in watts) based on a test using the portable tank. --The new requirements allow the specified minimum values of material strength for austenitic steels to be increased by 15% according to recognized material standards when greater values are provided in the material inspection certificates. --The new requirements allow the combined capacity of all pressure relief devices to be sufficient to limit the pressure to 120% of the MAWP for liquefied compressed gases.#
Passage 55Section 178.274. One commenter stated that the required test pressure for UN portable tanks used for the transportation of propane would increase from 320 psig to 400 psig. We believe that the values cited by the commenter are not accurate. Based on the Fourth Edition of the Compressed Gas Association Handbook of Compressed Gases, the vapor pressure of propane is approximately 220-230 psia at a reference temperature of 115 deg.F (46.1 deg.C) and approximately 270-275 psia at 130 deg.F (54.4 deg.C). The required MAWP according to Sec. 173.315 is 250 psi. The test pressure for a UN portable tank would be approximately the same as that for a DOT 51 portable tank and in some cases may be slightly less. In this case, it would not be in the interest of harmonization to vary from the internationally agreed design pressure formulas. Based on the above, we are adopting the requirement as proposed. One commenter stated that aluminum should be authorized as a material for portable tank shell construction. The UN Recommendations allows aluminum only for portable tanks intended for liquid and solid materials when approved by the competent authority. Aluminum is not authorized for portable tank shells intended for non-refrigerated liquefied gases, however, aluminum is authorized for shells of portable tanks intended for the transportation of refrigerated liquefied gases. Based on the merits of these comments and to be consistent with the UN Recommendations, we are amending paragraph (b) accordingly. Also regarding paragraph (b), some commenters requested background information explaining the justification and application of the proposed -40 deg.C lower range for the design temperature applicable to UN portable tanks. This lower temperature was adopted because the UN working group recognized that -20 deg.C was not sufficient to represent temperatures that UN portable tanks may experience in certain parts of the world. One commenter stated that it was not clear whether the requirement was applicable to all portable tank components or only to the shell. In response to this comment, we point out that the design temperature range applies to the shell which is the primary pressure and lading retention component of the portable tank. The general requirements for design and construction state that ``Portable tank materials must be suitable for the external environment where they#
Passage 56will be transported taking into account the determined design temperature range.'' This provision requires service equipment to be suitable for the climatic conditions to which it will be exposed. For these reasons, we are not amending the proposed language. One commenter stated that the change from the very prescriptive relief device location for IM portable tanks in Sec. 178.270- 11(b)(1)(i) to the less specific requirement is ``too open to interpretation'' and requested clarification. We do not agree with the commenter. The main safety concern is that when the tank is filled to its maximum filling condition, the relief device is located in the vapor space and will ensure that escaping vapor can be discharged free from any obstruction. The text accomplishes this objective and is more flexible and performance-oriented. Specifically limiting the location by specifying exact tolerances forces us to issue exemptions and approvals when the location varies from these specific parameters. In addition, the text as proposed in this section is consistent with how the HMR specifies pressure relief device location for DOT specification 400 series cargo tanks#
Passage 57(see178.345-10(c)). We are adopting the text as proposed. One commenter stated that the proposed requirement to group outlet openings in paragraph Sec. 178.274(e)(7) of the NPRM should not apply to portable tanks used for refrigerated liquified gases due to their unique design. The commenter explained that this requirement does not currently apply to exemption cryogenic portable tanks or MC 338 Specification cargo tanks (see Sec. 178.338-7), nor is it a requirement under the UN Recommendations. We agree with this commenter and are amending the paragraph to reflect that the external fitting grouping requirement applies only to portable tanks intended for the transportation of non-refrigerated liquefied gases. This amendment is consistent with the current requirement that applies to DOT Specification 51 portable tanks in Sec. 178.245-1(c). We agree that the additional exceptions applicable to locating openings in other locations in Sec. 178.245-1(d)(1), (2) and (3) should also apply and, therefore, we are revising the text accordingly. Because these requirements are applicable only to portable tanks intended for the transport of non-refrigerated liquified gases, we are moving the text to the more appropriate location of Sec. 178.276. We received two comments concerning the proposed requirements for the internal valve emergency shut-off device in paragraph (e)(7). One commenter stated that there is no requirement in the UN Recommendations nor the IMDG Code for a thermally activated closure. Our intent with this paragraph is consistency with a requirement that was published under a final rule (Docket HM-166Y; 63 FR 37453) on July 10, 1998, requiring an IM portable tank to be retrofitted if unloaded while it remained on a transport vehicle with the power unit attached. The commenter stated that we proposed to expand the concept by making a thermally activated device part of the service equipment for all UN portable tanks and that the requirement would be contrary to harmonization because UN portable tanks are used worldwide. They suggested that the requirement should first be introduced at the UN Committee of Experts for consideration. Although the requirement is only a condition for unloading IM portable tanks from vehicles while the motor unit is attached, we were informed through meetings with portable tank users and manufacturers that it is not feasible to de#
Passage 58termine which IM portable tanks would be offloaded in this manner and that all IM portable tanks would need to be retrofitted with thermally activated closure devices (fusible links) in order to comply with the requirement in Sec. 177.834(o). In a request for an interim final rule concerning the retrofitting requirement published in HM-166Y final rule, the Hazardous Materials Advisory Council (HMAC) stated ``For commercial and economic reasons, it is not practical to remove all tanks from service at once to retrofit the bottom outlet valves with thermally activated closure devices. Tanks are either in a transport cycle, in storage, or in repair/maintenance shops. If all of the portable tanks were taken out of service at the same time to complete this retrofit, many industrial operations would be severely disrupted.'' DOT 51 portable tanks are required to be fitted with these closures (see Sec. 178.245-1(d)(iii)) and in the HM-215D NPRM we proposed that UN portable tanks used for non-refrigerated liquified gases be fitted with these devices consistent with paragraph 6.7.3.5.4 of the UN Recommendations. The UN Recommendations require ``quick closing'' shut-off devices that close automatically in the event of fire engulfment and unintended movement of the portable tank for portable tanks used to transport flammable refrigerated and flammable and toxic non-refrigerated liquified gases. We are removing the requirements for these shut-off devices to operate based on unintended movement because we believe it is not practical. We believe that even though this is not a requirement under the UN Recommendations for liquid materials, it is a domestic requirement and from the safety perspective, as discussed under Docket HM-166Y, it should be applied to U.S. manufactured UN portable tanks intended for the transportation of liquid hazardous materials which are flammable, pyrophoric, oxidizing or toxic. We believe it would be in the best interest of safety to fit these portable tanks with thermally activated closures. We estimate that the cost of installing a fusible link will be approximately $40.00 to $70.00 per portable tank based on information provided by tank and tank valve and component manufacturers. Installation at the time of manufacture will avoid downstream retrofitting costs, costs associated with shipping delays and logistical problems at a later date. In pre#
Passage 59vious discussions with the Hazardous Materials Advisory Council and the Tank Container Association, we were informed that retrofitting of portable tanks would cost approximately $200.00 to $250.00 per portable tank. On the basis of these costs, it makes economic sense to install the devices at the time of manufacture. We agree that this requirement should be proposed to the UN Committee of Experts and will follow-up accordingly. On the basis of enhanced safety, minimal cost at the time of manufacture, shipping delays and logistics, we are requiring U.S. manufactured UN portable tanks intended for transporting certain liquids to be fitted with thermally activated closures (fusible links). The internal valve shut-off requirements are revised for consistency in Secs. 178.275(d)(3), 178.276(c)(4) and 178.277(d). Concerning paragraph (i), one commenter stated that markings such as maximum allowable working pressure, test pressure, maximum gross mass and the applicable T Code should be marked on the tanks following the ``UN'' mark in order to convey that the cargo is authorized for that particular portable tank. We agree that a T marking on the tank may be advantageous, however, the UN Recommendations do not require a T mark and imposing such a requirement is beyond the scope of this final rule. Incorporation of a T code marking in this rule could lead to different requirements in domestic and international regulations if such a proposal is not adopted by the UN Transport Subcommittee. With regard to the other markings, the information is marked on a specification plate (see Sec. 178.274(i) of the regulatory text). Finally, we moved the requirements for the initial inspection and test of portable tanks from Sec. 180.605(d), as presented in the NPRM, to the more appropriate location Sec. 178.274(j). Sections 178.274 and 178.275. One commenter stated that although the term ``fusible elements'' is used in the UN Recommendations, the purpose of the devices and whether they are mandatory service equipment is unclear. The commenter stated that in the final rule it would be helpful to clarify the definition and use of these devices. We agree with the commenter and are adding a definition for ``fusible elements'' in Sec. 178.274(a)(3) and are clarifying the use of ``fusible elements'' in Sec. 178.275(f)(4). A commenter requested that we allow UN portable tanks used for th#
Passage 60e transportation of refrigerated liquefied gases to be tested using an inert gas as an alternative to hydrostatic testing with water. The commenter explained that this is a common industry practice and is necessary because the saddle designs for these portable tanks are not designed to hold the associated weight of the water necessary to conduct the#
Passage 61hydrostatic test. The commenter further explained that the alternative method is necessary because it is difficult to entirely remove all of the water in the inner tank after the hydrostatic test is completed. In addition, the UN Recommendations authorize the pressure test using an inert gas. We accept this comment and are amending Sec. 178.274(j)(2) to include a provision to allow, as an alternative to hydrostatic testing with water, testing with an inert gas for portable tanks used for the transportation of refrigerated liquefied gases. Section 178.275. Regarding paragraph (c), a commenter stated that damage to the liner in a portable tank would be inevitable when welding a blind (blank) flange on the inside and outside of the portable tank shell. The commenter suggested a tamper proof flange as an alternative to the welded flange as proposed in the NPRM. The UN portable tank working group considered a number of alternate configurations or possibilities for closing bottom openings in portable tanks when they are retrofitted to remove bottom opening configurations. The working group was opposed to use of a bolted flange because of the possibility that it may leak during transportation. While inclusion of an alternative to welding is beyond the scope of this rule, a means of authorizing non-welded bottom flange configurations may be considered under the alternative arrangement approval provisions. Another commenter stated that the presence of a liner in a portable tank should not be justification for authorizing the portable tank to be used without an internal shut-off valve. The commenter stated that internal shut-off valves can be fitted on lined portable tanks and that the proposed exception would result in a decrease in safety. We agree and based on the merits of the comment, we believe that a lined tank should have a internal shut-off and are removing the proposed exception in paragraph (c)(4) which states, ``For a lined shell, the internal stop valve required by paragraph (c)(3)(i) of this section may be replaced by an additional external stop valve.'' One commenter stated that the external design pressure should not be based on the internal pressure because, as proposed, the requirement would impose unrealistic external design pressure requirements. We agree with this commenter and are revising the wording in paragraph (e) to remove the reference to t#
Passage 62he internal pressure. On this basis, a shell that is to be equipped with a vacuum-relief device must be designed to withstand, without permanent deformation, an external pressure of not less than 0.21 bar. Section 178.276. See discussion under Sec. 178.274 for discussion concerning the relocation of certain text. We received a comment stating that Sec. 178.276 should be revised to provide an exception from the internal stop valve requirement for portable tanks used for the transportation of chlorine. The commenter requested alternative wording to clarify whether a threaded cap or pipe plug can be used as the third means of closure on portable tank openings. We agree and are revising the text in Sec. 178.276(c)(1) to state ``* * * and the third being a blank flange, threaded cap, plug or equivalent liquid tight closure device.'' We are also revising Sec. 178.276(c)(3) to indicate that this paragraph only applies to openings below the liquid level of the portable tank. This wording will eliminate the need for portable tanks used to transport chlorine from having to be fitted with internal stop valves because these portable tanks have loading and unloading fittings only at the top of the tank. We are also including a new paragraph (7) to address inlets and discharge outlets, internal excess flow valves on portable tanks used to transport chlorine. Section 178.277. One commenter stated that the NPRM preamble included a new filling limit for helium, yet it was not contained in the regulatory text in Sec. 178.277. We recognized the oversight and added a new tank provision, TP5 to address the filling limit. (See Sec. 172.102, Special Provisions.) Another commenter stated that it is not necessary to specify impact test requirements in paragraph Sec. 178.277(b)(4) and that the proposed provision for conducting impact tests at 0 deg.F on materials to be used for refrigerated liquefied gases are not suitable because such portable tanks operate at much lower temperatures. The commenter went on to say that the ASME Code adequately addresses this issue. We agree with the commenter and have removed the proposed provision. Another commenter stated that we overlooked the fact that the UN Recommendations do not require portable tanks used for the transportation of refrigerated liquefied gases to have an opening for inspection. The commenter stated that the internal inspection#
Passage 63requirements for these portable tanks should be removed because: (1) The portable tanks are not currently fitted with inspection openings, (2) internal corrosion is not a factor for portable tanks used to transport refrigerated liquefied gases, (3) the UN Recommendations do not require internal inspection for these portable tanks, and (4) fitting of inspection openings on these portable tanks does not enhance safety. We agree with the commenter and are including the exceptions for refrigerated liquefied gas portable tanks in paragraphs (d)(7) and Sec. 180.605(e) and (f). We are including the above discussed amendments and, as proposed in the NPRM, we are adding five new sections (Secs. 178.273 through 178.277) to the HMR as follows: Sec. 178.273 is added by moving the current requirements for the approval of Specification portable tanks from Sec. 173.32a and introducing similar requirements for UN portable tanks; Sec. 178.274 is added for the UN portable tank general design and construction requirements; Sec. 178.275 is added for the additional specifications for UN portable tanks intended for the transportation of liquid and solid materials of Classes 3 through 9; Sec. 178.276 is added for the additional requirements for UN portable tanks intended for the transportation of liquefied compressed gases; and Sec. 178.277 is added for the additional requirements for the design, construction, inspection and testing of UN portable tanks intended for the transport of refrigerated liquefied gases. Section 178.703. Consistent with Sec. 178.3(a)(4), paragraph (a)(1) is revised by including a minimum height of 12 mm (0.5 inches) for IBC markings and by adding a requirement to allow use of the ``W'' mark for approval of equivalent IBC packagings, as provided for in Sec. 178.801(i). Two commenters stated that while they support a minimum marking size of 12 mm for IBCs, it is not clear how this would apply to IBCs manufactured prior to the effective date of this final rule. In response to these commenters, we revised paragraph (a)(1) to clarify that the minimum marking size only applies to IBCs manufactured after the effective date of this final rule (October 1, 2001). Section 178.705. We are revising the minimum wall thickness requirements to take into account the capacity in the case of metal IBCs. Section 178.801. In paragraph (i), we are adding an approval provision#
Passage 64for the use of large packagings, as defined in Sec. 171.8 of this NPRM, provided the large packagings conform to the construction standards, performance testing and packaging marking as specified in UN Recommendations. Section 178.812. Based on our initiative, we are revising paragraph (c)(1) and adding a new paragraph (c)(3) to include an alternate method for conducting the top lift test for flexible IBCs. Prior to this final rule, the alternate method was authorized in several approvals issued by the Associate Administrator. Section 179.102-4. Consistent with the proper shipping name revisions that replace the word ``inhibited'' with ``stabilized'' (see Sec. 172.101), we are revising one such proper shipping name in this section.#
Passage 65Sections 180.601, 180.603, 180.605. We are moving the qualification and maintenance requirements for portable tanks from Sec. 173.32(c) to part 180. As discussed in the NPRM, we believe that these requirements are more appropriately placed in part 180 along with the qualification and maintenance requirements for cargo tanks, IBCs and tank cars. Therefore, as proposed, we are adding new subpart G to part 180 for the qualification and maintenance of portable tanks. (Also see Sec. 173.32.) One commenter suggested that we incorporate certain editorial changes to Sec. 173.32 and part 180, subpart G, to clarify that not all portable tanks have a maximum allowable working pressure (MAWP) and that some requirements do not apply to all portable tanks, such as DOT Specification 56 and 57 portable tanks. We agree and have made the clarification revisions accordingly. Section 180.603. A commenter requested that grandfather provisions be included in Sec. 180.603 to recognize that portable tanks constructed and used in accordance with existing DOT exemptions are authorized for continued use provided they meet the applicable periodic inspection and test requirements. We do not agree with this request because such exemptions remain valid and their continued use are not affected by this final rule. Section 180.605. Several commenters stated that the periodic inspection requirements for portable tanks proposed in the NPRM are not entirely consistent with those specified in the UN Recommendations. They quoted the UN Recommendations as stating: ``A portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection.'' In addition, a portable tank may be transported after the date of expiry of the last periodic test and inspection after emptying but before cleaning, for purposes of performing the next required test or inspection prior to refilling and unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this exemption shall be mentioned in the transport document. The commenters requested that we adopt this text from the UN Recommendation#
Passage 66s in the final rule. We do not agree that the UN Recommendations' text should be included in the HMR. We believe that the UN text imposes arbitrary limits on the length of time that a portable tank may be transported after expiration of the inspection and test date. The HMR text allows a portable tank to continue to be transported after the expiration of the test date while prohibiting filling of a tank once the periodic inspection and test dates have expired. We wish to clarify that the text as proposed was based on existing text for cargo tanks (see 173.33(a)(3)) and for portable tanks (see 173.32(e)(5)). The text in place prior to this final rule, as well as the text adopted in this final rule, allows portable tanks which contain a residue, or are being transported to a cleaning, testing or repair facility, to be transported after the inspection and test date expires. In the NPRM, we simply consolidated this requirement in a more appropriate section and applied it universally to all portable tanks. We are adopting the text as proposed, even though it is less restrictive than the UN Recommendations text, because it is practical and does not impose unnecessary burdens on the regulated public or government. On this basis, we are not adopting the suggestions of the commenters. We also wish to note that the text in Sec. 180.605(b)(3), as proposed and adopted, requires a portable tank that has been out of service for more than one year to be periodically retested. Several commenters stated that they support our efforts to adopt the UN portable tank requirements. The commenters support the requirement that DOT 51 Specification portable tanks not be allowed to be manufactured after January 1, 2003, however, they do not support the conditions for continued use of existing DOT 51 portable tanks as proposed in the NPRM. We did not introduce new requirements for periodically retesting DOT Specification 51 portable tanks in the NPRM nor was it our intention to do so. The retest provisions for DOT Specification 51 portable tanks are specified in Sec. 180.605(c)(2) and requires that the portable tanks be retested at least once every 5 years. For paragraphs (e) and (f), see Sec. 178.277(d)(7) discussion regarding an exception from the requirement for portable tanks used for the transportation of refrigerated liquefied gases to have an opening for inspection. We moved the#
Passage 67initial inspection and test requirements from Sec. 180.605(d), as proposed in the NPRM, to Sec. 178.274(j) which we believe is a more appropriate location. For a comment on an alternative to hydrostatic testing with water, see Sec. 178.274(j). We also received a comment stating that we should have included an exception from the requirement for UN portable tanks intended for the transportation of ``Helium refrigerated liquid (cryogenic liquid),'' UN1963 and ``Hydrogen, refrigerated liquid (cryogenic liquid),'' UN1966 to be subjected to the 4 G rail impact test as prescribed in Sec. 180.605(d)(6). The commenter reasoned that high thermal performance liquid hydrogen and helium containers are not transported on railroads due to the large impact loads experienced during coupling and that such UN portable tanks are marked with the words ``NOT FOR RAIL TRANSPORTATION.'' We agree with the commenter. When the requirements for UN portable tanks were developed, the UN working group agreed that portable tanks used for the transportation of refrigerated liquefied helium and hydrogen should be excepted from rail impact testing. A special provision was added allowing the transportation of these refrigerated liquefied gases under conditions specified by the competent authority. In this final rule, we are excepting portable tanks intended for the transport of refrigerated liquefied helium and hydrogen from the requirements of a rail impact test. Instead of requiring an approval provision, we are adding a sentence to Sec. 180.605(d)(6) to except portable tanks from the 4 G impact test when the portable tanks are used in dedicated service for the transportation of ``Helium, refrigerated liquid,'' UN1963 and ``Hydrogen, refrigerated liquid,'' UN1966 and are marked ``NOT FOR RAIL TRANSPORT'' in letters of a minimum height of 20 cm (8 inches) on at least two sides of the portable tank. Another commenter stated that the proposed marking size amendment in Sec. 180.605(l) requires inspection and test markings that are not included on the specification plate of a portable tank to be 32 mm (1.25 inches) high, yet as the commenter points out, currently Sec. 173.32(e)(3) allows markings for DOT Specifications 51, 56, 57 and 60 portable tanks to be a minimum height of 12 mm. We agree with the commenter and after considering the proposed amendment, we do not believe that a marking height#
Passage 68of 32 mm is necessary for these particular portable tanks. Therefore, we are adopting a minimum test and inspection marking height of 3 mm when the markings are on the specification plate, and a marking height of 12 mm when the markings are directly on the portable tank. A. Executive Order 12866 and DOT Regulatory Policies and Procedures This final rule is not considered a significant regulatory action under section 3(f) of Executive Order 12866 and, therefore, was not reviewed by the Office of Management and Budget. This final rule is not considered a significant rule under the Regulatory Policies and Procedures of the Department of Transportation (44 FR 11034). Benefits resulting from this final rule include enhanced transportation safety resulting from the consistency of domestic and international hazard communications and continued access to foreign markets by domestic shippers of hazardous materials. Many companies involved in domestic, as well as global operations, will realize economic benefits as a result of the amendments in this rulemaking. The total net increase in costs to businesses in implementing this rulemaking is minimal and we have determined that the intended benefits of harmonizing the HMR with international standards outweigh the minimal increase in costs to industry. For interested parties, a regulatory analysis is available for review in the public docket.#
Passage 69This final rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13132 (``Federalism''). This final rule preempts State, local and Indian tribe requirements but does not adopt any regulation that has substantial direct effects on the States, the relationship between the national government and the States, or the distribution of power and responsibilities among the various levels of government. Therefore, the consultation and funding requirements of Executive Order 13132 do not apply. The Federal hazardous material transportation law, 49 U.S.C. 5101- 5127, contains an express preemption provision (49 U.S.C. 5125(b)) that preempts State, local, and Indian tribe requirements on certain covered subjects. Covered subjects are: (1) The designation, description, and classification of hazardous materials; (2) The packing, repacking, handling, labeling, marking, and placarding of hazardous materials; (3) The preparation, execution, and use of shipping documents related to hazardous materials and requirements related to the number, contents, and placement of those documents; (4) The written notification, recording, and reporting of the unintentional release in transportation of hazardous; or (5) The design, manufacture, fabrication, marking, maintenance, recondition, repair, or testing of a packaging or container represented, marked, certified, or sold as qualified for use in transporting hazardous material. This final rule addresses covered subject items (1), (2), (3), and (5) above and would preempt State, local, and Indian tribe requirements not meeting the ``substantively the same'' standard. This final rule is necessary to incorporate changes already adopted in international standards. If the changes in this final rule are not adopted in the HMR, U.S. companies, including numerous small entities competing in foreign markets, would be at an economic disadvantage. These companies would be forced to comply with a dual system of regulation. The changes in this final rule are intended to avoid this result. Federal hazardous materials transportation law provides at section 5125(b)(2) that, if DOT issues a regulation concerning any of the covered subjects, DOT must determine and publish in the Federal Register the effective date of Federal preemption. The effective date may not be earlier than the 90th day following the date#
Passage 70of issuance of the final rule and not later than two years after the date of issuance. Thus, RSPA lacks discretion in this area. The effective date of Federal preemption will be December 18, 2001. This final rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13084 (``Consultation and Coordination with Indian Tribal Governments''). Because this final rule does not significantly or uniquely affect the communities of the Indian tribal governments and does not impose substantial direct compliance costs, the funding and consultation requirements of Executive Order 13084 do not apply.#
Passage 71The Regulatory Flexibility Act (5 U.S.C. 601 et seq.) requires an agency to review regulations to assess their impact on small entities, unless the agency determines that a rule is not expected to have a significant impact on a substantial number of small entities. This final rule will serve to facilitate the transportation of hazardous materials in international commerce by providing consistency with international standards. This final rule applies to offerors and carriers of hazardous materials, some of whom are small entities, such as, chemical manufacturers, chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, radiopharmaceutical companies and training companies. Based on our assessment in the regulatory analysis, which is available in the public docket, I hereby certify that this final rule will not have a significant economic impact on a substantial number of small entities. The majority of amendments in this final rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America. For example, cost savings will be realized by shippers and carriers as a result of eliminating the differences between primary and subsidiary labels. As a result of this change, it will no longer be necessary to stock two sets of labels for each hazard class. To ease any burden associated with this change, we are incorporating a reasonable transition period where labels meeting requirements in effect immediately prior to this final rule and the requirements adopted in this final rule may be used. Other cost savings include providing greater flexibility for the use of IBCs and portable tanks; retaining current IM 101, 102 and DOT Specification 51 portable tank requirements and providing authorizations for their use; deleting numerous entries from the marine pollutant list for consistency with the IMDG Code; authorizing greater flexibility for transporting samples of hazardous materials; authorizing the use of a single explosives placard when explosives of several compatibility groups are transported in a single freight container or vehicle; and revising requirements for large lithium batteries which will simplify the regulatory requirements applicable to batteries used in high energy efficient hybrid vehicles. Fina#
Passage 72lly, we are authorizing immediate voluntary compliance, delayed effective dates and a one-year transition period to allow for training of employees and to ease any burden on entities affected by the amendments.#
Passage 73We have current information collection approvals under OMB No. 2137-0018, Inspection and Testing of Portable Tanks and Intermediate Bulk Containers, which expires March 31, 2002, with 51,340 burden hours and $10,235,000 annual costs, and OMB No. 2137-0557, Approvals for Hazardous Materials, which expires March 31, 2002, with 18,302 burden hours and $413,737.40 annual costs. We believe that this final rule may result in minor incremental increases in the annual burden hours and costs. The current approvals has been revised and resubmitted to OMB for extension and reapproval. OMB No. 2137-0018 contains the information collection and recordkeeping requirements in current Secs. 173.32, 173.32a, 173.32b, 178.245 and 178.801 for tests, inspections and related records related to the manufacture, qualification, repair or modification of portable tanks or intermediate bulk containers. This information is used to verify that portable tanks and intermediate bulk containers meet the required manufacturing standards prior to being authorized for initial use, and that once manufactured, the packagings are maintenance in conformance with the applicable HMR requirements. OMB No. 2137-0018 is revised to include UN portable tanks and to revise section references to the portable tank requalification requirements which are being relocated to subpart G in Part 180. OMB No. 2137-0557 contains the information collection and recordkeeping requirements for packagings and hazardous materials approvals. This information is used to verify that portable tank designs meet the applicable standards. OMB No. 2137-0557 is revised to include UN portable tanks and to revise the section references to the portable tank design approval requirements which are being relocated to Part 178. We estimate that the adjusted total information collection and recordkeeping burdens are as follows: OMB No. 2137-0018: Affected Public: Manufacturers, requalifiers, repairers and modifiers, and owners of certain DOT specification and exemption portable tanks and intermediate bulk containers. Number of Respondents: 8,770. Total Annual Responses: 86,100. Total Annual Burden Hours: 66,390. Total Annual Burden Cost: $ 7,137,500. One-time Annual Start Up Burden Hours: 350.#
Passage 74OMB No. 2137-0557: Number of Respondents: 3,518. Total Annual Responses: 3,869. Total Annual Burden Hours: 18,381. Total Annual Burden Cost: $ 413,737.40. Requests for a copy of the information collection approvals, requests and data should be directed to Deborah Boothe, Office of Hazardous Materials Standards (DHM-10), Research and Special Programs Administration, Room 8102, 400 Seventh Street, SW, Washington, DC 20590-0001, Telephone (202) 366-8553. A regulation identifier number (RIN) is assigned to each regulatory action listed in the Unified Agenda of Federal Regulations. The Regulatory Information Service Center publishes the Unified Agenda in April and October of each year. The RIN number contained in the heading of this document can be used to cross-reference this action with the Unified Agenda. This final rule does not impose unfunded mandates under the Unfunded Mandates Reform Act of 1995. It does not result in costs of $100 million or more to either State, local or tribal governments, in the aggregate, or to the private sector, and is the least burdensome alternative that achieves the objective of the rule. The National Environmental Policy Act of 1969 (NEPA) requires Federal agencies to consider the consequences of major federal actions and prepare a detailed statement on actions significantly affecting the quality of the human environment. We developed an assessment to determine the effects of these revisions on the environment and whether a more comprehensive environmental impact statement may be required. Our findings conclude that there are no significant environmental impacts associated with this final rule. Consistency in regulations for the transportation of hazardous materials aids in the shipper's understanding of what is required and permits shippers to more easily comply with safety regulations and avoid the potential for environmental damage or contamination. For interested parties, an environmental assessment is available in the public docket. Exports, Hazardous materials transportation, Hazardous waste, Imports, Incorporation by reference, Reporting and recordkeeping requirements. Education, Hazardous materials transportation, Hazardous waste, Labeling, Markings, Packaging and containers, Reporting and recordkeeping requirements.#
Passage 75Hazardous materials transportation, Packaging and containers, Radioactive materials, Reporting and recordkeeping requirements, Uranium. Air carriers, Hazardous materials transportation, Radioactive materials, Reporting and recordkeeping requirements. Hazardous materials transportation, Maritime carriers, Radioactive materials, Reporting and recordkeeping requirements. Hazardous materials transportation, Motor carriers, Radioactive materials, Reporting and recordkeeping requirements. Hazardous materials transportation, Motor vehicle safety, Packaging and containers, Reporting and recordkeeping requirements. Hazardous materials transportation, Railroad safety, Reporting and recordkeeping requirements. Hazardous materials transportation, Motor carriers, Motor vehicle safety, Packaging and containers, Railroad safety, Reporting and recordkeeping requirements. In consideration of the foregoing, 49 CFR Chapter I is amended as follows: PART 171--GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS 1. The authority citation for part 171 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 2. In Sec. 171.7, in paragraph (a)(1), the fourth sentence is revised and in the paragraph (a)(3) table: a. Under the entry ``American Society for Testing and Materials'', a new entry is added in alpha-numeric order; b. Under the entry ``International Atomic Energy Agency (IAEA)'', a new entry is added in alpha-numeric order; c. Under the entry ``International Civil Aviation Organization (ICAO)'', the existing entry is revised; d. Under the entry ``International Maritime Organization (IMO)'', for the entry ``International Maritime Dangerous Goods (IMDG) Code, 2000 edition'', in the second column, add ``; 176.720'' after ``176.30''; and e. Under the entry ``International Organization for Standardization'', three new entries are added in alpha-numeric order. The revisions and additions read as follows: (a) Matter incorporated by reference-- (1) * * * The material listed in paragraph (a)(3) has been approved for incorporation by reference by the Director of the Federal Register in accordance with 5 U.S.C 552(a) and 1 CFR part 51. * * * * * * * * (3) Table of material incorporated by reference. * * *#
Passage 76------------------------------------------------------------------------ Source and name of material 49 CFR reference ------------------------------------------------------------------------ * * * * * * * American Society for Testing and Materials * * * * * * * ASTM E 112-96 Standard Test Methods for 178.274 Determining Average Grain Size, 1996 Edition. * * * * * * * International Atomic Energy Agency (IAEA) * * * * * * * IAEA, Regulations for the Safe Transport of 171.12 Radioactive Material, No. TS-R-1, 1996 Edition. * * * * * * * International Civil Aviation Organization (ICAO) * * * * * * * Technical Instructions for the Safe 171.11; 172.202; 172.401; Transport of Dangerous Goods by Air (ICAO 172.512; 172.602 Technical Instructions), DOC 9284-AN/905, 2001-2002 Edition. * * * * * * * International Organization for Standardization * * * * * * * ISO 1496-3 Series 1 freight containers-- 178.274 Specification and testing, Part 3: Tank containers for liquids, gases and pressurized dry bulk, March 1, 1995, Fourth Edition. * * * * * * * ISO 4126-1 Safety valves--Part 1: General Requirements, December 15, 178.274 1991, First Edition. * * * * * * * ISO 6892 Metallic materials--Tensile 178.274 testing, July 15, 1984, First Edition. * * * * * * * ------------------------------------------------------------------------ 3. In Sec. 171.8, the following definitions are added in appropriate alphabetical order to read as follows: Sec. 171.8 Definitions and abbreviations.#
Passage 77* * * * * Large packaging means a packaging that-- (1) Consists of an outer packaging which contains articles or inner packagings; (2) Is designated for mechanical handling; (3) Exceeds 400 kg net mass or 450 liters (118.9 gallons) capacity; (4) Has a volume of not more than 3 m\3\ (see Sec. 178.801(i) of this subchapter); and (5) Conforms to the requirements for the construction, testing and marking of large packagings as specified in the UN Recommendations. * * * * * Stabilized means that the hazardous material is in a condition that precludes uncontrolled reaction. This may be achieved by methods such as adding an inhibiting chemical, degassing the hazardous material to remove dissolved oxygen and inerting the air space in the package, or maintaining the hazardous material under temperature control. * * * * * UN portable tank means a intermodal tank having a capacity of more than 450 liters (118.9 gallons). It includes a shell fitted with service equipment and structural equipment, including stabilizing members external to the shell and skids, mountings or accessories to facilitate mechanical handling. A UN portable tank must be capable of being filled and discharged without the removal of its structural equipment and must be capable of being lifted when full. Cargo tanks, rail tank car tanks, non-metallic tanks, non-specification tanks, bulk bins, and IBCs and packagings made to cylinder specifications are not UN portable tanks. * * * * * 4. In Sec. 171.10, in paragraph (c)(2), the Table of Conversion Factors for SI Units, a unit of measure is added as the last entry, and in the abbreviation notes following the Table, in the (SI) abbreviations, a new abbreviation ``; Newton, N'' is added after ``mSv'' to read as follows: Table of Conversion Factors for SI Units ---------------------------------------------------------------------------------------------------------------- Measurement SI to U.S. standard U.S. standard to SI ---------------------------------------------------------------------------------------------------------------- * * * * * * * Force................................. 1 Newton = 0.2248 Pound-force 1 Pound-force=4.483 N ----------------------------------------------------------------------------------------------------------------#
Passage 785. In Sec. 171.11, the introductory text is revised, the comma at the end of paragraphs (d)(6)(i) and (d)(6)(ii) are removed and a period is added in its place, '', and'' at the end of paragraph (d)(6)(iv) is removed and a period is added in their place, and new paragraphs (d)(6)(vi) and (d)(17) are added to read as follows: Sec. 171.11 Use of ICAO Technical Instructions. Notwithstanding the requirements of parts 172 and 173 of this subchapter, a hazardous material may be transported by aircraft, and by motor vehicle either before or after being transported by aircraft, in accordance with the ICAO Technical Instructions (see Sec. 171.7) if the hazardous material; * * * * * (d) * * * (6) * * * (vi) The definition for ``radioactive material'' in Sec. 173.403 of this subchapter applies to radioactive materials transported under the provisions of this section. * * * * * (17) An organic peroxide that is not identified by technical name in the Organic Peroxide Table in Sec. 173.225(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. 6. In Sec. 171.12, paragraph (b)(5) is revised, new paragraph (b)(20) is added, paragraphs (d) heading and introductory text and (d)(4) are revised, ``and'' at the end of paragraph (d)(5) is removed, the period at the end of paragraph (d)(6) is removed and ``; and'' is added in its place, and paragraph (d)(7) is added to read as follows: Sec. 171.12 Import and export shipments.#
Passage 79* * * * * (b) * * * (5) Except for IBCs and UN portable tanks intended for liquids or solids, hazardous materials that conform to the requirements of the IMDG Code, bulk packagings must conform to the requirements of this subchapter. For UN portable tanks, Special Provisions TP37, TP38, TP44 and TP45 must be met when applicable. Except as specified in paragraph (b)(8) of this section for a material poisonous (toxic) by inhalation (see Sec. 171.8 of this subchapter), the T Codes specified for specific hazardous materials in Column 13 of the Dangerous Goods List of the IMDG Code may be applied to the transportation of those materials in IM, IMO and DOT Specification 51 portable tanks. * * * * * (20) An organic peroxide that is not identified by technical name in the Organic Peroxide Table in Sec. 173.225(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. * * * * * (d) Use of International Atomic Energy Agency (IAEA) regulations for Class 7 (radioactive) materials. Class 7 (radioactive) materials being imported into or exported from the United States, or passing through the United States in the course of being shipped between places outside the United States, may be offered and accepted for transportation when packaged, marked, labeled, and otherwise prepared for shipment in accordance with IAEA ``Regulations for the Safe Transport of Radioactive Material,'' Safety Series No. 6, 1985 edition, or TS-R-1, 1996 edition (see Sec. 171.7) , if-- * * * * * (4) The country of origin for the shipment has adopted the corresponding edition (Safety Series No. 6, 1985 Edition, or TS-R-1, 1996 Edition) of the IAEA ``Regulations for the Safe Transport of Radioactive Material'; * * * * * (7) The definition for ``radioactive material'' in Sec. 173.403 of this subchapter is applied to radioactive materials transported under the provisions of this section. 7. In Sec. 171.12a, a new paragraph (b)(18) is added to read as follows: Sec. 171.12a Canadian shipments and packagings. * * * * * (b) * * * (18) An organic peroxide that is not identified by technical name in the Organic Peroxide Table in Sec. 173.225(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter.#
Passage 808. In Sec. 171.14, paragraphs (d) introductory text, (d)(1) and (d)(2) introductory text are revised and new paragraphs (d)(4) and (d)(5) are added to read as follows: Sec. 171.14 Transitional provisions for implementing certain requirements. * * * * * (d) A final rule published in the Federal Register on June 21, 2001, effective October 1, 2001, resulted in revisions to this subchapter. During the transition period, until October 1, 2002, as provided in paragraph (d)(1) of this section, a person may elect to comply with either the applicable requirements of this subchapter in effect on September 30, 2001, or the requirements published in the June 21, 2001 final rule. (1) Transition dates. The effective date of the June 21, 2001 final rule is October 1, 2001. A delayed compliance date of October 1, 2002 is authorized. On October 1, 2002, all applicable regulatory requirements adopted in the June 21, 2001 final rule in effect on October 1, 2001 must be met. (2) Intermixing old and new requirements. Prior to October 1, 2002, it is recommended that the hazard communication requirements be consistent where practicable. Marking, labeling, placarding, and shipping paper descriptions should conform to either the old requirements of this subchapter in effect on September 30, 2001, or the new requirements of this subchapter in the June 21, 2001 final rule without intermixing communication elements. However, intermixing is permitted, during the applicable transition period, for packaging, hazard communication, and handling provisions, as follows: * * * * * (4) Until January 1, 2010, a hazardous material may be transported in an IM or IMO portable tank in accordance with the T Codes (Special Provisions) assigned to a hazardous material in Column (7) of the HMT in effect on September 30, 2001. (5) Until October 1, 2005, proper shipping names that included the word ``inhibited'' prior to the June 21, 2001 final rule in effect on October 1, 2001, may continue to be shown on packagings in place of ``stabilized.'' PART 172--HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS,HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION,AND TRAINING REQUIREMENTS 9. The authority citation for part 172 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.#
Passage 8110-11. In Sec. 172.101, paragraphs (b)(1) and (c)(11) are revised, new paragraphs (c)(16) and (k)(6) through (k)(20) are added, and the Hazardous Materials Table is revised to read as follows: Sec. 172.101 Purpose and use of hazardous materials table.#
Passage 82* * * * * (b) * * * (1) The plus (+) sign fixes the proper shipping name, hazard class and packing group for that entry without regard to whether the material meets the definition of that class, packing group or any other hazard class definition. When the plus sign is assigned to a proper shipping name in Column (1) of the Sec. 172.101 Table, it means that the material is known to pose a risk to humans. When a plus sign is assigned to mixtures or solutions containing a material where the hazard to humans is significantly different from that of the pure material or where no hazard to humans is posed, the material may be described using an alternative shipping name that represents the hazards posed by the material. An appropriate alternate proper shipping name and hazard class may be authorized by the Associate Administrator. * * * * * (c) * * * (11) Except for a material subject to or prohibited by Secs. 173.21, 173.54, 173.56(d), 173.56(e), 173.224(c) or 173.225(c) of this subchapter, a material that is considered to be a hazardous waste or a sample of a material for which the hazard class is uncertain and must be determined by testing may be assigned a tentative proper shipping name, hazard class, identification number and packing group, if applicable, based on the shipper's tentative determination according to: (i) Defining criteria in this subchapter; (ii) The hazard precedence prescribed in Sec. 173.2a of this subchapter; (iii) The shippers knowledge of the material; (iv) In addition to paragraphs (c)(11)(i) through (iii) of this section, for a sample of a material, other than a waste, the following must be met: (A) Except when the word ``Sample'' already appears in the proper shipping name, the word ``Sample'' must appear in association with the basic description of a sample on the shipping paper; (B) When the proper shipping description for a sample is assigned a ``G'' in Column (1) of the Sec. 172.101 Table, and the primary constituent(s) for which the tentative classification is based are not known, the provisions requiring a technical name for the constituent(s) do not apply; and (C) A sample must be transported in a combination packaging which conforms to the requirements of this subchapter that are applicable to the tentative packing group assigned, and may not exceed a net mass of 2.5 kg. (5.5 pounds) per package.#
Passage 83Note to Paragraph (c)(11): For the transportation of self- reactive, organic peroxide and explosive samples, see Secs. 173.224(c)(3), 173.225(c)(2) and 173.56(d) of this subchapter, respectively.#
Passage 84* * * * * (16) Unless it is already included in the proper shipping name in the Sec. 172.101 Table, the qualifying words ``liquid'' or ``solid'' may be added in association with the proper shipping name when a hazardous material specifically listed by name in the Sec. 172.101 Table may, due to the differing physical states of the various isomers of the material, be either a liquid or a solid (for example ``Dinitrotoluenes, liquid'' and ``Dinitrotoluenes, solid''). Use of the words ``liquid'' or ``solid'' is subject to the limitations specified for the use of the words ``mixture'' or ``solution'' in paragraph (c)(10) of this section. The qualifying word ``molten'' may be added in association with the proper shipping name when a hazardous material, which is a solid in accordance with the definition in Sec. 171.8 of this subchapter, is offered for transportation in the molten state (for example, ``Alkylphenols, solid, n.o.s., molten''). * * * * * (k) * * * (6) Stowage category ``01'' means the material may be stowed ``on deck'' or ``under deck'' on a cargo vessel (up to 12 passengers) and on a passenger vessel. (7) Stowage category ``02'' means the material may be stowed ``on deck'' or ``under deck'' on a cargo vessel (up to 12 passengers) and ``on deck'' in closed cargo transport units or ``under deck'' in closed cargo transport units on a passenger vessel. (8) Stowage category ``03'' means the material may be stowed ``on deck'' or ``under deck'' on a cargo vessel (up to 12 passengers) and ``on deck'' in closed cargo transport units on a passenger vessel. (9) Stowage category ``04'' means the material may be stowed ``on deck'' or ``under deck'' on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel. (10) Stowage category ``05'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' on a cargo vessel (up to 12 passengers) and on a passenger vessel. (11) Stowage category ``06'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' on a cargo vessel (up to 12 passengers) and ``on deck'' in closed cargo transport units or ``under deck'' in closed cargo transport units on a passenger vessel. (12) Stowage category ``07'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' on a cargo vessel (up to 12 passeng#
Passage 85ers) and ``on deck'' only in closed cargo transport units on a passenger vessel. (13) Stowage category ``08'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel. (14) Stowage category ``09'' means the material may be stowed ``on deck only'' in closed cargo transport units or ``under deck'' in closed cargo transport units on a cargo vessel (up to 12 passengers) and on a passenger vessel. (15) Stowage category ``10'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' in closed cargo transport units on a cargo vessel (up to 12 passengers) and ``on deck'' only in closed cargo transport units on a passenger vessel. (16) Stowage category ``11'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' in magazine stowage type ``c'' on a cargo vessel (up to 12 passengers) and ``on deck'' only in closed cargo transport units on a passenger vessel. (17) Stowage category ``12'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' in magazine stowage type ``c'' on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel. (18) Stowage category ``13'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' in magazine stowage type ``A'' on a cargo vessel (up to 12 passengers) and ``on deck'' only in closed cargo transport units on a passenger vessel. (19) Stowage category ``14'' means the material may be stowed ``on deck'' in closed cargo transport units on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel. (20) Stowage category ``15'' means the material may be stowed ``on deck'' in closed cargo transport units or ``under deck'' in closed cargo transport units on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel. * * * * * BILLING CODE 4910-60-P#
Passage 86Sec. 172.101 Hazardous Materials Table ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ (8) Packaging (9) (10) Vessel Hazardous materials Hazard Special --------------(Sec. 173.***)-----------------Quantity limitations-----------stowage------ Symbols descriptions and class or Identification PG Label provisions (Sec. Passenger proper shipping Division Numbers Codes 172.102) Exceptions Non-bulk Bulk aircraft/ Cargo air- Location Other names rail craft only ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ (1) (2)................. (3) (4) (5) (6)....... (7) (8A).......... (8B)....... (8C)....... (9A) (9B) (10A) (10B) ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 87Accellerene, see p- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrosodimethylanil ine. Accumulators, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... electric, see Batteries, wet etc. Acetal.............. 3 UN1088 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Acetaldehyde........ 3 UN1089 I 3......... A3, B16, T11, None.......... 201........ 243........ Forbidden 30 L E ....... TP2, TP7 A Acetaldehyde ammonia 9 UN1841 III 9......... IB8, IP6 155........... 204........ 240........ 200 kg 200 kg A 34 Acetaldehyde oxime.. 3 UN2332 III 3......... B1, IB3, T4, TP1 150........... 203........ 242........ 60 L 220 L A ....... Acetic acid, glacial 8 UN2789 II 8, 3...... A3, A6, A7, A10, 154........... 202........ 243........ 1 L 30 L A ....... or Acetic acid B2, IB2, T7, TP2 solution, with more than 80 percent acid, by mass. Acetic acid 8 UN2790 II 8......... A3, A6, A7, A10, 154........... 202........ 242........ 1 L 30 L A ....... solution, not less B2, IB2, T7, TP2 than 50 percent but not more than 80 percent acid, by mass. Acetic acid 8 UN2790 III 8......... IB3, T4, TP1 154........... 203........ 242........ 5 L 60 L A ....... solution, with more than 10 percent and less than 50 percent acid, by mass. Acetic anhydride.... 8 UN1715 II 8, 3...... A3, A6, A7, A10, 154........... 202........ 243........ 1 L 30 L A 40 B2, IB2, T7, TP2 Acetone............. 3 UN1090 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Acetone cyanohydrin, 6.1 UN1541 I 6.1....... 2, A3, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 25, 40, stabilized. B32, B76, B77, 49 N34, T20, TP2, TP13, TP38, TP45 Acetone oils........ 3 UN1091 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... Acetonitrile........ 3 UN1648 II 3......... IB2, T7, TP2 150........... 202........ 242........ 5L 60 L B 40 Acetyl acetone Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxide with more than 9 percent by mass active oxygen. Acetyl benzoyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... .....#
Passage 88.. peroxide, solid, or with more than 40 percent in solution. Acetyl bromide...... 8 UN1716 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L C 40 TP12 Acetyl chloride..... 3 UN1717 II 3, 8...... A3, A6, A7, IB1, None.......... 202........ 243........ 1 L 5 L B 40 N34, T8, TP2, TP12 Acetyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent water. Acetyl iodide....... 8 UN1898 II 8......... B2, IB2, T7, TP2, 154........... 202........ 242........ 1 L 30 L C 40 TP13 Acetyl methyl 3 UN2621 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... carbinol. Acetyl peroxide, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, or with more than 25 percent in solution. Acetylene, dissolved 2.1 UN1001 ....... 2.1....... None.......... 303........ None....... Forbidden 15 kg D 25, 40, 57 Acetylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (liquefied). Acetylene silver Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrate. Acetylene ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... tetrabromide, see Tetrabromoethane. Acid butyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... phosphate, see Butyl acid phosphate. Acid, sludge, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Sludge acid. Acridine............ 6.1 UN2713 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Acrolein dimer, 3 UN2607 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A 40 stabilized. Acrolein, stabilized 6.1 UN1092 I 6.1, 3.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 B42, B72, B77, T22, TP2, TP7, TP13, TP38, TP44 Acrylamide.......... 6.1 UN2074 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg#
Passage 89A 12 Acrylic acid, 8 UN2218 II 8, 3...... B2, IB2, T7, TP2 154........... 202........ 243........ 1 L 30 L C 25, 40 stabilized. Acrylonitrile, 3 UN1093 I 3, 6.1.... B9, T14, TP2, None.......... 201........ 243........ Forbidden 30 L E 40 stabilized. TP13 Actuating cartridge, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... explosive, see Cartridges, power device. Adhesives, 3 UN1133 I 3......... B42, T11, TP1, 150........... 201........ 243........ 1 L 30 L B ....... containing a TP8, TP27 flammable liquid.#
Passage 90.................... ........... .................. II 3......... B52, IB2, T4, 150........... 173........ 242........ 5 L 60 L B ....... TP1, TP8 .................... ........... .................. III 3......... B1, B52, IB3, T2, 150........... 173........ 242........ 60 L 220 L A ....... TP1 Adiponitrile........ 6.1 UN2205 III 6.1....... IB3, T3, TP1 153........... 203........ 241........ 60 L 220 L A ....... Aerosols, corrosive, 2.2 UN1950 ....... 2.2, 8.... A34 306........... None....... None....... 75 kg 150 kg A 40, 48, Packing Group II or 85 III, (each not exceeding 1 L capacity). Aerosols, flammable, 2.1 UN1950 ....... 2.1....... N82 306........... None....... None....... 75 kg 150 kg A 40, 48, (each not exceeding 85 1 L capacity). Aerosols, flammable, 2.1 UN1950 ....... 2.1....... N82 306........... None....... None....... Forbidden 150 kg A 40, 48, n.o.s. (engine 85 starting fluid) (each not exceeding 1 L capacity). Aerosols, non- 2.2 UN1950 ....... 2.2....... 306, 307...... None....... None....... 75 kg 150 kg A 48, 85 flammable, (each not exceeding 1 L capacity). Aerosols, poison, 2.2 UN1950 ....... 2.2....... 306........... None....... None....... Forbidden Forbidden A 40, 48, each not exceeding 85 1 L capacity. Air bag inflators, 2.2 UN3353 ....... 2.2....... 133 166........... 166........ 166........ 75 kg 150 kg A ....... compressed gas or Air bag modules, compressed gas or Seat-belt pretensioners, compressed gas. Air bag inflators, 1.4G UN0503 II 1.4G...... 166........... 166........ 166........ Forbidden 75 kg 02 24E pyrotechnic or Air bag modules, pyrotechnic or Seat- belt pretensioner, pyrotechnic. Air bag inflators, 9 UN3268 III 9......... 166........... 166........ 166........ 25 kg 100 kg A ....... pyrotechnic or Air bag modules, pyrotechnic or Seat- belt pretensioner, pyrotechnic. Air, compressed..... 2.2 UN1002 ....... 2.2....... 78 306........... 302........ 302........ 75 kg 150 kg A ....... Air, refrigerated 2.2 UN1003 ....... 2.2, 5.1.. T75, TP5, TP22 320........... 316........ 318, 319... Forbidden 150 kg D 51 liquid, (cryogenic liquid). Air, refrigerated 2.2 UN1003 ....... 2.2, 5.1.. T75, TP5, TP22 320........... 316........ 318, 319... Forbidden Forbidden D 51 liquid, (cryogenic liquid) non- pressurized. Aircraft engines ........... .................. .......... ............. .......... .......... ........... ........... ....#
Passage 91....... ....... (including turbines), see Engines, internal combustion. Aircraft evacuation ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... slides, see Life saving appliances etc. Aircraft hydraulic 3 UN3165 I 3, 6.1, 8. None.......... 172........ None....... Forbidden 42 L E ....... power unit fuel tank (containing a mixture of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel). Aircraft survival ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... kits, see Life saving appliances etc. G Alcoholates 3 UN3274 II 3, 8...... IB2 None.......... 202........ 243........ 1 L 5 L B ....... solution, n.o.s., in alcohol. Alcoholic beverages. 3 UN3065 II 3......... 24, B1, IB2, T4, 150........... 202........ 242........ 5 L 60 L A ....... TP1 .................... ........... .................. III 3......... 24, B1, IB3, N11, 150........... 203........ 242........ 60 L 220 L A ....... T2, TP1 Alcohols, n.o.s..... 3 UN1987 I 3......... T11, TP1, TP8, None.......... 201........ 243........ 1 L 30 L E ....... TP27 .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 G Alcohols, flammable, 3 UN1986 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L E 40 toxic, n.o.s.. TP27 .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP27 .................... ........... .................. III 3, 6.1.... B1, IB3, T7, TP1, None.......... 203........ 242........ 60 L 220 L A ....... TP28 Aldehydes, n.o.s.... 3 UN1989 I 3......... T11, TP1, TP27 None.......... 201........ 243........ 1 L 30 L E ....... .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 G Aldehydes, 3 UN1988 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ For#
Passage 92bidden 30 L E 40 flammable, toxic, TP27 n.o.s.. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP27 .................... ........... .................. III 3, 6.1.... B1, IB3, T7, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP28 Aldol............... 6.1 UN2839 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 12 G Alkali metal 4.2 UN3206 II 4.2, 8.... 64, IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg B ....... alcoholates, self- heating, corrosive, n.o.s.. .................... ........... .................. III 4.2, 8.... 64, IB8, IP3 None.......... 213........ 242........ 25 kg 100 kg B ....... Alkali metal alloys, 4.3 UN1421 I 4.3....... A2, A3, B48, N34 None.......... 201........ 244........ Forbidden 1 L D ....... liquid, n.o.s.. Alkali metal 4.3 UN1389 I 4.3....... A2, A3, N34 None.......... 201........ 244........ Forbidden 1 L D 40 amalgam, liquid. Alkali metal 4.3 UN1389 I 4.3....... IB4, IP1, N40 None.......... 211........ 242........ Forbidden 15 kg D ....... amalgam, solid. Alkali metal amides. 4.3 UN1390 II 4.3....... A6, A7, A8, A19, 151........... 212........ 241........ 15 kg 50 kg E 40 A20, IB7, IP2 Alkali metal 4.3 UN1391 I 4.3....... A2, A3 None.......... 201........ 244........ Forbidden 1 L D ....... dispersions, or Alkaline earth metal dispersions.#
Passage 93Alkaline corrosive ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquids, n.o.s., see Caustic alkali liquids, n.o.s.. G Alkaline earth metal 4.2 UN3205 II 4.2....... 65, IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg B ....... alcoholates, n.o.s.. .................... ........... .................. III 4.2....... 65, IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg B ....... Alkaline earth metal 4.3 UN1393 II 4.3....... A19, IB7, IP2 151........... 212........ 241........ 15 kg 50 kg E ....... alloys, n.o.s.. Alkaline earth metal 4.3 UN1392 I 4.3....... A19, IB4, IP1, None.......... 211........ 242........ Forbidden 15 kg D ....... amalgams. N34, N40 G Alkaloids, liquid, 6.1 UN3140 I 6.1....... A4, T14, TP2, None.......... 201........ 243........ 1 L 30 L A ....... n.o.s., or Alkaloid TP27 salts, liquid, n.o.s.. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L A ....... TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A ....... TP28 G Alkaloids, solid, 6.1 UN1544 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A ....... n.o.s. or Alkaloid salts, solid, n.o.s. poisonous. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Alkyl sulfonic 8 UN2584 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L B ....... acids, liquid or TP12, TP13 Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid. Alkyl sulfonic 8 UN2586 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L B ....... acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid. Alkyl sulfonic 8 UN2583 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric acid. Alkyl sulfonic 8 UN2585 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... acids, so#
Passage 94lid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid. Alkylphenols, 8 UN3145 I 8......... T14, TP2 None.......... 201........ 243........ 0.5 L 2.5 L B ....... liquid, n.o.s. (including C2-C12 homologues). .................... ........... .................. II 8......... IB2, T11, TP2, 154........... 202........ 242........ 1 L 30 L B ....... TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A ....... TP28 Alkylphenols, solid, 8 UN2430 I 8......... IB7, IP1, T10, None.......... 211........ 242........ 1 kg 25 kg B ....... n.o.s. (including TP2, TP28 C2-C12 homologues). .................... ........... .................. II 8......... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg B ....... T3, TP2 .................... ........... .................. III 8......... IB8, IP3, T3, TP1 154........... 213........ 240........ 25 kg 100 kg A ....... Alkylsulfuric acids. 8 UN2571 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L C 14 TP12, TP13 Allethrin, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Pesticides, liquid, toxic, n.o.s.. Allyl acetate....... 3 UN2333 II 3, 6.1.... IB2, T7, TP1, None.......... 202........ 243........ 1 L 60 L E 40 TP13 Allyl alcohol....... 6.1 UN1098 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Allyl bromide....... 3 UN1099 I 3, 6.1.... T14, TP2, TP13 None.......... 201........ 243........ Forbidden 30 L B 40 Allyl chloride...... 3 UN1100 I 3, 6.1.... T14, TP2, TP13 None.......... 201........ 243........ Forbidden 30 L E 40 Allyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... chlorocarbonate, see Allyl chloroformate. Allyl chloroformate. 6.1 UN1722 I 6.1, 3, 8. 2, A3, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 40 B32, B74, N41, T20, TP2, TP13, TP38, TP45 Allyl ethyl ether... 3 UN2335 II 3, 6.1.... IB2, T7, TP1, None.......... 202........ 243........ 1 L 60 L E 40 TP13 Allyl formate....... 3 UN2336 I 3, 6.1.... T14, TP2, TP13 None.......... 201........ 243........ Forbidden 30 L E 40 Allyl glycidyl ether 3 UN2219 III#
Passage 953......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Allyl iodide........ 3 UN1723 II 3, 8...... A3, A6, IB1, N34, None.......... 202........ 243........ 1 L 5 L B 40 T7, TP2, TP13 Allyl 6.1 UN1545 II 6.1, 3.... A3, A7, IB2, T7, None.......... 202........ 243........ Forbidden 60 L D 40 isothiocyanate, TP2 stabilized. Allylamine.......... 6.1 UN2334 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 Allyltrichlorosilane 8 UN1724 II 8, 3...... A7, B2, B6, IB2, None.......... 202........ 243........ Forbidden 30 L C 40 , stabilized. N34, T7, TP2, TP13 Aluminum alkyl 4.2 UN3052 I 4.2, 4.3.. B9, B11, T21, None.......... 181........ 244........ Forbidden Forbidden D ....... halides. TP2, TP7 Aluminum alkyl 4.2 UN3076 I 4.2, 4.3.. B9, B11, T21, None.......... 181........ 244........ Forbidden Forbidden D ....... hydrides. TP2, TP7 Aluminum alkyls..... 4.2 UN3051 I 4.2, 4.3.. B9, B11, T21, None.......... 181........ 244........ Forbidden Forbidden D ....... TP2, TP7 Aluminum borohydride 4.2 UN2870 I 4.2, 4.3.. B11 None.......... 181........ 244........ Forbidden Forbidden D ....... or Aluminum borohydride in devices. Aluminum bromide, 8 UN1725 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A 40 anhydrous. Aluminum bromide, 8 UN2580 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... solution. Aluminum carbide.... 4.3 UN1394 II 4.3....... A20, IB7, IP2, 151........... 212........ 242........ 15 kg 50 kg A ....... N41#
Passage 96Aluminum chloride, 8 UN1726 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A 40 anhydrous. Aluminum chloride, 8 UN2581 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... solution. Aluminum dross, wet Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... or hot. Aluminum 4.3 UN1395 II 4.3, 6.1.. A19, IB5, IP2 151........... 212........ 242........ 15 kg 50 kg A 40, 85, ferrosilicon powder. 103 .................... ........... .................. III 4.3, 6.1.. A19, A20, IB4 151........... 213........ 241........ 25 kg 100 kg A 40, 85, 103 Aluminum hydride.... 4.3 UN2463 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... D Aluminum, molten.... 9 NA9260 III 9......... IB3, T1, TP3 None.......... None....... 247........ Forbidden Forbidden D ....... Aluminum nitrate.... 5.1 UN1438 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Aluminum phosphate ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Corrosive liquids, etc. Aluminum phosphide.. 4.3 UN1397 I 4.3, 6.1.. A8, A19, N40 None.......... 211........ 242........ Forbidden 15 kg E 40, 85 Aluminum phosphide 6.1 UN3048 I 6.1....... A8, IB7, IP1 None.......... 211........ 242........ Forbidden 15 kg E 40, 85 pesticides. Aluminum powder, 4.1 UN1309 II 4.1....... IB8, IP2, IP4 151........... 212........ 240........ 15 kg 50 kg A 13, 39, coated. 101 .................... ........... .................. III 4.1....... IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A 13, 39, 101 Aluminum powder, 4.3 UN1396 II 4.3....... A19, A20, IB7, 151........... 212........ 242........ 15 kg 50 kg A 39 uncoated. IP2 .................... ........... .................. III 4.3....... A19, A20, IB8, 151........... 213........ 241........ 25 kg 100 kg A 39 IP4 Aluminum resinate... 4.1 UN2715 III 4.1....... IB6 151........... 213........ 240........ 25 kg 100 kg A ....... Aluminum silicon 4.3 UN1398 III 4.3....... A1, A19, IB8, IP4 151........... 213........ 241........ 25 kg 100 kg A 40, 85, powder, uncoated. 103 Aluminum smelting by- 4.3 UN3170 II 4.3....... 128, B115, IB7, None.......... 212........ 242........ 15 kg 50 kg B 8#
Passage 975, 103 products or IP2 Aluminum remelting by-products. .................... ........... .................. III 4.3....... 128, B115, IB8, None.......... 213........ 241........ 25 kg 100 kg B 85, 103 IP4 Amatols, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Explosives, blasting, type B. G Amines, flammable, 3 UN2733 I 3, 8...... T14, TP1, TP27 None.......... 201........ 243........ 0.5 L 2.5 L D 40 corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s.. .................... ........... .................. II 3, 8...... IB2, T11, TP1, None.......... 202........ 243........ 1 L 5 L B 40 TP27 .................... ........... .................. III 3, 8...... B1, IB3, T7, TP1, 150........... 203........ 242........ 5 L 60 L A 40 TP28 G Amines, liquid, 8 UN2734 I 8, 3...... A3, A6, N34, T14, None.......... 201........ 243........ 0.5 L 2.5 L A ....... corrosive, TP2, TP27 flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s.. .................... ........... .................. II 8, 3...... IB2, T11, TP2, None.......... 202........ 243........ 1 L 30 L A ....... TP27 G Amines, liquid, 8 UN2735 I 8......... A3, A6, B10, N34, None.......... 201........ 243........ 0.5 L 2.5 L A ....... corrosive, n.o.s, T14, TP2, TP27 or Polyamines, liquid, corrosive, n.o.s.. .................... ........... .................. II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L A ....... TP1, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A ....... TP28 G Amines, solid, 8 UN3259 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg A ....... corrosive, n.o.s., or Polyamines, solid, corrosive n.o.s.. .................... ........... .................. II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... .................... ........... .................. III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... 2-Amino-4- 6.1 UN2673 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... chlorophenol. 2-Amino-5- 6.1 UN2946 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... diethylaminopentane. 2-Amino-4,6- 4.1 UN3317 I 4.1#
Passage 98....... 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg E 28, 36 Dinitrophenol, N41 wetted with not less than 20 percent water by mass. 2-(2-Aminoethoxy) 8 UN3055 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... ethanol. N- 8 UN2815 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A 12 Aminoethylpiperazin e. + Aminophenols (o-; m- 6.1 UN2512 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... ; p-). Aminopropyldiethanol ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... amine, see Amines, etc. n- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Aminopropylmorpholi ne, see Amines, etc. Aminopyridines (o-; 6.1 UN2671 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B 12, 40 m-; p-). T7, TP2 I Ammonia, anhydrous.. 2.3 UN1005 ....... 2.3, 8.... 4, T50 None.......... 304........ 314, 315... Forbidden 25 kg D 40, 57 D Ammonia, anhydrous.. 2.2 UN1005 ....... 2.2....... 13, T50 None.......... 304........ 314, 315... Forbidden 25 kg D 40, 57 D Ammonia solution, 2.2 UN3318 ....... 2.2....... 13, T50 None.......... 304........ 314, 315... Forbidden 25 kg D 40, 57 relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia. I Ammonia solution, 2.3 UN3318 ....... 2.3, 8.... 4, T50 None.......... 304........ 314, 315... Forbidden 25 kg D 40, 57 relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia. Ammonia solutions, 8 UN2672 III 8......... IB3, T7, TP1 154........... 203........ 241........ 5 L 60 L A 40, 85 relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia.#
Passage 99Ammonia solutions, 2.2 UN2073 ....... 2.2....... 306........... 304........ 314, 315... Forbidden 150 kg E 40, 57 relative density less than 0.880 at 15 degrees C in water, with more than 35 percent but not more than 50 percent ammonia. Ammonium arsenate... 6.1 UN1546 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Ammonium azide...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammonium bifluoride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, see Ammonium hydrogen difluoride, solid. Ammonium bifluoride ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Ammonium hydrogen difluoride, solution. Ammonium bromate.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammonium chlorate... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammonium dichromate. 5.1 UN1439 II 5.1....... IB8, IP2, IP4 152........... 212........ 242........ 5 kg 25 kg A ....... Ammonium dinitro-o- 6.1 UN1843 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B 36, 65, cresolate. T7, TP2 66, 77 Ammonium fluoride... 6.1 UN2505 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 Ammonium 6.1 UN2854 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 fluorosilicate. Ammonium fulminate.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammonium hydrogen 8 UN2506 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A 40 sulfate. Ammonium 8 UN1727 II 8......... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg A 25, 26, hydrogendifluoride, N34 40 solid. Ammonium 8 UN2817 II 8, 6.1.... IB2, N34, T8, None.......... 202........ 243........ 1 L 30 L B 40 hydrogendifluoride, TP2, TP12, TP13 solution. .................... ........... .................. III 8, 6.1.... IB3, T4, TP1, 154........... 203........ 241........ 5 L 60 L B 40, 95 TP12, TP13 Ammonium ........... .............#
Passage 100..... .......... ............. .......... .......... ........... ........... ........... ....... hydrosulfide, solution, see Ammonium sulfide solution. D Ammonium hydroxide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ammonia solutions, etc. Ammonium 6.1 UN2859 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... metavanadate. D Ammonium nitrate 5.1 NA2072 III 5.1....... 7, IB8 152........... 213........ 240........ 25 kg 100 kg B 48, 59, fertilizers. 60, 117 Ammonium nitrate 5.1 UN2067 III 5.1....... 52, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg B 48, 59, fertilizers; 60, 117 uniform non- segregating mixtures of ammonium nitrate with added matter which is inorganic and chemically inert towards ammonium nitrate, with not less than 90 percent ammonium nitrate and not more than 0.2 percent combustible material (including organic material calculated as carbon), or with more than 70 percent but less than 90 percent ammonium nitrate and not more than 0.4 percent total combustible material. A W Ammonium nitrate 9 UN2071 III 9......... 132, IB8 155........... 213........ 240........ 200 kg 200 kg A ....... fertilizers: uniform non- segregating mixtures of nitrogen/phosphate or nitrogen/postash types or complete fertilizers of nitrogen/phosphate/ postash type, with not more than 70 percent ammonium nitrate and not more than 0.4 percent total added combustible material or with not more than 45 percent ammonium nitrate with unrestricted combustible material. D Ammonium nitrate- 1.5D NA0331 II 1.5D...... None.......... 62......... None....... Forbidden Forbidden 10 19E fuel oil mixture containing only prilled ammonium nitrate and fuel oil. Ammonium nitrate, 5.1 UN2426 ....... 5.1....... B5, T7 None.......... None....... 243........ Forbidden Forbidden D 59, 60 liquid (hot concentrated solution). D Ammonium nitrate 5.1 NA2069 III 5.1....... 10, IB8 152........... 213........ 240........ 25 kg 100 kg B 48, 59, mixed fertlizers. 60, 117 Ammonium nitrate, 1.1D UN0222 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 19E with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance. Ammonium nitrate, 5.1 UN1942 III 5.1.......#
Passage 101A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 48, 59, with not more than 60, 116 0.2 percent of combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance. Ammonium nitrite.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammonium perchlorate 1.1D UN0402 II 1.1D...... 107 None.......... 62......... None....... Forbidden Forbidden 10 19E Ammonium perchlorate 5.1 UN1442 II 5.1....... 107, A9, IB6, IP2 152........... 212........ 242........ 5 kg 25 kg E 58, 69, 106#
Passage 102Ammonium Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... permanganate. Ammonium persulfate. 5.1 UN1444 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Ammonium picrate, 1.1D UN0004 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E, 19E dry or wetted with less than 10 percent water, by mass. Ammonium picrate, 4.1 UN1310 I 4.1....... 23, A2, N41 None.......... 211........ None....... 0.5 kg 0.5 kg D 28, 36 wetted with not less than 10 percent water, by mass. Ammonium 8 UN2818 II 8, 6.1.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 30 L B 12, 26, polysulfide, TP13 40 solution. .................... ........... .................. III 8, 6.1.... IB3, T4, TP1, 154........... 203........ 241........ 5 L 60 L B 12, 26, TP13 40 Ammonium 6.1 UN2861 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... polyvanadate. Ammonium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... silicofluoride, see Ammonium fluorosilicate. Ammonium sulfide 8 UN2683 II 8, 6.1, 3. IB1, T7, TP2, None.......... 202........ 243........ 1 L 30 L B 12, 22, solution. TP13 26, 100 Ammunition, blank, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Cartridges for weapons, blank. Ammunition, 1.2G UN0171 II 1.2G...... ............. 62......... None....... Forbidden Forbidden 03 ....... illuminating with or without burster, expelling charge or propelling charge. Ammunition, 1.3G UN0254 II 1.3G...... ............. 62......... None....... Forbidden Forbidden 03 ....... illuminating with or without burster, expelling charge or propelling charge. Ammunition, 1.4G UN0297 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 02 ....... illuminating with or without burster, expelling charge or propelling charge. Ammunition, 1.3J UN0247 II 1.3J...... ............. 62......... None....... Forbidden Forbidden 04 23E incendiary liquid or gel, with burster, expelling charge or propelling charge. Ammunition, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... incendiary (water- activated contr#
Passage 103ivances) with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc.. Ammunition, 1.2H UN0243 II 1.2H...... ............. 62......... None....... Forbidden Forbidden 08 8E, incendiary, white 14E, phosphorus, with 15E, burster, expelling 17E charge or propelling charge. Ammunition, 1.3H UN0244 II 1.3H...... ............. 62......... None....... Forbidden Forbidden 08 8E, incendiary, white 14E, phosphorus, with 15E, burster, expelling 17E charge or propelling charge. Ammunition, 1.2G UN0009 II 1.2G...... ............. 62......... None....... Forbidden Forbidden 03 ....... incendiary with or without burster, expelling charge, or propelling charge. Ammunition, 1.3G UN0010 II 1.3G...... ............. 62......... None....... Forbidden Forbidden 03 ....... incendiary with or without burster, expelling charge, or propelling charge. Ammunition, 1.4G UN0300 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 02 ....... incendiary with or without burster, expelling charge or propelling charge. Ammunition, practice 1.4G UN0362 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 02 ....... Ammunition, practice 1.3G UN0488 II 1.3G...... ............. 62......... None....... Forbidden Forbidden 03 ....... Ammunition, proof... 1.4G UN0363 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 02 ....... Ammunition, rocket, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Warheads, rocket etc. Ammunition, SA ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... (small arms), see Cartridges for weapons, etc. Ammunition, smoke ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... (water-activated contrivances), white phosphorus, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0248). Ammunition, smoke ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... (water-activated contrivances), without white phosphorus or phosphides, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0249). Ammunition smoke, 1.2H UN0245 II 1.2H...... .......#
Passage 104...... 62......... None....... Forbidden Forbidden 08 8E, white phosphorus 14E, with 15E, burster,expelling 17E charge, or propelling charge. Ammunition, smoke, 1.3H UN0246 II 1.3H...... ............. 62......... None....... Forbidden Forbidden 08 8E, white phosphorus 14E, with burster, 15E, expelling charge, 17E or propelling charge. Ammunition, smoke 1.2G UN0015 II 1.2G, 8... ............. 62......... None....... Forbidden Forbidden ........... 8E, with or without 17E, burster, expelling 20E charge or propelling charge.#
Passage 105Ammunition, smoke 1.3G UN0016 II 1.3G, 8... ............. 62......... None....... Forbidden Forbidden ........... 8E, with or without 17E, burster, expelling 20E charge or propelling charge. Ammunition, smoke 1.4G UN0303 II 1.4G, 8... ............. 62......... None....... Forbidden 75 kg ........... 7E, 8E, with or without 14E, burster, expelling 15E, charge or 17E propelling charge. Ammunition, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... sporting, see Cartridges for weapons, etc. (UN 0012; UN 0328; UN 0339). Ammunition, tear- 6.1 UN2017 II 6.1, 8.... None.......... 212........ None....... Forbidden 50 kg E 13, 40 producing, non- explosive, without burster or expelling charge, non-fuzed. Ammunition, tear- 1.2G UN0018 II 1.2G, 8, ............. 62......... None....... Forbidden Forbidden ........... 8E, producing with 6.1. 17E, burster, expelling 20E charge or propelling charge. Ammunition, tear- 1.3G UN0019 II 1.3G, 8, ............. 62......... None....... Forbidden Forbidden ........... 8E, producing with 6.1. 17E, burster, expelling 20E charge or propelling charge. Ammunition, tear- 1.4G UN0301 II 1.4G, 8, ............. 62......... None....... Forbidden 75 kg ........... 7E, 8E, producing with 6.1. 14E, burster, expelling 15E, charge or 17E propelling charge. Ammunition, toxic, 6.1 UN2016 II 6.1....... None.......... 212........ None....... Forbidden 100 kg E 13, 40 non-explosive, without burster or expelling charge, non-fuzed. Ammunition, toxic ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... (water-activated contrivances), with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. G Ammunition, toxic 1.2K UN0020 II 1.2K, 6.1. ............. 62......... None....... Forbidden Forbidden 08 8E, with burster, 14E, expelling charge, 15E, or propelling 17E charge. G Ammunition, toxic 1.3K UN0021 II 1.3K, 6.1. ............. 62......... None....... Forbidden Forbidden 08 8E, with burster, 14E, expelling charge, 15E, or propelling 17E charge. Amyl acetates....... 3 UN1104 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Amyl acid phosphate. 8 UN2819 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Amyl but#
Passage 106yrates...... 3 UN2620 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Amyl chlorides...... 3 UN1107 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Amyl formates....... 3 UN1109 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Amyl mercaptans..... 3 UN1111 II 3......... A3, IB2, T4, TP1 None.......... 202........ 242........ 5 L 60 L B 95, 102 n-Amyl methyl ketone 3 UN1110 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Amyl nitrate........ 3 UN1112 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A 40 Amyl nitrites....... 3 UN1113 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E 40 Amylamines.......... 3 UN1106 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... .................... ........... .................. III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A ....... Amyltrichlorosilane. 8 UN1728 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 N34, T7, TP2, TP13 Anhydrous ammonia, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ammonia, anhydrous. Anhydrous ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrofluoric acid, see Hydrogen fluoride, anhydrous. + Aniline............. 6.1 UN1547 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Aniline 6.1 UN1548 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... hydrochloride. Aniline oil, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Aniline. Anisidines.......... 6.1 UN2431 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Anisole............. 3 UN2222 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Anisoyl chloride.... 8 UN1729 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L C 40 Anti-freeze, liquid, ........... .................. .......... ............. .......... .........#
Passage 107. ........... ........... ........... ....... see Flammable liquids, n.o.s.. Antimonous chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Antimony trichloride. Antimony compounds, 6.1 UN3141 III 6.1....... 35, IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A ....... inorganic, liquid, TP28 n.o.s.. Antimony compounds, 6.1 UN1549 III 6.1....... 35, IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... inorganic, solid, n.o.s.. Antimony lactate.... 6.1 UN1550 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Antimony 8 UN1730 II 8......... B2, IB2, T7, TP2 None.......... 202........ 242........ 1 L 30 L C 40 pentachloride, liquid. Antimony 8 UN1731 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L C 40 pentachloride, solutions. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L C 40 Antimony 8 UN1732 II 8, 6.1.... A3, A6, A7, A10, None.......... 202........ 243........ Forbidden 30 L D 40 pentafluoride. IB2, N3, T7, TP2 Antimony potassium 6.1 UN1551 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... tartrate. Antimony powder..... 6.1 UN2871 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Antimony sulfide and Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... a chlorate, mixtures of. Antimony sulfide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, see Antimony compounds, inorganic, n.o.s.. Antimony 8 UN1733 II 8......... B2, IB2 154........... 202........ 242........ 1 L 30 L C 40 trichloride, liquid. Antimony 8 UN1733 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A 40 trichloride, solid.#
Passage 108Aqua ammonia, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammonia solution, etc. Argon, compressed... 2.2 UN1006 ....... 2.2....... 306........... 302........ 314, 315... 75 kg 150 kg A ....... Argon, refrigerated 2.2 UN1951 ....... 2.2....... T75, TP5 320........... 316........ 318........ 50 kg 500 kg B ....... liquid (cryogenic liquid). Arsenic............. 6.1 UN1558 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Arsenic acid, liquid 6.1 UN1553 I 6.1....... T20, TP2, TP7, None.......... 201........ 243........ 1 L 30 L B 46 TP13 Arsenic acid, solid. 6.1 UN1554 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Arsenic bromide..... 6.1 UN1555 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 12, 40 Arsenic chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Arsenic trichloride. Arsenic compounds, 6.1 UN1556 I 6.1....... None.......... 201........ 243........ 1 L 30 L B 40 liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.. .................... ........... .................. II 6.1....... IB2 None.......... 202........ 243........ 5 L 60 L B 40 .................... ........... .................. III 6.1....... IB3 153........... 203........ 241........ 60 L 220 L B 40 Arsenic compounds, 6.1 UN1557 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A ....... solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Arsenic pentoxide... 6.1 UN1559 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Arsenic sulfide and Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... a chlorate, mixtures of. Arsenic trichloride.#
Passage 1096.1 UN1560 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 40 B74, T20, TP2, TP13, TP38, TP45 Arsenic trioxide.... 6.1 UN1561 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Arsenic, white, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, see Arsenic trioxide. Arsenical dust...... 6.1 UN1562 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Arsenical 3 UN2760 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Arsenical 6.1 UN2994 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Arsenical 6.1 UN2993 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Arsenical 6.1 UN2759 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Arsenious acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, see Arsenic trioxide. Arsenious and ........... .................. .......... ......#
Passage 110....... .......... .......... ........... ........... ........... ....... mercuric iodide solution, see Arsenic compounds, liquid, n.o.s.. Arsine.............. 2.3 UN2188 ....... 2.3, 2.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 Articles, explosive, 1.6N UN0486 II 1.6N...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... extremely insensitive or Articles, EEI. G Articles, explosive, 1.4S UN0349 II 1.4S...... 101 None.......... 62......... None....... 25 kg 100 kg 05 ....... n.o.s.. G Articles, explosive, 1.4B UN0350 II 1.4B...... 101 None.......... 62......... None....... Forbidden Forbidden 06 ....... n.o.s.. G Articles, explosive, 1.4C UN0351 II 1.4C...... 101 None.......... 62......... None....... Forbidden 75 kg 06 ....... n.o.s.. G Articles, explosive, 1.4D UN0352 II 1.4D...... 101 None.......... 62......... None....... Forbidden 75 kg 06 ....... n.o.s.. G Articles, explosive, 1.4G UN0353 II 1.4G...... 101 None.......... 62......... None....... Forbidden 75 kg 06 ....... n.o.s.. G Articles, explosive, 1.1L UN0354 II 1.1L...... 101 None.......... 62......... None....... Forbidden Forbidden 08 8E, n.o.s.. 14E, 15E, 17E G Articles, explosive, 1.2L UN0355 II 1.2L...... 101 None.......... 62......... None....... Forbidden Forbidden 08 8E, n.o.s.. 14E, 15E, 17E G Articles, explosive, 1.3L UN0356 II 1.3L...... 101 None.......... 62......... None....... Forbidden Forbidden 08 8E, n.o.s.. 14E, 15E, 17E G Articles, explosive, 1.1C UN0462 II 1.1C...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s.. G Articles, explosive, 1.1D UN0463 II 1.1D...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s.. G Articles, explosive, 1.1E UN0464 II 1.1E...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s.. G Articles, explosive, 1.1F UN0465 II 1.1F...... 101 None.......... 62......... None....... Forbidden Forbidden 08 ....... n.o.s.. G Articles, explosive, 1.2C UN0466 II 1.2C...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s..#
Passage 111G Articles, explosive, 1.2D UN0467 II 1.2D...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s.. G Articles, explosive, 1.2E UN0468 II 1.2E...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s.. G Articles, explosive, 1.2F UN0469 II 1.2F...... 101 None.......... 62......... None....... Forbidden Forbidden 08 ....... n.o.s.. G Articles, explosive, 1.3C UN0470 II 1.3C...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... n.o.s.. G Articles, explosive, 1.4E UN0471 II 1.4E...... 101 None.......... 62......... None....... Forbidden 75 kg 06 ....... n.o.s.. G Articles, explosive, 1.4F UN0472 II 1.4F...... 101 None.......... 62......... None....... Forbidden Forbidden 08 ....... n.o.s.. Articles, 2.2 UN3164 ....... 2.2....... 306........... 302, 304... None....... No limit No limit A ....... pressurized pneumatic or hydraulic containing non- flammable gas. Articles, pyrophoric 1.2L UN0380 II 1.2L...... None.......... 62......... None....... Forbidden Forbidden 08 8E, 14E, 15E, 17E Articles, 1.1G UN0428 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... pyrotechnic for technical purposes. Articles, 1.2G UN0429 II 1.2G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... pyrotechnic for technical purposes. Articles, 1.3G UN0430 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... pyrotechnic for technical purposes. Articles, 1.4G UN0431 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... pyrotechnic for technical purposes. Articles, 1.4S UN0432 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... pyrotechnic for technical purposes. D Asbestos............ 9 NA2212 III 9......... IB8, IP2, IP4 155........... 216........ 240........ 200 kg 200 kg A 34, 40 Ascaridole (organic Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxide). D Asphalt, at or above 3 NA1999 III 3......... IB3, T1, TP3 150........... 203........ 247........ Forbidden Forbidden D ....... its flash point. D Asphalt, cut back, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Tars, liquid, etc. Automobile, ........... .........#
Passage 112......... .......... ............. .......... .......... ........... ........... ........... ....... motorcycle, tractor, other self- propelled vehicle, engine, or other mechanical apparatus, see Vehicles or Battery etc. A G Aviation regulated 9 UN3334 ....... 9......... A35 155........... 204........ .......... No limit No limit A ....... liquid, n.o.s.. A G Aviation regulated 9 UN3335 ....... 9......... A35 155........... 204........ .......... No limit No limit A ....... solid, n.o.s.. Azaurolic acid (salt Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... of) (dry). Azido guanidine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... picrate (dry). 5-Azido-1-hydroxy Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetrazole. Azido hydroxy Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetrazole (mercury and silver salts). 3-Azido-1,2- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Propylene glycol dinitrate. Azidodithiocarbonic Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... acid. Azidoethyl nitrate.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 1- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Aziridinylphosphine oxide-(tris), see Tris-(1-aziridinyl) phosphine oxide, solution. Azodicarbonamide.... 4.1 UN3242 II 4.1....... 38, IB8 151........... 212........ 240........ Forbidden Forbidden D 12, 61, 74 Azotetrazole (dry).. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Barium.............. 4.3 UN1400 II 4.3....... A19, IB7, IP2 151........... 212........ 241........ 15 kg 50 kg E ....... Barium alloys, 4.2 UN1854 I 4.2....... None.......... 181........ None....... Forbidden Forbidden D ....... pyrophoric. Barium azide, dry or 1.1A UN0224 II 1.1A, 6.1. 111, 117 None.......... 62......... None....... Forbidden Forbidden 1#
Passage 1132 ....... wetted with less than 50 percent water, by mass. Barium azide, wetted 4.1 UN1571 I 4.1, 6.1.. A2 None.......... 182........ None....... Forbidden 0.5 kg D 28 with not less than 50 percent water, by mass. Barium bromate...... 5.1 UN2719 II 5.1, 6.1.. IB8, IP2, IP4 None.......... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Barium chlorate..... 5.1 UN1445 II 5.1, 6.1.. A9, IB6, IP2, None.......... 212........ 242........ 5 kg 25 kg A 56, 58, N34, T4, TP1 106 Barium compounds, 6.1 UN1564 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... n.o.s.. .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Barium cyanide...... 6.1 UN1565 I 6.1....... IB7, IP1, N74, None.......... 211........ 242........ 5 kg 50 kg A 26, 40 N75 Barium hypochlorite 5.1 UN2741 II 5.1, 6.1.. A7, A9, IB8, IP2, 152........... 212........ None....... 5 kg 25 kg B 56, 58, with more than 22 IP4, N34 106 percent available chlorine. Barium nitrate...... 5.1 UN1446 II 5.1, 6.1.. IB8, IP2, IP4 None.......... 212........ 242........ 5 kg 25 kg A ....... Barium oxide........ 6.1 UN1884 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Barium perchlorate.. 5.1 UN1447 II 5.1, 6.1.. IB6, IP2, T4, TP1 None.......... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Barium permanganate. 5.1 UN1448 II 5.1, 6.1.. IB6, IP2 None.......... 212........ 242........ 5 kg 25 kg D 56, 58, 69, 106, 107 Barium peroxide..... 5.1 UN1449 II 5.1, 6.1.. IB6, IP2 None.......... 212........ 242........ 5 kg 25 kg A 13, 75, 106 Barium selenate, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Barium selenite, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Batteries, 4.3 UN3292 II 4.3....... 189........... 189........ 189........ Forbidden No limit A ....... containing sodium.#
Passage 114Batteries, dry, 8 UN3028 III 8......... None.......... 213........ None....... 25 kg gross 230 kg A ....... containing gross potassium hydroxide solid, electric, storage. Batteries, wet, 8 UN2794 III 8......... 159........... 159........ 159........ 30 kg gross No limit A ....... filled with acid, electric storage. Batteries, wet, non- 8 UN2800 III 8......... 159........... 159........ 159........ No Limit No Limit A ....... spillable, electric storage. Batteries, dry, not ........... .................. .......... 130 ............. .......... .......... ........... ........... ........... ....... subject to the requirements of this subchapter. Battery fluid, acid. 8 UN2796 II 8......... A3, A7, B2, B15, 154........... 202........ 242........ 1 L 30 L B ....... IB2, N6, N34, T8, TP2, TP12 Battery fluid, 8 UN2797 II 8......... B2, IB2, N6, T7, 154........... 202........ 242........ 1 L 30 L A ....... alkali. TP2 Battery lithium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... type, see Lithium batteries etc. Battery-powered 9 UN3171 ....... 9......... 134 220........... 220........ None....... No limit No limit ........... ....... vehicle or Battery- powered equipment. Battery, wet, filled ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... with acid or alkali with vehicle or mechanical equipment containing an internal combustion engine, see Vehicle, etc. or Engines, internal combustion, etc. + Benzaldehyde........ 9 UN1990 III 9......... IB3, T2, TP1 155........... 203........ 241........ 100 L 220 L A ....... Benzene............. 3 UN1114 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Benzene diazonium Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... chloride (dry). Benzene diazonium Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrate (dry). Benzene phosphorus ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... dichloride, see Phenyl phosphorus dichloride. Benzene phosphorus ........... .................. .......... ............. .......... .......... ........... .........#
Passage 115.. ........... ....... thiodichloride, see Phenyl phosphorus thiodichloride. Benzene sulfonyl 8 UN2225 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A 40 chloride. Benzene triozonide.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Benzenethiol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Phenyl mercaptan. Benzidine........... 6.1 UN1885 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Benzol, see Benzene. ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Benzonitrile........ 6.1 UN2224 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 26, 40 Benzoquinone........ 6.1 UN2587 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Benzotrichloride.... 8 UN2226 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A 40 Benzotrifluoride.... 3 UN2338 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Benzoxidiazoles Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Benzoyl azide....... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Benzoyl chloride.... 8 UN1736 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L C 40 TP12, TP13 Benzyl bromide...... 6.1 UN1737 II 6.1, 8.... A3, A7, IB2, N33, None.......... 202........ 243........ 1 L 30 L D 13, 40 N34, T8, TP2, TP12, TP13 Benzyl chloride..... 6.1 UN1738 II 6.1, 8.... A3, A7, B70, IB2, None.......... 202........ 243........ 1 L 30 L D 13, 40 N33, N42, T8, TP2, TP12, TP13 Benzyl chloride 6.1 UN1738 II 6.1, 8.... A3, A7, B8, B11, None.......... 202........ 243........ 1 L 30 L D 13, 40 unstabilized. IB2, N33, N34, N43, T8, TP2, TP12, TP13 Benzyl chloroformate 8 UN1739 I 8......... A3, A6, B4, N41, None.......... 201........ 243........ Forbidden 2.5 L D 40 T10, TP2, TP12, TP13 Benzyl iodide....... 6.1 UN2653 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L B 12, 40 Benzyldimethylamine. 8 UN2619 II 8, 3...... B2,#
Passage 116IB2, T7, TP2 154........... 202........ 243........ 1 L 30 L A 40, 48 Benzylidene chloride 6.1 UN1886 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L D 40 Beryllium compounds, 6.1 UN1566 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... n.o.s.. .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Beryllium nitrate... 5.1 UN2464 II 5.1, 6.1.. IB8, IP2, IP4 None.......... 212........ 242........ 5 kg 25 kg A ....... Beryllium, powder... 6.1 UN1567 II 6.1, 4.1.. IB8, IP2, IP4 None.......... 212........ 242........ 15 kg 50 kg A ....... Bicyclo [2,2,1] 3 UN2251 II 3......... IB2, T7, TP2 150........... 202........ 242........ 5 L 60 L D ....... hepta-2,5-diene, stabilized or 2,5- Norbornadiene, stabilized. Biphenyl triozonide. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Bipyridilium 3 UN2782 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L E ....... pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Bipyridilium 6.1 UN3016 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Bipyridilium 6.1 UN3015 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 21, 40 pesticides, liquid, TP27 toxic, flammable, flash point not less than 23 degrees C.#
Passage 117.................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 21, 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 21, 40 TP28 Bipyridilium 6.1 UN2781 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Bis (Aminopropyl) ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... piperazine, see Corrosive liquid, n.o.s.. Bisulfate, aqueous 8 UN2837 II 8......... A7, B2, IB2, N34, 154........... 202........ 242........ 1 L 30 L A ....... solution. T7, TP2 .................... ........... .................. III 8......... A7, IB3, N34, T4, 154........... 203........ 241........ 5 L 60 L A ....... TP1 Bisulfites, aqueous 8 UN2693 III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A 26, 40 solutions, n.o.s.. TP28 Black powder, 1.1D UN0028 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... compressed or Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets. Black powder or 1.1D UN0027 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Gunpowder, granular or as a meal. D Black powder for 4.1 NA0027 I 4.1....... 70 None.......... 170........ None....... Forbidden Forbidden E ....... small arms. Blasting agent, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... n.o.s., see Explosives, blasting etc. Blasting cap ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... assemblies, see Detonator assemblies, non- electric, for blasting. Blasting caps, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... electric, see Detonators, electric for blasting. Blasting caps, non- ........... .................. .......... .#
Passage 118............ .......... .......... ........... ........... ........... ....... electric, see Detonators, non- electric, for blasting. Bleaching powder, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Calcium hypochlorite mixtures, etc. I Blue asbestos 9 UN2212 II 9......... IB8, IP2, IP4 155........... 216........ 240........ Forbidden Forbidden A 34, 40 (Crocidolite) or Brown asbestos (amosite, mysorite). Bombs, photo-flash.. 1.1F UN0037 II 1.1F...... ............. 62......... None....... Forbidden Forbidden 08 ....... Bombs, photo-flash.. 1.1D UN0038 II 1.1D...... ............. 62......... None....... Forbidden Forbidden 03 ....... Bombs, photo-flash.. 1.2G UN0039 II 1.2G...... ............. 62......... None....... Forbidden Forbidden 03 ....... Bombs, photo-flash.. 1.3G UN0299 II 1.3G...... ............. 62......... None....... Forbidden Forbidden 03 ....... Bombs, smoke, non- 8 UN2028 II 8......... None.......... 160........ None....... Forbidden 50 kg E 40 explosive, with corrosive liquid, without initiating device. Bombs, with bursting 1.1F UN0033 II 1.1F...... ............. 62......... None....... Forbidden Forbidden 08 ....... charge. Bombs, with bursting 1.1D UN0034 II 1.1D...... ............. 62......... None....... Forbidden Forbidden 03 ....... charge. Bombs, with bursting 1.2D UN0035 II 1.2D...... ............. 62......... None....... Forbidden Forbidden 03 ....... charge. Bombs, with bursting 1.2F UN0291 II 1.2F...... ............. 62......... None....... Forbidden Forbidden 08 ....... charge. Bombs with flammable 1.1J UN0399 II 1.1J...... ............. 62......... None....... Forbidden Forbidden 04 23E liquid, with bursting charge. Bombs with flammable 1.2J UN0400 II 1.2J...... ............. 62......... None....... Forbidden Forbidden 04 23E liquid, with bursting charge. Boosters with 1.1B UN0225 II 1.1B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... detonator. Boosters with 1.2B UN0268 II 1.2B...... None.......... 62......... None....... Forbidden Forbidden 07 ....... detonator. Boosters, without 1.1D UN0042 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... detonator. Boosters, without 1.2D UN0283 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... detonator. Borate and ch#
Passage 119lorate ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures, see Chlorate and borate mixtures. Borneol............. 4.1 UN1312 III 4.1....... A1, IB8, IP3 None.......... 213........ 240........ 25 kg 100 kg A ....... + Boron tribromide.... 8 UN2692 I 8, 6.1.... 2, A3, A7, B9, None.......... 227........ 244........ Forbidden Forbidden C 12 B14, B32, B74, N34, T20, TP2, TP12, TP13, TP38, TP45 Boron trichloride... 2.3 UN1741 ....... 2.3, 8.... 3, B9, B14 None.......... 304........ 314........ Forbidden Forbidden D 25, 40 Boron trifluoride, 2.3 UN1008 ....... 2.3....... 2, B9, B14 None.......... 302........ 314, 315... Forbidden Forbidden D 40 compressed. Boron trifluoride 8 UN1742 II 8......... B2, B6, IB2, T8, 154........... 202........ 242........ 1 L 30 L A ....... acetic acid complex. TP2, TP12 Boron trifluoride 8 UN2604 I 8, 3...... A19, T10, TP2 None.......... 201........ 243........ 0.5 L 2.5 L D 40 diethyl etherate. Boron trifluoride 8 UN2851 II 8......... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg B 12, 40, dihydrate. T7, TP2 Boron trifluoride 4.3 UN2965 I 4.3, 8, 3. A19, T10, TP2, None.......... 201........ 243........ Forbidden 1 L D 21, 28, dimethyl etherate. TP7 40, 49, 100 Boron trifluoride 8 UN1743 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L A ....... propionic acid TP12 complex. Box toe gum, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrocellulose etc. Bromates, inorganic, 5.1 UN3213 II 5.1....... IB2, T4, TP1 152........... 202........ 242........ 1 L 5 L B 56, 58, aqueous solution, 106 n.o.s.. Bromates, inorganic, 5.1 UN1450 II 5.1....... IB8, IP2, IP4 152........... 212........ 242........ 5 kg 25 kg A 56, 58, n.o.s.. 106 Bromine azide....... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... + Bromine or Bromine 8 UN1744 I 8, 6.1.... 1, A3, A6, B9, None.......... 226........ 249........ Forbidden Forbidden ........... 12, 40, solutions. B64, B85, N34, 66, 74, N43, T22, TP2, 89, 90 TP10, TP12, TP13#
Passage 120Bromine chloride.... 2.3 UN2901 ....... 2.3, 8, 2, B9, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40, 89, 5.1. 90 + Bromine 5.1 UN1745 I 5.1, 6.1, 1, B9, B14, B30, None.......... 228........ 244........ Forbidden Forbidden D 25, 40, pentafluoride. 8. B72, T22, TP2, 66, 90 TP12, TP13, TP38, TP44 + Bromine trifluoride. 5.1 UN1746 I 5.1, 6.1, 2, B9, B14, B32, None.......... 228........ 244........ Forbidden Forbidden D 25, 40, 8. B74, T22, TP2, 66, 90 TP12, TP13, TP38, TP45 4-Bromo-1,2- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrobenzene. 4-Bromo-1,2- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrobenzene (unstable at 59 degrees C.). 1-Bromo-3- 6.1 UN2688 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... chloropropane. 1-Bromo-3- 3 UN2341 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... methylbutane. 1-Bromo-3- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrobenzene (unstable at 56 degrees C). 2-Bromo-2- 4.1 UN3241 III 4.1....... 46, IB8, IP3 151........... 213........ None....... 25 kg 50 kg C 12, 25, nitropropane-1,3- 40 diol. Bromoacetic acid, 8 UN1938 II 8......... A7, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A ....... solid. IP4, N34, T7 Bromoacetic acid, 8 UN1938 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A 40 solution. + Bromoacetone........ 6.1 UN1569 II 6.1, 3.... 2, T20, TP2, TP13 None.......... 193........ 245........ Forbidden Forbidden D 40 Bromoacetyl bromide. 8 UN2513 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L C 40 TP12 Bromobenzene........ 3 UN2514 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Bromobenzyl 6.1 UN1694 I 6.1....... T14, TP2, TP13 None.......... 201........ 243........ Forbidden 30 L D 12, 40 cyanides, liquid. Bromobenzyl 6.1 UN1694 I 6.1....... T14, TP2, TP13 None.......... 211........ 242........ Forbidden 50 kg D 12, 40 cyanides, solid. 1-Bromobutane....... 3 UN1126 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5L 60 L B 40 2-Bromobutane#
Passage 121....... 3 UN2339 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Bromochloromethane.. 6.1 UN1887 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... 2-Bromoethyl ethyl 3 UN2340 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 ether. Bromoform........... 6.1 UN2515 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 12, 40 Bromomethylpropanes. 3 UN2342 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... 2-Bromopentane...... 3 UN2343 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Bromopropanes....... 3 UN2344 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 .................... ........... .................. III 3......... IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... 3-Bromopropyne...... 3 UN2345 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L D 40 Bromosilane......... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Bromotoluene-alpha, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Benzyl bromide. Bromotrifluoroethyle 2.1 UN2419 ....... 2.1....... None.......... 304........ 314, 315... Forbidden 150 kg B 40 ne. Bromotrifluoromethan 2.2 UN1009 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... e or Refrigerant gas, R 13B1.. Brucine............. 6.1 UN1570 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A ....... Bursters, explosive. 1.1D UN0043 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Butadienes, 2.1 UN1010 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 stabilized. Butane see also 2.1 UN1011 ....... 2.1....... 19, T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 Petroleum gases, liquefied. Butane, butane ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures and mixtures having similar properties in cartridges each not exceeding 500 grams, see Receptacles, etc. Butanedione......... 3 UN2346 II 3.........#
Passage 122IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... 1,2,4-Butanetriol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trinitrate. Butanols............ 3 UN1120 II 3......... IB2, T4, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP29 .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... tert-Butoxycarbonyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... azide. Butyl acetates...... 3 UN1123 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Butyl acid phosphate 8 UN1718 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Butyl acrylates, 3 UN2348 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... stabilized. Butyl alcohols, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Butanols. Butyl benzenes...... 3 UN2709 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... n-Butyl bromide, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... 1-Bromobutane. n-Butyl chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Chlorobutanes. D sec-Butyl 6.1 NA2742 I 6.1, 3, 8. 2, B9, B14, B32, None.......... 227........ 244........ 1 L 30 L A 12, 13, chloroformate. B74, T20, TP4, 22, 25, TP12, TP13, TP38, 40, 48, TP45 100 n-Butyl 6.1 UN2743 I 6.1, 8, 3. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden A 12, 13, chloroformate. B74, T20, TP2, 21, 25, TP13, TP38, TP45 40, 100 Butyl ethers, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Dibutyl ethers. Butyl ethyl ether, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethyl#
Passage 123butyl ether. n-Butyl formate..... 3 UN1128 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... tert-Butyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... hydroperoxide, with more than 90 percent with water. tert-Butyl 4.2 UN3255 I 4.2, 8.... None.......... 211........ 243........ Forbidden Forbidden D ....... hypochlorite. N-n-Butyl imidazole. 6.1 UN2690 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A .......#
Passage 124tert-Butyl 6.1 UN2484 I 6.1, 3.... 1, A7, B9, B14, None.......... 226........ 244........ Forbidden Forbidden D 40 isocyanate. B30, B72, T22, TP2, TP13, TP38, TP44 n-Butyl isocyanate.. 6.1 UN2485 I 6.1, 3.... 2, A7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 40 B32, B74, B77, T20, TP2, TP13, TP38, TP45 Butyl mercaptans.... 3 UN2347 II 3......... A3, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L D 26, 95 n-Butyl 3 UN2227 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... methacrylate, stabilized. Butyl methyl ether.. 3 UN2350 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Butyl nitrites...... 3 UN2351 I 3......... T11, TP1, TP8, 150........... 201........ 243........ 1 L 30 L E 40 TP27 .................... ........... .................. II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A 40 tert-Butyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxyacetate, with more than 76 percent in solution. n-Butyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxydicarbonate, with more than 52 percent in solution. tert-Butyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxyisobutyrate, with more than 77 percent in solution. Butyl phosphoric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... acid, see Butyl acid phosphate. Butyl propionates... 3 UN1914 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... 5-tert-Butyl-2,4,6- 4.1 UN2956 III 4.1....... None.......... 214........ None....... Forbidden Forbidden D 12 trinitro-m-xylene or Musk xylene. Butyl vinyl ether, 3 UN2352 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 stabilized. n-Butylamine........ 3 UN1125 II 3, 8...... IB2, T7, TP1 None.......... 202........ 242........ 1 L 5 L B 40 N-Butylaniline...... 6.1 UN2738 II 6.1....... IB2, T7, TP2 None.......... 202........ 24#
Passage 1253........ 5 L 60 L A ....... tert- 6.1 UN2747 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 12, 13, Butylcyclohexylchlo 25 roformate. Butylene see also 2.1 UN1012 ....... 2.1....... 19, T50 None.......... 304........ 314, 315... Forbidden 150 kg E 40 Petroleum gases, liquefied. 1,2-Butylene oxide, 3 UN3022 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 49 stabilized. Butyltoluenes....... 6.1 UN2667 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Butyltrichlorosilane 8 UN1747 II 8, 3...... A7, B2, B6, IB2, None.......... 202........ 243........ Forbidden 30 L C 40 N34, T7, TP2, TP13 1,4-Butynediol...... 6.1 UN2716 III 6.1....... A1, IB8, IP3 None.......... 213........ 240........ 100 kg 200 kg A 61, 70 Butyraldehyde....... 3 UN1129 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Butyraldoxime....... 3 UN2840 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Butyric acid........ 8 UN2820 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A 12 Butyric anhydride... 8 UN2739 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Butyronitrile....... 3 UN2411 II 3, 6.1.... IB2, T7, TP1, None.......... 202........ 243........ 1 L 60 L E 40 TP13 Butyryl chloride.... 3 UN2353 II 3, 8...... IB2, T8, TP2, None.......... 202........ 243........ 1 L 5 L C 40 TP12, TP13 Cacodylic acid...... 6.1 UN1572 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg E 26 Cadmium compounds... 6.1 UN2570 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A ....... .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Caesium hydroxide... 8 UN2682 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... Caesium hydroxide 8 UN2681 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L#
Passage 126A ....... Calcium............. 4.3 UN1401 II 4.3....... IB7, IP2 151........... 212........ 241........ 15 kg 50 kg E ....... Calcium arsenate.... 6.1 UN1573 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Calcium arsenate and 6.1 UN1574 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... calcium arsenite, mixtures, solid. Calcium bisulfite ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Calcium carbide..... 4.3 UN1402 I 4.3....... A1, A8, B55, B59, None.......... 211........ 242........ Forbidden 15 kg B ....... IB4, IP1, N34 .................... ........... .................. II 4.3....... A1, A8, B55, B59, 151........... 212........ 241........ 15 kg 50 kg B ....... IB7, IP2, N34 Calcium chlorate.... 5.1 UN1452 II 5.1....... IB8, IP2, IP4, 152........... 212........ 242........ 5 kg 25 kg A 56, 58, N34 106 Calcium chlorate 5.1 UN2429 II 5.1....... A2, IB2, N41, T4, 152........... 202........ 242........ 1 L 5 L B 56, 58, aqueous solution. TP1 106 .................... ........... .................. III 5.1....... A2, IB2, N41, T4, 152........... 203........ 241........ 2.5 L 30 L B 56, 68, TP1 106 Calcium chlorite.... 5.1 UN1453 II 5.1....... A9, IB8, IP2, 152........... 212........ 242........ 5 kg 25 kg A 56, 58, IP4, N34 106 Calcium cyanamide 4.3 UN1403 III 4.3....... A1, A19, IB8, IP4 151........... 213........ 241........ 25 kg 100 kg A ....... with more than 0.1 percent of calcium carbide. Calcium cyanide..... 6.1 UN1575 I 6.1....... IB7, IP1, N79, None.......... 211........ 242........ 5 kg 50 kg A 26, 40 N80 Calcium dithionite 4.2 UN1923 II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg E 13 or Calcium IP2 hydrosulfite. Calcium hydride..... 4.3 UN1404 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... Calcium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrosulfite, see Calcium dithionite.#
Passage 127Calcium 5.1 UN1748 II 5.1....... A7, A9, IB8, IP2, 152........... 212........ None....... 5 kg 25 kg D 4, 5, hypochlorite, dry IP4, N34, W9 25, 48, or Calcium 56, 58, hypochlorite 69 mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen). Calcium 5.1 UN2880 II 5.1....... IB8, IP2, IP4, W9 152........... 212........ 240........ 5 kg 25 kg D 4, 5, hypochlorite, 25, 48, hydrated or Calcium 56, 58, hypochlorite, 69 hydrated mixtures, with not less than 5.5 percent but not more than 10 percent water. Calcium hypochlorite 5.1 UN2208 III 5.1....... A1, A29, IB8, 152........... 213........ 240........ 25 kg 100 kg D 4, 5, mixtures, dry, with IP3, N34, W9 25, 48, more than 10 56, 58, percent but not 69 more than 39 percent available chlorine. Calcium manganese 4.3 UN2844 III 4.3....... A1, A19, IB8, 151........... 213........ 241........ 25 kg 100 kg A 85, 103 silicon. IP2, IP4 Calcium nitrate..... 5.1 UN1454 III 5.1....... 34, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... A Calcium oxide....... 8 UN1910 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... Calcium perchlorate. 5.1 UN1455 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Calcium permanganate 5.1 UN1456 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg D 56, 58, 69, 106, 107 Calcium peroxide.... 5.1 UN1457 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 13, 75, 106 Calcium phosphide... 4.3 UN1360 I 4.3, 6.1.. A8, A19, N40 None.......... 211........ 242........ Forbidden 15 kg E 40, 85 Calcium, pyrophoric 4.2 UN1855 I 4.2....... None.......... 187........ None....... Forbidden Forbidden D ....... or Calcium alloys, pyrophoric. Calcium resinate.... 4.1 UN1313 III 4.1....... A1, A19, IB6 None.......... 213........ 240........ 25 kg 100 kg A ....... Calcium resinate, 4.1 UN1314 III 4.1....... A1, A19, IB4 None.......... 213........ 240........ 25 kg 100 kg A ....... fused. Calcium selenate, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Selenates or Selenites. Calcium silicide.... 4.3 UN1405 II 4.3....... A19, IB7, IP2 151........... 212........ 241........ 15 kg 50 kg B 85, 103 .................... ........... .................. III 4.3....... A1, A19,#
Passage 128IB8, IP4 151........... 213........ 241........ 25 kg 100 kg B 85, 103 Camphor oil......... 3 UN1130 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Camphor, synthetic.. 4.1 UN2717 III 4.1....... A1, IB8, IP3 None.......... 213........ 240........ 25 kg 100 kg A ....... Cannon primers, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Primers, tubular. Caproic acid........ 8 UN2829 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Caps, blasting, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Detonators, etc. Carbamate 3 UN2758 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Carbamate 6.1 UN2992 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Carbamate 6.1 UN2991 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Carbamate 6.1 UN2757 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Carbolic acid, see .......#
Passage 129.... .................. .......... ............. .......... .......... ........... ........... ........... ....... Phenol, solid or Phenol, molten. Carbolic acid ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solutions, see Phenol solutions. I Carbon, activated... 4.2 UN1362 III 4.2....... IB8, IP3 None.......... 213........ 241........ 0.5 kg 0.5 kg A 12 I Carbon, animal or 4.2 UN1361 II 4.2....... IB6 None.......... 212........ 242........ Forbidden Forbidden A 12 vegetable origin. .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ Forbidden Forbidden A 12 Carbon bisulfide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Carbon disulfide. Carbon dioxide...... 2.2 UN1013 ....... 2.2....... 306........... 302, 304... 302, 314, 75 kg 150 kg A ....... 315. Carbon dioxide and 2.2 UN1015 ....... 2.2....... 306........... None....... 314, 315... 75 kg 150 kg A ....... nitrous oxide mixtures. Carbon dioxide and 2.2 UN1014 ....... 2.2, 5.1.. 77 306........... 304........ 314, 315... 75 kg 150 kg A ....... oxygen mixtures, compressed. Carbon dioxide, 2.2 UN2187 ....... 2.2....... T75, TP5 306........... 304........ 314, 315... 50 kg 500 kg B ....... refrigerated liquid. A W Carbon dioxide, 9 UN1845 III None...... 217........... 217........ 240........ 200 kg 200 kg C 40 solid or Dry ice. Carbon disulfide.... 3 UN1131 I 3, 6.1.... B16, T14, TP2, None.......... 201........ 243........ Forbidden Forbidden D 18, 40, TP7, TP13 115 Carbon monoxide, 2.3 UN1016 ....... 2.3, 2.1.. 4 None.......... 302........ 314, 315... Forbidden 25 kg D 40 compressed. Carbon monoxide and 2.3 UN2600 ....... 2.3, 2.1.. 6 None.......... 302........ 302........ Forbidden Forbidden D 40 hydrogen mixture, compressed.#
Passage 130D Carbon monoxide, 2.3 NA9202 ....... 2.3, 2.1.. 4, T75, TP5 None.......... 316........ 318........ Forbidden Forbidden D ....... refrigerated liquid (cryogenic liquid). Carbon tetrabromide. 6.1 UN2516 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 25 Carbon tetrachloride 6.1 UN1846 II 6.1....... IB2, N36, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Carbonyl chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Phosgene. Carbonyl fluoride, 2.3 UN2417 ....... 2.3, 8.... 2 None.......... 302........ None....... Forbidden Forbidden D 40 compressed. Carbonyl sulfide.... 2.3 UN2204 ....... 2.3, 2.1.. 3, B14 None.......... 304........ 314, 315... Forbidden 25 kg D 40 Cartridge cases, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... empty primed, see Cases, cartridge, empty, with primer. Cartridges, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... actuating, for aircraft ejector seat catapult, fire extinguisher, canopy removal or apparatus, see Cartridges, power device. Cartridges, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... explosive, see Charges, demolition. Cartridges, flash... 1.1G UN0049 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Cartridges, flash... 1.3G UN0050 II 1.3G...... None.......... 62......... None....... Forbidden 75 kg 07 ....... Cartridges for 1.1C UN0326 II 1.1C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... weapons, blank. Cartridges for 1.2C UN0413 II 1.2C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... weapons, blank. Cartridges for 1.4S UN0014 II None...... 63............ 62......... None....... 25 kg 100 kg 05 ....... weapons, blank or Cartridges, small arms, blank. Cartridges for 1.3C UN0327 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... weapons, blank or Cartridges, small arms, blank. Cartridges for 1.4C UN0338 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 06 ....... weapons, blank or Cartridges, small arms, blank. Cartridges for 1.2C UN#
Passage 1310328 II 1.2C...... None.......... 62......... None....... Forbidden Forbidden 03 ....... weapons, inert projectile. Cartridges for 1.4S UN0012 II None...... 63............ 62......... None....... 25 kg 100 kg 05 ....... weapons, inert projectile or Cartridges, small arms. Cartridges for 1.4C UN0339 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 06 ....... weapons, inert projectile or Cartridges, small arms. Cartridges for 1.3C UN0417 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 06 ....... weapons, inert projectile or Cartridges, small arms. Cartridges for 1.1F UN0005 II 1.1F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... weapons, with bursting charge. Cartridges for 1.1E UN0006 II 1.1E...... None.......... 62......... None....... Forbidden Forbidden 03 ....... weapons, with bursting charge. Cartridges for 1.2F UN0007 II 1.2F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... weapons, with bursting charge. Cartridges for 1.2E UN0321 II 1.2E...... None.......... 62......... None....... Forbidden Forbidden 03 ....... weapons, with bursting charge. Cartridges for 1.4F UN0348 II 1.4F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... weapons, with bursting charge. Cartridges for 1.4E UN0412 II 1.4E...... None.......... 62......... None....... Forbidden 75 kg 02 ....... weapons, with bursting charge. Cartridges, oil well 1.3C UN0277 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Cartridges, oil well 1.4C UN0278 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Cartridges, power 1.3C UN0275 II 1.3C...... None.......... 62......... None....... Forbidden 75 kg 07 ....... device. Cartridges, power 1.4C UN0276 II 1.4C...... 110 None.......... 62......... None....... Forbidden 75 kg 06 ....... device. Cartridges, power 1.4S UN0323 II 1.4S...... 110 63............ 62......... None....... 25 kg 100 kg 05 ....... device. Cartridges, power 1.2C UN0381 II 1.2C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... device. Cartridges, safety, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... blank, see Cartridges for weapons, blank (UN 0014). Cartridges, safety, ........... ..................#
Passage 132.......... ............. .......... .......... ........... ........... ........... ....... see Cartridges for weapons, other than blank or Cartridges, power device (UN 0323). Cartridges, signal.. 1.3G UN0054 II 1.3G...... None.......... 62......... None....... Forbidden 75 kg 07 ....... Cartridges, signal.. 1.4G UN0312 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Cartridges, signal.. 1.4S UN0405 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... D Cartridges, small ORM-D .................. ....... None...... 63............ None....... None....... 30 kg gross 30 kg gross A ....... arms. Cartridges, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... sporting, see Cartridges for weapons, other than blank. Cartridges, starter, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... jet engine, see Cartridges, power device. Cases, cartridge, 1.4S UN0055 II 1.4S...... 50 None.......... 62......... None....... 25 kg 100 kg 05 ....... empty with primer. Cases, cartridges, 1.4C UN0379 II 1.4C...... 50 None.......... 62......... None....... Forbidden 75 kg 06 ....... empty with primer. Cases, combustible, 1.4C UN0446 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 06 ....... empty, without primer. Cases, combustible, 1.3C UN0447 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... empty, without primer. Casinghead gasoline ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Gasoline. A W Castor beans or 9 UN2969 II None...... IB8, IP2, IP4 155........... 204........ 240........ No limit No limit E 34, 40 Castor meal or Castor pomace or Castor flake. G Caustic alkali 8 UN1719 II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L A ....... liquids, n.o.s.. TP2, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A ....... TP28 Caustic potash, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Potassium hydroxide etc.#
Passage 133Caustic soda, (etc.) ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sodium hydroxide etc. Cells, containing 4.3 UN3292 II 4.3....... 189........... 189........ 189........ 25 kg gross No limit A ....... sodium. Celluloid, in block, 4.1 UN2000 III 4.1....... None.......... 213........ 240........ 25 kg 100 kg A ....... rods, rolls, sheets, tubes, etc., except scrap. Celluloid, scrap.... 4.2 UN2002 III 4.2....... IB8, IP3 None.......... 213........ 241........ Forbidden Forbidden D ....... Cement, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Adhesives containing flammable liquid. Cerium, slabs, 4.1 UN1333 II 4.1....... IB8, IP2, IP4, None.......... 212........ 240........ 15 kg 50 kg A 74, 91 ingots, or rods. N34 Cerium, turnings or 4.3 UN3078 II 4.3....... A1, IB7, IP2 151........... 212........ 242........ 15 kg 50 kg E ....... gritty powder. Cesium or Caesium... 4.3 UN1407 I 4.3....... A19, IB1, IP1, None.......... 211........ 242........ Forbidden 15 kg D ....... N34, N40 Cesium nitrate or 5.1 UN1451 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Caesium nitrate. D Charcoal briquettes, 4.2 NA1361 III 4.2....... IB8 151........... 213........ 240........ 25 kg 100 kg A 12 shell, screenings, wood, etc.. Charges, bursting, 1.1D UN0457 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... plastics bonded. Charges, bursting, 1.2D UN0458 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... plastics bonded. Charges, bursting, 1.4D UN0459 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 06 ....... plastics bonded. Charges, bursting, 1.4S UN0460 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... plastics bonded. Charges, demolition. 1.1D UN0048 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 03 ....... Charges, depth...... 1.1D UN0056 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 03 ....... Charges, expelling, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... explosive, for fire extinguishers, see Cartridges, power device. Charges, ex#
Passage 134plosive, 1.1D UN0442 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... commercial without detonator. Charges, explosive, 1.2D UN0443 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... commercial without detonator. Charges, explosive, 1.4D UN0444 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 06 ....... commercial without detonator. Charges, explosive, 1.4S UN0445 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... commercial without detonator. Charges, propelling. 1.1C UN0271 II 1.1C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Charges, propelling. 1.3C UN0272 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Charges, propelling. 1.2C UN0415 II 1.2C...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Charges, propelling. 1.4C UN0491 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Charges, propelling, 1.3C UN0242 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... for cannon. Charges, propelling, 1.1C UN0279 II 1.1C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... for cannon. Charges, propelling, 1.2C UN0414 II 1.2C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... for cannon. Charges, shaped, 1.4D UN0237 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 06 ....... flexible, linear. Charges, shaped, 1.1D UN0288 II 1.1D...... 101 None.......... 62......... None....... Forbidden Forbidden 07 ....... flexible, linear. Charges, shaped, 1.1D UN0059 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... without detonator. Charges, shaped, 1.2D UN0439 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... without detonator. Charges, shaped, 1.4D UN0440 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 06 ....... without detonator. Charges, shaped, 1.4S UN0441 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... without detonator. Charges, 1.1D UN0060 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... supplementary explosive. D Chemical kit........ 8 NA1760 II 8......... 154........... 161........ None.#
Passage 135...... 1 L 30 L B 40 Chemical kits....... 9 UN3316 ....... 9......... 15 None.......... None....... None....... 10 kg 10 kg A ....... Chloral, anhydrous, 6.1 UN2075 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L D 40 stabilized. Chlorate and borate 5.1 UN1458 II 5.1....... A9, IB8, IP2, 152........... 212........ 240........ 5 kg 25 kg A 56, 58, mixtures. IP4, N34 106 .................... ........... .................. III 5.1....... A9, IB8, IP3, N34 152........... 213........ 240........ 25 kg 100 kg A 56, 58, 106 Chlorate and 5.1 UN1459 II 5.1....... A9, IB8, IP2, 152........... 212........ 240........ 5 kg 25 kg A 56, 58, magnesium chloride IP4, N34, T4, TP1 106 mixtures. .................... ........... .................. III 5.1....... A9, IB8, IP3, 152........... 213........ 240........ 25 kg 100 kg A 56, 58, N34, T4, TP1 106 Chlorate of potash, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Potassium chlorate. Chlorate of soda, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sodium chlorate. Chlorates, 5.1 UN3210 II 5.1....... IB2, T4, TP1 152........... 202........ 242........ 1 L 5 L B 56, 58, inorganic, aqueous 106 solution, n.o.s.. Chlorates, 5.1 UN1461 II 5.1....... A9, IB6, IP2, N34 152........... 212........ 242........ 5 kg 25 kg A 56, 58, inorganic, n.o.s.. 106 Chloric acid aqueous 5.1 UN2626 II 5.1....... IB2 None.......... 229........ None....... Forbidden Forbidden D 56, 58, solution, with not 106 more than 10 percent chloric acid. Chloride of ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... phosphorus, see Phosphorus trichloride. Chloride of sulfur, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sulfur chloride. Chlorinated lime, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Calcium hypochlorite mixtures, etc. Chlorine............ 2.3 UN1017 ....... 2.3, 8.... 2, B9, B14, T50, None.......... 304........ 314, 315... Forbidden Forbidden D 40, 51, TP19 55, 62, 68, 89, 90#
Passage 136Chlorine azide...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... D Chlorine dioxide, 5.1 NA9191 II 5.1, 6.1.. None.......... 229........ None....... Forbidden Forbidden E ....... hydrate, frozen. Chlorine dioxide Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (not hydrate). Chlorine 2.3 UN2548 ....... 2.3, 5.1, 1, B7, B9, B14 None.......... 304........ 314........ Forbidden Forbidden D 40, 89, pentafluoride. 8. 90 Chlorine trifluoride 2.3 UN1749 ....... 2.3, 5.1, 2, B7, B9, B14 None.......... 304........ 314........ Forbidden Forbidden D 40, 89, 8. 90 Chlorite solution... 8 UN1908 II 8......... A3, A6, A7, B2, 154........... 202........ 242........ 1 L 30 L B 26 IB2, N34, T7, TP2, TP24 .................... ........... .................. III 8......... A3, A6, A7, B2, 154........... 203........ 241........ 5 L 60 L B 26 IB3, N34, T4, TP2, TP24 Chlorites, 5.1 UN1462 II 5.1....... A7, IB6, IP2, N34 152........... 212........ 242........ 5 kg 25 kg A 56, 58, inorganic, n.o.s.. 106 1-Chloro-1,1- 2.1 UN2517 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 difluoroethane or Refrigerant gas R 142b. 3-Chloro-4- 6.1 UN2236 II 6.1....... IB2 None.......... 202........ 243........ 5 L 60 L B 40 methylphenyl isocyanate. 1-Chloro-1,2,2,2- 2.2 UN1021 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... tetrafluoroethaneor Refrigerant gas R 124. 4-Chloro-o-toluidine 6.1 UN1579 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... hydrochloride. 1-Chloro-2,2,2- 2.2 UN1983 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... trifluoroethane or Refrigerant gas R 133a. Chloroacetic acid, 6.1 UN3250 II 6.1, 8.... IB1, T7, TP3 None.......... 202........ 243........ Forbidden Forbidden C 40 molten. Chloroacetic acid, 6.1 UN1751 II 6.1, 8.... A3, A7, IB8, IP4, None.......... 212........ 242........ 15 kg 50 kg A 40 solid. N34 Chloroacetic acid, 6.1 UN1750 II 6.1, 8.... A7, IB2, N34, T7, None.......... 202........ 243........ 1 L 30 L C 40 solution. TP2 Chloroacetone, 6.1 UN1695 I 6.1, 3, 8. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 21, 40, stabilized. B74, N12, N32, 100#
Passage 137N34, T20, TP2, TP13, TP38, TP45 Chloroacetone Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (unstabilized). + Chloroacetonitrile.. 6.1 UN2668 II 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden A 12, 26, B74, IB99, T20, 40 TP2, TP38, TP45 Chloroacetophenone 6.1 UN1697 II 6.1....... A3, IB2, N12, None.......... 202........ 243........ Forbidden 60 L D 12, 40 (CN), liquid. N32, N33, T11, TP2, TP13, TP27 Chloroacetophenone 6.1 UN1697 II 6.1....... A3, IB8, IP2, None.......... 212........ None....... Forbidden 100 kg D 12, 40 (CN), solid. IP4, N12, N32, N33, N34, T7, TP2, TP13 Chloroacetyl 6.1 UN1752 I 6.1, 8.... 2, A3, A6, A7, None.......... 227........ 244........ Forbidden Forbidden D 40 chloride. B3, B8, B9, B14, B32, B74, B77, N34, N43, T20, TP2, TP13, TP38, TP45 Chloroanilines, 6.1 UN2019 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... liquid. Chloroanilines, 6.1 UN2018 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... solid. T7, TP2 Chloroanisidines.... 6.1 UN2233 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Chlorobenzene....... 3 UN1134 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Chlorobenzol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorobenzene. Chlorobenzotrifluori 3 UN2234 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A 40 des. Chlorobenzyl 6.1 UN2235 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... chlorides. Chlorobutanes....... 3 UN1127 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Chlorocresols, 6.1 UN2669 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 12 liquid. Chlorocresols, solid 6.1 UN2669 II 6.1....... IB8, IP2, IP3, T7 None.......... 212........ 242........ 25 kg 100 kg A 12 Chlorodifluorobromom 2.2 UN1974 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... ethane or Refrigerant gas R 12B1. Chlorodifluoromethan 2.2 UN1973 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... e#
Passage 138and chloropentafluoroet hane mixture or Refrigerant gas R 502 with fixed boiling point, with approximately 49 percent chlorodifluorometha ne. Chlorodifluoromethan 2.2 UN1018 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... e or Refrigerant gas R 22. + Chlorodinitrobenzene 6.1 UN1577 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 91 s. T7, TP2 2-Chloroethanal..... 6.1 UN2232 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 Chloroform.......... 6.1 UN1888 III 6.1....... IB3, N36, T7, TP2 153........... 203........ 241........ 60 L 220 L A 40 G Chloroformates, 6.1 UN2742 II 6.1, 8, 3. 5, IB1, T7, TP2 None.......... 202........ 243........ 1 L 30 L A 12, 13, toxic, corrosive, 21, 25, flammable, n.o.s.. 40, 100 G Chloroformates, 6.1 UN3277 II 6.1, 8.... IB2, T8, TP2, None.......... 202........ 243........ 1 L 30 L A 12, 13, toxic, corrosive, TP13, TP28 25, 40 n.o.s.. Chloromethyl 6.1 UN2745 II 6.1, 8.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 30 L A 12, 13, chloroformate. TP13 21, 25, 40, 100#
Passage 139Chloromethyl ethyl 3 UN2354 II 3, 6.1.... IB2, T7, TP1, None.......... 202........ 243........ 1 L 60 L E 40 ether. TP13 Chloronitroanilines. 6.1 UN2237 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... + Chloronitrobenzene, 6.1 UN1578 II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L A ....... ortho, liquid. TP13, TP27 + Chloronitrobenzenes 6.1 UN1578 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... meta or para, solid. T7, TP2 Chloronitrotoluenes, 6.1 UN2433 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... liquid. Chloronitrotoluenes, 6.1 UN2433 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... solid. Chloropentafluoroeth 2.2 UN1020 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... ane or Refrigerant gas R 115. Chlorophenolates, 8 UN2904 III 8......... IB3 154........... 203........ 241........ 5 L 60 L A ....... liquid or Phenolates, liquid. Chlorophenolates, 8 UN2905 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... solid or Phenolates, solid. Chlorophenols, 6.1 UN2021 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... liquid. Chlorophenols, solid 6.1 UN2020 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... Chlorophenyltrichlor 8 UN1753 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 osilane. N34, T7, TP2 + Chloropicrin........ 6.1 UN1580 I 6.1....... 2, B7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 40 B32, B46, B74, T20, TP2, TP13, TP38, TP45 Chloropicrin and 2.3 UN1581 ....... 2.3....... 2, B9, B14, T50 None.......... 193........ 314, 315... Forbidden Forbidden D 25, 40 methyl bromide mixtures. Chloropicrin and 2.3 UN1582 ....... 2.3....... 2, T50 None.......... 193........ 245........ Forbidden Forbidden D 25, 40 methyl chloride mixtures. Chloropicrin ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixture, flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point below 100 degrees F) see Toxic liquids, flammable, etc. Chloropicrin 6.1 UN1583 I 6.1....... 5 None....#
Passage 140...... 201........ 243........ Forbidden Forbidden C 40 mixtures, n.o.s.. .................... ........... .................. II 6.1....... IB2 None.......... 202........ 243........ Forbidden Forbidden C 40 .................... ........... .................. III 6.1....... IB3 153........... 203........ 241........ Forbidden Forbidden C 40 D Chloropivaloyl 6.1 NA9263 I 6.1, 8.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 40 chloride. B74, T20, TP4, TP12, TP13, TP38, TP45 Chloroplatinic acid, 8 UN2507 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... solid. Chloroprene, 3 UN1991 I 3, 6.1.... B57, T14, TP2, None.......... 201........ 243........ Forbidden 30 L D 40 stabilized. TP13 Chloroprene, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... uninhibited. 2-Chloropropane..... 3 UN2356 I 3......... N36, T11, TP2, 150........... 201........ 243........ 1 L 30 L E ....... TP13 3-Chloropropanol-1.. 6.1 UN2849 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... 2-Chloropropene..... 3 UN2456 I 3......... A3, N36, T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... 2-Chloropropionic 8 UN2511 III 8......... IB3, T4, TP2 154........... 203........ 241........ 5 L 60 L A 8 acid. 2-Chloropyridine.... 6.1 UN2822 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Chlorosilanes, 8 UN2986 II 8, 3...... IB2, T11, TP2, None.......... 202........ 243........ 1 L 30 L C 40 corrosive, TP27 flammable, n.o.s.. Chlorosilanes, 8 UN2987 II 8......... B2, IB2, T14, 154........... 202........ 242........ 1 L 30 L C 40 corrosive, n.o.s.. TP2, TP27 Chlorosilanes, 3 UN2985 II 3, 8...... IB1, T11, TP2, None.......... 201........ 243........ 1 L 5 L B 40 flammable, TP13, TP27 corrosive, n.o.s.. Chlorosilanes, water- 4.3 UN2988 I 4.3, 3, 8. A2, T10, TP2, None.......... 201........ 244........ Forbidden 1 L D 21, 28, reactive, TP7, TP13 40, 49, flammable, 100 corrosive, n.o.s.. + Chlorosulfonic acid 8 UN1754 I 8, 6.1.... 2, A3, A6, A10, None.......... 227........ 244........ Forbidden Forbidden C 40 (with or without B9, B10, B14, sulfur trioxide). B32, B74, T20, TP2, TP12, TP38, TP45 Chlorotoluenes...... 3 UN2238 III 3......... B1, IB3, T2, TP1 150........... 203........ 24#
Passage 1412........ 60 L 220 L A ....... Chlorotoluidines 6.1 UN2239 III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A ....... liquid. TP28 Chlorotoluidines 6.1 UN2239 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... solid. Chlorotrifluorometha 2.2 UN2599 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... ne and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluorometh ane. Chlorotrifluorometha 2.2 UN1022 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... ne or Refrigerant gas R 13. Chromic acid 8 UN1755 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L C 40 solution. TP12 .................... ........... .................. III 8......... IB3, T4, TP1, 154........... 203........ 241........ 5 L 60 L C 40 TP12 Chromic anhydride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Chromium trioxide, anhydrous. Chromic fluoride, 8 UN1756 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A 26 solid. Chromic fluoride, 8 UN1757 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Chromium nitrate.... 5.1 UN2720 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A .......#
Passage 142Chromium oxychloride 8 UN1758 I 8......... A3, A6, A7, B10, None.......... 201........ 243........ 0.5 L 2.5 L C 40, 66, N34, T10, TP2, 74, 89, TP12 90 Chromium trioxide, 5.1 UN1463 II 5.1, 8.... IB8, IP4 None.......... 212........ 242........ 5 kg 25 kg A ....... anhydrous. Chromosulfuric acid. 8 UN2240 I 8......... A3, A6, A7, B4, None.......... 201........ 243........ 0.5 L 2.5 L B 40, 66, B6, N34, T10, 74, 89, TP2, TP12, TP13 90 Chromyl chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Chromium oxychloride. Cigar and cigarette ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... lighters, charged with fuel, see Lighters for cigars, cigarettes, etc. Coal briquettes, hot Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Coal gas, compressed 2.3 UN1023 ....... 2.3, 2.1.. 3 None.......... 302........ 314, 315... Forbidden 25 kg D 40 Coal tar 3 UN1136 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... distillates, flammable. .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Coal tar dye, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... corrosive, liquid, n.o.s, see Dyes, liquid or solid, n.o.s. or Dye intermediates, liquid or solid, corrosive, n.o.s.. Coating solution 3 UN1139 I 3......... T11, TP1, TP8, 150........... 201........ 243........ 1 L 30 L E ....... (includes surface TP27 treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining). .................... ........... .................. II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Cobalt naphthenates, 4.1 UN2001 III 4.1....... A19, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A ....... powder. Cobalt resinate, 4.1 UN1318 III 4.1....... A1, A19, IB6 151........... 213........ 240........ 25 kg 100 kg A ....... precipitated.#
Passage 143Coke, hot........... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Collodion, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrocellulose etc. D G Combustible liquid, Combustible NA1993 III None...... IB3,T1, T4, TP1 150........... 203........ 241........ 60 L 220 L A ....... n.o.s.. G Components, 1.2B UN0382 II 1.2B...... 101 None.......... 62......... None....... Forbidden Forbidden 11 ....... explosive train, n.o.s.. G Components, 1.4B UN0383 II 1.4B...... 101 None.......... 62......... None....... Forbidden 75 kg 06 ....... explosive train, n.o.s.. G Components, 1.4S UN0384 II 1.4S...... 101 None.......... 62......... None....... 25 kg 100 kg 05 ....... explosive train, n.o.s.. G Components, 1.1B UN0461 II 1.1B...... 101 None.......... 62......... None....... Forbidden Forbidden 11 ....... explosive train, n.o.s.. Composition B, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexolite, etc. D G Compounds, cleaning 8 NA1760 I 8......... A7, B10, T14, None.......... 201........ 243........ 0.5 L 2.5 L B 40 liquid. TP2, TP9, TP27 .................... ........... .................. II 8......... B2, IB2, N37, 154........... 202........ 242........ 1 L 30 L B 40 T11, TP2, TP27 .................... ........... .................. III 8......... IB3, N37, T7, 154........... 203........ 241........ 5 L 60 L A 40 TP1, TP28 D G Compounds, cleaning 3 NA1993 I 3......... T11, TP1, TP9 150........... 201........ 243........ 1 L 30 L E ....... liquid. .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, B52, IB3, T4, 150........... 203........ 242........ 60 L 220 L A ....... TP1, TP29 D G Compounds, tree 8 NA1760 I 8......... A7, B10, T14, None.......... 201........ 243........ 0.5 L 2.5 L B 40 killing, liquid or TP2, TP9, TP27 Compounds, weed killing, liquid. .................... ........... .................. II 8......... B2, IB2, N37, 154........... 202........ 242........ 1 L 30 L B 40 T11, TP2, TP27 .................... ........... .................. III 8......... IB3,#
Passage 144N37, T7, 154........... 203........ 241........ 5 L 60 L A 40 TP1, TP28 D G Compounds, tree 3 NA1993 I 3......... T11, TP1, TP9 150........... 201........ 243........ 1 L 30 L E ....... killing, liquid or Compounds, weed killing, liquid. .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, B52, IB3, T4, 150........... 203........ 242........ 60 L 220 L A ....... TP1, TP29 D G Compounds, tree 6.1 NA2810 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 killing, liquid or TP27 Compounds, weed killing, liquid. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A 40 TP28 G Compressed gas, 2.1 UN1954 ....... 2.1....... 306........... 302, 305... 314, 315... Forbidden 150 kg D 40 flammable, n.o.s.. G Compressed gas, 2.2 UN1956 ....... 2.2....... 306, 307...... 302, 305... 314, 315... 75 kg 150 kg A ....... n.o.s.. G Compressed gas, 2.2 UN3156 ....... 2.2, 5.1.. 306........... 302........ 314, 315... 75 kg 150 kg D ....... oxidizing, n.o.s.. G I Compressed gas, 2.3 UN3304 ....... 2.3, 8.... 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone A. G I Compressed gas, 2.3 UN3304 ....... 2.3, 8.... 2 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone B. G I Compressed gas, 2.3 UN3304 ....... 2.3, 8.... 3 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone C. G I Compressed gas, 2.3 UN3304 ....... 2.3, 8.... 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone D.#
Passage 145G I Compressed gas, 2.3 UN3305 ....... 2.3, 2.1, 1 None.......... 192........ 245........ Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone A. G I Compressed gas, 2.3 UN3305 ....... 2.3, 2.1, 2 None.......... 302, 305... 314, 315... Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone B. G I Compressed gas, 2.3 UN3305 ....... 2.3, 2.1, 3 None.......... 302, 305... 314, 315... Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone C. G I Compressed gas, 2.3 UN3305 ....... 2.3, 2.1, 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone D. G Compressed gas, 2.3 UN1953 ....... 2.3, 2.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation hazard Zone A. G Compressed gas, 2.3 UN1953 ....... 2.3, 2.1.. 2, B9, B14 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation hazard Zone B. G Compressed gas, 2.3 UN1953 ....... 2.3, 2.1.. 3, B14 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation Hazard Zone C. G Compressed gas, 2.3 UN1953 ....... 2.3, 2.1.. 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation Hazard Zone D. G Compressed gas, 2.3 UN1955 ....... 2.3....... 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone A. G Compressed gas, 2.3 UN1955 ....... 2.3....... 2, B9, B14 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone B. G Compressed gas, 2.3 UN1955 ....... 2.3....... 3, B14 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone C. G Compressed gas, 2.3 UN1955 ....... 2.3....... 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone D. G I Compressed gas, 2.3 UN3306 ....... 2.3, 5.1, 1 None.......... 192........ 244........ Forbidden Forbidden D 40, 89, toxic, oxdizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone A. G I Compressed gas, 2.3 UN3306 ....... 2.3, 5.1, 2 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40, 89, toxic, oxidizing, 8. 90 corrosive, n.o.s. Inhalation#
Passage 146Hazard Zone B. G I Compressed gas, 2.3 UN3306 ....... 2.3, 5.1, 3 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40, 89, toxic, oxidizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone C. G I Compressed gas, 2.3 UN3306 ....... 2.3, 5.1, 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40, 89, toxic, oxidizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone D. G Compressed gas, 2.3 UN3303 ....... 2.3, 5.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone A. G Compressed gas, 2.3 UN3303 ....... 2.3, 5.1.. 2 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone B. G Compressed gas, 2.3 UN3303 ....... 2.3, 5.1.. 3 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone C. G Compressed gas, 2.3 UN3303 ....... 2.3, 5.1.. 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone D. D Consumer commodity.. ORM-D .................. ....... None...... 156, 306...... 156, 306... None....... 30 kg gross 30 kg gross A ....... Contrivances, water- 1.2L UN0248 II 1.2L...... 101 None.......... 62......... None....... Forbidden Forbidden 08 8E, activated, with 14E, burster, expelling 15E, charge or 17E propelling charge. Contrivances, water- 1.3L UN0249 II 1.3L...... 101 None.......... 62......... None....... Forbidden Forbidden 08 8E, activated, with 14E, burster, expelling 15E, charge or 17E propelling charge. Copper acetoarsenite 6.1 UN1585 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Copper acetylide.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Copper amine azide.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Copper arsenite..... 6.1 UN1586 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Copper based 3 UN2776 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202.....#
Passage 147... 243........ 1 L 60 L B 40 TP13, TP27 Copper based 6.1 UN3010 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Copper based 6.1 UN3009 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Copper based 6.1 UN2775 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic.#
Passage 148.................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Copper chlorate..... 5.1 UN2721 II 5.1....... A1, IB8, IP2, IP4 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Copper chloride..... 8 UN2802 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... Copper cyanide...... 6.1 UN1587 II 6.1....... IB8, IP2, IP4 None.......... 204........ 242........ 25 kg 100 kg A 26 Copper selenate, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Copper selenite, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Copper tetramine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrate. A W Copra............... 4.2 UN1363 III 4.2....... IB8, IP3, IP6 None.......... 213........ 241........ Forbidden Forbidden A 13, 19, 48, 119 Cord, detonating, 1.1D UN0065 II 1.1D...... 102 63(a)......... 62......... None....... Forbidden Forbidden 07 ....... flexible. Cord, detonating, 1.4D UN0289 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 06 ....... flexible. Cord detonating or 1.2D UN0102 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Fuse detonating metal clad. Cord, detonating or 1.1D UN0290 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Fuse, detonating metal clad. Cord, detonating, 1.4D UN0104 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 06 ....... mild effect or Fuse, detonating, mild effect metal clad. Cord, igniter....... 1.4G UN0066 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Cordeau detonant ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... fuse, see Cord, detonating, etc; Cord, detonating, flexible. Cordite, see Powder, ........... .................. .......... ............. .......... .......... ........... ........... .......#
Passage 149.... ....... smokeless. G Corrosive liquid, 8 UN3264 I 8......... B10, T14, TP2, None.......... 201........ 243........ 0.5 L 2.5 L B 40 acidic, inorganic, TP27 n.o.s.. .................... ........... .................. II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L B 40 TP2, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A 40 TP28 G Corrosive liquid, 8 UN3265 I 8......... B10, T14, TP2, None.......... 201........ 243........ 0.5 L 2.5 L B 40 acidic, organic, TP27 n.o.s.. .................... ........... .................. II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L B 40 TP2, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A 40 TP28 G Corrosive liquid, 8 UN3266 I 8......... B10, T14, TP2, None.......... 201........ 243........ 0.5 L 2.5 L B 40 basic, inorganic, TP27 n.o.s.. .................... ........... .................. II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L B 40 TP2, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A 40 TP28 G Corrosive liquid, 8 UN3267 I 8......... B10, T14, TP2, None.......... 201........ 243........ 0.5 L 2.5 L B 40 basic, organic, TP27 n.o.s.. .................... ........... .................. II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L B 40 TP2, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A 40 TP28 G Corrosive liquid, 8 UN3301 I 8, 4.2.... B10 None.......... 201........ 243........ 0.5 L 2.5 L D ....... self-heating, n.o.s.. .................... ........... .................. II 8, 4.2.... B2, IB1 154........... 202........ 242........ 1 L 30 L D ....... G Corrosive liquids, 8 UN2920 I 8, 3...... B10, T14, TP2, None.......... 201........ 243........ 0.5 L 2.5 L C 25, 40 flammable, n.o.s.. TP27 .................... ........... .................. II 8, 3...... B2, IB2, T11, None.......... 202........ 243........ 1 L 30 L C 25, 40 TP2, TP27 G Corrosive liquids, 8 UN1760 I 8......... A7, B10, T14, None.......... 201........ 243........ 0.5 L 2.5 L B 40 n.o.s.. TP2#
Passage 150, TP27 .................... ........... .................. II 8......... B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L B 40 TP2, TP27 .................... ........... .................. III 8......... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A 40 TP28 G Corrosive liquids, 8 UN3093 I 8, 5.1.... None.......... 201........ 243........ Forbidden 2.5 L C 89 oxidizing, n.o.s.. .................... ........... .................. II 8, 5.1.... IB2 None.......... 202........ 243........ 1 L 30 L C 89 G Corrosive liquids, 8 UN2922 I 8, 6.1.... A7, B10, T14, None.......... 201........ 243........ 0.5 L 2.5 L B 40 toxic, n.o.s.. TP2, TP13, TP27 .................... ........... .................. II 8, 6.1.... B3, IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L B 40 .................... ........... .................. III 8, 6.1.... IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L B 40 TP28 G Corrosive liquids, 8 UN3094 I 8, 4.3.... None.......... 201........ 243........ Forbidden 1 L E ....... water-reactive, n.o.s.. .................... ........... .................. II 8, 4.3.... None.......... 202........ 243........ 1 L 5 L E ....... G Corrosive solid, 8 UN3260 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg B ....... acidic, inorganic, n.o.s.. .................... ........... .................. II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg B ....... .................... ........... .................. III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... G Corrosive solid, 8 UN3261 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg B ....... acidic, organic, n.o.s.. .................... ........... .................. II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg B ....... .................... ........... .................. III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... G Corrosive solid, 8 UN3262 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg B ....... basic, inorganic, n.o.s.. .................... ........... .................. II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg B ....... .................... ........... .................. III 8......... IB8, IP3 154........#
Passage 151... 213........ 240........ 25 kg 100 kg A ....... G Corrosive solid, 8 UN3263 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg B ....... basic, organic, n.o.s..#
Passage 152.................... ........... .................. II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg B ....... .................... ........... .................. III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... G Corrosive solids, 8 UN2921 I 8, 4.1.... IB6 None.......... 211........ 242........ 1 kg 25 kg B 12, 25 flammable, n.o.s.. .................... ........... .................. II 8, 4.1.... IB8, IP2, IP4 None.......... 212........ 242........ 15 kg 50 kg B 12, 25 G Corrosive solids, 8 UN1759 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg B ....... n.o.s.. .................... ........... .................. II 8......... 128, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A ....... IP4 .................... ........... .................. III 8......... 128, IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... G Corrosive solids, 8 UN3084 I 8, 5.1.... None.......... 211........ 242........ 1 kg 25 kg C ....... oxidizing, n.o.s.. .................... ........... .................. II 8, 5.1.... IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... G Corrosive solids, 8 UN3095 I 8, 4.2.... None.......... 211........ 243........ 1 kg 25 kg C ....... self-heating, n.o.s.. .................... ........... .................. II 8, 4.2.... IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... G Corrosive solids, 8 UN2923 I 8, 6.1.... IB7 None.......... 211........ 242........ 1 kg 25 kg B 40 toxic, n.o.s.. .................... ........... .................. II 8, 6.1.... IB8, IP2, IP4 None.......... 212........ 240........ 15 kg 50 kg B 40 .................... ........... .................. III 8, 6.1.... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg B 40, 95 G Corrosive solids, 8 UN3096 I 8, 4.3.... IB4, IP1 None.......... 211........ 243........ 1 kg 25 kg D ....... water-reactive, n.o.s.. .................... ........... .................. II 8, 4.3.... IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg D ....... D W Cotton.............. 9 NA1365 ....... 9......... 137, IB8, IP2, None.......... None....... None....... No limit No limit A ....... IP4, W41 A W Cotton waste, oily.. 4.2 UN1364 III 4.2....... IB8, IP6 None.......... 213........ None....... Forbidden Forbidden A 54 A I#
Passage 153W Cotton, wet......... 4.2 UN1365 III 4.2....... IB8, IP6 None.......... 204........ 241........ Forbidden Forbidden A ....... Coumarin derivative 3 UN3024 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Coumarin derivative 6.1 UN3026 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Coumarin derivative 6.1 UN3025 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP1, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Coumarin derivative 6.1 UN3027 I 6.1....... IB7, IP1, T14, None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, TP2, TP27 toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 40 T11, TP2, TP27 .................... ........... .................. III 6.1....... IB8, IP3, T7, 153........... 213........ 240........ 100 kg 200 kg A 40 TP1, TP28 Cresols............. 6.1 UN2076 II 6.1, 8.... IB8, IP2, IP4, None.......... 202........ 243........ 1 L 30 L B ....... T7, TP2 Cresylic acid....... 6.1 UN2022 II 6.1, 8.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 30 L B ....... TP13 Crotonaldehyde, 6.1 UN1143 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 40 stabilized. B74, B77, T20, TP2, TP13, TP38, TP45 Crotonic acid liquid 8 UN2823 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A 12 Crotonic acid, solid 8 UN2823 III 8....#
Passage 154..... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A 12 Crotonylene......... 3 UN1144 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... Cupriethylenediamine 8 UN1761 II 8, 6.1.... IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L A ....... solution. .................... ........... .................. III 8, 6.1.... IB3, T7, TP1, 154........... 203........ 242........ 5 L 60 L A 95 TP28 Cutters, cable, 1.4S UN0070 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... explosive. Cyanide or cyanide ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures, dry, see Cyanides, inorganic, solid, n.o.s.. Cyanide solutions, 6.1 UN1935 I 6.1....... B37, T14, TP2, None.......... 201........ 243........ 1 L 30 L B 40, 52 n.o.s.. TP13, TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L A 40, 52 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40, 52 TP13, TP28 Cyanides, inorganic, 6.1 UN1588 I 6.1....... IB7, IP1, N74, None.......... 211........ 242........ 5 kg 50 kg A 52 solid, n.o.s.. N75 .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 52 N74, N75 .................... ........... .................. III 6.1....... IB8, IP3, N74, 153........... 213........ 240........ 100 kg 200 kg A 52 N75 Cyanogen............ 2.3 UN1026 ....... 2.3, 2.1.. 2 None.......... 192........ 245........ Forbidden Forbidden D 40 Cyanogen bromide.... 6.1 UN1889 I 6.1, 8.... A6, A8 None.......... 211........ 242........ 1 kg 15 kg D 40 Cyanogen chloride, 2.3 UN1589 ....... 2.3, 8.... 1 None.......... 192........ 245........ Forbidden Forbidden D 40 stabilized. Cyanuric chloride... 8 UN2670 II 8......... IB8, IP2, IP4 None.......... 212........ 240........ 15 kg 50 kg A 12, 40 Cyanuric triazide... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Cyclobutane......... 2.1 UN2601 ....... 2.1....... 306........... 304........ 314, 315... Forbidden 150 kg B 40 Cyclobutyl 6.1 UN2744 II 6.1, 8, 3. IB1, T7, TP2, None.......#
Passage 155... 202........ 243........ 1 L 30 L A 12, 13, chloroformate. TP13 21, 25, 40, 100#
Passage 1561,5,9- 6.1 UN2518 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 40 Cyclododecatriene. Cycloheptane........ 3 UN2241 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Cycloheptatriene.... 3 UN2603 II 3, 6.1.... IB2, T7, TP1, None.......... 202........ 243........ 1 L 60 L E 40 TP13 Cycloheptene........ 3 UN2242 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Cyclohexane......... 3 UN1145 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Cyclohexanone....... 3 UN1915 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Cyclohexene......... 3 UN2256 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Cyclohexenyltrichlor 8 UN1762 II 8......... A7, B2, IB2, N34, None.......... 202........ 242........ Forbidden 30 L C 40 osilane. T7, TP2, TP13 Cyclohexyl acetate.. 3 UN2243 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Cyclohexyl 6.1 UN2488 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 isocyanate. B74, B77, T20, TP2, TP13, TP38, TP45 Cyclohexyl mercaptan 3 UN3054 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A 40, 95 Cyclohexylamine..... 8 UN2357 II 8, 3...... IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L A 40 Cyclohexyltrichloros 8 UN1763 II 8......... A7, B2, IB2, N34, None.......... 202........ 242........ Forbidden 30 L C 40 ilane. T7, TP2, TP13 Cyclonite and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... cyclotetramethylene tetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite and HMX ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite, see ........... .................. .......... ......#
Passage 157....... .......... .......... ........... ........... ........... ....... Cyclotrimethylenetr initramine, etc. Cyclooctadiene ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... phosphines, see 9- Phosphabicyclononan es. Cyclooctadienes..... 3 UN2520 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Cyclooctatetraene... 3 UN2358 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Cyclopentane........ 3 UN1146 II 3......... IB2, T7, TP1 150........... 202........ 242........ 5 L 60 L E ....... Cyclopentane, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... methyl, see Methylcyclopentane. Cyclopentanol....... 3 UN2244 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Cyclopentanone...... 3 UN2245 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Cyclopentene........ 3 UN2246 II 3......... IB2, IP8, T7, TP2 150........... 202........ 242........ 5 L 60 L E ....... Cyclopropane........ 2.1 UN1027 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 Cyclotetramethylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetranitramine (dry or unphlegmatized) (HMX). Cyclotetramethylenet 1.1D UN0484 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... etranitramine, desensitized or Octogen, desensitized or HMX, desensitized. Cyclotetramethylenet 1.1D UN0226 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... etranitramine, wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass. Cyclotrimethylenetri ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... nitramine and cyclotetramethylene tetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclotrimethylenenit ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... ramine and octogen, mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or d#
Passage 158esensitized etc. Cyclotrimethylenetri ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... nitramine and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclotrimethylenetri 1.1D UN0483 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... nitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized. Cyclotrimethylenetri 1.1D UN0072 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... nitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass. Cymenes............. 3 UN2046 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Dangerous Goods in 9 UN3363 ....... .......... 136 None.......... 222........ None....... No limit No limit A ....... Machinery or Dangerous Goods in Apparatus.#
Passage 159Decaborane.......... 4.1 UN1868 II 4.1, 6.1.. A19, A20, IB6, None.......... 212........ None....... Forbidden 50 kg A ....... IP2 Decahydronaphthalene 3 UN1147 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... n-Decane............ 3 UN2247 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Deflagrating metal 1.3C UN0132 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 5E salts of aromatic nitroderivatives, n.o.s.. Delay electric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... igniter, see Igniters. Depth charges, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Charges, depth. Detonating relays, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Detonators, etc. Detonator 1.1B UN0360 II 1.1B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... assemblies, non- electric for blasting. Detonator 1.4B UN0361 II 1.4B...... 103 63(f), 63(g).. 62......... None....... Forbidden 75 kg 06 ....... assemblies, non- electric, for blasting. Detonator, 1.4S UN0500 II 1.4S...... 63(f), 63(g).. 62......... None....... 25 kg 100 kg 05 ....... assemblies, non- electric for blasting. Detonators, 1.1B UN0030 II 1.1B...... 63(f), 63(g).. 62......... None....... Forbidden Forbidden 11 ....... electric, for blasting. Detonators, 1.4B UN0255 II 1.4B...... 103 63(f), 63(g).. 62......... None....... Forbidden 75 kg 06 ....... electric, for blasting. Detonators, electric 1.4S UN0456 II 1.4S...... 63(f), 63(g).. 62......... None....... 25 kg 100 kg 05 ....... for blasting. Detonators for 1.1B UN0073 II 1.1B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... ammunition. Detonators for 1.2B UN0364 II 1.2B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... ammunition. Detonators for 1.4B UN0365 II 1.4B...... 103 None.......... 62......... None....... Forbidden 75 kg 06 ....... ammunition. Detonators for 1.4S UN0366 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... ammunition. Detonators, non- 1.1B UN0029 II 1.1B...... None.......... 62......... None....... Forbi#
Passage 160dden Forbidden 11 ....... electric, for blasting. Detonators, non- 1.4B UN0267 II 1.4B...... 103 63(f), 63(g).. 62......... None....... Forbidden 75 kg 06 ....... electric, for blasting. Detonators, non- 1.4S UN0455 II 1.4S...... 63(f), 63(g).. 62......... None....... 25 kg 100 kg 5 ....... electric,for blasting. Deuterium, 2.1 UN1957 ....... 2.1....... 306........... 302........ None....... Forbidden 150 kg E 40 compressed. Devices, small, 2.1 UN3150 ....... 2.1....... 306........... 304........ None....... Forbidden 150 kg B 40 hydrocarbon gas powered or Hydrocarbon gas refills for small devices with release device. Di-n-amylamine...... 3 UN2841 III 3, 6.1.... B1, IB3, T4, TP1 150........... 203........ 242........ 60 L 220 L A ....... Di-n-butyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxydicarbonate, with more than 52 percent in solution. Di-n-butylamine..... 8 UN2248 II 8, 3...... IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L A ....... 2,2-Di-(tert- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... butylperoxy) butane, with more than 55 percent in solution. Di-(tert- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... butylperoxy) phthalate, with more than 55 percent in solution. 2,2-Di-(4,4-di-tert- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... butylperoxycyclohex yl) propane, with more than 42 percent with inert solid. Di-2,4- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dichlorobenzoyl peroxide, with more than 75 percent with water. 1,2-Di- 3 UN2372 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... (dimethylamino)etha ne. Di-2-ethylhexyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... phosphoric acid, see Diisooctyl acid phosphate. Di-(1- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... hydroxytetrazole) (dry). Di-(1-naphthoyl) Forbidden .................. .......... ............. .......... .....#
Passage 161..... ........... ........... ........... ....... peroxide. a,a'-Di-(nitroxy) Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methylether. Di-(beta- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitroxyethyl) ammonium nitrate. Diacetone alcohol... 3 UN1148 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Diacetone alcohol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass. Diacetyl, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Butanedione. Diacetyl peroxide, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, or with more than 25 percent in solution. Diallylamine........ 3 UN2359 II 3, 6.1, 8. IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 21, 40, 100 Diallylether........ 3 UN2360 II 3, 6.1.... IB2, N12, T7, None.......... 202........ 243........ 1 L 60 L E 40 TP1, TP13 4,4'-Diaminodiphenyl 6.1 UN2651 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... methane. p-Diazidobenzene.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 1,2-Diazidoethane... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 1,1'- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Diazoaminonaphthale ne. Diazoaminotetrazole Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Diazodinitrophenol Forbidden .................. .......... ............. .......... .......... ........... ...........#
Passage 162Diazodinitrophenol, 1.1A UN0074 II 1.1A...... 111, 117 None.......... 62......... None....... Forbidden Forbidden 12 ....... wetted with not less than 40 percent water or mixture of alcohol and water, by mass. Diazodiphenylmethane Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Diazonium nitrates Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Diazonium Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... perchlorates (dry). 1,3-Diazopropane.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Dibenzyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxydicarbonate, with more than 87 percent with water. Dibenzyldichlorosila 8 UN2434 II 8......... B2, IB2, T7, TP2, 154........... 202........ 242........ 1 L 30 L C 40 ne. TP13 Diborane, compressed 2.3 UN1911 ....... 2.3, 2.1.. 1 None.......... 302........ None....... Forbidden Forbidden D 40, 57 D Diborane mixtures... 2.1 NA1911 ....... 2.1....... 5 None.......... 302........ 245........ Forbidden Forbidden D 40, 57 Dibromoacetylene.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 1,2-Dibromobutan-3- 6.1 UN2648 II 6.1....... IB2 None.......... 202........ 243........ 5 L 60 L B 40 one. Dibromochloropropane 6.1 UN2872 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... A Dibromodifluorometha 9 UN1941 III None...... T11, TP2 155........... 203........ 241........ 100 L 220 L A 25 ne, R12B2. 1,2-Dibromoethane, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethylene dibromide. Dibromomethane...... 6.1 UN2664 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Dibutyl ethers...... 3 UN1149 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Dibutylaminoethanol. 6.1 UN2873 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... N,N'- Forbidden .................. .....#
Passage 163..... ............. .......... .......... ........... ........... ........... ....... Dichlorazodicarbona midine (salts of) (dry). 1,1-Dichloro-1- 6.1 UN2650 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 12, 40 nitroethane. D 3,5-Dichloro-2,4,6- 6.1 NA9264 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden A 40 trifluoropyridine. B74, T20, TP4, TP12, TP13, TP38, TP45 Dichloroacetic acid. 8 UN1764 II 8......... A3, A6, A7, B2, 154........... 202........ 242........ 1 L 30 L A ....... IB2, N34, T8, TP2, TP12 1,3-Dichloroacetone. 6.1 UN2649 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg B 12, 40 Dichloroacetyl 8 UN1765 II 8......... A3, A6, A7, B2, 154........... 202........ 242........ 1 L 30 L D 40 chloride. B6, IB2, N34, T7, TP2 Dichloroacetylene... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... + Dichloroanilines, 6.1 UN1590 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 liquid. + Dichloroanilines, 6.1 UN1590 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 40 solid. T7, TP2 + o-Dichlorobenzene... 6.1 UN1591 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... 2,2'-Dichlorodiethyl 6.1 UN1916 II 6.1, 3.... IB2, N33, N34, None.......... 202........ 243........ 5 L 60 L A ....... ether. T7, TP2 Dichlorodifluorometh 2.2 UN2602 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... ane and difluoroethane azeotropic mixture or Refrigerant gas R 500 with approximately 74 percent dichlorodifluoromet hane. Dichlorodifluorometh 2.2 UN1028 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... ane or Refrigerant gas R 12. Dichlorodimethyl 6.1 UN2249 I 6.1....... None.......... 201........ 243........ Forbidden Forbidden D 40 ether, symmetrical. 1,1-Dichloroethane.. 3 UN2362 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 1,2-Dichloroethane, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethylene dichloride. Dichloroethyl Forbidden .................. .......... ............. .......... .......... ........... ........... .........#
Passage 164.. ....... sulfide. 1,2-Dichloroethylene 3 UN1150 II 3......... IB2, T7, TP2 150........... 202........ 242........ 5 L 60 L B ....... Dichlorofluoromethan 2.2 UN1029 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... e or Refrigerant gas R21. Dichloroisocyanuric 5.1 UN2465 II 5.1....... 28, IB8, IP4 152........... 212........ 240........ 5 kg 25 kg A 13 acid, dry or Dichloroisocyanuric acid salts. Dichloroisopropyl 6.1 UN2490 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L B ....... ether. Dichloromethane..... 6.1 UN1593 III 6.1....... IB3, IP8, N36, 153........... 203........ 241........ 60 L 220 L A ....... T7, TP2 Dichloropentanes.... 3 UN1152 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Dichlorophenyl 6.1 UN2250 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B 25, 40, isocyanates. T7, TP2 48 Dichlorophenyltrichl 8 UN1766 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 orosilane. N34, T7, TP2, TP13 1,2-Dichloropropane. 3 UN1279 II 3......... IB2, N36, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... 1,3-Dichloropropanol- 6.1 UN2750 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 12, 40 2. Dichloropropene and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... propylene dichloride mixture, see 1,2- Dichloropropane. Dichloropropenes.... 3 UN2047 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Dichlorosilane...... 2.3 UN2189 ....... 2.3, 2.1, 2, B9, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 17, 40 8. 1,2-Dichloro-1,1,2,2- 2.2 UN1958 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... tetrafluoroethane or Refrigerant gas R 114. Dichlorovinylchloroa Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... rsine.#
Passage 165Dicycloheptadiene, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Bicyclo [2,2,1] hepta-2,5-diene, stabilized. Dicyclohexylamine... 8 UN2565 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Dicyclohexylammonium 4.1 UN2687 III 4.1....... IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A 48 nitrite. Dicyclopentadiene... 3 UN2048 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Didymium nitrate.... 5.1 UN1465 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... D Diesel fuel......... 3 NA1993 III None...... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 I Diesel fuel......... 3 UN1202 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Diethanol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrosamine dinitrate (dry). Diethoxymethane..... 3 UN2373 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... 3,3-Diethoxypropene. 3 UN2374 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Diethyl carbonate... 3 UN2366 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Diethyl cellosolve, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethylene glycol diethyl ether. Diethyl ether or 3 UN1155 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E 40 Ethyl ether. Diethyl ketone...... 3 UN1156 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Diethyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxydicarbonate, with more than 27 percent in solution. Diethyl sulfate..... 6.1 UN1594 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L C ....... Diethyl sulfide..... 3 UN2375 II 3......... IB2, T7, TP1, None.......... 202........ 243........ 5 L 60 L E ....... TP13 Diethylamine........ 3 UN1154 II 3, 8...... IB2, N34, T7, TP1 None.......... 202........ 243........ 1 L 5 L E 40 2- 8 UN2686 II 8, 3#
Passage 166...... B2, IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L A ....... Diethylaminoethanol. Diethylaminopropylam 3 UN2684 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A ....... ine. + N, N-Diethylaniline. 6.1 UN2432 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Diethylbenzene...... 3 UN2049 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Diethyldichlorosilan 8 UN1767 II 8, 3...... A7, B6, IB2, N34, None.......... 202........ 243........ Forbidden 30 L C 40 e. T7, TP2, TP13 Diethylene glycol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrate. Diethyleneglycol 1.1D UN0075 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 13 21E dinitrate, desensitized with not less than 25 percent non- volatile water- insoluble phlegmatizer, by mass. Diethylenetriamine.. 8 UN2079 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A 40 N,N- 8 UN2685 II 8, 3...... IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L A ....... Diethylethylenediam ine. Diethylgold bromide. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Diethylthiophosphory 8 UN2751 II 8......... B2, IB2,T7, TP2 154........... 202........ 242........ 1 L 39 L A 40 l chloride. Diethylzinc......... 4.2 UN1366 I 4.2, 4.3.. B11, T21, TP2, None.......... 181........ 244........ Forbidden Forbidden D 18 TP7 Difluorochloroethane ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... s, see 1-Chloro-1,1- difluoroethanes. 1,1-Difluoroethane 2.1 UN1030 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 or Refrigerant gas R 152a. 1,1-Difluoroethylene 2.1 UN1959 ....... 2.1....... 306........... 304........ None....... Forbidden 150 kg E 40 or Refrigerant gas R 1132a. Difluoromethane or 2.1 UN3252 ....... 2.1....... T50 306........... 302........ 314, 315... Forbidden 150 kg D 40 Refrigerant gas R 32. Difluorophosphoric 8 UN1768 II 8......... A6, A7, B2, IB2, None.......... 202........ 242........ 1 L 30 L A 40 acid, anhydrous. N5, N34, T8, TP2, TP12 2,3-Dihydropyran.... 3 UN2376 II 3........#
Passage 167. IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... 1,8-Dihydroxy- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 2,4,5,7- tetranitroanthraqui none (chrysamminic acid). Diiodoacetylene..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Diisobutyl ketone... 3 UN1157 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Diisobutylamine..... 3 UN2361 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A ....... Diisobutylene, 3 UN2050 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... isomeric compounds. Diisooctyl acid 8 UN1902 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... phosphate. Diisopropyl ether... 3 UN1159 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E 40 Diisopropylamine.... 3 UN1158 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... Diisopropylbenzene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... hydroperoxide, with more than 72 percent in solution. Diketene, stabilized 6.1 UN2521 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40, 49 B74, T20, TP2, TP13, TP38, TP45 1,2-Dimethoxyethane. 3 UN2252 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... 1,1-Dimethoxyethane. 3 UN2377 II 3......... IB2, T7, TP1 150........... 202........ 242........ 5 L 60 L B ....... Dimethyl carbonate.. 3 UN1161 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Dimethyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... chlorothiophosphate , see Dimethyl thiophosphoryl chloride. 2,5-Dimethyl-2,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dihydroperoxy hexane, with more than 82 percent with water. Dimethyl disulfide.. 3 UN2381 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Dimethyl ether...... 2.1 UN1033 ....... 2.1....... T50 306........... 304.......#
Passage 168. 314, 315... Forbidden 150 kg B 40 Dimethyl-N- 3 UN2266 II 3, 8...... IB2, T7, TP2, None.......... 202........ 243........ 1 L 5 L B 40 propylamine. TP13#
Passage 169Dimethyl sulfate.... 6.1 UN1595 I 6.1, 8.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Dimethyl sulfide.... 3 UN1164 II 3......... IB1, IP8, T7, TP2 None.......... 202........ 242........ 5 L 60 L E 40 Dimethyl 6.1 UN2267 II 6.1, 8.... IB2, T7, TP2 None.......... 202........ 243........ 1 L 30 L B 25 thiophosphoryl chloride. Dimethylamine, 2.1 UN1032 ....... 2.1....... T50 None.......... 304........ 314, 315... Forbidden 150 kg D 40 anhydrous. Dimethylamine 3 UN1160 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... solution. 2- 3 UN2378 II 3, 6.1.... IB2, T7, TP1 None.......... 202........ 243........ 1 L 60 L A 26, 40 Dimethylaminoaceton itrile. 2- 8 UN2051 II 8, 3...... B2, IB2, T7, TP2 154........... 202........ 243........ 1 L 30 L A ....... Dimethylaminoethano l. 2-Dimethylaminoethyl 6.1 UN3302 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L D 25 acrylate. 2-Dimethylaminoethyl 6.1 UN2522 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L B 40 methacrylate. N,N-Dimethylaniline. 6.1 UN2253 II 6.1....... IB1, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... 2,3-Dimethylbutane.. 3 UN2457 II 3......... IB2, T7, TP1 150........... 202........ 242........ 5 L 60 L E ....... 1,3- 3 UN2379 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... Dimethylbutylamine. Dimethylcarbamoyl 8 UN2262 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A 40 chloride. Dimethylcyclohexanes 3 UN2263 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Dimethylcyclohexylam 8 UN2264 II 8, 3...... B2, IB2, T7, TP2 154........... 202........ 243........ 1 L 30 L A 40 ine. Dimethyldichlorosila 3 UN1162 II 3, 8...... B77, IB2, T7, None.......... 202........ 243........ Forbidden Forbidden B 40 ne. TP2, TP13 Dimethyldiethoxysila 3 UN2380 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... ne. Dimethyldioxanes.... 3 UN2707 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... N,N- 3 UN2265 III 3......... B1, IB3, T2, TP#
Passage 1702 150........... 203........ 242........ 60 L 220 L A ....... Dimethylformamide. Dimethylhexane Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dihydroperoxide (dry). Dimethylhydrazine, 6.1 UN2382 I 6.1, 3.... 2, A7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 40 symmetrical. B32, B74, B77, T20, TP2, TP13, TP38, TP45 Dimethylhydrazine, 6.1 UN1163 I 6.1, 3, 8. 2, B7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 21, 38, unsymmetrical. B32, B74, T20, 40, 100 TP2, TP13, TP38, TP45 2,2-Dimethylpropane. 2.1 UN2044 ....... 2.1....... 306........... 304........ 314, 315... Forbidden 150 kg E 40 Dimethylzinc........ 4.2 UN1370 I 4.2, 4.3.. B11, B16, T21, None.......... 181........ 244........ Forbidden Forbidden D 18 TP2, TP7 Dinitro-o-cresol, 6.1 UN1598 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... solid. T7, TP2 Dinitro-o-cresol, 6.1 UN1598 II 6.1....... IB2, IP2, IP4, None.......... 202........ 243........ 5 L 60 L A ....... solution. T7, TP2 1,3-Dinitro-5,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dimethyl hydantoin. Dinitro-7,8- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dimethylglycoluril (dry). 1,3-Dinitro-4,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrosobenzene. 1,4-Dinitro-1,1,4,4- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetramethylolbutane tetranitrate (dry). 2,4-Dinitro-1,3,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trimethylbenzene. Dinitroanilines..... 6.1 UN1596 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 91 T7, TP2 Dinitrobenzenes, 6.1 UN1597 II 6.1....... 11, IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 91 liquid. Dinitrobenzenes, 6.1 UN1597 II 6.1....... 11, IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 91 solid. Dinitrochlorobenzene ........... .................. .......... ............. .......... .......... ...#
Passage 171........ ........... ........... ....... , see Chlorodinitrobenzen e. 1,2-Dinitroethane... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 1,1-Dinitroethane Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Dinitrogen tetroxide 2.3 UN1067 ....... 2.3, 5.1, 1, B7, B14, B45, None.......... 336........ 314........ Forbidden Forbidden D 40, 89, 8. B46, B61, B66, 90 B67, B77, T50, TP21 Dinitroglycoluril or 1.1D UN0489 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Dingu. Dinitromethane...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Dinitrophenol, dry 1.1D UN0076 II 1.1D, 6.1. None.......... 62......... None....... Forbidden Forbidden 10 5E or wetted with less than 15 percent water, by mass. Dinitrophenol 6.1 UN1599 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 36 solutions. .................... ........... .................. III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 36 Dinitrophenol, 4.1 UN1320 I 4.1, 6.1.. 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg E 28, 36 wetted with not N41 less than 15 percent water, by mass. Dinitrophenolates 1.3C UN0077 II 1.3C, 6.1. None.......... 62......... None....... Forbidden Forbidden 10 5E alkali metals, dry or wetted with less than 15 percent water, by mass. Dinitrophenolates, 4.1 UN1321 I 4.1, 6.1.. 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg E 28, 36 wetted with not N41 less than 15 percent water, by mass. Dinitropropylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... glycol. Dinitroresorcinol, 1.1D UN0078 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E dry or wetted with less than 15 percent water, by mass. 2,4- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Dinitroresorcinol (heavy metal salts of) (dry). 4,6- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Dinitroresorcinol (heavy metal salts of) (dry). Di#
Passage 172nitroresorcinol, 4.1 UN1322 I 4.1....... 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg E 28, 36 wetted with not N41 less than 15 percent water, by mass.#
Passage 1733,5-Dinitrosalicylic Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... acid (lead salt) (dry). Dinitrosobenzene.... 1.3C UN0406 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Dinitrosobenzylamidi Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... ne and salts of (dry). 2,2-Dinitrostilbene. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Dinitrotoluenes, 6.1 UN2038 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... liquid. Dinitrotoluenes, 6.1 UN1600 II 6.1....... T7, TP3 None.......... 202........ 243........ Forbidden Forbidden C ....... molten. Dinitrotoluenes, 6.1 UN2038 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... solid. T7, TP2 1,9-Dinitroxy Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... pentamethylene-2,4, 6,8-tetramine (dry). Dioxane............. 3 UN1165 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Dioxolane........... 3 UN1166 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Dipentene........... 3 UN2052 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Diphenylamine 6.1 UN1698 I 6.1....... None.......... 201........ None....... Forbidden Forbidden D 40 chloroarsine. Diphenylchloroarsine 6.1 UN1699 I 6.1....... A8, B14, B32, None.......... 201........ 243........ Forbidden 30 L D 40 , liquid. N33, N34, T14, TP2, TP13, TP27 Diphenylchloroarsine 6.1 UN1699 I 6.1....... A8, B14, B32, None.......... 211........ 242........ Forbidden 15 kg D 40 , solid. IB7, IP1, N33, N34 Diphenyldichlorosila 8 UN1769 II 8......... A7, B2, IB2, N34, None.......... 202........ 242........ Forbidden 30 L C 40 ne. T7, TP2, TP13 Diphenylmethyl 8 UN1770 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg D 40 bromide. Dipicryl sulfide, 1.1D UN0401 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... dry or wetted with less than 10 percent water, by mass. Dipicryl sulfide, 4.1 UN2852 I 4.1....... A2, N41 None.......#
Passage 174... 211........ None....... Forbidden 0.5 kg D 28 wetted with not less than 10 percent water, by mass. Dipicrylamine, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitrodiphenylam ine. Dipropionyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxide, with more than 28 percent in solution. Di-n-propyl ether... 3 UN2384 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Dipropyl ketone..... 3 UN2710 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Dipropylamine....... 3 UN2383 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... G Disinfectant, 8 UN1903 I 8......... A7, B10, T14, None.......... 201........ 243........ 0.5 L 2.5 L B ....... liquid, corrosive, TP2, TP27 n.o.s.. G Disinfectants, 8 UN1903 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L B ....... liquid, corrosive n.o.s.. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... G Disinfectants, 6.1 UN3142 I 6.1....... A4, T14, TP2, None.......... 201........ 243........ 1 L 30 L A 40 liquid, toxic, TP27 n.o.s.. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L A 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A 40 TP28 G Disinfectants, 6.1 UN1601 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 solid, toxic, n.o.s.. .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Disodium 8 UN3253 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... trioxosilicate. G Dispersant gases, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... n.o.s. see Refrigerant gases, n.o.s.. Divinyl ether, 3 UN1167 I 3......... T11, TP2 None.......... 201........ 243........ 1 L 30 L E 40 stabilized. Dodecyltrichlorosila 8 UN1771 II 8......... A7, B2, B6, IB2, None.........#
Passage 175. 202........ 242........ Forbidden 30 L C 40 ne. N34, T7, TP2, TP13 Dry ice, see Carbon ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... dioxide, solid. G Dyes, liquid, 8 UN2801 I 8......... 11, B10, T14, None.......... 201........ 243........ 0.5 L 2.5 L A ....... corrosive, n.o.s. TP2, TP27 or Dye intermediates, liquid, corrosive, n.o.s.. .................... ........... .................. II 8......... 11, B2, IB2, T11, 154........... 202........ 242........ 1 L 30 L A ....... TP2, TP27 .................... ........... .................. III 8......... 11, IB3, T7, TP1, 154........... 203........ 241........ 5 L 60 L A ....... TP28 G Dyes, liquid, toxic, 6.1 UN1602 II 6.1....... IB2 None.......... 202........ 243........ 5 L 60 L A ....... n.o.s. or Dye intermediates, liquid, toxic, n.o.s.. .................... ........... .................. III 6.1....... IB3 153........... 203........ 241........ 60 L 220 L A ....... G Dyes, solid, 8 UN3147 I 8......... IB7, IP1 None.......... 211........ 242........ 1 kg 25 kg A ....... corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s.. .................... ........... .................. II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... .................... ........... .................. III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... G Dyes, solid, toxic, 6.1 UN3143 I 6.1....... A5, IB7, IP1, None.......... 211........ 242........ 5 kg 50 kg A ....... n.o.s. or Dye T14, TP2, TP27 intermediates, solid, toxic, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Dynamite, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Explosive, blasting, type A. Electrolyte (acid or ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... alkali) for batteries, see Battery fluid, acid or Battery fluid, alkali. Elevated temperature 3 UN3256 III 3......... IB1, T3, TP3, None.......... None....... 247..#
Passage 176...... Forbidden Forbidden A ....... liquid, flammable, TP29 n.o.s., with flash point above 37.8 C, at or above its flash point.#
Passage 177Elevated temperature 9 UN3257 III 9......... IB1, T3, TP3, None.......... None....... 247........ Forbidden Forbidden A 85 liquid, n.o.s., at TP29 or above 100 C and below its flash point (including molten metals, molten salts, etc.). Elevated temperature 9 UN3258 III 9......... 247(h) (4).... None....... 247........ Forbidden Forbidden A 85 solid, n.o.s., at or above 240 C, see Sec. 173.247(h)(4). Engines, internal 9 UN3166 ....... 9......... 135 220........... 220........ 220........ Forbidden No limit A ....... combustion, flammable gas powered. Engines, internal 9 UN3166 ....... 9......... 135 220........... 220........ 220........ No limit No limit A ....... combustion, flammable liquid powered. G Environmentally 9 UN3082 III 9......... 8, IB3, T4, TP1, 155........... 203........ 241........ No limit No limit A ....... hazardous TP29 substances, liquid, n.o.s.. G Environmentally 9 UN3077 III 9......... 8, B54, IB8, N20 155........... 213........ 240........ No limit No limit A ....... hazardous substances, solid, n.o.s.. Epibromohydrin...... 6.1 UN2558 I 6.1, 3.... T14, TP2, TP13 None.......... 201........ 243........ Forbidden Forbidden D 40 + Epichlorohydrin..... 6.1 UN2023 II 6.1, 3.... IB2, T7, TP2, None.......... 202........ 243........ 5 L 60 L A 40 TP13 1,2-Epoxy-3- 3 UN2752 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... ethoxypropane. Esters, n.o.s....... 3 UN3272 II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Etching acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquid, n.o.s., see Hydrofluoric acid, solution etc. Ethane.............. 2.1 UN1035 ....... 2.1....... 306........... 304........ 302........ Forbidden 150 kg E 40 D Ethane-Propane 2.1 NA1961 ....... 2.1....... T75, TP5 None.......... 316........ 314, 315... Forbidden Forbidden D 40 mixture, refrigerated liquid. Ethane, refrigerated 2.1 UN1961 ....... 2.1....... T75, TP5 None.......... None....... 315........ Forbidden Forbidden D 40 liquid. Ethanol amine Forbidden .................. .......... ............. .......... .......... ........... ........... ...........#
Passage 178....... dinitrate. Ethanol or Ethyl 3 UN1170 II 3......... 24, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L A ....... alcohol or Ethanol solutions or Ethyl alcohol solutions. .................... ........... .................. III 3......... 24, B1, IB3, T2, 150........... 203........ 242........ 60 L 220 L A ....... TP1 Ethanolamine or 8 UN2491 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Ethanolamine solutions. Ether, see Diethyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... ether. Ethers, n.o.s....... 3 UN3271 II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Ethyl acetate....... 3 UN1173 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Ethyl acrylate, 3 UN1917 II 3......... IB2, T4, TP1, 150........... 202........ 242........ 5 L 60 L B 40 stabilized. TP13 Ethyl alcohol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Ethanol. Ethyl aldehyde, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Acetaldehyde. Ethyl amyl ketone... 3 UN2271 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... N-Ethyl-N- 6.1 UN2274 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... benzylaniline. Ethyl borate........ 3 UN1176 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Ethyl bromide....... 6.1 UN1891 II 6.1....... IB2, IP8, T7, None.......... 202........ 243........ 5 L 60 L B 40, 85 TP2, TP13 Ethyl bromoacetate.. 6.1 UN1603 II 6.1, 3.... IB2, T7, TP2 None.......... 202........ 243........ Forbidden Forbidden D 40 Ethyl butyl ether... 3 UN1179 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Ethyl butyrate...... 3 UN1180 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Ethyl chloride...... 2.1 UN1037 ....... 2.1....... B77, T50 None.......... 322........ 314, 315... Forbid#
Passage 179den 150 kg B 40 Ethyl chloroacetate. 6.1 UN1181 II 6.1, 3.... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Ethyl chloroformate. 6.1 UN1182 I 6.1, 3, 8. 2, A3, A6, A7, None.......... 227........ 244........ Forbidden Forbidden D 21, 40, B9, B14, B32, 100 B74, N34, T20, TP2, TP13, TP38, TP45 Ethyl 2- 3 UN2935 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... chloropropionate. + Ethyl 8 UN2826 II 8, 6.1, 3. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden A 40 chlorothioformate. B74, T20, TP2, TP38, TP45 Ethyl crotonate..... 3 UN1862 II 3......... IB2, T4, TP2 150........... 202........ 242........ 5 L 60 L B ....... Ethyl ether, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Diethyl ether. Ethyl fluoride or 2.1 UN2453 ....... 2.1....... 306........... 304........ 314, 315... Forbidden 150 kg E 40 Refrigerant gas R161. Ethyl formate....... 3 UN1190 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Ethyl hydroperoxide. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Ethyl isobutyrate... 3 UN2385 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... + Ethyl isocyanate.... 3 UN2481 I 3, 6.1.... 1, A7, B9, B14, None.......... 226........ 244........ Forbidden Forbidden D 40 B30, B72, T22, TP2, TP13, TP38, TP44 Ethyl lactate....... 3 UN1192 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Ethyl mercaptan..... 3 UN2363 I 3......... T11, TP2, TP13 None.......... 201........ 243........ Forbidden 30 L E 95, 102 Ethyl methacrylate.. 3 UN2277 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Ethyl methyl ether.. 2.1 UN1039 ....... 2.1....... None.......... 201........ 314, 315... Forbidden 150 kg B 40 Ethyl methyl ketone 3 UN1193 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... or Methyl ethyl ketone. Ethyl nitrite 3 UN1194 I 3, 6.1.... None.......... 201........ None....... Forbidden Forbidden E 40, 105 solutions. Ethyl orthoformate.. 3 UN2524 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Ethyl oxalate.....#
Passage 180.. 6.1 UN2525 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Ethyl perchlorate... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... .......#
Passage 181D Ethyl 6.1 NA2927 I 6.1, 8.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 phosphonothioic B74, T20, TP4, dichloride, TP12, TP13, TP38, anhydrous. TP45 D Ethyl phosphonous 6.1 NA2845 I 6.1, 4.2.. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 18 dichloride, B74, T20, TP4, anhydrous TP12, TP13, TP38, pyrophoric liquid. TP45 D Ethyl 6.1 NA2927 I 6.1, 8.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 phosphorodichlorida B74, T20, TP4, te. TP12, TP13, TP38, TP45 Ethyl propionate.... 3 UN1195 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Ethyl propyl ether.. 3 UN2615 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Ethyl silicate, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Tetraethyl silicate. Ethylacetylene, 2.1 UN2452 ....... 2.1....... None.......... 304........ 314, 315... Forbidden 150 kg B 40 stabilized. Ethylamine.......... 2.1 UN1036 ....... 2.1....... B77, T50 None.......... 321........ 314, 315... Forbidden 150 kg D 40 Ethylamine, aqueous 3 UN2270 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 solution with not less than 50 percent but not more than 70 percent ethylamine. N-Ethylaniline...... 6.1 UN2272 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... 2-Ethylaniline...... 6.1 UN2273 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Ethylbenzene........ 3 UN1175 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... N- 6.1 UN2753 III 6.1....... IB3, T7, TP1 153........... 203........ 241........ 60 L 220 L A ....... Ethylbenzyltoluidin es liquid. N- 6.1 UN2753 III 6.1....... IB8, IP3, T7, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... Ethylbenzyltoluidin es solid. 2-Ethylbutanol...... 3 UN2275 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Ethylbutyl acetate.. 3 UN1177 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... 2-Ethylbutyraldehyde 3 UN1178 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Ethyldichloroarsine#
Passage 182. 6.1 UN1892 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 Ethyldichlorosilane. 4.3 UN1183 I 4.3, 8, 3. A2, A3, A7, N34, None.......... 201........ 244........ Forbidden 1 L D 21, 28, T10, TP2, TP7, 40, 49, TP13 100 Ethylene, acetylene 2.1 UN3138 ....... 2.1....... T75, TP5 None.......... 304........ 314, 315... Forbidden Forbidden D 40 and propylene in mixture, refrigerated liquid with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene. Ethylene 6.1 UN1135 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 chlorohydrin. B74, T20, TP2, TP13, TP38, TP45 Ethylene, compressed 2.1 UN1962 ....... 2.1....... 306........... 304........ 302........ Forbidden 150 kg E 40 Ethylene diamine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diperchlorate. Ethylene dibromide.. 6.1 UN1605 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Ethylene dibromide ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... and methyl bromide liquid mixtures, see Methyl bromide and ethylene dibromide, liquid mixtures. Ethylene dichloride. 3 UN1184 II 3, 6.1.... IB2, T7, TP1 None.......... 202........ 243........ 1 L 60 L B 40 Ethylene glycol 3 UN1153 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... diethyl ether. Ethylene glycol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrate. Ethylene glycol 3 UN1171 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... monoethyl ether. Ethylene glycol 3 UN1172 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... monoethyl ether acetate. Ethylene glycol 3 UN1188 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... monomethyl ether. Ethylene glycol 3 UN1189 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... monomethyl ether acetate. Ethylene oxide and 2.3 UN3300 ....... 2.3, 2.1.. 4#
Passage 183None.......... 304........ 314, 315... Forbidden Forbidden D 40 carbon dioxide mixture with more than 87 percent ethylene oxide. Ethylene oxide and 2.1 UN1041 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 25 kg B 40 carbon dioxide mixtures with more than 9 percent but not more than 87 percent ethylene oxide. Ethylene oxide and 2.2 UN1952 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... carbon dioxide mixtures with not more than 9 percent ethylene oxide. Ethylene oxide and 2.2 UN3297 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... chlorotetrafluoroet hane mixture with not more than 8.8 percent ethylene oxide. Ethylene oxide and 2.2 UN3070 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... dichlorodifluoromet hane mixture, with not more than 12.5 percent ethylene oxide. Ethylene oxide and 2.2 UN3298 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... pentafluoroethane mixture with not more than 7.9 percent ethylene oxide.#
Passage 184Ethylene oxide and 3 UN2983 I 3, 6.1.... 5, A11, N4, N34, None.......... 201........ 243........ Forbidden 30 L E 40 propylene oxide T14, TP2, TP7, mixtures, with not TP13 more than 30 percent ethylene oxide. Ethylene oxide and 2.2 UN3299 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide. Ethylene oxide or 2.3 UN1040 ....... 2.3, 2.1.. 4, T50, TP20 None.......... 323........ 323........ Forbidden 25 kg D 40 Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C. Ethylene, 2.1 UN1038 ....... 2.1....... T75, TP5 None.......... 316........ 318, 319... Forbidden Forbidden D 40 refrigerated liquid (cryogenic liquid). Ethylenediamine..... 8 UN1604 II 8, 3...... IB2, T7, TP2 154........... 202........ 243........ 1 L 30 L A 40 Ethyleneimine, 6.1 UN1185 I 6.1, 3.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 stabilized. B72, B77, N25, N32, T22, TP2, TP13, TP38, TP44 Ethylhexaldehyde, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Octyl aldehydes etc. 2-Ethylhexyl 6.1 UN2748 II 6.1, 8.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 30 L A 12, 13, chloroformate. TP13 21, 25, 40, 100 2-Ethylhexylamine... 3 UN2276 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A 40 Ethylphenyldichloros 8 UN2435 II 8......... A7, B2, IB2, N34, None.......... 202........ 242........ Forbidden 30 L C ....... ilane. T7, TP2, TP13 1-Ethylpiperidine... 3 UN2386 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... N-Ethyltoluidines... 6.1 UN2754 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Ethyltrichlorosilane 3 UN1196 II 3, 8...... A7, IB1, N34, T7, None.......... 202........ 243........ 1 L 5 L B 40 TP2, TP13 Etiologic agent, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Infectious substances, etc. Explosive articles, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Articles, explosive , n.o.s. etc. Explosive, blasting, 1.1D UN0081 II 1.1D...... None.......... 62......... N#
Passage 185one....... Forbidden Forbidden 10 21E type A. Explosive, blasting, 1.1D UN0082 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... type B. Explosive, blasting, 1.5D UN0331 II 1.5D...... 105, 106 None.......... 62......... None....... Forbidden Forbidden 10 ....... type B or Agent blasting, Type B. Explosive, blasting, 1.1D UN0083 II 1.1D...... 123 None.......... 62......... None....... Forbidden Forbidden 10 22E type C. Explosive, blasting, 1.1D UN0084 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... type D. Explosive, blasting, 1.1D UN0241 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 19E type E. Explosive, blasting, 1.5D UN0332 II 1.5D...... 105, 106 None.......... 62......... None....... Forbidden Forbidden 10 ....... type E or Agent blasting, Type E. Explosive, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... forbidden. See Sec. 173.54. Explosive ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... substances, see Substances, explosive, n.o.s. etc. Explosives, slurry, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Explosive, blasting, type E. Explosives, water ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... gels, see Explosive, blasting, type E. Extracts, aromatic, 3 UN1169 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... liquid. .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Extracts, flavoring, 3 UN1197 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... liquid. .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Fabric with animal ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... or vegetable oil, see Fibers or fabrics, etc. Ferric arsenate..... 6.1 UN1606 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg#
Passage 186A ....... Ferric arsenite..... 6.1 UN1607 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Ferric chloride, 8 UN1773 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... anhydrous. Ferric chloride, 8 UN2582 III 8......... B15, IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... solution. Ferric nitrate...... 5.1 UN1466 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Ferrocerium......... 4.1 UN1323 II 4.1....... 59, A19, IB8, 151........... 212........ 240........ 15 kg 50 kg A ....... IP2, IP4 Ferrosilicon, with 4.3 UN1408 III 4.3, 6.1.. A1, A19, IB8, IP4 151........... 213........ 240........ 25 kg 100 kg A 13, 40, 30 percent or more 85, 103 but less than 90 percent silicon. Ferrous arsenate.... 6.1 UN1608 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... D Ferrous chloride, 8 NA1759 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... solid. D Ferrous chloride, 8 NA1760 II 8......... B3, IB2, T11, 154........... 202........ 242........ 1 L 30 L B 40 solution. TP2, TP27 Ferrous metal 4.2 UN2793 III 4.2....... A1, A19, IB8, None.......... 213........ 241........ 25 kg 100 kg A ....... borings or Ferrous IP3, IP6 metal shavings or Ferrous metal turnings or Ferrous metal cuttings in a form liable to self- heating. Fertilizer 2.2 UN1043 ....... 2.2....... 306........... 304........ 314, 315... Forbidden 150 kg E 40 ammoniating solution with free ammonia. A W Fibers or Fabrics, 4.2 UN1373 III 4.2....... 137, IB8, IP3 None.......... 213........ 241........ Forbidden Forbidden A ....... animal or vegetable or Synthetic, n.o.s. with animal or vegetable oil. Fibers or Fabrics 4.1 UN1353 III 4.1....... A1, IB8, IP3 None.......... 213........ 240........ 25 kg 100 kg D ....... impregnated with weakly nitrated nitrocellulose, n.o.s..#
Passage 187Films, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrocellulose base, from which gelatine has been removed; film scrap, see Celluloid scrap. Films, 4.1 UN1324 III 4.1....... None.......... 183........ None....... 25 kg 100 kg D 91 nitrocellulose base, gelatine coated (except scrap). Fire extinguisher 8 UN1774 II 8......... N41 154........... 202........ None....... 1 L 30 L A ....... charges, corrosive liquid. Fire extinguisher ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... charges, expelling, explosive, see Cartridges, power device. Fire extinguishers 2.2 UN1044 ....... 2.2....... 18, 110 309........... 309........ None....... 75 kg 150 kg A ....... containing compressed or liquefied gas. Firelighters, solid 4.1 UN2623 III 4.1....... A1, A19 None.......... 213........ None....... 25 kg 100 kg A ....... with flammable liquid. Fireworks........... 1.1G UN0333 II 1.1G...... 108 None.......... 62......... None....... Forbidden Forbidden 07 ....... Fireworks........... 1.2G UN0334 II 1.2G...... 108 None.......... 62......... None....... Forbidden Forbidden 07 ....... Fireworks........... 1.3G UN0335 II 1.3G...... 108 None.......... 62......... None....... Forbidden Forbidden 07 ....... Fireworks........... 1.4G UN0336 II 1.4G...... 108 None.......... 62......... None....... Forbidden 75 kg 06 ....... Fireworks........... 1.4S UN0337 II 1.4S...... 108 None.......... 62......... None....... 25 kg 100 kg 05 ....... First aid kits...... 9 UN3316 ....... 9......... 15 None.......... None....... None....... 10 kg 10 kg A ....... W Fish meal, 9 UN2216 III None...... IB8 155........... 218........ 218........ No limit No limit A 88 stabilized or Fish scrap, stabilized. Fish meal, 4.2 UN1374 II 4.2....... A1, A19, IB8, IP2 None.......... 212........ 241........ 15 kg 50 kg A 119, unstablized or Fish 120 scrap, unstabilized. Fissile radioactive ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... materials, see Radioactive material, fissile, n.o.s.. Flammable compressed ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... gas, see Compressed or Liquefied gas, flammable, etc. Flammable#
Passage 188compressed ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... gas (small receptacles not fitted with a dispersion device, not refillable), see Receptacles, etc. Flammable gas in ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... lighters, see Lighters or lighter refills, cigarettes, containing flammable gas. G Flammable liquid, 3 UN3286 I 3, 6.1, 8. T14, TP2, TP13, None.......... 201........ 243........ Forbidden 2.5 L E 21, 40, toxic, corrosive, TP27 100 n.o.s.. .................... ........... .................. II 3, 6.1, 8. IB2, T11, TP2, None.......... 202........ 243........ 1 L 5 L B 21, 40, TP13, TP27 100 G Flammable liquids, 3 UN2924 I 3, 8...... T14, TP2 None.......... 201........ 243........ 0.5 L 2.5 L E 40 corrosive, n.o.s.. .................... ........... .................. II 3, 8...... IB2, T11, TP2, None.......... 202........ 243........ 1 L 5 L B 40 TP27 .................... ........... .................. III 3, 8...... B1, IB3, T7, TP1, 150........... 203........ 242........ 5 L 60 L A 40 TP28 G Flammable liquids, 3 UN1993 I 3......... T11, TP1 150........... 201........ 243........ 1 L 30 L E ....... n.o.s.. .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, B52, IB3, T4, 150........... 203........ 242........ 60 L 220 L A ....... TP1, TP29 G Flammable liquids, 3 UN1992 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L E 40 toxic, n.o.s.. TP27 .................... ........... .................. II 3, 6.1.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13 .................... ........... .................. III 3, 6.1.... B1, IB3, T7, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP28 G Flammable solid, 4.1 UN3180 II 4.1, 8.... A1, IB6, IP2 151........... 212........ 242........ 15 kg 50 kg D 40 corrosive, inorganic, n.o.s.. .................... ........... .................. III 4.1, 8.... A1, IB6 151........... 213........ 242........ 25 kg 100 kg D 40 G Flammable solid, 4.1 UN3178 II 4.1....... A1, IB8, IP2, IP4 151........... 212........ 240........ 15 kg#
Passage 18950 kg B ....... inorganic, n.o.s.. .................... ........... .................. III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg B ....... G Flammable solid, 4.1 UN3176 II 4.1....... IB1, T3, TP3, 151........... 212........ 240........ Forbidden Forbidden C ....... organic, molten, TP26 n.o.s.. .................... ........... .................. III 4.1....... IB1, T1, TP3, 151........... 213........ 240........ Forbidden Forbidden C ....... TP26 G Flammable solid, 4.1 UN3097 II 4.1, 5.1.. 131 None.......... 214........ 214........ Forbidden Forbidden E 40 oxidizing, n.o.s.. .................... ........... .................. III 4.1, 5.1.. 131 None.......... 214........ 214........ Forbidden Forbidden D 40 G Flammable solid, 4.1 UN3179 II 4.1, 6.1.. A1, IB6, IP2 151........... 212........ 242........ 15 kg 50 kg B 40 toxic, inorganic, n.o.s.. .................... ........... .................. III 4.1, 6.1.. A1, IB6 151........... 213........ 242........ 25 kg 100 kg B 40 G Flammable solids, 4.1 UN2925 II 4.1, 8.... A1, IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg D 40 corrosive, organic, n.o.s.. .................... ........... .................. III 4.1, 8.... A1, IB6 151........... 213........ 242........ 25 kg 100 kg D 40 G Flammable solids, 4.1 UN1325 II 4.1....... A1, IB8, IP2, 151........... 212........ 240........ 15 kg 50 kg B ....... organic, n.o.s.. IP4, T3, TP1 .................... ........... .................. III 4.1....... A1, IB8, IP3, T1, 151........... 213........ 240........ 25 kg 100 kg B ....... TP1 G Flammable solids, 4.1 UN2926 II 4.1, 6.1.. A1, IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg B 40 toxic, organic, n.o.s.. .................... ........... .................. III 4.1, 6.1.. A1, IB6 151........... 213........ 242........ 25 kg 100 kg B 40 Flares, aerial...... 1.3G UN0093 II 1.3G...... None.......... 62......... None....... Forbidden 75 kg 07 ....... Flares, aerial...... 1.4G UN0403 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Flares, aerial...... 1.4S UN0404 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 .......#
Passage 190Flares, aerial...... 1.1G UN0420 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Flares, aerial...... 1.2G UN0421 II 1.2G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Flares, airplane, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Flares, aerial. Flares, signal, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Cartridges, signal. Flares, surface..... 1.3G UN0092 II 1.3G...... None.......... 62......... None....... Forbidden 75 kg 07 ....... Flares, surface..... 1.1G UN0418 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Flares, surface..... 1.2G UN0419 II 1.2G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Flares, water- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... activated, see Contrivances, water- activated, etc. Flash powder........ 1.1G UN0094 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 15 ....... Flash powder........ 1.3G UN0305 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 15 ....... Flue dusts, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... poisonous, see Arsenical dust. Fluoric acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrofluoric acid, etc. Fluorine, compressed 2.3 UN1045 ....... 2.3, 5.1, 1 None.......... 302........ None....... Forbidden Forbidden D 40, 89, 8. 90 Fluoroacetic acid... 6.1 UN2642 I 6.1....... IB7, IP1 None.......... 211........ 242........ 1 kg 15 kg E ....... Fluoroanilines...... 6.1 UN2941 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Fluorobenzene....... 3 UN2387 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Fluoroboric acid.... 8 UN1775 II 8......... A6, A7, B2, B15, 154........... 202........ 242........ 1 L 30 L A ....... IB2, N3, N34, T7, TP2 Fluorophosphoric 8 UN1776 II 8......... A6, A7, B2, IB2, None.......... 202........ 242........ 1 L 30 L A ....... acid anhydrou#
Passage 191s. N3, N34, T8, TP2, TP12 Fluorosilicates, 6.1 UN2856 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 n.o.s.. Fluorosilicic acid.. 8 UN1778 II 8......... A6, A7, B2, B15, None.......... 202........ 242........ 1 L 30 L A ....... IB2, N3, N34, T8, TP2, TP12 Fluorosulfonic acid. 8 UN1777 I 8......... A3, A6, A7, A10, None.......... 201........ 243........ 0.5 L 2.5 L D 40 B6, B10, N3, T10, TP2, TP12 Fluorotoluenes...... 3 UN2388 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 Forbidden materials. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... See Sec. 173.21. Formaldehyde, 3 UN1198 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A 40 solutions, flammable. Formaldehyde, 8 UN2209 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... solutions, with not less than 25 percent formaldehyde. Formalin, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Formaldehyde, solutions. Formic acid......... 8 UN1779 II 8......... B2, B28, IB2, T7, 154........... 202........ 242........ 1 L 30 L A 40 TP2 Fracturing devices, 1.1D UN0099 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... explosive, without detonators for oil wells. Fuel, aviation, 3 UN1863 I 3......... T11, TP1, TP8 150........... 201........ 243........ 1 L 30 L E ....... turbine engine. .................... ........... .................. II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... D Fuel oil (No. 1, 2, 3 NA1993 III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... 4, 5, or 6). TP29 Fuel system ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... components (including fuel control units (FCU), carburetors, fuel lines, fuel pumps) see Dangerous Goods in Apparatus or Dangerous Goods in Machinery. Fulminate of mercury Forbidden .................. .......... ............. .......... .......... ........... ........... ..#
Passage 192......... ....... (dry). Fulminate of ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mercury, wet, see Mercury fulminate, etc. Fulminating gold.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Fulminating mercury. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Fulminating platinum Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Fulminating silver.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Fulminic acid....... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Fumaryl chloride.... 8 UN1780 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L C 8, 40 Fumigated lading, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Secs. 172.302(g), 173.9 and 176.76(h). Fumigated transport ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... vehicle or freight container see 173.9. Furaldehydes........ 6.1 UN1199 II 6.1, 3.... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Furan............... 3 UN2389 I 3......... T12, TP2, TP13 None.......... 201........ 243........ 1 L 30 L E 40 Furfuryl alcohol.... 6.1 UN2874 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 26, 74 Furfurylamine....... 3 UN2526 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A 40 Fuse, detonating, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... metal clad, see Cord, detonating, metal clad. Fuse, detonating, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mild effect, metal clad, see Cord, detonating, mild effect, metal clad. Fuse, igniter 1.4G UN0103 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... tubular metal clad. Fuse, non-detonating 1.3G#
Passage 193UN0101 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... instantaneous or quickmatch.#
Passage 194Fuse, safety........ 1.4S UN0105 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... D Fusee (railway or 4.1 NA1325 II 4.1....... None.......... 184........ None....... 15 kg 50 kg B ....... highway). Fusel oil........... 3 UN1201 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Fuses, tracer, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Tracers for ammunition. Fuzes, combination, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... percussion and time, see Fuzes, detonating (UN0257, UN0367); Fuzes, igniting (UN0317, UN0368). Fuzes, detonating... 1.1B UN0106 II 1.1B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... Fuzes, detonating... 1.2B UN0107 II 1.2B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... Fuzes, detonating... 1.4B UN0257 II 1.4B...... 116 None.......... 62......... None....... Forbidden 75 kg 06 ....... Fuzes, detonating... 1.4S UN0367 II 1.4S...... 116 None.......... 62......... None....... 25 kg 100 kg 05 ....... Fuzes, detonating, 1.1D UN0408 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... with protective features. Fuzes, detonating, 1.2D UN0409 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... with protective features. Fuzes, detonating, 1.4D UN0410 II 1.4D...... 116 None.......... 62......... None....... Forbidden 75 kg 06 ....... with protective features. Fuzes, igniting..... 1.3G UN0316 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Fuzes, igniting..... 1.4G UN0317 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Fuzes, igniting..... 1.4S UN0368 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Galactsan trinitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Gallium............. 8 UN2803 III 8......... None.......... 162........ 240........ 20 kg 20 kg B 48 Gas cartridges, 2.1 UN2037 ....... 2.1.....#
Passage 195.. 306........... 304........ None....... 1 kg 15 kg B 40 (flammable) without a release device, non-refillable. Gas generator 2.2 .................. ....... 2.2....... None.......... 335........ None....... 75 kg 150 kg A ....... assemblies (aircraft), containing a non- flammable non-toxic gas and a propellant cartridge. D Gas identification 2.3 NA9035 ....... 2.3....... 6 None.......... 194........ None....... Forbidden Forbidden D ....... set. Gas oil............. 3 UN1202 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... G Gas, refrigerated 2.1 UN3312 ....... 2.1....... T75, TP5 None.......... 316........ 318........ Forbidden Forbidden D 40 liquid, flammable, n.o.s. (cryogenic liquid). G Gas, refrigerated 2.2 UN3158 ....... 2.2....... T75, TP5 320........... 316........ 318........ 50 kg 500 kg D ....... liquid, n.o.s. (cryogenic liquid). G Gas, refrigerated 2.2 UN3311 ....... 2.2, 5.1.. T75, TP5 320........... 316........ 318........ Forbidden Forbidden D ....... liquid, oxidizing, n.o.s. (cryogenic liquid). Gas sample, non- 2.1 UN3167 ....... 2.1....... 306........... 302, 304... None....... 1 L 5 L D ....... pressurized, flammable, n.o.s., not refrigerated liquid. Gas sample, non- 2.3 UN3168 ....... 2.3, 2.1.. 306........... 302........ None....... Forbidden 1 L D ....... pressurized, toxic, flammable, n.o.s., not refrigerated liquid. Gas sample, non- 2.3 UN3169 ....... 2.3....... 306........... 302, 304... None....... Forbidden 1 L D ....... pressurized, toxic, n.o.s., not refrigerated liquid. D Gasohol gasoline 3 NA1203 II 3......... 150........... 202........ 242........ 5 L 60 L E ....... mixed with ethyl alcohol, with not more than 20 percent alcohol. Gasoline............ 3 UN1203 II 3......... B33, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Gasoline, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... casinghead, see Gasoline. Gelatine, blasting, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Explosive, blasting, type A. Gelatine dynamites, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Explosive, blasting, type A. Germane............. 2.3 UN2192 ......#
Passage 196. 2.3, 2.1.. 2 None.......... 192........ 245........ Forbidden Forbidden D 40 Glycerol-1,3- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrate. Glycerol gluconate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trinitrate. Glycerol lactate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trinitrate. Glycerol alpha- 6.1 UN2689 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... monochlorohydrin. Glyceryl trinitrate, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Nitroglycerin, etc. Glycidaldehyde...... 3 UN2622 II 3, 6.1.... IB2, IP8, T7, TP1 150........... 202........ 243........ 1 L 60 L A 40 Grenades, hand or 1.1D UN0284 II 1.1D...... ............. 62......... None....... Forbidden Forbidden 07 ....... rifle, with bursting charge. Grenades, hand or 1.2D UN0285 II 1.2D...... ............. 62......... None....... Forbidden Forbidden 07 ....... rifle, with bursting charge. Grenades, hand or 1.1F UN0292 II 1.1F...... ............. 62......... None....... Forbidden Forbidden 08 ....... rifle, with bursting charge. Grenades, hand or 1.2F UN0293 II 1.2F...... ............. 62......... None....... Forbidden Forbidden 08 ....... rifle, with bursting charge. Grenades, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... illuminating, see Ammunition, illuminating, etc. Grenades, practice, 1.4S UN0110 II 1.4S...... ............. 62......... None....... 25 kg 100 kg 05 ....... hand or rifle. Grenades, practice, 1.3G UN0318 II 1.3G...... ............. 62......... None....... Forbidden Forbidden 07 ....... hand or rifle. Grenades, practice, 1.2G UN0372 II 1.2G...... ............. 62......... None....... Forbidden Forbidden 07 ....... hand or rifle. Grenades practice 1.4G UN0452 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 06 ....... Hand or rifle. Grenades, smoke, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Ammunition, smoke, etc. Guanidine nitrate... 5.1 UN1467 III 5.#
Passage 1971....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 73 Guanyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrosaminoguanylid ene hydrazine (dry).#
Passage 198Guanyl 1.1A UN0113 II 1.1A...... 111, 117 None.......... 62......... None....... Forbidden Forbidden 12 ....... nitrosaminoguanylid ene hydrazine, wetted with not less than 30 percent water, by mass. Guanyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrosaminoguanylte trazene (dry). Guanyl 1.1A UN0114 II 1.1A...... 111, 117 None.......... 62......... None....... Forbidden Forbidden 12 ....... nitrosaminoguanylte trazene, wetted or Tetrazene, wetted with not less than 30 percent water or mixture of alcohol and water, by mass. Gunpowder, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... compressed or Gunpowder in pellets, see Black powder (UN 0028). Gunpowder, granular ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... or as a meal, see Black powder (UN 0027). Hafnium powder, dry. 4.2 UN2545 I 4.2....... None.......... 211........ 242........ Forbidden Forbidden D ....... .................... ........... .................. II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg D ....... IP2, N34 .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg D ....... Hafnium powder, 4.1 UN1326 II 4.1....... A6, A19, A20, None.......... 212........ 241........ 15 kg 50 kg E ....... wetted with not IB6, IP2, N34 less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Hand signal device, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Signal devices, hand. Hazardous ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... substances, liquid or solid, n.o.s., see Environmentally hazardous substances, etc. D G Hazardous waste, 9 NA3082 III 9......... IB3, T2, TP1 155........... 203........ 241........ No limit No limit A ....... liquid, n.o.s.. D G Hazardous waste, 9 NA3077 III 9......... B54, IB8, IP2 155........... 213........ 240........ No limit No limit A ....... solid, n.o.s..#
Passage 199Heating oil, light.. 3 UN1202 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Helium, compressed.. 2.2 UN1046 ....... 2.2....... 306........... 302........ 302, 314... 75 kg 150 kg A 85 Helium-oxygen ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixture, see Rare gases and oxygen mixtures. Helium, refrigerated 2.2 UN1963 ....... 2.2....... T75, TP5 320........... 316........ 318........ 50 kg 500 kg B ....... liquid (cryogenic liquid). Heptafluoropropane 2.2 UN3296 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... or Refrigerant gas R 227. n-Heptaldehyde...... 3 UN3056 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Heptanes............ 3 UN1206 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... n-Heptene........... 3 UN2278 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Hexachloroacetone... 6.1 UN2661 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L B 12, 40 Hexachlorobenzene... 6.1 UN2729 III 6.1....... IB3 153........... 203........ 241........ 60 L 220 L A ....... Hexachlorobutadiene. 6.1 UN2279 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Hexachlorocyclopenta 6.1 UN2646 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 diene. B74, B77, T20, TP2, TP13, TP38, TP45 Hexachlorophene..... 6.1 UN2875 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Hexadecyltrichlorosi 8 UN1781 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 lane. N34, T7, TP2 Hexadienes.......... 3 UN2458 II 3......... IB2, T4, TP1 None.......... 202........ 242........ 5 L 60 L B ....... Hexaethyl 2.3 UN1612 ....... 2.3....... 3 None.......... 334........ None....... Forbidden Forbidden D 40 tetraphosphate and compressed gas mixtures. Hexaethyl 6.1 UN1611 II 6.1....... IB2, IP2, IP4, None.......... 202........ 243........ 5 L 60 L E 40 tetraphosphate, N76 liquid. Hexaethyl 6.1 UN1611 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg E 40 tetraphosphate, N76 solid. Hexafluoroacetone... 2.3 UN2420 ......#
Passage 200. 2.3, 8.... 2, B9, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 Hexafluoroacetone 6.1 UN2552 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L B 40 hydrate. Hexafluoroethane, 2.2 UN2193 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... compressed or Refrigerant gas R 116. Hexafluorophosphoric 8 UN1782 II 8......... A6, A7, B2, IB2, None.......... 202........ 242........ 1 L 30 L A ....... acid. N3, N34, T8, TP2, TP12 Hexafluoropropylene 2.2 UN1858 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... compressed or Refrigerant gas R 1216. Hexaldehyde......... 3 UN1207 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Hexamethylene 6.1 UN2281 II 6.1....... IB2, T7, TP2, None.......... 202........ 243........ 5 L 60 L C 13, 40 diisocyanate. TP13 Hexamethylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... triperoxide diamine (dry). Hexamethylenediamine 8 UN2280 III 8......... IB8, IP3, T4, TP1 154........... 213........ 240........ 25 kg 100 kg A 12 , solid. Hexamethylenediamine 8 UN1783 II 8......... IB2, T7, TP2 None.......... 202........ 242........ 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Hexamethyleneimine.. 3 UN2493 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 Hexamethylenetetrami 4.1 UN1328 III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A ....... ne. Hexamethylol benzene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... hexanitrate. Hexanes............. 3 UN1208 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E .......#
Passage 2012,2',4,4',6,6'- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitro-3,3'- dihydroxyazobenzene (dry). Hexanitroazoxy Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... benzene. N,N'- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (hexanitrodiphenyl) ethylene dinitramine (dry). Hexanitrodiphenyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... urea. 2,2',3',4,4',6- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitrodiphenylam ine. Hexanitrodiphenylami 1.1D UN0079 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... ne or Dipicrylamine or Hexyl. 2,3',4,4',6,6'- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitrodiphenylet her. Hexanitroethane..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitrooxanilide.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitrostilbene... 1.1D UN0392 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Hexanoic acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Corrosive liquids, n.o.s.. Hexanols............ 3 UN2282 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... 1-Hexene............ 3 UN2370 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Hexogen and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... cyclotetramethylene tetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Hexogen and HMX ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Hexog#
Passage 202en and octogen ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Hexogen, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Cyclotrimethylenetr initramine, etc. Hexolite, or Hexotol 1.1D UN0118 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... dry or wetted with less than 15 percent water, by mass. Hexotonal........... 1.1D UN0393 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Hexyl, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanitrodiphenylam ine. Hexyltrichlorosilane 8 UN1784 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 N34, T7, TP2, TP13 High explosives, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... individual explosives' entries. HMX, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Cyclotetramethylene te tranitramine, etc. Hydrazine, anhydrous 8 UN2029 I 8, 3, 6.1. A3, A6, A7, A10, None.......... 201........ 243........ Forbidden 2.5 L D 21, 40, or Hydrazine B7, B16, B53 42, 100 aqueous solutions with more than 64 percent hydrazine, by mass. Hydrazine, aqueous 6.1 UN3293 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... solution with not more than 37 percent hydrazine, by mass. Hydrazine azide..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrazine chlorate.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrazine dicarbonic Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... acid diazide. Hydrazine hydrate or 8 UN2030 II 8, 6.1.... B16, B53, IB2, None.......... 202........ 243........ Forbidden 30 L D 40, 42, Hydrazine aqueous T7, TP2, TP13 82 solutions, with not less than 37 percent but not more than 64 percent hydr#
Passage 203azine, by mass. Hydrazine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... perchlorate. Hydrazine selenate.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydriodic acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... anhydrous, see Hydrogen iodide, anhydrous. Hydriodic acid...... 8 UN1787 II 8......... A3, A6, B2, IB2, 154........... 202........ 242........ 1 L 30 L C ....... N41, T7, TP2 .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L C 8 Hydrobromic acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... anhydrous, see Hydrogen bromide, anhydrous. Hydrobromic acid, 8 UN1788 II 8......... B2, B15, IB2, 154........... 202........ 242........ Forbidden Forbidden C ....... with more than 49 N41, T7, TP2 percent hydrobromic acid. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ Forbidden Forbidden C 8 Hydrobromic acid, 8 UN1788 II 8......... A3, A6, B2, B15, 154........... 202........ 242........ 1 L 30 L C ....... with not more than IB2, N41, T7, TP2 49 percent hydrobromic acid. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 30 L C 8 Hydrocarbon gas 2.1 UN1964 ....... 2.1....... 306........... 302........ 314, 315... Forbidden 150 kg E 40 mixture, compressed, n.o.s.. Hydrocarbon gas 2.1 UN1965 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 mixture, liquefied, n.o.s.. Hydrocarbons, 3 UN3295 I 3......... T11, TP1, TP8 150........... 201........ 243........ 1 L 30 L E ....... liquid, n.o.s..#
Passage 204.................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Hydrochloric acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... anhydrous, see Hydrogen chloride, anhydrous. Hydrochloric acid... 8 UN1789 II 8......... A3, A6, B3, B15, 154........... 202........ 242........ 1 L 30 L C ....... IB2, N41, T8, TP2, TP12 .................... ........... .................. III 8......... IB3, T4, TP1, 154........... 203........ 241........ 5 L 60 L C 8 TP12 Hydrocyanic acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... anhydrous, see Hydrogen cyanide etc. Hydrocyanic acid, 6.1 UN1613 I 6.1....... 2, B61, B65, B77, None.......... 195........ 244........ Forbidden Forbidden D 40 aqueous solutions B82, T20, TP2, or Hydrogen TP13 cyanide, aqueous solutions with not more than 20 percent hydrogen cyanide. D Hydrocyanic acid, 6.1 NA1613 II 6.1....... IB1, T14, TP2, None.......... 195........ 243........ Forbidden 5 L D 40 aqueous solutions TP13, TP27 with less than 5 percent hydrogen cyanide. Hydrocyanic acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquefied, see Hydrogen cyanide, etc. Hydrocyanic acid Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (prussic), unstabilized. Hydrofluoric acid 8 UN1786 I 8, 6.1.... A6, A7, B15, B23, None.......... 201........ 243........ Forbidden 2.5 L D 40 and Sulfuric acid N5, N34, T10, mixtures. TP2, TP12, TP13 Hydrofluoric acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... anhydrous, see Hydrogen fluoride, anhydrous. Hydrofluoric acid, 8 UN1790 I 8, 6.1.... A6, A7, B4, B15, None.......... 201........ 243........ 0.5 L 2.5 L D 12, 40 with more than 60 B23, N5, N34, percent strength. T10, TP2, TP12, TP13 Hydrofluoric acid, 8 UN1790 II 8, 6.1.... A6, A7, B15, IB2, None.......... 202........ 243........ 1 L 30 L D 12, 40 with not mo#
Passage 205re than N5, N34, T8, TP2, 60 percent strength. TP12 Hydrofluoroboric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... acid, see Fluoroboric acid. Hydrofluorosilicic ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... acid, see Fluorosilicic acid. Hydrogen and Methane 2.1 UN2034 ....... 2.1....... 306........... 302........ 302, 314, Forbidden 150 kg E 40 mixtures, 315. compressed. Hydrogen bromide, 2.3 UN1048 ....... 2.3, 8.... 3, B14 None.......... 304........ 314, 315... Forbidden 25 kg D 40 anhydrous. Hydrogen chloride, 2.3 UN1050 ....... 2.3, 8.... 3 None.......... 304........ None....... Forbidden Forbidden D 40 anhydrous. Hydrogen chloride, 2.3 UN2186 ....... 2.3, 8.... 3, B6 None.......... None....... 314, 315... Forbidden Forbidden B 40 refrigerated liquid. Hydrogen, compressed 2.1 UN1049 ....... 2.1....... 306........... 302........ 302, 314... Forbidden 150 kg E 40, 57 Hydrogen cyanide, 6.1 UN3294 I 6.1, 3.... 2, 25, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 40 solution in alcohol B32, B74, T20, with not more than TP2, TP13, TP38, 45 percent hydrogen TP45 cyanide. Hydrogen cyanide, 6.1 UN1051 I 6.1, 3.... 1, B35, B61, B65, None.......... 195........ 244........ Forbidden Forbidden D 40 stabilized with B77, B82 less than 3 percent water. Hydrogen cyanide, 6.1 UN1614 I 6.1....... 5 None.......... 195........ None....... Forbidden Forbidden D 25, 40 stabilized, with less than 3 percent water and absorbed in a porous inert material. Hydrogen fluoride, 8 UN1052 I 8, 6.1.... 3, B7, B46, B71, None.......... 163........ 243........ Forbidden Forbidden D 40 anhydrous. B77, T10, TP2 Hydrogen iodide, 2.3 UN2197 ....... 2.3....... 3, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 anhydrous. Hydrogen iodide ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Hydriodic acid, solution. Hydrogen peroxide 5.1 UN3149 II 5.1, 8.... A2, A3, A6, B53, None.......... 202........ 243........ 1 L 5 L D 25, 66, and peroxyacetic IB2, IP5, T7, 75, 106 acid mixtures, TP2, TP6, TP24 stabilized with acids, water and not more than 5 percent peroxyacetic acid. Hydrogen peroxide, 5.1 UN2014 II 5.1, 8.... 12, A3#
Passage 206, A6, B53, None.......... 202........ 243........ Forbidden Forbidden D 25, 66, aqueous solutions B80, B81, B85, 75, 106 with more than 40 IB2, IP5, T7, percent but not TP2, TP6, TP24 more than 60 percent hydrogen peroxide (stabilized as necessary). Hydrogen peroxide, 5.1 UN2014 II 5.1, 8.... A2, A3, A6, B53, None.......... 202........ 243........ 1 L 5 L D 25, 66, aqueous solutions IB2, IP5, T7, 75, 106 with not less than TP2, TP6, TP24 20 percent but not more than 40 percent hydrogen peroxide (stabilized as necessary). Hydrogen peroxide, 5.1 UN2984 III 5.1....... A1, IB2, IP5, T4, 152........... 203........ 241........ 2.5 L 30 L B 25, 75, aqueous solutions TP1, TP6, TP24 106 with not less than 8 percent but less than 20 percent hydrogen peroxide (stabilized as necessary).#
Passage 207Hydrogen peroxide, 5.1 UN2015 I 5.1, 8.... 12, A3, A6, B53, None.......... 201........ 243........ Forbidden Forbidden D 25, 66, stabilized or B80, B81, B85, 75, 106 Hydrogen peroxide T10, TP2, TP6, aqueous solutions, TP24 stabilized with more than 60 percent hydrogen peroxide. Hydrogen, 2.1 UN1966 ....... 2.1....... T75, TP5 None.......... 316........ 318, 319... Forbidden Forbidden D 40 refrigerated liquid (cryogenic liquid). Hydrogen selenide, 2.3 UN2202 ....... 2.3, 2.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 anhydrous. Hydrogen sulfate, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sulfuric acid. Hydrogen sulfide.... 2.3 UN1053 ....... 2.3, 2.1.. 2, B9, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 Hydrogendifluorides, 8 UN1740 II 8......... IB5, IP2, IP4, None.......... 212........ 240........ 15 kg 50 kg A 25, 26, n.o.s. solid. N3, N34 40 .................... ........... .................. III 8......... IB8, IP3, N3, N34 154........... 213........ 240........ 25 kg 100 kg A 25, 26, 40 Hydrogendifluorides, 8 UN1740 II 8......... IB2, N3, N34 None.......... 202........ 242........ 1 L 30 L A 25, 26, n.o.s. solutions. 40 .................... ........... .................. III 8......... IB3, IP3, N3, N34 154........... 203........ 241........ 5 L 60 L A 25, 26, 40 Hydroquinone........ 6.1 UN2662 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... Hydrosilicofluoric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... acid, see Fluorosilicic acid. Hydroxyl amine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... iodide. Hydroxylamine 8 UN2865 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... sulfate. Hypochlorite 8 UN1791 II 8......... A7, B2, B15, IB2, 154........... 202........ 242........ 1 L 30 L B 26 solutions. IP5, N34, T7, TP2, TP24 .................... ........... .................. III 8......... IB3, N34, T4, 154........... 203........ 241........ 5 L 60 L B 26 TP2, TP24 Hypochlorites, 5.1 UN3212 II 5.1....... IB8, IP2, IP4 152........... 212........ 240........ 5 kg 25 kg D 48, 56, inorganic, n.o.s.. 5#
Passage 2088, 69, 106, 116, 118 Hyponitrous acid.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Igniter fuse, metal ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... clad, see Fuse, igniter, tubular, metal clad. Igniters............ 1.1G UN0121 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Igniters............ 1.2G UN0314 II 1.2G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Igniters............ 1.3G UN0315 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Igniters............ 1.4G UN0325 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Igniters............ 1.4S UN0454 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... 3,3'- 8 UN2269 III 8......... IB3, T4, TP2 154........... 203........ 241........ 5 L 60 L A ....... Iminodipropylamine. G Infectious 6.2 UN2900 ....... 6.2....... 134........... 196........ None....... 50 mL or 50 4 L or 4 kg B ....... substances, g affecting animals only. G Infectious 6.2 UN2814 ....... 6.2....... 134........... 196........ None....... 50 mL or 50 4 L or 4 kg B ....... substances, g affecting humans. Inflammable, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Flammable. Initiating Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... explosives (dry). Inositol hexanitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). G Insecticide gases, 2.2 UN1968 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... n.o.s.. G Insecticide gases, 2.1 UN3354 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg D 40 flammable, n.o.s.. G Insecticide gases, 2.3 UN3355 ....... 2.3, 2.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation hazard Zone A. G Insecticide gases, 2.3 UN3355 ....... 2.3, 2.1.. 2, B9, B14 None.......... 302, 305... 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation hazard Zone B. G Ins#
Passage 209ecticide gases, 2.3 UN3355 ....... 2.3, 2.1.. 3, B14 None.......... 302, 305... 314, 315... Forbidden Forbidden D ....... toxic, flammable, n.o.s. Inhalation hazard Zone C. G Insecticide gases, 2.3 UN3355 ....... 2.3, 2.1.. 4 None.......... 302, 305... 314, 315... Forbidden Forbidden D ....... toxic, flammable, n.o.s. Inhalation hazard Zone D. G Insecticide gases, 2.3 UN1967 ....... 2.3....... 3 None.......... 193, 334... 245........ Forbidden Forbidden D 40 toxic, n.o.s.. Inulin trinitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Iodine azide (dry).. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Iodine monochloride. 8 UN1792 II 8......... B6, IB8, IP2, None.......... 212........ 240........ Forbidden 50 kg D 40, 66, IP4, N41, T7, TP2 74, 89, 90 Iodine pentafluoride 5.1 UN2495 I 5.1, 6.1, None.......... 205........ 243........ Forbidden 2.5 L D 25, 40, 8. 66, 90 2-Iodobutane........ 3 UN2390 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Iodomethylpropanes.. 3 UN2391 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Iodopropanes........ 3 UN2392 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Iodoxy compounds Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Iridium Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitratopentamine iridium nitrate. Iron chloride, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Ferric chloride. Iron oxide, spent, 4.2 UN1376 III 4.2....... B18, IB8, IP3 None.......... 213........ 240........ Forbidden Forbidden E ....... or Iron sponge, spent obtained from coal gas purification.#
Passage 210Iron pentacarbonyl.. 6.1 UN1994 I 6.1, 3.... 1, B9, B14, B30, None.......... 192........ 244........ Forbidden Forbidden D 40 B72, B77, T22, TP2, TP13, TP38, TP44 Iron sesquichloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ferric chloride. Irritating material, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Tear gas substances, etc. Isobutane see also 2.1 UN1969 ....... 2.1....... 19, T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 Petroleum gases, liquefied. Isobutanol or 3 UN1212 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Isobutyl alcohol. Isobutyl acetate.... 3 UN1213 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isobutyl acrylate, 3 UN2527 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... stabilized. Isobutyl alcohol, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Isobutanol. Isobutyl aldehyde, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Isobutyraldehyde. D Isobutyl 6.1 NA2742 I 6.1, 3, 8. 2, B9, B14, B32, None.......... 227........ 244........ 1 L 30 L A 12, 13, chloroformate. B74, T20, TP4, 22, 25, TP12, TP13, TP38, 40, 48, TP45 100 Isobutyl formate.... 3 UN2393 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isobutyl isobutyrate 3 UN2528 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... + Isobutyl isocyanate. 3 UN2486 I 3, 6.1.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP27 Isobutyl 3 UN2283 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... methacrylate, stabilized. Isobutyl propionate. 3 UN2394 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L B ....... Isobutylamine....... 3 UN1214 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 Isobutylene see also 2.1 UN1055 ....... 2.1....... 19, T50 306........... 304........ 314, 315... Forbidden 150 kg E#
Passage 21140 Petroleum gases, liquefied. Isobutyraldehyde or 3 UN2045 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E 40 Isobutyl aldehyde. Isobutyric acid..... 3 UN2529 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A ....... Isobutyronitrile.... 3 UN2284 II 3, 6.1.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 60 L E 40 TP13 Isobutyryl chloride. 3 UN2395 II 3, 8...... IB1, T7, TP2 None.......... 202........ 243........ 1 L 5 L C 40 G Isocyanates, 3 UN2478 II 3, 6.1.... 5, A3, A7, IB2, None.......... 202........ 243........ 1 L 60 L D 40 flammable, toxic, T11, TP2, TP13, n.o.s. or TP27 Isocyanate solutions, flammable, toxic, n.o.s. flash point less than 23 degrees C. G Isocyanates, toxic, 6.1 UN3080 II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 25, 40, flammable, n.o.s. TP13, TP27 48 or Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C. G Isocyanates, toxic, 6.1 UN2206 II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L E 25, 40, n.o.s. or TP13, TP27 48 Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C. .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L E 25, 40, TP13, TP28 48 Isocyanatobenzotrifl 6.1 UN2285 II 6.1, 3.... 5, IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L D 25, 40, uorides. 48 Isoheptenes......... 3 UN2287 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isohexenes.......... 3 UN2288 II 3......... IB2, IP8, T11, 150........... 202........ 242........ 5 L 60 L E ....... TP1 Isooctane, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Octanes. Isooctenes.......... 3 UN1216 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isopentane, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Pentane. Isopentanoic acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Corro#
Passage 212sive liquids, n.o.s.. Isopentenes......... 3 UN2371 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... Isophorone 6.1 UN2290 III 6.1....... IB3, T4, TP2 153........... 203........ 241........ 60 L 220 L B 40 diisocyanate. Isophoronediamine... 8 UN2289 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Isoprene, stabilized 3 UN1218 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... Isopropanol or 3 UN1219 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isopropyl alcohol. Isopropenyl acetate. 3 UN2403 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isopropenylbenzene.. 3 UN2303 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Isopropyl acetate... 3 UN1220 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isopropyl acid 8 UN1793 III 8......... IB8, IP3, T4, TP1 154........... 213........ 240........ 25 kg 100 kg A ....... phosphate. Isopropyl alcohol, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Isopropanol. Isopropyl butyrate.. 3 UN2405 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Isopropyl 3 UN2947 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... chloroacetate. Isopropyl 6.1 UN2407 I 6.1, 3, 8. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 40 chloroformate. B74, B77, T20, TP2, TP13, TP38, TP44 Isopropyl 2- 3 UN2934 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... chloropropionate. Isopropyl 3 UN2406 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... isobutyrate. + Isopropyl isocyanate 3 UN2483 I 3, 6.1.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP38, TP44 Isopropyl mercaptan, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Propanethiols.#
Passage 213Isopropyl nitrate... 3 UN1222 II 3......... IB2, IP7 150........... 202........ None....... 5 L 60 L D ....... Isopropyl phosphoric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... acid, see Isopropyl acid phosphate. Isopropyl propionate 3 UN2409 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Isopropylamine...... 3 UN1221 I 3, 8...... T11, TP2 None.......... 201........ 243........ 0.5 L 2.5 L E ....... Isopropylbenzene.... 3 UN1918 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Isopropylcumyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... hydroperoxide, with more than 72 percent in solution. Isosorbide dinitrate 4.1 UN2907 II 4.1....... IB6, IP2 None.......... 212........ None....... 15 kg 50 kg E ....... mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate. Isosorbide-5- 4.1 UN3251 III 4.1....... 66, IB8 151........... 213........ 240........ Forbidden Forbidden D 12 mononitrate. Isothiocyanic acid.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Jet fuel, see Fuel ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... aviation, turbine engine. D Jet perforating 1.1D NA0124 II 1.1D...... 55, 56 None.......... 62......... None....... Forbidden Forbidden 07 ....... guns, charged oil well, with detonator. D Jet perforating 1.4D NA0494 II 1.4D...... 55, 56 None.......... 62......... None....... Forbidden Forbidden 06 ....... guns, charged oil well, with detonator. Jet perforating 1.1D UN0124 II 1.1D...... 55 None.......... 62......... None....... Forbidden Forbidden 07 ....... guns, charged oil well, without detonator. Jet perforating 1.4D UN0494 II 1.4D...... 55, 114 None.......... 62......... None....... Forbidden 300 kg 06 ....... guns, charged, oil well, without detonator. Jet perforators, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Charges, shaped, etc. Jet tappers, without ........... .................. .......... ............. .......... .......... ........... ...........#
Passage 214........... ....... detonator, see Charges, shaped, etc. Jet thrust igniters, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... for rocket motors or Jato, see Igniters. Jet thrust unit ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... (Jato), see Rocket motors. Kerosene............ 3 UN1223 III 3......... B1, IB3, T2, TP2 150........... 203........ 242........ 60 L 220 L A ....... G Ketones, liquid, 3 UN1224 I 3......... T11, TP1, TP8, None.......... 201........ 243........ 1 L 30 L E ....... n.o.s.. TP27 .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Krypton, compressed. 2.2 UN1056 ....... 2.2....... 306........... 302........ None....... 75 kg 150 kg A ....... Krypton, 2.2 UN1970 ....... 2.2....... T75, TP5 320........... None....... None....... 50 kg 500 kg B ....... refrigerated liquid (cryogenic liquid). Lacquer base or ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... lacquer chips, nitrocellulose, dry, see Nitrocellulose, etc. (UN 2557). Lacquer base or ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... lacquer chips, plastic, wet with alcohol or solvent, see Nitrocellulose (UN2059, UN2555, UN2556, UN2557) or Paint etc.(UN1263). Lead acetate........ 6.1 UN1616 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Lead arsenates...... 6.1 UN1617 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Lead arsenites...... 6.1 UN1618 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Lead azide (dry).... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Lead azide, wetted 1.1A UN0129 II 1.1A...... 111, 117 None.......... 62......... None....... Forbidden Forbidden 12 ....... with not less than 20 percent water or mixture of alcohol and water, by mass. L#
Passage 215ead compounds, 6.1 UN2291 III 6.1....... 138, IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... soluble, n.o.s.. Lead cyanide........ 6.1 UN1620 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 26 Lead dioxide........ 5.1 UN1872 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Lead dross, see Lead ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... sulfate, with more than 3 percent free acid. Lead nitrate........ 5.1 UN1469 II 5.1, 6.1.. IB8, IP2, IP4 None.......... 212........ 242........ 5 kg 25 kg A ....... Lead Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitroresorcinate (dry). Lead perchlorate, 5.1 UN1470 II 5.1, 6.1.. IB6, IP2, T4, TP1 None.......... 212........ 242........ 5 kg 25 kg A 56, 58, solid. 106 Lead perchlorate, 5.1 UN1470 II 5.1, 6.1.. IB1, T4, TP1 None.......... 202........ 243........ 1 L 5 L A 56, 58, solution. 106 Lead peroxide, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Lead dioxide. Lead phosphite, 4.1 UN2989 II 4.1....... IB8, IP2, IP4 None.......... 212........ 240........ 5 kg 25 kg B 34 dibasic. .................... ........... .................. III 4.1....... IB8, IP3 151........... 213........ 240........ 15 kg 50 kg B 34 Lead picrate (dry).. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Lead styphnate (dry) Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Lead styphnate, 1.1A UN0130 II 1.1A...... 111, 117 None.......... 62......... None....... Forbidden Forbidden 12 ....... wetted or Lead trinitroresorcinate , wetted with not less than 20 percent water or mixture of alcohol and water, by mass. Lead sulfate with 8 UN1794 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... more than 3 percent free acid. Lead ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... trinitroresorcinate , see Lead styphnate, etc.#
Passage 216Life-saving 9 UN3072 ....... None...... 143 None.......... 219........ None....... No limit No limit A ....... appliances, not self inflating containing dangerous goods as equipment. Life-saving 9 UN2990 ....... None...... None.......... 219........ None....... No limit No limit A ....... appliances, self inflating. Lighter replacement ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... cartridges containing liquefied petroleum gases (and similar devices, each not exceeding 65 grams), see Lighters or lighter refills etc. containing flammable gas. Lighters, fuse...... 1.4S UN0131 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Lighters or Lighter 2.1 UN1057 ....... 2.1....... N10 None.......... 21, 308.... None....... 1 kg 15 kg B 40 refills cigarettes, containing flammable gas. Lime, unslaked, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Calcium oxide. G Liquefied gas, 2.1 UN3161 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg D 40 flammable, n.o.s.. G Liquefied gas, 2.2 UN3163 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... n.o.s.. G Liquefied gas, 2.2 UN3157 ....... 2.2, 5.1.. 306........... 304........ 314, 315... 75 kg 150 kg D ....... oxidizing, n.o.s.. G I Liquefied gas, 2.3 UN3308 ....... 2.3, 8.... 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone A. G I Liquefied gas, 2.3 UN3308 ....... 2.3, 8.... 2 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone B. G I Liquefied gas, 2.3 UN3308 ....... 2.3, 8.... 3 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone C. G I Liquefied gas, 2.3 UN3308 ....... 2.3, 8.... 4 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, corrosive, n.o.s. Inhalation Hazard Zone D. G I Liquefied gas, 2.3 UN3309 ....... 2.3, 2.1, 1 None.......... 192........ 245........ Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone A. G I Liquefied gas toxic, 2.3 UN3309 ....... 2.3, 2.1, 2 None.......... 304........ 314, 315... Forbidden Forbidden D 17, 40 flam#
Passage 217mable, 8. corrosive, n.o.s. Inhalation Hazard Zone B. G I Liquefied gas, 2.3 UN3309 ....... 2.3, 2.1, 3 None.......... 304........ 314, 315... Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone C. G I Liquefied gas, 2.3 UN3309 ....... 2.3, 2.1, 4 None.......... 304........ 314, 315... Forbidden Forbidden D 17, 40 toxic, flammable, 8. corrosive, n.o.s. Inhalation Hazard Zone D. G Liquefied gas, 2.3 UN3160 ....... 2.3, 2.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation Hazard Zone A. G Liquefied gas, 2.3 UN3160 ....... 2.3, 2.1.. 2, B9, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation Hazard Zone B. G Liquefied gas, 2.3 UN3160 ....... 2.3, 2.1.. 3, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation Hazard Zone C. G Liquefied gas, 2.3 UN3160 ....... 2.3, 2.1.. 4 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, flammable, n.o.s. Inhalation Hazard Zone D. G Liquefied gas, 2.3 UN3162 ....... 2.3....... 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone A. G Liquefied gas, 2.3 UN3162 ....... 2.3....... 2, B9, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone B. G Liquefied gas, 2.3 UN3162 ....... 2.3....... 3, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone C. G Liquefied gas, 2.3 UN3162 ....... 2.3....... 4 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, n.o.s. Inhalation Hazard Zone D. G I Liquefied gas, 2.3 UN3310 ....... 2.3, 5.1, 1 None.......... 192........ 245........ Forbidden Forbidden D 40, 89, toxic, oxidizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone A. G I Liquefied gas, 2.3 UN3310 ....... 2.3, 2.1, 2 None.......... 304........ 314, 315... Forbidden Forbidden D 40, 89, toxic, oxidizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone B. G I Liquefied gas, 2.3 UN3310 ....... 2.3, 2.1, 3 None.......... 304........ 314, 315... Forbidden Forbidden D 40, 89, toxic, oxidizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone C. G I Liquefied gas, 2.3 UN3310 ....... 2.3, 2.1, 4 None.......... 304........ 314, 315... Forbidden Forbidden D 40, 89, toxi#
Passage 218c, oxidizing, 8. 90 corrosive, n.o.s. Inhalation Hazard Zone D. G Liquefied gas, 2.3 UN3307 ....... 2.3, 5.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone A. G Liquefied gas, 2.3 UN3307 ....... 2.3, 5.1.. 2 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone B. G Liquefied gas, 2.3 UN3307 ....... 2.3, 5.1.. 3 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone C. G Liquefied gas, 2.3 UN3307 ....... 2.3, 5.1.. 4 None.......... 304........ 314, 315... Forbidden Forbidden D 40 toxic, oxidizing, n.o.s. Inhalation Hazard Zone D. Liquefied gases, non- 2.2 UN1058 ....... 2.2....... 306........... 304........ None....... 75 kg 150 kg A ....... flammable charged with nitrogen, carbon dioxide or air.#
Passage 219Liquefied ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrocarbon gas, see Hydrocarbon gas mixture, liquefied, n.o.s.. Liquefied natural ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... gas, see Methane, etc. (UN 1972). Liquefied petroleum ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... gas see Petroleum gases, liquefied. Lithium............. 4.3 UN1415 I 4.3....... A7, A19, IB1, None.......... 211........ 244........ Forbidden 15 kg E ....... IP1, N45 Lithium acetylide ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... ethylenediamine complex, see Water reactive solid etc. Lithium alkyls...... 4.2 UN2445 I 4.2, 4.3.. B11, T21, TP2, None.......... 181........ 244........ Forbidden Forbidden D ....... TP7 Lithium aluminum 4.3 UN1410 I 4.3....... A19 None.......... 211........ 242........ Forbidden 15 kg E ....... hydride. Lithium aluminum 4.3 UN1411 I 4.3, 3.... A2, A3, A11, N34 None.......... 201........ 244........ Forbidden 1 L D 40 hydride, ethereal. Lithium batteries, 9 UN3091 II 9......... 29 185(i)........ 185........ None....... 5 kg 5 kg A ....... contained in equipment. Lithium batteries 9 UN3091 II 9......... 29 185........... 185........ None....... 5 kg gross 35 kg gross A ....... packed with equipment. Lithium battery..... 9 UN3090 II 9......... 29 185........... 185........ None....... 5 kg gross 35 kg gross A ....... Lithium borohydride. 4.3 UN1413 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... Lithium ferrosilicon 4.3 UN2830 II 4.3....... A19, IB7, IP2 151........... 212........ 241........ 15 kg 50 kg E 40, 85, 103 Lithium hydride..... 4.3 UN1414 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... Lithium hydride, 4.3 UN2805 II 4.3....... A8, A19, A20, IB4 151........... 212........ 241........ 15 kg 50 kg E ....... fused solid. Lithium hydroxide, 8 UN2680 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... monohydrate or Lithium hydroxide, solid. Lithium hydroxide, 8 UN2679 II 8......... B2, IB2, T7, TP2 154........... 202........ 242......#
Passage 220.. 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP2 154........... 203........ 241........ 5 L 60 L A 96 Lithium 5.1 UN1471 II 5.1....... A9, IB8, IP2, 152........... 212........ 240........ 5 kg 25 kg A 48, 56, hypochlorite, dry IP4, N34 58, 69, with more than 39% 106, available chlorine 116 (8.8% available oxygen) or Lithium hypochlorite mixtures, dry with more than 39% available chlorine (8.8% available oxygen). Lithium in ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... cartridges, see Lithium. Lithium nitrate..... 5.1 UN2722 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Lithium nitride..... 4.3 UN2806 I 4.3....... A19, IB4, IP1, None.......... 211........ 242........ Forbidden 15 kg E ....... N40 Lithium peroxide.... 5.1 UN1472 II 5.1....... A9, IB6, IP2, N34 152........... 212........ None....... 5 kg 25 kg A 13, 75, 106 Lithium silicon..... 4.3 UN1417 II 4.3....... A19, A20, IB7, 151........... 212........ 241........ 15 kg 50 kg A 85, 103 IP2 LNG, see Methane ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... etc. (UN 1972). London purple....... 6.1 UN1621 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... LPG, see Petroleum ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... gases, liquefied. Lye, see Sodium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydroxide, solutions. Magnesium alkyls.... 4.2 UN3053 I 4.2, 4.3.. B11, T21, TP2, None.......... 181........ 244........ Forbidden Forbidden D 18 TP7 Magnesium aluminum 4.3 UN1419 I 4.3, 6.1.. A19, N34, N40 None.......... 211........ 242........ Forbidden 15 kg E 40, 85 phosphide. + Magnesium arsenate.. 6.1 UN1622 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Magnesium bisulfite ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Magnesium bromate... 5.1 UN1473 II 5.1....... A1, IB8, IP4 152........... 212......#
Passage 221.. 242........ 5 kg 25 kg A 56, 58, 106 Magnesium chlorate.. 5.1 UN2723 II 5.1....... IB8, IP2, IP4 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Magnesium diamide... 4.2 UN2004 II 4.2....... A8, A19, A20, IB6 None.......... 212........ 241........ 15 kg 50 kg C ....... Magnesium diphenyl.. 4.2 UN2005 I 4.2....... None.......... 187........ 244........ Forbidden Forbidden C ....... Magnesium dross, wet Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... or hot. Magnesium 6.1 UN2853 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 fluorosilicate. Magnesium granules, 4.3 UN2950 III 4.3....... A1, A19, IB8, IP4 151........... 213........ 240........ 25 kg 100 kg A ....... coated, particle size not less than 149 microns. Magnesium hydride... 4.3 UN2010 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... Magnesium or 4.1 UN1869 III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A 39 Magnesium alloys with more than 50 percent magnesium in pellets, turnings or ribbons. Magnesium nitrate... 5.1 UN1474 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Magnesium 5.1 UN1475 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 56, 58, perchlorate. 106 Magnesium peroxide.. 5.1 UN1476 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 13, 75, 106 Magnesium phosphide. 4.3 UN2011 I 4.3, 6.1.. A19, N40 None.......... 211........ None....... Forbidden 15 kg E 40, 85 Magnesium, powder or 4.3 UN1418 I 4.3, 4.2.. A19, B56 None.......... 211........ 244........ Forbidden 15 kg A 39 Magnesium alloys, powder. .................... ........... .................. II 4.3, 4.2.. A19, B56, IB5, None.......... 212........ 241........ 15 kg 50 kg A 39 IP2 .................... ........... .................. III 4.3, 4.2.. A19, B56, IB8, None.......... 213........ 241........ 25 kg 100 kg A 39 IP4 Magnesium scrap, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Magnesium, etc. (UN 1869).#
Passage 222Magnesium silicide.. 4.3 UN2624 II 4.3....... A19, A20, IB7, 151........... 212........ 241........ 15 kg 50 kg B 85, 103 IP2 Magnetized material, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sec. 173.21. Maleic anhydride.... 8 UN2215 III 8......... IB8, IP3, T4, TP1 154........... 213........ 240........ 25 kg 100 kg A ....... Malononitrile....... 6.1 UN2647 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 12 Mancozeb (manganese ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... ethylenebisdithioca rbamate complex with zinc) see Maneb. Maneb or Maneb 4.2 UN2210 III 4.2, 4.3.. 57, A1, A19, IB6 None.......... 213........ 242........ 25 kg 100 kg A 34 preparations with not less than 60 percent maneb. Maneb stabilized or 4.3 UN2968 III 4.3....... 54, A1, A19, IB8, 151........... 213........ 242........ 25 kg 100 kg B 34 Maneb preparations, IP4 stabilized against self-heating. Manganese nitrate... 5.1 UN2724 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Manganese resinate.. 4.1 UN1330 III 4.1....... A1, IB6 151........... 213........ 240........ 25 kg 100 kg A ....... Mannitan Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetranitrate. Mannitol hexanitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Mannitol 1.1D UN0133 II 1.1D...... 121 None.......... 62......... None....... Forbidden Forbidden 10 ....... hexanitrate, wetted or Nitromannite, wetted with not less than 40 percent water, or mixture of alcohol and water, by mass. Marine pollutants, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquid or solid, n.o.s., see Environmentally hazardous substances, liquid or solid, n.o.s.. Matches, block, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Matches, 'strike anywhere'. Matches, fusee...... 4.1 UN2254 III 4.1....... 186........... 186........ None....... Forbidden Forbidden A ....... Matches, safety 4.1 UN1944 III 4.1....... 186...#
Passage 223........ 186........ None....... 25 kg 100 kg A ....... (book, card or strike on box). Matches, strike 4.1 UN1331 III 4.1....... 186........... 186........ None....... Forbidden Forbidden B ....... anywhere. Matches, wax, Vesta. 4.1 UN1945 III 4.1....... 186........... 186........ None....... 25 kg 100 kg B ....... Matting acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Sulfuric acid. Medicine, liquid, 3 UN3248 II 3, 6.1.... 36, IB2 None.......... 202........ None....... 1 L 5 L B 40 flammable, toxic, n.o.s.. .................... ........... .................. III 3, 6.1.... 36, IB3 150........... 203........ None....... 5 L 5 L A ....... Medicine, liquid, 6.1 UN1851 II 6.1....... 153........... 202........ 243........ 5 L 5 L C 40 toxic, n.o.s.. .................... ........... .................. III 6.1....... 153........... 203........ 241........ 5 L 5 L C 40 Medicine, solid, 6.1 UN3249 II 6.1....... 36 153........... 212........ None....... 5 kg 5 kg C 40 toxic, n.o.s.. .................... ........... .................. III 6.1....... 36 153........... 213........ None....... 5 kg 5 kg C 40 Memtetrahydrophthali ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... c anhydride, see Corrosive liquids, n.o.s.. Mercaptans, liquid, 3 UN3336 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E 95 flammable, n.o.s. or Mercaptan mixture, liquid, flammable, n.o.s.. .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B 95 TP8, TP28 .................... ........... .................. III 3......... B1, B52, IB3, T4, 150........... 203........ 241........ 60 L 220 L B 95 TP1, TP29 Mercaptans, liquid, 3 UN1228 II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ Forbidden 60 L B 40, 95 flammable, toxic, TP27 n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s.. .................... ........... .................. III 3, 6.1.... B1, IB3, T7, TP1, 150........... 203........ 242........ 5 L 220 L A 40, 95 TP28 Mercaptans, liquid, 6.1 UN3071 II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L C 40, 121 toxic, flammable, TP13, TP27 n.o.s. or Mercaptan mixtures, liquid, toxic, fla#
Passage 224mmable, n.o.s., flash point not less than 23 degrees C. 5-Mercaptotetrazol-1- 1.4C UN0448 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 09 ....... acetic acid. Mercuric arsenate... 6.1 UN1623 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercuric chloride... 6.1 UN1624 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercuric compounds, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Mercury compounds, etc. Mercuric nitrate.... 6.1 UN1625 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... N73 + Mercuric potassium 6.1 UN1626 I 6.1....... IB7, IP1, N74, None.......... 211........ 242........ 5 kg 50 kg A 26 cyanide. N75 Mercuric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... sulfocyanate, see Mercury thiocyanate. Mercurol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Mercury nucleate. Mercurous azide..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Mercurous compounds, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Mercury compounds, etc. Mercurous nitrate... 6.1 UN1627 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... A W Mercury............. 8 UN2809 III 8......... 164........... 164........ 240........ 35 kg 35 kg B 40, 97 Mercury acetate..... 6.1 UN1629 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury acetylide... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Mercury ammonium 6.1 UN1630 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... chloride. Mercury based 3 UN2778 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202.#
Passage 225....... 243........ 1 L 60 L B 40 TP13, TP27 Mercury based 6.1 UN3012 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic.#
Passage 226.................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Mercury based 6.1 UN3011 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Mercury based 6.1 UN2777 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Mercury benzoate.... 6.1 UN1631 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury bromides.... 6.1 UN1634 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury compounds, 6.1 UN2024 I 6.1....... None.......... 201........ 243........ 1 L 30 L B 40 liquid, n.o.s.. .................... ........... .................. II 6.1....... IB2 None.......... 202........ 243........ 5 L 60 L B 40 .................... ........... .................. III 6.1....... IB3 153........... 203........ 241........ 60 L 220 L B 40 Mercury compounds, 6.1 UN2025 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A ....... solid, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... A Mercury contained in 8 UN2809 III 8......... None.......... 164........ None....... No limit No limit B 40, 97 manufactured articles. Mercury cyanide..... 6.1 UN1636 II 6.1....... IB8, IP2, IP4, None.......... 212........ 24#
Passage 2272........ 25 kg 100 kg A 26 N74, N75 Mercury fulminate, 1.1A UN0135 II 1.1A...... 111, 117 None.......... 62......... None....... Forbidden Forbidden 12 ....... wetted with not less than 20 percent water, or mixture of alcohol and water, by mass. Mercury gluconate... 6.1 UN1637 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury iodide, 6.1 UN1638 II 6.1....... IB2, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... solid. Mercury iodide Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... aquabasic ammonobasic (Iodide of Millon's base). Mercury iodide, 6.1 UN1638 II 6.1....... IB8, IP2, IP4 None.......... 202........ 243........ 5 L 60 L A ....... solution. Mercury nitride..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Mercury nucleate.... 6.1 UN1639 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury oleate...... 6.1 UN1640 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury oxide....... 6.1 UN1641 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury oxycyanide.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Mercury oxycyanide, 6.1 UN1642 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 26, 91 desensitized. Mercury potassium 6.1 UN1643 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... iodide. Mercury salicylate.. 6.1 UN1644 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... + Mercury sulfates.... 6.1 UN1645 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mercury thiocyanate. 6.1 UN1646 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Mesityl oxide....... 3 UN1229 III 3......... B1, IB3, T2, TP1 None.......... 203........ 242........ 60 L 220 L A ....... Metal alkyl halides, 4.2 UN3049 I 4.2, 4.3.. B9, B11, T21, None.......... 181........ 244........ Forbidden Forbidden D ....... water-reactive TP2, TP7 n.o.s. or Metal aryl halides, water- reactive, n.#
Passage 228o.s.. Metal alkyl 4.2 UN3050 I 4.2, 4.3.. B9, B11, T21, None.......... 181........ 244........ Forbidden Forbidden D ....... hydrides, water- TP2, TP7 reactive, n.o.s. or Metal aryl hydrides, water- reactive, n.o.s.. Metal alkyls, water- 4.2 UN2003 I 4.2, 4.3.. B11, T21, TP2, None.......... 181........ 244........ Forbidden Forbidden D ....... reactive, n.o.s. or TP7 Metal aryls, water- reactive n.o.s.. Metal carbonyls, 6.1 UN3281 I 6.1....... 5, T14, TP2, None.......... 201........ 243........ 1 L 30 L B 40 n.o.s.. TP13, TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Metal catalyst, dry. 4.2 UN2881 I 4.2....... N34 None.......... 187........ None....... 25 kg 100 kg C ....... .................... ........... .................. II 4.2....... IB6, IP2, N34 None.......... 187........ 242........ Forbidden 50 kg C ....... .................... ........... .................. III 4.2....... IB8, IP3, N34 None.......... 187........ 241........ 25 kg 100 kg C ....... Metal catalyst, 4.2 UN1378 II 4.2....... A2, A8, IB1, N34 None.......... 212........ None....... Forbidden 50 kg C ....... wetted with a visible excess of liquid. Metal hydrides, 4.1 UN3182 II 4.1....... A1, IB4 151........... 212........ 240........ 15 kg 50 kg E ....... flammable, n.o.s.. .................... ........... .................. III 4.1....... A1, IB4 151........... 213........ 240........ 25 kg 100 kg E ....... Metal hydrides, 4.3 UN1409 I 4.3....... A19, N34, N40 None.......... 211........ 242........ Forbidden 15 kg D ....... water reactive, n.o.s.. .................... ........... .................. II 4.3....... A19, IB4, N34, 151........... 212........ 242........ 15 kg 50 kg D ....... N40 Metal powder, self- 4.2 UN3189 II 4.2....... IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg C ....... heating, n.o.s.. .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg C ....... Metal powders, 4.1 UN3089 II 4.1....... IB8, IP2, IP4 151........... 212........ 240........ 15 kg 50 kg B ....... flammable, n.o.s.. .................... ........... .................. III 4.1.......#
Passage 229IB6 151........... 213........ 240........ 25 kg 100 kg B ....... Metal salts of Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methyl nitramine (dry). G Metal salts of 4.1 UN3181 II 4.1....... A1, IB8, IP2, IP4 151........... 212........ 240........ 15 kg 50 kg B 40 organic compounds, flammable, n.o.s.. .................... ........... .................. III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg B 40 Metaldehyde......... 4.1 UN1332 III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A ....... G Metallic substance, 4.3 UN3208 I 4.3....... IB4 None.......... 211........ 242........ Forbidden 15 kg E 40 water-reactive, n.o.s.. .................... ........... .................. II 4.3....... IB7, IP2 151........... 212........ 242........ 15 kg 50 kg E 40#
Passage 230.................... ........... .................. III 4.3....... IB8, IP4 151........... 213........ 241........ 25 kg 100 kg E 40 G Metallic substance, 4.3 UN3209 I 4.3, 4.2.. None.......... 211........ 242........ Forbidden 15 kg E 40 water-reactive, self-heating, n.o.s.. .................... ........... .................. II 4.3, 4.2.. IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg E 40 .................... ........... .................. III 4.3, 4.2.. IB8, IP4 None.......... 213........ 242........ 25 kg 100 kg E 40 Methacrylaldehyde, 3 UN2396 II 3, 6.1.... 45, IB2, T7, TP1, None.......... 202........ 243........ 1 L 60 L E 40 stabilized. TP13 Methacrylic acid, 8 UN2531 II 8......... IB3, T4, TP1, 154........... 202........ 242........ 1 L 30 L A ....... stabilized. TP18 + Methacrylonitrile, 3 UN3079 I 3, 6.1.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 12, 40, stabilized. B74, T20, TP2, 48 TP13, TP38, TP45 Methallyl alcohol... 3 UN2614 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Methane and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrogen, mixtures, see Hydrogen and methane, mixtures, etc. Methane, compressed 2.1 UN1971 ....... 2.1....... 306........... 302........ 302........ Forbidden 150 kg E 40 or Natural gas, compressed (with high methane content). Methane, 2.1 UN1972 ....... 2.1....... T75, TP5 None.......... None....... 318........ Forbidden Forbidden D 40 refrigerated liquid (cryogenic liquid) or Natural gas, refrigerated liquid (cryogenic liquid), with high methane content). Methanesulfonyl 6.1 UN3246 I 6.1, 8.... 2, 25, B9, B14, None.......... 227........ 244........ Forbidden Forbidden D 40 chloride. B32, B74, T20, TP2, TP12, TP13, TP38, TP45 + I Methanol............ 3 UN1230 II 3, 6.1.... IB2, T7, TP2 150........... 202........ 242........ 1 L 60 L B 40 D Methanol............ 3 UN1230 II 3......... IB2, T7, TP2 150........... 202........ 242........ 1 L 60 L B 40 Methazoic acid...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 4-Methoxy-4- 3 UN2293 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... methylpentan-2-one. 1-Methoxy-2-propanol 3 UN3092#
Passage 231III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... + Methoxymethyl 3 UN2605 I 3, 6.1.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 isocyanate. B72, T22, TP2, TP13, TP38, TP44 Methyl acetate...... 3 UN1231 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methyl acetylene and 2.1 UN1060 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 propadiene mixtures, stabilized. Methyl acrylate, 3 UN1919 II 3......... IB2, T4, TP1, 150........... 202........ 242........ 5 L 60 L B ....... stabilized. TP13 Methyl alcohol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Methanol. Methyl allyl 3 UN2554 II 3......... IB2, T4, TP1, 150........... 202........ 242........ 5 L 60 L E ....... chloride. TP13 Methyl amyl ketone, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Amyl methyl ketone. Methyl bromide...... 2.3 UN1062 ....... 2.3....... 3, B14, T50 None.......... 193........ 314, 315... Forbidden 25 kg D 40 Methyl bromide and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... chloropicrin mixtures with more than 2 percent chloropicrin, see Chloropicrin and methyl bromide mixtures. Methyl bromide and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... chloropicrin mixtures with not more than 2 percent chloropicrin, see Methyl bromide. Methyl bromide and 6.1 UN1647 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden C 40 ethylene dibromide B74, N65, T20, mixtures, liquid. TP2, TP13, TP38, TP44 Methyl bromoacetate. 6.1 UN2643 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L D 40 2-Methyl-1-butene... 3 UN2459 I 3......... T11, TP2 None.......... 201........ 243........ 1 L 30 L E ....... 2-Methyl-2-butene... 3 UN2460 II 3......... IB2, IP8, T7, TP1 None.......... 202........ 242........ 5 L 60 L E ....... 3-Methyl-1-butene... 3 UN2561 I 3......... T11, TP2 None.......... 201........ 243........ 1 L 30 L E ....... Methyl tert-butyl 3 UN2398 II 3......... IB2, T7, TP1 150.......#
Passage 232.... 202........ 242........ 5 L 60 L E ....... ether. Methyl butyrate..... 3 UN1237 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methyl chloride, or 2.1 UN1063 ....... 2.1....... T50 306........... 304........ 314, 315... 5 kg 100 kg D 40 Refrigerant gas R 40. Methyl chloride and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... chloropicrin mixtures, see Chloropicrin and methyl chloride mixtures. Methyl chloride and 2.1 UN1912 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg D 40 methylene chloride mixtures. Methyl chloroacetate 6.1 UN2295 I 6.1, 3.... T14, TP2, TP13 None.......... 201........ 243........ 1 L 30 L D ....... Methyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... chlorocarbonate, see Methyl chloroformate. Methyl chloroform, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see 1,1,1- Trichloroethane. Methyl chloroformate 6.1 UN1238 I 6.1, 3, 8. 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 21, 40, B72, N34, T22, 100 TP2, TP13, TP38, TP44 Methyl chloromethyl 6.1 UN1239 I 6.1, 3.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 ether. B72, T22, TP2, TP38, TP44 Methyl 2- 3 UN2933 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... chloropropionate. Methyl 6.1 UN2299 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... dichloroacetate.#
Passage 233Methyl ethyl ether, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethyl methyl ether. Methyl ethyl ketone, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethyl methyl ketone. Methyl ethyl ketone Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... peroxide, in solution with more than 9 percent by mass active oxygen. 2-Methyl-5- 6.1 UN2300 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... ethylpyridine. Methyl fluoride, or 2.1 UN2454 ....... 2.1....... 306........... 304........ 314, 315... Forbidden 150 kg E 40 Refrigerant gas R 41. Methyl formate...... 3 UN1243 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... 2-Methyl-2- 6.1 UN3023 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40, 102 heptanethiol. B74, T20, TP2, TP13, TP38, TP45 Methyl iodide....... 6.1 UN2644 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden A 12, 40 B74, T20, TP2, TP13, TP38, TP45 Methyl isobutyl 3 UN2053 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... carbinol. Methyl isobutyl 3 UN1245 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... ketone. Methyl isobutyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... ketone peroxide, in solution with more than 9 percent by mass active oxygen. Methyl isocyanate... 6.1 UN2480 I 6.1, 3.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 26, 40 B72, T22, TP2, TP13, TP38, TP44 Methyl isopropenyl 3 UN1246 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... ketone, stabilized. Methyl 6.1 UN2477 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden A ....... isothiocyanate. B74, T20, TP2, TP13, TP38, TP45 Methyl isovalerate.. 3 UN2400 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methyl magnesium 4.3 UN1928 I 4.3, 3.... None.......... 201........ 243........ Forbidden 1 L D ....... bromide, in ethyl et#
Passage 234her. Methyl mercaptan.... 2.3 UN1064 ....... 2.3, 2.1.. 3, B7, B9, B14, None.......... 304........ 314, 315... Forbidden 25 kg D 40 T50 Methyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mercaptopropionalde hyde, see Thia-4- pentanal. Methyl methacrylate 3 UN1247 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 monomer, stabilized. Methyl nitramine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Methyl nitrate...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Methyl nitrite...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Methyl norbornene ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... dicarboxylic anhydride, see Corrosive liquids, n.o.s.. Methyl orthosilicate 6.1 UN2606 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden E 40 B74, T20, TP2, TP13, TP38, TP45 D Methyl phosphonic 6.1 NA9206 I 6.1, 8.... 2, A3, B9, B14, None.......... 227........ 244........ Forbidden Forbidden C ....... dichloride. B32, B74, N34, N43, T20, TP4, TP12, TP13, TP38, TP45 Methyl ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... phosphonothioic dichloride, anhydrous, see Corrosive liquid, n.o.s.. D Methyl phosphonous 6.1 NA2845 I 6.1, 4.2.. 2, B9, B14, B16, None.......... 227........ 244........ Forbidden Forbidden D 18 dichloride, B32, B74, T20, pyrophoric liquid. TP4, TP12, TP13, TP38, TP45 Methyl picric acid Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (heavy metal salts of). Methyl propionate... 3 UN1248 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methyl propyl ether. 3 UN2612 II 3......... IB2, IP8, T7, TP2 150........... 202........ 242........ 5 L 60 L E 40 Methyl propyl ketone 3 UN1249 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methyl sulfate, see ........... .................. .......... ............. ..#
Passage 235........ .......... ........... ........... ........... ....... Dimethyl sulfate. Methyl sulfide, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Dimethyl sulfide. Methyl 6.1 UN2533 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... trichloroacetate. Methyl trimethylol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methane trinitrate. Methyl vinyl ketone, 6.1 UN1251 I 6.1, 3, 8. 1, 25, B9, B14, None.......... 226........ 244........ Forbidden Forbidden B 40 stabilized. B30, B72, T22, TP2, TP13, TP38, TP44 Methylal............ 3 UN1234 II 3......... IB2, IP8, T7, TP2 None.......... 202........ 242........ 5 L 60 L E ....... Methylamine, 2.1 UN1061 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 anhydrous. Methylamine, aqueous 3 UN1235 II 3, 8...... B1, IB2, T7, TP1 150........... 202........ 243........ 1 L 5 L E 41 solution. Methylamine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitramine and dry salts thereof. Methylamine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitroform. Methylamine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... perchlorate (dry). Methylamyl acetate.. 3 UN1233 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... N-Methylaniline..... 6.1 UN2294 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... alpha-Methylbenzyl 6.1 UN2937 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... alcohol. 3-Methylbutan-2-one. 3 UN2397 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B .......#
Passage 236N-Methylbutylamine.. 3 UN2945 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 Methylchlorosilane.. 2.3 UN2534 ....... 2.3, 2.1, 2, A2, A3, A7, None.......... 226........ 314, 315... Forbidden Forbidden D 17, 40 8. B9, B14, N34 Methylcyclohexane... 3 UN2296 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methylcyclohexanols, 3 UN2617 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... flammable. Methylcyclohexanone. 3 UN2297 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Methylcyclopentane.. 3 UN2298 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... D Methyldichloroarsine 6.1 NA1556 I 6.1....... 2, T20, TP4, None.......... 192........ None....... Forbidden Forbidden D 40 TP12, TP13, TP38, TP45 Methyldichlorosilane 4.3 UN1242 I 4.3, 8, 3. A2, A3, A7, B6, None.......... 201........ 243........ Forbidden 1 L D 21, 28, B77, N34, T10, 40, 49, TP2, TP7, TP13 100 Methylene chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Dichloromethane. Methylene glycol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... dinitrate. 2-Methylfuran....... 3 UN2301 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... a-Methylglucoside Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetranitrate. a-Methylglycerol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trinitrate. 5-Methylhexan-2-one. 3 UN2302 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Methylhydrazine..... 6.1 UN1244 I 6.1, 3, 8. 1, B7, B9, B14, None.......... 226........ 244........ Forbidden Forbidden D 21, 40, B30, B72, B77, 49, 100 N34, T22, TP2, TP13, TP38, TP44 4-Methylmorpholine 3 UN2535 II 3, 8...... B6, IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 or n- methylmorpholine. Methylpentadienes... 3 UN2461 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... 2-Methylpentan-2-ol. 3 UN2560 III 3......... B1, IB3, T2#
Passage 237, TP1 150........... 203........ 242........ 60 L 220 L A ....... Methylpentanes, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanes. Methylphenyldichloro 8 UN2437 II 8......... IB2, T7, TP2, 154........... 202........ 242........ 1 L 30 L C 40 silane. TP13 1-Methylpiperidine.. 3 UN2399 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B ....... Methyltetrahydrofura 3 UN2536 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... n. Methyltrichlorosilan 3 UN1250 I 3, 8...... A7, B6, B77, N34, None.......... 201........ 243........ Forbidden 2.5 L B 40 e. T11, TP2, TP13 alpha- 3 UN2367 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Methylvaleraldehyde. Mine rescue ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... equipment containing carbon dioxide, see Carbon dioxide. Mines with bursting 1.1F UN0136 II 1.1F...... ............. 62......... None....... Forbidden Forbidden 08 ....... charge. Mines with bursting 1.1D UN0137 II 1.1D...... ............. 62......... None....... Forbidden Forbidden 03 ....... charge. Mines with bursting 1.2D UN0138 II 1.2D...... ............. 62......... None....... Forbidden Forbidden 03 ....... charge. Mines with bursting 1.2F UN0294 II 1.2F...... ............. 62......... None....... Forbidden Forbidden 08 ....... charge. Mixed acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrating acid, mixtures etc. Mobility aids, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Battery powered equipment or Battery powered vehicle'. D Model rocket motor.. 1.4C NA0276 II 1.4C...... 51 None.......... 62......... None....... Forbidden 75 kg 06 ....... D Model rocket motor.. 1.4S NA0323 II 1.4S...... 51 None.......... 62......... None....... 25 kg 100 kg 05 ....... Molybdenum 8 UN2508 III 8......... IB8, IP3, T4, TP1 154........... 213........ 240........ 25 kg 100 kg C 40 pentachloride. Monochloroacetone Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (unstabilized). Mon#
Passage 238ochloroethylene, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Vinyl chloride, stabilized. Monoethanolamine, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ethanolamine, solutions. Monoethylamine, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Ethylamine. Morpholine.......... 8 UN2054 I 8, 3...... T10, TP2 None.......... 201........ 243........ .5 L 2.5 L C 25,40 Morpholine, aqueous, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixture, see Corrosive liquids, n.o.s.. Motor fuel anti- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... knock compounds see Motor fuel anti- knock mixtures. + Motor fuel anti- 6.1 UN1649 I 6.1, 3.... 14, B9, B90, T14, None.......... 201........ 244........ Forbidden 30 L D 25, 40 knock mixtures. TP2, TP13 Motor spirit, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Gasoline. Muriatic acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrochloric acid. Musk xylene, see 5- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... tert-Butyl-2,4,6- trinitro-m-xylene. Naphtha see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Petroleum distillates n.o.s.. Naphthalene, crude 4.1 UN1334 III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A ....... or Naphthalene, refined. Naphthalene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diozonide. beta-Naphthylamine.. 6.1 UN1650 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... T7, TP2 alpha-Naphthylamine. 6.1 UN2077 III 6.1....... IB8, IP3, T3, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... Naphthalene, molten. 4.1 UN2304 III 4.1....... A1, IB1, T1, TP3 151....#
Passage 239....... 213........ 241........ Forbidden Forbidden C ....... Naphthylamineperchlo Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... rate. Naphthylthiourea.... 6.1 UN1651 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Naphthylurea........ 6.1 UN1652 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Natural gases (with ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... high methane content), see Methane, etc. (UN 1971, UN 1972). Neohexane, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexanes.#
Passage 240Neon, compressed.... 2.2 UN1065 ....... 2.2....... 306........... 302........ 302........ 75 kg 150 kg A ....... Neon, refrigerated 2.2 UN1913 ....... 2.2....... T75, TP5 320........... 316........ None....... 50 kg 500 kg B ....... liquid (cryogenic liquid). New explosive or ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... explosive device, see Secs. 173.51 and 173.56. Nickel carbonyl..... 6.1 UN1259 I 6.1, 3.... 1 None.......... 198........ None....... Forbidden Forbidden D 18, 40 Nickel cyanide...... 6.1 UN1653 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 26 N74, N75 Nickel nitrate...... 5.1 UN2725 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Nickel nitrite...... 5.1 UN2726 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 56, 58 Nickel picrate...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Nicotine............ 6.1 UN1654 II 6.1....... IB2 None.......... 202........ 243........ 5 L 60 L A ....... Nicotine compounds, 6.1 UN3144 I 6.1....... A4 None.......... 201........ 243........ 1 L 30 L B 40 liquid, n.o.s. or Nicotine preparations, liquid, n.o.s.. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L B 40 TP28 Nicotine compounds, 6.1 UN1655 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg B ....... solid, n.o.s. or Nicotine preparations, solid, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Nicotine 6.1 UN1656 II 6.1....... IB2, IP2, IP4 None.......... 202........ 243........ 5 L 60 L A ....... hydrochloride or Nicotine hydrochloride solution. Nicotine salicylate. 6.1 UN1657 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Nicotine sulfate, 6.1 UN1658 II 6.1....... IB8, IP2, IP4#
Passage 241None.......... 212........ 242........ 25 kg 100 kg A ....... solid. Nicotine sulfate, 6.1 UN1658 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... solution. Nicotine tartrate... 6.1 UN1659 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Nitrated paper Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (unstable). Nitrates, inorganic, 5.1 UN3218 II 5.1....... 58, IB2, T4, TP1 152........... 202........ 242........ 1 L 5 L B 46 aqueous solution, n.o.s.. .................... ........... .................. III 5.1....... 58, IB2, T4, TP1 152........... 203........ 241........ 2.5 L 30 L B 46 Nitrates, inorganic, 5.1 UN1477 II 5.1....... IB8, IP2, IP4 152........... 212........ 240........ 5 kg 25 kg A 46 n.o.s.. .................... ........... .................. III 5.1....... IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 46 Nitrates of Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diazonium compounds. Nitrating acid 8 UN1826 I 8, 5.1.... T10, TP2, TP12, None.......... 158........ 243........ Forbidden 2.5 L D 40, 66 mixtures, spent TP13 with more than 50 percent nitric acid. Nitrating acid 8 UN1826 II 8......... B2, IB2, T8, TP2, None.......... 158........ 242........ Forbidden 30 L D 40 mixtures spent with TP12 not more than 50 percent nitric acid. Nitrating acid 8 UN1796 I 8, 5.1.... T10, TP2, TP12, None.......... 158........ 243........ Forbidden 2.5 L D 40, 66 mixtures with more TP13 than 50 percent nitric acid. Nitrating acid 8 UN1796 II 8......... B2, IB2, T8, TP2, None.......... 158........ 242........ Forbidden 30 L D 40 mixtures with not TP12, TP13 more than 50 percent nitric acid. Nitric acid other 8 UN2031 I 8, 5.1.... B47, B53, T10, None.......... 158........ 243........ Forbidden 2.5 L D 44, 66, than red fuming, TP2, TP12, TP13 89, 90, with more than 70 110, percent nitric acid. 111 Nitric acid other 8 UN2031 II 8......... B2, B47, B53, None.......... 158........ 242........ Forbidden 30 L D 44, 66, than red fuming, IB2, T8, TP2, 89, 90, with not more than TP12 110, 70 percent nitric 111 acid. + Nitric acid, red 8 UN2032 I 8, 5.1, 2, B9, B32, B74, None.......... 227........ 244........ Forbidden Forbidden D 40, 6#
Passage 2426, fuming. 6.1. T20, TP2, TP12, 74, 89, TP13, TP38, TP45 90 Nitric oxide, 2.3 UN1660 ....... 2.3, 5.1, 1, B37, B46, B50, None.......... 337........ None....... Forbidden Forbidden D 40, 89, compressed. 8. B60, B77 90 Nitric oxide and 2.3 UN1975 ....... 2.3, 5.1, 1, B7, B9, B14, None.......... 337........ None....... Forbidden Forbidden D 40, 89, dinitrogen 8. B45, B46, B61, 90 tetroxide mixtures B66, B67, B77 or Nitric oxide and nitrogen dioxide mixtures. G Nitriles, flammable, 3 UN3273 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L E 40, 52 toxic, n.o.s.. TP27 .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40, 52 TP13, TP27 G Nitriles, toxic, 6.1 UN3275 I 6.1, 3.... 5, T14, TP2, None.......... 201........ 243........ 1 L 30 L B 40 flammable, n.o.s.. TP13, TP27 .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 G Nitriles, toxic, 6.1 UN3276 I 6.1....... 5, T14, TP2, None.......... 201........ 243........ 1 L 30 L B ....... n.o.s.. TP13, TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B ....... TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A ....... TP28 Nitrites, inorganic, 5.1 UN3219 II 5.1....... IB1, T4, TP1 152........... 202........ 242........ 1 L 5 L B 46, 56, aqueous solution, 58 n.o.s.. .................... ........... .................. III 5.1....... IB2, T4, TP1 152........... 203........ 241........ 2.5 L 30 L B 46, 56, 58 Nitrites, inorganic, 5.1 UN2627 II 5.1....... 33, IB8, IP4 152........... 212........ None....... 5 kg 25 kg A 46, 56, n.o.s.. 58 3-Nitro-4- 6.1 UN2307 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 chlorobenzotrifluor ide. 6-Nitro-4- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diazotoluene-3- sulfonic acid (dry). Nitro isobutane Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... triol trinitrate.#
Passage 243N-Nitro-N- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methylglycolamide nitrate. 2-Nitro-2- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methylpropanol nitrate. Nitro urea.......... 1.1D UN0147 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... N-Nitroaniline...... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... + Nitroanilines (o-; m- 6.1 UN1661 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... ; p-;). T7, TP2 + Nitroanisole........ 6.1 UN2730 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... + Nitrobenzene........ 6.1 UN1662 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 m-Nitrobenzene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diazonium perchlorate. Nitrobenzenesulfonic 8 UN2305 II 8......... IB2 154........... 202........ 242........ 1 L 30 L A ....... acid. Nitrobenzol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrobenzene. 5-Nitrobenzotriazol. 1.1D UN0385 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Nitrobenzotrifluorid 6.1 UN2306 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 es. Nitrobromobenzenes 6.1 UN2732 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... liquid. Nitrobromobenzenes 6.1 UN2732 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... solid. Nitrocellulose, dry 1.1D UN0340 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 13 27E or wetted with less than 25 percent water (or alcohol), by mass. Nitrocellulose 4.1 UN3270 II 4.1....... 43, A1 151........... 212........ 240........ 1 kg 15 kg D ....... membrane filters, with not more than 12.6% nitrogen, by dry mass. Nitrocellulose, 1.3C UN0343 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... plasticized with not less than 18 percent plasticizing substance,#
Passage 244by mass. Nitrocellulose, 3 UN2059 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose. .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Nitrocellulose, 1.1D UN0341 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 13 27E unmodified or plasticized with less than 18 percent plasticizing substance, by mass. Nitrocellulose, 1.3C UN0342 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... wetted with not less than 25 percent alcohol, by mass. Nitrocellulose with 4.1 UN2556 II 4.1....... 151........... 212........ None....... 1 kg 15 kg D 28 alcohol with not less than 25 percent alcohol by mass, and with not more than 12.6 percent nitrogen, by dry mass. Nitrocellulose, with 4.1 UN2557 II 4.1....... 44 151........... 212........ None....... 1 kg 15 kg D 28 not more than 12.6 percent nitrogen, by dry mass, or Nitrocellulose mixture with pigment or Nitrocellulose mixture with plasticizer or Nitrocellulose mixture with pigment and plasticizer. Nitrocellulose with 4.1 UN2555 II 4.1....... 151........... 212........ None....... 15 kg 50 kg E 28 water with not less than 25 percent water, by mass. Nitrochlorobenzene, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Chloronitrobenzenes etc. Nitrocresols........ 6.1 UN2446 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Nitroethane......... 3 UN2842 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Nitroethyl nitrate.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitroethylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... polymer. Nitrogen, compressed 2.2 UN1066 ....... 2.2....... 306........... 302........ 314, 315... 75 kg 150 kg A ....... Nitrogen dioxide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Dinitrogen tetroxide. Nitrogen fertilizer ..#
Passage 245......... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Fertilizer ammoniating solution etc. Nitrogen, mixtures ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... with rare gases, see Rare gases and nitrogen mixtures. Nitrogen peroxide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Dinitrogen tetroxide. Nitrogen, 2.2 UN1977 ....... 2.2....... T75, TP5 320........... 316........ 318........ 50 kg 500 kg D ....... refrigerated liquid cryogenic liquid. Nitrogen tetroxide ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... and nitric oxide mixtures, see Nitric oxide and nitrogen tetroxide mixtures. Nitrogen tetroxide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Dinitrogen tetroxide. Nitrogen trichloride Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrogen 2.2 UN2451 ....... 2.2, 5.1.. None.......... 302........ None....... 75 kg 150 kg D 40 trifluoride, compressed. Nitrogen triiodide.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrogen triiodide Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... monoamine. Nitrogen trioxide... 2.3 UN2421 ....... 2.3, 5.1, 1 None.......... 336........ 245........ Forbidden Forbidden D 40, 89, 8. 90#
Passage 246Nitroglycerin, 1.1D UN0143 II 1.1D, 6.1. 125 None.......... 62......... None....... Forbidden Forbidden 13 21E desensitized with not less than 40 percent non- volatile water insoluble phlegmatizer, by mass. Nitroglycerin, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... liquid, not desensitized. Nitroglycerin 3 UN3343 ....... 3......... 129 None.......... 214........ None....... Forbidden Forbidden D ....... mixture, desensitized, liquid, flammable, n.o.s. with not more than 30 percent nitroglycerin, by mass. Nitroglycerin 3 UN3357 II 3......... 142 None.......... 202........ 243........ 5 L 60 L E ....... mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin, by mass. Nitroglycerin 4.1 UN3319 II 4.1....... 118 None.......... None....... None....... Forbidden 0.5 kg E ....... mixture, desensitized, solid, n.o.s. with more than 2 percent but not more than 10 percent nitroglycerin, by mass. Nitroglycerin, 3 UN3064 II 3......... N8 None.......... 202........ None....... Forbidden 5 L E ....... solution in alcohol, with more than 1 percent but not more than 5 percent nitroglycerin. Nitroglycerin, 1.1D UN0144 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 21E solution in alcohol, with more than 1 percent but not more than 10 percent nitrogylcerin. Nitroglycerin 3 UN1204 II 3......... IB2, N34 None.......... 202........ None....... 5 L 60 L B ....... solution in alcohol with not more than 1 percent nitroglycerin. Nitroguanidine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrate. Nitroguanidine or 1.1D UN0282 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Picrite, dry or wetted with less than 20 percent water, by mass. Nitroguanidine, 4.1 UN1336 I 4.1....... 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg E 28 wetted or Picrite, N41 wetted with not less than 20 percent water, by mass. 1-Nitrohydantoin.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrohydrochloric 8 UN1798 I 8......... A3, B10, N41, None.......... 201........ 243........ Forbidden 2.5 L D 40, 66, acid. T10, TP2, TP12, 74, 89, TP13 90 Nitromannite (dry).. Forbidden .......#
Passage 247........... .......... ............. .......... .......... ........... ........... ........... ....... Nitromannite, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... wetted, see Mannitol hexanitrate, etc. Nitromethane........ 3 UN1261 II 3......... 150........... 202........ None....... Forbidden Forbidden A ....... Nitromuriatic acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Nitrohydrochloric acid. Nitronaphthalene.... 4.1 UN2538 III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A ....... + Nitrophenols (o-; m- 6.1 UN1663 III 6.1....... IB8, IP3, T4, TP3 153........... 213........ 240........ 100 kg 200 kg A ....... ; p-;). m-Nitrophenyldinitro Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methane. Nitropropanes....... 3 UN2608 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... p- 4.2 UN1369 II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg D 34 Nitrosodimethylanil IP2, N34 ine. Nitrostarch, dry or 1.1D UN0146 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... wetted with less than 20 percent water, by mass. Nitrostarch, wetted 4.1 UN1337 I 4.1....... 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg D 28 with not less than N41 20 percent water, by mass. Nitrosugars (dry)... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitrosyl chloride... 2.3 UN1069 ....... 2.3, 8.... 3, B14 None.......... 304........ 314, 315... Forbidden Forbidden D 40 Nitrosylsulfuric 8 UN2308 II 8......... A3, A6, A7, B2, 154........... 202........ 242........ 1 L 30 L D 40, 66, acid. IB2, N34, T8, 74, 89, TP2, TP12 90 Nitrotoluenes, 6.1 UN1664 II 6.1....... IB2, IP2, IP4, None.......... 202........ 243........ 5 L 60 L A ....... liquid o-; m-; p-;. T7, TP2 Nitrotoluenes, solid 6.1 UN1664 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... m-, or p-. T7, TP2 Nitrotoluidines 6.1 UN2660 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... (mono). Nitrotriazolone or#
Passage 2481.1D UN0490 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... NTO. Nitrous oxide and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... carbon dioxide mixtures, see Carbon dioxide and nitrous oxide mixtures. Nitrous oxide....... 2.2 UN1070 ....... 2.2, 5.1.. 306........... 304........ 314, 315... 75 kg 150 kg A 40 Nitrous oxide, 2.2 UN2201 ....... 2.2, 5.1.. B6, T75, TP5, None.......... 304........ 314, 315... Forbidden Forbidden B 40 refrigerated liquid. TP22 Nitroxylenes, (o-; m- 6.1 UN1665 II 6.1....... IB2, IP2, IP4, None.......... 202........ 243........ 5 L 60 L A ....... ; p-). T7, TP2 Nitroxylol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitroxylenes. Nonanes............. 3 UN1920 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Non-flammable gas, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... n.o.s., see Compressed gas, etc. or Liquefied gas, etc. Nonliquefied gases, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Compressed gases, etc. Nonliquefied ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrocarbon gas, see Hydrocarbon gas mixture, compressed, n.o.s..#
Passage 249Nonyltrichlorosilane 8 UN1799 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 N34, T7, TP2, TP13 Nordhausen acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Sulfuric acid, fuming etc. 2,5-Norbornadiene, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... stabilized, see Bicyclo 2,2,1 hepta- 2,5-diene stabilized. Octadecyltrichlorosi 8 UN1800 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 lane. N34, T7, TP2, TP13 Octadiene........... 3 UN2309 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... 1,7-Octadine-3,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diyne-1,8-dimethoxy- 9-octadecynoic acid. Octafluorobut-2-ene 2.2 UN2422 ....... 2.2....... None.......... 304........ 314, 315... 75 kg 150 kg A ....... or Refrigerant gas R 1318. Octafluorocyclobutan 2.2 UN1976 ....... 2.2....... T50 None.......... 304........ 314, 315... 75 kg 150 kg A ....... e, or Refrigerant gas RC 1318. Octafluoropropaneor 2.2 UN2424 ....... 2.2....... T50 None.......... 304........ 314, 315... 75 kg 150 kg A ....... Refrigerant gas R 218. Octanes............. 3 UN1262 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Octogen, etc. see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Cyclotetramethylene tetranitramine, etc.. Octolite or Octol, 1.1D UN0266 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... dry or wetted with less than 15 percent water, by mass. Octonal............. 1.1D UN0496 ....... 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Octyl aldehydes..... 3 UN1191 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Octyltrichlorosilane 8 UN1801 II 8......... A7, B2, B6, IB2, None.......... 202........ 242........ Forbidden 30 L C 40 N34, T7, TP2, TP13 Oil gas, compressed. 2.3 UN1071 ....... 2.3, 2.1.. 6 None.......... 304........ 314, 315... Forbidden 25 kg D 40 Oleum, see Sulfuric ........... .................. ......#
Passage 250.... ............. .......... .......... ........... ........... ........... ....... acid, fuming. Organic peroxide Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... type A, liquid or solid. G Organic peroxide 5.2 UN3101 II 5.2, 1.... 53 152........... 225........ None....... Forbidden Forbidden D 12, 40 type B, liquid. G Organic peroxide 5.2 UN3111 II 5.2, 1.... 53 None.......... 225........ None....... Forbidden Forbidden D 2, 40 type B, liquid, temperature controlled. G Organic peroxide 5.2 UN3102 II 5.2, 1.... 53 152........... 225........ None....... Forbidden Forbidden D 12, 40 type B, solid. G Organic peroxide 5.2 UN3112 II 5.2, 1.... 53 None.......... 225........ None....... Forbidden Forbidden D 2, 40 type B, solid, temperature controlled. G Organic peroxide 5.2 UN3103 II 5.2....... 152........... 225........ None....... 5 L 10 L D 12, 40 type C, liquid. G Organic peroxide 5.2 UN3113 II 5.2....... None.......... 225........ None....... Forbidden Forbidden D 2, 40 type C, liquid, temperature controlled. G Organic peroxide 5.2 UN3104 II 5.2....... 152........... 225........ None....... 5 kg 10 kg D 12, 40 type C, solid. G Organic peroxide 5.2 UN3114 II 5.2....... None.......... 225........ None....... Forbidden Forbidden D 2, 40 type C, solid, temperature controlled. G Organic peroxide 5.2 UN3105 II 5.2....... 152........... 225........ None....... 5 L 10 L D 12, 40 type D, liquid. G Organic peroxide 5.2 UN3115 II 5.2....... None.......... 225........ None....... Forbidden Forbidden D 2, 40 type D, liquid, temperature controlled. G Organic peroxide 5.2 UN3106 II 5.2....... 152........... 225........ None....... 5 kg 10 kg D 12, 40 type D, solid. G Organic peroxide 5.2 UN3116 II 5.2....... None.......... 225........ None....... Forbidden Forbidden D 2, 40 type D, solid, temperature controlled. G Organic peroxide 5.2 UN3107 II 5.2....... 152........... 225........ None....... 10 L 25 L D 12, 40 type E, liquid. G Organic peroxide 5.2 UN3117 II 5.2....... None.......... 225........ None....... Forbidden Forbidden D 2, 40 type E, liquid, temperature controlled. G Organic peroxide 5.2 UN3108 II 5.2....... 152........... 225........ None....... 10 kg 25 kg D 12, 40 type E, solid. G Organic peroxide 5.2 UN3118 II 5.2....... None.......... 225........ None....... Forbidden Forbidden D 2, 40#
Passage 251type E, solid, temperature controlled. G Organic peroxide 5.2 UN3109 II 5.2....... IB52, IP5, T23 152........... 225........ 225........ 10 L 25 L D 12, 40 type F, liquid. G Organic peroxide 5.2 UN3119 II 5.2....... IB52, IP5, T23 None.......... 225........ 225........ Forbidden Forbidden D 2, 40 type F, liquid, temperature controlled. G Organic peroxide 5.2 UN3110 II 5.2....... IB52, T23 152........... 225........ 225........ 10 kg 25 kg D 12, 40 type F, solid. G Organic peroxide 5.2 UN3120 II 5.2....... T23 None.......... 225........ 225........ Forbidden Forbidden D 2, 40 type F, solid, temperature controlled. D Organic phosphate, 2.3 NA1955 ....... 2.3....... 3 None.......... 334........ None....... Forbidden Forbidden D 40 mixed with compressed gas or Organic phosphate compound, mixed with compressed gas or Organic phosphorus compound, mixed with compressed gas. Organic pigments, 4.2 UN3313 II 4.2....... IB8, IP4 None.......... 212........ 241........ 15 kg 50 kg C ....... self-heating. .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg C ....... Organoarsenic 6.1 UN3280 I 6.1....... 5, IB7, IP1, T14, None.......... 211........ 242........ 5 kg 50 kg B ....... compound, n.o.s.. TP2, TP27 .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B ....... T11, TP2, TP27 .................... ........... .................. III 6.1....... IB8, IP3, T7, 153........... 213........ 240........ 100 kg 200 kg A ....... TP1, TP28 Organochlorine 3 UN2762 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Organochlorine 6.1 UN2996 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic.#
Passage 252.................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Organochlorine 6.1 UN2995 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Organochlorine 6.1 UN2761 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 G Organometallic 4.3 UN3207 I 4.3, 3.... T13, TP2, TP7 None.......... 201........ 244........ Forbidden 1 L E 40 compound or Compound solution or Compound dispersion, water- reactive, flammable, n.o.s.. .................... ........... .................. II 4.3, 3.... IB1, IP2, T7, None.......... 202........ 243........ 1 L 5 L E 40 TP2, TP7 .................... ........... .................. III 4.3, 3.... IB2, IP4, T7, None.......... 203........ 242........ 5 L 60 L E 40 TP2, TP7 G Organometallic 6.1 UN3282 I 6.1....... IB7, IP1, T14, None.......... 211........ 242........ 5 kg 50 kg B ....... compound, toxic TP2, TP27 n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B ....... T11, TP2, TP27 .................... ........... .................. III 6.1....... IB8, IP3, T7, 153........... 213........ 240........ 100 kg 200 kg A ....... TP1, TP28 Organophosphorus 6.1 UN3279 I 6.1, 3.... 5, T14, TP2, TP13 None.......... 201........ 243........ 1 L 30 L B 40 compound, toxic, flammable, n.o.s.. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP1#
Passage 2533, TP27 Organophosphorus 6.1 UN3278 I 6.1....... 5, IB7, T14, TP2, None.......... 201........ 243........ 1 L 30 L B ....... compound, toxic TP13, TP27 n.o.s.. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B ....... TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A ....... TP28 Organophosphorus 3 UN2784 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Organophosphorus 6.1 UN3018 I 6.1....... N76, T14, TP2, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP13, TP27 toxic. .................... ........... .................. II 6.1....... IB2, N76, T11, None.......... 202........ 243........ 5 L 60 L B 40 TP2, TP13, TP27 .................... ........... .................. III 6.1....... IB3, N76, T7, 153........... 203........ 241........ 60 L 220 L A 40 TP2, TP28 Organophosphorus 6.1 UN3017 I 6.1, 3.... N76, T14, TP2, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP13, TP27 toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, N76, T11, None.......... 202........ 243........ 5 L 60 L B 40 TP2, TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, N76, T7, 153........... 203........ 242........ 60 L 220 L A 40 TP2, TP28 Organophosphorus 6.1 UN2783 I 6.1....... IB7, IP1, N77 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A 40 N77 .................... ........... .................. III 6.1....... IB8, IP3, N77 153........... 213........ 240........ 100 kg 200 kg A 40 Organotin compounds, 6.1 UN2788 I 6.1....... A3, N33, N34, None.......... 201........ 243........ 1 L 30 L B 40 liquid, n.o.s.. T14, TP2, TP13, TP27 .................... ........... .................. II 6.1....... A3, IB2, N33, None.......... 202.......#
Passage 254. 243........ 5 L 60 L A 40 N34, T11, TP2, TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Organotin compounds, 6.1 UN3146 I 6.1....... A5, IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg B 40 solid, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Organotin 3 UN2787 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Organotin 6.1 UN3020 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28#
Passage 255Organotin 6.1 UN3019 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, TP27 toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Organotin 6.1 UN2786 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Orthonitroaniline, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Nitroanilines etc. Osmium tetroxide.... 6.1 UN2471 I 6.1....... A8, IB7, IP1, None.......... 211........ 242........ 5 kg 50 kg B 40 N33, N34 D G Other regulated 9 NA3082 III 9......... IB3, T2, TP1 155........... 203........ 241........ No limit No limit A ....... substances, liquid, n.o.s.. D G Other regulated 9 NA3077 III 9......... B54, IB8, IP2 155........... 213........ 240........ No limit No limit A ....... substances, solid, n.o.s.. G Oxidizing liquid, 5.1 UN3098 I 5.1, 8.... None.......... 201........ 244........ Forbidden 2.5 L D 13, 56, corrosive, n.o.s.. 58, 69, 106 .................... ........... .................. II 5.1, 8.... IB1 None.......... 202........ 243........ 1 L 5 L B 34, 56, 58, 69, 106 .................... ........... .................. III 5.1, 8.... IB2 152........... 203........ 242........ 2.5 L 30 L B 34, 56, 58, 69, 106 G Oxidizing liquid, 5.1 UN3139 I 5.1....... 127, A2 None.......... 201........ 243........ Forbidden 2.5 L D 56, 58, n.o.s.. 69, 106 .................... ........... .................. II 5.1....... 127, A2, IB2 152........... 202........ 242........ 1 L 5 L B 56, 58, 69, 106 .................... ........... .................. III 5.1....... 127, A2, IB2 152........... 203........ 241........ 2.5 L 30 L B 56, 58, 69, 106 G Oxidizing liquid, 5.1 UN3099 I 5.1, 6.1.. None.......... 201........ 244........ Forbidde#
Passage 256n 2.5 L D 56, 58, toxic, n.o.s.. 69, 106 .................... ........... .................. II 5.1, 6.1.. IB1 None.......... 202........ 243........ 1 L 5 L B 56, 58, 95, 106 .................... ........... .................. III 5.1, 6.1.. IB2 152........... 203........ 242........ 2.5 L 30 L B 56, 58, 95, 106 G Oxidizing solid, 5.1 UN3085 I 5.1, 8.... None.......... 211........ 242........ 1 kg 15 kg D 13, 56, corrosive, n.o.s.. 58, 69, 106 .................... ........... .................. II 5.1, 8.... IB6, IP2 None.......... 212........ 242........ 5 kg 25 kg B 13, 34, 56, 58, 69, 106 .................... ........... .................. III 5.1, 8.... IB8, IP3 152........... 213........ 240........ 25 kg 100 kg B 13, 34, 56, 58, 69, 106 G Oxidizing solid, 5.1 UN3137 I 5.1, 4.1.. None.......... 214........ 214........ Forbidden Forbidden ........... ....... flammable, n.o.s.. G Oxidizing solid, 5.1 UN1479 I 5.1....... IB6, IP1 None.......... 211........ 242........ 1 kg 15 kg D 56, 58, n.o.s.. 69, 106 .................... ........... .................. II 5.1....... IB8, IP2, IP4 152........... 212........ 240........ 5 kg 25 kg B 56, 58, 69, 106 .................... ........... .................. III 5.1....... IB8, IP3 152........... 213........ 240........ 25 kg 100 kg B 56, 58, 69, 106 G Oxidizing solid, 5.1 UN3100 II 5.1, 4.2.. None.......... 214........ 214........ Forbidden Forbidden ........... ....... self-heating, n.o.s.. G Oxidizing solid, 5.1 UN3087 I 5.1, 6.1.. None.......... 211........ 242........ 1 kg 15 kg D 56, 58, toxic, n.o.s.. 69, 106 .................... ........... .................. II 5.1, 6.1.. IB6, IP2 None.......... 212........ 242........ 5 kg 25 kg B 56, 58, 69, 95, 106 .................... ........... .................. III 5.1, 6.1.. IB8, IP3 152........... 213........ 240........ 25 kg 100 kg B 56, 58, 69, 95, 106 G Oxidizing solid, 5.1 UN3121 ....... 5.1, 4.3.. None.......... 214........ 214........ Forbidden Forbidden ........... ....... water-reactive, n.o.s.. Oxygen and carbon ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... dioxide mixtures, see Carbon dioxide and oxygen mixtures. Oxygen, compressed.. 2.2 UN1072 ....... 2.2, 5.1.. A52 306........... 302........ 314, 315... 75 kg 150 kg A ....... Oxygen difluoride, 2.3 UN2190 ....... 2.3, 5.1,#
Passage 2571 None.......... 304........ None....... Forbidden Forbidden D 13, 40, compressed. 8. 89, 90 Oxygen generator, 5.1 UN3356 II 5.1....... 60, A51 None.......... 212........ None....... Forbidden 25 kg gross D 56, 58, chemical (including 69, 106 when contained in associated equipment, e.g., passenger service units (PSUs), portable breathing equipment (PBE), etc).. + Oxygen generator, 9 NA3356 III 9......... 61 None.......... 213........ None....... Forbidden Forbidden A ....... chemical, spent. Oxygen, mixtures ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... with rare gases, see Rare gases and oxygen mixtures. Oxygen, refrigerated 2.2 UN1073 ....... 2.2, 5.1.. T75, TP5, TP22 320........... 316........ 318........ Forbidden Forbidden D ....... liquid (cryogenic liquid).#
Passage 258Paint including 3 UN1263 I 3......... T11, TP1, TP8 150........... 201........ 243........ 1 L 30 L E ....... paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base. .................... ........... .................. II 3......... B52, IB2, T4, 150........... 173........ 242........ 5 L 60 L B ....... TP1, TP8 .................... ........... .................. III 3......... B1, B52, IB3, T2, 150........... 173........ 242........ 60 L 220 L A ....... TP1 Paint or Paint 8 UN3066 II 8......... B2, IB2, T7, TP2 154........... 173........ 242........ 1 L 30 L A ....... related material. .................... ........... .................. III 8......... B52, IB3, T4, TP1 154........... 173........ 241........ 5 L 60 L A ....... Paint related 3 UN1263 I 3......... T11, TP1, TP8 150........... 201........ 243........ 1 L 30 L E ....... material including paint thinning, drying, removing, or reducing compound. .................... ........... .................. II 3......... B52, IB2, T4, 150........... 173........ 242........ 5 L 60 L B ....... TP1, TP8 .................... ........... .................. III 3......... B1, B52, IB3, T2, 150........... 173........ 242........ 60 L 220 L A ....... TP1 Paper, unsaturated 4.2 UN1379 III 4.2....... IB8, IP3 None.......... 213........ 241........ Forbidden Forbidden A ....... oil treated incompletely dried (including carbon paper). Paraformaldehyde.... 4.1 UN2213 III 4.1....... A1, IB8, IP3 151........... 213........ 240........ 25 kg 100 kg A ....... Paraldehyde......... 3 UN1264 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Paranitroaniline, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solid, see Nitroanilines etc. D Parathion and 2.3 NA1967 ....... 2.3....... 3 None.......... 334........ 245........ Forbidden Forbidden E 40 compressed gas mixture. Paris green, solid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Copper acetoarsenite. A W PCB, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Polychlorinated biphenyls. + Pentaborane......... 4.2 UN1380 I 4.2, 6.1.. 1 None.......... 205.......#
Passage 259. 245........ Forbidden Forbidden D ....... Pentachloroethane... 6.1 UN1669 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Pentachlorophenol... 6.1 UN3155 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Pentaerythrite Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... tetranitrate (dry). Pentaerythrite 4.1 UN3344 II 4.1....... 118 None.......... 214........ None....... Forbidden Forbidden E 40 tetranitrate mixture, desensitized, solid, n.o.s. with more than 10 percent but not more than 20 percent PETN, by mass. Pentaerythrite 1.1D UN0411 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... tetranitrate or Pentaerythritol tetranitrate or PETN, with not less than 7 percent wax by mass. Pentaerythrite 1.1D UN0150 II 1.1D...... 121 None.......... 62......... None....... Forbidden Forbidden 10 ....... tetranitrate, wetted or Pentaerythritol tetranitrate, wetted, or PETN, wetted with not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pentaerythritol tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass. Pentaerythritol ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... tetranitrate, see Pentaerythrite tetranitrate, etc. Pentafluoroethane or 2.2 UN3220 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... Refrigerant gas R 125. Pentamethylheptane.. 3 UN2286 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Pentane-2,4-dione... 3 UN2310 III 3, 6.1.... B1, IB3, T4, TP1 150........... 203........ 242........ 60 L 220 L A ....... Pentanes............ 3 UN1265 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... .................... ........... .................. II 3......... IB2, IP8, T4, TP1 150........... 202........ 242........ 5 L 60 L E ....... Pentanitroaniline Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Pentanols........... 3 UN1105 II 3......... IB2, T4, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP29 .................... ........... .................. III 3......#
Passage 260... B1, B3, IB3, T2, 150........... 203........ 242........ 60 L 220 L A ....... TP1 1-Pentene (n- 3 UN1108 I 3......... T11, TP2 150........... 201........ 243........ 1 L 30 L E ....... amylene). 1-Pentol............ 8 UN2705 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L B 38 Pentolite, dry or 1.1D UN0151 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... wetted with less than 15 percent water, by mass. Pepper spray, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Aerosols, etc. or Self-defense spray, non-pressurized. Perchlorates, 5.1 UN3211 II 5.1....... IB2, T4, TP1 152........... 202........ 242........ 1 L 5 L B 46, 56, inorganic, aqueous 58 solution, n.o.s.. .................... ........... .................. III 5.1....... IB2, T4, TP1 152........... 202........ 241........ 2.5 L 30 L B 56, 58, 69, 106 Pepper spray, see ........... .................. III 5.1....... 152........... 203........ 241........ 2.5 L 30 L B 56, 58, Aerosols, etc. or 69, 106 Self-defense spray, non-pressurized. Perchlorates, 5.1 UN1481 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 46, 56 inorganic, n.o.s.. .................... ........... .................. III 5.1....... IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 46, 56 Perchloric acid, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... with more than 72 percent acid by mass. Perchloric acid with 5.1 UN1873 I 5.1, 8.... A2, A3, N41, T10, None.......... 201........ 243........ Forbidden 2.5 L D 66 more than 50 TP1, TP12 percent but not more than 72 percent acid, by mass.#
Passage 261Perchloric acid with 8 UN1802 II 8, 5.1.... IB2, N41, T7, TP2 None.......... 202........ 243........ Forbidden 30 L C 66 not more than 50 percent acid by mass. Perchloroethylene, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Tetrachloroethylene. Perchloromethyl 6.1 UN1670 I 6.1....... 2, A3, A7, B9, None.......... 227........ 244........ Forbidden Forbidden D 40 mercaptan. B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45 Perchloryl fluoride. 2.3 UN3083 ....... 2.3, 5.1.. 2, B9, B14 None.......... 302........ 314, 315... Forbidden Forbidden D 40 Percussion caps, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Primers, cap type. Perfluoro-2-butene, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Octafluorobut-2- ene. Perfluoro(ethyl 2.1 UN3154 ....... 2.1....... 306........... 302, 304, 314, 315... Forbidden 150 kg E 40 vinyl ether). 305. Perfluoro(methyl 2.1 UN3153 ....... 2.1....... T50 306........... 302, 304, 314, 315... Forbidden 150 kg E 40 vinyl ether). 305. Perfumery products 3 UN1266 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 15 L 60 L B ....... with flammable solvents. .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Permanganates, 5.1 UN3214 II 5.1....... 26, IB2, T4, TP1 152........... 202........ 242........ 1 L 5 L D 56, 58, inorganic, aqueous 69, solution, n.o.s.. 106, 107 Permanganates, 5.1 UN1482 II 5.1....... 26, A30, IB6, IP2 152........... 212........ 242........ 5 kg 25 kg D 56, 58, inorganic, n.o.s.. 69, 106, 107 .................... ........... .................. III 5.1....... 26, A30, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg D 56, 58, 69, 106, 107 Peroxides, 5.1 UN1483 II 5.1....... A7, A20, IB6, None.......... 212........ 242........ 5 kg 25 kg A 13, 75, inorganic, n.o.s.. IP2, N34 106 .................... ........... .................. III 5.1....... A7, A20, IB8, 152........... 213........ 240........ 25 kg 100 kg A 13, 75, IP3, N34 106 Peroxyacetic acid, Forbidden .................. .......... ............. .......... .......... ........... ........... .........#
Passage 262.. ....... with more than 43 percent and with more than 6 percent hydrogen peroxide. Persulfates, 5.1 UN3216 III 5.1....... IB2, T4, TP1, 152........... 203........ 241........ 2.5 L 30 L A ....... inorganic, aqueous TP29 solution, n.o.s.. Persulfates, 5.1 UN3215 III 5.1....... IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... inorganic, n.o.s.. G Pesticides, liquid, 3 UN3021 I 3, 6.1.... B5, T14, TP2, None.......... 201........ 243........ Forbidden 30 L B ....... flammable, toxic, TP13, TP27 flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B ....... TP13, TP27 G Pesticides, liquid, 6.1 UN2903 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 toxic, flammable, TP27 n.o.s. flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2 153........... 203........ 242........ 60 L 220 L A 40 G Pesticides, liquid, 6.1 UN2902 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 toxic, n.o.s.. TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 G Pesticides, solid, 6.1 UN2588 I 6.1....... IB7 None.......... 211........ 242........ 5 kg 50 kg A 40 toxic, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 PETN, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Pentaerythrite tetranitrate. PETN/TNT, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Pentolite, etc. Petrol, see Gasoline ........... .................. .......... ............. .......... .......... ..#
Passage 263......... ........... ........... ....... Petroleum crude oil. 3 UN1267 I 3......... T11, TP1, TP8 None.......... 201........ 243........ 1 L 30 L E ....... .................... ........... .................. II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Petroleum 3 UN1268 I 3......... T11, TP1, TP8 150........... 201........ 243........ 1 L 30 L E ....... distillates, n.o.s. or Petroleum products, n.o.s.. .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Petroleum gases, 2.1 UN1075 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 liquefied or Liquefied petroleum gas. D Petroleum oil....... 3 NA1270 I 3......... T11, TP1, TP9 None.......... 201........ 243........ 1 L 30 L E ....... .................... ........... .................. II 3......... IB2, T7, TP1, 150........... 202........ 242........ 5 L 60 L B ....... TP8, TP28 .................... ........... .................. III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... TP29 Phenacyl bromide.... 6.1 UN2645 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg B 40 + Phenetidines........ 6.1 UN2311 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Phenol, molten...... 6.1 UN2312 II 6.1....... B14, T7, TP3 None.......... 202........ 243........ Forbidden Forbidden B 40#
Passage 264+ Phenol, solid....... 6.1 UN1671 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... N78, T6, TP2 Phenol solutions.... 6.1 UN2821 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... .................... ........... .................. III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Phenolsulfonic acid, 8 UN1803 II 8......... B2, IB2, N41, T7, 154........... 202........ 242........ 1 L 30 L C 14 liquid. TP2 Phenoxyacetic acid 3 UN3346 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 derivative TP27 pesticide, liquid, flammable, toxic flash point less than 23 degrees C.. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Phenoxyacetic acid 6.1 UN3348 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 derivative TP27 pesticide, liquid, toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, 153........... 202........ 243........ 5 L 60 L B 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Phenoxyacetic acid 6.1 UN3347 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 derivative TP27 pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, 153........... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Phenoxyacetic acid 6.1 UN3345 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 derivative pesticide, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 153........... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Phenyl chloroformate 6.1 UN2746 II 6.1, 8.... IB2, T7, TP2, None.......... 202........ 243........ 1 L 30 L A 12, 13, TP13 21, 25, 40, 100 Phenyl isocyanate... 6.1 UN2487 I 6.1, 3.... 2, B9#
Passage 265, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 B74, B77, N33, N34, T20, TP2, TP13, TP38, TP45 Phenyl mercaptan.... 6.1 UN2337 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 26, 40 B74, B77, T20, TP2, TP13, TP38, TP45 Phenyl phosphorus 8 UN2798 II 8......... B2, B15, IB2, T7, 154........... 202........ 242........ Forbidden 30 L B 40 dichloride. TP2 Phenyl phosphorus 8 UN2799 II 8......... B2, B15, IB2, T7, 154........... 202........ 242........ Forbidden 30 L B 40 thiodichloride. TP2 Phenyl urea 6.1 UN3002 I 6.1....... T14, TP2, TP27 None.......... 201........ 243........ 1 L 30 L B 40 pesticides, liquid, toxic. .................... ........... .................. II 6.1....... T7, TP2 None.......... 202........ 243........ 5 L 60 L B 40 .................... ........... .................. III 6.1....... T4, TP1 153........... 203........ 241........ 60 L 220 L A 40 Phenylacetonitrile, 6.1 UN2470 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 26 liquid. Phenylacetyl 8 UN2577 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L C 40 chloride. Phenylcarbylamine 6.1 UN1672 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 chloride. B74, T20, TP2, TP13, TP38, TP45 m-Phenylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diaminediperchlorat e (dry). + Phenylenediamines (o- 6.1 UN1673 III 6.1....... IB8, IP3, T7, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... , m-, p-). Phenylhydrazine..... 6.1 UN2572 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Phenylmercuric 6.1 UN1674 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... acetate. Phenylmercuric 6.1 UN2026 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A ....... compounds, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Phenylmercuric 6.1 UN1894 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg#
Passage 266100 kg A ....... hydroxide. Phenylmercuric 6.1 UN1895 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... nitrate. Phenyltrichlorosilan 8 UN1804 II 8......... A7, B6, IB2, N34, None.......... 202........ 242........ Forbidden 30 L C 40 e. T7, TP2 Phosgene............ 2.3 UN1076 ....... 2.3, 8.... 1, B7, B46 None.......... 192........ 314........ Forbidden Forbidden D 40 9- 4.2 UN2940 II 4.2....... A19, IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg A ....... Phosphabicyclononan es or Cyclooctadiene phosphines. Phosphine........... 2.3 UN2199 ....... 2.3, 2.1.. 1 None.......... 192........ 245........ Forbidden Forbidden D 40 Phosphoric acid..... 8 UN1805 III 8......... A7, IB3, IP3, 154........... 203........ 241........ 5 L 60 L A ....... N34, T4, TP1 Phosphoric acid ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... triethyleneimine, see Tris-(1- aziridiyl)phosphine oxide, solution. Phosphoric ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... anhydride, see Phosphorus pentoxide. Phosphorous acid.... 8 UN2834 III 8......... IB8, IP3, T3, TP1 154........... 213........ 240........ 25 kg 100 kg A 48 Phosphorus, 4.1 UN1338 III 4.1....... A1, A19, B1, B9, None.......... 213........ 243........ 25 kg 100 kg A 74 amorphous. B26, IB8, IP3 Phosphorus bromide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Phosphorus tribromide. Phosphorus chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Phosphorus trichloride.#
Passage 267Phosphorus 4.1 UN1339 II 4.1....... A20, IB4, N34 None.......... 212........ 240........ 15 kg 50 kg B 74 heptasulfide, free from yellow or white phosphorus. Phosphorus 8 UN1939 II 8......... B8, IB8, IP2, None.......... 212........ 240........ Forbidden 50 kg C 12, 40 oxybromide. IP4, N41, N43, T7, TP2 Phosphorus 8 UN2576 II 8......... B2, B8, IB1, N41, None.......... 202........ 242........ Forbidden Forbidden C 40 oxybromide, molten. N43, T7, TP3, TP13 + Phosphorus 8 UN1810 II 8, 6.1.... 2, A7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden C 40 oxychloride. B32, B74, B77, N34, T20, TP2, TP38, TP45 Phosphorus 8 UN2691 II 8......... A7, IB8, IP2, 154........... 212........ 240........ Forbidden 50 kg B 12, 40 pentabromide. IP4, N34 Phosphorus 8 UN1806 II 8......... A7, IB8, IP2, None.......... 212........ 240........ Forbidden 50 kg C 40 pentachloride. IP4, N34 Phosphorus 2.3 UN2198 ....... 2.3, 8.... 2, B9, B14 None.......... 302, 304... 314, 315... Forbidden Forbidden D 40 pentafluoride, compressed. Phosphorus 4.3 UN1340 II 4.3, 4.1.. A20, B59, IB4 151........... 212........ 242........ 15 kg 50 kg B 74 pentasulfide, free from yellow or white phosphorus. Phosphorus pentoxide 8 UN1807 II 8......... A7, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A ....... IP4, N34 Phosphorus 4.1 UN1341 II 4.1....... A20, IB4, N34 None.......... 212........ 240........ 15 kg 50 kg B 74 sesquisulfide, free from yellow or white phosphorus. Phosphorus 8 UN1808 II 8......... A3, A6, A7, B2, None.......... 202........ 242........ Forbidden 30 L C 40 tribromide. B25, IB2, N34, N43, T7, TP2 Phosphorus 6.1 UN1809 I 6.1, 8.... 2, B9, B14, B15, None.......... 227........ 244........ Forbidden Forbidden C 40 trichloride. B32, B74, B77, N34, T20, TP2, TP13, TP38, TP45 Phosphorus trioxide. 8 UN2578 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A 12 Phosphorus 4.1 UN1343 II 4.1....... A20, IB4, N34 None.......... 212........ 240........ 15 kg 50 kg B 74 trisulfide, free from yellow or white phosphorus. Phosphorus, white 4.2 UN1381 I 4.2, 6.1.. B9, B26, N34, T9, None.......... 188........ 243........ Forbidden Forbidden E ....... dry or Phosphorus, TP3 white, under water or Phosphorus white, in solution or Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution. Phosphorus white, 4.2#
Passage 268UN2447 I 4.2, 6.1.. B9, B26, N34, None.......... 188........ 243........ Forbidden Forbidden D ....... molten. T21, TP3, TP7, TP26 Phosphorus (white or Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... red) and a chlorate, mixtures of. Phosphoryl chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Phosphorus oxychloride. Phthalic anhydride 8 UN2214 III 8......... IB8, IP3, T4, TP3 154........... 213........ 240........ 25 kg 100 kg A ....... with more than .05 percent maleic anhydride. Picolines........... 3 UN2313 III 3......... B1, IB3, T4, TP1 150........... 203........ 242........ 60 L 220 L A 40 Picric acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitrophenol, etc. Picrite, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Nitroguanidine, etc. Picryl chloride, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitrochlorobenze ne. Pine oil............ 3 UN1272 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... alpha-Pinene........ 3 UN2368 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Piperazine.......... 8 UN2579 III 8......... IB8, IP3, T4, TP1 154........... 213........ 240........ 25 kg 100 kg A 12 Piperidine.......... 8 UN2401 I 8, 3...... T10, TP2 None.......... 201........ 243........ 0.5 L 2.5 L B ....... Pivaloyl chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Trimethylacetyl chloride. Plastic molding 9 UN3314 III 9......... 32, IB8, IP6 155........... 221........ 221........ 100 kg 200 kg A 85, 87 compound in dough, sheet or extruded rope form evolving flammable vapor. Plastic solvent, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... n.o.s., see Flammable liquids, n.o.s.. Plastics, 4.2 UN2006 III 4.2....... None.......... 213........ None....... Forbidden Forbidden C ....... nitrocellulose- based, self- heating#
Passage 269, n.o.s.. Poisonous gases, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... n.o.s., see Compressed or liquefied gases, flammable or toxic, n.o.s.. Polyalkylamines, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... n.o.s., see Amines, etc. Polychlorinated 9 UN2315 II 9......... 9, 81, 140, IB3, 155........... 202........ 241........ 100 L 220 L A 95 biphenyls, liquid. T4, TP1 Polychlorinated 9 UN2315 II 9......... 9, 81, 140, IB7 155........... 212........ 240........ 100 kg 200 kg A 95 biphenyls, solid. Polyester resin kit. 3 UN3269 ....... 3......... 40 152........... 225........ None....... 5 kg 5 kg B ....... Polyhalogenated 9 UN3151 II 9......... IB3 155........... 204........ 241........ 100 L 220 L A 95 biphenyls, liquid or Polyhalogenated terphenyls liquid. Polyhalogenated 9 UN3152 II 9......... IB8, IP2, IP4 155........... 204........ 241........ 100 kg 200 kg A 95 biphenyls, solid or Polyhalogenated terphenyls, solid.#
Passage 270Polymeric beads, 9 UN2211 III None...... 32, IB8, IP6 155........... 221........ 221........ 100 kg 200 kg A 85, 87 expandable, evolving flammable vapor. Potassium........... 4.3 UN2257 I 4.3....... A19, A20, B27, None.......... 211........ 244........ Forbidden 15 kg D ....... IB1, IP1, N6, N34, T9, TP3, TP7 Potassium arsenate.. 6.1 UN1677 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Potassium arsenite.. 6.1 UN1678 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Potassium bisulfite ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Potassium 4.3 UN1870 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... borohydride. Potassium bromate... 5.1 UN1484 II 5.1....... IB8, IP4 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Potassium carbonyl.. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Potassium chlorate.. 5.1 UN1485 II 5.1....... A9, IB8, IP4, N34 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Potassium chlorate, 5.1 UN2427 II 5.1....... A2, IB2, T4, TP1 152........... 202........ 241........ 1 L 5 L B 56, 58, aqueous solution. 106 .................... ........... .................. III 5.1....... A2, IB2, T4, TP1 152........... 203........ 241........ 2.5 L 30 L B 56, 58, 69, 106 Potassium chlorate ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixed with mineral oil, see Explosive, blasting, type C. Potassium 6.1 UN1679 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 26 cuprocyanide. Potassium cyanide... 6.1 UN1680 I 6.1....... B69, B77, IB7, None.......... 211........ 242........ 5 kg 50 kg B 52 IP1, N74, N75, T14, TP2, TP13 Potassium dichloro ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... isocyanurate or Potassium dichloro- s-triazinetrione, see Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts etc. Potassium dithionite 4.2 UN1929 II 4.2....... A8, A19, A20, None.......... 212........ 241........ 15 kg 50 kg E 13 o#
Passage 271r Potassium IB6, IP2 hydrosulfite. Potassium fluoride.. 6.1 UN1812 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A 26 Potassium 6.1 UN2628 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg E ....... fluoroacetate. Potassium 6.1 UN2655 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 fluorosilicate. Potassium hydrate, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Potassium hydroxide, solid. Potassium hydrogen ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... fluoride, see Potassium hydrogen difluoride. Potassium hydrogen ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... fluoride solution, see Corrosive liquid, n.o.s.. Potassium hydrogen 8 UN2509 II 8......... A7, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A ....... sulfate. IP4, N34 Potassium 8 UN1811 II 8, 6.1.... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg A 25, 26, hydrogendifluoride, N3, N34, T7, TP2 40 solid. Potassium 8 UN1811 II 8, 6.1.... IB8, IP2, IP4, 154........... 202........ 243........ 1 L 30 L A 25, 26, hydrogendifluoride, N3, N34, T7, TP2 40 solution. Potassium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrosulfite, see Potassium dithionite. Potassium hydroxide, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquid, see Potassium hydroxide solution. Potassium hydroxide, 8 UN1813 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... solid. Potassium hydroxide, 8 UN1814 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Potassium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hypochlorite, solution, see Hypochlorite solutions, etc. Potassium, metal 4.3 UN1420 I 4.3....... A19, A20, B27, None..........#
Passage 272211........ 244........ Forbidden 15 kg D ....... alloys. IB4, IP1 Potassium metal, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquid alloy, see Alkali metal alloys, liquid, n.o.s.. Potassium 6.1 UN2864 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... metavanadate. Potassium monoxide.. 8 UN2033 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... Potassium nitrate... 5.1 UN1486 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Potassium nitrate 5.1 UN1487 II 5.1....... B78, IB8, IP4 152........... 212........ 240........ 5 kg 25 kg A 56, 58 and sodium nitrite mixtures. Potassium nitrite... 5.1 UN1488 II 5.1....... IB8, IP4 152........... 212........ 242........ 5 kg 25 kg A 56, 58 Potassium 5.1 UN1489 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 56, 58, perchlorate, solid. 106 Potassium 5.1 UN1489 II 5.1....... IB2, T4, TP1 152........... 202........ 242........ 1 L 5 L A 56, 58, perchlorate, 106 solution. Potassium 5.1 UN1490 II 5.1....... IB8, IP4 152........... 212........ 240........ 5 kg 25 kg D 56, 58, permanganate. 69, 106, 107 Potassium peroxide.. 5.1 UN1491 I 5.1....... A20, IB6, IP1, None.......... 211........ None....... Forbidden 15 kg B 13, 75, N34 106 Potassium persulfate 5.1 UN1492 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Potassium phosphide. 4.3 UN2012 I 4.3, 6.1.. A19, N40 None.......... 211........ None....... Forbidden 15 kg E 40, 85 Potassium selenate, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Selenates or Selenites. Potassium selenite, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Selenates or Selenites.#
Passage 273Potassium sodium 4.3 UN1422 I 4.3....... A19, B27, IB4, None.......... 211........ 244........ Forbidden 15 kg D ....... alloys. IP1, N34, N40, T9, TP3, TP7 Potassium sulfide, 4.2 UN1382 II 4.2....... A19, A20, B16, None.......... 212........ 241........ 15 kg 50 kg A ....... anhydrous or IB6, IP2, N34 Potassium sulfide with less than 30 percent water of crystallization. Potassium sulfide, 8 UN1847 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A 26 hydrated with not less than 30 percent water of crystallization. Potassium superoxide 5.1 UN2466 I 5.1....... A20, IB6, IP1 None.......... 211........ None....... Forbidden 15 kg B 13, 75, 106 Powder cake, wetted 1.1C UN0433 II 1.1C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... or Powder paste, wetted with not less than 17 percent alcohol by mass. Powder cake, wetted 1.3C UN0159 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 ....... or Powder paste, wetted with not less than 25 percent water, by mass. Powder paste, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Powder cake, etc. Powder, smokeless... 1.1C UN0160 II 1.1C...... None.......... 62......... None....... Forbidden Forbidden ........... 26E Powder, smokeless... 1.3C UN0161 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden ........... 26E Power device, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... explosive, see Cartridges, power device. Primers, cap type... 1.4S UN0044 II None...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Primers, cap type... 1.1B UN0377 II 1.1B...... None.......... 62......... None....... Forbidden Forbidden 11 ....... Primers, cap type... 1.4B UN0378 II 1.4B...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Primers, small arms, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Primers, cap type. Primers, tubular.... 1.3G UN0319 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Primers, tubular.... 1.4G UN0320 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Primers, tubular.... 1.4S UN0376#
Passage 274II None...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Printing ink, 3 UN1210 I 3......... T11, TP1, TP8 150........... 173........ 243........ 1 L 30 L E ....... flammable or Printing ink related material (including printing ink thinning or reducing compound), flammable. .................... ........... .................. II 3......... IB2, T4, TP1, TP8 150........... 173........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 173........ 242........ 60 L 220 L A ....... Projectiles, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... illuminating, see Ammunition, illuminating, etc. Projectiles, inert 1.4S UN0345 II 1.4S...... ............. 62......... None....... 25 kg 100 kg 01 ....... with tracer. Projectiles, inert, 1.3G UN0424 II 1.3G...... ............. 62......... None....... Forbidden Forbidden 03 ....... with tracer. Projectiles, inert, 1.4G UN0425 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 02 ....... with tracer. Projectiles, with 1.2D UN0346 II 1.2D...... ............. 62......... None....... Forbidden Forbidden 03 ....... burster or expelling charge. Projectiles, with 1.4D UN0347 II 1.4D...... ............. 62......... None....... Forbidden 75 kg 02 ....... burster or expelling charge. Projectiles, with 1.2F UN0426 II 1.2F...... ............. 62......... None....... Forbidden Forbidden 08 ....... burster or expelling charge. Projectiles, with 1.4F UN0427 II 1.4F...... ............. 62......... None....... Forbidden Forbidden 08 ....... burster or expelling charge. Projectiles, with 1.2G UN0434 II 1.2G...... ............. 62......... None....... Forbidden Forbidden 03 ....... burster or expelling charge. Projectiles, with 1.4G UN0435 II 1.4G...... ............. 62......... None....... Forbidden 75 kg 02 ....... burster or expelling charge. Projectiles, with 1.1F UN0167 II 1.1F...... ............. 62......... None....... Forbidden Forbidden 08 ....... bursting charge. Projectiles, with 1.1D UN0168 II 1.1D...... ............. 62......... None....... Forbidden Forbidden 03 ....... bursting charge. Projectiles, with 1.2D UN0169 II 1.2D...... ............. 62......... None....... Forbidden Forbidden 03 ....... bursting charge. Projectiles, with 1.2F UN0324#
Passage 275II 1.2F...... ............. 62......... None....... Forbidden Forbidden 08 ....... bursting charge. Projectiles, with 1.4D UN0344 II 1.4D...... ............. 62......... None....... Forbidden 75 kg 02 ....... bursting charge. Propadiene, 2.1 UN2200 ....... 2.1....... None.......... 304........ 314, 315... Forbidden 150 kg B 40 stabilized. Propadiene mixed ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... with methyl acetylene, see Methyl acetylene and propadiene mixtures, stabilized. Propane see also 2.1 UN1978 ....... 2.1....... 19, T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 Petroleum gases, liquefied. Propanethiols....... 3 UN2402 II 3......... IB2, T4, TP1, 150........... 202........ 242........ 5 L 60 L E 95, 102 TP13 n-Propanol or Propyl 3 UN1274 II 3......... B1, IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... alcohol, normal. .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Propellant, liquid.. 1.3C UN0495 II 1.3C...... 37 None.......... 62......... None....... Forbidden Forbidden 10 ....... Propellant, liquid.. 1.1C UN0497 II 1.1C...... 37 None.......... 62......... None....... Forbidden Forbidden 10 ....... Propellant, solid... 1.1C UN0498 II 1.1C...... None.......... 62......... None....... Forbidden Forbidden ........... 26E Propellant, solid... 1.3C UN0499 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden ........... 26E Propellant, solid... 1.4C UN0501 ....... 1.4C...... None.......... 62......... None....... Forbidden Forbidden A 24E Propionaldehyde..... 3 UN1275 II 3......... IB2, T7, TP1 150........... 202........ 242........ 5 L 60 L E ....... Propionic acid...... 8 UN1848 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Propionic anhydride. 8 UN2496 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Propionitrile....... 3 UN2404 II 3, 6.1.... IB2, T7, TP1, None.......... 202........ 243........ Forbidden 60 L E 40 TP13 Propionyl chloride.. 3 UN1815 II 3, 8...... IB1, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 n-Propyl acetate.... 3 UN1276 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B .......#
Passage 276Propyl alcohol, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Propanol. n-Propyl benzene.... 3 UN2364 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Propyl chloride..... 3 UN1278 II 3......... IB2, IP8, N34, None.......... 202........ 242........ Forbidden 60 L E ....... T7, TP2#
Passage 277n-Propyl 6.1 UN2740 I 6.1, 3, 8. 2, A3, A6, A7, None.......... 227........ 244........ Forbidden Forbidden B 21, 40, chloroformate. B9, B14, B32, 100 B74, B77, N34, T20, TP2, TP13, TP38, TP44 Propyl formates..... 3 UN1281 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... n-Propyl isocyanate. 6.1 UN2482 I 6.1, 3.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP38, TP44 Propyl mercaptan, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Propanethiols. n-Propyl nitrate.... 3 UN1865 II 3......... IB2, IP7 150........... 202........ None....... 5 L 60 L D ....... Propylamine......... 3 UN1277 II 3, 8...... IB2, N34, T7, TP1 None.......... 202........ 243........ 1 L 5 L E 40 Propylene see also 2.1 UN1077 ....... 2.1....... 19, T50 306........... 304........ 314, 315... Forbidden 150 kg E 40 Petroleum gases, liquefied. Propylene 6.1 UN2611 II 6.1, 3.... IB2, T7, TP2, None.......... 202........ 243........ 5 L 60 L A 12, 40, chlorohydrin. TP13 48 Propylene oxide..... 3 UN1280 I 3......... A3, N34, T11, None.......... 201........ 243........ 1 L 30 L E 40 TP2, TP7 Propylene tetramer.. 3 UN2850 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... 1,2-Propylenediamine 8 UN2258 II 8, 3...... A3, A6, IB2, N34, None.......... 202........ 243........ 1 L 30 L A 40 T7, TP2 Propyleneimine, 3 UN1921 I 3, 6.1.... A3, N34, T14, None.......... 201........ 243........ 1 L 30 L B 40 stabilized. TP2, TP13 Propyltrichlorosilan 8 UN1816 II 8, 3...... A7, B2, B6, IB2, None.......... 202........ 243........ Forbidden 30 L C 40 e. N34, T7, TP2, TP13 Prussic acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrogen cyanide. Pyrethroid 3 UN3350 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticide, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Pyrethroid 6.1 UN3352 I 6.1....... T14, TP2, TP13, None.......... 211........ 242........ 1 L 30 L A 40 pesticide, liquid TP27 toxic. ....................#
Passage 278........... .................. II 6.1....... IB2, T11, TP2, 153........... 212........ 242........ 5 L 60 L A 40 TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 213........ 240........ 60 L 220 L A 40 TP28 Pyrethroid 6.1 UN3351 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 pesticide, liquid, TP27 toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L B 40 TP28 Pyrethroid 6.1 UN3349 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticide, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 153........... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Pyridine............ 3 UN1282 II 3......... IB2, T4, TP2 None.......... 202........ 242........ 5 L 60 L B 21, 100 Pyridine perchlorate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... G Pyrophoric liquid, 4.2 UN3194 I 4.2....... None.......... 181........ 244........ Forbidden Forbidden D 18 inorganic, n.o.s.. G Pyrophoric liquids, 4.2 UN2845 I 4.2....... B11, T22, TP2, None.......... 181........ 244........ Forbidden Forbidden D 18 organic, n.o.s.. TP7 G Pyrophoric metals, 4.2 UN1383 I 4.2....... B11 None.......... 187........ 242........ Forbidden Forbidden D ....... n.o.s., or Pyrophoric alloys, n.o.s.. G Pyrophoric 4.2 UN3203 I 4.2, 4.3.. T21, TP2, TP7 None.......... 187........ 242........ Forbidden Forbidden D 18 organometallic compound, water- reactive, n.o.s.. G Pyrophoric solid, 4.2 UN3200 I 4.2....... None.......... 187........ 242........ Forbidden Forbidden D ....... inorganic, n.o.s.. G Pyrophoric solids, 4.2 UN2846 I 4.2....... None.......... 187........ 242........ Forbidden Forbidden D ....... organic, n.o.s.. Pyrosulfuryl 8 UN1817 II 8......... B2, IB2, T8, TP2, 154........... 202........ 242........ 1 L 30 L C 40 chloride. TP12 Pyroxylin solution ........... ......#
Passage 279............ .......... ............. .......... .......... ........... ........... ........... ....... or solvent, see Nitrocellulose. Pyrrolidine......... 3 UN1922 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 Quebrachitol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... pentanitrate. Quicklime, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Calcium oxide. Quinoline........... 6.1 UN2656 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A 12 R 12, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Dichlorodifluoromet hane. R 12B1, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorodifluorobromo methane. R 13, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorotrifluorometh ane. R 13B1, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Bromotrifluorometha ne. R 14, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Tetrafluoromethane. R 21, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Dichlorofluorometha ne. R 22, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorodifluorometha ne. R 114, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Dichlorotetrafluoro ethane. R 115, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chloropentafluoroet hane. R 116, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hexafluoroethane. R 124, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorotetrafluoroet hane. R 133a, see#
Passage 280........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorotrifluoroetha ne.#
Passage 281R 152a, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Difluoroethane. R 500, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Dichlorodifluoromet hane and difluorethane, etc. R 502, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorodifluorometha ne and chloropentafluoroet hane mixture, etc. R 503, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Chlorotrifluorometh ane and trifluoromethane, etc. D Radioactive 7 UN2910 ....... None...... 422, 426...... 422, 426... 422, 426... ........... ........... A ....... material, excepted package-articles manufactured from natural or depleted uranium or natural thorium. I Radioactive 7 UN2909 ....... None...... 422, 426...... 422, 426... 422, 426... ........... ........... A ....... material, excepted package-articles manufactured from natural uranium or depleted uranium or natural thorium. D Radioactive 7 UN2910 ....... Empty..... 428........... 428........ 428........ ........... ........... A ....... material, excepted package-empty package or empty packaging. I Radioactive 7 UN2908 ....... Empty..... 422, 428...... 422, 428... 422, 428... ........... ........... A ....... material, excepted package-empty packaging. D Radioactive 7 UN2910 ....... None...... 422, 424...... 422, 424... 422, 424... ........... ........... A ....... material, excepted package-instruments or articles. I Radioactive 7 UN2911 ....... None...... 422, 424...... 422, 424... 422, 424... ........... ........... A ....... material, excepted package-instruments or articles. Radioactive 7 UN2910 ....... None...... 421, 422...... 421, 422... 421, 422... ........... ........... A ....... material, excepted package-limited quantity of material. D Radioactive 7 UN2918 ....... 7......... 453........... 417........ 417........ ........... ........... A 40, 95 material, fissile, n.o.s.. I Radioactive 7 UN2912 ....... 7......... T5, TP4, W7 421, 422, 428. 427........ 427........ ........... ........... A 95 material, low specific activity (LSA-I) non fissile or fissile-excepted. I Radioactive 7 UN3321 ....... 7......... T5, TP4, W7 421, 422, 428.#
Passage 282427........ 427........ ........... ........... A 95 material, low specific activity (LSA-II) non fissile or fissile- excepted. I Radioactive 7 UN3322 ....... 7......... T5, TP4, W7 421, 422, 428. 427........ 427........ ........... ........... A 95 material, low specific activity (LSA-III) non fissile or fissile excepted. D Radioactive 7 UN2912 ....... 7......... T5, TP4 421, 428...... 427........ 427........ ........... ........... A ....... material, low specific activity, n.o.s. or Radioactive material, LSA, n.o.s.. D Radioactive 7 UN2982 ....... 7......... 421, 428...... 415, 416... 415, 416... ........... ........... A 40, 95 material, n.o.s.. D Radioactive 7 UN2974 ....... 7......... 421, 424...... 415, 416... 415, 416... ........... ........... A ....... material, special form, n.o.s.. D Radioactive 7 UN2913 ....... 7......... ................. 421, 424, 426. 427........ 427........ ........... ........... A ....... material, surface contaminated object or Radioactive material, SCO. I Radioactive 7 UN2913 ....... 7......... 421, 422, 428. 427........ 427........ ........... ........... A 95 material, surface contaminated objects (SCO-I or SCO-II) non fissile or fissile-excepted. I Radioactive 7 UN2919 ....... 7......... 139 ............. .......... .......... ........... ........... ........... ....... material, transported under special arrangement, non fissile or fissile excepted. I Radioactive 7 UN3331 ....... 7......... 139 ............. .......... .......... ........... ........... ........... ....... material, transported under special arrangement, fissile. I Radioactive 7 UN3327 ....... 7......... W7, W8 453........... 417........ 417........ ........... ........... A 95 material, Type A package, fissile non-special form. I Radioactive 7 UN2915 ....... 7......... W7, W8 ............. 415........ 415........ ........... ........... A 95 material, Type A package non-special form, non fissile or fissile-excepted. I Radioactive 7 UN3332 ....... 7......... W7, W8 ............. 415, 476... 415, 476... ........... ........... A 95 material, Type A package, special form non fissile or fissile-excepted. I Radioactive 7 UN3333 ....... 7......... W7, W8 453........... 417, 476... 417, 476... ........... ........... A ....... material, Type A package, special form, fissile. I Radioactive 7 UN3329 ....... 7......... 453........... 417........ 417........#
Passage 283........... ........... A ....... material, Type B(M) package, fissile. I Radioactive 7 UN2917 ....... 7......... ............. 416........ 416........ ........... ........... A 95 material, Type B(M) package non fissile or fissile-excepted. I Radioactive 7 UN3328 ....... 7......... 453........... 417........ 417........ ........... ........... A ....... material, Type B(U) package, fissile. I Radioactive 7 UN2916 ....... 7......... ............. 416........ 416........ ........... ........... A 95 material, Type B(U) package non fissile or fissile-excepted. I Radioactive 7 UN2978 ....... 7, 8...... 423........... 420, 427... 420, 427... ........... ........... A 95 material, uranium hexafluoride non fissile or fissile- excepted. I Radioactive 7 UN2977 ....... 7, 8...... 453........... 417, 420... 417, 420... ........... ........... A ....... material, uranium hexafluoride, fissile.#
Passage 284Railway torpedo, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Signals, railway track, explosive. Rare gases and 2.2 UN1981 ....... 2.2....... 306........... 302........ None....... 75 kg 150 kg A ....... nitrogen mixtures, compressed. Rare gases and 2.2 UN1980 ....... 2.2....... 79 306........... 302........ None....... 75 kg 150 kg A ....... oxygen mixtures, compressed. Rare gases mixtures, 2.2 UN1979 ....... 2.2....... 306........... 302........ None....... 75 kg 150 kg A ....... compressed. RC 318, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Octafluorocyclobuta ne. RDX and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... cyclotetramethylene tetranitramine, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized. RDX and HMX 1.1D UN0391 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... mixtures, wetted with not less than 15 percent water by mass or RDX and HMX mixtures, desensitized with not less than 10 percent phlegmatizer by mass. RDX and Octogen ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. RDX, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Cyclotrimethylene trinitramine, etc. Receptacles, small, 2.1 UN2037 ....... 2.1....... 306........... 304........ None....... 1 kg 15 kg B 40 containing gas (gas cartridges) flammable, without release device, not refillable and not exceeding 1 L capacity. Receptacles, small, 2.2 UN2037 ....... 2.2....... 306........... 304........ None....... 1 kg 15 kg B 40 containing gas (gas cartridges) non- flammable, without release device, not refillable and not exceeding 1 L capacity. Red phosphorus, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Phosphorus, amorphous. Refrigerant gas R 2.2 UN3337 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... 404A. Refrigerant gas R 2.2 UN3338 ....... 2.2...#
Passage 285.... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... 407A. Refrigerant gas R 2.2 UN3339 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... 407B. Refrigerant gas R 2.2 UN3340 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... 407C. G Refrigerant gases, 2.2 UN1078 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... n.o.s.. D Refrigerant gases, 2.1 NA1954 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg D 40 n.o.s. or Dispersant gases, n.o.s.. Refrigerating 2.1 UN3358 ....... 2.1....... 306........... 306........ 306........ Forbidden Forbidden C 40 machines, containing flammable, non- toxic, liquefied gas. Refrigerating 2.2 UN2857 ....... 2.2....... A53 306, 307...... 306........ 306, 307... 450 kg 450 kg A ....... machines, containing non- flammable, non- toxic, liquefied gas or ammonia solution (UN2672). Regulated medical 6.2 UN3291 II 6.2....... A13, A14 134........... 197........ None....... No limit No limit E ....... waste. Release devices, 1.4S UN0173 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... explosive. Resin solution, 3 UN1866 I 3......... B52, T11, TP1, 150........... 201........ 243........ 1 L 30 L E ....... flammable. TP8 .................... ........... .................. II 3......... B52, IB2, T4, 150........... 173........ 242........ 5 L 60 L B ....... TP1, TP8 .................... ........... .................. III 3......... B1, B52, IB3, T2, 150........... 173........ 242........ 60 L 220 L A ....... TP1 Resorcinol.......... 6.1 UN2876 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Rifle grenade, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Grenades, hand or rifle, etc. Rifle powder, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Powder, smokeless (UN 0160). Rivets, explosive... 1.4S UN0174 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Road asphalt or tar ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... liquid, see Tars, liquid, etc. Rocket motors....... 1.3C UN#
Passage 2860186 II 1.3C...... 109 None.......... 62......... None....... Forbidden 220 kg 03 ....... Rocket motors....... 1.1C UN0280 II 1.1C...... 109 None.......... 62......... None....... Forbidden Forbidden 03 ....... Rocket motors....... 1.2C UN0281 II 1.2C...... 109 None.......... 62......... None....... Forbidden Forbidden 03 ....... Rocket motors, 1.2J UN0395 II 1.2J...... 109 None.......... 62......... None....... Forbidden Forbidden 04 23E liquid fueled. Rocket motors, 1.3J UN0396 II 1.3J...... 109 None.......... 62......... None....... Forbidden Forbidden 04 23E liquid fueled. Rocket motors with 1.3L UN0250 II 1.3L...... 109 None.......... 62......... None....... Forbidden Forbidden 08 8E, hypergolic liquids 14E, with or without an 15E expelling charge. Rocket motors with 1.2L UN0322 II 1.2L...... 109 None.......... 62......... None....... Forbidden Forbidden 08 8E, hypergolic liquids 14E, with or without an 15E expelling charge. Rockets, line- 1.2G UN0238 II 1.2G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... throwing. Rockets, line- 1.3G UN0240 II 1.3G...... None.......... 62......... None....... Forbidden 75 kg 07 ....... throwing. Rockets, line- 1.4G UN0453 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... throwing. Rockets, liquid 1.1J UN0397 II 1.1J...... None.......... 62......... None....... Forbidden Forbidden 04 23E fueled with bursting charge. Rockets, liquid 1.2J UN0398 II 1.2J...... None.......... 62......... None....... Forbidden Forbidden 04 23E fueled with bursting charge.#
Passage 287Rockets, with 1.1F UN0180 II 1.1F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... bursting charge. Rockets, with 1.1E UN0181 II 1.1E...... None.......... 62......... None....... Forbidden Forbidden 03 ....... bursting charge. Rockets, with 1.2E UN0182 II 1.2E...... None.......... 62......... None....... Forbidden Forbidden 03 ....... bursting charge. Rockets, with 1.2F UN0295 II 1.2F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... bursting charge. Rockets, with 1.2C UN0436 II 1.2C...... None.......... 62......... None....... Forbidden Forbidden 03 ....... expelling charge. Rockets, with 1.3C UN0437 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 03 ....... expelling charge. Rockets, with 1.4C UN0438 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 02 ....... expelling charge. Rockets, with inert 1.3C UN0183 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 03 ....... head. Rockets, with inert 1.2C UN0502 ....... 1.2....... None.......... 62......... None....... Forbidden Forbidden B 1E, 5E head. Rosin oil........... 3 UN1286 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Rubber solution..... 3 UN1287 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Rubidium............ 4.3 UN1423 I 4.3....... 22, A7, A19, IB1, None.......... 211........ 242........ Forbidden 15 kg D ....... IP1, N34, N40, N45 Rubidium hydroxide.. 8 UN2678 II 8......... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg A ....... T7, TP2 Rubidium hydroxide 8 UN2677 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Safety fuse, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Fuse, safety. Sand acid, see ........... .................. ...#
Passage 288....... ............. .......... .......... ........... ........... ........... ....... Fluorosilicic acid. Seed cake, 4.2 UN1386 III None...... IB8, IP3, IP6, N7 None.......... 213........ 241........ Forbidden Forbidden A 13 containing vegetable oil solvent extractions and expelled seeds, with not more than 10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined. I Seed cake with more 4.2 UN1386 III None...... IB8, IP3, IP6, N7 None.......... 213........ 241........ Forbidden Forbidden E 13 than 1.5 percent oil and not more than 11 percent moisture. I Seed cake with not 4.2 UN2217 III None...... IB8, IP3, IP6, N7 None.......... 213........ 241........ Forbidden Forbidden A 13 more than 1.5 percent oil and not more than 11 percent moisture. Selenates or 6.1 UN2630 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg E ....... Selenites. Selenic acid........ 8 UN1905 I 8......... IB7, IP1, N34 None.......... 211........ 242........ Forbidden 25 kg A ....... Selenium compound, 6.1 UN3283 I 6.1....... IB7, IP1, T14, None.......... 211........ 242........ 5 kg 50 kg B ....... n.o.s.. TP2, TP27 .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B ....... T11, TP2, TP27 .................... ........... .................. III 6.1....... IB8, IP3, T7, 153........... 213........ 240........ 100 kg 200 kg A ....... TP1, TP28 Selenium disulfide.. 6.1 UN2657 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Selenium 2.3 UN2194 ....... 2.3, 8.... 1 None.......... 302........ None....... Forbidden Forbidden D 40 hexafluoride. Selenium nitride.... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenium oxychloride 8 UN2879 I 8, 6.1.... A3, A6, A7, N34, None.......... 201........ 243........ 0.5 L 2.5 L E 40 T10, TP2, TP12, TP13 Self-defense spray, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... aerosol, see Aerosols, etc. + A D Self-defense spray, 9 NA3334 III 9......... A37 155........... 203........ None....... No limit No limit A ....... non-pressurized. G Self-heating liquid, 4.2 UN3188 II 4.2, 8.... IB2 No#
Passage 289ne.......... 202........ 243........ 1 L 5 L C ....... corrosive, inorganic, n.o.s.. .................... ........... .................. III 4.2, 8.... IB2 None.......... 203........ 241........ 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3185 II 4.2, 8.... IB2 None.......... 202........ 243........ 1 L 5 L C ....... corrosive, organic, n.o.s.. .................... ........... .................. III 4.2, 8.... IB2 None.......... 203........ 241........ 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3186 II 4.2....... IB2 None.......... 202........ 242........ 1 L 5 L C ....... inorganic, n.o.s.. .................... ........... .................. III 4.2....... IB2 None.......... 203........ 241........ 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3183 II 4.2....... IB2 None.......... 202........ 242........ 1 L 5 L C ....... organic, n.o.s.. .................... ........... .................. III 4.2....... IB2 None.......... 203........ 241........ 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3187 II 4.2, 6.1.. IB2 None.......... 202........ 243........ 1 L 5 L C ....... toxic, inorganic, n.o.s.. .................... ........... .................. III 4.2, 6.1.. IB2 None.......... 203........ 241........ 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3184 II 4.2, 6.1.. IB2 None.......... 202........ 243........ 1 L 5 L C ....... toxic, organic, n.o.s.. .................... ........... .................. III 4.2, 6.1.. IB2 None.......... 203........ 241........ 5 L 60 L C ....... G Self-heating solid, 4.2 UN3192 II 4.2, 8.... IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... corrosive, inorganic, n.o.s.. .................... ........... .................. III 4.2, 8.... IB8, IP3 None.......... 213........ 242........ 25 kg 100 kg C ....... G Self-heating, solid, 4.2 UN3126 II 4.2, 8.... IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... corrosive, organic, n.o.s.. .................... ........... .................. III 4.2, 8.... IB8, IP3 None.......... 213........ 242........ 25 kg 100 kg C ....... G Self-heating solid, 4.2 UN3190 II 4.2....... IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg C ....... inorganic, n.o.s.. .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg C ....... G Self-heating, solid, 4.2 UN3088 II 4.#
Passage 2902....... IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg C ....... organic, n.o.s.. .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg C ....... G Self-heating, solid, 4.2 UN3127 ....... 4.2, 5.1.. None.......... 214........ 214........ Forbidden Forbidden ........... ....... oxidizing, n.o.s.. G Self-heating solid, 4.2 UN3191 II 4.2, 6.1.. IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... toxic, inorganic, n.o.s.. .................... ........... .................. III 4.2, 6.1.. IB8, IP3 None.......... 213........ 242........ 25 kg 100 kg C .......#
Passage 291G Self-heating, solid, 4.2 UN3128 II 4.2, 6.1.. IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... toxic, organic, n.o.s.. .................... ........... .................. III 4.2, 6.1.. IB8, IP3 None.......... 213........ 242........ 25 kg 100 kg C ....... Self-propelled ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... vehicle, see Engines or Batteries etc. G Self-reactive liquid 4.1 UN3221 II 4.1....... 53 None.......... 224........ None....... Forbidden Forbidden D 61 type B. G Self-reactive liquid 4.1 UN3231 II 4.1....... 53 None.......... 224........ None....... Forbidden Forbidden D 2, 61 type B, temperature controlled. G Self-reactive liquid 4.1 UN3223 II 4.1....... None.......... 224........ None....... 5 L 10 L D 61 type C. G Self-reactive liquid 4.1 UN3233 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type C, temperature controlled. G Self-reactive liquid 4.1 UN3225 II 4.1....... None.......... 224........ None....... 5 L 10 L D 61 type D. G Self-reactive liquid 4.1 UN3235 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type D, temperature controlled. G Self-reactive liquid 4.1 UN3227 II 4.1....... None.......... 224........ None....... 10 L 25 L D 61 type E. G Self-reactive liquid 4.1 UN3237 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type E, temperature controlled. G Self-reactive liquid 4.1 UN3229 II 4.1....... None.......... 224........ None....... 10 L 25 L D 61 type F. G Self-reactive liquid 4.1 UN3239 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type F, temperature controlled. G Self-reactive solid 4.1 UN3222 II 4.1....... 53 None.......... 224........ None....... Forbidden Forbidden D 61 type B. G Self-reactive solid 4.1 UN3232 II 4.1....... 53 None.......... 224........ None....... Forbidden Forbidden D 2, 61 type B, temperature controlled. G Self-reactive solid 4.1 UN3224 II 4.1....... None.......... 224........ None....... 5 kg 10 kg D 61 type C. G Self-reactive solid 4.1 UN3234 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type C, temperature controlled. G Self-reactive solid 4.1 UN3226 II 4.1....... None.......... 224........ None....... 5 kg 10 kg D 61 type D. G Self-r#
Passage 292eactive solid 4.1 UN3236 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type D, temperature controlled. G Self-reactive solid 4.1 UN3228 II 4.1....... None.......... 224........ None....... 10 kg 25 kg D 61 type E. G Self-reactive solid 4.1 UN3238 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type E, temperature controlled. G Self-reactive solid 4.1 UN3230 II 4.1....... None.......... 224........ None....... 10 kg 25 kg D 61 type F. G Self-reactive solid 4.1 UN3240 II 4.1....... None.......... 224........ None....... Forbidden Forbidden D 2, 61 type F, temperature controlled. Shale oil........... 3 UN1288 I 3......... T11, TP1, TP8, None.......... 201........ 243........ 1 L 30 L B ....... TP27 .................... ........... .................. II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Shaped charges, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Charges, shaped, etc. Signal devices, hand 1.4G UN0191 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Signal devices, hand 1.4S UN0373 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Signals, distress, 1.1G UN0194 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... ship. Signals, distress, 1.3G UN0195 II 1.3G...... None.......... 62......... None....... Forbidden 75 kg 07 ....... ship. Signals, highway, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Signal devices, hand. Signals, railway 1.1G UN0192 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... track, explosive. Signals, railway 1.4S UN0193 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... track, explosive. Signals, railway 1.3G UN0492 ....... 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... track, explosive. Signals, railway 1.4G UN0493 ....... 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... track, explosive. Signals, ship ........... .#
Passage 293................. .......... ............. .......... .......... ........... ........... ........... ....... distress, water- activated, see Contrivances, water- activated, etc. Signals, smoke...... 1.1G UN0196 II 1.1G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Signals, smoke...... 1.4G UN0197 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... Signals, smoke...... 1.2G UN0313 II 1.2G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Signals, smoke...... 1.3G UN0487 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... Silane, compressed.. 2.1 UN2203 ....... 2.1....... None.......... 302........ None....... Forbidden Forbidden E 40, 57, 104 Silicofluoric acid, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Fluorosilicic acid. Silicon chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Silicon tetrachloride. Silicon powder, 4.1 UN1346 III 4.1....... A1, IB8, IP3 None.......... 213........ 240........ 25 kg 100 kg A ....... amorphous. Silicon 8 UN1818 II 8......... A3, A6, B2, B6, 154........... 202........ 242........ 1 L 30 L C 40 tetrachloride. IB2, T7, TP2, TP7 Silicon 2.3 UN1859 ....... 2.3, 8.... 2 None.......... 302........ None....... Forbidden Forbidden D 40 tetrafluoride, compressed. Silver acetylide Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Silver arsenite..... 6.1 UN1683 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Silver azide (dry).. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Silver chlorite Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Silver cyanide...... 6.1 UN1684 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 26, 40 Silver fulminate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Silver nitrate...... 5.1 UN1493 II 5.1....... IB8, IP4 152........... 212........ 242........#
Passage 2945 kg 25 kg A ....... Silver oxalate (dry) Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Silver picrate (dry) Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Silver picrate, 4.1 UN1347 I 4.1....... None.......... 211........ None....... Forbidden Forbidden D 28, 36 wetted with not less than 30 percent water, by mass. Sludge, acid........ 8 UN1906 II 8......... A3, A7, B2, IB2, None.......... 202........ 242........ Forbidden 30 L C 14 N34, T8, TP2, TP12 D Smokeless powder for 4.1 NA3178 I 4.1....... 16 None.......... 171........ None....... Forbidden 7.3 kg A ....... small arms (100 pounds or less). Soda lime with more 8 UN1907 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... than 4 percent sodium hydroxide.#
Passage 295Sodium.............. 4.3 UN1428 I 4.3....... A7, A8, A19, A20, None.......... 211........ 244........ Forbidden 15 kg D ....... B9, B48, B68, IB4, IP1, N34, T9, TP3, TP7, TP46 Sodium aluminate, 8 UN2812 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... solid. Sodium aluminate, 8 UN1819 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A ....... solution. .................... ........... .................. III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Sodium aluminum 4.3 UN2835 II 4.3....... A8, A19, A20, IB1 151........... 212........ 242........ Forbidden 50 kg E ....... hydride. Sodium ammonium 6.1 UN2863 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... vanadate. Sodium arsanilate... 6.1 UN2473 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Sodium arsenate..... 6.1 UN1685 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Sodium arsenite, 6.1 UN1686 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... aqueous solutions. .................... ........... .................. III 6.1....... IB3, T4, TP2 153........... 203........ 241........ 60 L 220 L A ....... Sodium arsenite, 6.1 UN2027 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... solid. Sodium azide........ 6.1 UN1687 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 36, 52, 91 Sodium bifluoride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sodium hydrogendifluoride. Sodium bisulfite, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Sodium borohydride.. 4.3 UN1426 I 4.3....... N40 None.......... 211........ 242........ Forbidden 15 kg E ....... Sodium borohydride 8 UN3320 II 8......... B2, IB2, N34, T7, 154........... 202........ 242........ 1 L 30 L A 26 and sodium TP2 hydroxide solution, with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass. .................... ........... .................. III 8......... B2, IB3, N34, T4, 1#
Passage 29654........... 203........ 241........ 5 L 60 L A ....... TP2 Sodium bromate...... 5.1 UN1494 II 5.1....... IB8, IP4 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Sodium cacodylate... 6.1 UN1688 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 26 Sodium chlorate..... 5.1 UN1495 II 5.1....... A9, IB8, IP4, 152........... 212........ 240........ 5 kg 25 kg A 56, 58, N34, T4, TP1 106 Sodium chlorate, 5.1 UN2428 II 5.1....... A2, IB2, T4, TP1 152........... 202........ 241........ 1 L 5 L B 56, 58, aqueous solution. 106 .................... ........... .................. III 5.1....... A2, IB2, T4, TP1 152........... 203........ 241........ 2.5 L 30 L B 56, 58, 69, 106 Sodium chlorate ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... mixed with dinitrotoluene, see Explosive blasting, type C. Sodium chlorite..... 5.1 UN1496 II 5.1....... A9, IB8, IP2, None.......... 212........ 242........ 5 kg 25 kg A 56, 58, IP4, N34, T4, TP1 106 Sodium chloroacetate 6.1 UN2659 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... Sodium cuprocyanide, 6.1 UN2316 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 26 solid. Sodium cuprocyanide, 6.1 UN2317 I 6.1....... T14, TP2, TP13 None.......... 201........ 243........ 1 L 30 L B 26, 40 solution. Sodium cyanide...... 6.1 UN1689 I 6.1....... B69, B77, IB7, None.......... 211........ 242........ 5 kg 50 kg B 52 IP1, N74, N75, T14, TP2, TP13 Sodium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... dichloroisocyanurat e or Sodium dichloro-s- triazinetrione, see Dichloroisocyanuric acid etc. Sodium dinitro-o- 1.3C UN0234 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 5E cresolate, dry or wetted with less than 15 percent water, by mass. Sodium dinitro-o- 4.1 UN1348 I 4.1, 6.1.. 23, A8, A19, A20, None.......... 211........ None....... 1 kg 15 kg E 28, 36 cresolate, wetted N41 with not less than 15 percent water, by mass. Sodium dithionite or 4.2 UN1384 II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg E 13 Sodium hydrosulfite. IP2 Sodium fluoride..... 6.1 UN1690 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240.......#
Passage 297. 100 kg 200 kg A 26 Sodium fluoroacetate 6.1 UN2629 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg E ....... Sodium 6.1 UN2674 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 fluorosilicate. Sodium hydrate, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Sodium hydroxide, solid. Sodium hydride...... 4.3 UN1427 I 4.3....... A19, N40 None.......... 211........ 242........ Forbidden 15 kg E ....... Sodium 8 UN2439 II 8......... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg A 12, 25, hydrogendifluoride, N3, N34 26, 40 solid. Sodium 8 UN2439 II 8......... IB8, IP2, IP4, 154........... 202........ 242........ 1 L 30 L A 12, 25, hydrogendifluoride N3, N34 26, 40 solution. Sodium hydrosulfide, 4.2 UN2318 II 4.2....... A7, A19, A20, None.......... 212........ 241........ 15 kg 50 kg A ....... with less than 25 IB6, IP2 percent water of crystallization. Sodium hydrosulfide 8 UN2949 II 8......... A7, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A 26 with not less than IP4, T7, TP2 25 percent water of crystallization. Sodium hydrosulfite, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sodium dithionite. Sodium hydroxide, 8 UN1823 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... solid. Sodium hydroxide 8 UN1824 II 8......... B2, IB2, N34, T7, 154........... 202........ 242........ 1 L 30 L A ....... solution. TP2 .................... ........... .................. III 8......... IB3, N34, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... Sodium hypochlorite, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Hypochlorite solutions etc.#
Passage 298Sodium metal, liquid ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... alloy, see Alkali metal alloys, liquid, n.o.s.. Sodium methylate.... 4.2 UN1431 II 4.2, 8.... A19, IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg B ....... Sodium methylate 3 UN1289 II 3, 8...... IB2, T7, TP1, TP8 None.......... 202........ 243........ 1 L 5 L B ....... solutions in alcohol. .................... ........... .................. III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A ....... Sodium monoxide..... 8 UN1825 II 8......... IB8, IP2, IP4 154........... 212........ 240........ 15 kg 50 kg A ....... Sodium nitrate...... 5.1 UN1498 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Sodium nitrate and 5.1 UN1499 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... potassium nitrate mixtures. Sodium nitrite...... 5.1 UN1500 III 5.1, 6.1.. A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 56, 58 Sodium 6.1 UN2567 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... pentachlorophenate. Sodium perchlorate.. 5.1 UN1502 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Sodium permanganate. 5.1 UN1503 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg D 56, 58, 69, 106, 107 Sodium peroxide..... 5.1 UN1504 I 5.1....... A20, IB6, IP1, None.......... 211........ None....... Forbidden 15 kg B 13, 75, N34 106 Sodium peroxoborate, 5.1 UN3247 II 5.1....... IB8, IP4 152........... 212........ 240........ 5 kg 25 kg A 13, 25, anhydrous. 106 Sodium persulfate... 5.1 UN1505 III 5.1....... A1, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Sodium phosphide.... 4.3 UN1432 I 4.3, 6.1.. A19, N40 None.......... 211........ None....... Forbidden 15 kg E 40, 85 Sodium picramate, 1.3C UN0235 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 5E dry or wetted with less than 20 percent water, by mass. Sodium picramate, 4.1 UN1349 I 4.1....... 23, A8, A19, N41 None.......... 211........ None....... Forbidden 15 kg E 28, 36 wetted with not less than 20 percent water, by mass. Sodium picryl Forbidden .................. .......... ...........#
Passage 299.. .......... .......... ........... ........... ........... ....... peroxide. Sodium potassium ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... alloys, see Potassium sodium alloys. Sodium selenate, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Sodium sulfide, 4.2 UN1385 II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg A ....... anhydrous or Sodium IP2, N34 sulfide with less than 30 percent water of crystallization. Sodium sulfide, 8 UN1849 II 8......... IB8, IP2, IP4, 154........... 212........ 240........ 15 kg 50 kg A 26 hydrated with not T7, TP2 less than30 percent water. Sodium superoxide... 5.1 UN2547 I 5.1....... A20, IB6, IP1, None.......... 211........ None....... Forbidden 15 kg E 13, 75, N34 106 Sodium tetranitride. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... G Solids containing 8 UN3244 II 8......... 49, IB5 154........... 212........ 240........ 15 kg 50 kg B 40 corrosive liquid, n.o.s.. G Solids containing 4.1 UN3175 II 4.1....... 47, IB6, IP2 151........... 212........ 240........ 15 kg 50 kg B ....... flammable liquid, n.o.s.. G Solids containing 6.1 UN3243 II 6.1....... 48, IB2 None.......... 212........ 240........ 25 kg 100 kg B 40 toxic liquid, n.o.s.. Sounding devices, 1.2F UN0204 II 1.2F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... explosive. Sounding devices, 1.1F UN0296 II 1.1F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... explosive. Sounding devices, 1.1D UN0374 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... explosive. Sounding devices, 1.2D UN0375 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 07 ....... explosive. Spirits of salt, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrochloric acid. Squibs, see Igniters ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... etc. Stannic chloride, 8 UN1827 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L C .......#
Passage 300anhydrous. Stannic chloride, 8 UN2440 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... pentahydrate. Stannic phosphide... 4.3 UN1433 I 4.3, 6.1.. A19, N40 None.......... 211........ 242........ Forbidden 15 kg E 40, 85 Steel swarf, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Ferrous metal borings, etc. Stibine............. 2.3 UN2676 ....... 2.3, 2.1.. 1 None.......... 304........ None....... Forbidden Forbidden D 40 Storage batteries, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... wet, see Batteries, wet etc. Strontium arsenite.. 6.1 UN1691 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Strontium chlorate.. 5.1 UN1506 II 5.1....... A1, A9, IB8, IP2, 152........... 212........ 242........ 5 kg 25 kg A 56, 58, IP4, N34 106 Strontium nitrate... 5.1 UN1507 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Strontium 5.1 UN1508 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 56, 58, perchlorate. 106 Strontium peroxide.. 5.1 UN1509 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 13, 75, 106 Strontium phosphide. 4.3 UN2013 I 4.3, 6.1.. A19, N40 None.......... 211........ None....... Forbidden 15 kg E 40, 85 Strychnine or 6.1 UN1692 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 Strychnine salts. Styphnic acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitroresorcinol, etc. Styrene monomer, 3 UN2055 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... stabilized. G Substances, 1.1L UN0357 II 1.1L...... 101 None.......... 62......... None....... Forbidden Forbidden ........... 8E, explosive, n.o.s.. 14E, 15E, 17E G Substances, 1.2L UN0358 II 1.2L...... 101 None.......... 62......... None....... Forbidden Forbidden ........... 8E, explosive, n.o.s.. 14E, 15E, 17E#
Passage 301G Substances, 1.3L UN0359 II 1.3L...... 101 None.......... 62......... None....... Forbidden Forbidden ........... 8E, explosive, n.o.s.. 14E, 15E, 17E G Substances, 1.1A UN0473 II 1.1A...... 101, 111 None.......... 62......... None....... Forbidden Forbidden 12 ....... explosive, n.o.s.. G Substances, 1.1C UN0474 II 1.1C...... 101 None.......... 62......... None....... Forbidden Forbidden 10 ....... explosive, n.o.s.. G Substances, 1.1D UN0475 II 1.1D...... 101 None.......... 62......... None....... Forbidden Forbidden 10 ....... explosive, n.o.s.. G Substances, 1.1G UN0476 II 1.1G...... 101 None.......... 62......... None....... Forbidden Forbidden 08 ....... explosive, n.o.s.. G Substances, 1.3C UN0477 II 1.3C...... 101 None.......... 62......... None....... Forbidden Forbidden 10 ....... explosive, n.o.s.. G Substances, 1.3G UN0478 II 1.3G...... 101 None.......... 62......... None....... Forbidden Forbidden 08 ....... explosive, n.o.s.. G Substances, 1.4C UN0479 II 1.4C...... 101 None.......... 62......... None....... Forbidden 75 kg 09 ....... explosive, n.o.s.. 6 Substances, 1.4D UN0480 II 1.4D...... 101 None.......... 62......... None....... Forbidden 75 kg 09 ....... explosive, n.o.s.. G Substances, 1.4S UN0481 II 1.4S...... 101 None.......... 62......... None....... 25 kg 75 kg 05 ....... explosive, n.o.s.. G Substances, 1.4G UN0485 II 1.4G...... 101 None.......... 62......... None....... Forbidden 75 kg 08 ....... explosive, n.o.s.. G Substances, 1.5D UN0482 II 1.5D...... 101 None.......... 62......... None....... Forbidden Forbidden 10 ....... explosive, very insensitive, n.o.s., or Substances, EVI, n.o.s.. Substituted 3 UN2780 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 nitrophenol TP27 pesticides, liquid, flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Substituted 6.1 UN3014 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 nitrophenol TP27 pesticides, liquid, toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241....#
Passage 302.... 60 L 220 L A 40 TP28 Substituted 6.1 UN3013 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 nitrophenol TP27 pesticides, liquid, toxic, flammable flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... B1, IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Substituted 6.1 UN2779 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 nitrophenol pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Sucrose octanitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Sulfamic acid....... 8 UN2967 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... D Sulfur.............. 9 NA1350 III 9......... 30, IB8, IP2 None.......... None....... 240........ No limit No limit A 19, 74 I Sulfur.............. 4.1 UN1350 III 4.1....... 30, IB8, IP3, T1, None.......... None....... 240........ No limit No limit A 19, 74 TP1 Sulfur and chlorate, Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... loose mixtures of. Sulfur chlorides.... 8 UN1828 I 8......... 5, A3, B10, B77, None.......... 201........ 243........ Forbidden 2.5 L C 40 N34, T20, TP2, TP12 Sulfur dichloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sulfur chlorides. Sulfur dioxide...... 2.3 UN1079 ....... 2.3, 8.... 3, B14, T50, TP19 None.......... 304........ 314, 315... Forbidden 25 kg D 40 Sulfur dioxide ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Sulfurous acid. Sulfur hexafluoride. 2.2 UN1080 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... D Sulfur, molten...... 9 NA2448 III 9......... IB3, T1, TP3 None.......... 213#
Passage 303........ 247........ Forbidden Forbidden C 61 I Sulfur, molten...... 4.1 UN2448 III 4.1....... IB1, T1, TP3 None.......... 213........ 247........ Forbidden Forbidden C 61 Sulfur tetrafluoride 2.3 UN2418 ....... 2.3, 8.... 1 None.......... 302........ 245........ Forbidden Forbidden D 40 + Sulfur trioxide, 8 UN1829 I 8, 6.1.... 2, A7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden A 40 stabilized. B32, B49, B74, B77, N34, T20, TP4, TP12, TP13, TP25, TP26, TP38, TP45 Sulfuretted ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrogen, see Hydrogen sulfide. Sulfuric acid, 8 UN1831 I 8......... A3, A7, B84, N34, None.......... 201........ 243........ Forbidden 2.5 L C 14, 40 fuming with less T20, TP2, TP12, than 30 percent TP13 free sulfur trioxide. + Sulfuric acid, 8 UN1831 I 8, 6.1.... 2, A3, A6, A7, None.......... 227........ 244........ Forbidden Forbidden C 14, 40 fuming with 30 B9, B14, B32, percent or more B74, B77, B84, free sulfur N34, T20, TP2, trioxide. TP12, TP13 Sulfuric acid, spent 8 UN1832 II 8......... A3, A7, B2, B83, None.......... 202........ 242........ Forbidden 30 L C 14 B84, IB2, N34, T8, TP2, TP12 Sulfuric acid with 8 UN1830 II 8......... A3, A7, B3, B83, 154........... 202........ 242........ 1 L 30 L C 14 more than 51 B84, IB2, N34, percent acid. T8, TP2, TP12 Sulfuric acid with 8 UN2796 II 8......... A3, A7, B2, B15, 154........... 202........ 242........ 1 L 30 L B ....... not more than 51% IB2, N6, N34, T8, acid. TP2, TP12#
Passage 304Sulfuric and ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... hydrofluoric acid mixtures, see Hydrofluoric and sulfuric acid mixtures. Sulfuric anhydride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Sulfur trioxide, stabilized. Sulfurous acid...... 8 UN1833 II 8......... B3, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L B 40 + Sulfuryl chloride... 8 UN1834 I 8, 6.1.... 1, A3, B6, B9, None.......... 226........ 244........ Forbidden Forbidden C 40 B10, B14, B30, B74, B77, N34, T22, TP2, TP12, TP38, TP44 Sulfuryl fluoride... 2.3 UN2191 ....... 2.3....... 4 None.......... 304........ 314, 315... Forbidden 25 kg D 40 Tars, liquid 3 UN1999 II 3......... B13, IB2, T3, 150........... 202........ 242........ 5 L 60 L B ....... including road TP3, TP29 asphalt and oils, bitumen and cut backs. .................... ........... .................. III 3......... B1, B13, IB3, T1, 150........... 203........ 242........ 60 L 220 L A ....... TP3 Tear gas candles.... 6.1 UN1700 II 6.1, 4.1.. None.......... 340........ None....... Forbidden 50 kg D 40 Tear gas cartridges, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Ammunition, tear-producing, etc. D Tear gas devices 6.1 NA1693 I 6.1....... None.......... 340........ None....... Forbidden Forbidden D 40 with more than 2 percent tear gas substances, by mass. .................... ........... .................. II 6.1....... None.......... 340........ None....... Forbidden Forbidden D 40 Tear gas devices, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... with not more than 2 percent tear gas substances, by mass, see Aerosols, etc. Tear gas grenades, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Tear gas candles. G Tear gas substances, 6.1 UN1693 I 6.1....... None.......... 201........ None....... Forbidden Forbidden D 40 liquid, n.o.s.. .................... ........... .................. II 6.1....... IB2 None.......... 202........ None....... Forbidden 5 L D 40 G Tear gas substances, 6.1 UN1693 I 6.1....... None.......... 211.......#
Passage 305. None....... Forbidden 15 kg D 40 solid, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ None....... Forbidden 25 kg D 40 Tellurium compound, 6.1 UN3284 I 6.1....... IB7, IP1, T14, None.......... 211........ 242........ 5 kg 50 kg B ....... n.o.s.. TP2, TP27 .................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B ....... T11, TP2, TP27 .................... ........... .................. III 6.1....... IB8, IP3, T7, 153........... 213........ 240........ 100 kg 200 kg A ....... TP1, TP28 Tellurium 2.3 UN2195 ....... 2.3, 8.... 1 None.......... 302........ None....... Forbidden Forbidden D 40 hexafluoride. Terpene 3 UN2319 III 3......... B1, IB3, T4, TP1, 150........... 203........ 242........ 60 L 220 L A ....... hydrocarbons, TP29 n.o.s.. Terpinolene......... 3 UN2541 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Tetraazido benzene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... quinone. Tetrabromoethane.... 6.1 UN2504 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Tetrachloroethane... 6.1 UN1702 II 6.1....... IB2, N36, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Tetrachloroethylene. 6.1 UN1897 III 6.1....... IB3, N36, T4, TP1 153........... 203........ 241........ 60 L 220 L A 40 Tetraethyl 6.1 UN1704 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg D 40 dithiopyrophosphate. Tetraethyl silicate. 3 UN1292 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Tetraethylammonium Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... perchlorate (dry). Tetraethylenepentami 8 UN2320 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... ne. 1,1,1,2- 2.2 UN3159 ....... 2.2....... T50 306........... 304........ 314, 315... 75 kg 150 kg A ....... Tetrafluoroethane or Refrigerant gas R 134a. Tetrafluoroethylene, 2.1 UN1081 ....... 2.1....... 306........... 304........ None....... Forbidden 150 kg E 40 stabilized. Tetrafluoromethane, 2.2 UN1982 ....... 2.2....... None.......... 302.......#
Passage 306. None....... 75 kg 150 kg A ....... compressed or Refrigerant gas R 14. 1,2,3,6- 3 UN2498 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Tetrahydrobenzaldeh yde. Tetrahydrofuran..... 3 UN2056 II 3......... IB2, T4, TP1 None.......... 202........ 242........ 5 L 60 L B ....... Tetrahydrofurfurylam 3 UN2943 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... ine. Tetrahydrophthalic 8 UN2698 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... anhydrides with more than 0.05 percent of maleic anhydride. 1,2,3,6- 3 UN2410 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Tetrahydropyridine. Tetrahydrothiophene. 3 UN2412 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Tetramethylammonium 8 UN1835 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L A ....... hydroxide. Tetramethylene Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diperoxide dicarbamide. Tetramethylsilane... 3 UN2749 I 3......... T14, TP2 None.......... 201........ 243........ Forbidden 30 L D ....... Tetranitro Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diglycerin. Tetranitroaniline... 1.1D UN0207 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... + Tetranitromethane... 5.1 UN1510 I 5.1, 6.1.. 2, B9, B14, B32, None.......... 227........ None....... Forbidden Forbidden D 40, 66, B74, T20, TP2, 106 TP13, TP38, TP44 2,3,4,6- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Tetranitrophenol. 2,3,4,6- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Tetranitrophenyl methyl nitramine. 2,3,4,6- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Tetranitrophenylnit ramine. Tetranitroresorcinol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). 2,3,5,6-Tetranitroso- Forbidden .................. .......... ............. .......... ..#
Passage 307........ ........... ........... ........... ....... 1,4-dinitrobenzene. 2,3,5,6-Tetranitroso Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitrobenzene (dry). Tetrapropylorthotita 3 UN2413 III 3......... B1, IB3, T4, TP1 150........... 203........ 242........ 60 L 220 L A ....... nate. Tetrazene, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Guanyl nitrosaminoguanylte trazene.#
Passage 308Tetrazine (dry)..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Tetrazol-1-acetic 1.4C UN0407 II 1.4C...... None.......... 62......... None....... Forbidden 75 kg 09 ....... acid. 1H-Tetrazole........ 1.1D UN0504 ....... 1.1D...... None.......... 62......... None....... Forbidden Forbidden B 1E, 5E Tetrazolyl azide Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... (dry). Tetryl, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitrophenylmethy lnitramine. Thallium chlorate... 5.1 UN2573 II 5.1, 6.1.. IB6, IP2 None.......... 212........ 242........ 5 kg 25 kg A 56, 58, 106 Thallium compounds, 6.1 UN1707 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... n.o.s.. Thallium nitrate.... 6.1 UN2727 II 6.1, 5.1.. IB6, IP2 None.......... 212........ 242........ 5 kg 25 kg A ....... 4-Thiapentanal...... 6.1 UN2785 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L D 25, 49 Thioacetic acid..... 3 UN2436 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Thiocarbamate 3 UN2772 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 pesticide, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP13, None.......... 202........ 243........ 1 L 60 L B 40 TP27 Thiocarbamate 6.1 UN3005 I 6.1, 3.... T14, TP2, TP13 None.......... 201........ 243........ 1 L 30 L B 40 pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Thiocarbamate 6.1 UN3006 I 6.1....... T14, TP2, TP13 None.......... 201........ 243........ 1 L 30 L B 40 pesticide, liquid, toxic. .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... ........#
Passage 309.......... III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Thiocarbamate 6.1 UN2771 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 pesticides, solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Thiocarbonylchloride ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... , see Thiophosgene. Thioglycol.......... 6.1 UN2966 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Thioglycolic acid... 8 UN1940 II 8......... A7, B2, IB2, N34, 154........... 202........ 242........ 1 L 30 L A ....... T7, TP2 Thiolactic acid..... 6.1 UN2936 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Thionyl chloride.... 8 UN1836 I 8......... A7, B6, B10, N34, None.......... 201........ 243........ Forbidden Forbidden C 40 T10, TP2, TP12, TP13 Thiophene........... 3 UN2414 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B 40 + Thiophosgene........ 6.1 UN2474 II 6.1....... 2, A7, B9, B14, None.......... 227........ 244........ Forbidden Forbidden B 26, 40 B32, B74, N33, N34, T20, TP2, TP38, TP45 Thiophosphoryl 8 UN1837 II 8......... A3, A7, B2, B8, None.......... 202........ 242........ Forbidden 30 L C 40 chloride. B25, IB2, N34, T7, TP2 Thiourea dioxide.... 4.2 UN3341 II 4.2....... IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg D ....... .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg D ....... D Thorium metal, 7 UN2975 ....... 7, 4.2.... None.......... 418........ None....... Forbidden Forbidden D ....... pyrophoric. D Thorium nitrate, 7 UN2976 ....... 7, 5.1.... None.......... 419........ None....... Forbidden 15 kg A ....... solid. Tin chloride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... fuming, see Stannic chloride, anhydrous. Tin perchloride or ........... .................. .......... ............. .......... .......... ........... ........... ....#
Passage 310....... ....... Tin tetrachloride, see Stannic chloride, anhydrous. Tinctures, medicinal 3 UN1293 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Tinning flux, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Zinc chloride. Titanium disulphide. 4.2 UN3174 III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg A ....... Titanium hydride.... 4.1 UN1871 II 4.1....... A19, A20, IB4, None.......... 212........ 241........ 15 kg 50 kg E ....... N34 Titanium powder, dry 4.2 UN2546 I 4.2....... None.......... 211........ 242........ Forbidden Forbidden D ....... .................... ........... .................. II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg D ....... IP2, N5, N34 .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg D ....... Titanium powder, 4.1 UN1352 II 4.1....... A19, A20, IB6, None.......... 212........ 240........ 15 kg 50 kg E ....... wetted with not IP2, N34 less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Titanium sponge 4.1 UN2878 III 4.1....... A1, IB8, IP3 None.......... 213........ 240........ 25 kg 100 kg D ....... granules or Titanium sponge powders. + Titanium 8 UN1838 II 8, 6.1.... 2, A3, A6, B7, None.......... 227........ 244........ Forbidden Forbidden C 40 tetrachloride. B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 Titanium trichloride 8 UN2869 II 8......... A7, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A 40 mixtures. IP4, N34 .................... ........... .................. III 8......... A7, IB8, IP3, N34 154........... 213........ 240........ 25 kg 100 kg A 40#
Passage 311Titanium 4.2 UN2441 I 4.2, 8.... A7, A8, A19, A20, None.......... 181........ 244........ Forbidden Forbidden D 40 trichloride, N34 pyrophoric or Titanium trichloride mixtures, pyrophoric. TNT mixed with ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... aluminum, see Tritonal. TNT, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitrotoluene, etc. Toluene............. 3 UN1294 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... + Toluene diisocyanate 6.1 UN2078 II 6.1....... IB2, T7, TP2, None.......... 202........ 243........ 5 L 60 L D 25, 40 TP13 Toluene sulfonic ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... acid, see Alkyl, or Aryl sulfonic acid etc. + Toluidines liquid... 6.1 UN1708 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... + Toluidines solid.... 6.1 UN1708 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... T7, TP2 2,4-Toluylenediamine 6.1 UN1709 III 6.1....... IB8, IP3, T4, TP1 153........... 213........ 240........ 100 kg 200 kg A ....... or 2,4- Toluenediamine. Torpedoes, liquid 1.3J UN0450 II 1.3J...... ............. 62......... None....... Forbidden Forbidden 04 23E fueled, with inert head. Torpedoes, liquid 1.1J UN0449 II 1.1J...... ............. 62......... None....... Forbidden Forbidden 04 23E fueled, with or without bursting charge. Torpedoes with 1.1E UN0329 II 1.1E...... ............. 62......... None....... Forbidden Forbidden 03 ....... bursting charge. Torpedoes with 1.1F UN0330 II 1.1F...... ............. 62......... None....... Forbidden Forbidden 08 ....... bursting charge. Torpedoes with 1.1D UN0451 II 1.1D...... ............. 62......... None....... Forbidden Forbidden 03 ....... bursting charge. G Toxic liquid, 6.1 UN3289 I 6.1, 8.... T14, TP2, TP13, None.......... 201........ 243........ 0.5 L 2.5 L A ....... corrosive, TP27 inorganic, n.o.s.. .................... ........... .................. II 6.1, 8.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 30 L A ....... TP27 G Toxic liquid, 6.1 UN3289 I 6.1, 8.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forb#
Passage 312idden B 40 corrosive, B72, T22, TP2, inorganic, n.o.s. TP13, TP27, TP38, Inhalation Hazard, TP44 Packing Group I, Zone A. G Toxic liquid, 6.1 UN3289 I 6.1, 8.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 40 corrosive, B74, T20, TP2, inorganic, n.o.s. TP13, TP27, TP38, Inhalation Hazard, TP45 Packing Group I, Zone B. G Toxic liquid, 6.1 UN3287 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L A ....... inorganic, n.o.s.. TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L A ....... TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A ....... TP28 G Toxic liquid, 6.1 UN3287 I 6.1....... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden B 40 inorganic, n.o.s. B72, T22, TP2, Inhalation Hazard, TP13, TP27, TP38, Packing Group I, TP44 Zone A. G Toxic liquid, 6.1 UN3287 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden B 40 inorganic, n.o.s. B74, T20, TP2, Inhalation Hazard, TP13, TP27, TP38, Packing Group I, TP45 Zone B. G Toxic liquids, 6.1 UN2927 I 6.1, 8.... T14, TP2, TP13, None.......... 201........ 243........ 0.5 L 2.5 L B 40 corrosive, organic, TP27 n.o.s.. .................... ........... .................. II 6.1, 8.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 30 L B 40 TP27 G Toxic liquids, 6.1 UN2927 I 6.1, 8.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 corrosive, organic, B72, T22, TP2, n.o.s., inhalation TP13, TP27, TP38, hazard, Packing TP44 Group I, Zone A. G Toxic liquids, 6.1 UN2927 I 6.1, 8.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 corrosive, organic, B74, T20, TP2, n.o.s., inhalation TP13, TP27, TP38, hazard, Packing TP45 Group I, Zone B. G Toxic liquids, 6.1 UN2929 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 flammable, organic, TP27 n.o.s.. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 G Toxic liquids, 6.1 UN2929 I 6.1, 3.... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 flammable, organi#
Passage 313c, B72, T22, TP2, n.o.s., inhalation TP13, TP27, TP38, hazard, Packing TP44 Group I, Zone A. G Toxic liquids, 6.1 UN2929 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 flammable, organic, B74, T20, TP2, n.o.s., inhalation TP13, TP27, TP38, hazard, Packing TP45 Group I, Zone B. G Toxic, liquids, 6.1 UN2810 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 organic, n.o.s.. TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP1, 153........... 203........ 241........ 60 L 220 L A 40 TP28 G Toxic, liquids, 6.1 UN2810 I 6.1....... 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden D 40 organic, n.o.s. B72, T22, TP2, Inhalation hazard, TP13, TP27, TP38, Packing Group I, TP44 Zone A. G Toxic, liquids, 6.1 UN2810 I 6.1....... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden D 40 organic, n.o.s. B74, T20, TP2, Inhalation hazard, TP13, TP27, TP38, Packing Group I, TP45 Zone B.#
Passage 314G Toxic liquids, 6.1 UN3122 I 6.1, 5.1.. A4 None.......... 201........ 243........ Forbidden 2.5 L C ....... oxidizing, n.o.s.. .................... ........... .................. II 6.1, 5.1.. IB2 None.......... 202........ 243........ 1 L 5 L C ....... G Toxic liquids, 6.1 UN3122 I 6.1, 5.1.. 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden C ....... oxidizing, n.o.s. B72, T22, TP2, Inhalation hazard, TP13, TP38, TP44 Packing Group I, Zone A. G Toxic liquids, 6.1 UN3122 I 6.1, 5.1.. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden C ....... oxidizing, n.o.s. T20, TP2, TP13, Inhalation Hazard, TP38, TP44 Packing Group I, Zone B. G Toxic liquids, water- 6.1 UN3123 I 6.1, 4.3.. A4 None.......... 201........ 243........ Forbidden 1 L E 40 reactive, n.o.s.. .................... ........... .................. II 6.1, 4.3.. IB2 None.......... 202........ 243........ 1 L 5 L E 40 G Toxic liquids, water- 6.1 UN3123 I 6.1, 4.3.. 1, B9, B14, B30, None.......... 226........ 244........ Forbidden Forbidden E 40 reactive, n.o.s. B72, T22, TP2, Inhalation hazard, TP13, TP38, TP44 packing group I, Zone A. G Toxic liquids, water- 6.1 UN3123 I 6.1, 4.3.. 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden E 40 reactive, n.o.s. B74, T20, TP2, Inhalation hazard, TP13, TP38, TP44 packing group I, Zone B. G Toxic solid, 6.1 UN3290 I 6.1, 8.... IB7 None.......... 211........ 242........ 1 kg 25 kg A ....... corrosive, inorganic, n.o.s.. .................... ........... .................. II 6.1, 8.... IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg A ....... G Toxic solid, 6.1 UN3288 I 6.1....... IB7 None.......... 211........ 242........ 5 kg 50 kg A ....... inorganic, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... G Toxic solids, 6.1 UN2928 I 6.1, 8.... IB7 None.......... 211........ 242........ 1 kg 25 kg B 40 corrosive, organic, n.o.s.. .................... ........... .................. II 6.1, 8.... IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg B 40 G Toxic solids, 6.1 UN2930 I 6.1, 4.1.. IB6 None.......... 211........ 242........ 1#
Passage 315kg 15 kg B ....... flammable, organic, n.o.s.. .................... ........... .................. II 6.1, 4.1.. IB8, IP2, IP4 None.......... 212........ 242........ 15 kg 50 kg B ....... G Toxic solids, 6.1 UN2811 I 6.1....... IB7 None.......... 211........ 242........ 5 kg 50 kg B ....... organic, n.o.s.. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg B ....... .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A ....... G Toxic solids, 6.1 UN3086 I 6.1, 5.1.. None.......... 211........ 242........ 1 kg 15 kg C ....... oxidizing, n.o.s.. .................... ........... .................. II 6.1, 5.1.. IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg C ....... G Toxic solids, self- 6.1 UN3124 I 6.1, 4.2.. A5 None.......... 211........ 242........ 5 kg 15 kg D 40 heating, n.o.s.. .................... ........... .................. II 6.1, 4.2.. IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg D 40 G Toxic solids, water- 6.1 UN3125 I 6.1, 4.3.. A5 None.......... 211........ 242........ 5 kg 15 kg D 40 reactive, n.o.s.. .................... ........... .................. II 6.1, 4.3.. IB6, IP2 None.......... 212........ 242........ 15 kg 50 kg D 40 D Toy Caps............ 1.4S NA0337 II 1.4S...... None.......... 62......... None....... 25 kg 100 kg 05 ....... Tracers for 1.3G UN0212 II 1.3G...... None.......... 62......... None....... Forbidden Forbidden 07 ....... ammunition. Tracers for 1.4G UN0306 II 1.4G...... None.......... 62......... None....... Forbidden 75 kg 06 ....... ammunition. Tractors, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Vehicle, etc. Tri-(b-nitroxyethyl) Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... ammonium nitrate. Triallyl borate..... 6.1 UN2609 III 6.1....... IB3 153........... 203........ 241........ 60 L 220 L A 13 Triallylamine....... 3 UN2610 III 3, 8...... B1, IB3, T4, TP1 None.......... 203........ 242........ 5 L 60 L A 40 Triazine pesticides, 3 UN2764 I 3, 6.1.... T14, TP2, TP13, None.......... 201........ 243........ Forbidden 30 L B 40 liquid, flammable, TP27 toxic, flash point less than#
Passage 31623 degrees C. .................... ........... .................. II 3, 6.1.... IB2, T11, TP2, None.......... 202........ 243........ 1 L 60 L B 40 TP13, TP27 Triazine pesticides, 6.1 UN2998 I 6.1....... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 liquid, toxic. TP27 .................... ........... .................. II 6.1....... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1....... IB3, T7, TP2, 153........... 203........ 241........ 60 L 220 L A 40 TP28 Triazine pesticides, 6.1 UN2997 I 6.1, 3.... T14, TP2, TP13, None.......... 201........ 243........ 1 L 30 L B 40 liquid, toxic, TP27 flammable, flash point not less than 23 degrees C. .................... ........... .................. II 6.1, 3.... IB2, T11, TP2, None.......... 202........ 243........ 5 L 60 L B 40 TP13, TP27 .................... ........... .................. III 6.1, 3.... IB3, T7, TP2, 153........... 203........ 242........ 60 L 220 L A 40 TP28 Triazine pesticides, 6.1 UN2763 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 40 solid, toxic. .................... ........... .................. II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A 40 .................... ........... .................. III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 Tributylamine....... 6.1 UN2542 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Tributylphosphane... 4.2 UN3254 I 4.2....... None.......... 211........ 242........ Forbidden Forbidden D ....... Trichloro-s- ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... triazinetrione dry, with more than 39 percent available chlorine, see Trichloroisocyanuri c acid, dry. Trichloroacetic acid 8 UN1839 II 8......... A7, IB8, IP2, 154........... 212........ 240........ 15 kg 50 kg A ....... IP4, N34 Trichloroacetic 8 UN2564 II 8......... A3, A6, A7, B2, 154........... 202........ 242........ 1 L 30 L B ....... acid, solution. IB2, N34, T7, TP2 .................... ........... .................. III 8......... A3, A6, A7, IB3, 154........... 203........ 241........ 5 L 60 L B 8 N34, T4, TP1 + Trichloroacetyl 8 UN2442 II 8, 6.1.... 2, A3, A7, B9, None...#
Passage 317....... 227........ 244........ Forbidden Forbidden D 40 chloride. B14, B32, B74, N34, T20, TP2, TP38, TP45 Trichlorobenzenes, 6.1 UN2321 III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... liquid. Trichlorobutene..... 6.1 UN2322 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 25, 40 1,1,1- 6.1 UN2831 III 6.1....... IB3, N36, T4, TP1 153........... 203........ 241........ 60 L 220 L A 40 Trichloroethane. Trichloroethylene... 6.1 UN1710 III 6.1....... IB3, N36, T4, TP1 153........... 203........ 241........ 60 L 220 L A 40#
Passage 318Trichloroisocyanuric 5.1 UN2468 II 5.1....... IB8, IP4 152........... 212........ 240........ 5 kg 25 kg A 13 acid, dry. Trichloromethyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... perchlorate. Trichlorosilane..... 4.3 UN1295 I 4.3, 3, 8. A7, N34, T14, None.......... 201........ 244........ Forbidden Forbidden D 21, 28, TP2, TP7, TP13 40, 49, 100 Tricresyl phosphate 6.1 UN2574 II 6.1....... A3, IB2, N33, None.......... 202........ 243........ 5 L 60 L A ....... with more than 3 N34, T7, TP2 percent ortho isomer. Triethyl phosphite.. 3 UN2323 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Triethylamine....... 3 UN1296 II 3, 8...... IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40 Triethylenetetramine 8 UN2259 II 8......... B2, IB2, T7, TP2 154........... 202........ 242........ 1 L 30 L B 40 Trifluoroacetic acid 8 UN2699 I 8......... A3, A6, A7, B4, None.......... 201........ 243........ 0.5 L 2.5 L B 12, 40 N3, N34, T10, TP2, TP12 Trifluoroacetyl 2.3 UN3057 ....... 2.3, 8.... 2, B7, B9, B14, None.......... 304........ 314, 315... Forbidden Forbidden D 40 chloride. T50, TP21 Trifluorochloroethyl 2.3 UN1082 ....... 2.3, 2.1.. 3, B14, T50 None.......... 304........ 314, 315... Forbidden Forbidden D 40 ene, stabilized. 1,1,1- 2.1 UN2035 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 Trifluoroethane, compressed or Refrigerant gas R 143a. Trifluoromethane or 2.2 UN1984 ....... 2.2....... 306........... 304........ 314, 315... 75 kg 150 kg A ....... Refrigerant gas R 23. Trifluoromethane, 2.2 UN3136 ....... 2.2....... T75, TP5 306........... None....... 314, 315... 50 kg 500 kg D ....... refrigerated liquid. 2- 6.1 UN2942 III 6.1....... IB3 153........... 203........ 241........ 60 L 220 L A ....... Trifluoromethylanil ine. 3- 6.1 UN2948 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A 40 Trifluoromethylanil ine. Triformoxime Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trinitrate. Triisobutylene...... 3 UN2324 III 3......... B1, IB3, T4, TP1 150........... 203........ 242........ 60 L 220 L A ....... Triisopropyl borate. 3 UN2616 II 3......... IB2, T4, TP1 150........... 202........ 242......#
Passage 319.. 5 L 60 L A ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... D Trimethoxysilane.... 6.1 NA9269 I 6.1, 3.... 2, B9, B14, B32, None.......... 227........ 244........ Forbidden Forbidden E 40 B74, T20, TP4, TP12, TP13, TP38, TP45 Trimethyl borate.... 3 UN2416 II 3......... IB2, T7, TP1 150........... 202........ 242........ 5 L 60 L B ....... Trimethyl phosphite. 3 UN2329 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... 1,3,5-Trimethyl- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 2,4,6- trinitrobenzene. Trimethylacetyl 6.1 UN2438 I 6.1, 8, 3. 2, A3, A6, A7, None.......... 227........ 244........ Forbidden Forbidden D 25, 40 chloride. B3, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45 Trimethylamine, 2.1 UN1083 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 anhydrous. Trimethylamine, 3 UN1297 I 3, 8...... T11, TP1 None.......... 201........ 243........ 0.5 L 2.5 L D 40, 41 aqueous solutions with not more than 50 percent trimethylamine by mass. .................... ........... .................. II 3, 8...... B1, IB2, T7, TP1 None.......... 202........ 243........ 1 L 5 L B 40, 41 .................... ........... .................. III 3, 8...... B1, IB3, T7, TP1 150........... 203........ 242........ 5 L 60 L A 40, 41 1,3,5- 3 UN2325 III 3......... B1, IB3, T2, TP1 None.......... 203........ 242........ 60 L 220 L A ....... Trimethylbenzene. Trimethylchlorosilan 3 UN1298 II 3, 8...... A3, A7, B77, IB2, None.......... 202........ 243........ 1 L 5 L E 40 e. N34, T7, TP2, TP13 Trimethylcyclohexyla 8 UN2326 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... mine. Trimethylene glycol Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diperchlorate. Trimethylhexamethyle 6.1 UN2328 III 6.1....... IB3, T4, TP2, 153........... 203........ 241........ 60 L 220 L B ....... ne diisocyanate. TP13 Trimethylhexamethyle 8 UN2327 III 8......... IB3, T4, TP1 154........... 203........ 241........ 5 L 60 L A ....... nediamines. Trimethylol Forbidden .................. .......... ............. .......... .......... ...#
Passage 320........ ........... ........... ....... nitromethane trinitrate. Trinitro-meta-cresol 1.1D UN0216 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E 2,4,6-Trinitro-1,3- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... diazobenzene. 2,4,6-Trinitro-1,3,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... triazido benzene (dry). Trinitroacetic acid. Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitroacetonitrile Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitroamine cobalt Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitroaniline or 1.1D UN0153 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Picramide. Trinitroanisole..... 1.1D UN0213 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Trinitrobenzene, dry 1.1D UN0214 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... or wetted with less than 30 percent water, by mass. Trinitrobenzene, 4.1 UN1354 I 4.1....... 23, A2, A8, A19, None.......... 211........ None....... 0.5 kg 0.5 kg E 28 wetted with not N41 less than 30 percent water, by mass. Trinitrobenzenesulfo 1.1D UN0386 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E nic acid. Trinitrobenzoic 1.1D UN0215 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... acid, dry or wetted with less than 30 percent water, by mass. Trinitrobenzoic 4.1 UN1355 I 4.1....... 23, A2, A8, A19, None.......... 211........ None....... 0.5 kg 0.5 kg E 28 acid, wetted with N41 not less than 30 percent water, by mass. Trinitrochlorobenzen 1.1D UN0155 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... e or Picryl chloride. Trinitroethanol..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitroethylnitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... .......#
Passage 321Trinitrofluorenone.. 1.1D UN0387 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Trinitromethane..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... 1,3,5- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Trinitronaphthalene.#
Passage 322Trinitronaphthalene. 1.1D UN0217 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Trinitrophenetole... 1.1D UN0218 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Trinitrophenol or 1.1D UN0154 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E Picric acid, dry or wetted with less than 30 percent water, by mass. Trinitrophenol, 4.1 UN1344 I 4.1....... 23, A8, A19, N41 None.......... 211........ None....... 1 kg 15 kg E 28, 36 wetted with not less than 30 percent water, by mass. 2,4,6-Trinitrophenyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... guanidine (dry). 2,4,6-Trinitrophenyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... nitramine. 2,4,6-Trinitrophenyl Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... trimethylol methyl nitramine trinitrate (dry). Trinitrophenylmethyl 1.1D UN0208 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... nitramine or Tetryl. Trinitroresorcinol 1.1D UN0219 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass. Trinitroresorcinol, 1.1D UN0394 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 5E wetted or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass. 2,4,6-Trinitroso-3- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... methyl nitraminoanisole. Trinitrotetramine Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... cobalt nitrate. Trinitrotoluene and 1.1D UN0388 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Trinitrobenzene mixtures or TNT and trinitrobenzene mixtures or TNT and hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures. Trinitrotoluene 1.1D UN0389 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... mixtures containing Trinitrobenzene and Hexanitr#
Passage 323ostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene. Trinitrotoluene or 1.1D UN0209 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... TNT, dry or wetted with less than 30 percent water, by mass. Trinitrotoluene, 4.1 UN1356 I 4.1....... 23, A2, A8, A19, None.......... 211........ None....... 0.5 kg 0.5 kg E 28 wetted with not N41 less than 30 percent water, by mass. Tripropylamine...... 3 UN2260 III 3, 8...... B1, IB3, T4, TP1 150........... 203........ 242........ 5 L 60 L A 40 Tripropylene........ 3 UN2057 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Tris-(1- 6.1 UN2501 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... aziridinyl)phosphin e oxide, solution. .................... ........... .................. III 6.1....... IB3, T4, TP1 153........... 203........ 241........ 60 L 220 L A ....... Tris, bis- Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... bifluoroamino diethoxy propane (TVOPA). Tritonal............ 1.1D UN0390 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 10 ....... Tungsten 2.3 UN2196 ....... 2.3, 8.... 2 None.......... 338........ None....... Forbidden Forbidden D 40 hexafluoride. Turpentine.......... 3 UN1299 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Turpentine 3 UN1300 I 3......... T11, TP1, TP8, None.......... 201........ 243........ 1 L 30 L B ....... substitute. TP27 .................... ........... .................. II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Undecane............ 3 UN2330 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... D Uranium 7 UN2978 ....... 7, 8...... 423........... 420, 427... 420, 427... ........... ........... ........... ....... hexafluoride, fissile excepted or non-fissile. D Uranium 7 UN2977 ....... 7, 8...... 453........... 417, 420... 417, 420... ........... .....#
Passage 324...... A ....... hexafluoride, fissile (with more than 1 percent U- 235). D Uranium metal, 7 UN2979 ....... 7, 4.2.... None.......... 418........ None....... ........... ........... D ....... pyrophoric. D Uranyl nitrate 7 UN2980 ....... 7, 8...... 421, 427...... 415, 416, 415, 416, ........... ........... D ....... hexahydrate 417. 417. solution. D Uranyl nitrate, 7 UN2981 ....... 7, 5.1.... None.......... 419........ None....... Forbidden 15 kg A ....... solid. Urea hydrogen 5.1 UN1511 III 5.1, 8.... A1, A7, A29, IB8, 152........... 213........ 240........ 25 kg 100 kg A 13 peroxide. IP3 Urea nitrate, dry or 1.1D UN0220 II 1.1D...... 119 None.......... 62......... None....... Forbidden Forbidden 10 ....... wetted with less than 20 percent water, by mass. Urea nitrate, wetted 4.1 UN1357 I 4.1....... 39, A8, A19, N41 None.......... 211........ None....... 1 kg 15 kg A 28 with not less than 20 percent water, by mass. Urea peroxide, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Urea hydrogen peroxide. Valeraldehyde....... 3 UN2058 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... Valeric acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Corrosive liquids, n.o.s.. Valeryl chloride.... 8 UN2502 II 8, 3...... A3, A6, A7, B2, 154........... 202........ 243........ 1 L 30 L C 40 IB2, N34, T7, TP2 Vanadium compound, 6.1 UN3285 I 6.1....... IB7, IP1, T14, None.......... 211........ 242........ 5 kg 50 kg B ....... n.o.s.. TP2, TP27#
Passage 325.................... ........... .................. II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg B ....... T11, TP2, TP27 .................... ........... .................. III 6.1....... IB8, IP3, T7, 153........... 213........ 240........ 100 kg 200 kg A ....... TP1, TP28 Vanadium 8 UN2443 II 8......... A3, A6, A7, B2, 154........... 202........ 242........ Forbidden 30 L C 40 oxytrichloride. B16, IB2, N34, T7, TP2 Vanadium pentoxide, 6.1 UN2862 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 40 non-fused form. Vanadium 8 UN2444 I 8......... A3, A6, A7, B4, None.......... 201........ 243........ Forbidden 2.5 L C 40 tetrachloride. N34, T10, TP2 Vanadium trichloride 8 UN2475 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A 40 Vanadyl sulfate..... 6.1 UN2931 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Vehicle, flammable 9 UN3166 ....... 9......... 135 220........... 220........ 220........ Forbidden No limit A ....... gas powered. Vehicle, flammable 9 UN3166 ....... 9......... 135 220........... 220........ 220........ No limit No limit A ....... liquid powered. Very signal ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... cartridge, see Cartridges, signal. Vinyl acetate, 3 UN1301 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... stabilized. Vinyl bromide, 2.1 UN1085 ....... 2.1....... T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 stabilized. Vinyl butyrate, 3 UN2838 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... stabilized. Vinyl chloride, 2.1 UN1086 ....... 2.1....... 21, B44, T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 stabilized or Vinyl chloride, stabilized. Vinyl chloroacetate. 6.1 UN2589 II 6.1, 3.... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Vinyl ethyl ether, 3 UN1302 I 3......... A3, T11, TP2 None.......... 201........ 243........ 1 L 30 L D ....... stabilized. Vinyl fluoride, 2.1 UN1860 ....... 2.1....... 306........... 304........ 314, 315... Forbidden 150 kg E 40 stabilized. Vinyl isobutyl 3 UN1304 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... ether, stabil#
Passage 326ized. Vinyl methyl ether, 2.1 UN1087 ....... 2.1....... B44, T50 306........... 304........ 314, 315... Forbidden 150 kg B 40 stabilized. Vinyl nitrate Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... polymer. Vinylidene chloride, 3 UN1303 I 3......... T12, TP2, TP7 150........... 201........ 243........ 1 L 30 L E 40 stabilized. Vinylpyridines, 6.1 UN3073 II 6.1, 3, 8. IB1, T7, TP2, None.......... 202........ 243........ 1 L 30 L B 40 stabilized. TP13 Vinyltoluenes, 3 UN2618 III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... stabilized. Vinyltrichlorosilane 3 UN1305 I 3, 8...... A3, A7, B6, N34, None.......... 201........ 243........ Forbidden 2.5 L B 40 , stabilized. T11, TP2, TP13 Warheads, rocket 1.4D UN0370 II 1.4D...... None.......... 62......... None....... Forbidden 75 kg 02 ....... with burster or expelling charge. Warheads, rocket 1.4F UN0371 II 1.4F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... with burster or expelling charge. Warheads, rocket 1.1D UN0286 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 03 ....... with bursting charge. Warheads, rocket 1.2D UN0287 II 1.2D...... None.......... 62......... None....... Forbidden Forbidden 03 ....... with bursting charge. Warheads, rocket 1.1F UN0369 II 1.1F...... None.......... 62......... None....... Forbidden Forbidden 08 ....... with bursting charge. Warheads, torpedo 1.1D UN0221 II 1.1D...... None.......... 62......... None....... Forbidden Forbidden 03 ....... with bursting charge. G Water-reactive 4.3 UN3129 I 4.3, 8.... None.......... 201........ 243........ Forbidden 1 L D ....... liquid, corrosive, n.o.s.. .................... ........... .................. II 4.3, 8.... IB1 None.......... 202........ 243........ 1 L 5 L E 85 .................... ........... .................. III 4.3, 8.... IB2 None.......... 203........ 242........ 5 L 60 L E ....... G Water-reactive 4.3 UN3148 I 4.3....... None.......... 201........ 244........ Forbidden 1 L E 40 liquid, n.o.s.. .................... ........... .................. II 4.3....... IB1 None.......... 202........ 243........ 1 L 5 L E 40 .................... ........... .................. III 4.3....... IB2 None.......... 203........ 242........ 5 L 60 L E 40 G Water-reactive 4.3#
Passage 327UN3130 I 4.3, 6.1.. A4 None.......... 201........ 243........ Forbidden 1 L D ....... liquid, toxic, n.o.s.. .................... ........... .................. II 4.3, 6.1.. IB1 None.......... 202........ 243........ 1 L 5 L E 85 .................... ........... .................. III 4.3, 6.1.. IB2 None.......... 203........ 242........ 5 L 60 L E 85 G Water-reactive 4.3 UN3131 I 4.3, 8.... IB4, IP1, N40 None.......... 211........ 242........ Forbidden 15 kg D ....... solid, corrosive, n.o.s.. .................... ........... .................. II 4.3, 8.... IB6, IP2 151........... 212........ 242........ 15 kg 50 kg E 85 .................... ........... .................. III 4.3, 8.... IB8, IP4 151........... 213........ 241........ 25 kg 100 kg E 85 G Water-reactive 4.3 UN3132 I 4.3, 4.1.. IB4, N40 None.......... 211........ 242........ Forbidden 15 kg D ....... solid, flammable, n.o.s.. .................... ........... .................. II 4.3, 4.1.. IB4 151........... 212........ 242........ 15 kg 50 kg E ....... .................... ........... .................. III 4.3, 4.1.. IB6 151........... 213........ 241........ 25 kg 100 kg E ....... G Water-reactive 4.3 UN2813 I 4.3....... IB4, N40 None.......... 211........ 242........ Forbidden 15 kg E 40 solid, n.o.s.. .................... ........... .................. II 4.3....... IB7, IP2 151........... 212........ 242........ 15 kg 50 kg E 40 .................... ........... .................. III 4.3....... IB8, IP4 151........... 213........ 241........ 25 kg 100 kg E 40 G Water-reactive, 4.3 UN3133 II 4.3, 5.1.. None.......... 214........ 214........ Forbidden Forbidden E 40 solid, oxidizing, n.o.s.. .................... ........... .................. III 4.3, 5.1.. None.......... 214........ 214........ Forbidden Forbidden E 40 G Water-reactive 4.3 UN3135 I 4.3, 4.2.. N40 None.......... 211........ 242........ Forbidden 15 kg E ....... solid, self- heating, n.o.s.. .................... ........... .................. II 4.3, 4.2.. IB5, IP2 None.......... 212........ 242........ 15 kg 50 kg E ....... .................... ........... .................. III 4.3, 4.2.. IB8, IP4 None.......... 213........ 241........ 25 kg 100 kg E ....... G Water-reactive 4.3 UN3134 I 4.3, 6.1.. A8, IB4, IP1, N40 None.......... 211........ 242........ Forbidden 15 kg D ....... solid, toxic, n.o.s.. .................#
Passage 328... ........... .................. II 4.3, 6.1.. IB5, IP2 151........... 212........ 242........ 15 kg 50 kg E 85 .................... ........... .................. III 4.3, 6.1.. IB8, IP4 151........... 213........ 241........ 25 kg 100 kg E 85 Wheel chair, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... electric, see Battery powered vehicle or Battery powered equipment. White acid, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Hydrofluoric acid. I White asbestos 9 UN2590 III 9......... IB8, IP2, IP3 155........... 216........ 240........ 200 kg 200 kg A 34, 40 (chrysotile, actinolite, anthophyllite, tremolite). Wood preservatives, 3 UN1306 II 3......... IB2, T4, TP1, TP8 150........... 202........ 242........ 5 L 60 L B 40 liquid. .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A 40 Xanthates........... 4.2 UN3342 II 4.2....... IB6, IP2 None.......... 212........ 241........ 15 kg 50 kg D 40#
Passage 329.................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg D 40 Xenon, compressed... 2.2 UN2036 ....... 2.2....... 306........... 302........ None....... 75 kg 150 kg A ....... Xenon, refrigerated 2.2 UN2591 ....... 2.2....... T75, TP5 320........... None....... None....... 50 kg 500 kg B ....... liquid (cryogenic liquids). Xylenes............. 3 UN1307 II 3......... IB2, T4, TP1 150........... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB3, T2, TP1 150........... 203........ 242........ 60 L 220 L A ....... Xylenols............ 6.1 UN2261 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... T7, TP2 Xylidines, solid.... 6.1 UN1711 II 6.1....... IB8, IP2, IP4, None.......... 212........ 242........ 25 kg 100 kg A ....... T7, TP2 Xylidines, solution. 6.1 UN1711 II 6.1....... IB2, T7, TP2 None.......... 202........ 243........ 5 L 60 L A ....... Xylyl bromide....... 6.1 UN1701 II 6.1....... A3, A6, A7, IB2, None.......... 340........ None....... Forbidden 60 L D 40 N33, T7, TP2, TP13 p-Xylyl diazide..... Forbidden .................. .......... ............. .......... .......... ........... ........... ........... ....... Zinc ammonium 5.1 UN1512 II 5.1....... IB8, IP4 None.......... 212........ 242........ 5 kg 25 kg E ....... nitrite. Zinc arsenate or 6.1 UN1712 II 6.1....... IB8, IP2, IP4 None.......... 212........ 242........ 25 kg 100 kg A ....... Zinc arsenite or Zinc arsenate and zinc arsenite mixtures. Zinc ashes.......... 4.3 UN1435 III 4.3....... A1, A19, IB8, IP4 151........... 213........ 241........ 25 kg 100 kg A ....... Zinc bisulfite ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Zinc bromate........ 5.1 UN2469 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A 56, 58, 106 Zinc chlorate....... 5.1 UN1513 II 5.1....... A9, IB8, IP2, 152........... 212........ 242........ 5 kg 25 kg A 56, 58, IP4, N34 106 Zinc chloride, 8 UN2331 III 8......... IB8, IP3 None.......... 213........ 240........ 25 kg 100 kg A ....... anhydrous. Zinc chloride, 8 UN1840 III 8......... IB3, T4, TP1 154........... 203........ 241.......#
Passage 330. 5 L 60 L A ....... solution. Zinc cyanide........ 6.1 UN1713 I 6.1....... IB7, IP1 None.......... 211........ 242........ 5 kg 50 kg A 26 Zinc dithionite or 9 UN1931 III None...... IB8 155........... 204........ 240........ 100 kg 200 kg A 49 Zinc hydrosulfite. Zinc ethyl, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Diethylzinc. Zinc fluorosilicate. 6.1 UN2855 III 6.1....... IB8, IP3 153........... 213........ 240........ 100 kg 200 kg A 26 Zinc hydrosulfite, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Zinc dithionite. Zinc muriate ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... solution, see Zinc chloride, solution. Zinc nitrate........ 5.1 UN1514 II 5.1....... IB8, IP4 152........... 212........ 240........ 5 kg 25 kg A ....... Zinc permanganate... 5.1 UN1515 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg D 56, 58, 69, 106, 107 Zinc peroxide....... 5.1 UN1516 II 5.1....... IB6, IP2 152........... 212........ 242........ 5 kg 25 kg A 13, 75, 106 Zinc phosphide...... 4.3 UN1714 I 4.3, 6.1.. A19, N40 None.......... 211........ None....... Forbidden 15 kg E 40, 85 Zinc powder or Zinc 4.3 UN1436 I 4.3, 4.2.. A19, IB4, IP1, None.......... 211........ 242........ Forbidden 15 kg A ....... dust. N40 .................... ........... .................. II 4.3, 4.2.. A19, IB7, IP2 None.......... 212........ 242........ 15 kg 50 kg A ....... .................... ........... .................. III 4.3, 4.2.. IB8, IP4 None.......... 213........ 242........ 25 kg 100 kg A ....... Zinc resinate....... 4.1 UN2714 III 4.1....... A1, IB6 151........... 213........ 240........ 25 kg 100 kg A ....... Zinc selenate, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Zinc selenite, see ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... Selenates or Selenites. Zinc silicofluoride, ........... .................. .......... ............. .......... .......... ........... ........... ........... ....... see Zinc fluorosilicate. Zirconium, dry, 4.1 UN2858#
Passage 331III 4.1....... A1, IB8 151........... 213........ 240........ 25 kg 100 kg A ....... coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns). Zirconium, dry, 4.2 UN2009 III 4.2....... A1, A19, IB8 None.......... 213........ 240........ 25 kg 100 kg D ....... finished sheets, strip or coiled wire. Zirconium hydride... 4.1 UN1437 II 4.1....... A19, A20, IB4, None.......... 212........ 240........ 15 kg 50 kg E ....... N34 Zirconium nitrate... 5.1 UN2728 III 5.1....... A1, A29, IB8, IP3 152........... 213........ 240........ 25 kg 100 kg A ....... Zirconium picramate, 1.3C UN0236 II 1.3C...... None.......... 62......... None....... Forbidden Forbidden 10 5E dry or wetted with less than 20 percent water, by mass. Zirconium picramate, 4.1 UN1517 I 4.1....... 23, N41 None.......... 211........ None....... 1 kg 15 kg D 28, 36 wetted with not less than 20 percent water, by mass. Zirconium powder, 4.2 UN2008 I 4.2....... None.......... 211........ 242........ Forbidden Forbidden D ....... dry. .................... ........... .................. II 4.2....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg D ....... IP2, N5, N34 .................... ........... .................. III 4.2....... IB8, IP3 None.......... 213........ 241........ 25 kg 100 kg D ....... Zirconium powder, 4.1 UN1358 II 4.1....... A19, A20, IB6, None.......... 212........ 241........ 15 kg 50 kg E ....... wetted with not IP2, N34 less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Zirconium scrap..... 4.2 UN1932 III 4.2....... IB8, IP3, N34 None.......... 213........ 240........ Forbidden Forbidden D ....... Zirconium suspended 3 UN1308 I 3......... None.......... 201........ 243........ Forbidden Forbidden B ....... in a liquid. .................... ........... .................. II 3......... IB2 None.......... 202........ 242........ 5 L 60 L B ....... .................... ........... .................. III 3......... B1, IB2 150........... 203........ 242........ 60 L 220 L B ....... Zirconium 8 UN2503 III 8......... IB8, IP3 154........... 213........ 240........ 25 kg 100 kg A ....... tetrachloride.#
Passage 332BILLING CODE 14910 60 S 12. In Appendix B to Sec. 172.101, paragraphs 1. and 2. are revised and the List of Marine Pollutants is amended by removing 94 entries, adding 16 entries and revising 1 entry in appropriate alphabetical order to read as follows: Appendix B to Sec. 172.101--List of Marine Pollutants 1. See Sec. 171.4 of this subchapter for applicability to marine pollutants. This appendix lists potential marine pollutants as defined in Sec. 171.8 of this subchapter. 2. Marine pollutants listed in this appendix are not necessarily listed by name in the Sec. 172.101 Table. If a marine pollutant not listed by name or by synonym in the Sec. 172.101 Table meets the definition of any hazard Class 1 through 8, then you must determine the class and division of the material in accordance with Sec. 173.2a of this subchapter. You must also select the most appropriate hazardous material description and proper shipping name. If a marine pollutant not listed by name or by synonym in the Sec. 172.101 Table does not meet the definition of any Class 1 through 8, then you must offer it for transportation under the most appropriate of the following two Class 9 entries: ``Environmentally hazardous substances, liquid, n.o.s.,'' UN3082, or ``Environmentally hazardous substances, solid, n.o.s.'' UN3077.#
Passage 333List of Marine Pollutants ------------------------------------------------------------------------ S.M.P. Marine Pollutant ------------------------------------------------------------------------ (1) (2) ------------------------------------------------------------------------ [Remove:] AcetalAcetaldehyde Amyl mercaptans Anisole Benzaldehyde Butyl benzenes n-Butyl butyrate Butyl mercaptans Butylphenols, liquid Butylphenols, solid Butyraldehyde Calcium naphthenate Camphor oil Chlorotoluenes (ortho-, meta-, para- ) Coal tar Coal tar naphtha Creosote (coal tar) Creosote (wood tar) Cresols (o-; m-; p-) Cresylic acid Cresylic acid sodium salt normal-Decaldehyde normal-Decanol Decyl acrylate 1,2-Dichlorobenzene Dichlorobenzene (meta; ortho; para) Dichlorophenols, liquid Dichlorophenols, solid 2,4-Dichlorophenoxyacetic acid (see also 2,4D) 2,4 Dichlorophenoxyacetic acid diethanolamine salt 2,4 Dichlorophenoxyacetic acid dimethylamine salt 2,4-Dichlorophenoxyacetic acid triisopropylamine salt Diethybenzenes (mixed isomers) Diisopropylnaphthalene Dimethyl disulphide Dimethyl glyoxal (butanedione) Dimethyl sulphide Diphenyl ether Diphenyl ether/biphenyl phenyl ether mixtures Diphenyl/diphenyl ether (mixtures) EPTC (ISO) Ethyl acrylate, inhibited Ethyl chlorothioformate 1-Ethyl-2-methylbenzene 2-Ethylbutyraldehyde 2-Ethylhexenal 2,4-Hexadiene aldehyde normal-Hexaldehyde Iron oxide, spent Iron sponge, spent Isobutyl aldehyde Isobutyl isobutyrate Isobutyl priopionate Isobutyraldehyde Isodecaldehyde Isodecanol Isononanol Isooctanol Isopropylbenzene Isovaleraldehyde 1-Methyl-4-ethylbenzene 2-Methyl-5-ethylpyridine Methyl salicylate 2-Methylbutyraldehyde Methylnaphthalenes, liquid Methylnaphthalenes, solid Methylstyrenes, inhibited Naphthalene, crude or refined Naphthalene, molten Naphthenic acids, liquid Naphthenic acids, solid Nitrocresols Nitrotolueunes (ortho-;meta-;para- ), liquid Nitrotoluenes (ortho-;meta-;para-), solid 1-Nonanal 1-Nonanol 1-Octanol Phenylethylene, inhibited alpha-Pinene Propanethiols Propionaldehyde n-Propylbenzene Styrene monomer, inhibited n-Tetramethylbenzenes 4-Thiapentanal 1,2,3-Trimethylbenzene 1,2,4-Trimethyl benzene 1,3,5-Trimethyl benzene Turpentine 1-Undecanol normal-Valeraldehyde Vinylbenzene, inhibited Vinyltoluenes, inhibited mixed isomers Xylenols [Add:] * * * * * Dichlorobenzene (meta-; para-)#
Passage 334* * * * * Diisopropylnaphthalenes, mixed isomers * * * * * Vinylidene chloride, stabilized Vinyltoluenes, stabilized * * * * * [Revise:] PP Dodecyl hydroxypropyl sulfide 13. In Sec. 172.102: a. In paragraph (c)(1), Special Provisions 43, 110 and 136 are revised and Special Provisions 139, 142 and 143 are added; b. In paragraph (c)(2), Special Provision A53 is added; c. Paragraph (c)(3) introductory text and Special Provisions B53 and B69 are revised; d. In paragraph (c)(3), Special Provisions B100, B101, B103, B104, B105, B106, B108, B109 and B110 are removed; e. Paragraphs (c)(4) and (c)(7) are revised; and f. Paragraph (c)(8), Special Provisions W7, W8 and W9 are added in numerical order. The additions and revisions read as follows:#
Passage 335* * * * * 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (see Sec. 171.7 of this subchapter). On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (see Sec. 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of this subchapter when contained individually in an article or a sealed packet. * * * * * 110 Fire extinguishers transported under UN1044 may include installed actuating cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per extinguishing unit. * * * * * 136 This entry only applies to machinery and apparatus containing hazardous materials as in integral element of the machinery or apparatus. It may not be used to describe machinery or apparatus for which a proper shipping name exists in the Sec. 172.101 Table. Except when approved by the Associate Administrator, machinery or apparatus may only contain hazardous materials for which exceptions are referenced in Column (8) of the Sec. 172.101 Table and are provided in part 173, subpart D, of this subchapter. Hazardous materials shipped under this entry are excepted from the labeling requirements of this subchapter unless offered for transportation or transported by aircraft and are not subject to the placarding requirements of part 173, subpart F, of this subchapter. Orientation markings as described in Sec. 172.312 (a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. The machinery or apparatus, if unpackaged, or the packaging in which it is contained shall be marked ``Dangerous#
Passage 336goods in machinery'' or ``Dangerous goods in apparatus'', as appropriate, with the identification number UN3363. For transportation by aircraft, machinery or apparatus may not contain any material forbidden for transportation by passenger or cargo aircraft. The Associate Administrator may except from the requirements of this subchapter, equipment, machinery and apparatus provided: a. It is shown that it does not pose a significant risk in transportation; b. The quantities of hazardous materials do not exceed those specified in Sec. 173.4 of this subchapter; and c. The equipment, machinery or apparatus conforms with Sec. 173.222 of this subchapter. * * * * * 139 Use of the ``special arrangement'' proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in Sec. 173.471, Sec. 173.472, or Sec. 173.473 of this subchapter. Use of these proper shipping names for domestic shipments may be made only under a DOT exemption, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. * * * * * 142 These hazardous materials may not be classified and transported unless authorized by the Associate Administrator. The Associate Administrator will base the authorization on results from Series 2 tests and a Series 6(c) test from the UN Manual of Tests and Criteria (see Sec. 171.7 of this subchapter) on packages as prepared for transport in accordance with the requirements of this subchapter. 143 These articles may contain: a. Division 2.2 compressed gases, including oxygen; b. Signal devices (Class 1) which may include smoke and illumination signal flares. Signal devices must be packed in plastic or fiberboard inner packagings; c. Electric storage batteries; d. First aid kits; or e. Strike anywhere matches. * * * * * A53 Refrigerating machines and refrigerating machine components are not subject to the requirements of this subchapter when containing less than 12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3 gallons) or less of ammonia solution (UN2672) (see Sec. 173.307 of this subchapter). (3) ``B'' codes. These provisions apply only to bulk packagings, other than IBCs:#
Passage 337* * * * * B53 Packagings must be made of either aluminum or steel. * * * * * B69 Dry sodium cyanide or potassium cyanide may be shipped in sift-proof weather-resistant metal covered hopper cars, covered motor vehicles, portable tanks or non-specification bins. Siftproof, water-resistant, fiberboard IBCs are permitted when transported in closed freight containers or transport vehicles. Bins must be approved by the Associate Administrator. * * * * * (4) Table 1, Table 2, and Table 3--IB Codes, Organic Peroxide IBC Code, and IP Special IBC Packing Provisions. These provisions apply only to transportation in IBCs. IBCs may be used for the transportation of hazardous materials when no IBC code is assigned in the Sec. 172.101 Table for the specific material only when approved by the Associate Administrator. Tables 1, 2, and 3 follow:#
Passage 338Table 1.--IB Codes (IBC Codes) ------------------------------------------------------------------------ IBC Code Authorized IBCs ------------------------------------------------------------------------ IB1.................... Authorized IBCs: Metal (31A, 31B and 31N). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 deg.C (1.1 bar at 122 deg.F), or 130 kPa at55 deg.C (1.3 bar at 131 deg.F) are authorized. IB2.................... Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 deg.C (1.1 bar at 122 deg.F), or 130kPa at 55 deg.C (1.3 bar at 131 deg.F) are authorized. IB3.................... Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 deg.C (1.1 bar at 122 deg.F), or 130 kPa at 55 deg.C (1.3 bar at 131 deg.F) are authorized. IB4.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N). IB5.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1). IB6.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport. IB7.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F). Additional Requirement: Liners of wooden IBCs must be sift-proof. IB8.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IB99....#
Passage 339............... IBCs are only authorized if approved by the Associate Administrator. ------------------------------------------------------------------------#
Passage 340Table 2.--Organic Peroxide IBC Code (IB52) [This IBC Code applies to organic peroxides of type F. For formulations not listed in this table, only IBCs that are approved by the Associate Administrator may be used.] ---------------------------------------------------------------------------------------------------------------- Maximum UN No. Organic peroxide Type of IBC quantity Control Emergency (liters) temperature temperature ---------------------------------------------------------------------------------------------------------------- 3109............... ORGANIC PEROXIDE, TYPE F, LIQUID tert-Butyl 31A 1250 hydroperoxide, not more than 72% with water. tert-Butyl 31A 1250 peroxyacetate, not 31HA1 1000 more than 32% in diluent type A. tert-Butyl peroxy- 31A 1250 3,5,5- 31HA1 1000 trimethylhexanoate , not more than 32% in diluent type A. Cumyl 31HA1 1250 hydroperoxide, not more than 90% in diluent type A. Dibenzoyl peroxide, 31H1 1000 not more than 42% as a stable dispersion. Di-tert-butyl 31A 1250 peroxide, not more 31HA1 1000 than 52% in diluent type A. 1,1-Di-(tert- 31H1 1000 butylperoxy) cyclohexane, not more than 42% in diluent type A. Dilauroyl peroxide, 31HA1 1000 not more than 42%, stable dispersion, in water. Isopropyl cumyl 31HA1 1250 hydroperoxide, not more than 72% in diluent type A. p-Menthyl 31HA1 1250 hydroperoxide, not more than 72% in diluent type A. Peroxyacetic acid, 31H1 1500 stabilized, not 31HA1 1500 more than 17%. 31A 1500 3110............... Organic peroxide 31A type F, solid. 31H1 31HA1 Dicumyl peroxide... 31A 31H1 31HA1 3119............... ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED tert-Butyl peroxy-2- 31HA1 1000 +30 deg.C +35 deg.C ethylhexanoate, 31A 1250 +30 deg.C +35 deg.C not more than 32% in diluent type B. tert-Butyl 31A 1250 0 deg.C +10 deg.C peroxyneodecanoate , not more than 32% in diluent type A. tert-Butyl 31A 1250 -5 deg.C +5 deg.C peroxyneodecanoate , not more than 42% stable dispersion, in water. tert-Butyl 31HA1 1000 +10 deg.C +15 deg.C peroxypivalate, 31A 1250 +10 deg.C +15 deg.C not more than 27% in diluent type B. Cumyl 31A 1250 -15 deg.C -5 deg.C peroxyneodecanoate , not more than 52%, stable dispersion, in water. Di-(4-tert- 31HA1 1000 +30 deg.C +35 deg.C butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water. Dicetyl 31HA1 1000 +30 deg.C +35 deg.C peroxydicarbonate, not#
Passage 341more than 42%, stable dispersion, in water. Di-(2-ethylhexyl) 31A 1250 -20 deg.C -10 deg.C peroxydicarbonate, not more than 52%, stable dispersion, in water. Dimyristyl 31HA1 1000 +15 deg.C +20 deg.C peroxydicarbonate, not more than 42%, stable dispersion, in water. Di-(3,5,5- 31HA1 1000 +10 deg.C +15 deg.C trimethylhexanoyl) 31A 1250 +10 deg.C +15 deg.C peroxide, not more than 38% in diluent type A. Di-(3,5,5- 31A 1250 +10 deg.C +15 deg.C trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water. 1,1,3,3- 31A 1250 -5 deg.C +5 deg.C Tetramethylbutyl peroxyneodecanoate , not more than 52%, stable dispersion, in water. ---------------------------------------------------------------------------------------------------------------- Table 3.--IP Codes ------------------------------------------------------------------------ ------------------------------------------------------------------------- IP1 IBCs must be packed in closed freight containers or a closed transport vehicle. IP2 When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. IP3 Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. IP4 Flexible, fiberboard or wooden IBCs must be sift-proof and water- resistant or be fitted with a sift-proof and water-resistant liner. IP5 IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. IP6 Non-specification bulk bins are authorized. IP7 For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter. ------------------------------------------------------------------------#
Passage 342* * * * * (7) ``T'' codes. (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. In T23, the organic peroxides and self- reactive substances which are authorized to be transported in portable tanks are listed along with the applicable control and emergency temperatures. Liquefied compressed gases are assigned to portable tank instruction T50. T50 provides the maximum allowable working pressures, bottom opening requirements, pressure relief requirements and degree of filling requirements for liquefied compressed gases permitted for transport in portable tanks. Refrigerated liquefied gases which are authorized to be transported in portable tanks are specified in tank instruction T75. (ii) The following table specifies the portable tank requirements applicable to T Codes T1 through T22. Column 1 specifies the T Code. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by Sec. 180.605 of this subchapter must be conducted. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of Sec. 178.275(g)(3) of this subchapter for the pressure relief devices. When the word ``Normal'' is indicated, Sec. 178.275(g)(3) of this subchapter does not apply. Column 5 references the applicable requirements for bottom openings in part 178 of this subchapter or references ``Prohibited'' which means bottom openings are prohibited. The table follows:#
Passage 343Table of Portable Tank T Coder T1-T22 [Portable tank code T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.] ---------------------------------------------------------------------------------------------------------------- Minimum test Minimum shell thickness Pressure-relief Bottom opening Portable tank pressure (in mm-reference steel) requirements (See requirements (See Sec. instruction (bar) (See Sec. 178.274(d)) Sec. 178.275(g)) 178.275(d)) (1) (2) (3) (4)............... (5) ---------------------------------------------------------------------------------------------------------------- T1.................. 1.5 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(2). T2.................. 1.5 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3). T3.................. 2.65 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(2). T4.................. 2.65 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3). T5.................. 2.65 Sec. 178.274(d)(2) Sec. 178.275(g)(3 Prohibited. ). T6.................. 4 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(2). T7.................. 4 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3). T8.................. 4 Sec. 178.274(d)(2) Normal............ Prohibited. T9.................. 4 6 mm Normal............ Prohibited. T10................. 4 6 mm Sec. 178.275(g)(3 Prohibited. ). T11................. 6 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3). T12................. 6 Sec. 178.274(d)(2) Sec. 178.275(g)(3 Sec. 178.275(d)(3). ). T13................. 6 6 mm Normal............ Prohibited. T14................. 6 6 mm Sec. 178.275(g)(3 Prohibited. ). T15................. 10 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3). T16................. 10 Sec. 178.274(d)(2) Sec. 178.275(g)(3 Sec. 178.275(d)(3). ). T17................. 10 6 mm Normal............ Sec. 178.275(d)(3). T18................. 10 6 mm Sec. 178.275(g)(3 Sec. 178.275(d)(3). ). T19................. 10 6 mm Sec. 178.275(g)(3 Prohibited. ). T20................. 10 8 mm Sec. 178.275(g)(3 Prohibited. ). T21................. 10 10 mm Normal............ Prohibited. T22................. 10 10 mm Sec. 178.275(g)(3 Prohibited. ). ----------------------------------------------------------------------------------------------------------------#
Passage 344(iii) The following table specifies the portable tank requirements applicable to T23 for self-reactive substances of Division 4.1 and organic peroxides of Division 5.2 which are authorized to be transported in portable tanks:#
Passage 345Portable Tank Code T23 [Portable tank code T23 applies to self-reactive substances of Division 4.1 and organic peroxides of Division 5.2.] -------------------------------------------------------------------------------------------------------------------------------------------------------- Minimum Minimum shell Hazardous test thickness (mm- Bottom opening Pressure-relief Control Emergency UN No. material pressure reference steel) requirements See requirements See Filling limits tempereature temperature (bar) See . . . . . . . . . -------------------------------------------------------------------------------------------------------------------------------------------------------- 3109 Organic peroxide, 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than Type F, liquid 2) 3) 1) 90% at 59 deg. F (15 deg.C) tert-Butyl 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than hydroperoxide, 2) 3) 1) 90% at 59 deg. not more than F (15 deg.C) 72% with water. *Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water Cumyl hydro- 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than peroxide, not 2) 3) 1) 90% at 59 deg. more than 90% in F (15 deg.C) diluent type A Di-tert-butyl 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than peroxide, not 2) 3) 1) 90% at 59 deg. more than 32% in F (15 deg.C) diluent type A Isopropyl cumyl 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than hydro-peroxide, 2) 3) 1) 90% at 59 deg. not more than F (15 deg.C) 72% in diluent type A p-Menthyl hydro- 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than peroxide, not 2) 3) 1) 90% at 59 deg. more than 72% in F (15 deg.C) diluent type A Pinanyl hydro- 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than peroxide, not 2) 3) 1) 90% at 59 deg. more than 50% in F (15 deg.C) diluent type A -------------------------------------------------------------------------------------------------------------------------------------------------------- 3110 Organic peroxide, 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than Type F, solid 2) 3) 1) 90% at 59 deg. F (15 deg.C) Dicumyl peroxide. *Maximum quantity per portable tank 2,000 kg -------------------------------------------------------------------------------------------------------#
Passage 346------------------------------------------------- 3119 Organic peroxide, 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than As approved by As approved by Type F, liquid, 2) 3) 1) 90% at 59 deg. Assoc. Admin. Assoc. Admin. temperature F (15 deg.C) controlled tert-Butyl 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than +30 deg.C +35 deg.C peroxyacetate, 2) 3) 1) 90% at 59 deg. not more than F (15 deg.C) 32% in diluent tyupe B tert-Butyl peroxy- 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than +15 deg.C +20 deg.C 2- 2) 3) 1) 90% at 59 deg. ethylhexanoate, F (15 deg.C) not more than 32% in diluent type B tert-Butyl 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than -5 deg.C +10 deg.C peroxypivalate, 2) 3) 1) 90% at 59 deg. not more than F (15 deg.C) 27% in diluent type B#
Passage 347tert-Butyl peroxy- 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than +35 deg.C +40 deg.C 3,5,5-trimethyl- 2) 3) 1) 90% at 59 deg. hexanoate, not F (15 deg.C) more than 32% in dileunt type B Di-(3,5,5- 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than 0 deg.C +5 deg.C trimethyl- 2) 3) 1) 90% at 59 deg. hexanoyl) F (15 deg.C) peroxide, not more htan 38% in diluent type A -------------------------------------------------------------------------------------------------------------------------------------------------------- 3120 Organix peroxide, 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than As approved by As approved by Type F, solid, 2) 3) 1) 90% at 59 deg. Assoc. Admin. Assoc. Admin. temperature F (15 deg.C) controlled -------------------------------------------------------------------------------------------------------------------------------------------------------- 3229 Self-reactive 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than liquid Type F 2) 3) 1) 90% at 59 deg. F (15 deg.C) -------------------------------------------------------------------------------------------------------------------------------------------------------- 3230 Self-reactive 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than solid Type F 2) 3) 1) 90% at 59 deg. F (15 deg.C) -------------------------------------------------------------------------------------------------------------------------------------------------------- 3239 Self-reactive 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than As approved by As approved by liquid Type F, 2) 3) 1) 90% at 59 deg. Assoc. Admin. Assoc. Admin. temperature F (15 deg.C) controlled -------------------------------------------------------------------------------------------------------------------------------------------------------- 3240 Self-reactive 4 Sec. 178.274(d)( Sec. 178.275(d)( Sec. 178.275(g)( Not more than As approved by As approved by solid Type F, 2) 3) 1) 90% at 59 deg. Assoc. Admin. Assoc. Admin. temperature F (15 deg.C) controlled --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 348(iv) The following portable tank instruction applies to portable tanks used for the transportation of liquefied compressed gases. The T50 table provides the UN identification number and proper shipping name for each liquefied compressed gas authorized to be transported in a T50 portable tank. The table provides maximum allowable working pressures, bottom opening requirements, pressure relief device requirements and degree of filling requirements for each liquefied compressed gases permitted for transportation in a T50 portable tank. In the minimum test pressure column, ``small'' means a portable tank with a diameter of 1.5 meters or less when measured at the widest part of the shell, ``sunshield'' means a portable tank with a shield covering at least the upper third of the shell, ``bare'' means no sunshield or insulation is provided, and ``insulated'' means a complete cladding of sufficient thickness of insulating material necessary to provide a minimum conductance of not more than 0.67 w/m2/k. In the pressure relief requirements column, the word ``Normal'' denotes that a frangible disc as specified in Sec. 178.276(e)(3) of this subchapter is not required. The T50 table follows:#
Passage 349Portable Tank Code T50 [Portable tank code T50 applies to liquefied compressed gases.] -------------------------------------------------------------------------------------------------------------------------------------------------------- Non-refrigerated Max. allowable working Pressure relief UN No. liquefied pressure (bar) small; bare; Openings below liquid requirements (see Sec. Maximum filling density compressed gases sunshield; insulated level 178.27(e)) (kg/l) -------------------------------------------------------------------------------------------------------------------------------------------------------- 1005............... Ammonia, anhydrous 29.0....................... Allowed................... Sec. 178.276(e)(3)....... 0.53 25.7....................... 22.0....................... 19.7....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1009............... Bromotrifluorometh 38.0....................... Allowed................... Normal.................... 1.13 ane or 34.0....................... Refrigerant gas R 30.0....................... 13B1. 27.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1010............... Butadienes, 7.5........................ Allowed................... Normal.................... 0.55 stabilized. 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1011............... Butane............ 7.0........................ Allowed................... Normal.................... 0.51 7.0........................ 7.0........................ 7.0........................ --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 3501012............... Butylene.......... 8.0........................ Allowed................... Normal.................... 0.53 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1017............... Chlorine.......... 19.0....................... Not Allowed............... Sec. 178.276(e)(3)....... 1.25 17.0....................... 15.0....................... 13.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1018............... Chlorodifluorometh 26.0....................... Allowed................... Normal.................... 1.03 ane or 24.0....................... Refrigerant gas R 21.0....................... 22. 19.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1020............... Chloropentafluoroe 23.0....................... Allowed................... Normal.................... 1.06 thane or 20.0....................... Refrigerant gas R 18.0....................... 115. 16.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1021............... 1-Chloro-1,2,2,2- 10.3....................... Allowed................... Normal.................... 1.2 tetrafluoroethane 9.8........................ or Refrigerant 7.9........................ gas R 124. 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1027............... Cyclopropane...... 18.0....................... Allowed................... Normal.................... 0.53 16.0....................... 14.5....................... 13.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1028............... Dichlorodifluorome 16.0....................... Allowed................... Normal....................#
Passage 3511.15 thane or 15.0....................... Refrigerant gas R 13.0....................... 12. 11.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1029............... Dichlorofluorometh 7.0........................ Allowed................... Normal.................... 1.23 ane or 7.0........................ Refrigerant gas R 7.0........................ 21. 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1030............... 1,1-Difluoroethane 16.0....................... Allowed................... Normal.................... 0.79 or Refrigerant 14.0....................... gas R 152a. 12.4....................... 11.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1032............... Dimethylamine, 7.0........................ Allowed................... Normal.................... 0.59 anhydrous. 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1033............... Dimethyl ether.... 15.5....................... Allowed................... Normal.................... 0.58 13.8....................... 12.0....................... 10.6....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1036............... Ethylamine........ 7.0........................ Allowed................... Normal.................... 0.61 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1037............... Ethyl chloride.... 7.0........................ Allowed................... Normal.................... 0.8 7.0........................ 7.0........................ 7.0........................ ---------------------------------------#
Passage 352-----------------------------------------------------------------------------------------------------------------#
Passage 3531040............... Ethylene oxide Only authorized in 10 bar Not allowed............... Sec. 178.276(e)(3)....... 0.78 with nitrogen up insulatedportable tanks. to a total pressure of 1MPa (10 bar) at 50 deg.C. -------------------------------------------------------------------------------------------------------------------------------------------------------- 1041............... Ethylene oxide and See MAWP defination in Sec. Allowed................... Normal.................... See Sec. 173.32(f) carbon dioxide 178.276(a). mixture with more than 9% butnot more than 87% ethylene oxide. -------------------------------------------------------------------------------------------------------------------------------------------------------- 1055............... Isobutylene....... 8.1........................ Allowed................... Normal.................... 0.52 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1060............... Methyl acetylene 28.0....................... Allowed................... Normal.................... 0.43 and propadiene 24.5....................... mixture, 22.0....................... stabilized. 20.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1061............... Methylamine, 10.8....................... Allowed................... Normal.................... 0.58 anhydrous. 9.6........................ 7.8........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1062............... Methyl bromide.... 7.0........................ Not allowed............... Sec. 178.276(e)(3)....... 1.51 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1063............... Methyl chloride or 14.5....................... Allowed................... Normal.................... 0.81 Refrigerant gas R 12.7...............#
Passage 354........ 40. 11.3....................... 10.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1064............... Methyl mercaptan.. 7.0........................ Not allowed............... Sec. 178.276(e)(3)....... 0.78 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1067............... Dinitrogen 7.0........................ Not allowed............... Sec. 178.276(e)(3)....... 1.3 tetroxide. 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1075............... Petroleum gas, See MAWP definition in Sec. Allowed................... Normal.................... See Sec. 173.32(f) liquefied. 178.276(a). -------------------------------------------------------------------------------------------------------------------------------------------------------- 1077............... Propylene......... 28.0....................... Allowed................... Normal.................... 0.43 24.5....................... 22.0....................... 20.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1078............... Refrigerant gas, See MAWP definition in Sec. Allowed................... Normal.................... See Sec. 173.32(f) n.o.s.. 178.276(a). -------------------------------------------------------------------------------------------------------------------------------------------------------- 1079............... Sulphur dioxide... 11.6....................... Not allowed............... Sec. 178.276(e)(3)....... 1.23 10.3....................... 8.5........................ 7.6........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1082............... Trifluorochloroeth 17.0....................... Not allowed............... Sec. 178.2#
Passage 35576(e)(3)....... 1.13 ylene, stabilized 15.0....................... or Refrigerant 13.1....................... gas R 1113. 11.6....................... --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 3561083............... Trimethylamine, 7.0........................ Allowed................... Normal.................... 0.56 anhydrous. 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1085............... Vinyl bromide, 7.0........................ Allowed................... Normal.................... 1.37 stabilized. 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1086............... Vinyl chloride, 10.6....................... Allowed................... Normal.................... 0.81 stabilized. 9.3........................ 8.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1087............... Vinyl methyl 7.0........................ Allowed................... Normal.................... 0.67 ether, stabilized. 7.0........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1581............... Chloropicrin and 7.0........................ Not Allowed............... Sec. 178.276(e)(3)....... 1.51 methyl bromide 7.0........................ mixture. 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1582............... Chloropicrin and 19.2....................... Not allowed............... Sec. 178.276(e)(3)....... 0.81 methyl chloride 16.9....................... mixture. 15.1....................... 13.1....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1858............... Hexafluoropropylen 19.2....................... Allowed................... Normal.................... 1.11 e compressed or#
Passage 35716.9....................... Refrigerant gas R 15.1....................... 1216. 13.1....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1912............... Methyl chloride 15.2....................... Allowed................... Normal.................... 0.811954 and methylene 13.0....................... chloride mixture. 11.6....................... 10.1....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- NA 1954............ Insecticide gases, See MAWP definition in Sec. Allowed................... Normal.................... Sec. 173.32(f) flammable, n.o.s.. 178.276(a). -------------------------------------------------------------------------------------------------------------------------------------------------------- 1958............... 1,2-Dichloro- 7.0........................ Allowed................... Normal.................... 1.3 1,1,2,2- 7.0........................ tetrafluoroethane 7.0........................ or Refrigerant 7.0........................ gas R 114. -------------------------------------------------------------------------------------------------------------------------------------------------------- 1965............... Hydrocarbon gas, See MAWP definition in Allowed................... Normal.................... See Sec. 173.32(f) mixture 178.276(a). liquefied, n.o.s.. -------------------------------------------------------------------------------------------------------------------------------------------------------- 1969............... Isobutane......... 8.5........................ Allowed................... Normal.................... 0.49 7.5........................ 7.0........................ 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1973............... Chlorodifluorometh 28.3....................... Allowed................... Normal.................... 1.05 ane and 25.3....................... chloropentafluoro 22.8....................... ethane mixture 20.3....................... with fixed boiling point, withapproximately 49% chlorodifluoromet hane or#
Passage 358Refrigerant gas R502. -------------------------------------------------------------------------------------------------------------------------------------------------------- 1974............... Chlorodifluorobrom 7.4........................ Allowed................... Normal.................... 1.61 omethane or 7.0........................ Refrigerant gas R 7.0........................ 12B1. 7.0........................ --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 3591976............... Octafluorocyclobut 8.8........................ Allowed................... Normal.................... 1.34 ane or 7.8........................ Refrigerant gas 7.0........................ RC 318. 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 1978............... Propane........... 22.5....................... Allowed................... Normal.................... 0.42 20.4....................... 18.0....................... 16.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 1983............... 1-Chloro-2,2,2- 7.0........................ Allowed................... Normal.................... 1.18 trifluoroethane 7.0........................ or Refrigerant 7.0........................ gas R 133a. 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 2035............... 1,1,1- 31.0....................... Allowed................... Normal.................... 0.76 Trifluoroethane 27.5....................... compressed or 24.2....................... Refrigerant gas R 21.8....................... 143a. -------------------------------------------------------------------------------------------------------------------------------------------------------- 2424............... Octafluoropropane 23.1....................... Allowed................... Normal.................... 1.07 or Refrigerant 20.8....................... gas R 218. 18.6....................... 16.6....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 2517............... 1-Chloro-1,1- 8.9........................ Allowed................... Normal.................... 0.99 difluoroethane or 7.8........................ Refrigerant gas R 7.0........................ 142b. 7.0........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 2602............... Dichlorodifluorome 20.0....#
Passage 360................... Allowed................... Normal.................... 1.01 thane and 18.0....................... difluoroethane 16.0....................... azeotropic 14.5....................... mixture with approximately 74% dichlorodifluorom ethane or Refrigerant gas R 500. -------------------------------------------------------------------------------------------------------------------------------------------------------- 3057............... Trifluoroacetyl 14.6....................... Not allowed............... Sec. 178.276(e)(3)....... 1.17 chloride. 12.9....................... 11.3....................... 9.9........................ -------------------------------------------------------------------------------------------------------------------------------------------------------- 3070............... Ethylene oxide and 14.0....................... Allowed................... Sec. 178.276(e)(3)....... 1.09 dichlorodifluorom 12.0....................... ethane mixture 11.0....................... with not more 9.0........................ than 12.5% ethylene oxide. -------------------------------------------------------------------------------------------------------------------------------------------------------- 3153............... Perfluoro (methyl 14.3....................... Allowed................... Normal.................... 1.14 vinyl ether). 13.4....................... 11.2....................... 10.2....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3159............... 1,1,1,2- 17.7....................... Allowed................... Normal.................... 1.04 Tetrafluoroethane 15.7....................... or Refrigerant 13.8....................... gas R 134a. 12.1....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3161............... Liquefied gas, See MAWP definition in Sec. Allowed................... Normal.................... Sec. 173.32(f) flammable, n.o.s.. 178.276(a). -------------------------------------------------------------------------------------------------------------------------------------------------------- 3163............... Liquefied gas, See MAWP definition in Sec. Allowed.#
Passage 361.................. Normal.................... Sec. 173.32(f) n.o.s.. 178.276(a). --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 3623220............... Pentafluoroethane 34.4....................... Allowed................... Normal.................... 0.95 or Refrigerant 30.8....................... gas R 125. 27.5....................... 24.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3252............... Difluoromethane or 43.0....................... Allowed................... Normal.................... 0.78 Refrigerant gas R 39.0....................... 32. 34.4....................... 30.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3296............... Heptafluoropropane 16.0....................... Allowed................... Normal.................... 1.2 or Refrigerant 14.0....................... gas R 227. 12.5....................... 11.0....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3297............... Ethylene oxide and 8.1........................ Allowed................... Normal.................... 1.16 chlorotetrafluoro 7.0........................ ethane mixture, 7.0........................ with not more 7.0........................ than 8.8% ethylene oxide. -------------------------------------------------------------------------------------------------------------------------------------------------------- 3298............... Ethylene oxide and 25.9....................... Allowed................... Normal.................... 1.02 pentafluoroethane 23.4....................... mixture, with not 20.9....................... more than 7.9% 18.6....................... ethylene oxide. -------------------------------------------------------------------------------------------------------------------------------------------------------- 3299............... Ethylene oxide and 16.7....................... Allowed................... Normal.................... 1.03 tetrafluoroethane 14.7....................... mixture, with not 12.9....................... more than 5.6% 11.2....................... ethylene oxide. -----------------------------------------------------------------------------------------------#
Passage 363--------------------------------------------------------- 3318............... Ammonia solution, See MAWP definition in Allowed................... Sec. 178.276(e)(3)....... Sec. 173.32(f) relative density 178.276(a). less than 0.880 at 15 deg.C in water, with more than 50% ammonia. -------------------------------------------------------------------------------------------------------------------------------------------------------- 3337............... Refrigerant gas R 31.6....................... Allowed................... Normal.................... 0.84 404A. 28.3....................... 25.3....................... 22.5....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3338............... Refrigerant gas R 31.3....................... Allowed................... Normal.................... 0.95 407A. 28.1....................... 25.1....................... 22.4....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3339............... Refrigerant gas R 33.0....................... Allowed................... Normal.................... 0.95 407B. 29.6....................... 26.5....................... 23.6....................... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3340............... Refrigerant gas R 29.9....................... Allowed................... Normal.................... 0.95 407C. 26.8....................... 23.9....................... 21.3....................... --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 364(v) When portable tank instruction T75 is referenced in Column (7) of the Sec. 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of Sec. 178.277 of this subchapter. (vi) UN and IM portable tank codes/special provisions. When a specific portable tank instruction is specified by a T Code in Column (7) of the Sec. 172.101 Table for a specific hazardous material, a Specification portable tank conforming to an alternative tank instruction may be used if: (A) the alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) the alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) the alternative portable tank has a pressure relief device as specified in the T Code. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and (D) With regard to bottom openings-- (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or (3) When no bottom openings are authorized, the alternative portable tank must ot have bottom openings. (vii) When a hazardous material is not assigned a portable tank T Code or TP 9 is referenced in Column (7) of the Sec. 172.101 Table, the hazardous material may only be transported in a portable tank if approved by the Associate Administrator. (viii) Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the Sec. 172.101 Table. The following is a list of the portable tank special provisions:#
Passage 365TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: [GRAPHIC] [TIFF OMITTED] TN21JN01.000 tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following: [GRAPHIC] [TIFF OMITTED] TN21JN01.001 tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions may be calculated using the formula: [GRAPHIC] [TIFF OMITTED] TN21JN01.009 d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 deg.C (59 deg.F) and 50 deg.C (122 deg.F), respectively. TP3 For liquids transported under elevated temperature, the maximum degree of filling is determined by the following: [GRAPHIC] [TIFF OMITTED] TN21JN01.002 dt is the density of the material at the maximum mean bulk temperature during transport; and df is the density of the material at the temperature in degrees celsius of the liquid during filling; and df is the density of the liquid at the mean temperature of the liquid during filling, and dt is the maximum mean bulk temperature during transport.#
Passage 366TP4 The maximum degree of filling for portable tanks must not exceed 90%. TP5 For a portable tank used for the transport of flammable refrigerated liquefied gases or refrigerated liquefied oxygen, the maximum rate at which the portable tank may be filled must not exceed the liquid flow capacity of the primary pressure relief system rated at a pressure not exceeding 120 percent of the portable tank's design pressure. For portable tanks used for the transport of refrigerated liquefied helium and refrigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the tank is filled must not exceed the liquid flow capacity of the pressure relief device rated at 130 percent of the portable tank's design pressure. Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. No outage is required for helium. TP6 To prevent the tank from bursting in an event, including fire engulfment (the conditions prescribed in CGA pamphlet S-1.2 (see Sec. 171.7 of this subchapter) may be used to consider the fire engulfment condition), it must be equipped with pressure relief devices that are adequate in relation to the capacity of the tank and the nature of the hazardous material transported. TP7 The vapor space must be purged of air by nitrogen or other means. TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 deg.C (32 deg.F). TP9 A hazardous material assigned to special provision TP9 in Column (7) of the Sec. 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. TP10 The portable tank must be fitted with a lead lining at least 5 mm (0.2 inches) thick. The lead lining must be tested annually to ensure that it is intact and functional. Another suitable lining material may be used if approved by the Associate Administrator. TP12 This material is considered highly corrosive to steel. TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. TP16 The portable tank must be protected against over and under pressurization which may be experienc#
Passage 367ed during transportation. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. The pressure relief device must be preceded by a frangible disk in accordance with the requirements in Sec. 178.275(g)(3) of this subchapter to prevent crystallization of the product in the pressure relief device. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. TP18 The temperature of this material must be maintained between 18 deg.C (64.4 deg.F) and 40 deg.C (104 deg.F) while in transportation. Portable tanks containing solidified methacrylic acid must not be reheated during transportation. TP19 The calculated wall thickness must be increased by 3 mm at the time of construction. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). The portable tank must not be used if the wall thickness is less than that prescribed by the applicable T code in Column (7) of the Table for this material. TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket. TP21 The wall thickness must not be less than 8 mm. Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. TP22 Lubricants for portable tank fittings (for example, gaskets, shut-off valves, flanges) must be oxygen compatible. TP24 The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. The device must be in the vapor space when the tank is filled under maximum filling conditions. This device must also prevent an unacceptable amount of leakage of liquid in the case of overturning. TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 deg.C (90.5 deg.F). TP26 The heating device must be exterior to the shell. For UN 3176, this requirement only applies when the hazardous material reacts dangerously with water. TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in S#
Passage 368ec. 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in Sec. 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in Sec. 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. TP30 This hazardous material may only be transported in insulated tanks. TP31 This hazardous material may only be transported in tanks in the solid state. TP37 IM portable tanks are only authorized for the shipment of hydrogen peroxide solutions in water containing 72% or less hydrogen peroxide by weight. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. In addition, the portable tank must be designed so that internal surfaces may be effectively cleaned and passivated. Each tank must be equipped with pressure relief devices conforming to the following requirements: ------------------------------------------------------------------------ Concentration of hydrogen per peroxide solution Total -------------------------------------------------------------------\1\-- 52% or less................................................... 11 Over 52%, but not greater than 60%............................ 22 Over 60%, but not greater than 72%............................ 32 ------------------------------------------------------------------------ \1\ Total venting capacity in standard cubic feet hour (S.C.F.H.) per pound of hydrogen peroxide solution.#
Passage 369TP38 Each portable tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 deg.C (60 deg.F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials may not promote corrosion to steel when wet. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of Sec. 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads must be the greater of 7.62 mm (0.300 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.5 times the vapor pressure of the hazardous material at 46 deg.C (115 deg.F). TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 deg.C (115 deg.F). TP46 Portable tanks in sodium metal service are not required to be hydrostatically retested. W7 Vessel stowage category for uranyl nitrate hexahydrate solution is ``D'' as defined in Sec. 172.101(k)(4). W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is ``D'' as defined in Sec. 172.101(k)(4). W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. * * * * * 14. In Sec. 172.202, paragraphs (a)(4) and (e) are revised to read as follows: Sec. 172.202 Description of hazardous material on shipping papers.#
Passage 370(a) * * * (4) The packing group in Roman numerals, as designated for the hazardous material in Column 5 of the Sec. 172.101 Table. Class 1 (explosives) materials, self-reactive substances, organic peroxides and entries that are not assigned a packing group are excepted from this requirement. The packing group may be preceded by the letters ``PG'' (for example, ``PG II''); and * * * * * (e) Except for those materials in the UN Recommendations, the ICAO Technical Instructions, or the IMDG Code (see Sec. 171.7 of this subchapter), a material that is not a hazardous material according to this subchapter may not be offered for transportation or transported when its description on a shipping paper includes a hazard class or an identification number specified in the Sec. 172.101 Table. 15. In Sec. 172.203, paragraph (d)(11) is revised, new paragraphs (i)(5) and (i)(6) are added, and paragraph (n) is revised to read as follows: Sec. 172.203 Additional description requirements. * * * * * (d) * * * (11) For a shipment of low specific activity material or surface contaminated objects, the appropriate group notation of LSA-I, LSA-II, LSA-III, SCO-I, or SCO-II, unless the group notation is contained in the proper shipping name as described in the Sec. 172.101 Table. * * * * * (i) * * * (5) Minimum flash point if 61 deg.C or below (in deg.C closed cup (c.c.) in association with the basic description. (6) Subsidiary hazards not communicated in the proper shipping name shown either following the hazard class or division in parentheses, or in association with the basic description. * * * * * (n) Elevated temperature materials. If a liquid material in a package meets the definition of an elevated temperature material in Sec. 171.8 of this subchapter, and the fact that it is an elevated temperature material is not disclosed in the proper shipping name (for example, when the words ``Molten'' or ``Elevated temperature'' are part of the proper shipping name), the word ``HOT'' must immediately precede the proper shipping name of the material on the shipping paper. * * * * *#
Passage 37116. In Sec. 172.330, in paragraph (a)(1)(ii), the following changes are made: a. The proper shipping name, ``Acrolein, inhibited'' is revised to read ``Acrolein, stabilized''. b. The proper shipping name, ``Chloroprene, inhibited'' is revised to read ``Chloroprene, stabilized''. c. The proper shipping name, ``Sulfur trioxide, inhibited'' is revised to read ``Sulfur trioxide, stabilized''. 17. In Sec. 172.402, paragraph (b) is revised to read as follows: Sec. 172.402 Additional labeling requirements. * * * * * (b) Display of hazard class on labels. The appropriate hazard class or division number must be displayed in the lower corner of a primary hazard label and a subsidiary hazard label. A subsidiary label meeting the specifications of this section which were in effect on September 30, 2001, such as, a label without the hazard class or division number displayed in the lower corner of the label) may continue to be used as a subsidiary label in domestic transportation by rail or highway until October 1, 2005, provided the color tolerances are maintained and are in accordance with the display requirements in this subchapter. * * * * * 18. In Sec. 172.405, the following changes are made: a. In paragraph (a) introductory text, the wording ``subsidiary label when--'' is removed and the wording ``subsidiary label.'' is added in its place. b. Paragraphs (a)(1) and (a)(2) are removed. 19-20. In Sec. 172.411, the section heading, the text of paragraph (c) preceding the labels, and paragraph (d) are revised and, in paragraph (c), the wording ``EXPLOSIVE SUBSIDIARY LABEL:'' and the explosive subsidiary label following it are removed, to read as follows: Sec. 172.411 EXPLOSIVE 1.1, 1.2, 1.3, 1.4, 1.5 and 1.6 labels. * * * * * (c) Except for size and color, the EXPLOSIVE 1.4, EXPLOSIVE 1.5 and EXPLOSIVE 1.6 labels must be as follows: * * * * * (d) In addition to complying with Sec. 172.407, the background color on the EXPLOSIVE 1.4, EXPLOSIVE 1.5, EXPLOSIVE 1.6 and EXPLOSIVE subsidiary label must be orange. The ``*'' shall be replaced with the appropriate compatibility group. The compatibility group letter must be shown as a capitalized Roman letter. Division numerals must measure at least 30 mm (1.2 inches) in height and at least 5 mm (0.2 inches) in width. 21. In Sec. 172.502, paragraph (b)(1) is revised to read as follows:#
Passage 372Sec. 172.502 Prohibited and permissive placarding. * * * * * (b) * * * (1) The restrictions in paragraph (a) of this section do not apply to a bulk packaging, freight container, unit load device, transport vehicle or rail car which is placarded in conformance with TDG Regulations, the IMDG Code or the UN Recommendations (see Sec. 171.7 of this subchapter). * * * * * 22. In Sec. 172.504, in paragraph (g), a sentence is added at the end of the existing text and paragraphs (g)(1) through (g)(4) are added to read as follows: Sec. 172.504 General placarding requirements. * * * * * (g) * * * When more than one compatibility group placard is required for Class 1 materials, only one placard is required to be displayed as follows: (1) Explosive articles of compatibility groups C, D or E may be placarded displaying compatibility group E. (2) Explosive articles of compatibility groups C, D, E or N may be placarded displaying compatibility group D. (3) Explosive substances of compatibility groups C and D may be placarded displaying compatibility group D. (4) Explosive articles of compatibility groups C, D, E or G, except for fireworks, may be placarded displaying compatibility group E. 23. In Sec. 172.512, in paragraph (a)(3), the wording ``ICAO Technical Instructions'' is removed and ``ICAO Technical Instructions (see Sec. 171.7 of this subchapter)'' is added in its place. 24. In Sec. 172.519, paragraph (b)(4) is revised to read as follows: Sec. 172.519 General specifications for placards.#
Passage 373* * * * * (b) * * * (4) For a placard corresponding to the primary or subsidiary hazard class of a material, the hazard class or division number must be displayed in the lower corner of the placard. However, a permanently affixed subsidiary placard meeting the specifications of this section which were in effect on September 30, 2001, (such as, a placard without the hazard class or division number displayed in the lower corner of the placard) and which was installed prior to September 30, 2001, may continue to be used as a subsidiary placard in domestic transportation by rail or highway, provided the color tolerances are maintained and are in accordance with the display requirements in this subchapter. Stocks of non-permanently affixed subsidiary placards in compliance with the requirements in effect on September 30, 2001, may continue to be used in domestic transportation by rail or highway until October 1, 2005, or until current stocks are depleted, whichever occurs first. * * * * * PART 173--SHIPPERS--GENERAL REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS 25. The authority citation for part 173 continues to read as follows: Authority: 49 U.S.C. 5101-5127, 44701; 49 CFR 1.53. 26. In Sec. 173.2a, in paragraph (b), in the Precedence of Hazard Table, in the first column, the first three entries are amended by adding a footnote reference ``\2\'' immediately following ``I'', ``II'', and ``III'', respectively, and footnote 2 at the end of the Precedence of Hazard Table is revised to read as follows: Sec. 173.2a Classification of a material having more than one hazard. Precedence of Hazard Table ------------------------------------------------------------------------ ------------------------------------------------------------------------- * * * * * * * * * * ------------------------------------------------------------------------ * * * * * \2\ Materials of Division 4.1 other than self-reactive substances and solid desensitized explosives, and materials of Class 3 other than liquid desensitized explosives. 27. In Sec. 173.4, paragraph (a)(1) introductory text is revised to read as follows: (a) * * * (1) The maximum quantity of material per inner receptacle or article is limited to-- * * * * * 28. In Sec. 173.24b, paragraph (e) is added to read as follows: Sec. 173.24b Additional general requirements for bulk packagings.#
Passage 374* * * * * (e) UN portable tanks. (1) A UN portable tank manufactured in the United States must conform in all details to the applicable requirements in parts 172, 173, 178 and 180 of this subchapter. (2) UN portable tanks manufactured outside the United States. A UN portable tank manufactured outside the United States, in accordance with national or international regulations based on the UN Recommendations on the Transport of Dangerous Goods which is an authorized packaging under Sec. 173.24 of this subchapter, may be filled, offered and transported in the United States, if the Sec. 172.101 Table of this subchapter authorizes the hazardous material for transportation in the UN portable tank and it conforms to the applicable T codes, and tank provision codes, or other special provisions assigned to the hazardous material in Column (7) of the Table when manufactured in a country other than the United States. In addition, the portable tank must be-- (i) Conform to applicable provisions in the UN Recommendations on the Transport of Dangerous Goods (see Sec. 171.7 of this subchapter) and the requirements of this subpart; (ii) Be capable of passing the prescribed tests and inspections in part 180 of this subchapter applicable to the UN portable tank specification; (iii) Be designed and manufactured according to the ASME Code (see Sec. 171.7 of this subchapter) or a pressure vessel design code approved by the Associate Administrator; (iv) Be approved by the Associate Administrator when the portable tank is designed and constructed under the provisions of an alternative arrangement (see Sec. 178.274(a)(2) of this subchapter); and (v) The competent authority of the country of manufacture must provide reciprocal treatment for UN portable tanks manufactured in the United States. 29. In Sec. 173.31, in paragraph (b)(2)(ii), in the first sentence, the wording ``chloroprene, inhibited'' is revised to read ``chloroprene, stabilized'. 30. Section 173.32 is revised to read as follows: Sec. 173.32 Requirements for the use of portable tanks.#
Passage 375(a) General requirements. No person may offer a hazardous material for transportation in a portable tank except as authorized by this subchapter. (1) Except as otherwise provided in this subpart, no person may use a portable tank for the transportation of a hazardous material unless it meets the requirements of this subchapter. (2) No person may fill and offer for transportation a portable tank when the prescribed periodic test or inspection under subpart G of part 180 of this subchapter has become due until the test or inspection has been successfully completed. This requirement does not apply to any portable tank filled prior to the test or inspection due date. (3) When a portable tank is used as a cargo tank motor vehicle, it must conform to all the requirements prescribed for cargo tank motor vehicles. (See Sec. 173.33.) (b) Substitute packagings. A particular Specification portable tank may be substituted for another portable tank as follows: (1) An IM or UN portable tank may be used whenever an IM or UN portable tank having less stringent requirements is authorized provided the portable tank meets or exceeds the requirements for pressure-relief devices, bottom outlets and any other special provisions specified in Sec. 172.102(c)(7)(vi) of this subchapter. (2) Where a Specification IM101 or IM102 portable tank is prescribed, a UN portable tank or Specification 51 portable tank otherwise conforming to the special commodity requirements of Sec. 172.102(c)(7) of this subchapter for the material to be transported may be used. (3) A DOT Specification 51 portable tank may be used whenever a DOT Specification 56, 57, or 60 portable tank is authorized. A DOT Specification 60 portable tank may be used whenever a DOT Specification 56 or 57 portable tank is authorized. A higher integrity tank used instead of a specified portable tank must meet the same design profile; for example, a DOT Specification 51 portable tank must be lined if used instead of a lined DOT Specification 60 portable tank. (c) Grandfather provisions for portable tanks--(1) Continued use of Specification 56 and 57 portable tanks. Continued use of an existing portable tank constructed to DOT Specification 56 or 57 is authorized only for a portable tank constructed before October 1, 1996. A stainless steel portable tank internally lined with polyethylene that was constructed on or before October 1#
Passage 376, 1996, and that meets all requirements of DOT Specification 57 except for being equipped with a polypropylene discharge ball valve and polypropylene secondary discharge opening closure, may be marked as a Specification 57 portable tank and used in accordance with the provisions of this section. (2) A DOT Specification 51, IM 101, or IM 102 portable tank may not be manufactured after January 1, 2003; however, such tanks may continue to be used for the transportation of a hazardous material provided they meet the requirements of this subchapter, including the specification requirements and the requirements of this subchapter for the transportation of the particular hazardous material (see Sec. 171.14(d)(4) of this subchapter), and provided it conforms to the periodic inspection and tests specified for the particular portable tank in subpart G of part 180 of this subchapter. After January 1, 2003, all newly manufactured portable tanks must conform to the requirements for the design, construction and approval of UN portable tanks as specified in Secs. 178.273, 178.274, 178.275, 178.276, 178.277 and part 180, subpart G, of this subchapter. (3) A DOT Specification portable tank manufactured prior to January 1, 1992 that is equipped with a non-reclosing pressure relief device may continue in service for the hazardous materials for which it is authorized. Except for a DOT Specification 56 or 57 portable tank, a DOT Specification portable tank manufactured after January 1, 1992, used for materials meeting the definition for Division 6.1 liquids, Packing Group I or II, Class 2 gases, or Class 3 or 4 liquids, must be equipped with a reclosing pressure relief valve having adequately sized venting capacity unless otherwise specified in this subchapter (see Secs. 178.275(f)(4) and 178.277 of this subchapter). (4) Any portable tank container constructed prior to May 15, 1950, complying with the requirements of either the ASME Code for Unfired Pressure Vessels, 1946 Edition, or the API ASME Code for Unfired Pressure Vessels, 1943 Edition (see Sec. 171.7 of this subchapter), may be used for the transportation of liquefied compressed gas, provided it fulfills all the requirements of the part and specifications for the particular gas or gases to be transported. Such portable tanks must be marked ``ICC Specification 51X'' on the plate required by the specification, except as m#
Passage 377odified by any or all of the following: (i) Portable tanks designed and constructed in accordance with Pars. U-68, U-69, or U-201 of the ASME Code (see Sec. 171.7 of this subchapter) may be used. Portable tanks designed and constructed in accordance with Par. U-68 or Par. U-69 may be re-rated at a working pressure 25 percent in excess of the design pressure for which the portable tank was originally constructed. If the portable tank is re- rated, the re-rated pressure must be marked on the plate as follows: ``Re-rated working pressure--psig''. Note to Paragraph (c)(4)(i): For purposes of setting safety relief valves, pressure control valves, establishing retest pressure and maximum and minimum design pressures, the re-rated working pressure must be considered as the equivalent of the design pressure as defined in the specification. (ii) Loading and unloading accessories, valves, piping, fittings, safety and gauging devices, do not have to comply with the requirements for the particular location on the portable tank. (5) Any ICC Specification 50 portable tank fulfilling the requirements of that specification may be continued in service for transportation of a liquefied petroleum gas if it is retested every five years in accordance with the requirements in Sec. 180.605 of this subchapter. Use of existing portable tanks is authorized. New construction is not authorized. (d) Determination of an authorized portable tank. Prior to filling and offering a portable tank for transportation, the shipper must ensure that the portable tank conforms to the authorized specification and meets the applicable requirements in this subchapter for the hazardous material. The shipper must ensure that the MAWP, design pressure or test pressure of the portable tank, as applicable, is appropriate for the hazardous material being transported. Determination of the applicable pressure must take into account the maximum pressure used to load or unload the hazardous material, the vapor pressure, static head and surge pressures of the hazardous#
Passage 378material and the temperatures that the hazardous material will experience during transportation. (e) External inspection prior to filling. Each portable tank must be given a complete external inspection prior to filling. Any unsafe condition must be corrected prior to its being filled and offered for transportation. The external inspection shall include a visual inspection of: (1) The shell, piping, valves and other appurtenances for corroded areas, dents, defects in welds and other defects such as missing, damaged, or leaking gaskets; (2) All flanged connections or blank flanges for missing or loose nuts and bolts; (3) All emergency devices for corrosion, distortion, or any damage or defect that could prevent their normal operation; (4) All required markings on the tank for legibility; and (5) Any device for tightening manhole covers to ensure such devices are operative and adequate to prevent leakage at the manhole cover. (f) Loading requirements. (1) A hazardous material may not be loaded into a portable tank if the hazardous material would: (i) Damage the portable tank; (ii) React with the portable tank; or (iii) Otherwise compromise its product retention capability. (2) A hazardous material may not be loaded in a DOT Specification 51, DOT Specification 60, an IM or UN portable tank unless the portable tank has a pressure relief device that provides total relieving capacity meeting the requirements of this subchapter. (3) Except during a pressure test, a portable tank may not be subjected to a pressure greater than its marked maximum allowable working pressure or, when appropriate, its marked design pressure. (4) A portable tank may not be loaded to a gross mass greater than the maximum allowable gross mass specified on its identification plate. (5) Except for a non-flowable solid or a liquid with a viscosity of 2,680 centistokes (millimeters squared per second) or greater at 20 deg.C (68 deg.F), an IM or UN portable tank, or compartment thereof, having a volume greater than 7,500 L (1,980 gallons) may not be loaded to a filling density of more than 20% and less than 80% by volume. This filling restriction does not apply if a portable tank is divided by partitions or surge plates into compartments of not more than 7,500 L (1,980 gallons) capacity; this portable tank must not be offered for transportation in an ullage condition liable to produce an unacce#
Passage 379ptable hydraulic force due to surge. (6) The outage for a portable tank may not be less than 2% at a temperature of 50 deg.C (122 deg.F) unless otherwise specified in this subchapter. For UN portable tanks, the applicable maximum filling limits apply as specified according to the assigned TP codes in Column (7) of the Sec. 172.101 Table of this subchapter except when transported domestically. (7) Each tell-tale indicator or pressure gauge located in the space between a frangible disc and a safety relief valve mounted in series must be checked after the tank is filled and prior to transportation to ensure that the frangible disc is leak free. Any leakage through the frangible disc must be corrected prior to offering the tank for transportation. (8) During filling, the temperature of the hazardous materials shall not exceed the limits of the design temperature range of the portable tank. (9) The maximum mass of liquefied compressed gas per liter (gallon) of shell capacity (kg/L or lbs./gal.) may not exceed the density of the liquefied compressed gas at 50 deg.C (122 deg.F). The portable tank must not be liquid full at 60 deg.C (140 deg.F). (g) Additional requirements for specific modal transport. In addition to other applicable requirements, the following apply: (1) A portable tank containing a hazardous material may not be loaded on to a highway or rail transport vehicle unless loaded entirely within the horizontal outline thereof, without overhang or projection of any part of the tank assembly. In addition, for unloading a portable tank, see Sec. 177.834(i)(2) of this subchapter. (2) An IM or UN portable tank used for the transportation of flammable liquids by rail may not be fitted with non-reclosing pressure relief devices except in series with reclosing pressure relief valves. (3) A portable tank or Specification 106A or 110A multi-unit tank car containing a hazardous material may not be offered for transportation aboard a passenger vessel unless: (i) The vessel is operating under a change to its character of vessel certification as defined in Sec. 171.8 of this subchapter; and (ii) The material is permitted to be transported aboard a passenger vessel in the Sec. 172.101 Table of this subchapter. (h) Additional general commodity-specific requirements. In addition to other applicable requirements, the following requirements apply: (1) Each uninsulated port#
Passage 380able tank used for the transportation of a liquefied compressed gas must have an exterior surface finish that is significantly reflective, such as a light-reflecting color if painted, or a bright reflective metal or other material if unpainted. (2) If a hazardous material is being transported in a molten state, the portable tank must be thermally insulated with suitable insulation material of sufficient thickness that the overall thermal conductance is not more than 0.080 Btu per hour per square foot per degree Fahrenheit differential. (i) Additional requirements for portable tanks other than IM specification and UN portable tanks. (1) The bursting strength of any piping and fittings must be at least four times the design pressure of the tank, and at least four times the pressure to which, in any instance, it may be subjected in service by the action of a pump or other device (not including safety relief valves) that may subject piping to pressures greater than the design pressure of the tank. (2) Pipe joints must be threaded, welded or flanged. If threaded pipe is used, the pipe and pipe fittings must not be lighter than Schedule 80 weight. Where copper tubing is permitted, joints must be brazed or be of equally strong metal union type. The melting point of brazing material may not be lower than 1,000 deg.F (537.8 deg.C). The method of joining tubing must not decrease the strength of the tubing such as by the cutting of threads. (3) Non-malleable metals may not be used in the construction of valves or fittings. (4) Suitable provision must be made in every case to allow for expansion, contraction, jarring and vibration of all pipe. Slip joints may not be used for this purpose. (5) Piping and fittings must be grouped in the smallest practicable space and must be protected from damage as required by the specification. (6) All piping, valves and fittings on every portable tank must be leakage tested with gas or air after installation and proved tight at not less than the design pressure of the portable tank on which they are used. In the event of replacement, all such piping, valves, or fittings must be tested in accordance with the requirements of this section before the portable tank is returned to transportation service. The requirements of this section apply to all hoses used on portable tanks, except that hoses may be tested either before or after installa#
Passage 381tion on the portable tank. (7) All materials used in the construction of portable tanks and their appurtenances may not be subject to#
Passage 382destructive attack by the contents of the portable tank. (8) No aluminum, copper, silver, zinc nor their alloys may be used. Brazed joints may not be used. All parts of a portable tank and its appurtenances used for anhydrous ammonia must be steel. (9) Each outlet of a portable tank used for the transportation of non-refrigerated liquefied compressed gases, except carbon dioxide, must be provided with a suitable automatic excess-flow valve (see definition in Sec. 178.337-1(g) of this subchapter). The valve must be located inside the portable tank or at a point outside the portable tank where the line enters or leaves the portable tank. The valve seat must be located inside the portable tank or may be located within a welded flange or its companion flange, or within a nozzle or within a coupling. The installation must be made in such a manner as to reasonably assure that any undue strain which causes failure requiring functioning of the valve shall cause failure in such a manner that it will not impair the operation of the valve. (i) A safety device connection or liquid level gauging device that is constructed so that the outward flow of the tank contents will not exceed that passed by an opening of 0.1397 cm (0.0550 inches) is not required to be equipped with excess-flow valves. (ii) An excess-flow valve must close automatically if the flow reaches the rated flow of gas or liquid specified by the original valve manufacturer when piping mounted directly on the valve is sheared off before the first valve, pump, or fitting downstream from the excess flow valve. (iii) An excess-flow valve may be designed with a by-pass, not to exceed a 0.1016 cm (0.040 inches) diameter opening to allow equalization of pressure. (iv) Filling and discharge lines must be provided with manually operated shut-off valves located as close to the tank as practical. Unless this valve is manually operable at the valve, the line must also have a manual shut-off valve. The use of ``Stop-Check'' valves to satisfy with one valve the requirements of this section is forbidden. For portable tanks used for refrigerated liquefied gases, a ``stop check'' valve may be used on the vapor side of the pressure buildup circuit. (10) Each portable tank used for carbon dioxide or nitrous oxide must be lagged with a suitable insulation material of such thickness that the overall thermal conductance is not m#
Passage 383ore than 0.08 Btu per square foot per degree Fahrenheit differential in temperature per hour. The conductance must be determined at 60 deg. Fahrenheit. Insulation material used on portable tanks for nitrous oxide must be noncombustible. (11) Refrigerating or heating coils must be installed in portable tanks used for carbon dioxide and nitrous oxide. Such coils must be tested externally to at least the same pressure as the test pressure of the portable tank. The coils must also be tested internally to at least twice the working pressure of the heating or refrigerating system to be used, but in no case less than the test pressure of the portable tank. Such coils must be securely anchored. In the event of leakage, the refrigerant or heating medium to be circulated through the coil or coils must have no adverse chemical reaction with the portable tank or its contents. (12) Excess flow valves are not required for portable tanks used for the transport of refrigerated liquefied gases. 34. In Sec. 173.34, in the paragraph (e)(13) table, in the second column, the following changes are made: a. In the second entry, the wording ``Butadiene, inhibited'' is revised to read ``Butadiene, stabilized'. b. In the ninth entry, the wording ``Ethyleneimine, inhibited'' is revised to read ``Ethyleneimine, stabilized'. 35. In Sec. 173.61, paragraph (e)(3) is revised and a new paragraph (e)(8) is added to read as follows: Sec. 173.61 Mixed packaging requirements. * * * * * (e) * * * (3) Explosives of compatibility group S may be packaged together with explosives of any other compatibility group except A or L, and the combined package may be treated as belonging to any of the packaged compatibility groups except S. * * * * * (8) Explosive articles of compatibility group G, except for fireworks and articles requiring special packaging, may be packaged together with explosive articles of compatibility groups C, D or E and the combined package shall be treated as belonging to compatibility group E. 36. In Sec. 173.62, in paragraph (b), in the Explosives Table, two entries are added in appropriate alphanumerical order and in paragraph (c), in the Explosives Packing Instructions Table, in the fourth column, for the packing instruction entry 144, under the Boxes entry ``plastics, expanded (4H1)'' add an entry for Drums to read as follows:#
Passage 384Sec. 173.62 Specific packaging requirements for explosives. Explosives Table ------------------------------------------------------------------------ ID# PI ------------------------------------------------------------------------ * * * * * UN0502...................................... 130 UN0504...................................... 112(c) * * * * * ------------------------------------------------------------------------ Table of Packing Methods -------------------------------------------------------------------------------------------------------------------------------------------------------- Packing instruction Inner packagings Intermediate packagings Outer packagings -------------------------------------------------------------------------------------------------------------------------------------------------------- * * * * * * * 144 * * * * * * * * * * * * Drums. Steel, removable head (1A2). Aluminum, removable head (1B2). Plastics, removable head (1H2). Plywood (1D). * * * * * * * -------------------------------------------------------------------------------------------------------------------------------------------------------- 37. In addition, in Sec. 173.62, in paragraph (c), in the Explosives Packing Instructions Table, in the fourth column, the following changes are made in appropriate packaging specification number order: a. For packing instruction entries, 112(a), 112(b), 112(c), 113, 115, 116, 130, 131, 134, 135, 136, 138, 140, 141 and 142, under the word ``Drums'', the wording ``plywood (1D)'' is added in the alpha- numeric order of the parenthetical. b. For the packing instruction entries, 112(c), 113, 115, 134, 138 and 140, under the word ``Drums'', the wording ``plastics, removable head (1H2)'' is added in the alpha-numeric order of the parenthetical. c. For the packing instruction entries, 134 and 138, under the word ``Drums'', the wording ``fiberboard (1G)'' is added in the alpha- numeric order of the parenthetical. d. For the packing instruction entries, 112(c) and 113, under the word ``Boxes'', the wording ``aluminum (4B)'' is added in the alpha- numeric order of the parenthetical. e. For the packing instruction entry, 144, under the word ``Boxes'', the wording ``plastics, solid (4H2)'' is added in the alpha- numeric order of the parenthetical. 38. In Sec. 173.150, paragraph (d)(2) is revised to read as follows:#
Passage 385Sec. 173.150 Exceptions for Class 3 (flammable) and combustible liquids. * * * * * (d) * * * (2) Is in an inner packaging of five liters (1.3 gallons) or less for transportation on passenger-carrying aircraft and conforms to Sec. 175.10(a)(17) of this subchapter as checked or carry-on baggage; or * * * * * 39. In Sec. 173.162, paragraphs (a) introductory text and (a)(1) are revised to read as follows: (a) Except when packaged in cylinders or steel flasks, gallium must be packaged in packagings which meet the requirements of part 178 of this subchapter at the Packing Group I performance level for transportation by aircraft, and at the Packing Group III performance level for transport by highway, rail or vessel, as follows: (1) In combination packagings intended to contain liquids consisting of glass, earthenware or rigid plastic inner packagings with a maximum net mass of 15 kg (33 pounds) each. The inner packagings must be packed in wood boxes (4C1, 4C2, 4D, 4F), fiberboard boxes (4G), plastic boxes (4H1, 4H2), fiber drums (1G) or removable head steel and plastic drums or jerricans (1A2, 1H2, 3A2 or 3H2) with sufficient cushioning materials to prevent breakage. Either the inner packagings or the outer packagings must have an inner liner that is leakproof or bags of strong leakproof and puncture-resistant material impervious to the contents and completely surrounding the contents to prevent it from escaping from the package, irrespective of its position. * * * * * 40. Section 173.185 is revised to read as follows: Sec. 173.185 Lithium batteries and cells.#
Passage 386(a) Except as otherwise provided in this subpart, a lithium cell or battery is authorized for transportation only if it conforms to the provisions of this section. For the purposes of this subchapter, ``lithium content'' means the mass of lithium in the anode of a lithium metal or lithium alloy cell, except in the case of a lithium ion cell or battery where the ``equivalent lithium content'' in grams is calculated to be 0.3 times the rated capacity in ampere-hours. (b) Exceptions. Cells and batteries are not subject to the requirements of this subchapter if they meet the following requirements: (1) Each cell with a liquid cathode may contain not more than 0.5 g of lithium content. Each cell with a solid cathode may contain not more than 1.0 g of lithium content. Each lithium ion cell may contain not more than 1.5 g of equivalent lithium content; (2) Each battery with a liquid cathode may contain an aggregate quantity of not more than 1.0 g of lithium content. Each battery with a solid cathode may contain an aggregate quantity of not more than 2.0 g of lithium content. Each lithium-ion battery may contain an aggregate quantity of not more than 8.0 grams of equivalent lithium content; (3) Each cell or battery containing a liquid cathode must be hermetically sealed; (4) Cells and batteries must be packed in such a way so as to prevent short circuits and must be packed in strong packagings, except when installed in equipment; and (5) If when fully charged, the aggregate lithium content of the anodes in a liquid cathode battery is more than 0.5 g, or the aggregate lithium content of the anodes in a solid cathode battery is more than 1.0 g, then the battery may not contain a liquid or gas that is a hazardous material according to this subchapter unless the liquid or gas, if free, would be completely absorbed or neutralized by other materials in the battery. (c) Additional exceptions. Cells and batteries also are not subject to this subchapter if they meet the following requirements: (1) The lithium content of the anode of each cell, when fully charged, is not more than 5 g; (2) The aggregate lithium content of the anodes of each battery, when fully charged, is not more than 25 g; (3) Each cell or battery is of the type proven to be non-dangerous by testing in accordance with tests in the UN Manual of Tests and Criteria (see Sec. 171.7 of this subchapter). Such tes#
Passage 387ting must be carried out on each type of cell or battery prior to the initial transport of that type; and (4) Cells and batteries are designed or packed in such a way as to prevent short circuits under conditions normally encountered in transportation. (d) Cells and batteries and equipment containing cells and batteries which were first transported prior to January 1, 1995, and were assigned to Class 9 on the basis of the requirements of this subchapter in effect on October 1, 1993, may continue to be transported in accordance with the applicable requirements in effect on October 1, 1993. (e) Cells and batteries may be transported as items of Class 9 if they meet the requirements in paragraphs (e)(1) through (e)(7) of this section: (1) Each cell and battery must be equipped with an effective means of preventing external short circuits. (2) Each cell and battery must incorporate a safety venting device or be designed in a manner that will preclude a violent rupture under conditions normally incidental to transportation. (3) Batteries containing cells or series of cells connected in parallel must be equipped with diodes to prevent reverse current flow. (4) Cells and batteries must be packed in inner packagings in such a manner as to effectively prevent short circuits and to prevent movement which could lead to short circuits. (5) Cells and batteries must be packaged in packagings conforming to the requirements of part 178 of this subchapter at the Packing Group II performance level: Inner packagings must be packed within metal boxes (4A or 4B), wooden boxes (4C1, 4C2, 4D or 4F), fiberboard boxes (4G), solid plastic boxes (4H2), fiber drums (1G), metal drums (1A2 or 1B2), plywood drums (1D), plastic jerricans (3H2), or metal jerricans (3A2 or 3B2).#
Passage 388(6) Each cell or battery must be of the type proven to meet the lithium battery requirements in the UN Manual of Tests and Criteria (see Sec. 171.7 of this subchapter). (7) Except as provided in paragraph (h) of this section, cells or batteries may not be offered for transportation or transported if any cell has been discharged to the extent that the open circuit voltage is less than two volts or is less than \2/3\ of the voltage of the fully charged cell, whichever is less. (f) Equipment containing or packed with cells and batteries meeting the requirements of paragraph (b) or (c) of this section is excepted from all other requirements of this subchapter. (g) Equipment containing or packed with cells and batteries may be transported as items of Class 9 if the batteries and cells meet all requirements of paragraph (e) of this section and are packaged as follows: (1) Equipment containing cells and batteries must be packed in a strong outer packaging that is waterproof or has a waterproof liner, unless the equipment is made waterproof by nature of its construction. The equipment must be secured within the outer packaging and be packed as to effectively prevent movement, short circuits, and accidental operation during transport; and (2) Cells and batteries packed with equipment must be packed in inner packagings conforming to (e)(5) of this section in such a manner as to effectively prevent movement and short circuits. (h) Cells and batteries, for disposal, may be offered for transportation or transported to a permitted storage facility and disposal site by motor vehicle when they meet the following requirements: (1) Be equipped with an effective means of preventing external short circuits; and (2) Be packed in a strong outer packaging conforming to the requirements of Secs. 173.24 and 173.24a. The packaging need not conform to performance requirements of part 178 of this subchapter. (i) Cells and batteries and equipment containing or packed with cells and batteries which do not comply with the provisions of this section may be transported only if they are approved by the Associate Administrator. (j) For testing purposes, when not contained in equipment, cells and batteries may be offered for transportation or transported by highway as items of Class 9. Packaging must conform with paragraph (e)(5) of this section.#
Passage 38941. In Sec. 173.224, paragraph (b)(4) is revised; in the table following paragraph (b)(7), the following entry is added in appropriate alphabetical order; and paragraph (d) is removed to read as follows: Sec. 173.224 Packaging and control and emergency temperatures for self-reactive materials. * * * * * (b) * * * (4) Packing method. Column 4 specifies the highest packing method which is authorized for the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in Sec. 173.225(d) defines the packing methods. Bulk packagings are authorized as specified in Sec. 173.225(d) for Type F self-reactive substances. Additional bulk packagings are authorized if approved by the Associate Administrator. * * * * * (7) * * * Self-Reactive Materials Table -------------------------------------------------------------------------------------------------------------------------------------------------------- Indentification Concentration Packing Control temperature-- (Emergency Self-reactive substance no. (%) method ( deg.C) temperature Notes -------------------------------------------------------------------------------------------------------------------------------------------------------- (1) (2) (3) (4) (5) (6) (7) -------------------------------------------------------------------------------------------------------------------------------------------------------- * * * * * * * 2,2'-Azodi(isobutyronitrile) as a water based paste.... ............... 3224 ............ 50% OP6 ............ * * * * * * * 42. In Sec. 173.225, in paragraph (b), in the Organic Peroxide Table, the following entries are removed and added in the appropriate alphabetical order; in Column (8), Notes ``7'' and ``10'' are removed each place they appear; and in the ``NOTES'' immediately following the Table, Notes ``7'' and ``10'' are removed and reserved and Note ``26'' is added in the appropriate numerical order; and paragraphs (e) introductory text, (e)(3) and (e)(5) are revised to read as follows: Sec. 173.225 Packaging requirements and other provisions for organic peroxides.#
Passage 390Organic Peroxide Table -------------------------------------------------------------------------------------------------------------------------------------------------------- Diluent (mass %) Temperature ( Concentration --------------------------- Water deg.C) Technical name ID No. (mass %) (mass Packing method -------------------- Notes A B I %) Control Emergency -------------------------------------------------------------------------------------------------------------------------------------------------------- (1) (2) (3) (4a) (4b) (4c) (5) (6)................. (7a) (7b) (8) -------------------------------------------------------------------------------------------------------------------------------------------------------- * * * * * * * [REMOVE:] tert-Amyl peroxybenzoate........... UN3105 96 32 42 OP8................. 0 +10 stable dispersion inwater].#
Passage 391* * * * * * * tert-Butyl peroxyneoheptanoate..... UN3115 77 27 77 72 90-100 OP5................. trimethylcyclohexane. 1,1-Di-(tert-butylperoxy)-3,5,5- UN3103 >57-90 57 57 32 77 OP7................. -15 -5 * * * * * * * Diisopropylperoxydicarbonate....... UN3115 52 10 OP7................. +20 +25 ethylhexanoylperoxy)hexane. 0 * * * * * * * Dimyristylperoxydicarbonate [as UN3119 42 IBC................. +15 +25 astable dispersion in water]. * * * * * * * Di-n-propylperoxydicarbonate....... UN3113 10 OP4................. -25 -15 0 * * * * * * * Di-(3,5,5- UN3119 38 32 1 -38 butylperoxydi-carbonate [and]Di- 5-18 isopropylperoxydicarbonate. +1 2-15 * * * * * * * 2,4,4-Trimethylpentyl-2- UN3115 72 52 OP8................. -5 +5 phenoxynedecanoate [asa stable dispersion inwater].. 2,4,4-Trimethylpentyl-2-peroxy UN3115 37 10 ....... ....... ....... ....... OP5................. ....... ......... ....... 0 * * * * * * * tert-Butyl peroxy-2-ethylhexanoate. UN3119 32 ....... 52 ....... ....... ....... ....... OP8................. 0 +10 ....... stable dispersion in water]. * * * * * * * tert-Butyl peroxyneodecanoate [as a UN3119 42 ....... ....... ....... ....... IBC................. -5 +5 ....... stable dispersion in water]. * * * * * * * tert-Butyl peroxyneodecanoate...... UN3119 32 77 27 ....... 52 ....... ....... ....... ....... IBC................. -15 -5 ....... stable dispersion in water]. * * * * * * * Cumyl peroxyneoheptanoate.......... UN3115 77 72 90-100 ....... ....... ....... ....... OP5................. ....... ......... ....... trimethylcyclohexane. * * * * * * * 1,1-Di-(tert-butylperoxy)-3,3,5- UN3103 >57-90 77 ....... 57 ....... ....... 57 32 22 ....... 52 ....... ....... ....... ....... IBC................. -20 -10 ....... [as a stable dispersion in water]. * * * * * * * Di-(2-ethoxyethyl) UN3115 52 ....... 77 ....... 62 ....... ....... ....... ....... OP8................. -15 -5 ....... [as a stable dispersion in water]. * * * * * * * Diisopropyl peroxydicarbonate...... UN3115 52 ....... 52 ....... 20 ....... 1 -58 +Dibenzoyl peroxide. 8 + 4 * * * * * * * 2,5 Dimethyl 2,5 di-2- UN3113 10 ....... ....... ....... ....... OP5................. +20 +25 ....... ethylhexanoylperoxy hexane. 0 * * * * * * * 2,5-Dimethyl-2,5-di-(tert- UN3108 77 ....... ....... 86-100 ....... ....... ....... ....... OP5................. ....... ......... ....... butylperoxy)hexyne#
Passage 392-3. * * * * * * * Dimyristyl peroxydicarbonate [as a UN3119 42 ....... ....... ....... ....... IBC................. +15 +20 ....... stable dispersion in water]. * * * * * * * Di-n-propyl peroxydicarbonate...... UN3113 10 ....... ....... ....... ....... OP3................. -25 -15 ....... 0 * * * * * * * Di-n-propyl peroxydicarbonate...... UN3113 77 ....... 71 72 ....... 37 72 ....... 52 ....... ....... ....... ....... IBC................. -5 +5 ....... peroxyneodecanoate [as a stable dispersion in water].. 1,1,3,3-Tetramethylbutyl peroxy UN3115 37 ....... 42 7.6%. * * * * *#
Passage 393(e) Bulk packagings for organic peroxides. The following bulk packagings are authorized: * * * * * (3) Portable tanks. The following requirements apply to portable tanks intended for the transport of Type F organic peroxides or Type F self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of T23 (see Sec. 172.102(c)(7) of this subchapter), when T23 is specified in Column (7) of the Sec. 171.101 Table of this subchapter for the Type F organic peroxide or Type F self-reactive substance. Type F organic peroxide or self-reactive substance formulations other than those indicated in T23 may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply: (i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4 bar). (ii) Portable tanks must be fitted with temperature-sensing devices. (iii) Portable tanks must be fitted with pressure relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell. (iv) The pressure relief devices must consist of reclosing devices fitted to prevent significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 deg.C (122 deg.F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The start-to- discharge pressure must in no case be such that liquid would escape from the pressure relief devices if the portable tank were overturned. (v)(A) The emergency-relief devices may be of the reclosing or frangible types, or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula: [GRAPHIC] [TIFF OMITTED] TN21JN01.003 Where: q = heat absorption (W) A = wetted area (m\2\) F = insulation factor (-)#
Passage 394(B) Insulation factor (F) in the formula in paragraph (e)(3)(v)(A) of this section equals 1 for non-insulated vessels and for insulated vessels F is calculated using the following formula: [GRAPHIC] [TIFF OMITTED] TN21JN01.004 Where: U = K/L = heat transfer coefficient of the insulation (Wm-\2\K-\1\); where K = heat conductivity of insulation layer (Wm-\1\K-\1\), and L = thickness of insulation layer (m). TPO = temperature of material at relieving conditions (K). (vi) The start-to-discharge pressure of emergency-relief devices must be higher than that specified for the pressure relief devices in paragraph (e)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank. Note to Paragraph (e)(3)(vi): An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (incorporated by reference, see Sec. 171.7 of this subchapter). (vii) For insulated portable tanks, the capacity and setting of emergency-relief devices must be determined assuming a loss of insulation from 1 percent of the surface area. (viii) Vacuum-relief devices and reclosing devices on portable tanks used for flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided. (ix) Service equipment such as devices and external piping must be designed and constructed so that no hazardous material remains in them after filling the portable tank. (x) Portable tanks may be either insulated or protected by a sun- shield. If the SADT of the hazardous material in the portable tank is 55 deg.C (131 deg.F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal. (xi) The degree of filling must not exceed 90% at 15 deg.C (59 deg.F). (xii) DOT 57 metal portable tanks are authorized only for tert- butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s), dicumyl peroxide and mixtures of two or more of these peroxides. DOT 57 portable tanks must conform to the venting requirements of paragraph (e)(5) of this section. These portable tanks are not subject to the requirements of#
Passage 395paragraphs (e)(3)(ii) and (e)(3)(iv) of this section. * * * * * (5) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to IB52 (see Sec. 172.102(c)(4) of this subchapter), as applicable, and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group II performance level. The following additional requirements also apply: (i) IBCs shall be provided with a device to allow venting during transportation. The inlet to the pressure relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation. (ii) To prevent explosive rupture of metal IBCs or composite IBCs with complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (e)(3)(v) of this section. The control and emergency temperatures specified in IB52 are based on a non-insulated IBC. 43. In Sec. 173.240, paragraphs (c) and (d) are revised to read as follows: Sec. 173.240 Bulk packaging for certain low hazard solid materials.#
Passage 396* * * * * (c) Portable tanks and closed bulk bins. DOT 51, 56, 57 and 60 portable tanks; IMO type 1, 2 and 5, and IM 101 and IM 102 portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and sift-proof non-DOT Specification portable tanks and closed bulk bins are authorized. (d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the Sec. 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the Sec. 172.101 Table of this subchapter for the material being transported. (1) IBCs may not be used for the following hazardous materials: (i) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation. (2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (i) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and (iv) Composite: 11HZ2 and 21HZ2. 44. In Sec. 173.241, paragraphs (c) and (d) are revised to read as follows: Sec. 173.241 Bulk packagings for certain low hazard liquid and solid materials.#
Passage 397* * * * * (c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; IMO type 1, 2 and 5, and IM 101 and IM 102 portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and non-DOT Specification portable tanks suitable for transport of liquids are authorized. (d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the Sec. 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the Sec. 172.101 Table for the material being transported. (1) IBCs may not be used for the following hazardous materials: (i) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation. (2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (i) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and (iv) Composite: 11HZ2 and 21HZ2. 45. In Sec. 173.242, paragraphs (c) introductory text and (d) are revised to read as follows: Sec. 173.242 Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.#
Passage 398* * * * * (c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; Specification IM and UN portable tanks when a T Code is specified in Column (7) of the Sec. 172.101 Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR part 64 are authorized. DOT Specification 57 portable tanks used for the transport by vessel of Class 3, Packaging Group II materials must conform to the following: * * * * * (d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the Sec. 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the Sec. 172.101 Table of this subchapter for the material being transported. (1) IBCs may not be used for the following hazardous materials: (i) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation. (2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (i) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and (iv) Composite: 11HZ2 and 21HZ2. 46. In Sec. 173.243, paragraphs (c) and (d) are revised to read as follows: Sec. 173.243 Bulk packaging for certain high hazard liquids and dual hazard materials which pose a moderate hazard.#
Passage 399* * * * * (c) Portable tanks. DOT Specification 51 and 60 portable tanks; UN portable tanks when a T code is specified in Column (7) of the Sec. 172.101 Table of this subchapter for a specific hazardous material; and marine portable tanks conforming to 46 CFR part 64 with design pressure of at least 172.4 kPa (25 psig) are authorized. (d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the Sec. 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the Sec. 172.101 Table of this subchapter for the material being transported. (1) IBCs may not be used for the following hazardous materials: (i) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation. (2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (i) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and (iv) Composite: 11HZ2 and 21HZ2. * * * * * 47. In Sec. 173.247, paragraph (c) is revised to read as follows: Sec. 173.247 Bulk packaging for certain elevated temperature materials (Class 9) and certain flammable elevated temperature materials (Class 3). * * * * * (c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; IM 101 and IM 102 portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; metal IBCs and non- specification portable tanks equivalent in structural design and accident damage resistance to specification packagings are authorized. * * * * * 48. In Sec. 173.301, in paragraph (d)(2), in the first sentence, the wording ``tetrafluoroethylene, inhibited'' is revised to read ``tetrafluoroethylene, stabilized''.#
Passage 40049. In Sec. 173.304, the following changes are made: a. In the paragraph (a)(2) table, in the first column, in the second to the last entry, the wording ``Vinyl fluoride, inhibited'' is revised to read ``Vinyl fluoride, stabilized''. b. In paragraph (b), in the first sentence, the wording ``vinyl fluoride, inhibited'' is revised to read ``vinyl fluoride, stabilized''. 50. In Sec. 173.306, paragraph (a)(4)(iii) is revised to read as follows: Sec. 173.306 Limited quantities of compressed gases. * * * * * (4) ** * (iii) Non-pressurized gases, flammable must be packed in hermetically-sealed glass or metal inner packagings of not more than 5 L (1.3 gallons) and overpacked in a strong outer packaging. * * * * * 51. In Sec. 173.314, the following changes are made: a. In the paragraph (c) table, in the first column, the last entry, ``Vinyl fluoride, inhibited'' is revised to read ``Vinyl fluoride, stabilized''. b. In paragraph (g) introductory text, the wording ``vinyl fluoride, inhibited'' is revised to read ``vinyl fluoride, stabilized''. 52. In Sec. 173.315: a. The text of paragraph (a) preceding the table is revised; b. In the paragraph (a) table, in the first column, the entry ``Butadiene, inhibited'' is revised to read ``'Butadiene, stabilized'' and the second to the last entry ``Vinyl fluoride, inhibited'' is revised to read ``Vinyl fluoride, stabilized''; c. In paragraph (b) introductory text, the wording ``butadiene, inhibited'' is revised to read ``butadiene, stabilized''; d. In the paragraph (h) table, in the first column, the sixth entry, ``Butadiene, inhibited'' is revised to read ``Butadiene, stabilized''; e. Paragraphs (i)(1)(iii), (i)(3), (i)(4) and (i)(8) are revised; and f. Paragraph (i)(7) is removed and reserved. The revisions read as follows: Sec. 173.315 Compressed gases in cargo tanks and portable tanks.#
Passage 401(a) Liquefied compressed gases that are transported in UN portable tanks must be loaded and offered for transportation in accordance with portable tank provision T50 in Sec. 172.102 of this subchapter. A liquefied compressed gas offered for transportation in a cargo tank motor vehicle or a portable tank must be prepared in accordance with this section, Sec. 173.32, Sec. 173.33 and subpart E or subpart G of part 180 of this subchapter, as applicable. For cryogenic liquids, see Sec. 173.318. For marking requirements, see Secs. 172.326 and 172.328 of this subchapter. Except for UN portable tanks, a liquefied compressed gas must be loaded and offered for transportation in accordance with the following table: * * * * * (i) * * * (1) * * * (iii) For an insulated tank, the required relieving capacity of the relief devices must be the same as for an uninsulated tank, unless the insulation will remain in place and will be effective under fire conditions. In this case, except for UN portable tanks, each insulated tank must be covered by a sheet metal jacket of not less than 16 gauge thickness. For UN portable tanks where the relieving capacity of the valves has been reduced on the basis of the insulation system, the insulation system must remain effective at all temperatures less than 649 deg.C (1200.2 deg.F) and be jacketed with a material having a melting point of 700 deg.C (1292.0 deg.F) or greater. * * * * * (3) Each safety relief valve on a portable tank, other than a UN portable tank, must be set to start-to-discharge at pressure no higher than 110% of the tank design pressure and no lower than the design pressure specified in paragraph (a) of this section for the gas transported. For UN portable tanks used for liquefied compressed gases and constructed in accordance with the requirements of Sec. 178.276 of this subchapter, the pressure relief device(s) must conform to Sec. 178.276(e) of this subchapter. (4) Except for UN portable tanks, each safety relief valve must be plainly and permanently marked with the pressure in p.s.i.g. at which it is set to discharge, with the actual rate of discharge of the device in cubic feet per minute of the gas or of air at 60 deg.F (15.6 deg.C) and 14.7 p.s.i.a., and with the manufacturer's name or trade name and catalog number. The start-to-discharge valve marking must be visible after the valve is installed. The rated dischar#
Passage 402ge capacity of the device must be determined at a pressure of 120% of the design pressure of the tank. For UN portable tanks, each pressure relief device must be clearly and permanently marked as specified in Sec. 178.274(f)(1) of this subchapter. * * * * * (8) Each safety relief valve outlet must be provided with a protective device to prevent the entrance and accumulation of dirt and water. This device must not impede flow through the valve. Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. * * * * * 53. In Sec. 173.320, paragraph (c) is revised to read as follows: Sec. 173.320 Cryogenic liquids; exceptions. * * * * * (c) For transportation aboard aircraft, see the ICAO Technical Instructions, Packing Instruction P202 and the packaging specifications in part 6, Chapter 5. (See Sec. 171.7 of this subchapter for ICAO Technical Instructions.) 54. The authority citation for part 175 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 55. In Sec. 175.10, paragraphs (a)(10) and (a)(16) are revised, and paragraph (a)(17) is added to read as follows: (a) * * * (10) Safety matches or a lighter intended for use by an individual when carried on one's person. However, lighters containing unabsorbed liquid fuel (other than liquefied gas), lighter fuel, and lighter refills are not permitted on one's person or in checked or carry-on baggage. * * * * * (16) Perfumes and colognes, purchased through duty-free sales, carried by passengers or crew in carry-on baggage. (17) Alcoholic beverages containing: (i) Not more than 24% alcohol by volume; or (ii) More than 24% and not more than 70% alcohol by volume when in retail packagings not exceeding 5 liters (1.3 gallons) carried by a crew member or passenger in checked or carry-on baggage, with a total net quantity per person of 5 liters (1.3 gallons) for such beverages. * * * * * 56. In Sec. 175.33, paragraph (a) introductory text is revised to read as follows: Sec. 175.33 Notification of pilot-in-command.#
Passage 403(a) Except as provided in Sec. 175.10, when a hazardous material subject to the provisions of this subchapter is carried in an aircraft, the operator of the aircraft must provide the pilot-in-command with accurate and legible written information as early as practicable before departure of the aircraft, which specifies at least the following: * * * * * 57. Sec. 175.78 is revised to read as follows: Sec. 175.78 Stowage compatibility of cargo. (a) For stowage on an aircraft, in a cargo facility, or in any other area at an airport designated for the stowage of hazardous materials, packages containing hazardous materials which might react dangerously with one another may not be placed next to each other or in a position that would allow a dangerous interaction in the event of leakage. (b) As a minimum, the segregation instructions prescribed in the following Segregation Table must be followed to maintain acceptable segregation between packages containing hazardous materials with different hazards. The Segregation Table instructions apply whether or not the class or division is the primary or subsidiary risk. The Segregation Table follows:#
Passage 404Segregation Table -------------------------------------------------------------------------------------------------------------------------------------------------------- Class or division Hazard label -------------------------------------------------------------------------------------------------------------- 1 2 3 4.2 4.3 5.1 5.2 8 -------------------------------------------------------------------------------------------------------------------------------------------------------- 1........................................ Note 1 Note 2 Note 2 Note 2 Note 2 Note 2 Note 2 Note 2 -------------------------------------------------------------------------------------------------------------------------------------------------------- 2........................................ Note 2 ............ ............ ............ ............ ............ ............ ........... -------------------------------------------------------------------------------------------------------------------------------------------------------- 3........................................ Note 2 ............ ............ ............ ............ X ............ ........... -------------------------------------------------------------------------------------------------------------------------------------------------------- 4.2...................................... Note 2 ............ ............ ............ ............ X ............ ........... -------------------------------------------------------------------------------------------------------------------------------------------------------- 4.3...................................... Note 2 ............ ............ ............ ............ ............ ............ X -------------------------------------------------------------------------------------------------------------------------------------------------------- 51....................................... Note 2 ............ X X ............ ............ ............ ........... -------------------------------------------------------------------------------------------------------------------------------------------------------- 5.2...................................... Note 2 ............ ............ ............ ............ ............ ............ ........... ------------------------------------------------------------------------------------------------------------------#
Passage 405-------------------------------------- 8........................................ Note 2 ............ ............ ............ X ............ ............ ........... -------------------------------------------------------------------------------------------------------------------------------------------------------- --------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 406(c) Instructions for using the Segregation Table are as follows:(1) The dots at the intersection of a row and column indicate that no restrictions apply. (2) The letter ``X'' at the intersection of a row and column indicates that packages containing these classes of hazardous materials may not be stowed next to or in contact with each other, or in a position which would allow interaction in the event of leakage of the contents. (3) Note 1. ``Note 1'' at the intersection of a row and column means the following: (i) For explosives in compatibility groups A through K and N -- (A) Packages bearing the same compatibility group letter and the same division number may be stowed together. (B) Explosives of the same compatibility group, but different divisions may be stowed together provided the whole shipment is treated as belonging to the division having the smaller number. However, when explosives of Division 1.5 Compatibility Group D are stowed together with explosives of Division 1.2 Compatibility Group D, the whole shipment must be treated as Division 1.1, Compatibility Group D. (C) Packages bearing different compatibility group letters may not be stowed together whether or not they belong to the same division, except as provided in paragraphs (c)(3)(ii) and (iii) of this section. (ii) Explosives in Compatibility Group L may not be stowed with explosives in other compatibility groups. They may only be stowed with the same type of explosives in Compatibility Group L. (iii) Explosives of Division 1.4, Compatibility Group S, may be stowed with explosives of all compatibility groups except for Compatibility Groups A and L. (iv) Other than explosives of Division 1.4, Compatibility Group S (see paragraph (c)(3)(iii) of this section), and Compatibility Groups C, D and E that may be stowed together, explosives that do not belong in the same compatibility group may not be stowed together. (A) Any combination of substances in Compatibility Groups C and D must be assigned to the most appropriate compatibility group shown in the Sec. 172.101 Table of this subchapter. (B) Explosives in Compatibility Group N may be stowed together with explosives in Compatibility Groups C, D or E when the combination is assigned Compatibility Group D. (4) Note 2. ``Note 2'' at the intersection of a row and column means that other than explosives of Division 1.4, Compatibility Group S, explos#
Passage 407ives may not be stowed together with that class. (5) Packages containing hazardous materials with multiple hazards in the class or divisions, which require segregation in accordance with the Segregation Table need not be segregated from other packages bearing the same UN number. (6) A package labeled ``BLASTING AGENT'' may not be stowed next to or in a position that will allow contact with a package of special fireworks or railway torpedoes. 58. In Sec. 175.85, paragraph (a) is revised to read as follows: (a) Except as provided in Sec. 175.10, no person may carry a hazardous material subject to the requirements of this subchapter in the cabin of a passenger-carrying aircraft or on the flight deck of any aircraft. Hazardous materials may be carried in a main deck cargo compartment of a passenger aircraft provided that the compartment is inaccessible to passengers and that it meets all certification requirements for a Class B aircraft cargo compartment in 14 CFR 25.857(b) or for a Class C aircraft cargo compartment in 14 CFR 25.857(c). * * * * * 59. The authority citation for part 176 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 60. In Sec. 176.2, the following definition is added in appropriate alphabetical order to read as follows: * * * * * INF cargo means packaged irradiated nuclear fuel, plutonium or high-level radioactive wastes as those terms are defined in the ``International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships' (INF Code) (contained in IMDG Code, 2000 edition, see Sec. 171.7 of this subchapter). * * * * * 61. In Sec. 176.63, a new paragraph (e) is added to read as follows:#
Passage 408* * * * * (e) Closed cargo transport unit, for the purpose of stowage of Class 1 (explosive) materials on board a vessel, means a clean, substantial, weatherproof box structure which can be secured to the ship's structure and includes a closed freight container, a closed vehicle, a closed rail wagon or a portable magazine. When this stowage is specified, stowage in small compartments such as deckhouses and mast lockers or oversized weatherproof packages (overpacks) are acceptable alternatives. The floor of any closed cargo transport unit or compartment shall be constructed of wood, close boarded or arranged so that goods are stowed on sparred gratings, wooden pallets or dunnage. Provided that the necessary additional specifications are met, a closed cargo transport unit may be used for Class 1 (explosive) magazine stowage type ``A,'' ``B'' or ``C,'' but not as a portable magazine. 62. In Sec. 176.84, in paragraph (b) Table of provisions, the entries ``4'' and ``5'' are revised; paragraph (c)(1) is revised; paragraph (c)(2), the List of Notes is revised; and paragraph (c)(3) is removed to read as follows: Sec. 176.84 Other requirements for stowage and segregation for cargo vessels and passenger vessels. ------------------------------------------------------------------------ Code Provisions ------------------------------------------------------------------------ * * * * * 4............................... Stow ``Separated from'' liquid organic materials. 5............................... Stow ``Separated from'' powdered metals and their compounds. * * * * * ------------------------------------------------------------------------ (c) * * * (1) Explosive substances and explosive articles must be stowed in accordance with Column (10A) and Column (10B) of the 172.101 Table of this subchapter. (2) * * *#
Passage 409------------------------------------------------------------------------ Notes Provisions ------------------------------------------------------------------------ 5E.............................. Stow ``away from'' lead and its compounds. 7E.............................. Stowage category ``04'' for projectiles or cartridges for guns, cannons or mortars; Stowage category ``08'' for other types. 8E.............................. When under deck, special stowage is required. 14E............................. On deck, cargo transport unit must be steel. 15E............................. On deck, cargo transport unit must be leakproof. 17E............................. On deck stowage is recommended. 19E............................. Stow ``away from'' Explosive, blasting, type C, UN0083 which contain chlorates or perchlorates. 20E............................. Stowage category ``03'' for projectiles or cartridges for guns, cannons or mortars; Stowage category ``07'' for other types; magazines must be of steel construction that prevents leakage. 21E............................. Cargo space ventilation must be carefully controlled to avoid excessive condensation. 22E............................. When containing chlorates or perchlorates, stow ``away from'' explosives containing ammonium nitrate or other ammonium salts. 23E............................. Segregate from other Class 1 (explosive) materials in the same manner as is required for flammable liquids. 26E............................. Stowage category ``13'' and, for on deck stowage, non-metallic lining of closed cargo transport unit is required when not in effectively sealed, sift-proof packages; Stowage category ``10'' permitted when in effectively sealed, sift-proof packages. 0127E........................... For closed cargo transport unit, a non- metallic lining is required. ------------------------------------------------------------------------ 63. In Sec. 176.128, in paragraph (c), the word ``UN 0600'' is revised to read ``UN 0060''. 64. In Sec. 176.136, in paragraph (e), the word ``portable'' is removed. 65. In Sec. 176.142, paragraph (a) is revised to read as follows: Sec. 176.142 Hazardous materials of extreme flammability.#
Passage 410(a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials: ---------------------------------------------------------------------------------------------------------------- ---------------------------------------------------------------------------------------------------------------- Carbon disulfide........................................... UN1131 Class 3 Diethylzinc................................................ UN1366 Division 4.2 Dimethylzinc............................................... UN1370 Division 4.2 Magnesium alkyls........................................... UN3053 Division 4.2 Methyl phosphonous dichloride, pyrophoric liquid........... NA2845 Division 6.1 Nickel carbonyl............................................ UN1259 Division 6.1 Pyrophoric liquid, inorganic, n.o.s........................ UN3194 Division 4.2 Pyrophoric liquids, organic, n.o.s......................... UN2845 Division 4.2 Pyrophoric organometallic compound, water-reactive, n.o.s.. UN3203 Division 4.2 ---------------------------------------------------------------------------------------------------------------- 66. A new section Sec. 176.720 is added to subpart M to read as follows: Sec. 176.720 Requirements for carriage of INF cargo in international transportation. A vessel carrying INF cargo (see Sec. 176.2, under INF cargo definition) in international transportation must meet the requirements of the INF Code (contained in IMDG Code, 2000 edition, see Sec. 171.7 of this subchapter) in addition to all other applicable requirements of this subchapter. 67. The authority citation for part 177 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 68. In Sec. 177.848, paragraph (g)(3)(vi) is revised to read as follows: Sec. 177.848 Segregation of hazardous materials. * * * * * (g) * * * (3) * * * (vi) ``6'' means explosive articles in compatibility group G, other than fireworks and those requiring special handling, may be loaded, transported and stored with other explosive articles of compatibility groups C, D and E, provided that explosive substances (such as those not contained in articles) are not carried in the same vehicle. * * * * *#
Passage 41169. The authority citation for part 178 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 70. A new section Sec. 178.273 is added to subpart H to read as follows: Sec. 178.273 Approval of Specification IM portable tanks and UN portable tanks.#
Passage 412(a) Application for approval. (1) An owner or manufacturer of a portable tank shall apply for approval to a designated approval agency authorized to approve the portable tank in accordance with the procedures in subpart E, part 107 of this subchapter. (2) Each application for approval must contain the following information: (i) Two complete copies of all engineering drawings, calculations, and test data necessary to ensure that the design meets the relevant specification. (ii) The manufacturer's serial number that will be assigned to each portable tank. (iii) A statement as to whether the design type has been examined by any approval agency previously and judged unacceptable. Affirmative statements must be documented with the name of the approval agency, reason for nonacceptance, and the nature of modifications made to the design type. (b) Action by approval agency. The approval agency must perform the following activities: (1) Review the application for approval to determine whether it is complete and conforms with the requirements of paragraph (a) of this section. If an application is incomplete, it will be returned to the applicant with an explanation as to why the application is incomplete. (2) Review all drawings and calculations to ensure that the design is in compliance with all requirements of the relevant specification. If the application is approved, one set of the approved drawings, calculations, and test data shall be returned to the applicant. The second (inspector's copy) set of approved drawings, calculations, and test data shall be retained by the approval agency. Maintain drawings and approval records for as long as the portable tank remains in service. The drawings and records must be provided to the Department of Transportation (DOT) upon request. (3) Witness all tests required for the approval of the portable tank specified in this section and part 180, subpart G of this subchapter. (4) Ensure, through appropriate inspection that each portable tank is fabricated in all respects in conformance with the approved drawings, calculations, and test data. (5) Determine and ensure that the portable tank is suitable for its intended use and that it conforms to the requirements of this subchapter. (6) For UN portable tanks intended for non-refrigerated and refrigerated liquefied gases and Division 6.1 liquids which meet the inhalation toxicity crit#
Passage 413eria (Zone A or B) as defined in Sec. 173.132 of this subchapter, or that are designated as toxic by inhalation materials in the Sec. 172.101 Table of this subchapter, the approval agency must ensure that: (i) The portable tank has been constructed in accordance with the ASME Code, Section VIII, Division 1 (see Sec. 171.7 of this subchapter). ASME Code, Section VIII, Division 2 (see Sec. 171.7 of this subchapter) or other design codes may be used if approved by the Associate Administrator (see Sec. 178.274(b)(1)); (ii) All applicable provisions of the design and construction have been met to the satisfaction of the designated approval agency in accordance with the rules established in the ASME Code and that the portable tank meets the requirements of the ASME Code and all the applicable requirements specified in this subchapter; (iii) The inspector has carried out all the inspections specified by the rules established in the ASME Code; and (iv) The portable tank is marked with a U stamp code symbol under the authority of the authorized independent inspector. (7) Upon successful completion of all requirements of this subpart, the approval agency must: (i) Apply its name, identifying mark or identifying number, and the date upon which the approval was issued, to the metal identification marking plate attached to the portable tank. Any approvals for UN portable tanks authorizing design or construction alternatives (Alternate Arrangements) approved by the Associate Administrator (see Sec. 178.274(a)(2)) must be indicated on the plate as specified in Sec. 178.274(i). (ii) Issue an approval certificate for each portable tank or, in the case of a series of identical portable tanks manufactured to a single design type, for each series of portable tanks. The approval certificate must include all the information required to be displayed on the required metal identification plate required by Sec. 178.270-14 of this subchapter for IM portable tanks, Sec. 178.245-6 for Specification 51 steel portable tanks, or Sec. 178.274(i) for UN portable tanks. The approval certificate must certify that the approval agency designated to approve the portable tank has approved the portable tank in accordance with the procedures in subpart E of part 107 of this subchapter and that the portable tank is suitable for its intended purpose and meets the requirements of this subchapter. When#
Passage 414a series of portable tanks is manufactured without change in the design type, the certificate may be valid for the entire series of portable tanks representing a single design type. For UN portable tanks, the certificate must refer to the prototype test report, the hazardous material or group of hazardous materials allowed to be transported, the materials of construction of the shell and lining (when applicable) and an approval number. The approval number must consist of the distinguishing sign or mark of the country (``USA'' for the United States of America) where the approval was granted and a registration number.#
Passage 415(iii) Retain a copy of each approval certificate. (8) For UN portable tanks, the approval certificate must also include the following: (i) The results of the applicable framework and rail impact test specified in part 180, subpart G, of this subchapter; and (ii) The results of the initial inspection and test in Sec. 180.605 of this subchapter. (9) The approval agency shall be independent from the manufacturer. The approval agency and the authorized inspector may be the same entity. (c) Manufacturers' responsibilities. The manufacturer is responsible for compliance with the applicable specifications for the design and construction of portable tanks. In addition to responsibility for compliance, manufacturers are responsible for ensuring that the contracted approval agency and authorized inspector, if applicable, are qualified, reputable and competent. The manufacturer of a portable tank shall-- (1) Comply with all the applicable requirements of the ASME Code (see Sec. 171.7 of this subchapter) and of this subpart including, but not limited to, ensuring that the quality control, design calculations and required tests are performed and that all aspects of the portable tank meet the applicable requirements. (2) Obtain and use a designated approval agency, if applicable, and obtain and use a DOT-designated approval agency to approve the design, construction and certification of the portable tank. (3) Provide a statement in the manufacturers' data report certifying that each portable tank that is manufactured complies with the relevant specification and all the applicable requirements of this subchapter. (4) Maintain records of the qualification of portable tanks for at least 5 years and provide copies to the approval agency, the owner or lessee of the tank. Upon request, provide these records to a representative of DOT. (d) Denial of application for approval. If an approval agency finds that a portable tank cannot be approved for any reason, it shall notify the applicant in writing and shall provide the applicant with the reasons for which the approval is denied. A copy of the notification letter shall be provided to the Associate Administrator. An applicant aggrieved by a decision of an approval agency may appeal the decision in writing, within 90 days of receipt, to the Associate Administrator. (e) Modifications to approved portable tanks. (1) Prior to modifica#
Passage 416tion of any approved portable tank which may affect conformance and the safe use of an IM or UN portable tank, which may involve a change to the design type or which may affect its ability to retain the hazardous material in transportation, the person desiring to make such modification shall inform the approval agency that issued the initial approval of the portable tank (or if unavailable another approval agency) of the nature of the modification and request approval of the modification. The person desiring to modify the tank must supply the approval agency with three sets of all revised drawings, calculations, and test data relative to the intended modification. (2) A statement as to whether the intended modification has been examined and determined to be unacceptable by any approval agency. The written statement must include the name of the approving agency, the reason for nonacceptance, and the nature of changes made to the modification since its original rejection. (3) The approval agency shall review the request for modification, and if it is determined that the proposed modification is in full compliance with the relevant DOT specification, including a UN portable tank, the request shall be approved and the approval agency shall perform the following activities: (i) Return one set of the approved revised drawings, calculations, and test data to the applicant. The second and third sets of the approved revised drawings, calculations, and data shall be retained by the approval agency as required in Sec. 107.404(a)(3) of this subchapter. (ii) Ensure through appropriate inspection that all modifications conform to the revised drawings, calculations, and test data. (iii) Determine the extent to which retesting of the modified tank is necessary based on the nature of the proposed modification, and ensure that all required retests are satisfactorily performed. (iv) If modification to an approved tank alters any information on the approval certificate, issue a new approval certificate for the modified tank and ensure that any necessary changes are made to the metal identification plate. A copy of each newly issued approval certificate shall be retained by the approval agency and by the owner of each portable tank. (4) If the approval agency determines that the proposed modification is not in compliance with the relevant DOT specification, the approval agency s#
Passage 417hall deny the request in accordance with paragraph (d) of this section. (f) Termination of Approval Certificate. (1) The Associate Administrator may terminate an approval issued under this section if he determines that-- (i) Information upon which the approval was based is fraudulent or substantially erroneous; or (ii) Termination of the approval is necessary to adequately protect against risks to life and property; or (iii) The approval was not issued by the approval agency in good faith; or (iv) The portable tank does not meet the specification. (2) Before an approval is terminated, the Associate Administrator gives the interested party(ies): (i) Written notice of the facts or conduct believed to warrant the termination; (ii) Opportunity to submit oral and written evidence; and (iii) Opportunity to demonstrate or achieve compliance with the applicable requirements. (3) If the Associate Administrator determines that a certificate of approval must be terminated to preclude a significant and imminent adverse affect on public safety, he may terminate the certificate immediately. In such circumstances, the opportunities of paragraphs (f)(2) (ii) and (iii) of this section need not be provided prior to termination of the approval, but shall be provided as soon as practicable thereafter. 71. Section 178.274 is added to subpart H to read as follows: Sec. 178.274 Specifications for UN portable tanks. (a) General. (1) Each UN portable tank must meet the requirements of this section. In addition to the requirements of this section, requirements specific to UN portable tanks used for liquid and solid hazardous materials, non-refrigerated liquefied gases and refrigerated liquefied gases are provided in Secs. 178.275, 178.276 and 178.277, respectively. Requirements for approval, maintenance, inspection, testing and use are provided in Sec. 178.273 and part 180, subpart G, of this subchapter. Any portable tank which meets the definition of a ``container'' within the terms of the International Convention for Safe Containers (CSC) must meet the requirements of the CSC as amended and 49 CFR parts 450 through 453 and must have a CSC safety approval plate. (2) In recognition of scientific and technological advances, the technical requirements applicable to UN portable#
Passage 418tanks may be varied if approved by the Associate Administrator and the portable tank is shown to provide a level of safety equal to or exceeding the requirements of this subchapter. Portable tanks approved to alternative technical requirements must be marked ``Alternative Arrangement'' as specified in paragraph (i) of this section. (3) Definitions. The following definitions apply for the purposes of design and construction of UN portable tanks under this subpart: Alternate Arrangement portable tank means a UN portable tank that has been approved to alternative technical requirements or testing methods other than those specified for UN portable tanks in part 178 or part 180 of this subchapter. Approval agency means the designated approval agency authorized to approve the portable tank in accordance with the procedures in subpart E of part 107 of this subchapter. Design pressure is defined according to the hazardous materials intended to be transported in the portable tank. See Secs. 178.275, 178.276 and 178.277, as applicable. Design type means a portable tank or series of portable tanks made of materials of the same material specifications and thicknesses, manufactured by a single manufacturer, using the same fabrication techniques (for example, welding procedures) and made with equivalent structural equipment, closures, and service equipment. Fine grain steel means steel which has a ferritic grain size of 6 or finer when determined in accordance with ASTM E 112-96 (see Sec. 171.7 of this subchapter). Fusible element means a non-reclosing pressure relief device that is thermally activated and that provides protection against excessive pressure buildup in the portable tank developed by exposure to heat, such as from a fire (see Sec. 178.275(g)). Jacket means the outer insulation cover or cladding which may be part of the insulation system. Leakage test means a test using gas to subject the shell and its service equipment to an internal pressure. Maximum allowable working pressure (MAWP) is defined according to the hazardous materials intended to be transported in the portable tank. See Secs. 178.275, 178.276 and 178.277, as applicable. Maximum permissible gross mass (MPGM) means the sum of the tare mass of the portable tank and the heaviest hazardous material authorized for transportation. Mild steel means a steel with a guaranteed minimum tensile strength of#
Passage 419360 N/mm\2\ to 440 N/mm\2\ and a guaranteed minimum elongation at fracture as specified in paragraph (c)(10) of this section. Offshore portable tank means a portable tank specially designed for repeated use in the transportation of hazardous materials to, from and between offshore facilities. An offshore portable tank is designed and constructed in accordance with the Guidelines for the Approval of Containers Handled in Open Seas specified in the IMDG Code (see Sec. 171.7 of this subchapter). Reference steel means a steel with a tensile strength of 370 N/ mm\2\ and an elongation at fracture of 27%. Service equipment means measuring instruments and filling, discharge, venting, safety, heating, cooling and insulating devices. Shell means the part of the portable tank which retains the hazardous materials intended for transportation, including openings and closures, but does not include service equipment or external structural equipment. Structural equipment means the reinforcing, fastening, protective and stabilizing members external to the shell. Test pressure means the maximum gauge pressure at the top of the shell during the hydraulic pressure test equal to not less than 1.5 times the design pressure for liquids and 1.3 for liquefied compressed gases. In some instances a pneumatic test is authorized as an alternative to the hydraulic test. The minimum test pressures for portable tanks intended for specific liquid and solid hazardous materials are specified in the applicable portable tank T codes (such as T1-T23) assigned to these hazardous materials in the Sec. 172.101 Table of this subchapter. (b) General design and construction requirements. (1) The design temperature range for the shell must be -40 deg.C to 50 deg.C (-40 deg.F to 122 deg.F) for hazardous materials transported under normal conditions of transportation, except for portable tanks used for refrigerated liquefied gases where the minimum design temperature must not be higher than the lowest (coldest) temperature (for example, service temperature) of the contents during filling, discharge or transportation. For hazardous materials handled under elevated temperature conditions, the design temperature must not be less than the maximum temperature of the hazardous material during filling, discharge or transportation. More severe design temperatures must be considered for portable tanks subjected#
Passage 420to severe climatic conditions (for example, portable tanks transported in arctic regions). Shells must be designed and constructed in accordance with the requirements of the ASME Code, Section VIII, Division 1 (see Sec. 171.7 of this subchapter), except as limited or modified in this subchapter. For portable tanks used for liquid or solid hazardous materials, a design code other than the ASME Code may be used if approved by the Associate Administrator. Portable tanks used for non-refrigerated and refrigerated liquified compressed gases require an ASME certification and U stamp. Shells must be made of metallic materials suitable for forming. Non-metallic materials may be used for the attachments and supports between the shell and jacket, provided their material properties at the minimum and maximum design temperatures are proven to be sufficient. For welded shells, only a material whose weldability has been fully demonstrated may be used. Welds must be of high quality and conform to a level of integrity at least equivalent to the welding requirements specified in Section VIII of the ASME Code for the welding of pressure vessels. When the manufacturing process or the materials make it necessary, the shells must be suitably heat-treated to guarantee adequate toughness in the weld and in the heat-affected zones. In choosing the material, the design temperature range must be taken into account with respect to risk of brittle fracture, stress corrosion cracking, resistance to impact, and suitability for the hazardous materials intended for transportation in the portable tank. When fine grain steel is used, the guaranteed value of the yield strength must be not more than 460 N/mm\2\ and the guaranteed value of the upper limit of the tensile strength must be not more than 725 N/ mm\2\ according to the material specification. Aluminum may not be used as a construction material for the shells of portable tanks intended for the transport of non-refrigerated liquefied gases. For portable tanks intended for the transport of liquid or solid hazardous materials, aluminum may only be used as a construction material for portable tank shells if approved by the Associate Administrator. Portable tank materials must be suitable for the external environment where they will be transported, taking into account the determined design temperature range. Portable tanks shall be designe#
Passage 421d to withstand, without loss of contents, at least the internal pressure due to the#
Passage 422contents and the static, dynamic and thermal loads during normal conditions of handling and transportation. The design must take into account the effects of fatigue, caused by repeated application of these loads through the expected life of the portable tank. (2) Portable tank shells, fittings, and pipework shall be constructed from materials that are: (i) Compatible with the hazardous materials intended to be transported; or (ii) Properly passivated or neutralized by chemical reaction, if applicable; or (iii) For portable tanks used for liquid and solid materials, lined with corrosion-resistant material directly bonded to the shell or attached by equivalent means. (3) Gaskets and seals shall be made of materials that are compatible with the hazardous materials intended to be transported. (4) When shells are lined, the lining must be compatible with the hazardous materials intended to be transported, homogeneous, non- porous, free from perforations, sufficiently elastic and compatible with the thermal expansion characteristics of the shell. The lining of every shell, shell fittings and piping must be continuous and must extend around the face of any flange. Where external fittings are welded to the tank, the lining must be continuous through the fitting and around the face of external flanges. Joints and seams in the lining must be made by fusing the material together or by other equally effective means. (5) Contact between dissimilar metals which could result in damage by galvanic action must be prevented by appropriate measures. (6) The construction materials of the portable tank, including any devices, gaskets, linings and accessories, must not adversely affect or react with the hazardous materials intended to be transported in the portable tank. (7) Portable tanks must be designed and constructed with supports that provide a secure base during transportation and with suitable lifting and tie-down attachments. (c) Design criteria. (1) Portable tanks and their fastenings must, under the maximum permissible loads and maximum permissible working pressures, be capable of absorbing the following separately applied static forces (for calculation purposes, acceleration due to gravity (g) =9.81m/s\2\): (i) In the direction of travel: 2g (twice the MPGM multiplied by the acceleration due to gravity); (ii) Horizontally at right angles to the direction of travel: 1g#
Passage 423(the MPGM multiplied by the acceleration due to gravity); (iii) Vertically upwards: 1g (the MPGM multiplied by the acceleration due to gravity); and (iv) Vertically downwards: 2g (twice the MPGM multiplied by the acceleration due to gravity). (2) Under each of the forces specified in paragraph (c)(1) of this section, the safety factor must be as follows: (i) For metals having a clearly defined yield point, a design margin of 1.5 in relation to the guaranteed yield strength; or (ii) For metals with no clearly defined yield point, a design margin of 1.5 in relation to the guaranteed 0.2% proof strength and, for austenitic steels, the 1% proof strength. (3) The values of yield strength or proof strength must be the values according to recognized material standards. When austenitic steels are used, the specified minimum values of yield strength or proof strength according to the material standards may be increased by up to 15% for portable tanks used for liquid and solid hazardous materials, other than toxic by inhalation liquids meeting the criteria of Hazard Zone A or Hazard Zone B (see Sec. 173.133 of this subchapter), when these greater values are attested in the material inspection certificate. (4) Portable tanks must be capable of being electrically grounded to prevent dangerous electrostatic discharge when they are used for Class 2 flammable gases or Class 3 flammable liquids, including elevated temperature materials transported at or above their flash point. (5) For shells of portable tanks used for liquefied compressed gases, the shell must consist of a circular cross section. Shells must be of a design capable of being stress-analysed mathematically or experimentally by resistance strain gauges as specified in UG-101, Section VIII of the ASME Code (see Sec. 171.7 of this subchapter), or other methods approved by the Associate Administrator. (6) Shells must be designed and constructed to withstand a hydraulic test pressure of not less than 1.5 times the design pressure for portable tanks used for liquids and 1.3 times the design pressure for portable tanks used for liquefied compressed gases. Specific requirements are provided for each hazardous material in the applicable T Code or portable tank special provision specified in the Sec. 172.101 Table of this subchapter. The minimum shell thickness requirements must also be taken into account. (7) For met#
Passage 424als exhibiting a clearly defined yield point or characterized by a guaranteed proof strength (0.2% proof strength, generally, or 1% proof strength for austenitic steels), the primary membrane stress (sigma) in the shell must not exceed 0.75 Re or 0.50 Rm, whichever is lower, at the test pressure, where: Re = yield strength in N/mm2, or 0.2% proof strength or, for austenitic steels, 1% proof strength; Rm = minimum tensile strength in N/mm\2\. (8) The values of Re and Rm to be used must be the specified minimum values according to recognized material standards. When austenitic steels are used, the specified minimum values for Re and Rm according to the material standards may be increased by up to 15% when greater values are attested in the material inspection certificate. (9) Steels which have a Re/Rm ratio of more than 0.85 are not allowed for the construction of welded shells. The values of Re and Rm to be used in determining this ratio must be the values specified in the material inspection certificate. (10) Steels used in the construction of shells must have an elongation at fracture, in percentage, of not less than 10,000/Rm with an absolute minimum of 16% for fine grain steels and 20% for other steels. (11) For the purpose of determining actual values for materials for sheet metal, the axis of the tensile test specimen must be at right angles (transversely) to the direction of rolling. The permanent elongation at fracture must be measured on test specimens of rectangular cross sections in accordance with ISO 6892 (see Sec. 171.7 of this subchapter), using a 50 mm gauge length. (d) Minimum shell thickness. (1) The minimum shell thickness must be the greatest thickness of the following: (i) the minimum thickness determined in accordance with the requirements of paragraphs (d)(2) through (d)(10) of this section; (ii) the minimum thickness determined in accordance with Section VIII of the ASME Code (see Sec. 171.7 of this subchapter) or other approved pressure vessel code; or (iii) the minimum thickness specified in the applicable T code or portable tank special provision indicated for each hazardous material in the Sec. 172.101 Table of this subchapter. (2) Shells (cylindrical portions, heads and manhole covers) not more than 1.80 m in diameter may not be less than 5 mm thick in the reference steel or of#
Passage 425equivalent thickness in the metal to be used. Shells more than 1.80 m in diameter may not be less than 6 mm (0.2 inches) thick in the reference steel or of equivalent thickness in the metal to be used. For portable tanks used only for the transportation of powdered or granular solid hazardous materials of Packing Group II or III, the minimum thickness requirement may be reduced to 5 mm in the reference steel or of equivalent thickness in the metal to be used regardless of the shell diameter. For vacuum-insulated tanks, the aggregate thickness of the jacket and the shell must correspond to the minimum thickness prescribed in this paragraph, with the thickness of the shell itself not less than the minimum thickness prescribed in paragraph (d)(3) of this section. (3) When additional protection against shell damage is provided in the case of portable tanks used for liquid and solid hazardous materials requiring test pressures less than 2.65 bar (265.0 kPa), subject to certain limitations specified in the UN Recommendations (see Sec. 171.7 of this subchapter), the Associate Administrator may approve a reduced minimum shell thickness. (4) The cylindrical portions, heads and manhole covers of all shells must not be less than 3 mm (0.1 inch) thick regardless of the material of construction, except for portable tanks used for liquefied compressed gases where the cylindrical portions, ends (heads) and manhole covers of all shells must not be less than 4 mm (0.2 inch) thick regardless of the material of construction. (5) When steel is used, that has characteristics other than that of reference steel, the equivalent thickness of the shell and heads must be determined according to the following formula: [GRAPHIC] [TIFF OMITTED] TN21JN01.005#
Passage 426e1 = required equivalent thickness (in mm) of the metal to be used; e0 = minimum thickness (in mm) of the reference steel specified in the applicable T code or portable tank special provision indicated for each material in the Sec. 172.101 Table of this subchapter; d1 = 1.8m, unless the formula is used to determine the equivalent minimum thickness for a portable tank shell that is required to have a minimum thickness of 8mm or 10mm according to the applicable T code indicated in the Sec. 172.101 Table of this subchapter. When reference steel thicknesses of 8mm or 10mm are specified, d1 is equal to the actual diameter of the shell but not less than 1.8m; Rm1 = guaranteed minimum tensile strength (in N/mm \2\) of the metal to be used; A1 = guaranteed minimum elongation at fracture (in %) of the metal to be used according to recognized material standards.#
Passage 427(6) The wall and all parts of the shell may not have a thickness less than that prescribed in paragraphs (d)(2), (d)(3) and (d)(4) of this section. This thickness must be exclusive of any corrosion allowance. (7) There must be no sudden change of plate thickness at the attachment of the heads to the cylindrical portion of the shell. (e) Service equipment. (1) Service equipment must be arranged so that it is protected against the risk of mechanical damage by external forces during handling and transportation. When the connections between the frame and the shell allow relative movement between the sub- assemblies, the equipment must be fastened to allow such movement without risk of damage to any working part. The external discharge fittings (pipe sockets, shut-off devices) and the internal stop-valve and its seating must be protected against mechanical damage by external forces (for example, by using shear sections). Each internal self- closing stop-valve must be protected by a shear section or sacrificial device located outboard of the valve. The shear section or sacrificial device must break at no more than 70% of the load that would cause failure of the internal self-closing stop valve. The filling and discharge devices (including flanges or threaded plugs) and any protective caps must be capable of being secured against unintended opening. (2) Each filling or discharge opening of a portable tank must be clearly marked to indicate its function. (3) Each stop-valve or other means of closure must be designed and constructed to a rated pressure not less than the MAWP of the shell taking into account the temperatures expected during transport. All stop-valves with screwed spindles must close by a clockwise motion of the handwheel. For other stop-valves, the position (open and closed) and direction of closure must be clearly indicated. All stop-valves must be designed to prevent unintentional opening. (4) Piping must be designed, constructed and installed to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping must be of a suitable metallic material. Welded pipe joints must be used wherever possible. (5) Joints in copper tubing must be brazed or have an equally strong metal union. The melting point of brazing materials must be no lower than 525 deg.C (977 deg.F). The joints must not decrease the strength#
Passage 428of the tubing, such as may happen when cutting threads. Brazed joints are not authorized for portable tanks intended for refrigerated liquefied gases. (6) The burst pressure of all piping and pipe fittings must be greater than the highest of four times the MAWP of the shell or four times the pressure to which it may be subjected in service by the action of a pump or other device (except pressure relief devices). (7) Ductile metals must be used in the construction of valves and accessories. (f) Pressure relief devices.--(1) Marking of pressure relief devices. Every pressure relief device must be clearly and permanently marked with the following: (i) the pressure (in bar or kPa) or temperature for fusible elements (in deg.C) at which it is set to discharge; (ii) the allowable tolerance at the discharge pressure for reclosing devices; (iii) the reference temperature corresponding to the rated pressure for frangible discs; (iv) the allowable temperature tolerance for fusible elements; (v) the rated flow capacity of the device in standard cubic meters of air per second (m\3\/s)determined according to ISO 4126-1 (see Sec. 171.7 of this subchapter); and (vi) when practicable, the device must show the manufacturer's name and product number. (2) Connections to pressure relief devices. Connections to pressure relief devices must be of sufficient size to enable the required discharge to pass unrestricted to the safety device. No stop-valve may be installed between the shell and the pressure relief devices except where duplicate devices are provided for maintenance or other reasons and the stop-valves serving the devices actually in use are locked open or the stop-valves are interlocked so that at least one of the devices is always in use. There must be no obstruction in an opening leading to a vent or pressure relief device which might restrict or cut-off the flow from the shell to that device. Vents or pipes from the pressure relief device outlets, when used, must deliver the relieved vapor or liquid to the atmosphere in conditions of minimum back-pressure on the relieving devices. (3) Location of pressure relief devices. (i) Each pressure relief device inlet must be situated on top of the shell in a position as near the longitudinal and#
Passage 429transverse center of the shell as reasonably practicable. All pressure relief device inlets must, under maximum filling conditions, be situated in the vapor space of the shell and the devices must be so arranged as to ensure that any escaping vapor is not restricted in any manner. For flammable hazardous materials, the escaping vapor must be directed away from the shell in such a manner that it cannot impinge upon the shell. For refrigerated liquefied gases, the escaping vapor must be directed away from the tank and in such a manner that it cannot impinge upon the tank. Protective devices which deflect the flow of vapor are permissible provided the required relief-device capacity is not reduced. (ii) Provisions must be implemented to prevent unauthorized persons from access to the pressure relief devices and to protect the devices from damage caused by the portable tank overturning. (g) Gauging devices. Unless a portable tank is intended to be filled by weight, it must be equipped with one or more gauging devices. Glass level-gauges and gauges made of other fragile material, which are in direct communication with the contents of the tank are prohibited. A connection for a vacuum gauge must be provided in the jacket of a vacuum-insulated portable tank. (h) Portable tank supports, frameworks, lifting and tie-down attachments. (1) Portable tanks must be designed and constructed with a support structure to provide a secure base during transport. The forces and safety factors specified in paragraphs (c)(1) and (c)(2) of this section, respectively, must be taken into account in this aspect of the design. Skids, frameworks, cradles or other similar structures are acceptable. (2) The combined stresses caused by portable tank mountings (for example, cradles, framework, etc.) and portable tank lifting and tie- down attachments must not cause stress that would damage the shell in a manner that would compromise its lading retention capability. Permanent lifting and tie-down attachments must be fitted to all portable tanks. Preferably they should be fitted to the portable tank supports but may be secured to reinforcing plates located on the shell at the points of support. Each portable tank must be designed so that the center of gravity of the filled tank is approximately centered within the points of attachment for lifting devices. (3) In the design of supports and fram#
Passage 430eworks, the effects of environmental corrosion must be taken into account. (4) Forklift pockets must be capable of being closed off. The means of closing forklift pockets must be a permanent part of the framework or permanently attached to the framework. Single compartment portable tanks with a length less than 3.65 m (12 ft.) need not have forklift pockets that are capable of being closed off provided that: (i) The shell, including all the fittings, are well protected from being hit by the forklift blades; and (ii) The distance between forklift pockets (measured from the center of each pocket) is at least half of the maximum length of the portable tank. (5) During transport, portable tanks must be adequately protected against damage to the shell, and service equipment resulting from lateral and longitudinal impact and overturning, or the shell and service equipment must be constructed to withstand the forces resulting from impact or overturning. External fittings must be protected so as to preclude the release of the shell contents upon impact or overturning of the portable tank on its fittings. Examples of protection include: (i) Protection against lateral impact which may consist of longitudinal bars protecting the shell on both sides at the level of the median line; (ii) Protection of the portable tank against overturning which may consist of reinforcement rings or bars fixed across the frame; (iii) Protection against rear impact which may consist of a bumper or frame; (iv) Protection of the shell against damage from impact or overturning by use of an ISO frame in accordance with ISO 1496-3 (see Sec. 171.7 of this subchapter); and (v) Protection of the portable tank from impact or damage that may result from overturning by an insulation jacket. (i) Marking. (1) Every portable tank must be fitted with a corrosion resistant metal plate permanently attached to the portable tank in a conspicuous place and readily accessible for inspection. When the plate cannot be permanently attached to the shell, the shell must be marked with at least the information required by Section VIII of the ASME Code (see Sec. 171.7 of this subchapter). At a minimum, the following information must be marked on the plate by stamping or by any other equivalent method:#
Passage 431Country of manufacture U N Approval Country Approval Number Alternative Arrangements (see Sec. 178.247(a)(2)) ``AA'' Manufacturer's name or mark Manufacturer's serial number Approval Agency (Authorized body for the design approval) Owner's registration number Year of manufacture Pressure vessel code to which the shell is designed Test pressure________bar gauge. MAWP________bar gauge. External design pressure (not required for portable tanks used for refrigerated liquefied gases)________bar gauge. Design temperature range________ deg.C to________ deg.C. (For portable tanks used for refrigerated liquefied gases, the minimum design temperature must be marked.) Water capacity at 20 deg.C/________liters. Water capacity of each compartment at 20 deg.C________liters. Initial pressure test date and witness identification. MAWP for heating/cooling system________bar gauge. Shell material(s) and material standard reference(s). Equivalent thickness in reference steel________mm. Lining material (when applicable). Date and type of most recent periodic test(s). Month________Year________Test pressure________bar gauge. Stamp of approval agency that performed or witnessed the most recent test. For portable tanks used for refrigerated liquefied gases: Either ``thermally insulated'' or ``vacuum insulated''________. Effectiveness of the insulation system (heat influx)________Watts (W). Reference holding time________days or hours and initial pressure________bar/kPa gauge and degree of filling________in kg for each refrigerated liquefied gas permitted for transportation. (2) The following information must be marked either on the portable tank itself or on a metal plate firmly secured to the portable tank: Name of the operator. Name of hazardous materials being transported and maximum mean bulk temperature (except for refrigerated liquefied gases, the name and temperature are only required when the maximum mean bulk temperature is higher than 50 deg.C). Maximum permissible gross mass (MPGM)________kg. Unladen (tare) mass________kg. Note to Paragraph (i)(2): For the identification of the hazardous materials being transported refer to part 172 of this subchapter.#
Passage 432(3) If a portable tank is designed and approved for open seas operations, such as offshore oil exploration, in accordance with the IMDG Code, the words ``OFFSHORE PORTABLE TANK'' must be marked on the identification plate.#
Passage 433(j) Initial inspection and test. The initial inspection and test of a portable tank must include the following: (1) A check of the design characteristics. (2) An internal and external examination of the portable tank and its fittings, taking into account the hazardous materials to be transported. For UN portable tanks used for refrigerated liquefied gases, a pressure test using an inert gas may be conducted instead of a hydrostatic test. An internal inspection is not required for a portable tank used for the dedicated transportation of refrigerated liquefied gases that are not filled with an inspection opening. (3) A pressure test as specified in paragraph (i) of this section. (4) A leakage test. (5) A test of the satisfactory operation of all service equipment including pressure relief devices must also be performed. When the shell and its fittings have been pressure-tested separately, they must be subjected to a leakage test after reassembly. All welds, subject to full stress level in the shell, must be inspected during the initial test by radiographic, ultrasonic, or another suitable non-destructive test method. This does not apply to the jacket. (6) A UN portable tank that meets the definition of ``container'' in the CSC (see 49 CFR 450.3(a)(2)) must be subjected to an impact test using a prototype representing each design type. The prototype portable tank must be shown to be capable of absorbing the forces resulting from an impact not less than 4 times (4 g) the maximum permissable gross mass of the fully loaded portable tank at a duration typical of the mechanical shocks experienced in rail transportation. A listing of standards describing methods acceptable for performing the impact test are provided in the UN Recommendations (see Sec. 171.7 of this subchapter). UN portable tanks used for the dedicated transportation of ``Helium, refrigerated liquid,'' UN1963 and ``Hydrogen, refrigerated liquid,'' UN1966 that are marked ``NOT FOR RAIL TRANSPORT'' in letters of a minimum height of 20 cm (8 inches) on at least two sides of the portable tank are excepted from the 4 g impact test. (7) The following tests must be completed on a portable tank or a series of portable tanks designed and constructed to a single design type that is also a CSC container without leakage or deformation that would render the portable tank unsafe for transportation and use: (i) Long#
Passage 434itudinal inertia. The portable tank loaded to its maximum gross weight must be positioned with its longitudinal axis vertical. It shall be held in this position for five minutes by support at the lower end of the base structure providing vertical and lateral restraint and by support at the upper end of the base structure providing lateral restraint only. (ii) Lateral inertia. The portable tank loaded to its maximum gross weight must be positioned for five minutes with its transverse axis vertical. It shall be held in this position for five minutes by support at the lower side of the base structure providing vertical and lateral restraint and by support at the upper side of the base structure providing lateral restraint only. 72. Section 178.275 is added to subpart H to read as follows: Sec. 178.275 Specification for UN Portable Tanks intended for the transportation of liquid and solid hazardous materials.#
Passage 435(a) In addition to the requirements of Sec. 178.274, this section sets forth definitions and requirements that apply to UN portable tanks intended for the transportation of liquid and solid hazardous materials. (b) Definitions and requirements.--(1) Design pressure means the pressure to be used in calculations required by the recognized pressure vessel code. The design pressure must not be less than the highest of the following pressures: (i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (ii) The sum of-- (A) The absolute vapor pressure (in bar) of the hazardous material at 65 deg.C, minus 1 bar (149 deg.F, minus 100 kPa); (B) The partial pressure (in bar) of air or other gases in the ullage space, resulting from their compression during filling without pressure relief by a maximum ullage temperature of 65 deg.C (149 deg.F) and a liquid expansion due to an increase in mean bulk temperature of 35 deg.C (95 deg.F); and (C) A head pressure determined on the basis of the forces specified in Sec. 178.274(c) of this subchapter, but not less than 0.35 bar (35 kPa). (2) Maximum allowable working pressure (MAWP) means a pressure that must not be less than the highest of the following pressures measured at the top of the shell while in operating position: (i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (ii) The maximum effective gauge pressure to which the shell is designed which must be not less than the design pressure. (c) Service equipment. (1) In addition to the requirements specified in Sec. 178.274, for service equipment, all openings in the shell, intended for filling or discharging the portable tank must be fitted with a manually operated stop-valve located as close to the shell as reasonably practicable. Other openings, except for openings leading to venting or pressure relief devices, must be equipped with either a stop-valve or another suitable means of closure located as close to the shell as reasonably practicable. (2) All portable tanks must be fitted with a manhole or other inspection openings of a suitable size to allow for internal inspection and adequate access for maintenance and repair of the interior. Compartmented portable tanks must have a manhole or other inspection openings for each compartment. (3) For insulated portable tanks, top fittings must be surr#
Passage 436ounded by a spill collection reservoir with suitable drains. (4) Piping must be designed, constructed and installed to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping must be of a suitable metallic material. Welded pipe joints must be used wherever possible. (d) Bottom openings. (1) Certain hazardous materials may not be transported in portable tanks with bottom openings. When the applicable T code or portable tank special provision, as referenced for materials in the Sec. 172.101 Table of this subchapter, specifies that bottom openings are prohibited, there must be no openings below the liquid level of the shell when it is filled to its maximum permissible filling limit. When an existing opening is closed, it must be accomplished by internally and externally welding one plate to the shell. (2) Bottom discharge outlets for portable tanks carrying certain solid, crystallizable or highly viscous hazardous materials must be equipped with at least two serially fitted and mutually independent shut-off devices. Use of only two shut-off devices is only authorized when this paragraph is referenced in the applicable T Code indicated for each hazardous material in the Sec. 172.101 Table of this subchapter. The design of the equipment must be to the satisfaction of the approval agency and must include: (i) An external stop-valve fitted as close to the shell as reasonably practicable; and (ii) A liquid tight closure at the end of the discharge pipe, which may be a bolted blank flange or a screw cap. (3) Except as provided in paragraph (c)(2) of this section, every bottom discharge outlet must be equipped with#
Passage 437three serially fitted and mutually independent shut-off devices. The design of the equipment must include: (i) A self-closing internal stop-valve, which is a stop-valve within the shell or within a welded flange or its companion flange, such that: (A) The control devices for the operation of the valve are designed to prevent any unintended opening through impact or other inadvertent act; (B) The valve is operable from above or below; (C) If possible, the setting of the valve (open or closed) must be capable of being verified from the ground; (D) Except for portable tanks having a capacity less than 1,000 liters (264.2 gallons), it must be possible to close the valve from an accessible position on the portable tank that is remote from the valve itself within 30 seconds of actuation; and (E) The valve must continue to be effective in the event of damage to the external device for controlling the operation of the valve; (ii) An external stop-valve fitted as close to the shell as reasonably practicable; (iii) A liquid tight closure at the end of the discharge pipe, which may be a bolted blank flange or a screw cap; and (iv) For portable tanks used for the transportation of liquid materials that are flammable, pyrophoric, oxidizing or toxic, the remote means of closure must be capable of thermal activation. The thermal means of activation must activate at a temperature of not more than 121 deg.C (250 deg.F). (e) Pressure relief devices. All portable tanks must be fitted with at least one pressure relief device. All relief devices must be designed, constructed and marked in accordance with the requirements of this subchapter. (f) Vacuum-relief devices. (1) A shell which is to be equipped with a vacuum-relief device must be designed to withstand, without permanent deformation, an external pressure of not less than 0.21 bar (21.0 kPa). The vacuum-relief device must be set to relieve at a vacuum setting not greater than -0.21 bar (-21.0 kPa) unless the shell is designed for a higher external over pressure, in which case the vacuum-relief pressure of the device to be fitted must not be greater than the tank design vacuum pressure. A shell that is not fitted with a vacuum-relief device must be designed to withstand, without permanent deformation, an external pressure of not less than 0.4 bar (40.0 kPa). (2) Vacuum-relief devices used on portable tanks intended for the#
Passage 438transportation of hazardous materials meeting the criteria of Class 3, including elevated temperature hazardous materials transported at or above their flash point, must prevent the immediate passage of flame into the shell or the portable tank must have a shell capable of withstanding, without leakage, an internal explosion resulting from the passage of flame into the shell. (g) Pressure relief devices. (1) Each portable tank with a capacity not less than 1,900 liters (501.9 gallons) and every independent compartment of a portable tank with a similar capacity, must be provided with one or more pressure relief devices of the reclosing type. Such portable tanks may, in addition, have a frangible disc or fusible element in parallel with the reclosing devices, except when the applicable T code assigned to a hazardous material requires that the frangible disc precede the pressure relief device, according to paragraph (g)(3) of this section, or when no bottom openings are allowed. The pressure relief devices must have sufficient capacity to prevent rupture of the shell due to over pressurization or vacuum resulting from filling, discharging, heating of the contents or fire. (2) Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. (3) When required for certain hazardous materials by the applicable T code or portable tank special provision specified for a hazardous material in the Sec. 172.101 Table of this subchapter, portable tanks must have a pressure relief device consistent with the requirements of this subchapter. Except for a portable tank in dedicated service that is fitted with an approved relief device constructed of materials compatible with the hazardous material, the relief device system must include a frangible disc preceding (such as, between the lading and the reclosing pressure relief device) a reclosing pressure relief device. A pressure gauge or suitable tell-tale indicator for the detection of disc rupture, pin-holing or leakage must be provided in the space between the frangible disc and the pressure relief device to allow the portable tank operator to check to determine if the disc is leak free. The frangible disc must rupture at a nominal pressure 10% above the start-to-discharge pressure of the reclosable pressure relief device. (4) Every#
Passage 439portable tank with a capacity less than 1,900 liters (501.9 gallons) must be fitted with a pressure relief device which, except as provided in paragraph (g)(3) of this section, may be a frangible disc when this disc is set to rupture at a nominal pressure equal to the test pressure at any temperature within the design temperature range. (5) When the shell is fitted for pressure discharge, a suitable pressure relief device must provide the inlet line to the portable tank and set to operate at a pressure not higher than the MAWP of the shell, and a stop-valve must be fitted as close to the shell as practicable to minimize the potential for damage. (6) Setting of pressure relief devices. (i) Pressure relief devices must operate only in conditions of excessive rise in temperature. The shell must not be subject to undue fluctuations of pressure during normal conditions of transportation. (ii) The required pressure relief device must be set to start to discharge at a nominal pressure of five-sixths of the test pressure for shells having a test pressure of not more than 4.5 bar (450 kPa) and 110% of two-thirds of the test pressure for shells having a test pressure of more than 4.5 bar (450 kPa). A self-closing relief device must close at a pressure not more than 10% below the pressure at which the discharge starts. The device must remain closed at all lower pressures. This requirement does not prevent the use of vacuum-relief or combination pressure relief and vacuum-relief devices. (h) Fusible elements. Fusible elements must operate at a temperature between 110 deg.C (230 deg.F) and 149 deg.C (300.2 deg.F) provided that the pressure in the shell at the fusing temperature will not exceed the test pressure. They must be placed at the top of the shell with their inlets in the vapor space and in no case may they be shielded from external heat. Fusible elements must not be utilized on portable tanks with a test pressure which exceeds 2.65 bar (265.0 kPa). Fusible elements used on portable tanks intended for the transport of elevated temperature hazardous materials must be designed to operate at a temperature higher than the maximum temperature that will be experienced during transport and must be designed to the satisfaction of the approval agency. (i) Capacity of pressure relief devices. (1) The reclosing pressure relief device required by paragraph (g)(1) of this sec#
Passage 440tion must have a minimum cross sectional flow area equivalent to an orifice of 31.75 mm (1.3 inches) diameter. Vacuum-relief devices, when used, must have a cross sectional flow area not less than 284 mm \2\ (11.2 inches \2\). (2) Under conditions of complete fire engulfment of the portable tank, the combined delivery capacity of the relief devices must be sufficient to limit the pressure in the shell to 20% above the start-to-discharge pressure specified in paragraph (g)(6) of this section. Emergency pressure relief devices may be used to achieve the full relief capacity prescribed. The total required capacity of the relief devices may be determined using the formula in paragraph (i)(2)(i)(A) of this section or the table in paragraph (i)(2)(iii) of this section. (i)(A) To determine the total required capacity of the relief devices, which must be regarded as being the sum of the individual capacities of all the contributing devices, the following formula must be used: [GRAPHIC] [TIFF OMITTED] TN21JN01.006 Q = minimum required rate of discharge in cubic meters of air per second (m \3\/s) at standard conditions: 1 bar and 0 deg.C (273 K); F = for uninsulated shells: 1; for insulated shells: U(649-t)/13.6 but in no case is less than 0.25 where: U = thermal conductance of the insulation, in kWm-\2\ K-\1\, at 38 deg.C; and t = actual temperature of the hazardous material during filling (in deg.C) or when this temperature is unknown, let t = 15 deg.C. The value of F given in this paragraph (i)(2)(i)(A) for insulated shells may only be used if the insulation is in conformance with paragraph (i)(2)(iv) of this section; A = total external surface area of shell in square meters; Z = the gas compressibility factor in the accumulating condition (when this factor is unknown, let Z equal 1.0); T = absolute temperature in Kelvin ( deg.C + 273) above the pressure relief devices in the accumulating condition; L = the latent heat of vaporization of the liquid, in kJ/kg, in the accumulating condition; M = molecular weight of the hazardous material. (B) The constant C, as shown in the formula in paragraph (i)(2)(i)(A) of this section, is derived from one of the following formula as a function of the ratio k of specific heats: [GRAPHIC] [TIFF OMITTED] TN21JN01.007 cp is the specific heat at constant pressure; and cv is the specific heat at constant volume.#
Passage 441(C) When k >1: [GRAPHIC] [TIFF OMITTED] TN21JN01.008 (D) When k = 1 or k is unknown, a value of 0.607 may be used for the constant C. C may also be taken from the following table: C Constant Value Table ---------------------------------------------------------------------------------------------------------------- k C k C k C ---------------------------------------------------------------------------------------------------------------- 1.00 0.607 1.26 0.660 1.52 0.704 1.02 0.611 1.28 0.664 1.54 0.707 1.04 0.615 1.30 0.667 1.56 0.710 1.06 0.620 1.32 0.671 1.58 0.713 1.08 0.624 1.34 0.674 1.60 0.716 1.10 0.628 1.36 0.678 1.62 0.719 1.12 0.633 1.38 0.681 1.64 0.722 1.14 0.637 1.40 0.685 1.66 0.725 1.16 0.641 1.42 0.688 1.68 0.728 1.18 0.645 1.44 0.691 1.70 0.731 1.20 0.649 1.46 0.695 2.00 0.770 1.22 0.652 1.48 0.698 2.20 0.793 1.24 0.656 1.50 0.701 ---------------------------------------------------------------------------------------------------------------- (ii) As an alternative to the formula in paragraph (i)(2)(i)(A) of this section, relief devices for shells used for transporting liquids may be sized in accordance with the table in paragraph (i)(2)(iii) of this section. The table in paragraph (i)(2)(iii) of this section assumes an insulation value of F = 1 and must be adjusted accordingly when the shell is insulated. Other values used in determining the table in paragraph (i)(2)(iii) of this section are: L = 334.94 kJ/kg; M = 86.7; T = 394 K; Z = 1; and C = 0.607. (iii) Minimum emergency vent capacity, Q, in cubic meters per air per second at 1 bar and 0 deg.C (273 K) shown in the following table: Minimum Emergency Vent Capacity [Q Values] ---------------------------------------------------------------------------------------------------------------- A Exposed area Q (Cubic meters of A Exposed area Q (Cubic meters of (square meters) air per second) (square meters) air per second) ---------------------------------------------------------------------------------------------- 2 0.230 37.5 2.539 3 0.320 40 2.677 4 0.405 42.5 2.814 5 0.487 45 2.949 6 0.565 47.5 3.082 7 0.641 50 3.215 8 0.715 52.5 3.346 9 0.788 55 3.476 10 0.859 57.5 3.605 12 0.998 60 3.733 14 1.132 62.5 3.860 16 1.263 65 3.987 18 1.391 67.5 4.112#
Passage 44220 1.517 70 4.236 22.5 1.670 75 4.483 25 1.821 80 4.726 27.5 1.969 85 4.967 30 2.115 90 5.206 32.5 2.258 95 5.442 35 2.400 100 5.676 ---------------------------------------------------------------------------------------------------------------- (iv) Insulation systems, used for the purpose of reducing venting capacity, must be specifically approved by the approval agency. In all cases, insulation systems approved for this purpose must-- (A) Remain effective at all temperatures up to 649 deg.C (1200.2 deg.F); and (B) Be jacketed with a material having a melting point of 700 deg.C (1292 deg.F) or greater. (j) Approval, inspection and testing. Approval procedures for UN portable tanks are specified in Sec. 178.273. Inspection and testing requirements are specified in Sec. 180.605 of this subchapter. 73. Section 178.276 is added to subpart H to read as follows: Sec. 178.276 Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of non- refrigerated liquefied compressed gases.#
Passage 443(a) In addition to the requirements of Sec. 178.274 applicable to UN portable tanks, the following requirements apply to UN portable tanks used for non-refrigerated liquefied compressed gases. In addition to the definitions in Sec. 178.274, the following definitions apply: (1) Design pressure means the pressure to be used in calculations required by the ASME Code, Section VIII (see Sec. 171.7 of this subchapter). The design pressure must be not less than the highest of the following pressures: (i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (ii) The sum of: (A) The maximum effective gauge pressure to which the shell is designed as defined in this paragraph under ``MAWP''; and (B) A head pressure determined on the basis of the dynamic forces specified in paragraph (h) of this section, but not less than 0.35 bar (35 kPa). (2) Design reference temperature means the temperature at which the vapor pressure of the contents is determined for the purpose of calculating the MAWP. The value for each portable tank type is as follows: (i) Shell with a diameter of 1.5 meters (4.9 ft.) or less: 65 deg.C (149 deg.F); or (ii) Shell with a diameter of more than 1.5 meters (4.9 ft.): (A) Without insulation or sun shield: 60 deg.C (140 deg.F); (B) With sun shield: 55 deg.C (131 deg.F); and (C) With insulation: 50 deg.C (122 deg.F). (3) Filling density means the average mass of liquefied compressed gas per liter of shell capacity (kg/l). (4) Maximum allowable working pressure (MAWP) means a pressure that must be not less than the highest of the following pressures measured at the top of the shell while in operating position, but in no case less than 7 bar (700 kPa): (i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (ii) The maximum effective gauge pressure to which the shell is designed, which must be: (A) Not less than the pressure specified for each liquefied compressed gas listed in portable tank special provision T50; and (B) Not less than the sum of: (1) The absolute vapor pressure (in bar) of the liquefied compressed gas at the design reference temperature minus 1 bar; and (2) The partial pressure (in bar) of air or other gases in the ullage space which is determined by the design reference temperature and the liquid phase expansion due to the increase of the mean bulk temperature of#
Passage 444tr-tf (tf = filling temperature, usually 15 deg.C, tr = 50 deg.C maximum mean bulk temperature). (b) General design and construction requirements. (1) Shells must be of seamless or welded steel construction, or combination of both, and have a water capacity greater than 450 liters (118.9 gallons). Shells must be designed, constructed, certified and stamped in accordance with the ASME Code, Section VIII (see Sec. 171.7 of this subchapter). (2) Portable tanks must be postweld heat-treated and radiographed as prescribed in Section VIII of the ASME Code, except that each portable tank constructed in accordance with part UHT of the ASME Code must be postweld heat-treated. Where postweld heat treatment is required, the portable tank must be treated as a unit after completion of all the welds in and/or to the shell and heads. The method must be as prescribed in the ASME Code. Welded attachments to pads may be made after postweld heat treatment is made. A portable tank used for anhydrous ammonia must be postweld heat-treated. The postweld heat treatment must be as prescribed in the ASME Code, but in no event at less than 1050 deg.F tank metal temperature. Additionally, portable tanks constructed in accordance with part UHT of the ASME Code must conform to the following requirements: (i) Welding procedure and welder performance tests must be made annually in accordance with Section IX of the ASME Code (see Sec. 171.7 of this subchapter). In addition to the essential variables named therein, the following must be considered to be essential variables: number of passes, thickness of plate, heat input per pass, and manufacturer's identification of rod and flux. The number of passes, thickness of plate and heat input per pass may not vary more than 25 percent from the qualified procedure. Records of the qualification must be retained for at least 5 years by the portable tank manufacturer or his designated agent and, upon request, made available to a representative of the Department of Transportation or the owner of the tank. (ii) Impact tests must be made on a lot basis. A lot is defined as 100 tons or less of the same heat and having a thickness variation no greater than plus or minus 25 percent. The minimum impact required for full-sized specimens shall#
Passage 445be 20 foot-pounds (or 10 foot-pounds for half-sized specimens) at 0 deg.F (-17.8 deg.F) Charpy V-Notch in both the longitudinal and transverse direction. If the lot test does not pass this requirement, individual plates may be accepted if they individually meet this impact requirement. (3) When the shells intended for the transportation of non- refrigerated liquefied compressed gases are equipped with thermal insulation, a device must be provided to prevent any dangerous pressure from developing in the insulating layer in the event of a leak, when the protective covering is closed it must be gas tight. The thermal insulation must not inhibit access to the fittings and discharge devices. In addition, the thermal insulation systems must satisfy the following requirements: (i) consist of a shield covering not less than the upper third, but not more than the upper half of the surface of the shell, and separated from the shell by an air space of approximately 40 mm (1.7 inches) across; or (ii) consist of a complete cladding of insulating materials. The insulation must be of adequate thickness and constructed to prevent the ingress of moisture and damage to the insulation. The insulation and cladding must have a thermal conductance of not more than 0.67 (Wm-2K-1) under normal conditions of transportation. (c) Service equipment. (1) Each opening with a diameter of more than 1.5 mm (0.1 inch) in the shell of a portable tank, except openings for pressure-relief devices, inspection openings and closed bleed holes, must be fitted with at least three mutually independent shut-off devices in series: the first being an internal stop-valve, excess flow valve, integral excess flow valve, or excess flow feature (see Sec. 178.337-1(g)), the second being an external stop-valve and the third being a blank flange, thread cap, plug or equivalent tight liquid closure device. (2) When a portable tank is fitted with an excess flow valve, the excess flow valve must be so fitted that its seating is inside the shell or inside a welded flange or, when fitted externally, its mountings must be designed so that in the event of impact it maintains its effectiveness. The excess flow valves must be selected and fitted so as to close automatically when the rated flow, specified by the manufacturer, is reached. Connections and accessories leading to or from such a valve must have a capacity for#
Passage 446a flow more than the excess flow valve's rated flow. (3) For filling and discharge openings that are located below the liquid level, the first shut-off device must be an internal stop-valve and the second must be a stop-valve placed in an accessible position on each discharge and filling pipe. (4) For filling and discharge openings located below the liquid level of portable tanks intended for the transportation of flammable and/or toxic liquefied compressed gases, the internal stop-valve must be a self-closing safety device that fully closes automatically during filling or discharge in the event of fire engulfment. The device shall fully close within 30 seconds of actuation and the thermal means of closure must actuate at a temperature of not more than 121 deg.C (250 deg.F). Except for portable tanks having a capacity less than 1,000 liters (264.2 gallons), this device must be operable by remote control. (5) In addition to filling, discharge and gas pressure equalizing orifices, shells may have openings in which gauges, thermometers and manometers can be fitted. Connections for such instruments must be made by suitable welded nozzles or pockets and may not be connected by screwed connections through the shell. (6) All portable tanks must be fitted with manholes or other inspection openings of suitable size to allow for internal inspection and adequate access for maintenance and repair of the interior. (7) Inlets and discharge outlets on chlorine portable tanks. The inlet and discharge outlets on portable tanks used to transport chlorine must meet the requirements of Sec. 178.337-1(c)(2) and must be fitted with an internal excess flow valve. In addition to the internal excess flow valve, the inlet and discharge outlets must be equipped with an external stop valve (angle valve). Excess flow valves must conform to the standards of The Chlorine Institute, Inc. (see Sec. 171.7 of this subchapter) as follows: (i) A valve conforming to Drawing 101-7, dated July 1993, must be installed under each liquid angle valve. (ii) A valve conforming to Drawing 106-6, dated July 1993, must be installed under each gas angle valve. For portable tanks used to transport non-refrigerated liquefied gases. (8) External fittings must be grouped together as close as reasonably practicable. The following openings may be installed at locations other than on the top or end of the tank: (#
Passage 447i) The openings for liquid level gauging devices, pressure gauges, or for safety devices, may be installed separately at the other location or in the side of the shell; (ii) One plugged opening of 2-inch National Pipe Thread or less provided for maintenance purposes may be located elsewhere; (iii) An opening of 3-inch National Pipe Size or less may be provided at another location, when necessary, to facilitate installation of condensing coils. (9) Filling and discharge connections are not required to be grouped and may be installed below the normal liquid level of the tank if: (i) The portable tank is permanently mounted in a full framework for containerized transport; (ii) For each portable tank design, a prototype portable tank, meets the requirements of parts 450 through 453 of this title for compliance with the requirements of Annex II of the International Convention for Safe Containers; and (iii) Each filling and discharge outlet meets the requirements of paragraph (c)(4) of this section. (d) Bottom openings. Bottom openings are prohibited on portable tanks when the portable tank special provision T50 in Sec. 172.102(c)(7) of this subchapter indicates that bottom openings are not allowed. In this case, there may be no openings located below the liquid level of the shell when it is filled to its maximum permissible filling limit. (e) Pressure relief devices. (1) Portable tanks must be provided with one or more reclosing pressure relief devices. The pressure relief devices must open automatically at a pressure not less than the MAWP and be fully open at a pressure equal to 110% of the MAWP. These devices must, after discharge, close at a pressure not less than 10% below the pressure at which discharge starts and must remain closed at all lower pressures. The pressure relief devices must be of a type that will resist dynamic forces including liquid surge. A frangible disc may only be used in series with a reclosing pressure relief device. (2) Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure. (3) A portable tank intended for the transportation of certain liquefied compressed gases identified in portable tank special provision T50 in Sec. 172.102 of this subchapter must have a pressure relief device which conforms to the requirements of this subchapter. Un#
Passage 448less a portable tank, in dedicated service, is fitted with a relief device constructed of materials compatible with the hazardous material, the relief device must be comprised of a frangible disc preceded by a reclosing device. The space between the frangible disc and the device must be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement must facilitate the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible disc must rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device. (4) In the case of portable tanks used for more than one gas, the pressure relief devices must open at a pressure indicated in paragraph (e)(1) of this section for the gas having the highest maximum allowable pressure of the gases allowed to be transported in the portable tank. (f) Capacity of relief devices. The combined delivery capacity of the relief devices must be sufficient so that, in the event of total fire engulfment, the pressure inside the shell cannot exceed 120% of the MAWP. Reclosing relief devices must be used to achieve the full relief capacity prescribed. In the case of portable tanks used for more than gas, the combined delivery capacity of the pressure relief devices must be taken for the liquefied compressed gas which requires the highest delivery capacity of the liquefied compressed gases allowed to be transported in the portable tank. The total required capacity of the relief devices must be determined according to the requirements in Sec. 178.275(h). These requirements apply only to liquefied compressed gases which have critical temperatures well above the temperature at the accumulating condition. For gases which have critical temperatures near or below the temperature at the accumulating condition, the calculation of the pressure relief device delivery capacity must consider the additional thermodynamic properties of the gas (for example, CGA S-1.2-1980 (see Sec. 171.7 of this subchapter). 74. A new Sec. 178.277 is added to subpart H to read as follows: Sec. 178.277 Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of refrigerated liquefied gases.#
Passage 449(a) In addition to the requirements of Sec. 178.274 applicable to UN portable tanks, the following requirements and definitions apply to UN portable tanks used for refrigerated liquefied gases: Design pressure For the purpose of this section the term ``design pressure'' is consistent with the definition for design pressure in the ASME Code, Section VIII (see Sec. 171.7 of this subchapter). Holding time is the time, as determined by testing, that will elapse from loading until the pressure of the contents, under equilibrium conditions, reaches the lowest set pressure of the pressure limiting device(s) (for example, pressure control valve or pressure relief device). Holding time must be determined as specified in Sec. 178.338-9. Maximum allowable working pressure (MAWP) means the maximum effective gauge pressure permissible at the top of the shell of a loaded portable tank in its operating position including the highest effective pressure during filling and discharge; Minimum design temperature means the temperature which is used for the design and construction of the shell not higher than the lowest (coldest) service temperature of the contents during normal conditions of filling, discharge and transportation. Shell means the part of the portable tank which retains the refrigerated liquefied gas intended for transport, including openings and their closures, but does not include service equipment or external structural equipment. Tank means a construction which normally consists of either: (1) A jacket and one or more inner shells where the space between the shell(s) and the jacket is exhausted of air (vacuum insulation) and may incorporate a thermal insulation system; or (2) A jacket and an inner shell with an intermediate layer of solid thermally insulating material (for example, solid foam). (b) General design and construction requirements. (1) Portable tanks must be of seamless or welded steel construction and have a water capacity of more than 450 liters (118.9 gallons). Portable tanks must be designed, constructed, certified and stamped in accordance with Section VIII of the ASME Code (see Sec. 171.7 of this subchapter). (2 ) Portable tanks must be postweld heat treated and radiographed as prescribed in the ASME Code except that each tank constructed in accordance with part UHT of the ASME Code must be postweld heat treated. Where postweld heat treatment#
Passage 450is required, the tank must be treated as a unit after completion of all the welds to the shell and heads. The method must be as prescribed in the ASME Code. Welded attachments to pads may be made after postweld heat treatment is made. The postweld heat treatment must be as prescribed in Section VIII of the ASME Code, but in no event at less than 1050 deg.F tank metal temperature. (3) Welding procedure and welder performance tests must be made annually in accordance with Section IX of the ASME Code (see Sec. 171.7 of this subchapter). In addition to the essential variables named in the ASME Code, the following must be considered as essential variables: number of passes, thickness of plate, heat input per pass, and the specified rod and flux. The number of passes, thickness of plate and heat input per pass may not vary more than 25% from the procedure qualification. Records of the qualification must be retained for at least 5 years by the portable tank manufacturer and made available to the approval agency and the owner of the portable tank as specified in Sec. 178.273. (4) Shells and jackets must be made of metallic materials suitable for forming. Jackets must be made of steel. Non-metallic materials may be used for the attachments and supports between the shell and jacket, provided their material properties at the minimum design temperature are proven to be sufficient. In choosing the material, the minimum design temperature must be taken into account with respect to risk of brittle fracture, to hydrogen embrittlement, to stress corrosion cracking and to resistance to impact. (5) Any part of a portable tank, including fittings, gaskets and pipe-work, which can be expected normally to come into contact with the refrigerated liquefied gas transported must be compatible with that refrigerated liquefied gas. (6) The thermal insulation system must include a complete covering of the shell with effective insulating materials. External insulation must be protected by a jacket so as to prevent the ingress of moisture and other damage under normal transport conditions. (7) When a jacket is so closed as to be gas-tight, a device must be provided to prevent any dangerous pressure from developing in the insulation space. (8) Materials which may react with oxygen or oxygen enriched atmospheres in a dangerous manner may not be used in portable tanks intended for the trans#
Passage 451port of refrigerated liquefied gases having a boiling point below minus 182 deg.C at atmospheric pressure in locations with the thermal insulation where there is a risk of contact with oxygen or with oxygen enriched fluid. (9) Insulating materials must not deteriorate to an extent that the effectiveness of the insulation system, as determined in accordance with paragraph (b)(11) of this section, would be reduced in service. (10) A reference holding time must be determined for each refrigerated liquefied gas intended for transport in a portable tank. The reference holding time must be determined by testing in accordance with the requirements of Sec. 178.338-9, considering the following factors: (i) The effectiveness of the insulation system, determined in accordance with paragraph (b)(11) of this section; (ii) The lowest set pressure of the pressure limiting device; (iii) The initial filling conditions; (iv) An assumed ambient temperature of 30 deg.C (86 deg.F); (v) The physical properties of the individual refrigerated liquefied gas intended to be transported. (11) The effectiveness of the insulation system (heat influx in watts) may be determined by type testing the portable tank in accordance with a procedure specified in Sec. 178.338-9(c) or by using the holding time test in Sec. 178.338-9(b). This test must consist of either: (i) A constant pressure test (for example, at atmospheric pressure) when the loss of refrigerated liquefied gas is measured over a period of time; or (ii) A closed system test when the rise in pressure in the shell is measured over a period of time. (12) When performing the constant pressure test, variations in atmospheric pressure must be taken into account. When performing either test, corrections must be made for any variation of the ambient temperature from the assumed ambient temperature reference value of 30 deg.C (86 deg.F). (13) The jacket of a vacuum-insulated double-wall tank must have either an external design pressure not less than 100 kPa (1 bar) gauge pressure calculated in accordance with the ASME Code or a calculated critical collapsing pressure of not less than 200 kPa (2 bar) gauge pressure. Internal and external reinforcements may be included in calculating the ability of the jacket to resist the external pressure.#
Passage 452Note to Paragraph (b): For the determination of the actual holding time, as indicated by paragraphs (b)(10), (11), (12), and (13), before each journey, refer to Sec. 178.338-9(b).#
Passage 453(c) Design criteria. For shells with vacuum insulation, the test pressure must not be less than 1.3 times the sum of the MAWP and 100 kPa (1 bar). In no case may the test pressure be less than 300 kPa (3 bar) gauge pressure. (d) Service equipment. (1) Each filling and discharge opening in portable tanks used for the transport of flammable refrigerated liquefied gases must be fitted with at least three mutually independent shut-off devices in series: the first being a stop-valve situated as close as reasonably practicable to the jacket, the second being a stop- valve and the third being a blank flange or equivalent device. The shut-off device closest to the jacket must be a self-closing device, which is capable of being closed from an accessible position on the portable tank that is remote from the valve within 30 seconds of actuation. This device must actuate at a temperature of not more than 121 deg.C (250 deg.F). (2) Each filling and discharge opening in portable tanks used for the transport of non-flammable refrigerated liquefied gases must be fitted with at least two mutually independent shut-off devices in series: the first being a stop-valve situated as close as reasonably practicable to the jacket and the second a blank flange or equivalent device. (3) For sections of piping which can be closed at both ends and where liquid product can be trapped, a method of automatic pressure relief must be provided to prevent excess pressure build-up within the piping. (4) Each filling and discharge opening on a portable tank must be clearly marked to indicate its function. (5) When pressure-building units are used, the liquid and vapor connections to that unit must be provided with a valve as close to the jacket as reasonably practicable to prevent the loss of contents in case of damage to the pressure-building unit. A check valve may be used for this purpose if it is located on the vapor side of the pressure build-up coil. (6) The materials of construction of valves and accessories must have satisfactory properties at the lowest operating temperature of the portable tank. (7) Vacuum insulated portable tanks are not required to have an inspection opening. (e) Pressure relief devices. (1) Every shell must be provided with not less than two independent reclosing pressure relief devices. The pressure relief devices must open automatically at a pressure not less than#
Passage 454the MAWP and be fully open at a pressure equal to 110% of the MAWP. These devices must, after discharge, close at a pressure not lower than 10% below the pressure at which discharge starts and must remain closed at all lower pressures. The pressure relief devices must be of the type that will resist dynamic forces including surge. (2) Except for portable tanks used for oxygen, portable tanks for non-flammable refrigerated liquefied gases (except oxygen) and hydrogen may in addition have frangible discs in parallel with the reclosing devices as specified in paragraphs (e)(4)(ii) and (e)(4)(iii) of this section. (3) Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure. (4) Capacity and setting of pressure relief devices. (i) In the case of the loss of vacuum in a vacuum-insulated tank or of loss of 20% of the insulation of a portable tank insulated with solid materials, the combined capacity of all pressure relief devices installed must be sufficient so that the pressure (including accumulation) inside the shell does not exceed 120% of the MAWP. (ii) For non-flammable refrigerated liquefied gases (except oxygen) and hydrogen, this capacity may be achieved by the use of frangible discs in parallel with the required safety-relief devices. Frangible discs must rupture at nominal pressure equal to the test pressure of the shell. (iii) Under the circumstances described in paragraphs (e)(4)(i) and (e)(4)(ii) of this section, together with complete fire engulfment, the combined capacity of all pressure relief devices installed must be sufficient to limit the pressure in the shell to the test pressure. (iv) The required capacity of the relief devices must be calculated in accordance with CGA Pamphlet S-1.2 (see Sec. 171.7 of this subchapter). 75. In Sec. 178.703, the section heading and paragraph (a)(1) introductory text are revised and in paragraph (a)(1)(ii), a new sentence is added at the end of the paragraph to read as follows:#
Passage 455(a) * * * (1) Mark every IBC in a durable and clearly visible manner. The marking may be applied in a single line or in multiple lines provided the correct sequence is followed with the information required by this section in letters, numerals and symbols of at least 12 mm in height. This minimum marking size applies only to IBCs manufactured after October 1, 2001). The following information is required in the sequence presented: * * * * * (ii) * * * The letter ``W'' must follow the IBC design type identification code on an IBC when the IBC differs from the requirements in subpart N of this part, or is tested using methods other than those specified in this subpart, and is approved by the Associate Administrator in accordance with the provisions in Sec. 178.801(i). * * * * * 76. In Sec. 178.705, the section heading and paragraph (c)(1)(iv)(A) are revised and a new paragraph (c)(1)(iv)(C) is added to read as follows: * * * * * (c) * * * (1) * * * (iv) * * * (A) For a reference steel having a product of Rm X Ao = 10,000, where Ao is the minimum elongation (as a percentage) of the reference steel to be used on fracture under tensile stress, (Rm X Ao = 10,000 X 145; if tensile strength is in U.S. Standard units of pounds per square inch) the wall thickness must not be less than: -------------------------------------------------------------------------------------------------------------------------------------------------------- Wall thickness (T) in mm ------------------------------------------------------------------------------------------------------------------------- Capacity (C) in liters \1\ Types 21A, 21B, 21N, 31A, 31B, 31N Types 11A, 11B, 11N --------------------------------------------------------------------------------------------- Unprotected Protected Unprotected Protected ----------------------------------------------------------------------------------------------------------------------------------------------- ----------- C 1000............... 2.0 1.5 2.5 2.0 1000 C 2000......... T=C/2000 + 1.5 T=C/2000 + 1.0 T=C/2000 + 2.0 T=C/2000 + 1.5 2000 C 3000......... T=C/2000 + 1.5 T=C/2000 + 1.0 T=C/1000 + 1.0 T=C/2000 + 1.5 -------------------------------------------------------------------------------------------------------------------------------------------------------- \1\ Where: gallons = liters X 0.264.#
Passage 456* * * * * (C) For purposes of the calculation described in paragraph (c)(1)(iv)(B) of this section, the guaranteed minimum tensile strength of the metal to be used (Rm1) must be the minimum value according to material standards. However, for austenitic (stainless) steels, the specified minimum value for Rm, according to the material standards, may be increased by up to 15% when a greater value is provided in the material inspection certificate. When no material standard exists for the material in question, the value of Rm must be the minimum value indicated in the material inspection certificate. * * * * * 77. In Sec. 178.801, in paragraph (i), two sentences are added at the end of the paragraph to read as follows: * * * * * (i) * * * A large packaging, as defined in Sec. 171.8 of this subchapter, may be used if approved by the Associate Administrator. The large packaging must conform to the construction standards, performance testing and packaging marking requirements specified in the UN Recommendations. * * * * * 78. In Sec. 178.812, paragraph (c)(1) is revised and a new paragraph (c)(3) is added to read as follows: * * * * * (c) Test method. (1) A metal or flexible IBC must be lifted in the manner for which it is designed until clear of the floor and maintained in that position for a period of five minutes. * * * * * (3) If not tested as indicated in paragraph (c)(1) of this section, a flexible IBC design type must be tested as follows: (i) Fill the flexible IBC to 95% full with a material representative of the product to be shipped. (ii) Suspend the flexible IBC by its lifting devices. (iii) Apply a constant downward force through a specially designed platen. The platen will be a minimum of 60% and a maximum of 80% of the cross sectional surface area of the flexible IBC. (iv) The combination of the mass of the filled flexible IBC and the force applied through the platen must be a minimum of six times the maximum net mass of the flexible IBC. The test must be conducted for a period of five minutes. (v) Other equally effective methods of top lift testing and preparation may be used with approval of the Associate Administrator. * * * * * 79. The authority citation for part 179 continues to read as follows: Authority: 49 U.S.C. 5105-5127; 49 CFR 1.53.#
Passage 45780. In Sec. 179.102-4, in the introductory text, the wording ``vinyl fluoride, inhibited'' is revised to read ``vinyl fluoride, stabilized''. PART 180--CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS 81. The authority citation for part 180 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 82. Subpart G is added to part 180 to read as follows: Subpart G--Qualification and Maintenance of Portable Tanks Sec. 180.601 Applicability. 180.603 Qualification of portable tanks. 180.605 Requirements for periodic testing, inspection and repair of portable tanks. Subpart G--Qualification and Maintenance of Portable Tanks This subpart prescribes requirements, in addition to those contained in parts 107, 171, 172, 173, and 178 of this subchapter, applicable to any person responsible for the continuing qualification, maintenance or periodic retesting of a portable tank. Sec. 180.603 Qualification of portable tanks. (a) Each portable tank used for the transportation of hazardous materials must be an authorized packaging. (b) To qualify as an authorized packaging, each portable tank must conform to the requirements of this subchapter and the applicable design specification to which the portable tank was constructed. (c) The following portable tanks are authorized for use provided they conform to all applicable safety requirements of this subchapter: 51, 56, 57, 60, IM 101, IM 102 and UN portable tanks. (d) A portable tank that also meets the definition of ``container'' in 49 CFR 450.3(a)(3) must conform to the requirements in parts 450 through 453 of this title for compliance with Annex II of the Convention for Safe Containers (CSC). (e) Exemption portable tanks based on DOT 51 portable tanks. The owner of a portable tank constructed in accordance with and used under an exemption issued prior to August 31, 1996, which was in conformance with the requirements for Specification DOT 51 portable tanks with the exception of the#
Passage 458location of fill and discharge outlets, shall examine the portable tank and its design to determine if it meets the outletrequirements in effect on October 1, 1996. If the owner determines that the portable tank is in compliance with all requirements of the DOT 51 specification, the exemption number stenciled on the portable tank shall be removed and the specification plate (or a plate placed adjacent to the specification plate) shall be durably marked ``DOT 51- E*****'' (where ***** is to be replaced by the exemption number). During the period the portable tank is in service, and for one year thereafter, the owner of the portable tank must retain on file, at its principal place of business, a copy of the last exemption in effect. Sec. 180.605 Requirements for periodic testing, inspection and repair of portable tanks.#
Passage 459(a) A portable tank constructed in accordance with a DOT specification for which a test or inspection specified in this subpart has become due, must be tested or inspected prior to being returned for transportation. (b) Conditions requiring test and inspection of portable tanks. Without regard to any other test or inspection requirements, a Specification or UN portable tank must be tested and inspected in accordance with this section prior to further use if any of the following conditions exist: (1) The portable tank shows evidence of dents, corroded or abraded areas, leakage, or any other condition that might render it unsafe for transportation service. (2) The portable tank has been in an accident and has been damaged to an extent that may adversely affect its ability to retain the hazardous material. (3) The portable tank has been out of hazardous materials transportation service for a period of one year or more. (4) The portable tank has been modified from its original design specification. (5) The portable tank is in an unsafe operating condition based on the existence of probable cause. (c) Schedule for periodic inspections and tests. Each Specification portable tank must be tested and inspected in accordance with the following schedule: (1) Each IM or UN portable tank must be given an initial inspection and test before being placed into service, a periodic inspection and test at least once every 5 years, and an intermediate periodic inspection and test at least every 2.5 years following the initial inspection and the last 5 year periodic inspection and test. (2) Each Specification 51 portable tank must be given a periodic inspection and test at least once every five years. (3) Each Specification 56 or 57 portable tank must be given a periodic inspection and test at least once every 2.5 years. (4) Each Specification 60 portable tank must be given a periodic inspection and test at the end of the first 4-year period after the original test; at least once every 2 years thereafter up to a total of 12 years of service; and at least once annually thereafter. Retesting is not required on a rubber-lined tank except before each relining. (d) Intermediate periodic inspection and test. For IM and UN portable tanks the intermediate 2.5 year periodic inspection and test must include at least an internal and external examination of the portable tank and its fittings#
Passage 460taking into account the hazardous materials intended to be transported; a leakage test; and a test of the satisfactory operation of all service equipment. Sheathing, thermal insulation, etc. need only be removed to the extent required for reliable appraisal of the condition of the portable tank. For portable tanks intended for the transportation of a single hazardous material, the internal examination may be waived if it is leakage tested in accordance with the procedures in paragraph (i) of this section prior to each filling, or if approved by the Associate Administrator. Portable tanks used for dedicated transportation of refrigerated liquefied gases that are not fitted with inspection openings are excepted from the internal inspection requirement. (e) Periodic inspection and test. The 5 year periodic inspection and test must include an internal and external examination and, unless excepted, a pressure test as specified in this section. Sheathing, thermal insulation, etc. need only to be removed to the extent required for reliable appraisal of the condition of the portable tank. Except for DOT Specification 56 and 57 portable tanks, reclosing pressure relief devices must be removed from the tank and tested separately unless they can be tested while installed on the portable tank. For portable tanks where the shell and equipment have been pressure-tested separately, after assembly they must be subjected together to a leakage test and effectively tested and inspected for corrosion. Portable tanks used for the transportation of refrigerated, liquefied gases are excepted from the requirement for internal inspection and the hydraulic pressure test if the portable tanks are pressure tested using an inert gas as prescribed in Sec. 178.338-16(a) and (b) of this subchapter. (f) Exceptional inspection and test. The exceptional inspection and test is necessary when a portable tank shows evidence of damaged or corroded areas, or leakage, or other conditions that indicate a deficiency that could affect the integrity of the portable tank. The extent of the exceptional inspection and test must depend on the amount of damage or deterioration of the portable tank. It must include at least the inspection and a pressure test according to paragraph (e) of this section. Pressure relief devices need not be tested or replaced unless there is reason to believe the relief devices#
Passage 461have been affected by the damage or deterioration. (g) Internal and external examination. The internal and external examinations must ensure that: (1) The shell is inspected for pitting, corrosion, or abrasions, dents, distortions, defects in welds or any other conditions, including leakage, that might render the portable tank unsafe for transportation; (2) The piping, valves, and gaskets are inspected for corroded areas, defects, and other conditions, including leakage, that might render the portable tank unsafe for filling, discharge or transportation; (3) Devices for tightening manhole covers are operative and there is no leakage at manhole covers or gaskets; (4) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened; (5) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves must be operated to demonstrate proper operation; (6) Required markings on the portable tank are legible and in accordance with the applicable requirements; and (7) The framework, the supports and the arrangements for lifting the portable tank are in satisfactory condition. (h) Pressure test procedures for specification 51, 57, 60, IM or UN portable tanks. (1) Each Specification 57 portable tank must be leak tested by a minimum sustained air pressure of at least 3 psig applied to the entire tank. Each Specification 51 or 56 portable tank must be tested by a minimum pressure (air or hydrostatic) of at least 2 psig or at least one and one-half times the design pressure (maximum allowable working pressure, or re-rated pressure) of the tank, whichever is greater. The leakage test for portable tanks used for refrigerated liquefied gas must be performed at 90% of MAWP. Leakage tests for all other portable tanks must be at a pressure of at least 25% of#
Passage 462MAWP. During each air pressure test, the entire surface of all joints under pressure must be coated with or immersed in a solution of soap and water, heavy oil, or other material suitable for the purpose of detecting leaks. The pressure must be held for a period of time sufficiently long to assure detection of leaks, but in no case less than five minutes. During the air or hydrostatic test, relief devices may be removed, but all the closure fittings must be in place and the relief device openings plugged. Lagging need not be removed from a lagged tank if it is possible to maintain the required test pressure at constant temperature with the tank disconnected from the source of pressure. (2) Each Specification 60 portable tank must be retested by completely filling the tank with water or other liquid having a similar viscosity, the temperature of the liquid must not exceed 37.7 deg.C (100 deg.F) during the test, and applying a pressure of 60 psig. The portable tank must be capable of holding the prescribed pressure for at least 10 minutes without leakage, evidence of impending failure, or failure. All closures shall be in place while the test is made and the pressure shall be gauged at the top of the tank. Safety devices and/or vents shall be plugged during this test. (3) Each Specification IM or UN portable tank, except for UN portable tanks used for non-refrigerated and refrigerated liquefied gases, and all piping, valves and accessories, except pressure relief devices, must be hydrostatically tested with water, or other liquid of similar density and viscosity, to a pressure not less than 150% of its maximum allowable working pressure. UN portable tanks used for the transportation of non-refrigerated liquefied gases must be hydrostatically tested with water, or other liquid of similar density and viscosity, to a pressure not less than 130% of its maximum allowable working pressure. UN portable tanks used for the transportation of refrigerated liquefied gases may be tested hydrostatically or pneumatically using an inert gas. For pneumatic testing, due regard for protection of all personnel must be taken because of the potential hazard involved in such a test. The pneumatic test pressure in the portable tank must be reached by gradually increasing the pressure to one-half of the test pressure. Thereafter, the test pressure must be increased in steps of approxi#
Passage 463mately one-tenth of the test pressure until the required test pressure has been reached. The pressure must then be reduced to a value equal to four-fifths of the test pressure and held for a sufficient time to permit inspection of the portable tank for leaks. The minimum test pressure for a portable tank is determined on the basis of the hazardous materials that are intended to be transported in the portable tanks. For liquid, solid and non-refrigerated liquefied gases, the minimum test pressure for specific hazardous materials are specified in the applicable T Codes assigned to a particular hazardous material in the Sec. 172.101 Table of this subchapter. While under pressure the tank shall be inspected for leakage, distortion, or any other condition which might render the tank unsafe for service. A portable tank fails to meet the requirements of the pressure test if, during the test, there is permanent distortion of the tank exceeding that permitted by the applicable specification; if there is any leakage; or if there are any deficiencies that would render the portable tank unsafe for transportation. Any portable tank that fails must be rejected and may not be used again for the transportation of a hazardous material unless the tank is adequately repaired, and, thereafter, a successful test is conducted in accordance with the requirements of this paragraph. An approval agency shall witness the hydrostatic or pneumatic test. Any damage or deficiency that might render the portable tank unsafe for service shall be repaired to the satisfaction of the witnessing approval agency. The repaired tank must be retested to the original pressure test requirements. Upon successful completion of the hydrostatic or pneumatic test, as applicable, the witnessing approval agency shall apply its name, identifying mark or identifying number in accordance with paragraph (k) of this section. (i) Rejection criteria. When evidence of any unsafe condition is discovered, the portable tank may not be returned to service until it has been repaired and the pressure test is repeated and passed. (j) Repair. The repair of a portable tank is authorized, provided such repairs are made in accordance with the requirements prescribed in the specification for the tank's original design and construction. In addition to any other provisions of the specification, no portable tank may be repaired so#
Passage 464as to cause leakage or cracks or so as to increase the likelihood of leakage or cracks near areas of stress concentration due to cooling metal shrinkage in welding operations, sharp fillets, reversal of stresses, or otherwise. No field welding may be done except to non-pressure parts. Any cutting, burning or welding operations on the shell of an IM or UN portable tank must be done with the approval of the approval agency and be done in accordance with the requirements of this subchapter, taking into account the pressure vessel code used for the construction of the shell. A pressure test to the original test pressure must be performed after the work is completed. (k) Inspection and test markings. Each IM or UN portable tank must be durably and legibly marked, in English, with the date (month and year) of the last pressure test, the identification markings of the approval agency witnessing the test, when required, and the date of the last visual inspection. The marking must be placed on or near the metal identification plate, in letters not less than 3 mm (0.118 inches) high when on the metal identification plate, and 12 mm (0.5 inches) high when on the portable tank. (l) Record retention. The owner of each portable tank or his authorized agent shall retain a written record of the date and results of all required inspections and tests, including an ASME manufacturer's date report, if applicable, and the name and address of the person performing the inspection or test, in accordance with the applicable specification. The manufacturer's data report, including a certificate(s) signed by the manufacturer, and the authorized design approval agency, as applicable, indicating compliance with the applicable specification of the portable tank, must be retained in the files of the owner, or his authorized agent, during the time that such portable tank is used for such service, except for Specifications 56 and 57 portable tanks. Issued in Washington, DC, on May 25, 2001, under authority delegated in 49 CFR part 1. Edward A. Brigham, Acting Deputy Administrator. [FR Doc. 01-13836 Filed 6-14-01; 9:34 am] BILLING CODE 4910-60-P#
This material provides agency context. It does not replace binding regulatory text, and its legal effect depends on the underlying authority and facts.