RegulusPipeline research69 FR 34724
Passage 1[Federal Register Volume 69, Number 119 (Tuesday, June 22, 2004)] [Proposed Rules] [Pages 34724-34857] From the Federal Register Online via the Government Publishing Office [www.gpo.gov] [FR Doc No: 04-12411] ----------------------------------------------------------------------- ----------------------------------------------------------------------- Research and Special Programs Administration ----------------------------------------------------------------------- 49 CFR Parts 171, 172, 173, 175, 176, 178 and 180 Harmonization With the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions; Proposed Rule Federal Register / Vol. 69, No. 119 / Tuesday, June 22, 2004 / Proposed Rules ----------------------------------------------------------------------- Research and Special Programs Administration 49 CFR Parts 171, 172, 173, 175, 176, 178 and 180 [Docket No. RSPA-04-17036 (HM-215G)] RIN 2137-AD92 Harmonization With the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions AGENCY: Research and Special Programs Administration (RSPA), DOT. ACTION: Notice of proposed rulemaking (NPRM). ----------------------------------------------------------------------- SUMMARY: RSPA is proposing to amend the Hazardous Materials Regulations (HMR) to maintain alignment with international standards by incorporating various amendments, including changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. Because of recent changes to the International Maritime Dangerous Goods Code (IMDG Code), the International Civil Aviation Organization's Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), and the United Nations Recommendations on the Transport of Dangerous Goods (UN Recommendations), these revisions are necessary to facilitate the transport of hazardous materials in international commerce. DATES: Comments must be received by August 23, 2004.#
Passage 2ADDRESSES: Address your comments to the Dockets Management System, U.S. Department of Transportation, 400 Seventh St., SW., Room PL 402, Washington, DC 20590. Comments. You may submit comments identified by the docket number (RSPA-04-17036) by any of the following methods: Federal eRulemaking Portal: http://www.regulations.gov. Follow the online instructions for submitting comments. Web site: http://dms.dot.gov. Follow the instructions for submitting comments on the DOT electronic docket site. Fax: 1-202-493-2251. Mail: Docket Management System; U.S. Department of Transportation, 400 Seventh Street, SW., Nassif Building, Room PL-402, Washington, DC 20590-001. Hand Delivery: To the Docket Management System; Room PL- 402 on the plaza level of the Nassif Building, 400 Seventh Street, SW., Washington, DC between 9 a.m. and 5 p.m., Monday through Friday, except Federal holidays. Instructions: All submissions must include the agency name and docket number or Regulatory Identification Number (RIN) for this notice. For detailed instructions on submitting comments and additional information on the rulemaking process, see the Public Participation heading of the SUPPLEMENTARY INFORMATION section of this document. Note that all comments received will be posted without change to http://dms.dot.gov including any personal information provided. Please see the Privacy Act heading under SUPPLEMENTARY INFORMATION. Docket: For access to the docket to read background documents or comments received, go to http://dms.dot.gov at any time or to the Docket Management System (see ADDRESSES). FOR FURTHER INFORMATION CONTACT: Charles Betts, Office of Hazardous Materials Standards, telephone (202) 366-8553, or Shane Kelley, International Standards, telephone (202) 366-0656, Research and Special Programs Administration, U.S. Department of Transportation, 400 Seventh Street, SW., Washington, DC 20590-0001.#
Passage 3I. Background II. Overview of Proposed Changes in this NPRM III. Overview of Amendments Not Being Considered for Adoption in this NPRM IV. Section-by-Section Review V. Regulatory Analyses and Notices A. Executive Order 12866 and DOT Regulatory Policies and Procedures B. Executive Order 13132 C. Executive Order 13175 D. Regulatory Flexibility Act, Executive Order 13272, and DOT Regulatory Policies and Procedures E. Paperwork Reduction Act F. Regulatory Identifier Number (RIN) G. Unfunded Mandates Reform Act H. Environmental Assessment I. Privacy Act#
Passage 4On December 21, 1990, RSPA (we) published a final rule (Docket HM- 181; 55 FR 52402) based on the UN Recommendations, which comprehensively revised the Hazardous Materials Regulations (HMR), 49 CFR parts 171 to 180, for harmonization with international standards. Since publication of the 1990 final rule, we have issued five additional international harmonization final rules (Dockets HM-215A, 59 FR 67390; HM-215B, 62 FR 24690; HM-215C, 64 FR 10742; HM-215D, 66 FR 33316; and HM-215E, 68 FR 44992). The rules provided additional harmonization with international transportation requirements by more fully aligning the HMR with the corresponding biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions. The UN Recommendations are not regulations, but rather are recommendations issued by the UN Committee of Experts on the Transport of Dangerous Goods (TDG) and on the Globally Harmonized System of Classification and Labeling (GHS). These recommendations are amended and updated biennially by the UN Committee of Experts. They serve as the basis for National, regional, and international modal regulations; specifically, the IMDG Code issued by the International Maritime Organization (IMO), and the ICAO Technical Instructions issued by the ICAO. In 49 CFR 171.12, the HMR authorize domestic transportation of hazardous materials shipments prepared in accordance with the IMDG Code if all or part of the transportation is by vessel, subject to certain conditions and limitations. In Sec. 171.11, subject to certain conditions and limitations, the HMR authorize the offering, acceptance and transport of hazardous materials by aircraft, and by motor vehicle either before or after being transported by aircraft, provided the shipment is in accordance with the ICAO Technical Instructions. The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation and at the same time ensures the safety of people, property and the environment. While the intent of the harmonization rulemakings is to align the HMR with international standards, we review and consider each amendment on its own merit. Each amendment is considered on the basis of the overall impact on transp#
Passage 5ortation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without sacrificing the current HMR level of safety and without imposing undue burdens on the regulated public. In our efforts to continue to align the HMR with international requirements, this notice of proposed rulemaking (NPRM) proposes changes to the HMR based on the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. Petitions for rulemaking concerning harmonization with international standards and the facilitation of international transportation are also addressed in this NPRM and serve as the basis of certain proposed amendments. Other proposed amendments are based on feedback from the regulated industry, other DOT modal administrations and our initiative. Also included are various proposed editorial clarifications. Unless otherwise stated, the proposed revisions are for harmonization with international standards. II. Overview of Proposed Changes in This NPRM#
Passage 6Proposed amendments to the HMR in this NPRM include, but are not limited to the following: Amendments to the Hazardous Materials Table (HMT) which would add, revise or remove certain proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, bulk packaging requirements, passenger and cargo aircraft maximum quantity limitations and vessel stowage provisions. Amendments to the List of Marine Pollutants. Revisions and additions of special provisions. Removal of the air eligibility marking requirement. Addition of a ``KEEP AWAY FROM HEAT'' marking requirement for packages offered for transportation by air. Amendment to require that aerosol cans that are carried aboard an aircraft in accordance with Sec. 175.10(a)(4) have their release devices protected by a cap or other suitable means. A grandfather provision to allow the shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72. A provision to require that the word ``overpack'' be marked on overpacks to indicate that this marking implies that inside packages comply with prescribed specifications. An amendment to the criteria for classification of materials that are corrosive to metals. Revision of the limited quantity provisions for Class 6.1, PG II materials and other hazard classes of materials to take into account materials with a subsidiary hazard of 6.1, PG II. Amendments to the packaging requirements for materials classified as Division 6.1, Packing Group I, Hazard Zone A or Hazard Zone B. Revision of the organic peroxide packaging requirements in order to have one consolidated packaging section for organic peroxides. The revised section will include three separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs, respectively. Additionally, the packaging tables will be updated through the amendments to the organic peroxide requirements that will add, revise, or delete certain entries in the organic peroxide tables. III. Overview of Amendments Not Being Considered for Adoption in This NPRM#
Passage 7This NPRM proposes changes to the HMR based on amendments to the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. However, we are not proposing to adopt all of the amendments to those documents into the HMR. In many cases, amendments to the international regulation have not been adopted because of the framework or structure of the HMR. In several cases, we are handling certain amendments in separate rulemakings. For example, all amendments related to infectious substances are being handled under Docket HM-226A. In some instances, such as the amendment to ICAO TI to allow certain oxygen generators aboard passenger carrying aircraft, we do not believe the amendment to be in the interest of public safety. If we have inadvertently omitted an amendment in this NPRM, we will attempt to include the omission in the final rule. However, our options for making changes in a final rule are limited by requirements of the Administrative Procedures Act. In some instances, we can adopt a provision inadvertently omitted from the NPRM if it is clearly within the scope of changes proposed in the notice, does not require substantive changes from the international standard on which it is based, and imposes minimal or no cost impacts on persons subject to the requirement. Otherwise, in order to provide opportunity for notice and comment the change must be proposed in an NPRM. One of the goals of this rulemaking is to continue to maintain consistency between the HMR and the international requirements. We are not striving to ``match-up'' the HMR with the international regulations but rather striving to remove potential barriers to international transportation. Below is a listing of those significant amendments to the international regulations that we are not proposing to adopt into the HMR with a brief explanation why: Requirements for infectious substances and genetically modified micro-organisms; (Amendments to the HMR related to infectious substances will be addressed in a future rulemaking under Docket HM-226A. Several other Federal agencies regulate genetically modified micro-organisms; thus we do not plan to adopt provisions for their transport in the HMR.) Compressed gas cylinders; (Amendments to the HMR related to compressed gas cylinders will be addres#
Passage 8sed in a future rulemaking under Docket HM-220E.) Environmentally hazardous substances; (Delay in action pending further amendments to the international regulations.) Hazardous materials security; (Amendments to the HMR related to the UN Model Regulation's hazardous materials security requirements were promulgated in a rulemaking under the HM-232 Docket series.) Requirements for radioactive materials; (Amendments to the HMR related to Class 7 (radioactive) materials are being addressed in a rulemaking under the HM-230 Docket series.) Non-specification bulk packagings; (We are not adopting the new requirements in the UN Recommendations for non-specification bulk packagings including the additional inspection, testing and marking requirements. We are unsure about the cost impacts of imposing these additional amendments and, therefore, are not proposing to adopt any additional amendments at this time.) The reference to EN 10028-3, Part 3 for defining steel grain size relevant to the definition of fine grain steel; (We do not believe there is a need to adopt the European standard EN 10028-3, Part 3 because this standard is equivalent to ASTM E 112-96 (IBR, see Sec. 171.7 of this subchapter). In addition, the ASTM standard is currently referenced in the HMR and is more commonly used and recognized in the U.S.) Bulk authorization for UN0331, UN0332 and UN3375; (For several years, we have authorized, under exemption, the transport of certain blasting agents in bulk packagings. We are currently#
Passage 9reviewing those exemptions to determine if they should be included in the HMR. The amendments in the UN Recommendations related to the bulk authorizations for UN0331, UN0332 and UN3375 will be included in that review.) The removal of wooden barrel requirements; (The removal of the wooden barrel requirements (2C1 and 2C2) may be considered in a future rulemaking.) The 24-hour gasket relaxation requirement; (A requirement that removable head packagings for liquids not be drop tested until at least 24 hours after filling and closing to allow for any possible gasket relaxation was adopted in the thirteenth revised edition of the UN Model Regulations. We have conducted testing in coordination with drum manufacturers and have determined that this requirement is not substantiated by the results of the tests conducted. Therefore, we are not adopting into the HMR amendments relative to the 24-hour gasket relaxation requirement. We also opposed this requirement when it was considered by the UN TDG Sub-Committee.) Authorization to transport protective breathing equipment (PBE's) with an oxygen generator as cargo onboard a passenger-carrying aircraft. (We do not believe that oxygen generators should be transported aboard passenger carrying aircraft. Therefore, we are not adopting the ICAO amendment that would allow oxygen generators in protective breathing equipment to be transported in passenger carrying aircraft.)#
Passage 10Section 171.7 Paragraph (a)(3) (incorporation by reference materials) would be updated to include the most recent edition of the ICAO Technical Instructions, the IMDG Code and the UN Recommendations. The updated editions of these standards become effective January 1, 2005. Additionally, the International Maritime Organization (IMO) recommends authorizing a one-year transition period, with a delayed compliance date of January 1, 2006, for the use of the updated edition (Amendment 32) of the IMDG Code. The standards would be updated as follows: The ICAO Technical Instructions, 2005-2006 Edition. The IMDG Code, Amendment 32. The UN Recommendations, Thirteenth Edition. The UN Manual of Tests and Criteria, 4th Revised Edition. Paragraph (b) (list of informational materials not requiring incorporation by reference) would be revised by adding an additional reference for a new method for determining the size of an emergency- relief device for portable tanks transporting organic peroxides. This revision is based on a petition for rulemaking numbered P-1428. The petition was submitted by Mr. Lynne Harris for the Organic Peroxides Producers Safety Division of the Society of the Plastics Industry, Inc. The reference would be added as follows: The Society of the Plastics Industry, Inc., Organic Peroxide Producers Safety Division, 1801 K Street, NW., Suite 600K, Washington, DC 20006-1301. Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology. Section 171.8 The definition for ``salvage packaging'' would be revised to include the term ``non-conforming.'' The term ``non-conforming'' was added to the definition by the UN Committee of Experts in December 2000. In addition to situations involving damaged, defective or leaking packages of dangerous goods, occasionally an undamaged primary container is found to be tested to a performance level which is less than that required for the specific substance it contains (e.g., a drum tested to PG II standards containing a PG I substance). In other instances, the primary container is found to be a non-performance tested packaging containing a regulated substance. In these situations, it may not be safe or practical to transfer the material to the correct packaging to continue on to the consignee. Therefore, the use of salvage packaging to contain ``non-conforming'' packages will minimize the risk to those handling the packa#
Passage 11ge during its transport back to the shipper or to an appropriate disposal location. Section 171.11 Paragraph (d)(15) would be revised to clarify that the limitations therein also apply to oxygen generators contained in personal breathing equipment. In addition, paragraph (d)(17) would be revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in Sec. 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. Section 171.12 In Sec. 171.12, paragraph (b)(20) would be revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in Sec. 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. Section 171.12a Paragraph (a) would be revised to clarify the requirements for the return to Canada of bulk packagings that correspond to DOT or UN Specification. Paragraph (b)(9)(ii) would be revised to indicate that the shipping certification must be completed for shipments from Canada that enter the U.S. Paragraph (b)(18) would be revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in Sec. 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. Section 171.14 Paragraphs (d) and (d)(1) would be revised to authorize a delayed implementation date for the proposed amendments in this NPRM. We are proposing an effective date of October 1, 2004, and a voluntary compliance date of January 1, 2005, to correspond with the effective implementation dates of the 2005-2006 ICAO Technical Instructions and Amendment 32 of the IMDG Code. This authorization would allow shippers to prepare their international shipments in accordance with international standards that will become effective on January 1, 2005. We are also, proposing to authorize a delayed compliance date of January 1, 2006, which is comparable to the transitional provisions provided in the final rule published under Docket HM-215E. The delayed mandatory compliance date would offer sufficient time to implement the new requirements.#
Passage 12Paragraph (d)(2) would be revised to authorize certain intermixing of old and new requirements. Section 172.101 In the regulatory text preceding the Hazardous Materials Table, we are proposing the following changes: Paragraph (c)(11) and the corresponding note to paragraph (c)(11) would be amended to revise a section reference. The reference to Sec. 173.225(c) in the first sentence would be revised to read Sec. 173.225(b) and the reference to Sec. 173.225(c)(2) in the note to paragraph (c)(11) would be revised to read Sec. 173.225(b)(2). Paragraph (d)(4) would be revised by adding a statement indicating that when the abbreviation ``Comb liq.'' is found in the ``Hazard class of division'' column of the Hazardous Materials Table (column 3), the material falls into the ``Combustible liquid'' hazard class. Paragraph (i)(3) of this section would be revised to specify that Column 7 of the Hazardous Materials Table contains additional bulk packaging authorizations and limitations for the use of UN portable tanks. Section 172.101 The Hazardous Materials Table (HMT). We are proposing to make various amendments to the HMT. Readers should review all changes for a complete understanding of the proposed Table amendments. The HMT is being reprinted in its entirety due to the numerous changes. Proposed amendments to the HMT for the purpose of harmonizing with international standards, unless otherwise stated, include, but are not limited to the following: We propose to revise several entries by adding the qualifying word ``liquid.'' This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows: UN1392 Alkaline earth metal amalgam UN1420 Potassium metal alloys UN1422 Potassium sodium alloys UN1701 Xylyl bromide UN1742 Boron trifluoride acetic acid complex UN1743 Boron trifluoride propionic acid complex UN2235 Chlorobenzyl chlorides UN2236 3-Chloro-4-methylphenyl isocyanate UN2306 Nitrobenzotrifluorides UN2445 Lithium alkyls UN2552 Hexafluoroacetone hydrate UN2937 alpha-Methylbenzyl alcohol UN3276 Nitriles, toxic, n.o.s. UN3278 Organophosphorus compound, toxic, n.o.s. UN3280 Organoarsenic compound, n.o.s. UN3282 Organometallic compound, toxic, n.o.s. UN3281 Metal carbonyls, n.o.s.#
Passage 13We propose to revise several entries by adding the qualifying word ``solid.'' This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows: UN1445 Barium chlorate UN1447 Barium perchlorate UN1459 Chlorate and magnesium chloride mixture UN1470 Lead perchlorate UN1578 Chloronitrobenzenes UN1579 4-Chloro-o-toluidine hydrochloride UN1650 beta-Naphthylamine UN1680 Potassium cyanide UN1689 Sodium cyanide UN1690 Sodium fluoride UN1697 Chloroacetophenone UN1709 2,4-Toluylenediamine UN1812 Potassium fluoride UN1843 Ammonium dinitro-o-cresolate UN2074 Acrylamide UN2239 Chlorotoluidines UN2261 Xylenols UN2446 Nitrocresols UN2662 Hydroquinone UN3283 Selenium compound, n.o.s. We propose to revise several entries by removing the qualifying word ``solid.'' This action would provide consistency with the Thirteenth Revised Edition of the UN Recommendations and enable us to remove all corresponding solution entries. The affected entries would be as follows: UN1489 Potassium perchlorate, solid UN1598 Dinitro-o-cresol, solid UN1638 Mercury iodide, solid UN1740 Hydrogendifluorides, n.o.s. solid UN2439 Sodium hydrogendifluoride, solid We propose to delete several entries. This action would remove from the HMR the solution form of entries that are not identified as solutions in the Thirteenth Revised Edition of the UN Recommendations. The deleted entries would be as follows: UN1489 Potassium perchlorate, solution UN1598 Dinitro-o-cresol, solution UN1638 Mercury iodide, solution UN1740 Hydrogendifluorides, n.o.s. solutions UN2439 Sodium hydrogendifluoride solution#
Passage 14We propose to revise the proper shipping name ``Butadienes, stabilized,'' UN1010 to read ``Butadienes, stabilized or Butadienes and hydrocarbon mixture, stabilized, containing more than 40% butadienes.'' We propose to revise the proper shipping name ``Potassium hydrogendifluoride, solid,'' UN1811 to read ``Potassium hydrogendifluoride, solid.'' We propose to revise the proper shipping name ``Refrigerating machines, containing non-flammable, non-toxic, liquefied gas or ammonia solution (UN2672),'' UN2857 to read ``Refrigerating machines containing non-flammable, non-toxic gases or ammonia solutions (UN2672).'' Four references to IB52 and four references to T23 would be removed from column 7 of the HMT. This change is necessary because IB52 and T23 would be relocated to Sec. 173.225. The affected entries would be: UN3109 Organic peroxide type F, liquid UN3110 Organic peroxide type F, solid UN3119 Organic peroxide type F, liquid, temperature controlled UN3120 Organic peroxide type F, solid, temperature controlled IP5 would be removed from column 7 of the HMT for the following UN numbers: UN1791 Hypochlorite solution UN2014 Hydrogen peroxide, aqueous solution with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary). UN3149 Hydrogen peroxide and peroxyacetic acid mixture with acid(s), water and not more than 5% peroxyacetic acid. We propose to delete several entries. This action is consistent with the deletion of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations that we are proposing to adopt into the HMR. The entries identified by corresponding ``UN'' numbers are: UN2003 Metal alkyls, water-reactive, n.o.s. or Metal aryls, water- reactive, n.o.s. UN3049 Metal alkyl halides, water-reactive, n.o.s. or Metal aryl halides, water-reactive, n.o.s. UN3050 Metal alkyl hydrides, water-reactive, n.o.s. or Metal aryl hydrides, water-reactive, n.o.s. UN3207 Organometallic compound or Compound solution or Compound dispersion, water-reactive, flammable, n.o.s. UN3203 Pyrophoric organometallic compound, water-reactive, n.o.s., liquid Pyrophoric organometallic compound, water-reactive, n.o.s., solid UN3372 Organometallic compound, solid, water-reactive, flammable, n.o.s.#
Passage 15We propose to add the following new entries. Many of these entries are the liquid or solid form of entries that are already listed in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows: UN3377 Sodium perborate monohydrate UN3378 Sodium carbonate peroxyhydrate UN3379 Desensitized explosives, liquid, n.o.s. UN3380 Desensitized explosives, solid, n.o.s. UN3401 Alkali metal amalgam, solid UN3402 Alkaline earth metal amalgam, solid UN3403 Potassium metal alloys, solid UN3404 Potassium sodium alloys, solid#
Passage 16UN3405 Barium chlorate solution UN3406 Barium perchlorate solution UN3407 Chlorate and magnesium chloride mixture solution UN3408 Lead perchlorate solution UN3409 Chloronitrobenzenes, liquid UN3410 4-Chloro-o-toluidine hydrochloride solution UN3411 beta-Naphthylamine solution UN3413 Potassium cyanide solution UN3414 Sodium cyanide solution UN3415 Sodium fluoride solution UN3416 Chloroacetophenone, liquid UN3417 Xylyl bromide, solid UN3418 2,4-Toluylenediamine solution UN3419 Boron trifluoride acetic acid complex, solid UN3420 Boron trifluoride propionic, acid complex, solid UN3421 Potassium hydrogendifluoride solution UN3422 Potassium fluoride solution UN3423 Tetramethylammonium hydroxide, solid UN3424 Ammonium dinitro-o-cresolate solution UN3425 Bromoacetic acid, solid UN3426 Acrylamide solution UN3427 Chlorobenzyl chlorides, solid UN3428 3-Chloro-4-Methylphenyl isocyanate, solid UN3429 Chloro-toluidines, liquid UN3430 Xylenols, liquids UN3431 Nitrobenzotrifluorides, solid UN3432 Polychlorinated biphenyls, solid UN3433 Lithium alkyls, solid UN3434 Nitrocresols, liquid UN3435 Hydroquinone solution UN3436 Hexafluoroacetone hydrate, solid UN3437 Chlorocresols, solid UN3438 alpha-Methylbenzyl alcohol, solid UN3439 Nitriles, toxic, solid, n.o.s. UN3440 Selenium compound, liquid, n.o.s. UN3441 Chlorodinitrobenzenes, solid UN3442 Dichloroanilines, solid UN3443 Dinitrobenzenes, solid UN3444 Nicotine hydrochloride, solid UN3445 Nicotine sulphate, solid UN3446 Nitrotoluenes, solid UN3447 Nitroxylenes, solid UN3448 Tear gas substance, solid, n.o.s. UN3449 Bromobenzyl cyanides, solid UN3450 Diphenylchloroarsine, solid UN3451 Toluidines, solid UN3452 Xylidines, solid UN3453 Phosphoric acid, solid UN3454 Dinitrotoluenes, solid UN3455 Cresols, solid UN3456 Nitrosyl-sulphuric acid, solid UN3457 Chloronitrotoluenes, solid UN3458 Nitroanisoles, solid UN3459 Nitrobromobenzenes, solid UN3460 N-Ethylbenzyltoluidines, solid UN3461 Aluminium alkyl halides, solid UN3462 Toxins, extracted from living sources, solid, n.o.s. UN3464 Organophosphorus compound, toxic, solid, n.o.s. UN3465 Organoarsenic compound, solid, n.o.s. UN3466 Metal carbonyls, solid, n.o.s. UN3467 Organometallic compound, toxic, solid, n.o.s. UN3468 Hydrogen in a metal hydride storage system#
Passage 17We propose to add the following new generic entries for materials that are poisonous by inhalation. These new names will replace the existing generic entries in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows: UN3381 Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50. UN3382 Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50. UN3383 Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50. UN3384 Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50. UN3385 Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50. UN3386 Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50. UN3387 Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50. UN3388 Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m 3 3 3 3 3 3 and saturated vapor concentration greater than or equal to 10 LC50. UN3389 Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50. UN3390 Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50.#
Passage 18We propose to add the following new generic entries for organometallic substances. We are not proposing to adopt the ``Flowchart scheme for organometallic substances'' because we believe that it is intuitive based on the hazard class precedence system in the HMR. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows: UN3391 Organometallic substance, solid, pyrophoric UN3392 Organometallic substance, liquid, pyrophoric UN3393 Organometallic substance, solid, pyrophoric, water-reactive UN3394 Organometallic substance, liquid, pyrophoric, water-reactive UN3395 Organometallic substance, solid, water-reactive UN3396 Organometallic substance, solid, water-reactive, flammable UN3397 Organometallic substance, solid, water-reactive, self-heating UN3398 Organometallic substance, liquid, water-reactive UN3399 Organometallic substance, liquid, water-reactive, flammable UN3400 Organometallic substance, solid, self-heating#
Passage 19In addition, we would continue to allow the following specific Organometallic proper shipping names: UN1366, UN1370, UN2005, UN2445, UN3051, UN3052, UN3053, and UN3076. However, we anticipate removing these entries from the HMT by January 1, 2007. The U.N. Recommendations have adopted a rationalized approach for the assignment of UN portable tank instructions for solid materials. Based on that rationalized approach, we are making several changes to UN portable tank authorizations in the HMR. These proposals are summarized as follows. For a more specific identification of the affected shipping descriptions, refer to the UN report located in the public Docket. For Division 4.1, Packing Group I materials, the use of UN portable tanks would not be authorized. For Division 4.3 materials with a subsidiary class of 6.1, in Packing Group I, the use of portable tanks would not be authorized. For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group II, Special Provisions T3 would be specified. For Division 4.2, Packing Group I materials, T21 and TP7 would be specified. For Division 4.3, Packing Group I materials, T9 and TP7 would be specified. For Division 5.1, Packing Group I materials, the use of UN portable tanks would not be authorized. For Division 6.1 and Class 8, Packing Group I materials, T6 would be specified. For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group III, Special Provisions T1 would be specified. Several entries in the HMT would be revised by amending column 9B to read ``forbidden'' so that the materials would no longer be authorized for transport aboard cargo aircraft. The entries are being revised because they meet the criteria of either Zone C or Zone D inhalation toxicity. All other Zone C and Zone D toxic by inhalation materials listed in the HMR are currently already forbidden from transport aboard passenger and cargo aircraft (these materials are already forbidden from transport aboard passenger aircraft). The entries to be revised include:#
Passage 20Zone C: UN2204 Carbonyl sulfide UN1023 Coal gas, compressed UN1064 Methyl mercaptan UN1048 Hydrogen bromide, anhydrous UN1079 Sulfur dioxide Zone D: UN1005 Ammonia, anhydrous UN3318 Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia UN1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C UN1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C UN2191 Sulfuryl fluoride Also, see Sec. 172.102 for additional HMT amendments. Appendix B to Sec. 172.101 In Appendix B to Sec. 172.101, List of Marine Pollutants, we are proposing to remove the entries ``Isoamyl mercaptan'' ``Pentanethiols'' and ``Tetrachlorophenol.'' We are propo sing to revise the entry ``2, 6-Di-tert-Butylphenol'' and we are proposing to add the entry ``Chloropicrin.'' Section 172.102 We are proposing to amend Sec. 172.102, Special Provisions, as follows: Several entries in the HMT would be revised by adding special provisions A3, A6, A7, A9, A10, N3, and N36 to align this section with the equivalent special provisions in the ICAO Technical Instructions (13, 2, 5, 4, 7, 21, and 3 respectively). We propose to remove the ``A'' special provisions for several entries because we have determined that the materials to which the provisions apply are currently not authorized for transportation on either passenger or cargo aircraft. The following entries would be revised by adding special provision A3: UN1154 Diethylamine UN1788 Hydrobromic acid, not more than 49% strength UN1789 Hydrochloric acid UN2031 Nitric acid, other than red fuming, with more than 70% nitric acid UN2604 Boron trifluoride diethyl etherate The following entries would revised by adding A6:#
Passage 21UN1111 Amyl mercaptan UN1228 Mercaptans, liquid, flammable, toxic, n.o.s. UN1760 Corrosive liquid, n.o.s. UN1903 Disinfectants, liquid, corrosive, n.o.s. UN2031 Nitric acid, other than red fuming, with not more than 70% nitric acid UN2054 Morpholine UN2347 Butyl mercaptan UN2363 Ethyl mercaptan UN2402 Propanethiols UN2801 Dye, liquid, corrosive, n.o.s. UN2920 Corrosive liquid, flammable, n.o.s. UN2922 Corrosive liquid, toxic, n.o.s. UN3071 Mercaptans, liquid, toxic, flammable, n.o.s. UN3093 Corrosive liquid, oxidizing, n.o.s. UN3093 Corrosive liquid, oxidizing, n.o.s. UN3094 Corrosive liquid, water-reactive, n.o.s. UN3094 Corrosive liquid, water-reactive, n.o.s. UN3098 Oxidizing liquid, corrosive, n.o.s. UN3099 Oxidizing liquid, toxic, n.o.s. UN3139 Oxidizing liquid, n.o.s. UN3145 Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) UN3264 Corrosive liquid, acidic, inorganic, n.o.s. UN3265 Corrosive liquid, acidic, organic, n.o.s. UN3266 Corrosive liquid, basic, inorganic, n.o.s. UN3267 Corrosive liquid, basic, organic, n.o.s. UN3301 Corrosive liquid, self-heating, n.o.s. The following entries would be revised by adding special provision A7:#
Passage 22UN1167 Divinyl ether, stabilized UN1277 Propylamine UN1389 Alkali metal amalgam, liquid UN1389 Alkali metal amalgam, solid UN1391 Alkali metal dispersion or Alkaline earth metal dispersion UN1407 Cesium or Caesium UN1420 Potassium metal alloys UN1421 Alkali metal alloy, liquid, n.o.s. UN1422 Potassium sodium alloys UN1431 Sodium methylate UN1796 Nitrating acid mixture with not more than 50% nitric acid UN1796 Nitrating acid mixture with more than 50% nitric acid UN1826 Nitrating acid mixture, spent with not more than 50% nitric acid UN1826 Nitrating acid mixture, spent with more than 50% nitric acid UN1828 Sulphur chlorides UN1938 Bromoacetic acid UN2257 Potassium UN2749 Tetramethylsilane UN3093 Corrosive liquid, oxidizing, n.o.s. UN3093 Corrosive liquid, oxidizing, n.o.s. UN3094 Corrosive liquid, water-reactive, n.o.s. UN3094 Corrosive liquid, water-reactive, n.o.s. UN3205 Alkaline earth metal alcoholates, n.o.s. UN3205 Alkaline earth metal alcoholates, n.o.s. UN3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s. UN3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s. UN3208 Metallic substance, water-reactive, n.o.s. UN3208 Metallic substance, water-reactive, n.o.s. UN3208 Metallic substance, water-reactive, n.o.s. UN3209 Metallic substance, water-reactive, self-heating, n.o.s. UN3209 Metallic substance, water-reactive, self-heating, n.o.s. UN3209 Metallic substance, water-reactive, self-heating, n.o.s. The following entries would be revised by adding special provision A9: UN1449 Barium peroxide UN1452 Calcium chlorate UN3212 Hypochlorites, inorganic, n.o.s. The following entries would be revised by adding special provision A10: UN1828 Sulphur chlorides UN2401 Piperidine The following entry would be revised by adding special provision N3: UN2817 Ammonium hydrogendifluoride solution The following entries would be revised by adding special provision N36: UN1184 Ethylene dichloride UN1732 Antimony pentafluoride UN1777 Fluorosulphonic acid UN2699 Trifluoroacetic acid The following entries would be revised by removing certain ``A'' special provisions since the materials themselves are forbidden for transportation aboard passenger and cargo aircraft:#
Passage 23UN1541 Acetone cyanohydrin, stabilized (remove A3) UN1722 Allyl chloroformate (remove A3) UN2692 Boron tribromide (remove A3, A7) UN1744 Bromine or Bromine solutions (remove A3, A6) UN2484 tert-Butyl isocyanate (remove A7) UN2485 n-Butyl isocyanate (remove A7) UN1752 Chloroacetyl chloride (remove A3, A6, A7) UN1754 Chlorosulfonic acid (with or without sulfur trioxide) (remove A3, A6, A10) UN2382 Dimethylhydrazine, symmetrical (remove A7) UN1182 Ethyl chloroformate (remove A3, A6, A7) UN2481 Ethyl isocyanate (remove A7) UN2014 Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary) (remove A3, A6) UN2015 Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more than 60 percent hydrogen peroxide (remove A3, A6) NA9206 Methyl phosphonic dichloride (remove A3) UN2534 Methylchlorosilane (remove A2, A3, A7) UN2304 Naphthalene, molten (remove A1) UN1670 Perchloromethyl mercaptan (remove A3, A7) UN1810 Phosphorus oxychloride (remove A7) UN2740 n-Propyl chloroformate (remove A3, A6, A7) UN1829 Sulfur trioxide, stabilized (remove A7) UN1831 Sulfuric acid, fuming with 30 percent or more free sulfur trioxide (remove A3, A6, A7) UN1834 Sulfuryl chloride (remove A3) UN1836 Thionyl chloride (remove A7) UN2474 Thiophosgene (remove A7) UN1838 Titanium tetrachloride (remove A3, A6) UN2441 Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric (remove A7, A8, A19, A20) UN2442 Trichloroacetyl chloride (remove A3, A7) UN1295 Trichlorosilane (remove A7) UN2438 Trimethylacetyl chloride (remove A3, A6, A7)#
Passage 24Paragraph (b)(3) of this section would be amended to specify that a ``B'' code refers to a special provision that applies only to certain bulk packaging requirements and that, unless otherwise stated, would not apply to UN portable tanks or IBCs. Paragraph (b)(4) of this section would be amended to specify that a code containing the letters ``IB'' or ``IP'' refers to a special provision that applies only to transportation in IBCs. Paragraph (b)(8) would be redesignated (b)(9) and a new paragraph (b)(8) would be added to specify that a code containing the letters ``TP'' refers to a special provision that is in addition to those provided by the portable tank instructions or the requirements in part 178. Special Provision 47 would be revised to include an additional exception currently in the UN Model Regulations specifying that a leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags. Special Provision 135 would be revised to expand the applicability of the proper shipping names ``Vehicle, flammable liquid powered'' and ``Vehicle, flammable gas powered'' to include hybrid electric vehicles. Special Provision 137 would be revised to expand the exception for ``Cotton, dry.'' Special Provision 143 would be removed and relocated to Sec. 173.219 so that the limitations on the types of hazardous materials authorized apply to both self-inflating and non-self- inflating life-saving appliances. Special Provision 153 would be relocated to new paragraph (k) in Sec. 173.115 and revised to include amended classification criteria for aerosols containing flammable constituents consistent with criteria in the UN Model Regulations. The revised criteria would include methods for the classification of aerosols based on the percentage of flammable components. New Special Provision 163 would be added to specify that Ammonium Nitrate Emulsions would be required to satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18. New Special Provision 164 would be added to specify that an approval is required for ``Desensitized explosives, liquid, n.o.s.'' and ``Desensitized explosives, solid, n.o.s.'' New Special Provision 165 would be added to the Calcium hypochlorite PG II and the PG III entries for UN1748 and UN2880 to specify the danger of exothermic decomposition and require shading from dir#
Passage 25ect sunlight and sources of heat during transportation. New Special Provision 166 would be added to the PG II entry for calcium hypochlorite, UN2880 and UN1748 to indicate that calcium hypochlorite in the non-friable tablet form may be transported as a PG III material. New Special Provision 167 would be added to the proposed new entry for ``Hydrogen in a metal hydride storage system'' to specify that such storage systems shall always be considered as containing hydrogen. New Special Provision 170 would be added to the newly proposed Organometallic substances entries (UN3391, UN3392, UN3393, and UN3394). The special provision would require air to be eliminated from the vapor space by nitrogen or other means. New Special Provision 171 would be added to the UN2880 PG III entry. Since UN2880 also covers mixtures of hydrated calcium hypochlorite in any concentration, some formulations in other than tablet form (e.g., in granular form) may meet the criteria for classification in Division 5.1, Packing Group III when subjected to the relevant test in the UN Manual of Tests and Criteria. The PG III entry for calcium hypochlorite would only be authorized when the material is offered in the non-friable tablet form or for granular or powered mixtures. This entry would not be authorized for the pure form of calcium hypochlorite hydrated. We also recognize that some formulations, when tested, do not meet the criteria for classification in Division 5.1. In light of this, we believe that a new Special Provision 171 should be added to the UN2880, PG III entry in the HMT to allow for the possibility to classify powered or granular mixtures of hydrated calcium hypochlorite in Packing Group III when data indicates that the mixture meets the criteria for assignment to PG III. Special Provision A11 is currently assigned to UN 2983, Ethylene oxide and Propylene oxide mixtures and UN 1411, Lithium aluminum hydride, ethereal. In the ICAO Technical Instructions these substances are only authorized for transport in metal cylinders. A11 states ``For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used.'' Therefore, to align with ICAO Particular Packing Requirement Number 8, Special Provision A11 would be amended to read ``Only specification cylinders constructed#
Passage 26of metals which are compatible with the hazardous material may be used.'' Consistent with ICAO, we are adding a proper shipping name to the HMT for ``Receptacles, small containing gas, 2.2 with a subsidiary of 5.1.'' A new ``A'' code (A14) would be added to prohibit material from being transported as a limited quantity or consumer commodity in accordance with Sec. 173.306 aboard an aircraft. This new ``A'' code would also be added to the following additional shipping names: ``Oxygen, compressed'', Carbon dioxide and oxygen mixtures'', ``Nitrous oxide'', ``Compressed gas oxidizing'', and ``Liquefied gas, oxidizing.'' For consistency, the authorization in Special Provision B69 to allow dry sodium or potassium cyanide in siftproof, water- resistant fiberboard IBCs would be relocated to new Special Provision IP20. Paragraph (c)(4) of this section would be amended by relocating ``Table 2.--Organic Peroxide IBC Code (IB52)'' to paragraph (e) of Sec. 173.225 and renaming it the ``Organic Peroxide IBC Table.'' Table 3.--IP Codes would then be redesignated Table 2.--IP Codes. The wording of paragraph (c)(4) would be revised to indicate that Table 3.--IP Codes had been redesignated Table 2.--IP Codes. All references to IB52 in the HMR would be removed and replaced with ``Organic Peroxide IBC Table'' or ``Sec. 173.225(e),'' as applicable. Paragraph (c)(7) would be amended by relocating the Portable Tank Code T50 Table to Sec. 173.313 and renaming it ``UN Portable Tank Table for Liquefied Compressed Gases.'' The T50 Table and#
Passage 27its description would be removed from paragraph (c)(7)(iv) and replaced with a statement indicating that the new ``UN Portable Tank Table for Liquefied Compressed Gases'' is found in Sec. 173.313. All references to T50 in the HMR would be removed and replaced with ``UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313''. In addition, paragraph (c)(7) would be amended by relocating Portable Tank Code T23 to paragraph (g) of Sec. 173.225 and renaming it the ``Organic Peroxide Portable Tank Table.'' Portable Tank Code T23 and its description found in paragraph (c)(7)(iii) would be removed and paragraphs (c)(7)(iv)-(c)(7)(vii) would be redesignated (c)(7)(iii)- (c)(7)(vi), respectively. All references to T23 in the HMR would be removed and replaced with ``Organic Peroxide Portable Tank Table'' or ``Sec. 173.225(g),'' as applicable. New paragraph (c)(8) would be added to provide an introduction to the ``TP'' codes (i.e., portable tank special provisions). The existing paragraph (c)(8) would be redesignated paragraph (c)(9). New Special IBC Packing Provision IP13 would be added to specify that transportation by vessel in IBCs would be prohibited. New Special IBC Packing Provision IP14 would be added to specify that air must be eliminated from the vapor space by nitrogen purging or other means. New Special IBC Packing Provision IP20 would be added to specify that dry sodium cyanide and potassium cyanide are also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. Portable tank Special Provision TP3 would be revised to include the maximum degree of filling (in %) for solids transported above their melting points. Special Provision TP6 would be revised by removing the word ``event'' and replacing it with the ``incident.'' Portable tank Special Provision TP9 would be removed from column (7) of the Hazardous Materials Table for all materials that reference a T code special provision. Special provision TP9 states that a material with TP9 in Column (7) may only be transported in a portable tank if approved by the Associate Administrator. A material that has been given a T code does not require approval and is not subject to Special Provision TP9. Section 172.202 Paragraph (a)(5)(i) would be revised to clarify that for explosive articles the quantity shown on a shipping paper must b#
Passage 28e expressed in terms of the net mass of the article. Section 172.203 Paragraph (f) would be revised by including the passenger and cargo aircraft limitation certification statement that is currently found in Sec. 172.204. This would align the HMR with the ICAO TI (see 4.1.5.8.1(b) of the ICAO TI). In addition, in paragraph (o)(3), the reference to Sec. 173.225(c)(2) would be amended to read Sec. 173.225(b)(2). Paragraph (m)(2) would be revised to specify that the phrase ``Poison Inhalation Hazard'' or ``Toxic Inhalation Hazard'' is not required to be repeated if it otherwise appears in the shipping description. Finally, a new paragraph (i)(3) would be added to specify additional shipping paper description requirements for a hazardous material consigned under an ``n.o.s.'' entry when offered for transportation by vessel. Section 172.204 and Section 172.321--Air Eligibility Marking Under HM-215E (68 FR 44992), the air eligibility marking was adopted into the HMR as new Sec. 172.321. Since publication of that final rule, the ICAO's Dangerous Goods Panel removed the air eligibility marking requirement. In lieu of this marking, ICAO adopted a requirement that the shipping paper certification statement include the statement ``I declare that all of the applicable air transport requirements have been met'' when a hazardous material is offered for air transportation. Additionally, the revised section provided examples of the applicable air transport requirements that must be met. Based on this action, we are proposing to revise the air eligibility marking requirement by making it optional rather than mandatory and adding the additional shipping paper certification statement for shipments going by aircraft. Therefore, we are proposing to revise Sec. 172.204(c)(3) by requiring that the statement ``I declare that all of the applicable air transport requirements have been met'' be included on the shipping paper in addition to the current certification statement when a hazardous material is offered for air transportation. Additionally, the revised section would provide examples of the applicable air transport requirements that must be met and various section references. In order to allow shippers to expend stocks of preprinted shipping papers containing the previous certification statement, we are providing an additional ten month transitional provision for the new certif#
Passage 29ication statement. Section 172.317 A new Sec. 172.317 would be added to require a ``KEEP AWAY FROM HEAT'' handling mark on packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 when such packages are transported by air. Section 173.3 The definition for ``salvage drums'' would be revised to include the term ``non-conforming.'' The term ``non-conforming'' was added to the definition by the UN Committee of Experts in December 2000. Section 173.24 For consistency with the UN Recommendations, paragraphs (g)(4) and (g)(5) would be revised to clarify the following: (A) That IBCs ( subject to the requirements in Sec. 173.24(g)) are permitted to be vented to reduce internal pressure; and (B) That venting of IBCs is not conditional upon whether a bulk special provision is indicated for a particular hazardous material in the Sec. 172.101 hazardous materials table. In addition, paragraph (i) would be revised to clarify that other general requirements specific to air transportation apply and are found in Sec. 173.27. Section 173.25 Paragraph (a)(2) would be revised by removing the requirement to mark an overpack with the air eligibility marking. In addition, in paragraph (a)(4), we propose to require overpacks to be marked with the word ``OVERPACK'' or, alternatively, until October 1, 2007, with a statement indicating that inside packages comply with prescribed specifications. This is in response to adoption by the United Nations of the ``OVERPACK'' marking to indicate that packages within an overpack comply with prescribed specifications when specification markings on inside packagings within the overpack are not visible. Section 173.27 Paragraph (i) would be revised to indicate that the air eligibility mark has been removed. This section would reference a new requirement for shippers to place the following statement at the end of the certification statement when a hazardous material is authorized for air transportation: ``I declare that all applicable air transport requirements have been met.''#
Passage 30Section 173.28 In paragraph (c)(2), we propose to delete the words ``or a UN 1H1 plastic drum.'' This would harmonize the HMR with the UN Model Regulations and remove a source of confusion within the regulated community regarding the reconditioning of a non-bulk packaging. Section 173.115 In Sec. 173.115, a new paragraph (k) would be added (see discussion under Sec. 172.102, Special Provision 153). Section 173.128 In paragraph (d)(1)(i), the section reference would be revised to read Sec. 173.225(c). In addition, in paragraphs (d)(1)(ii) and (d)(1)(iii), the section reference would be revised to read Sec. 173.225(b). Section 173.132 In paragraph (b)(1), we propose to revise the definition of LD50 for acute oral toxicity to indicate that adult albino rats may be tested without regard to gender. The current definition for LD50 for acute oral toxicity in Sec. 173.132(b)(1) is based on the Organization for Economic Co-Operation and Development (OECD) Test Guideline (TG) 401. The OECD has agreed to three test methods that will replace the current TG 401. The United Kingdom, Germany and the United States of America took the lead in the development of the three alternative tests that OECD has now adopted and published in the OECD Guidelines for the Testing of Chemicals. In a continuing attempt to improve the estimate of acute oral toxicity while reducing the number of animals used per test, three alternative TGs have been developed and implemented to replace TG 401. The three TGs are the Fixed Dose Procedure (FDP, TG 420), the Acute Toxic Class Method (ATCM, TG 423), and the Up-and-Down Procedure (UDP, TG 425). The proposed text would be consistent with the text in the 13th revised edition of the UN Model Regulations that was recently amended on the basis of a proposal from the United States. Section 173.136 We propose to add a new paragraph (d) to provide a grandfather clause that will allow the shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72. Section 173.137 In paragraph (c)(2), we propose to eliminate the references to ASTM G 31-72 as an acceptable test description and add a statement indicating an acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37. Sections 173.150, 173.151, 173.152, 173.153 and 173.154 We are proposing to allow most Division 6.1, Packing Group II materials to be transpo#
Passage 31rted as a limited quantities. For Packing Group II materials, we are proposing to allow inner packagings not over 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids to be transported as a limited quantity. However, consistent with the limited quantity authorization for Division 6.1, Packing Group III, we are not proposing a labeling exception for these materials. We are also not proposing to allow these materials to be shipped as a consumer commodity. In addition, we propose to revise the limited quantity sections for the other hazard classes of materials to take into account materials with a subsidiary hazard of 6.1 Packing Group II. Section 173.185 In Sec. 173.185, we propose to amend paragraphs (c)(3) and (e)(3), to specify that a cell, battery, lithium cell or battery and equipment containing a cell, battery or lithium cell or battery that was transported prior to the effective date of this rule and is of a type proven to meet the criteria of Class 9 by testing, in accordance with the tests prescribed in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 would not be required to be retested. Section 173.186 In Sec. 173.186, in paragraph (e), we propose to amend the gross weight for 4G outer packages authorized for the transportation of strike-anywhere matches, to be consistent with the UN Model Regulations by increasing the weight from 27 kg (60 pounds) to 30 kg (66 pounds). Section 173.187 We propose to revise Sec. 173.187 to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This proposal would also remove the need for DOT Exemption ``DOT-E 11548.'' Sections 173.211, 173.212, and 173.213 We propose to revise these sections to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This proposal would also remove the need for DOT Exemption ``DOT-E 11548.'' Section 173.219 We propose to revise Sec. 173.219 for consistency with the UN Model Regulations and the ICAO Technical Instructions. Included in the proposed revision is an allowance for self-inflating life-saving appliances to contain cartridges, power devices of Division 1.4S, for purposes of the self-inflating mechanism. In addition, we propose to provide an exception from regulation for lif#
Passage 32e-saving appliances containing only carbon dioxide cylinders not exceeding 100 cm\3\ capacity, provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg. Finally, the limitations currently found in Special Provision 143 would be relocated to Sec. 173.219 (see preamble discussion under Special Provision 143). Section 173.220 Paragraph (b)(2) would be amended to harmonize the requirements for transporting flammable gas powered vehicles by air with the requirements of Packing Instruction 900 of the ICAO Technical Instructions. Section 173.224 Paragraph (b)(4) of this section would be amended to include the new references for Sec. 173.225. The section reference to Sec. 173.225(e) for the authorization of bulk packagings would be replaced with Sec. 173.225(f) for IBCs and Sec. 173.225(h) for other bulk packagings. Section 173.225 This section would be amended to update the Organic Peroxide Table and eliminate special provisions IB52 and T23 from Sec. 172.102(c). The purpose of the change is to consolidate the packaging requirements for organic peroxides into one section and to have separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs. The proposed changes are as follows: Paragraph (a) would be revised by adding paragraphs (b) and (b)(6), which state that bulk packagings may require a lower control temperature than those specified for non-bulk packagings and that an organic peroxide not identified in either the Organic Peroxide Table, Organic Peroxide IBC Table, or Organic Peroxide Portable Tank Table must be approved under Sec. 173.128(c). Paragraph (b) would be revised to eliminate all IBC and other bulk packaging authorizations from column 6 of the Organic Peroxide Table. Various obsolete entries would also be removed.#
Passage 33The current paragraph (b), ``Organic Peroxide Table,'' would be moved to paragraph (c) and the current paragraph (c), ``New organic peroxides, formulations and samples,'' would be moved to paragraph (b). In the notes following the Organic Peroxide Table we propose to: Revise note 22 to indicate that ethylbenzene with greater than or equal to 25% of dilutant type A would be acceptable. Revise note 23 to indicate that methyl isobutyl keytone with greater than or equal to 19% of dilutant type A would be acceptable. Add a new note 29 to identify materials which are not included in the UN Model Regulations and note that a Competent Authority approval is required for international transportation. Remove Notes 9, 11, and 14 following the Organic Peroxide Table.#
Passage 34In addition, The Packing Method Table found in paragraph (d), would be revised by replacing the 200 kg maximum quantity for solids and combination packagings listed in OP8 with a 400 kg maximum quantity. Note 2, following the table, would be revised to allow 200 kg of solid material per box and up to 400 kg of material per authorized combination packaging. The note would also indicate that the outer packaging must be a box (4Cl, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and each inner packaging must be of plastics or fiber with a maximum net mass of 25 kg. Paragraph (d)(3) would be clarified by revising the text to state that the maximum content acceptable for glass receptacles used as inner packagings of a combination packaging is 0.5 kg for solids or 0.5 L for liquids. A new paragraph (e) would be added to include the new ``Organic Peroxide IBC Table'' that replaces the current ``Table 2--Organic Peroxide IBC Code (IB52)'' in Sec. 172.102(c)(4). The new table would be revised to add an organic peroxide, ``Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water.'' In addition, the new Organic Peroxide IBC Table would identify, by technical name, those organic peroxides authorized for transportation in the IBCs that are specifically listed in the table. A new paragraph (f) would be added to include the current IBC requirements contained in paragraph (e)(5) of this section. Paragraph (f) would also include requirements that are specific to organic peroxides packaged in IBCs. A new paragraph (g) would be added to include the new ``Organic Peroxide Portable Tank Table,'' that replaces the current ``Portable Tank Code T23'' found in Sec. 172.102(c)(7)(iii). The new table would be identical to the current table except that for UN 3109, in the entry for Pinanyl hydroperoxyde, 50% would be replaced by 56% and all references to self-reactive materials would be removed. In addition, the Organic Peroxide Portable Tank Table would provide certain portable tank requirements and identify, by technical name, those organic peroxides authorized for transportation in the bulk packagings listed in the new paragraph (h). The current paragraph (e) would be redesignated as paragraph (h). Paragraph (h) would establish requirements that are specific to organic peroxides packaged in certain bulk packagings. Additionally, the new ``Note to Paragraph (h)(3)(vi)'' would#
Passage 35be revised to include changes brought forth by petition for rulemaking P-1428. The petition proposed to amend the current paragraph (e)(3)(vi) and allow for a second but equally acceptable example of an emergency-relief device sizing method to be added to the HMR. We are in agreement with the petitioner and are proposing to add a statement to the new paragraph (h)(3)(vi) indicating that an additional example of an emergency-relief device sizing method can be found in the ``American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2)'' as referenced in Sec. 171.7(b). The proposed changes to this section would alter the order of the paragraphs within this section and various citations would need to be changed. Also, paragraphs referencing IB52 or TP23 would be revised to indicate that those provisions no longer exist and the updated requirements are found in paragraph (e) and (g), respectively. Sections 173.226 and 173.227 We propose to revise the packaging requirements of Sec. Sec. 173.226 and 173.227 for materials poisonous by inhalation, Division 6.1, Packing Group I, Hazardous Zone A and Hazard Zone B. These amendments would: Reduce the hydrostatic test pressure of the inner drum in a drum-within-a-drum configuration authorized in Sec. 173.226(b); standardize the minimum thickness requirements of the inner drums in the drum-within-a-drum configuration authorized in Sec. Sec. 173.226(b) and 173.227(b); clarify the test requirements for inner packaging systems in Sec. 173.226(b)(2)(iv); and in Sec. 173.226(d) add a provision to authorize transportation of PIH materials in single packages when subjected to additional operational controls and approved by the Associate Administrator for Hazardous Materials Safety. Section 173.226(c)(2) would be reformatted for ease of understanding. We would also remove an expired transitional date from paragraph (a) that allows the transport of welded cylinders filled before October 1, 2003 for the purpose of reprocessing or disposal of cylinders's content until December 31, 2003. Section 173.249 Paragraph (c) would be revised to be consistent with the current ``Bromine'' entry in the Sec. 172.101 ``Hazardous Material Table'' that authorizes the use of a UN portable tank conforming to tank code T22. Sections 173.306 and 173.307 To add clarity to the HMR, the text currently found i#
Passage 36n Sec. 173.306(i) would be removed and replace with the text currently found in Sec. 173.307(a)(5). Since Sec. 173.306 is devoted exclusively to limited quantities of compressed gases, relocating Sec. 173.307(a)(5) to Sec. 173.306 would make the exception easier to find. Section 173.313 A new Sec. 173.313 would be added to serve as the new location for the Portable Tank Code T50 Table. The table would be renamed ``UN Portable Tank Table for Liquefied Compressed Gases.'' The table provides the maximum allowable working pressures, bottom opening requirements, pressure relief requirements and degree of filling requirements for liquefied compressed gases permitted for transport in portable tanks. The change would relocate these packaging requirements to Part 173, which is a more appropriate location, and make the special provisions less cumbersome. In addition, the new UN Portable Tank Table for Liquefied Compressed Gases would be amended by revising the Column 3 heading to read ``Minimum design pressure (MAWP) (bar) * * *.'' The values in column 3 are actually minimum values, however the title of the column is misleading because it uses the term ``Maximum allowable working pressure (bar) * * *.'' Section 173.315 In paragraph (a), the reference to ``portable tank provision T50 in Sec. 172.102'' would be revised to read ``the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313''.#
Passage 37Section 173.323 In this rule we are proposing to revise the combination packaging authorizations for Ethylene Oxide to be consistent with the UN Recommendations. Paragraphs (b)(1)-(b)(3) would be revised and consolidated for consistency with current international requirements for the transportation of ethylene oxide in combination packagings. Paragraphs (b)(1)-(b)(3) provide the current authorizations for glass, aluminum, and metal receptacles respectively. Amendments to this section include (1) specifying a 2.5 kg limit per outer package and removing the HMR limitation of 12 inner receptacles per outer package currently applied to aluminum and other metal receptacles, (2) removing the overpack restriction in (b)(2) which specifies a maximum of 10 boxes per overpack, (3) requiring a hot water bath test for all inner receptacles, (4) removing the pressure relief device and burst pressure requirements currently applied to metal receptacles, (5) applying the same outer package authorizations consistently to all inner packaging types and allowing any outer package authorized in Sec. 172.201(b), and (6) requiring all inner packagings to be suitably cushioned (the top and bottom pad and perimeter liner requirement currently only applied to outer packages containing aluminum inner packagings would be removed). Though we are eliminating the option to utilize certain packaging authorizations for glass and aluminum inner packagings, we believe that this proposal will present little or no economic impact on the ethylene oxide industry because of the amount of materials that are transported in international commerce. If comments are received that contradict this understanding, RSPA may revise the final rule accordingly.#
Passage 38Section 175.10 Consistent with an amendment to the ICAO TI, we are proposing to require that aerosol cans that are carried aboard an aircraft in accordance with Sec. 175.10(a)(4) have their release devices protected by a cap or other suitable means. In addition, the ICAO Dangerous Goods Panel will convene a series of working groups to develop recommendations for consideration during the 20th session of the Dangerous Goods Panel to further review this issue. These recommendations may lead to additional amendments to the ICAO TI. Finally, we note that non-flammable gases (e.g., nitrogen) other than carbon dioxide are used for the operation of mechanical limbs. Consistent with an amendment to the ICAO TI, we are proposing to provide an exception from the HMR for mechanical limbs that are powered by any Division 2.2 gas. Section 175.85 In Sec. 175.85, a new paragraph (j) would be added to specify the cargo location of a package bearing the ``KEEP AWAY FROM HEAT'' handling marking.#
Passage 39Section 176.2 Certain definitions would be revised. The definition for ``Explosive article'' and ``Explosive substance'' would be revised to remove an incorrect reference. The definition for ``Magazine'' would be revised to include a compartment in the vessel. The definition for ``Magazine'' would also be revised to specify vessel storage location and accessibility. The term ``Transport unit'' would be revised to read ``Cargo transport unit'' to be consistent with Amendment 32 of the IMDG Code. In addition, in the definition ``In containers or the like'' the term ``transport unit'' would be removed and the term ``cargo transport unit'' would be added in its place. Section 176.27 In this section, the words ``transport unit'' would be replaced with the words ``transport vehicle'' in each place they appear to be consistent with the removal of the term ``transport unit'' from the definitions in Sec. 176.2. Section 176.63 Paragraph (e) would be revised to align the definition of ``Closed cargo transport unit'' to be consistent with the definition in Amendment 32 of the IMDG Code. Section 176.76 Paragraph (i) would be revised to clarify that for container ships, a distance equivalent to one container space athwartships (i.e., in the direction of the breadth of the vessel) away from possible sources of ignition applied in any direction would satisfy the requirement that a cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 [deg]C transported on deck be stowed ``away from'' possible ignition sources. This would be consistent with Amendment 32 of the IMDG Code. In addition, in paragraphs (h) and (i), the words ``transport unit'' would be removed and replaced with the words ``cargo transport unit'' in each place they appear to be consistent with Amendment 32 of the IMDG. Section 176.83 Paragraph (l) would be revised to correct an error pertaining to the Segregation Table that set forth the general requirements for segregation of containers on board hatchless container vessels. In addition, throughout the section the words ``transport units'' would be removed and replaced with the words ``cargo transport units'' in each place they appear to be consistent with Amendment 32 of the IMDG. A new paragraph (m) would be added to specify the provisions for segregation groups. Section 176.84 Paragraph (a) would be revised t#
Passage 40o specify the various chemical groups listed in the segregation table. In the paragraph (b) Table of Provision, we would add eleven new provisions (codes) for certain stowage and segregation requirements for hazardous materials that are transported by vessel. In addition, in paragraph (c)(2) Provisions for the stowage of Class 1 (explosive) materials, we would revise three notes. The terms ``separated from'' and ``away from'' in the codes are defined in Sec. 176.83 of the HMR. Code 133 would be added to the entries ``Barium chlorate solution,'' UN3405; ``Barium perchlorate solution,'' UN3406; and ``Chlorate and magnesium chloride mixture solution,'' UN3407, that requires the material to be stowed ``separated from'' sulfur. Code 134 would be added to the entry ``Aluminum alkyl halides, solid,'' UN3461, that requires the material to be stowed ``separated from'' UN2716. Code 135 would be added to the entries ``Methylamine, aqueous solution,'' UN1235 and ``Trimethylamine, aqueous solutions,'' UN1297, that requires the material to be stowed ``separated from'' mercury and mercury compounds. Code 136 would be added to the entry ``Tributylphosphane,'' UN3254, that requires the material to be stowed ``separated from'' tetrachloride. Code 137 would be added to the entries ``Arsenic compounds, liquid, n.o.s.,'' UN1556 and ``Arsenic compounds, solid, n.o.s.,'' UN1557, that requires arsenic sulphides to be stowed ``separated from'' acids. Code 138 would be added to the entries for UN1448; UN1456; UN1479; UN1482; UN1490; UN1503; UN1515; UN3085; UN3087; UN3098; UN3099; UN3139; and UN3214, that requires the material to be stowed ``separated from'' peroxides.#
Passage 41Code 139 would be added to the entry ``1, 4-Butynediol,'' UN2716, that requires the material to be stowed ``separated from'' mercury salts. Code 140 would be added to the entry ``1, 4-Butynediol,'' UN2716, that requires the material to be stowed ``separated from'' UN3052 and UN3461. Code 141 would be added to the entries for UN1732; UN1755; UN1806; UN1908; UN2433; UN2859; and UN2861, that requires the material to be stowed ``away from'' radioactive materials. Code 142 would be added to the entries for UN1748; UN2208; and UN 2880, that requires packages in cargo transport units to be stowed so as to allow for adequate air circulation throughout the cargo. Code 143 would be added to the entry for Organometallic Substance, Liquid, Pyrophoric, UN3392, prohibiting transportation on any vessel carrying explosives (except explosives in Division 1.4, Compatibility group S. Note 19E would be revised to specify that materials under entries NA0331; UN0004; UN0222; UN0241; and UN0402 must be stowed ``away from'' explosives containing chlorates or perchlorates. Note 22E would be revised to specify that materials under the entry ``Explosive, blasting, type C,'' must be stowed ``away from'' ammonium compounds and explosives containing ammonium compounds or salts. Note 23E would be revised to specify that materials under entries UN0247; UN0395; UN0396; UN0397; UN0398; UN0399; UN0400; UN0449; and UN0450 must be ``separated from'' Division 1.4 and ``separated longitudinally by an intervening complete compartment or hold from'' Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J. Section 176.116 In paragraph (c), the words ``transport units'' would be revised to read ``cargo transport units.'' In addition, a new paragraph (f) would be added to specify the under deck stowage requirements of Class 1 (explosive) materials allocated stowage categories 09 and 10. Sections 176.122 and 176.124 Sections 176.122 and 176.124 would be removed and reserved. Section 176.128 In Sec. 176.128, the section heading and section would be revised. Section 176.132 Section 176.132 would be removed and reserved. Section 176.133 Section 176.133 would be revised to clarify the construction and stowage location requirements for magazine stowage type C. Section 176.136 Section 176.136 would be revised to clarify the special stowage requirements of Class 1 (explosive) mate#
Passage 42rials. In addition, minor editorial revisions would be made. Section 176.138 Paragraph (a) would be removed and reserved to be consistent with Amendment 32 of the IMDG Code. This paragraph currently requires Class 1 (explosive) material that is stowed on deck to be carried as close to the vessel's centerline as practicable. (See also proposed change to Sec. 176.170.) Section 176.142 Paragraph (a) would be revised to remove ``Pyrophoric organometallic compound, water-reactive, n.o.s.'' from the list of liquid hazardous materials of extreme flammability that may not be transported in a vessel carrying Class 1 (explosive) materials. Additionally, we propose to add to the above list the following new liquid entries: ``Organometallic substance, liquid, pyrophoric, UN3392'' ``Organometallic substance , liquid, pyrophoric, water-reactive, UN3394'' These proposed changes would be consistent with Amendment 32 of the IMDG Code. Section 176.144 In this section, the words ``transport unit'' would be replaced with the words ``cargo transport unit'' in each place they appear to be consistent with the definition in Amendment 32 of the IMDG Code. Additional notes would be added to Table 176.144(a)--``Authorized Mixed Stowage For Explosives'' to address additional exceptions for mixed stowage of Class 1 materials. Section 176.146 In Sec. 176.146, in paragraph (d)(1), the wording ``transport units'' would be revised to read ``cargo transport units''. Section 176.168 In Sec. 176.168, in the title before the section heading, the wording ``TRANSPORT UNITS AND SHIPBORNE BARGES'' would be revised to read ``CARGO TRANSPORT UNITS AND SHIPBORNE BARGES''. Section 176.170 A new paragraph (b) would be added to prohibit freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, from being stowed in the outermost row of containers. This proposed change would be consistent with Amendment 32 of the IMDG Code. Section 176.174 Paragraphs (a) and (b) would be revised to remove the references to portable magazines. This proposed change would be consistent with Amendment 32 of the IMDG Code. Section 176.600 In Sec. 176.600, in paragraph (a), the wording ``closed transport units'' would be revised to read ``closed cargo transport units''.#
Passage 43Section 178.274 Paragraph (f)(v) would be revised to more clearly specify the rated flow capacity marking required to be placed on every UN portable tank's pressure relief device. Section 178.275 Paragraph (i)(2) would be revised to more clearly specify the combined delivery capacity of UN portable tank's pressure relief systems. Section 178.276 In paragraph (a)(4)(ii)(A), the reference to ``portable tank special provision T50'' would be revised to read ``the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313.'' In addition, paragraph (d), the reference to ``portable tank special provision T50 in Sec. 172.102(c)(7)'' would be revised to read ``UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313.'' Finally, in paragraph (e)(3), the reference to ``portable tank special provision T50 in Sec. 172.102'' would be revised to read ``the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313.'' Section 178.602 Paragraph (b) would be revised to clarify the requirements applicable to filling packaging other than bags in preparation for testing. Section 178.603 Paragraph (c) would be revised to add a definition indicating that a minimum specific gravity for solutions of water and anti-freeze is 0.95 for testing at -18 [deg]C (0 [deg]F) or lower. Additionally, in paragraph (e), we propose to specify the drop test height for liquids in single packagings and for inner packagings of combination packagings, when the test is performed in water. Section 178.810 Paragraph (b)(3) would be revised to specify that water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at -18 [deg]C (0 [deg]F) or lower are acceptable test liquids for use when conducting IBC drop tests. This is consistent with our amendment to Sec. 178.603(c)(1) regarding the testing of non-bulk packages. We are also proposing to add a sentence to clarify that when conditioning is required by Sec. 178.810(b), the conditioning specified in Sec. 178.802 (which requires a higher temperature) does not apply.#
Passage 44Section 180.350 Paragraph (c) would be revised to expand the definition of routine maintenance of IBCs to include flexible, plastic and textile IBCs. Section 180.352 A new paragraph (d)(1)(v) would be added to this section. This paragraph would state that retests and inspections performed under paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the tests and inspections required by paragraph (b) of this section. This addition would incorporate changes made to the 12th revised edition of the Transport of Dangerous Goods Model Regulations into the HMR. A. Executive Order 12866 and DOT Regulatory Policies and Procedures This proposed rule is not considered a significant regulatory action under section 3(f) of Executive Order 12866 and, therefore, was not reviewed by the Office of Management and Budget. This proposed rule is not considered a significant rule under the Regulatory Policies and Procedures of the Department of Transportation (44 FR 11034). Benefits resulting from the adoption of the amendments in this proposed rule include enhanced transportation safety resulting from the consistency of domestic and international hazard communications and continued access to foreign markets by domestic shippers of hazardous materials. This proposed rule applies to offerors and carriers of hazardous materials, such as chemical manufacturers, chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, radiopharmaceutical companies, and training companies. The majority of amendments in this proposed rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America. For example, cost savings will be realized by shippers and carriers as a result of the following: Eliminating the air eligibility marking requirement. Amendments allowing numerous Class 3, PG II materials with a Class 8 sub-risk and others to be transported as a limited quantity. Allowing cylinders to be used for many more substances than currently authorized. Allowing salvage packagings to be used for non-conforming packages; and generally minimizing differences between U.S. and international hazardous materials transportation regulations.#
Passage 45We would authorize a delayed effective date and a one-year transition period to allow for training of employees and to ease any burden on entities affected by the amendments. The total net increase in costs to businesses in implementing this rulemaking is considered to be minimal and a preliminary regulatory evaluation is available for review in the Docket.#
Passage 46This proposed rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13132 (``Federalism''). This proposed rule preempts State, local and Indian tribe requirements but does not propose any regulation that has substantial direct effects on the States, the relationship between the national government and the States, or the distribution of power and responsibilities among the various levels of government. Therefore, the consultation and funding requirements of Executive Order 13132 do not apply. The Federal hazardous material transportation law, 49 U.S.C. 5101- 5127, contains an express preemption provision (49 U.S.C. 5125(b)) that preempts State, local, and Indian tribe requirements on certain covered subjects. Covered subjects are: (1) The designation, description, and classification of hazardous materials; (2) The packing, repacking, handling, labeling, marking, and placarding of hazardous materials; (3) The preparation, execution, and use of shipping documents related to hazardous materials and requirements related to the number, contents, and placement of those documents; (4) The written notification, recording, and reporting of the unintentional release in transportation of hazardous; or (5) The design, manufacture, fabrication, marking, maintenance, recondition, repair, or testing of a packaging or container represented, marked, certified, or sold as qualified for use in transporting hazardous material. This proposed rule addresses covered subject items (1), (2), (3), and (5) above and would preempt State, local, and Indian tribe requirements not meeting the ``substantively the same'' standard. This proposed rule is necessary to incorporate changes adopted in international standards, effective January 1, 2003. If the changes in this proposed rule are not adopted in the HMR, U.S. companies, including numerous small entities competing in foreign markets, would be at an economic disadvantage. These companies would be forced to comply with a dual system of regulations. The changes proposed in this rulemaking are intended to avoid this result. Federal hazardous materials transportation law provides at section 5125(b)(2) that, if DOT issues a regulation concerning any of the covered subjects, DOT must determine and publish in the Federal Register the effective date of Federal preemption. The effective date may not be#
Passage 47earlier than the 90th day following the date of issuance of the final rule and not later than two years after the date of issuance. We propose that the effective date of Federal preemption be 90 days from the date of publication of a final rule in the Federal Register. This proposed rule was analyzed in accordance with the principles and criteria contained in Executive Order 13175 (``Consultation and Coordination with Indian Tribal Governments''). Because this proposed rule does not have tribal implications, does not impose substantial direct compliance costs, and is required by statute, the funding and consultation requirements of Executive Order 13175 do not apply. D. Regulatory Flexibility Act, Executive Order 13272, and DOT Procedures and Policies The Regulatory Flexibility Act (5 U.S.C. 601 et seq.) requires an agency to review regulations to assess their impact on small entities, unless the agency determines that a rule is not expected to have a significant impact on a substantial number of small entities. This proposed rule would serve to facilitate the transportation of hazardous#
Passage 48materials in international commerce by providing consistency with international standards. This proposed rule applies to offerors and carriers of hazardous materials, some of whom are small entities, such as chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, and training companies. As discussed above, under Executive Order 12866, the majority of amendments in this proposed rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America. Many companies will realize economic benefits as a result of the proposed amendments. If the changes proposed in this NPRM are not adopted, U.S. companies, including small entities competing in foreign markets, will be forced to comply with a dual system of regulations to their economic disadvantage. Therefore, I certify that these proposed amendments will not have a significant economic impact on a substantial number of small entities. This certification is subject to modification as a result of a review of comments received in response to this proposed rulemaking. This proposed rule has been developed in accordance with Executive Order 13272 (``Proper Consideration of Small Entities in Agency Rulemaking'') and DOT's procedures and policies to promote compliance with the Regulatory Flexibility Act to ensure that potential impacts of draft rules on small entities are properly considered.#
Passage 49Under the Paperwork Reduction Act of 1995, no person is required to respond to a collection of information unless it displays a valid Office of Management and Budget (OMB) control number. Section 1320.8(d), title 5, Code of Federal Regulations requires that RSPA provide interested members of the public and affected agencies an opportunity to comment on information collection and recordkeeping requests. RSPA currently has two approved information collections affecting this proposed rule: OMB Control Number 2137-0557, ``Approvals for Hazardous Materials'' with 25,605 burden hours and $562,837.40 burden costs; and OMB Control Number 2137-0613, ``Subsidiary Hazard Class & Number/Type of Packagings'' with 63,309 burden hours and $216,705 burden costs. There would be only minor editorial changes proposed under this rule. However, there is no net increase in burden for OMB Control Number 2137-0557 or OMB Control Number 2137-0613. We estimate that the proposed total information collection and recordkeeping burden as follows: ``Approvals for Hazardous Materials,'' OMB Number 2137-0557: Total Annual Number of Respondents: 3,523. Total Annual Responses: 3,874.8. Total Annual Burden Hours: 25,605. Total Annual Burden Cost: $562,837.40. ``Subsidiary Hazard Class & Number/Type of Packagings,'' OMB Number 2137-0613: Total Annual Number of Respondents: 250,000. Total Annual Responses: 6,337,500. Total Annual Burden Hours: 17,604. Total Annual Burden Cost: $216,705. Total First Year Burden Hours: 45,705. Total First Year Burden Cost: $1,115,992. Requests for a copy of this information collection should be directed to Deborah Boothe or T. Glenn Foster, Office of Hazardous Materials Standards (DHM-10), Research and Special Programs Administration, Room 8422, 400 Seventh Street, SW., Washington, DC 20590-0001, telephone (202) 366-8553. Written comments should be addressed to the Dockets Unit identified in the ADDRESSES section of this rulemaking. We should receive comments regarding information collection burdens prior to the close of the comment period identified in the DATES section of this rulemaking.#
Passage 50A regulation identifier number (RIN) is assigned to each regulatory actionlisted in the Unified Agenda of Federal Regulations. The Regulatory Information Service Center publishes the Unified Agenda in April and October of each year. The RIN contained in the heading of this document can be used to cross-reference this action with the Unified Agenda. This final rule does not impose unfunded mandates under the Unfunded Mandates Reform Act of 1995. It does not result in costs of $120.7 million or more to either State, local or tribal governments, in the aggregate, or to the private sector, and is the least burdensome alternative that achieves the objective of the rule. The National Environmental Policy Act of 1969 (NEPA) requires Federal agencies to consider the consequences of major Federal actions and prepare a detailed statement on actions significantly affecting the quality of the human environment. We developed an assessment to determine the effects of these revisions on the environment and whether a more comprehensive environmental impact statement may be required. Our findings conclude that there are no significant environmental impacts associated with this proposed rule. Consistency in the regulations for the transportation of hazardous materials aids in the shipper's understanding of what is required and permits shippers to more easily comply with safety regulations and avoid the potential for environmental damage or contamination. For interested parties, an environmental assessment is available in the public docket. Anyone is able to search the electronic form of any written communications and comments received into any of our dockets by the name of the individual submitting the document (or signing the document, if submitted on behalf of an association, business, labor union, etc.). You may review DOT's complete Privacy Act Statement in the Federal Register published on April 11, 2000 (volume 65, number 70; pages 19477-78), or you may visit http://dms.dot.gov. Exports, Hazardous materials transportation, Hazardous waste, Imports, Incorporation by reference, Reporting and recordkeeping requirements. Education, Hazardous materials transportation, Hazardous waste, Labeling, Markings, Packaging and containers, Reporting and recordkeeping requirements.#
Passage 51Hazardous materials transportation, Packaging and containers, Radioactive materials, Reporting and recordkeeping requirements, Uranium. Air carriers, Hazardous materials transportation, Radioactive materials, Reporting and recordkeeping requirements. Hazardous materials transportation, Maritime carriers, Radioactive materials, Reporting and recordkeeping requirements. Hazardous materials transportation, Motor vehicle safety, Packaging and containers, Reporting and recordkeeping requirements. Hazardous materials transportation, Motor carriers, Motor vehicle safety, Packaging and containers, Railroad safety, Reporting and recordkeeping requirements. In consideration of the foregoing, 49 CFR Chapter I is proposed to be amended as follows: PART 171--GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS 1. The authority citation for part 171 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 2. In Sec. 171.7, in the paragraph (a)(3) table, the following changes are made: a. Under the entry ``International Civil Aviation Organization (ICAO),'' the existing entry is revised; b. Under the entry ``International Maritime Organization (IMO),'' the entry ``International Maritime Dangerous Goods (IMDG) Code, 2002 Consolidated Edition, as amended by Amendment 31 (English edition)'' is revised; c. Under the entry ``United Nations,'' the entry ``UN Recommendations on the Transport of Dangerous Goods, Twelfth Revised Edition (2001)'' is revised; d. Under the entry ``United Nations,'' the entry ``UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Third Revised Edition (1999)'' is revised; and e. In Paragraph (b), under the entry ``The Society of the Plastics Industry, Inc., Organic Peroxide Producers Safety Division, 1275 K Street NW., Suite 400, Washington, DC 20005,'' the entry ``Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology'' would be added. The revisions and additions would read as follows: (a) * * * (3) Table of material incorporated by reference.* * * ------------------------------------------------------------------------ Source and name of material 49 CFR reference ------------------------------------------------------------------------ * * * * * * * International Civil Aviation Organization (ICAO),#
Passage 52* * * * * * * Technical Instructions for the Safe Transport 171.11; 172.202; 172.323; of Dangerous Goods by Air (ICAO Technical 172.401; 172.512; Instructions), 2005-2006 Edition. 172.602. International Maritime Organization (IMO), * * * * * * * International Maritime Dangerous Goods Code 171.12; 172.401; 172.502; (IMDG Code), as amended by Amendment 32 173.21; 176.2; 176.5; (English Edition). 176.11; 176.27; 176.30. * * * * * * * UN Recommendations on the Transport of 172.401; 172.407; Dangerous Goods, Thirteenth Revised Edition 172.502; 173.24. (2002). UN Recommendations on the Transport of 172.102; 173.21; 173.56; Dangerous Goods, Manual of Tests and 173.57; 173.124; Criteria, Fourth Revised Edition, (2003). 173.128; 173.166; 173.185. * * * * * * * ------------------------------------------------------------------------ (b) List of informational materials not requiring incorporation by reference. * * * ------------------------------------------------------------------------ Source and name of material 49 CFR reference ------------------------------------------------------------------------ * * * * * * * The Society of the Plastics Industry, Inc., Organic Peroxide Producers Safety Division, 1275 K Street NW., Suite 400, Washington, D.C. 20005. Example of a Test Method for Venting Sizing: Note to OPPSD/SPI Methodology. 173.225(h)(3)(vi). * * * * * * * ------------------------------------------------------------------------ 3. In Sec. 171.8, the definition for ``Salvage packaging'' is revised to read as follows: Sec. 171.8 Definitions and abbreviations. * * * * * Salvage packaging means a special packaging conforming to Sec. 173.3 of this subchapter into which damaged, defective, leaking, or non-conforming hazardous materials packages, or hazardous materials that have spilled or leaked, are placed for purposes of transport for recovery or disposal. * * * * * 4. In Sec. 171.11, paragraphs (d)(15) and (d)(17) are revised to read as follows: Sec. 171.11 Use of ICAO Technical Instructions.#
Passage 53* * * * * (d) * * * (15) A chemical oxygen generator, including when fitted in protective breathing equipment or other apparatus, is forbidden for transportation aboard a passenger-carrying aircraft and must be approved, classed, described and packaged in accordance with the requirements of this subchapter for transportation on cargo-only aircraft. A chemical oxygen generator that has been used or spent is also forbidden for transportation on aircraft. * * * * * (17) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in Sec. 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in Sec. 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. 5. In Sec. 171.12, paragraph (b)(20) is revised to read as follows: Sec. 171.12 Import and export shipments. * * * * * (b) * * * (20) A self-reactive substance that is not identified by technical name in the Self-Reactive Materials Table in Sec. 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in Sec. 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. * * * * * 6. In Sec. 171.12a, paragraphs (a), (b)(9), and (b)(18) are revised to read as follows: Sec. 171.12a Canadian shipments and packagings.#
Passage 54(a) Scope and applicability. This section sets forth provisions for the transportation by rail or highway of shipments of hazardous materials which conform to the regulations of the Government of Canada but which may differ from the requirements of this subchapter with regard to hazard communication, classification or packaging. Except as provided in paragraph (b)(5)(iv) of this section, the provisions apply only to shipments which originate in Canada and either terminate in the U.S. or transit the U.S. to a Canadian or foreign destination, and to the return to Canada of bulk packagings that meet the requirements of a DOT or UN Specification and other bulk packagings containing only residues of hazardous materials that were originally imported into the U.S. Reciprocal provisions, applicable to exports from the U.S., appear in the regulations of the Government of Canada. (b) * * * (9) For hazardous waste as defined in this subchapter-- (i) The word ``Waste'' must precede the proper shipping name on shipping papers and packages; and (ii) The requirements of Sec. 172.204 of this subchapter with respect to the shippers certification and Sec. 172.205 of this subchapter with respect to hazardous waste manifests are applicable; * * * * * (18) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in Sec. 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in Sec. 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of Sec. 173.128(d) of this subchapter. * * * * * 7. In Sec. 171.14, paragraphs (d) introductory text, (d)(1), and (d)(2) introductory text are revised to read as follows: Sec. 171.14 Transitional provisions for implementing certain requirements.#
Passage 55* * * * * (d) A final rule published in the Federal Register on [INSERT PUBLICATION DATE OF FINAL RULE], effective October 1, 2004, resulted in revisions to this subchapter. During the transition period, until January 1, 2006, as provided in paragraph (d)(1) of this section, a person may elect to comply with either the applicable requirements of this subchapter in effect on December 31, 2005, or the requirements published in the [INSERT PUBLICATION DATE OF FINAL RULE] final rule. (1) Transition dates. The effective date of the final rule published on [INSERT PUBLICATION DATE OF FINAL RULE] is October 1, 2004. A delayed compliance date of January 1, 2006 is authorized. On and after January 1, 2006, all applicable regulatory requirements adopted in the final rule in effect on October 1, 2004 must be met. (2) Intermixing old and new requirements. Marking, labeling, placarding, and shipping paper descriptions must conform to either the old requirements of this subchapter in effect on September 30, 2004, or the new requirements of this subchapter in the final rule without intermixing communication elements, except that intermixing is permitted, during the applicable transition period, for packaging, hazard communication, and handling provisions, as follows: * * * * * PART 172--HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND TRAINING REQUIREMENTS 8. The authority citation for part 172 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 9. In Sec. 172.101, the following amendments are made: a. paragraph (c)(11) is revised; b. paragraph (d)(4) is revised; c. paragraph (i)(3) is revised; d. Hazardous Materials Table is revised as set forth below: Sec. 172.101 Purpose and use of hazardous materials table.#
Passage 56* * * * * (c) * * * (11) Except for a material subject to or prohibited by Sec. 173.21, 173.54, 173.56(d), 173.56(e), 173.224(c) or 173.225(b) of this subchapter, a material that is considered to be a hazardous waste or a sample of a material for which the hazard class is uncertain and must be determined by testing may be assigned a tentative proper shipping name, hazard class, identification number and packing group, if applicable, based on the shipper's tentative determination according to: (i) Defining criteria in this subchapter; (ii) The hazard precedence prescribed in Sec. 173.2a of this subchapter; (iii) The shipper's knowledge of the material; (iv) In addition to paragraphs (c)(11)(i) through (iii) of this section, for a sample of a material other than a waste, the following must be met: (A) Except when the word ``Sample'' already appears in the proper shipping name, the word ``Sample'' must appear as part of the proper shipping name or in association with the basic description on the shipping paper. (B) When the proper shipping description for a sample is assigned a ``G'' in Column (1) of the Sec. 172.101 Table, and the primary constituent(s) for which the tentative classification is based are not known, the provisions requiring a technical name for the constituent(s) do not apply; and (C) A sample must be transported in a combination packaging that conforms to the requirements of this subchapter that are applicable to the tentative packing group assigned, and may not exceed a net mass of 2.5 kg (5.5 pounds) per package. Note to Paragraph (c)(11): For the transportation of self- reactive, organic peroxide and explosive samples, see Sec. Sec. 173.224(c)(3), 173.225(b)(2) and 173.56(d) of this subchapter, respectively.#
Passage 57* * * * * (d) * * * (4) When an entry in this column reads ``Comb liq'', the material is assigned to the hazard class ``Combustible liquid.'' Additionally, each reference to a Class 3 material is modified to read ``Combustible liquid'' when that material is reclassified in accordance with Sec. 173.150 (e) or (f) of this subchapter or has a flash point above 60.5 [deg]C (141 [deg]F) but below 93 [deg]C (200 [deg]F). * * * * * (i) * * * (3) Bulk packaging. Column 8C specifies the section in part 173 of this subchapter that prescribes packaging requirements for bulk packagings, subject to the limitations, requirements and additional authorizations of Column 7. A ``None'' in this column means bulk packagings are not authorized, except as may be provided by special provisions in Column 7. Additional authorizations and limitations for use of UN portable tanks are set forth in Column 7. For each reference in this column to a material that is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter ``A'' or ``W'' and that is offered for transportation or transported by a mode in which its transportation is not otherwise subject to the requirements of this subchapter: * * * * * Sec. 172.101 Hazardous Materials Table ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ (8) Packaging (Sec. 173.***) (9) Quantity (10) Vessel --------------------------------------- limitations stowage Hazardous materials Hazard Identification Label Special ---------------------------------------------- Symbols descriptions and proper class or Numbers PG Codes provisions (Sec. Passenger shipping names Division 172.102) Exceptions Non-bulk Bulk aircraft/ Cargo air- Location Other rail craft only ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ (1) (2)........................ (3) (4) (5) (6)...... (7) (8A)......... (8B)...... (8C)...... (9A) (9B) (10A) (10B) --------#
Passage 58Accellerene, see p- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrosodimethylaniline. Accumulators, electric, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Batteries, wet etc. Accumulators, pressurized, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... pneumatic or hydraulic (containing non-flamable gas), see Articles pressurized, pneumatic or hydraulic (containing non- flamable gas). Acetal..................... 3 UN1088 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Acetaldehyde............... 3 UN1089 I 3........ A3, B16, T11, None......... 201....... 243....... Forbidden 30 L E ....... TP2, TP7 A Acetaldehyde ammonia....... 9 UN1841 III 9........ IB8, IP3, IP7, 155.......... 204....... 240....... 200 kg 200 kg A 34 T1, TP33 Acetaldehyde oxime......... 3 UN2332 III 3........ B1, IB3, T4, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Acetic acid, glacial or 8 UN2789 II 8, 3..... A3, A6, A7, A10, 154.......... 202....... 243....... 1 L 30 L A ....... Acetic acid solution, with B2, IB2, T7, TP2 more than 80 percent acid, by mass. Acetic acid solution, not 8 UN2790 II 8........ A3, A6, A7, A10, 154.......... 202....... 242....... 1 L 30 L A ....... less than 50 percent but B2, IB2, T7, TP2 not more than 80 percent acid, by mass. Acetic acid solution, with 8 UN2790 III 8........ IB3, T4, TP1 154.......... 203....... 242....... 5 L 60 L A ....... more than 10 percent and less than 50 percent acid, by mass. Acetic anhydride........... 8 UN1715 II 8, 3..... A3, A6, A7, A10, 154.......... 202....... 243....... 1 L 30 L A 40 B2, IB2, T7, TP2 Acetone.................... 3 UN1090 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Acetone cyanohydrin, 6.1 UN1541 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 25, 40, stabilized. B76, B77, N34, 52, 53 T20, TP2, TP13, TP38, TP45 Acetone oils............... 3 UN1091 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8 Acetonitrile............... 3 UN1648 II 3........ IB2, T7, TP2 1#
Passage 5950.......... 202....... 242....... 5 L 60 L B 40 Acetyl acetone peroxide Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 9 percent by mass active oxygen. Acetyl benzoyl peroxide, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solid, or with more than 40 percent in solution. Acetyl bromide............. 8 UN1716 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L C 40 TP2, TP12 Acetyl chloride............ 3 UN1717 II 3, 8..... A3, A6, A7, IB1, 150.......... 202....... 243....... 1 L 5 L B 40 N34, T8, TP2, TP12 Acetyl cyclohexanesulfonyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxide, with more than 82 percent wetted with less than 12 percent water. Acetyl iodide.............. 8 UN1898 II 8........ B2, IB2, T7, 154.......... 202....... 242....... 1 L 30 L C 40 TP2, TP13 Acetyl methyl carbinol..... 3 UN2621 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Acetyl peroxide, solid, or Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 25 percent in solution. Acetylene, dissolved....... 2.1 UN1001 ....... 2.1...... ................ None......... 303....... None...... Forbidden 15 kg D 25, 40, 57 Acetylene (liquefied)...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Acetylene silver nitrate... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Acetylene tetrabromide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetrabromoethane. Acid butyl phosphate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Butyl acid phosphate. Acid, sludge, see Sludge ........... ................. ....... ......... ................ ...........#
Passage 60.. .......... .......... ........... ........... .......... ....... acid. Acridine................... 6.1 UN2713 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Acrolein dimer, stabilized. 3 UN2607 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 40 Acrolein, stabilized....... 6.1 UN1092 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B42, B72, B77, T22, TP2, TP7, TP13, TP38, TP44 Acrylamide, solid.......... 6.1 UN2074 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 12 TP33 Acrylamide solution........ 6.1 UN3426 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 12 Acrylic acid, stabilized... 8 UN2218 II 8, 3..... B2, IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L C 25, 40 Acrylonitrile, stabilized.. 3 UN1093 I 3, 6.1... B9, T14, TP2, None......... 201....... 243....... Forbidden 30 L E 40 TP13 Actuating cartridge, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... explosive, see Cartridges, power device. Adhesives, containing a 3 UN1133 I 3........ B42, T11, TP1, 150.......... 201....... 143....... 1 L 30 L B ....... flammable liquid. TP8, TP27 ........................... ........... ................. II 3........ 149, B52, IB2, 150.......... 173....... 242....... 5 L 60 L B ....... T4, TP1, TP8#
Passage 61........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 173....... 242....... 60 L 220 L A ....... T2, TP1 Adiponitrile............... 6.1 UN2205 III 6.1...... IB3, T3, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Aerosols, corrosive, 2.2 UN1950 ....... 2.2, 8... 153, A34 306.......... None...... None...... 75 kg 150 kg A 48, 87, Packing Group II or III, 126 (each not exceeding 1 L capacity). Aerosols, flammable, (each 2.1 UN1950 ....... 2.1...... 153, N82 306.......... None...... None...... 75 kg 150 kg A 48, 87, not exceeding 1 L 126 capacity). Aerosols, flammable, n.o.s. 2.1 UN1950 ....... 2.1...... 153, N82 306.......... 304....... None...... Forbidden 150 kg A 48, 87, (engine starting fluid) 126 (each not exceeding 1 L capacity). Aerosols, non-flammable, 2.2 UN1950 ....... 2.2...... 153 306, 307..... None...... None...... 75 kg 150 kg A 48, 87, (each not exceeding 1 L 126 capacity). Aerosols, poison, each not 2.2 UN1950 ....... 2.2, 6.1. 153 306.......... None...... None...... Forbidden Forbidden A 48, 87, exceeding 1 L capacity. 126 I Air bag inflators, or Air 1.4G UN0503 II 1.4G..... 161 None......... 62........ None...... Forbidden 75 kg 02 ....... bag modules, or Seat-belt pretensioners.. Air bag inflators, or Air 9 UN3268 III 9........ 160 166.......... 166....... 166....... 25 kg 100 kg A ....... bag modules, or Seat-belt pretensioners.. Air, compressed............ 2.2 UN1002 ....... 2.2...... 78 306.......... 302....... 302....... 75 kg 150 kg A ....... Air, refrigerated liquid, 2.2 UN1003 ....... 2.2, 5.1. T75, TP5, TP22 320.......... 316....... 318, 319.. Forbidden 150 kg D 51 (cryogenic liquid). Air, refrigerated liquid, 2.2 UN1003 ....... 2.2, 5.1. T75, TP5, TP22 320.......... 316....... 318, 319.. Forbidden Forbidden D 51 (cryogenic liquid) non- pressurized. Aircraft engines (including ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... turbines), see Engines, internal combustion. Aircraft evacuation slides, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Life saving appliances etc. Aircraft hydraulic power 3 UN3165 I 3, 6.1, 8 ................ None......... 172....... None...... Forbidden 42 L#
Passage 62E ....... unit fuel tank (containing a mixture of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel). Aircraft survival kits, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Life saving appliances etc. G Alcoholates solution, 3 UN3274 II 3, 8..... IB2 150.......... 202....... 243....... 1 L 5 L B ....... n.o.s., in alcohol. Alcoholic beverages........ 3 UN3065 II 3........ 24, 149, B1, 150.......... 202....... 242....... 5 L 60 L A ....... IB2, T4, TP1 ........................... ........... ................. III 3........ 24, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... N11, T2, TP1 Alcohols, n.o.s............ 3 UN1987 I 3........ T11, TP1, TP8, None......... 201....... 243....... 1 L 30 L E ....... TP27 ........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP29 G Alcohols, flammable, toxic, 3 UN1986 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L E 40 n.o.s.. TP27 ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP27 ........................... ........... ................. III 3, 6.1... B1, IB3, T7, None......... 203....... 242....... 60 L 220 L A ....... TP1, TP28 Aldehydes, n.o.s........... 3 UN1989 I 3........ T11, TP1, TP27 None......... 201....... 243....... 1 L 30 L E ....... ........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP29 G Aldehydes, flammable, 3 UN1988 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L E 40 toxic, n.o.s.. TP27 ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP27 ........................... ........... ................. III 3, 6.1... B1, IB3, T7, 150.......... 203....... 242....... 60 L 2#
Passage 6320 L A ....... TP1, TP28 Aldol...................... 6.1 UN2839 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 12 G Alkali metal alcoholates, 4.2 UN3206 II 4.2, 8... 64, A7, IB5, None......... 212....... 242....... 15 kg 50 kg B ....... self-heating, corrosive, IP2, T3, TP33 n.o.s.. ........................... ........... ................. III 4.2, 8... 64, A7, IB8, None......... 213....... 242....... 25 kg 100 kg B ....... IP3, T1, TP33 Alkali metal alloys, 4.3 UN1421 I 4.3...... A2, A3, A7, B48, None......... 201....... 244....... Forbidden 1 L D 52 liquid, n.o.s.. N34 Alkali metal amalgam, 4.3 UN1389 I 4.3...... A2, A3, A7, N34 None......... 201....... 244....... Forbidden 1 L D 40, 52 liquid. Alkali metal amalgam, solid 4.3 UN3401 I 4.3...... IB4, IP1, N40, None......... 211....... 242....... Forbidden 15 kg D 52 T9, TP7, TP33#
Passage 64Alkali metal amides........ 4.3 UN1390 II 4.3...... A6, A7, A8, A19, 151.......... 212....... 241....... 15 kg 50 kg E 40, 52 A20, IB7, IP2, T3, TP33 Alkali metal dispersions, 4.3 UN1391 I 4.3...... A2, A3, A7 None......... 201....... 244....... Forbidden 1 L D 52 or Alkaline earth metal dispersions. Alkaline corrosive liquids, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... n.o.s., see Caustic alkali liquids, n.o.s.. G Alkaline earth metal 4.2 UN3205 II 4.2...... 65, A7, IB6, None......... 212....... 241....... 15 kg 50 kg B ....... alcoholates, n.o.s.. IP2, T3, TP33 ........................... ........... ................. III 4.2...... 65, A7, IB8, None......... 213....... 241....... 25 kg 100 kg B ....... IP3, T1, TP33 Alkaline earth metal 4.3 UN1393 II 4.3...... A19, IB7, IP2, 151.......... 212....... 241....... 15 kg 50 kg E 52 alloys, n.o.s.. T3, TP33 Alkaline earth metal 4.3 UN1392 I 4.3...... A19, N34, N40 None......... 201....... 244....... Forbidden 1 L E 40, 52 amalgams, liquid. Alkaline earth metal 4.3 UN3402 I 4.3...... A19, N34, N40, None......... 211....... 242....... Forbidden 15 kg D 52 amalgams, solid. T9, TP7, TP33 G Alkaloids, liquid, n.o.s., 6.1 UN3140 I 6.1...... A4, T14, TP2, None......... 201....... 243....... 1 L 30 L A ....... or Alkaloid salts, liquid, TP27 n.o.s.. ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L A ....... TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A ....... TP28 G Alkaloids, solid, n.o.s. 6.1 UN1544 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A ....... [or] Alkaloid salts, TP33 solid, n.o.s. [poisonous]. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Alkyl sulfonic acids, 8 UN2584 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L B ....... liquid or Aryl sulfonic TP2, TP12, TP13 acids, liquid with more than 5 percent free sulfuric acid. Alkyl#
Passage 65sulfonic acids, 8 UN2586 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L B ....... liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid. Alkyl sulfonic acids, solid 8 UN2583 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... or Aryl sulfonic acids, T3, TP33 solid, with more than 5 percent free sulfuric acid. Alkyl sulfonic acids, solid 8 UN2585 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... or Aryl sulfonic acids, TP33 solid with not more than 5 percent free sulfuric acid. Alkylphenols, liquid, 8 UN3145 I 8........ A6, T14, TP2 None......... 201....... 243....... 0.5 L 2.5 L B ....... n.o.s. (including C2-C12 homologues). ........................... ........... ................. II 8........ IB2, T11, TP2, 154.......... 202....... 242....... 1 L 30 L B ....... TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A ....... TP28 Alkylphenols, solid, n.o.s. 8 UN2430 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg B ....... (including C2-C12 TP33 homologues). ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg B ....... T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Alkylsulfuric acids........ 8 UN2571 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L C 14 TP2, TP12, TP13, TP28 Allethrin, see Pesticides, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquid, toxic, n.o.s.. Allyl acetate.............. 3 UN2333 II 3, 6.1... IB2, T7, TP1, 150.......... 202....... 243....... 1 L 60 L E 40 TP13 Allyl alcohol.............. 6.1 UN1098 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Allyl bromide.............. 3 UN1099 I 3, 6.1... T14, TP2, TP13 None......... 201....... 243....... Forbidden 30 L B 40 Allyl chloride............. 3 UN1100 I 3, 6.1... T14, TP2, TP13 None......... 201....... 243....... Forbidden 30 L E 40 Allyl chlorocarbonate, see ......#
Passage 66..... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Allyl chloroformate. Allyl chloroformate........ 6.1 UN1722 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, N41, T20, TP2, TP13, TP38, TP45 Allyl ethyl ether.......... 3 UN2335 II 3, 6.1... IB2, T7, TP1, 150.......... 202....... 243....... 1 L 60 L E 40 TP13 Allyl formate.............. 3 UN2336 I 3, 6.1... T14, TP2, TP13 None......... 201....... 243....... Forbidden 30 L E 40 Allyl glycidyl ether....... 3 UN2219 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Allyl iodide............... 3 UN1723 II 3, 8..... A3, A6, IB1, 150.......... 202....... 243....... 1 L 5 L B 40 N34, T7, TP2, TP13 Allyl isothiocyanate, 6.1 UN1545 II 6.1, 3... A3, A7, IB2, T7, None......... 202....... 243....... Forbidden 60 L D 40 stabilized. TP2 Allylamine................. 6.1 UN2334 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45#
Passage 67Allyltrichlorosilane, 8 UN1724 II 8, 3..... A7, B2, B6, IB2, None......... 202....... 243....... Forbidden 30 L C 40 stabilized. N34, T7, TP2, TP13 Aluminum alkyl halides, 4.2 UN3052 I 4.2, 4.3. B9, B11, T21, None......... 181....... 244....... Forbidden Forbidden D 134 liquid. TP2, TP7 Aluminium alkyl halides, 4.2 UN3461 I 4.2, 4.3. T21, TP7, TP33 None......... 181....... 244....... Forbidden Forbidden D 134 solid. Aluminum alkyl hydrides.... 4.2 UN3076 I 4.2, 4.3. B9, B11, T21, None......... 181....... 244....... Forbidden Forbidden D ....... TP2, TP7 Aluminum alkyls............ 4.2 UN3051 I 4.2, 4.3. B9, B11, T21, None......... 181....... 244....... Forbidden Forbidden D ....... TP2, TP7 Aluminum borohydride or 4.2 UN2870 I 4.2, 4.3. B11, T21, TP7, None......... 181....... 244....... Forbidden Forbidden D ....... Aluminum borohydride in TP33 devices. Aluminum bromide, anhydrous 8 UN1725 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 40 T3, TP33 Aluminum bromide, solution. 8 UN2580 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Aluminum carbide........... 4.3 UN1394 II 4.3...... A20, IB7, IP2, 151.......... 212....... 242....... 15 kg 50 kg A 52 N41, T3, TP33 Aluminum chloride, 8 UN1726 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 40 anhydrous. T3, TP33 Aluminum chloride, solution 8 UN2581 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Aluminum dross, wet or hot. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Aluminum ferrosilicon 4.3 UN1395 II 4.3, 6.1. A19, IB5, IP2, 151.......... 212....... 242....... 15 kg 50 kg A 39, 40, powder. T3, TP33 52, 53, 85, 103 ........................... ........... ................. III 4.3, 6.1. A19, A20, IB4 151.......... 213....... 241....... 25 kg 100 kg A 39, 40, 52, 53, 85, 103 Aluminum hydride........... 4.3 UN2463 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E ....... D Aluminum, molten........... 9 NA9260 III 9........ IB3, T1, TP3 None......... None...... 247....... Forbidden Forbidden D ....... Aluminum nitrate........... 5.1 UN1438 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Aluminum phosphate ..........#
Passage 68. ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Corrosive liquids, etc. Aluminum phosphide......... 4.3 UN1397 I 4.3, 6.1. A8, A19, N40 None......... 211....... 242....... Forbidden 15 kg E 40, 52, 85 Aluminum phosphide 6.1 UN3048 I 6.1...... A8, IB7, IP1, None......... 211....... 242....... Forbidden 15 kg E 40, 85 pesticides. T6, TP33 Aluminum powder, coated.... 4.1 UN1309 II 4.1...... IB8, IP2, IP4, 151.......... 212....... 240....... 15 kg 50 kg A 13, 39, T3, TP33 52, 53, 74, 101 ........................... ........... ................. III 4.1...... IB8, IP3, T1, 151.......... 213....... 240....... 25 kg 100 kg A 13, 39, TP33 52, 53, 74, 101 Aluminum powder, uncoated.. 4.3 UN1396 II 4.3...... A19, A20, IB7, 151.......... 212....... 242....... 15 kg 50 kg A 39, 52, IP2, T3, TP33 53 ........................... ........... ................. III 4.3...... A19, A20, IB8, 151.......... 213....... 241....... 25 kg 100 kg A 39, 52, IP4, T1, TP33 53 Aluminum resinate.......... 4.1 UN2715 III 4.1...... IB6, T1, TP33 151.......... 213....... 240....... 25 kg 100 kg A ....... Aluminum silicon powder, 4.3 UN1398 III 4.3...... A1, A19, IB8, 151.......... 213....... 241....... 25 kg 100 kg A 39, 40, uncoated. IP4, T1, TP33 52, 53, 85, 103 Aluminum smelting by- 4.3 UN3170 II 4.3...... 128, B115, IB7, None......... 212....... 242....... 15 kg 50 kg B 85, 103 products or Aluminum IP2, T3, TP33 remelting by-products. ........................... ........... ................. III 4.3...... 128, B115, IB8, None......... 213....... 241....... 25 kg 100 kg B 85, 103 IP4, T1, TP33 Amatols, see Explosives, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... blasting, type B. G Amines, flammable, 3 UN2733 I 3, 8..... T14, TP1, TP27 None......... 201....... 243....... 0.5 L 2.5 L D 40 corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s.. ........................... ........... ................. II 3, 8..... IB2, T11, TP1, 150.......... 202....... 243....... 1 L 5 L B 40 TP27 ........................... ........... ................. III 3, 8..... B1, IB3, T7, 150.......... 203....... 242....... 5 L 60 L A 40 TP1, TP28 G Amines, liquid, corrosive, 8 UN2734 I 8, 3..... A3, A6, N34, None#
Passage 69......... 201....... 243....... 0.5 L 2.5 L A 52 flammable, n.o.s. or T14, TP2, TP27 Polyamines, liquid, corrosive, flammable, n.o.s.. ........................... ........... ................. II 8, 3..... IB2, T11, TP2, None......... 202....... 243....... 1 L 30 L A 52 TP27#
Passage 70G Amines, liquid, corrosive, 8 UN2735 I 8........ A3, A6, B10, None......... 201....... 243....... 0.5 L 2.5 L A 52 n.o.s., or Polyamines, N34, T14, TP2, liquid, corrosive, n.o.s.. TP27 ........................... ........... ................. II 8........ B2, IB2, T11, 154.......... 202....... 242....... 1 L 30 L A 52 TP1, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 52 TP28 G Amines, solid, corrosive, 8 UN3259 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg A 52 n.o.s., or Polyamines, TP33 solid, corrosive n.o.s.. ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 52 T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 52 TP33 2-Amino-4-chlorophenol..... 6.1 UN2673 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 2-Amino-5- 6.1 UN2946 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... diethylaminopentane. 2-Amino-4,6-Dinitrophenol, 4.1 UN3317 I 4.1...... 23, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28, 36 wetted with not less than A20, N41 20 percent water by mass. 2-(2-Aminoethoxy) ethanol.. 8 UN3055 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... N-Aminoethylpiperazine..... 8 UN2815 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A 12 + Aminophenols (o-; m-; p-).. 6.1 UN2512 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Aminopropyldiethanolamine, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Amines, etc. n-Aminopropylmorpholine, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Amines, etc. Aminopyridines (o-; m-; p-) 6.1 UN2671 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 12, 40 T3, TP33 I Ammonia, anhydrous......... 2.3 UN1005 ....... 2.3, 8... 4, T50 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 57 D Ammonia, anhydrou#
Passage 71s......... 2.2 UN1005 ....... 2.2...... 13, T50 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 57 D Ammonia solution, relative 2.2 UN3318 ....... 2.2...... 13, T50 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 57 density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia. I Ammonia solution, relative 2.3 UN3318 ....... 2.3, 8... 4, T50 None......... 304....... 314, 315.. Forbidden 25 kg D 40, 57 density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia. Ammonia solutions, relative 8 UN2672 III 8........ IB3, IP8, T7, 154.......... 203....... 241....... 5 L 60 L A 40, 85 density between 0.880 and TP1 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia. Ammonia solutions, relative 2.2 UN2073 ....... 2.2...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg E 40, 57 density less than 0.880 at 15 degrees C in water, with more than 35 percent but not more than 50 percent ammonia. Ammonium arsenate.......... 6.1 UN1546 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 53 T3, TP33 Ammonium azide............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonium bifluoride, solid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Ammonium hydrogen difluoride, solid. Ammonium bifluoride ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Ammonium hydrogen difluoride, solution. Ammonium bromate........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonium chlorate.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonium dichromate........ 5.1 UN1439 II 5.1...... IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A 52 T3, TP33 Ammonium dinitro-o- 6.1 UN1843 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 36, 65, cresolate, solid. T3, TP33 66, 77 Ammonium dinit#
Passage 72ro-o- 6.1 UN3424 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L B 36, 66, cresolate solution. 78, 91 ........................... ........... ................. III 6.1...... IB2, T7, TP2 153.......... 203....... 241....... 60 L 220 L A 36, 66, 78, 91 Ammonium fluoride.......... 6.1 UN2505 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Ammonium fluorosilicate.... 6.1 UN2854 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Ammonium fulminate......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonium hydrogen sulfate.. 8 UN2506 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 40 T3, TP33 Ammonium 8 UN1727 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 25, 40, hydrogendifluoride, solid. N34, T3, TP33 52 Ammonium 8 UN2817 II 8, 6.1... IB2, N34, T8, 154.......... 202....... 243....... 1 L 30 L B 40 hydrogendifluoride, TP2, TP12, TP13 solution. ........................... ........... ................. III 8, 6.1... IB3, N3, T4, 154.......... 203....... 241....... 5 L 60 L B 40, 95 TP1, TP12, TP13 Ammonium hydrosulfide, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Ammonium sulfide solution. D Ammonium hydroxide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonia solutions, etc. Ammonium metavanadate...... 6.1 UN2859 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 44, 89, T3, TP33 100, 141 Ammonium nitrate based 5.1 UN2067 III 5.1...... 52, 150, IB8, 152.......... 213....... 240....... 25 kg 100 kg B 48, 59, fertilizer. IP3, T1, TP33 60, 66, 117 A W Ammonium nitrate based 9 UN2071 III 9........ 132, IB8, IP3 155.......... 213....... 240....... 200 kg 200 kg A ....... fertilizer.#
Passage 73Ammonium nitrate emulsion 5.1 UN3375 II ......... 147, 163 None......... 214....... 214....... Forbidden Forbidden D 48, 59, or Ammonium nitrate 60, 66, suspension or Ammonium 124 nitrate gel, intermediate for blasting explosives. D Ammonium nitrate-fuel oil 1.5D NA0331 II 1.5D..... ................ None......... 62........ None...... Forbidden Forbidden 10 19E mixture containing only prilled ammonium nitrate and fuel oil. Ammonium nitrate, liquid 5.1 UN2426 ....... 5.1...... B5, T7 None......... None...... 243....... Forbidden Forbidden D 59, 60 (hot concentrated solution). Ammonium nitrate, with more 1.1D UN0222 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 19E than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance. Ammonium nitrate, with not 5.1 UN1942 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A 48, 59, more than 0.2% total IP3, T1, TP33 60, 116 combustible material, including any organic substance, calculated as carbon to the exclusion of any other added substance. Ammonium nitrite........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonium perchlorate....... 1.1D UN0402 II 1.1D..... 107 None......... 62........ None...... Forbidden Forbidden 10 19E Ammonium perchlorate....... 5.1 UN1442 II 5.1...... 107, A9, IB6, 152.......... 212....... 242....... 5 kg 25 kg E 58, 69 IP2, T3, TP33 Ammonium permanganate...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonium persulfate........ 5.1 UN1444 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Ammonium picrate, dry or 1.1D UN0004 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E, 19E wetted with less than 10 percent water, by mass. Ammonium picrate, wetted 4.1 UN1310 I 4.1...... 23, A2, N41 None......... 211....... None...... 0.5 kg 0.5 kg D 28, 36 with not less than 10 percent water, by mass. Ammonium polysulfide, 8 UN2818 II 8, 6.1... IB2, T7, TP2, 154.......... 202....... 243....... 1 L 30 L B 12, 40, solution. TP13 52 ........................... .........#
Passage 74.. ................. III 8, 6.1... IB3, T4, TP1, 154.......... 203....... 241....... 5 L 60 L B 12, 40, TP13 52 Ammonium polyvanadate...... 6.1 UN2861 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 44, 89, T3, TP33 100, 141 Ammonium silicofluoride, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Ammonium fluorosilicate. Ammonium sulfide solution.. 8 UN2683 II 8, 6.1, 3 IB1, T7, TP2, 154.......... 202....... 243....... 1 L 30 L B 12, 22, TP13 52, 100 Ammunition, blank, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cartridges for weapons, blank. Ammunition, illuminating 1.2G UN0171 II 1.2G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... with or without burster, expelling charge or propelling charge. Ammunition, illuminating 1.3G UN0254 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... with or without burster, expelling charge or propelling charge. Ammunition, illuminating 1.4G UN0297 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... with or without burster, expelling charge or propelling charge. Ammunition, incendiary 1.3J UN0247 II 1.3J..... ................ ............. 62........ None...... Forbidden Forbidden 04 23E liquid or gel, with burster, expelling charge or propelling charge. Ammunition, incendiary ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (water-activated contrivances) with burster, expelling charge or propelling charge, see Contrivances, water- activated, etc.. Ammunition, incendiary, 1.2H UN0243 II 1.2H..... ................ ............. 62........ None...... Forbidden Forbidden 08 8E, white phosphorus, with 14E, burster, expelling charge 15E, or propelling charge. 17E Ammunition, incendiary, 1.3H UN0244 II 1.3H..... ................ ............. 62........ None...... Forbidden Forbidden 08 8E, white phosphorus, with 14E, burster, expelling charge 15E, or propelling charge. 17E Ammunition, incendiary with 1.2G UN0009 II 1.2G..... ................ ............. 62........ None...... For#
Passage 75bidden Forbidden 03 ....... or without burster, expelling charge, or propelling charge. Ammunition, incendiary with 1.3G UN0010 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... or without burster, expelling charge, or propelling charge. Ammunition, incendiary with 1.4G UN0300 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... or without burster, expelling charge or propelling charge. Ammunition, practice....... 1.4G UN0362 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... Ammunition, practice....... 1.3G UN0488 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Ammunition, proof.......... 1.4G UN0363 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... Ammunition, rocket, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Warheads, rocket etc. Ammunition, SA (small ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... arms), see Cartridges for weapons, etc. Ammunition, smoke (water- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... activated contrivances), white phosphorus, with burster, expelling charge or propelling charge, see Contrivances, water- activated, etc. (UN 0248). Ammunition, smoke (water- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... activated contrivances), without white phosphorus or phosphides, with burster, expelling charge or propelling charge, see Contrivances, water- activated, etc. (UN 0249). Ammunition smoke, white 1.2H UN0245 II 1.2H..... ................ ............. 62........ None...... Forbidden Forbidden 08 8E, phosphorus with 14E, burster,expelling charge, 15E, or propelling charge. 17E Ammunition, smoke, white 1.3H UN0246 II 1.3H..... ................ ............. 62........ None...... Forbidden Forbidden 08 8E, phosphorus with burster, 14E, expelling charge, or 15E, propelling charge. 17E#
Passage 76Ammunition, smoke with or 1.2G UN0015 II 1.2G..... ................ ............. 62........ None...... Forbidden Forbidden .......... 8E, without burster, expelling 17E, charge or propelling 20E charge. Ammunition, smoke with or 1.3G UN0016 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden .......... 8E, without burster, expelling 17E, charge or propelling 20E charge. Ammunition, smoke with or 1.4G UN0303 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg .......... 7E, 8E, without burster, expelling 14E, charge or propelling 15E, charge. 17E Ammunition, sporting, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cartridges for weapons, etc. (UN 0012; UN 0328; UN 0339). Ammunition, tear-producing, 6.1 UN2017 II 6.1, 8... ................ None......... 212....... None...... Forbidden 50 kg E 13, 40 non-explosive, without burster or expelling charge, non-fuzed. Ammunition, tear-producing 1.2G UN0018 II 1.2G, 8, ................ ............. 62........ None...... Forbidden Forbidden .......... 8E, with burster, expelling 6.1. 17E, charge or propelling 20E charge. Ammunition, tear-producing 1.3G UN0019 II 1.3G, 8, ................ ............. 62........ None...... Forbidden Forbidden .......... 8E, with burster, expelling 6.1. 17E, charge or propelling 20E charge. Ammunition, tear-producing 1.4G UN0301 II 1.4G, 8, ................ ............. 62........ None...... Forbidden 75 kg .......... 7E, 8E, with burster, expelling 6.1. 14E, charge or propelling 15E, charge. 17E Ammunition, toxic, non- 6.1 UN2016 II 6.1...... ................ None......... 212....... None...... Forbidden 100 kg E 13, 40 explosive, without burster or expelling charge, non- fuzed. Ammunition, toxic (water- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... activated contrivances), with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. G Ammunition, toxic with 1.2K UN0020 II 1.2K, 6.1 ................ ............. 62........ None...... Forbidden Forbidden 08 8E, burster, expelling charge, 14E, or propelling charge. 15E, 17E G Ammunition, toxic with 1.3K UN0021 II 1.3K, 6.1 ................ ....#
Passage 77......... 62........ None...... Forbidden Forbidden 08 8E, burster, expelling charge, 14E, or propelling charge. 15E, 17E Amyl acetates.............. 3 UN1104 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Amyl acid phosphate........ 8 UN2819 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Amyl butyrates............. 3 UN2620 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Amyl chlorides............. 3 UN1107 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Amyl formates.............. 3 UN1109 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Amyl mercaptans............ 3 UN1111 II 3........ A3, A6, IB2, T4, None......... 202....... 242....... 5 L 60 L B 95, 102 TP1 n-Amyl methyl ketone....... 3 UN1110 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Amyl nitrate............... 3 UN1112 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 40 Amyl nitrites.............. 3 UN1113 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E 40 Amylamines................. 3 UN1106 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... ........................... ........... ................. III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A ....... Amyltrichlorosilane........ 8 UN1728 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Anhydrous ammonia, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammonia, anhydrous. Anhydrous hydrofluoric ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... acid, see Hydrogen fluoride, anhydrous. + Aniline.................... 6.1 UN1547 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40, 52 Aniline hydrochloride...... 6.1 UN1548 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Aniline oil, see Aniline... ........... ................. ....... ......... ................ ............. .......... .......... ...#
Passage 78........ ........... .......... ....... Anisidines................. 6.1 UN2431 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Anisole.................... 3 UN2222 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Anisoyl chloride........... 8 UN1729 II 8........ B2, B4, IB8, 154.......... 212....... 240....... 15 kg 50 kg A ....... IP2, IP4, T3, TP33 Anti-freeze, liquid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Flammable liquids, n.o.s.. Antimonous chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Antimony trichloride. Antimony compounds, 6.1 UN3141 III 6.1...... 35, IB3, T7, 153.......... 203....... 241....... 60 L 220 L A ....... inorganic, liquid, n.o.s.. TP1, TP28 Antimony compounds, 6.1 UN1549 III 6.1...... 35, IB8, IP3, 153.......... 213....... 240....... 100 kg 200 kg A ....... inorganic, solid, n.o.s.. T1, TP33 Antimony lactate........... 6.1 UN1550 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Antimony pentachloride, 8 UN1730 II 8........ B2, IB2, T7, TP2 None......... 202....... 242....... 1 L 30 L C 40 liquid. Antimony pentachloride, 8 UN1731 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L C 40 solutions. ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L C 40 Antimony pentafluoride..... 8 UN1732 II 8, 6.1... A3, A6, A7, A10, None......... 202....... 243....... Forbidden 30 L D 44, 89, IB2, N3, N36, 100, T7, TP2 141 Antimony potassium tartrate 6.1 UN1551 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33#
Passage 79Antimony powder............ 6.1 UN2871 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Antimony sulfide and a Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chlorate, mixtures of. Antimony sulfide, solid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Antimony compounds, inorganic, n.o.s.. Antimony trichloride, 8 UN1733 II 8........ B2, IB2 154.......... 202....... 242....... 1 L 30 L C 40 liquid. Antimony trichloride, solid 8 UN1733 II 8........ IB8, IP2, IP4 154.......... 212....... 240....... 15 kg 50 kg A 40 Aqua ammonia, see Ammonia ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, etc. Argon, compressed.......... 2.2 UN1006 ....... 2.2...... ................ 306.......... 302....... 314, 315.. 75 kg 150 kg A ....... Argon, refrigerated liquid 2.2 UN1951 ....... 2.2...... T75, TP5 320.......... 316....... 318....... 50 kg 500 kg B ....... (cryogenic liquid). Arsenic.................... 6.1 UN1558 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Arsenic acid, liquid....... 6.1 UN1553 I 6.1...... T20, TP2, TP7, None......... 201....... 243....... 1 L 30 L B 46 TP13 Arsenic acid, solid........ 6.1 UN1554 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Arsenic bromide............ 6.1 UN1555 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 12, 40 T3, TP33 Arsenic chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Arsenic trichloride. Arsenic compounds, liquid, 6.1 UN1556 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40, 137 n.o.s. inorganic, TP27 including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.. ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40, 137 TP13, TP27 ........................... ........... ...............#
Passage 80.. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L B 40, 137 TP28 Arsenic compounds, solid, 6.1 UN1557 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 137 n.o.s. inorganic, TP33 including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 137 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 137 TP33 Arsenic pentoxide.......... 6.1 UN1559 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Arsenic sulfide and a Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chlorate, mixtures of. Arsenic trichloride........ 6.1 UN1560 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 40 B74, T20, TP2, TP13, TP38, TP45 Arsenic trioxide........... 6.1 UN1561 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Arsenic, white, solid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Arsenic trioxide. Arsenical dust............. 6.1 UN1562 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Arsenical pesticides, 3 UN2760 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Arsenical pesticides, 6.1 UN2994 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Arsenical pesticides, 6.1 UN2993 I 6.1, 3... T14, TP2, TP13, No#
Passage 81ne......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP2, TP28 Arsenical pesticides, 6.1 UN2759 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33#
Passage 82Arsenious acid, solid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Arsenic trioxide. Arsenious and mercuric ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... iodide solution, see Arsenic compounds, liquid, n.o.s.. Arsine..................... 2.3 UN2188 ....... 2.3, 2.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 Articles, explosive, 1.6N UN0486 II 1.6N..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... extremely insensitive or Articles, EEI. G Articles, explosive, n.o.s. 1.4S UN0349 II 1.4S..... 101 None......... 62........ None...... 25 kg 100 kg 05 ....... G Articles, explosive, n.o.s. 1.4B UN0350 II 1.4B..... 101 None......... 62........ None...... Forbidden Forbidden 06 ....... G Articles, explosive, n.o.s. 1.4C UN0351 II 1.4C..... 101 None......... 62........ None...... Forbidden 75 kg 06 ....... G Articles, explosive, n.o.s. 1.4D UN0352 II 1.4D..... 101 None......... 62........ None...... Forbidden 75 kg 06 ....... G Articles, explosive, n.o.s. 1.4G UN0353 II 1.4G..... 101 None......... 62........ None...... Forbidden 75 kg 06 ....... G Articles, explosive, n.o.s. 1.1L UN0354 II 1.1L..... 101 None......... 62........ None...... Forbidden Forbidden 08 8E, 14E, 15E, 17E G Articles, explosive, n.o.s. 1.2L UN0355 II 1.2L..... 101 None......... 62........ None...... Forbidden Forbidden 08 8E, 14E, 15E, 17E G Articles, explosive, n.o.s. 1.3L UN0356 II 1.3L..... 101 None......... 62........ None...... Forbidden Forbidden 08 8E, 14E, 15E, 17E G Articles, explosive, n.o.s. 1.1C UN0462 II 1.1C..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.1D UN0463 II 1.1D..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.1E UN0464 II 1.1E..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.1F UN0465 II 1.1F..... 101 None......... 62........ None...... Forbidden Forbidden 08 ....... G Articles, explosive, n.o.s. 1.2C UN0466 II 1.2C..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.2D UN0467 II 1.2D..... 101 Non#
Passage 83e......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.2E UN0468 II 1.2E..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.2F UN0469 II 1.2F..... 101 None......... 62........ None...... Forbidden Forbidden 08 ....... G Articles, explosive, n.o.s. 1.3C UN0470 II 1.3C..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... G Articles, explosive, n.o.s. 1.4E UN0471 II 1.4E..... 101 None......... 62........ None...... Forbidden 75 kg 06 ....... G Articles, explosive, n.o.s. 1.4F UN0472 II 1.4F..... 101 None......... 62........ None...... Forbidden Forbidden 08 ....... Articles, pressurized 2.2 UN3164 ....... 2.2...... ................ 306.......... 302, 304.. None...... No limit No limit A ....... pneumatic or hydraulic containing non-flammable gas. Articles, pyrophoric....... 1.2L UN0380 II 1.2L..... ................ None......... 62........ None...... Forbidden Forbidden 08 8E, 14E, 15E, 17E Articles, pyrotechnic for 1.1G UN0428 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... technical purposes. Articles, pyrotechnic for 1.2G UN0429 II 1.2G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... technical purposes. Articles, pyrotechnic for 1.3G UN0430 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... technical purposes. Articles, pyrotechnic for 1.4G UN0431 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... technical purposes. Articles, pyrotechnic for 1.4S UN0432 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... technical purposes. D Asbestos................... 9 NA2212 III 9........ 156, IB8, IP2, 155.......... 216....... 240....... 200 kg 200 kg A 34, 40 IP4 Ascaridole (organic Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxide). D Asphalt, at or above its 3 NA1999 III 3........ IB3, T1, TP3 150.......... 203....... 247....... Forbidden Forbidden D ....... flash point. D Asphalt, cut back, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... .......#
Passage 84Tars, liquid, etc. Automobile, motorcycle, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tractor, other self- propelled vehicle, engine, or other mechanical apparatus, see Vehicles or Battery etc. A G Aviation regulated liquid, 9 UN3334 ....... 9........ A35 155.......... 204....... .......... No limit No limit A ....... n.o.s.. A G Aviation regulated solid, 9 UN3335 ....... 9........ A35 155.......... 204....... .......... No limit No limit A ....... n.o.s.. Azaurolic acid (salt of) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). Azido guanidine picrate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). 5-Azido-1-hydroxy tetrazole Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Azido hydroxy tetrazole Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (mercury and silver salts). 3-Azido-1,2-Propylene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... glycol dinitrate. Azidodithiocarbonic acid... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Azidoethyl nitrate......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1-Aziridinylphosphine oxide- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (tris), see Tris-(1- aziridinyl) phosphine oxide, solution. Azodicarbonamide........... 4.1 UN3242 II 4.1...... 38, IB8, T3, 151.......... 212....... 240....... Forbidden Forbidden D 12, 52, TP33 53, 74 Azotetrazole (dry)......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Barium..................... 4.3 UN1400 II 4.3...... A19, I#
Passage 85B7, IP2, 151.......... 212....... 241....... 15 kg 50 kg E 52 T3, TP33 Barium alloys, pyrophoric.. 4.2 UN1854 I 4.2...... T21, TP7, TP33 None......... 181....... None...... Forbidden Forbidden D ....... Barium azide, dry or wetted 1.1A UN0224 II 1.1A, 6.1 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... with less than 50 percent water, by mass. Barium azide, wetted with 4.1 UN1571 I 4.1, 6.1. 162, A2 None......... 182....... None...... Forbidden 0.5 kg D 28 not less than 50 percent water, by mass. Barium bromate............. 5.1 UN2719 II 5.1, 6.1. IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 T3, TP33 Barium chlorate, solid..... 5.1 UN1445 II 5.1, 6.1. A9, IB6, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 N34, T3, TP33#
Passage 86Barium chlorate, solution.. 5.1 UN3405 II 5.1, 6.1. A9, IB2, N34, 152.......... 202....... 243....... 1 L 5 L A 56, 58, T4, TP1 133 ........................... ........... ................. III 5.1, 6.1. A9, IB2, N34, 152.......... 203....... 242....... 2.5 L 30 L A 56, 58, T4, TP1 133 Barium compounds, n.o.s.... 6.1 UN1564 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Barium cyanide............. 6.1 UN1565 I 6.1...... IB7, IP1, N74, None......... 211....... 242....... 5 kg 50 kg A 40, 52 N75, T6, TP33 Barium hypochlorite with 5.1 UN2741 II 5.1, 6.1. A7, A9, IB8, 152.......... 212....... None...... 5 kg 25 kg B 4, 52, more than 22 percent IP2, IP4, N34, 56, 58, available chlorine. T3, TP33 106 Barium nitrate............. 5.1 UN1446 II 5.1, 6.1. IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A ....... T3, TP33 Barium oxide............... 6.1 UN1884 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Barium perchlorate, solid.. 5.1 UN1447 II 5.1, 6.1. IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Barium perchlorate, 5.1 UN3406 II 5.1, 6.1. IB2, T4, TP1 152.......... 202....... 243....... 1 L 5 L A 56, 58, solution. 133 ........................... ........... ................. III 5.1, 6.1. IB2, T4, TP1 152.......... 203....... 242....... 2.5 L 30 L A 56, 58, 133 Barium permanganate........ 5.1 UN1448 II 5.1, 6.1. IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg D 56, 58, TP33 138 Barium peroxide............ 5.1 UN1449 II 5.1, 6.1. A9, IB6, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 13, 52, T3, TP33 56, 75 Barium selenate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Barium selenite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Batteries, containing 4.3 UN3292 II 4.3...... ................ 189.......... 189....... 189....... Forbidden No limit A ....... sodium. Batteries, dry, containing 8 UN3028 III 8.......#
Passage 87. ................ None......... 213....... None...... 25 kg gross 230 kg A ....... potassium hydroxide solid, gross electric, storage. Batteries, wet, filled with 8 UN2794 III 8........ ................ 159.......... 159....... 159....... 30 kg gross No limit A ....... acid, electric storage. Batteries, wet, filled with 8 UN2795 III 8........ ................ 159.......... 159....... 159....... 30 kg gross No limit A ....... alkali, electric storage. Batteries, wet, non- 8 UN2800 III 8........ ................ 159.......... 159....... 159....... No Limit No Limit A ....... spillable, electric storage. Batteries, dry, not subject ........... ................. ....... ......... 130 ............. .......... .......... ........... ........... .......... ....... to the requirements of this subchapter. Battery fluid, acid........ 8 UN2796 II 8........ A3, A7, B2, B15, 154.......... 202....... 242....... 1 L 30 L B ....... IB2, N6, N34, T8, TP2, TP12 Battery fluid, alkali...... 8 UN2797 II 8........ B2, IB2, N6, T7, 154.......... 202....... 242....... 1 L 30 L A 29 TP2, TP28 Battery lithium type, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Lithium batteries etc. Battery-powered vehicle or 9 UN3171 ....... 9........ 134 220.......... 220....... None...... No limit No limit .......... ....... Battery-powered equipment. Battery, wet, filled with ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... acid or alkali with vehicle or mechanical equipment containing an internal combustion engine, see Vehicle, etc. or Engines, internal combustion, etc. + Benzaldehyde............... 9 UN1990 III 9........ IB3, T2, TP1 155.......... 203....... 241....... 100 L 220 L A ....... Benzene.................... 3 UN1114 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Benzene diazonium chloride Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). Benzene diazonium nitrate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). Benzene phosphorus ........... ................. ......#
Passage 88. ......... ................ ............. .......... .......... ........... ........... .......... ....... dichloride, see Phenyl phosphorus dichloride. Benzene phosphorus ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... thiodichloride, see Phenyl phosphorus thiodichloride. Benzene sulfonyl chloride.. 8 UN2225 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A 40 Benzene triozonide......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Benzenethiol, see Phenyl ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mercaptan. Benzidine.................. 6.1 UN1885 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Benzol, see Benzene........ ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Benzonitrile............... 6.1 UN2224 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40, 52 Benzoquinone............... 6.1 UN2587 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Benzotrichloride........... 8 UN2226 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 40 Benzotrifluoride........... 3 UN2338 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Benzoxidiazoles (dry)...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Benzoyl azide.............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... .......#
Passage 89Benzoyl chloride........... 8 UN1736 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L C 40 TP2, TP12, TP13 Benzyl bromide............. 6.1 UN1737 II 6.1, 8... A3, A7, IB2, 153.......... 202....... 243....... 1 L 30 L D 13, 40 N33, N34, T8, TP2, TP12, TP13 Benzyl chloride............ 6.1 UN1738 II 6.1, 8... A3, A7, B70, 153.......... 202....... 243....... 1 L 30 L D 13, 40 IB2, N33, N42, T8, TP2, TP12, TP13 Benzyl chloride 6.1 UN1738 II 6.1, 8... A3, A7, B8, B11, 153.......... 202....... 243....... 1 L 30 L D 13, 40 unstabilized. IB2, N33, N34, N43, T8, TP2, TP12, TP13 Benzyl chloroformate....... 8 UN1739 I 8........ A3, A6, B4, N41, None......... 201....... 243....... Forbidden 2.5 L D 40 T10, TP2, TP12, TP13 Benzyl iodide.............. 6.1 UN2653 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L B 12, 40 Benzyldimethylamine........ 8 UN2619 II 8, 3..... B2, IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L A 40, 48 Benzylidene chloride....... 6.1 UN1886 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L D 40 Beryllium compounds, n.o.s. 6.1 UN1566 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Beryllium nitrate.......... 5.1 UN2464 II 5.1, 6.1. IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A ....... T3, TP33 Beryllium, powder.......... 6.1 UN1567 II 6.1, 4.1. IB8, IP2, IP4, 153.......... 212....... 242....... 15 kg 50 kg A ....... T3, TP33 Bicyclo [2,2,1] hepta-2,5- 3 UN2251 II 3........ IB2, T7, TP2 150.......... 202....... 242....... 5 L 60 L D ....... diene, stabilized or 2,5- Norbornadiene, stabilized. Biphenyl triozonide........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Bipyridilium pesticides, 3 UN2782 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L E ....... liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Bipyridilium pesticides, 6.1 UN3016 I 6.1...... T14, TP2, TP13, None......#
Passage 90... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Bipyridilium pesticides, 6.1 UN3015 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 21, 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 21, 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 21, 40 TP2, TP28 Bipyridilium pesticides, 6.1 UN2781 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Bis (Aminopropyl) ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... piperazine, see Corrosive liquid, n.o.s.. Bisulfate, aqueous solution 8 UN2837 II 8........ A7, B2, IB2, 154.......... 202....... 242....... 1 L 30 L A ....... N34, T7, TP2 ........................... ........... ................. III 8........ A7, IB3, N34, 154.......... 203....... 241....... 5 L 60 L A ....... T4, TP1 Bisulfites, aqueous 8 UN2693 III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 40, 52 solutions, n.o.s.. TP28 Black powder, compressed or 1.1D UN0028 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets. Black powder or Gunpowder, 1.1D UN0027 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... granular or as a meal. D Black powder for small arms 4.1 NA0027 I 4.1...... 70 None......... 170....... None...... Forbidden Forbidden E ....... Blasting agent, n.#
Passage 91o.s., see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Explosives, blasting etc. Blasting cap assemblies, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Detonator assemblies, non-electric, for blasting. Blasting caps, electric, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Detonators, electric for blasting. Blasting caps, non- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... electric, see Detonators, non-electric, for blasting. Bleaching powder, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Calcium hypochlorite mixtures, etc. I Blue asbestos (Crocidolite) 9 UN2212 II 9........ 156, IB8, IP2, 155.......... 216....... 240....... Forbidden Forbidden A 34, 40 or Brown asbestos IP4, T3, TP33 (amosite, mysorite). Bombs, photo-flash......... 1.1F UN0037 II 1.1F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... Bombs, photo-flash......... 1.1D UN0038 II 1.1D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Bombs, photo-flash......... 1.2G UN0039 II 1.2G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Bombs, photo-flash......... 1.3G UN0299 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Bombs, smoke, non- 8 UN2028 II 8........ ................ None......... 160....... None...... Forbidden 50 kg E 40 explosive, with corrosive liquid, without initiating device. Bombs, with bursting charge 1.1F UN0033 II 1.1F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... Bombs, with bursting charge 1.1D UN0034 II 1.1D..... ................ ............. 62........ None...... Forbidden Forbidden 03 .......#
Passage 92Bombs, with bursting charge 1.2D UN0035 II 1.2D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Bombs, with bursting charge 1.2F UN0291 II 1.2F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... Bombs with flammable 1.1J UN0399 II 1.1J..... ................ ............. 62........ None...... Forbidden Forbidden 04 23E liquid, with bursting charge. Bombs with flammable 1.2J UN0400 II 1.2J..... ................ ............. 62........ None...... Forbidden Forbidden 04 23E liquid, with bursting charge. Boosters with detonator.... 1.1B UN0225 II 1.1B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... Boosters with detonator.... 1.2B UN0268 II 1.2B..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Boosters, without detonator 1.1D UN0042 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Boosters, without detonator 1.2D UN0283 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Borate and chlorate ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures, see Chlorate and borate mixtures. Borneol.................... 4.1 UN1312 III 4.1...... A1, IB8, IP3, None......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 + Boron tribromide........... 8 UN2692 I 8, 6.1... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden C 12 B74, N34, T20, TP2, TP12, TP13, TP38, TP45 Boron trichloride.......... 2.3 UN1741 ....... 2.3, 8... 3, B9, B14 None......... 304....... 314....... Forbidden Forbidden D 25, 40 Boron trifluoride.......... 2.3 UN1008 ....... 2.3...... 2, B9, B14 None......... 302....... 314, 315.. Forbidden Forbidden D 40 Boron trifluoride acetic 8 UN1742 II 8........ B2, B6, IB2, T8, 154.......... 202....... 242....... 1 L 30 L A ....... acid complex, liquid. TP2, TP12 Boron trifluoride acetic 8 UN3419 II 8........ B2, B6, IB8, 154.......... 212....... 240....... 15 kg 50 kg A ....... acid complex, solid. IP2, IP4, T3, TP33 Boron trifluoride diethyl 8 UN2604 I 8, 3..... A3, A19, T10, None......... 201....... 243....... 0.5 L 2.5 L D 40 etherate. TP2 Boron trifluoride dihydrate 8 UN2851 II 8........ IB#
Passage 932, T7, TP2 154.......... 212....... 240....... 15 kg 50 kg B 12, 40, Boron trifluoride dimethyl 4.3 UN2965 I 4.3, 8, 3 A19, T10, TP2, None......... 201....... 243....... Forbidden 1 L D 21, 28, etherate. TP7 40, 49, 100 Boron trifluoride propionic 8 UN1743 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L A ....... acid complex, liquid. TP2, TP12 Boron trifluoride propionic 8 UN3420 II 8........ B2, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A ....... acid complex, solid. IP4, T3, TP33 Box toe gum, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrocellulose etc. Bromates, inorganic, 5.1 UN3213 II 5.1...... IB2, T4, TP1 152.......... 202....... 242....... 1 L 5 L B 56, 58, aqueous solution, n.o.s.. 133 ........................... ........... ................. III 5.1...... IB2, T4, TP1 152.......... 203....... 241....... 2.5 L 30 L B 56, 58, 133 Bromates, inorganic, n.o.s. 5.1 UN1450 II 5.1...... IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 T3, TP33 Bromine azide.............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... + Bromine or Bromine 8 UN1744 I 8, 6.1... 1, B9, B64, B85, None......... 226....... 249....... Forbidden Forbidden .......... 12, 40, solutions. N34, N43, T22, 66, 74, TP2, TP10, TP12, 89, 90 TP13 Bromine chloride........... 2.3 UN2901 ....... 2.3, 8, 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 89, 5.1. 90 + Bromine pentafluoride...... 5.1 UN1745 I 5.1, 6.1, 1, B9, B14, B30, None......... 228....... 244....... Forbidden Forbidden D 25, 40, 8. B72, T22, TP2, 66, 90 TP12, TP13, TP38, TP44 + Bromine trifluoride........ 5.1 UN1746 I 5.1, 6.1, 2, B9, B14, B32, None......... 228....... 244....... Forbidden Forbidden D 25, 40, 8. B74, T22, TP2, 66, 90 TP12, TP13, TP38, TP45 4-Bromo-1,2-dinitrobenzene. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 4-Bromo-1,2-dinitrobenzene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (unstable at 59 degrees C). 1-Bromo-3-chloropropane.... 6.#
Passage 941 UN2688 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... 1-Bromo-3-methylbutane..... 3 UN2341 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 1-Bromo-3-nitrobenzene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (unstable at 56 degrees C). 2-Bromo-2-nitropropane-1,3- 4.1 UN3241 III 4.1...... 46, IB8, IP3 151.......... 213....... None...... 25 kg 50 kg C 12, 25, diol. 40 Bromoacetic acid, solid.... 8 UN3425 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A ....... IP4, N34, T3, TP33#
Passage 95Bromoacetic acid solution.. 8 UN1938 II 8........ A7, B2, IB2, T7, 154.......... 202....... 242....... 1 L 30 L A 40 TP2 ........................... ........... ................. III 8........ B2, IB3, T7, TP2 154.......... 203....... 241....... 5 L 60 L A 40 + Bromoacetone............... 6.1 UN1569 II 6.1, 3... 2, T20, TP2, None......... 193....... 245....... Forbidden Forbidden D 40 TP13 Bromoacetyl bromide........ 8 UN2513 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L C 40, 53 TP2, TP12 Bromobenzene............... 3 UN2514 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Bromobenzyl cyanides, 6.1 UN1694 I 6.1...... T14, TP2, TP13 None......... 201....... 243....... Forbidden 30 L D 12, 40, liquid. 52 Bromobenzyl cyanides, solid 6.1 UN3449 I 6.1...... T6, TP33 None......... 211....... 242....... 5 kg 50 kg D 12, 40, 52 1-Bromobutane.............. 3 UN1126 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 2-Bromobutane.............. 3 UN2339 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Bromochloromethane......... 6.1 UN1887 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... 2-Bromoethyl ethyl ether... 3 UN2340 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Bromoform.................. 6.1 UN2515 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 12, 40 Bromomethylpropanes........ 3 UN2342 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... 2-Bromopentane............. 3 UN2343 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Bromopropanes.............. 3 UN2344 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 ........................... ........... ................. III 3........ IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 3-Bromopropyne............. 3 UN2345 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L D 40 Bromosilane................ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Bromotoluene-alpha, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ....#
Passage 96....... .......... ....... Benzyl bromide. Bromotrifluoroethylene..... 2.1 UN2419 ....... 2.1...... ................ None......... 304....... 314, 315.. Forbidden 150 kg B 40 Bromotrifluoromethane or 2.2 UN1009 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas, R 13B1.. Brucine.................... 6.1 UN1570 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A ....... TP33 Bursters, explosive........ 1.1D UN0043 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Butadienes, stabilized or 2.1 UN1010 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Butadienes and Hydrocarbon mixture, stabilized containing more than 40% butadienes. Butane see also Petroleum 2.1 UN1011 ....... 2.1...... 19, T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 gases, liquefied. Butane, butane mixtures and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures having similar properties in cartridges each not exceeding 500 grams, see Receptacles, etc. Butanedione................ 3 UN2346 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... 1,2,4-Butanetriol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitrate. Butanols................... 3 UN1120 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP29 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... tert-Butoxycarbonyl azide.. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Butyl acetates............. 3 UN1123 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Butyl acid phosphate....... 8 UN1718 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Butyl acrylates, stabilized 3 UN2348 III 3........ B1, IB3, T2, TP1 150.......... 203.......#
Passage 97242....... 60 L 220 L A ....... Butyl alcohols, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Butanols. Butyl benzenes............. 3 UN2709 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... n-Butyl bromide, see 1- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Bromobutane. n-Butyl chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorobutanes. D sec-Butyl chloroformate.... 6.1 NA2742 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... 1 L 30 L A 12, 13, B74, T20, TP4, 22, 25, TP12, TP13, 40, 48, TP38, TP45 100 n-Butyl chloroformate...... 6.1 UN2743 I 6.1, 8, 3 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A 12, 13, B74, T20, TP2, 21, 25, TP13, TP38, TP45 40, 100 Butyl ethers, see Dibutyl ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ethers. Butyl ethyl ether, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethyl butyl ether. n-Butyl formate............ 3 UN1128 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... tert-Butyl hydroperoxide, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 90 percent with water. tert-Butyl hypochlorite.... 4.2 UN3255 I 4.2, 8... ................ None......... 211....... 243....... Forbidden Forbidden D ....... N-n-Butyl imidazole........ 6.1 UN2690 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... tert-Butyl isocyanate...... 6.1 UN2484 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP38, TP44 n-Butyl isocyanate......... 6.1 UN2485 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Butyl mercaptans........... 3 UN2347 II 3........ A3, A6, IB2, T4, 150..#
Passage 98........ 202....... 242....... 5 L 60 L D 52, 95 TP1#
Passage 99n-Butyl methacrylate, 3 UN2227 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... stabilized. Butyl methyl ether......... 3 UN2350 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Butyl nitrites............. 3 UN2351 I 3........ T11, TP1, TP8, 150.......... 201....... 243....... 1 L 30 L E 40 TP27 ........................... ........... ................. II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 40 tert-Butyl peroxyacetate, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 76 percent in solution. n-Butyl peroxydicarbonate, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 52 percent in solution. tert-Butyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxyisobutyrate, with more than 77 percent in solution. Butyl phosphoric acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Butyl acid phosphate. Butyl propionates.......... 3 UN1914 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 5-tert-Butyl-2,4,6-trinitro- 4.1 UN2956 III 4.1...... 159 None......... 223....... None...... Forbidden Forbidden D D12, m-xylene or Musk xylene. 25, 48, 127 Butyl vinyl ether, 3 UN2352 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 stabilized. n-Butylamine............... 3 UN1125 II 3, 8..... IB2, T7, TP1 150.......... 202....... 242....... 1 L 5 L B 40 N-Butylaniline............. 6.1 UN2738 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 74 tert- 6.1 UN2747 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 12, 13, Butylcyclohexylchloroforma 25 te. Butylene see also Petroleum 2.1 UN1012 ....... 2.1...... 19, T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 gases, liquefied. 1,2-Butylene oxide, 3 UN3022 II 3...#
Passage 100..... IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 27, 49 stabilized. Butyltoluenes.............. 6.1 UN2667 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Butyltrichlorosilane....... 8 UN1747 II 8, 3..... A7, B2, B6, IB2, None......... 202....... 243....... Forbidden 30 L C 40 N34, T7, TP2, TP13 1,4-Butynediol............. 6.1 UN2716 III 6.1...... A1, IB8, IP3, None......... 213....... 240....... 100 kg 200 kg A 52, 53, T1, TP33 70, 139, 140 Butyraldehyde.............. 3 UN1129 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Butyraldoxime.............. 3 UN2840 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Butyric acid............... 8 UN2820 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A 12 Butyric anhydride.......... 8 UN2739 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Butyronitrile.............. 3 UN2411 II 3, 6.1... IB2, T7, TP1, 150.......... 202....... 243....... 1 L 60 L E 40 TP13 Butyryl chloride........... 3 UN2353 II 3, 8..... IB2, T8, TP2, 150.......... 202....... 243....... 1 L 5 L C 40 TP12, TP13 Cacodylic acid............. 6.1 UN1572 II 6.1...... IB8, IP2, 153.......... 212....... 242....... 25 kg 100 kg E 52 IP4,T3, TP33 Cadmium compounds.......... 6.1 UN2570 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A ....... TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Caesium hydroxide.......... 8 UN2682 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 29 T3, TP33 Caesium hydroxide solution. 8 UN2681 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 29 ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A 29 Calcium.................... 4.3 UN1401 II 4.3...... IB7, IP2, T3, 151.......... 212....... 241....... 15 kg 50 kg E 52 TP33 Calcium arsenate........... 6.1 UN1573 II 6.1...... IB8, IP2, IP4, 152.......... 212....... 242....... 25 kg 100 kg A#
Passage 101....... T3, TP33 Calcium arsenate and 6.1 UN1574 II 6.1...... IB8, IP2, IP4, 152.......... 212....... 242....... 25 kg 100 kg A ....... calcium arsenite, T3, TP33 mixtures, solid. Calcium bisulfite solution, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Bisulfites, aqueous solutions, n.o.s.. Calcium carbide............ 4.3 UN1402 I 4.3...... A1, A8, B55, None......... 211....... 242....... Forbidden 15 kg B 52 B59, IB4, IP1, N34, T9, TP7, TP33 ........................... ........... ................. II 4.3...... A1, A8, B55, 151.......... 212....... 241....... 15 kg 50 kg B 52 B59, IB7, IP2, N34, T3, TP33#
Passage 102Calcium chlorate........... 5.1 UN1452 II 5.1...... A9, IB8, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 IP4, N34, T3, TP33 Calcium chlorate aqueous 5.1 UN2429 II 5.1...... A2, IB2, N41, 152.......... 202....... 242....... 1 L 5 L B 56, 58, solution. T4, TP1 133 ........................... ........... ................. III 5.1...... A2, IB2, N41, 152.......... 203....... 241....... 2.5 L 30 L B 56, 68, T4, TP1 133 Calcium chlorite........... 5.1 UN1453 II 5.1...... A9, IB8, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 IP4, N34, T3, TP33 Calcium cyanamide with more 4.3 UN1403 III 4.3...... A1, A19, IB8, 151.......... 213....... 241....... 25 kg 100 kg A 52 than 0.1 percent of IP4, T1, TP33 calcium carbide. Calcium cyanide............ 6.1 UN1575 I 6.1...... IB7, IP1, N79, None......... 211....... 242....... 5 kg 50 kg A 40, 52 N80, T6, TP33 Calcium dithionite or 4.2 UN1923 II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg E 13 Calcium hydrosulfite. IP2, T3, TP33 Calcium hydride............ 4.3 UN1404 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E 52 Calcium hydrosulfite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Calcium dithionite. Calcium hypochlorite, dry 5.1 UN1748 II 5.1...... 165, 166, A7, 152.......... 212....... None...... 5 kg 25 kg D 4, 25, or Calcium hypochlorite A9, IB8, IP2, 48, 52, mixtures dry with more IP4, IP13, N34, 56, 58, than 39 percent available W9 69, 142 chlorine (8.8 percent available oxygen). ........................... ........... ................. III 5.1...... 165, A7, A9, 152.......... 213....... 240....... 25 kg 100 kg D 4, 25, IB8, IP4, IP13, 48, 52, N34, W9 56, 58, 69, 142 Calcium hypochlorite, 5.1 UN2880 II 5.1...... 165, 166, IB8, 152.......... 212....... 240....... 5 kg 25 kg D 4, 25, hydrated or Calcium IP2, IP4, IP13, 48, 52, hypochlorite, hydrated W9 56, 58, mixtures, with not less 69, 142 than 5.5 percent but not more than 16 percent water. ........................... ........... ................. III 5.1...... 165, 171, IB8, 152.......... 213....... 240....... 25 kg 100 kg D 4, 25, IP4, IP13, W9 48, 52, 56, 58, 69, 142 Calcium hypochlorite 5.1 UN2208 III 5.1...... 165, A1, A29, 152.......... 213....... 240....... 25 kg 100 kg D 4,#
Passage 10325, mixtures, dry, with more IB8, IP3, IP13, 48, 52, than 10 percent but not N34, W9 56, 58, more than 39 percent 69, 142 available chlorine. Calcium manganese silicon.. 4.3 UN2844 III 4.3...... A1, A19, IB8, 151.......... 213....... 241....... 25 kg 100 kg A 52, 85, IP2, IP4, T1, 103 TP33 Calcium nitrate............ 5.1 UN1454 III 5.1...... 34, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 A Calcium oxide.............. 8 UN1910 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Calcium perchlorate........ 5.1 UN1455 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Calcium permanganate....... 5.1 UN1456 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg D 56, 58, TP33 138 Calcium peroxide........... 5.1 UN1457 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 13, 52, TP33 56, 75 Calcium phosphide.......... 4.3 UN1360 I 4.3, 6.1. A8, A19, N40 None......... 211....... 242....... Forbidden 15 kg E 40, 52, 85 Calcium, pyrophoric or 4.2 UN1855 I 4.2...... ................ None......... 187....... None...... Forbidden Forbidden D ....... Calcium alloys, pyrophoric. Calcium resinate........... 4.1 UN1313 III 4.1...... A1, A19, IB6, None......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Calcium resinate, fused.... 4.1 UN1314 III 4.1...... A1, A19, IB4, None......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Calcium selenate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Calcium silicide........... 4.3 UN1405 II 4.3...... A19, IB7, IP2, 151.......... 212....... 241....... 15 kg 50 kg B 52, 85, T3, TP33 103 ........................... ........... ................. III 4.3...... A1, A19, IB8, 151.......... 213....... 241....... 25 kg 100 kg B 52, 85, IP4, T1, TP33 103 Camphor oil................ 3 UN1130 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Camphor, synthetic......... 4.1 UN2717 III 4.1...... A1, IB8, IP3, None......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Cannon primers, see ........... ................. ....... ......... ................ ............. .......... .......... ........... .........#
Passage 104.. .......... ....... Primers, tubular. Caproic acid............... 8 UN2829 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Caps, blasting, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Detonators, etc. Carbamate pesticides, 3 UN2758 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Carbamate pesticides, 6.1 UN2992 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27#
Passage 105........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Carbamate pesticides, 6.1 UN2991 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP2, TP28 Carbamate pesticides, 6.1 UN2757 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Carbolic acid, see Phenol, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solid or Phenol, molten. Carbolic acid solutions, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Phenol solutions. I Carbon, activated.......... 4.2 UN1362 III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 0.5 kg 0.5 kg A 12 TP33 I Carbon, animal or vegetable 4.2 UN1361 II 4.2...... IB6, T3, TP33 None......... 212....... 242....... Forbidden Forbidden A 12 origin. ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... Forbidden Forbidden A 12 TP33 Carbon bisulfide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Carbon disulfide. Carbon dioxide............. 2.2 UN1013 ....... 2.2...... ................ 306.......... 302, 304.. 302, 314, 75 kg 150 kg A ....... 315. Carbon dioxide and nitrous 2.2 UN1015 ....... 2.2...... ................ 306.......... None...... 314, 315.. 75 kg 150 kg A ....... oxide mixtures. Carbon dioxide and oxygen 2.2 UN1014 ....... 2.2, 5.1. 77, A14 306.......... 304..#
Passage 106..... 314, 315.. 75 kg 150 kg A ....... mixtures, compressed. Carbon dioxide, 2.2 UN2187 ....... 2.2...... T75, TP5 306.......... 304....... 314, 315.. 50 kg 500 kg B ....... refrigerated liquid. A W Carbon dioxide, solid or 9 UN1845 III None..... ................ 217.......... 217....... 240....... 200 kg 200 kg C 40 Dry ice. Carbon disulfide........... 3 UN1131 I 3, 6.1... B16, T14, TP2, None......... 201....... 243....... Forbidden Forbidden D 18, 40, TP7, TP13 115 Carbon monoxide, compressed 2.3 UN1016 ....... 2.3, 2.1. 4 None......... 302....... 314, 315.. Forbidden 25 kg D 40 Carbon monoxide and 2.3 UN2600 ....... 2.3, 2.1. 6 None......... 302....... 302....... Forbidden Forbidden D 40, 57 hydrogen mixture, compressed. D Carbon monoxide, 2.3 NA9202 ....... 2.3, 2.1. 4, T75, TP5 None......... 316....... 318....... Forbidden Forbidden D ....... refrigerated liquid (cryogenic liquid). Carbon tetrabromide........ 6.1 UN2516 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 25 TP33 Carbon tetrachloride....... 6.1 UN1846 II 6.1...... IB2, N36, T7, 153.......... 202....... 243....... 5 L 60 L A 40 TP2 Carbonyl chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosgene. Carbonyl fluoride.......... 2.3 UN2417 ....... 2.3, 8... 2 None......... 302....... None...... Forbidden Forbidden D 40 Carbonyl sulfide........... 2.3 UN2204 ....... 2.3, 2.1. 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Cartridge cases, empty ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... primed, see Cases, cartridge, empty, with primer. Cartridges, actuating, for ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... aircraft ejector seat catapult, fire extinguisher, canopy removal or apparatus, see Cartridges, power device. Cartridges, explosive, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Charges, demolition. Cartridges, flash.......... 1.1G UN0049 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Car#
Passage 107tridges, flash.......... 1.3G UN0050 II 1.3G..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Cartridges for weapons, 1.1C UN0326 II 1.1C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... blank. Cartridges for weapons, 1.2C UN0413 II 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... blank. Cartridges for weapons, 1.4S UN0014 II None..... ................ 63........... 62........ None...... 25 kg 100 kg 05 ....... blank or Cartridges, small arms, blank. Cartridges for weapons, 1.3C UN0327 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... blank or Cartridges, small arms, blank. Cartridges for weapons, 1.4C UN0338 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... blank or Cartridges, small arms, blank. Cartridges for weapons, 1.2C UN0328 II 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... inert projectile. Cartridges for weapons, 1.4S UN0012 II None..... ................ 63........... 62........ None...... 25 kg 100 kg 05 ....... inert projectile or Cartridges, small arms. Cartridges for weapons, 1.4C UN0339 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... inert projectile or Cartridges, small arms. Cartridges for weapons, 1.3C UN0417 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 06 ....... inert projectile or Cartridges, small arms. Cartridges for weapons, 1.1F UN0005 II 1.1F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... with bursting charge. Cartridges for weapons, 1.1E UN0006 II 1.1E..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... with bursting charge.#
Passage 108Cartridges for weapons, 1.2F UN0007 II 1.2F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... with bursting charge. Cartridges for weapons, 1.2E UN0321 II 1.2E..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... with bursting charge. Cartridges for weapons, 1.4F UN0348 II 1.4F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... with bursting charge. Cartridges for weapons, 1.4E UN0412 II 1.4E..... ................ None......... 62........ None...... Forbidden 75 kg 02 ....... with bursting charge. Cartridges, oil well....... 1.3C UN0277 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Cartridges, oil well....... 1.4C UN0278 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Cartridges, power device... 1.3C UN0275 II 1.3C..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Cartridges, power device... 1.4C UN0276 II 1.4C..... 110 None......... 62........ None...... Forbidden 75 kg 06 ....... Cartridges, power device... 1.4S UN0323 II 1.4S..... 110 63........... 62........ None...... 25 kg 100 kg 05 ....... Cartridges, power device... 1.2C UN0381 II 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Cartridges, safety, blank, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Cartridges for weapons, blank (UN 0014). Cartridges, safety, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cartridges for weapons, other than blank or Cartridges, power device (UN 0323). Cartridges, signal......... 1.3G UN0054 II 1.3G..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Cartridges, signal......... 1.4G UN0312 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Cartridges, signal......... 1.4S UN0405 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... D Cartridges, small arms..... ORM-D ................. ....... None..... ................ 63........... None...... None...... 30 kg gross 30 kg gros#
Passage 109s A ....... D Cartridges power device ORM-D ................. ....... None..... ................ 63........... None...... None...... 30 kg gross 30 kg gross A ....... (used to project fastening devices). Cartridges, sporting, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cartridges for weapons, other than blank. Cartridges, starter, jet ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... engine, see Cartridges, power device. Cases, cartridge, empty 1.4S UN0055 II 1.4S..... 50 None......... 62........ None...... 25 kg 100 kg 05 ....... with primer. Cases, cartridges, empty 1.4C UN0379 II 1.4C..... 50 None......... 62........ None...... Forbidden 75 kg 06 ....... with primer. Cases, combustible, empty, 1.4C UN0446 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... without primer. Cases, combustible, empty, 1.3C UN0447 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... without primer. Casinghead gasoline see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Gasoline. A W Castor beans or Castor meal 9 UN2969 II None..... IB8, IP2, IP4, 155.......... 204....... 240....... No limit No limit E 34, 40 or Castor pomace or Castor T3, TP33 flake. G Caustic alkali liquids, 8 UN1719 II 8........ B2, IB2, T11, 154.......... 202....... 242....... 1 L 30 L A 29 n.o.s.. TP2, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 29 TP28 Caustic potash, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Potassium hydroxide etc. Caustic soda, (etc.) see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sodium hydroxide etc. Cells, containing sodium... 4.3 UN3292 II 4.3...... ................ 189.......... 189....... 189....... 25 kg gross No limit A ....... Celluloid, in block, rods, 4.1 UN2000 III 4.1...... ................ None.........#
Passage 110213....... 240....... 25 kg 100 kg A ....... rolls, sheets, tubes, etc., except scrap. Celluloid, scrap........... 4.2 UN2002 III 4.2...... IB8, IP3 None......... 213....... 241....... Forbidden Forbidden D ....... Cement, see Adhesives ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... containing flammable liquid. Cerium, slabs, ingots, or 4.1 UN1333 II 4.1...... IB8, IP2, IP4, None......... 212....... 240....... 15 kg 50 kg A 74, 91 rods. N34 Cerium, turnings or gritty 4.3 UN3078 II 4.3...... A1, IB7, IP2, 151.......... 212....... 242....... 15 kg 50 kg E 52 powder. T3, TP33 Cesium or Caesium.......... 4.3 UN1407 I 4.3...... A7, A19, IB4, None......... 211....... 242....... Forbidden 15 kg D 52 IP1, N34, N40 Cesium nitrate or Caesium 5.1 UN1451 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... nitrate. IP3, T1, TP33 D Charcoal briquettes, shell, 4.2 NA1361 III 4.2...... IB8, T1, TP33 151.......... 213....... 240....... 25 kg 100 kg A 12 screenings, wood, etc.. Charges, bursting, plastics 1.1D UN0457 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... bonded. Charges, bursting, plastics 1.2D UN0458 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... bonded. Charges, bursting, plastics 1.4D UN0459 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... bonded. Charges, bursting, plastics 1.4S UN0460 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... bonded. Charges, demolition........ 1.1D UN0048 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... Charges, depth............. 1.1D UN0056 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... Charges, expelling, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... explosive, for fire extinguishers, see Cartridges, power device. Charges, explosive, 1.1D UN0442 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... commercial without detonator. Charges, explosive, 1.2D UN0443 II 1.2D..... ................#
Passage 111None......... 62........ None...... Forbidden Forbidden 07 ....... commercial without detonator. Charges, explosive, 1.4D UN0444 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... commercial without detonator. Charges, explosive, 1.4S UN0445 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... commercial without detonator. Charges, propelling........ 1.1C UN0271 II 1.1C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Charges, propelling........ 1.3C UN0272 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Charges, propelling........ 1.2C UN0415 II 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Charges, propelling........ 1.4C UN0491 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Charges, propelling, for 1.3C UN0242 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... cannon. Charges, propelling, for 1.1C UN0279 II 1.1C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... cannon. Charges, propelling, for 1.2C UN0414 II 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... cannon. Charges, shaped, flexible, 1.4D UN0237 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... linear. Charges, shaped, flexible, 1.1D UN0288 II 1.1D..... 101 None......... 62........ None...... Forbidden Forbidden 07 ....... linear. Charges, shaped, without 1.1D UN0059 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... detonator. Charges, shaped, without 1.2D UN0439 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... detonator. Charges, shaped, without 1.4D UN0440 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... detonator. Charges, shaped, without 1.4S UN0441 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... detonator. Charges, supplementary 1.1D UN0060 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... explosive. D Chemical kit............... 8 NA1760 II 8#
Passage 112........ ................ 154.......... 161....... None...... 1 L 30 L B 40 Chemical kits.............. 9 UN3316 ....... 9........ 15 161.......... 161....... None...... 10 kg 10 kg A ....... Chloral, anhydrous, 6.1 UN2075 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L D 40 stabilized. Chlorate and borate 5.1 UN1458 II 5.1...... A9, IB8, IP2, 152.......... 212....... 240....... 5 kg 25 kg A 56, 58 mixtures. IP4, N34, T3, TP33#
Passage 113........................... ........... ................. III 5.1...... A9, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 N34, T1, TP33 Chlorate and magnesium 5.1 UN1459 II 5.1...... A9, IB8, IP2, 152.......... 212....... 240....... 5 kg 25 kg A 56, 58 chloride mixture, solid. IP4, N34, T3, TP33 Chlorate and magnesium 5.1 UN3407 II 5.1...... A9, IB2, N34, 152.......... 202....... 242....... 1 L 5 L A 56, 58, chloride mixture solution. T4, TP1 133 ........................... ........... ................. III 5.1...... A9, IB2, N34, 152.......... 203....... 241....... 2.5 L 30 L A 56, 58, T4, TP1 133 Chlorate and magnesium 5.1 UN1459 III 5.1...... A9, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 chloride mixture, solid. N34, T1, TP33 Chlorate of potash, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Potassium chlorate. Chlorate of soda, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sodium chlorate. Chlorates, inorganic, 5.1 UN3210 II 5.1...... IB2, T4, TP1 152.......... 202....... 242....... 1 L 5 L B 56, 58, aqueous solution, n.o.s.. 133 ........................... ........... ................. III 5.1...... IB2, T4, TP1 152.......... 203....... 241....... 2.5 L 30 L B 56, 58, 133 Chlorates, inorganic, 5.1 UN1461 II 5.1...... A9, IB6, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 n.o.s.. N34, T3, TP33 Chloric acid aqueous 5.1 UN2626 II 5.1...... IB2, T4, TP1 None......... 229....... None...... Forbidden Forbidden D 56, 58 solution, with not more than 10 percent chloric acid. Chloride of phosphorus, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosphorus trichloride. Chloride of sulfur, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sulfur chloride. Chlorinated lime, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Calcium hypochlorite mixtures, etc. Chlorine................... 2.3 UN1017 ....... 2.3, 8..#
Passage 114. 2, B9, B14, T50, None......... 304....... 314, 315.. Forbidden Forbidden D 40, 51, TP19 55, 62, 68, 89, 90 Chlorine azide............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... D Chlorine dioxide, hydrate, 5.1 NA9191 II 5.1, 6.1. ................ None......... 229....... None...... Forbidden Forbidden E ....... frozen. Chlorine dioxide (not Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hydrate). Chlorine pentafluoride..... 2.3 UN2548 ....... 2.3, 5.1, 1, B7, B9, B14 None......... 304....... 314....... Forbidden Forbidden D 40, 89, 8. 90 Chlorine trifluoride....... 2.3 UN1749 ....... 2.3, 5.1, 2, B7, B9, B14 None......... 304....... 314....... Forbidden Forbidden D 40, 89, 8. 90 Chlorite solution.......... 8 UN1908 II 8........ A3, A6, A7, B2, 154.......... 202....... 242....... 1 L 30 L B 26, 44, IB2, N34, T7, 89, TP2, TP24 100, 141 ........................... ........... ................. III 8........ A3, A6, A7, B2, 154.......... 203....... 241....... 5 L 60 L B 26, 44, IB3, N34, T4, 89, TP2, TP24 100, 141 Chlorites, inorganic, 5.1 UN1462 II 5.1...... A7, IB6, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 n.o.s.. N34, T3, TP33 1-Chloro-1,1-difluoroethane 2.1 UN2517 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 or Refrigerant gas R 142b. 3-Chloro-4-methylphenyl 6.1 UN2236 II 6.1...... IB2 153.......... 202....... 243....... 5 L 60 L B 40 isocyanate, liquid. 3-Chloro-4-methylphenyl 6.1 UN3428 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 40 isocyanate, solid. T3, TP33 1-Chloro-1,2,2,2- 2.2 UN1021 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... tetrafluoroethaneor Refrigerant gas R 124. 4-Chloro-o-toluidine 6.1 UN1579 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... hydrochloride, solid. TP33 4-Chloro-o-toluidine 6.1 UN3410 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... hydrochloride, solution. 1-Chloro-2,2,2- 2.2 UN1983 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... trifluoroethane or Refrigerant gas R 133a. Chloroacetic acid, molten.. 6.1 UN#
Passage 1153250 II 6.1, 8... IB1, T7, TP3, None......... 202....... 243....... Forbidden Forbidden C 40 TP28 Chloroacetic acid, solid... 6.1 UN1751 II 6.1, 8... A3, A7, IB8, 153.......... 212....... 242....... 15 kg 50 kg A 40 IP4, N34, T3, TP33 Chloroacetic acid, solution 6.1 UN1750 II 6.1, 8... A7, IB2, N34, 153.......... 202....... 243....... 1 L 30 L C 40 T7, TP2#
Passage 116Chloroacetone, stabilized.. 6.1 UN1695 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 21, 40, B74, N12, N32, 100 N34, T20, TP2, TP13, TP38, TP45 Chloroacetone Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (unstabilized). + Chloroacetonitrile......... 6.1 UN2668 II 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A 12, 40, B74, IB99, T20, 52 TP2, TP38, TP45 Chloroacetophenone, liquid 6.1 UN3416 II 6.1...... A3, IB2, N12, None......... 202....... 243....... Forbidden 60 L D 12, 40 CN. N32, N33, T7, TP2, TP13 Chloroacetophenone, solid 6.1 UN1697 II 6.1...... A3, IB8, IP2, None......... 212....... None...... Forbidden 100 kg D 12, 40 (CN). IP4, N12, N32, N33, N34, T3, TP33 TP2, TP13 Chloroacetyl chloride...... 6.1 UN1752 I 6.1, 8... 2, B3, B8, B9, None......... 227....... 244....... Forbidden Forbidden D 40 B14, B32, B74, B77, N34, N43, T20, TP2, TP13, TP38, TP45 Chloroanilines, liquid..... 6.1 UN2019 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 52 Chloroanilines, solid...... 6.1 UN2018 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Chloroanisidines........... 6.1 UN2233 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Chlorobenzene.............. 3 UN1134 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Chlorobenzol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorobenzene. Chlorobenzotrifluorides.... 3 UN2234 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 40 Chlorobenzyl chlorides, 6.1 UN2235 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... liquid. Chlorobenzyl chlorides, 6.1 UN3427 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... solid. TP33 Chlorobutanes.............. 3 UN1127 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Chlorocresols solution..... 6.1 UN2669 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 12 ........................... ........... ................. I#
Passage 117II 6.1...... IB3, T7, TP2 153.......... 203....... 241....... 60 L 220 L A 12 Chlorocresols, solid....... 6.1 UN3437 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 12 T3, TP33 Chlorodifluorobromomethane 2.2 UN1974 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... or Refrigerant gas R 12B1. Chlorodifluoromethane and 2.2 UN1973 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... chloropentafluoroethane mixture or Refrigerant gas R 502 with fixed boiling point, with approximately 49 percent chlorodifluoromethane. Chlorodifluoromethane or 2.2 UN1018 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 22. + Chlorodinitrobenzenes, 6.1 UN1577 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L B 91 liquid.. Chlorodinitro-benzenes, 6.1 UN3441 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 91 solid. T3, TP33 2-Chloroethanal............ 6.1 UN2232 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 Chloroform................. 6.1 UN1888 III 6.1...... IB3, N36, T7, 153.......... 203....... 241....... 60 L 220 L A 40 TP2 G Chloroformates, toxic, 6.1 UN2742 II 6.1, 8, 3 5, IB1, T7, TP2 153.......... 202....... 243....... 1 L 30 L A 12, 13, corrosive, flammable, 21, 25, n.o.s.. 40, 100 G Chloroformates, toxic, 6.1 UN3277 II 6.1, 8... IB2, T8, TP2, 153.......... 202....... 243....... 1 L 30 L A 12, 13, corrosive, n.o.s.. TP13, TP28 25, 40 Chloromethyl chloroformate. 6.1 UN2745 II 6.1, 8... IB2, T7, TP2, 153.......... 202....... 243....... 1 L 30 L A 12, 13, TP13 21, 25, 40, 100 Chloromethyl ethyl ether... 3 UN2354 II 3, 6.1... IB2, T7, TP1, 150.......... 202....... 243....... 1 L 60 L E 40 TP13 Chloronitroanilines........ 6.1 UN2237 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 + Chloronitrobenzene, liquid 6.1 UN3409 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... ortho. + Chloronitrobenzenes, solid 6.1 UN1578 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... meta or para. T3, TP33 Chloronitrotoluenes, liquid 6.1 UN2433 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 44, 89,#
Passage 118100, 141 Chloronitrotoluenes, solid. 6.1 UN3457 III 6.1...... IB8, IP3,T1, 153.......... 213....... 240....... 25 kg 200 kg A ....... TP33 Chloropentafluoroethane or 2.2 UN1020 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 115. Chlorophenolates, liquid or 8 UN2904 III 8........ IB3 154.......... 203....... 241....... 5 L 60 L A ....... Phenolates, liquid.#
Passage 119Chlorophenolates, solid or 8 UN2905 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... Phenolates, solid. TP33 Chlorophenols, liquid...... 6.1 UN2021 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Chlorophenols, solid....... 6.1 UN2020 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP1, TP33 Chlorophenyltrichlorosilane 8 UN1753 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2 + Chloropicrin............... 6.1 UN1580 I 6.1...... 2, B7, B9, B14, None......... 227....... 244....... Forbidden Forbidden D 40 B32, B46, B74, T20, TP2, TP13, TP38, TP45 Chloropicrin and methyl 2.3 UN1581 ....... 2.3...... 2, B9, B14, T50 None......... 193....... 314, 315.. Forbidden Forbidden D 25, 40 bromide mixtures. Chloropicrin and methyl 2.3 UN1582 ....... 2.3...... 2, T50 None......... 193....... 245....... Forbidden Forbidden D 25, 40 chloride mixtures. Chloropicrin mixture, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point below 100 degrees F) see Toxic liquids, flammable, etc. Chloropicrin mixtures, 6.1 UN1583 I 6.1...... 5 None......... 201....... 243....... Forbidden Forbidden C 40 n.o.s.. ........................... ........... ................. II 6.1...... IB2 153.......... 202....... 243....... Forbidden Forbidden C 40 ........................... ........... ................. III 6.1...... IB3 153.......... 203....... 241....... Forbidden Forbidden C 40 D Chloropivaloyl chloride.... 6.1 NA9263 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 40 B74, T20, TP4, TP12, TP13, TP38, TP45 Chloroplatinic acid, solid. 8 UN2507 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Chloroprene, stabilized.... 3 UN1991 I 3, 6.1... B57, T14, TP2, None......... 201....... 243....... Forbidden 30 L D 40 TP13 Chloroprene, uninhibited... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1-Chloropropane............ 3 UN1278 II 3........ IB2, IP8, N34, None......... 202....... 242....... Forbidden#
Passage 12060 L E ....... T7, TP2 2-Chloropropane............ 3 UN2356 I 3........ N36, T11, TP2, 150.......... 201....... 243....... 1 L 30 L E ....... TP13 3-Chloropropanol-1......... 6.1 UN2849 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... 2-Chloropropene............ 3 UN2456 I 3........ A3, N36, T11, 150.......... 201....... 243....... 1 L 30 L E ....... TP2 2-Chloropropionic acid..... 8 UN2511 III 8........ IB3, T4, TP2 154.......... 203....... 241....... 5 L 60 L A 8 2-Chloropyridine........... 6.1 UN2822 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 Chlorosilanes, corrosive, 8 UN2986 II 8, 3..... IB2, T11, TP2, None......... 202....... 243....... 1 L 30 L C 40 flammable, n.o.s.. TP27 Chlorosilanes, corrosive, 8 UN2987 II 8........ B2, IB2, T14, 154.......... 202....... 242....... 1 L 30 L C 40 n.o.s.. TP2, TP27 Chlorosilanes, flammable, 3 UN2985 II 3, 8..... IB1, T11, TP2, 150.......... 201....... 243....... 1 L 5 L B 40 corrosive, n.o.s.. TP13, TP27 Chlorosilanes, toxic, 6.1 UN3361 II 6.1, 8... IB1, T11, TP2, 153.......... 202....... 243....... 1 L 30 L C 40 corrosive, n.o.s.. TP13 Chlorosilanes, toxic, 6.1 UN3362 II 6.1, 3, 8 IB1, T11, TP2, 153.......... 202....... 243....... 1 L 30 L C 40, 125 corrosive, flammable, TP13 n.o.s.. Chlorosilanes, water- 4.3 UN2988 I 4.3, 3, 8 A2, T10, TP2, None......... 201....... 244....... Forbidden 1 L D 21, 28, reactive, flammable, TP7, TP13 40, 49, corrosive, n.o.s.. 100 + Chlorosulfonic acid (with 8 UN1754 I 8, 6.1... 2, B9, B10, B14, None......... 227....... 244....... Forbidden Forbidden C 40 or without sulfur B32, B74, T20, trioxide). TP2, TP12, TP38, TP45 Chlorotoluenes............. 3 UN2238 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Chlorotoluidines, liquid... 6.1 UN3429 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Chlorotoluidines, solid.... 6.1 UN2239 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Chlorotrifluoromethane and 2.2 UN2599 ....... 2.2...... ................ 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluoromethane. Chlorotrifluoromethane or 2.2 UN1022 ....... 2.2...... ................ 306.........#
Passage 121. 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 13.#
Passage 122Chromic acid solution...... 8 UN1755 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L C 40, 44, TP2, TP12 89, 100, 141 ........................... ........... ................. III 8........ IB3, T4, TP1, 154.......... 203....... 241....... 5 L 60 L C 40, 44, TP12 89, 100, 141 Chromic anhydride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chromium trioxide, anhydrous. Chromic fluoride, solid.... 8 UN1756 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 52 T3, TP33 Chromic fluoride, solution. 8 UN1757 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A ....... ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Chromium nitrate........... 5.1 UN2720 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Chromium oxychloride....... 8 UN1758 I 8........ A3, A6, A7, B10, None......... 201....... 243....... 0.5 L 2.5 L C 40, 66, N34, T10, TP2, 74, 89, TP12 90 Chromium trioxide, 5.1 UN1463 II 5.1, 8... IB8, IP4, T3, None......... 212....... 242....... 5 kg 25 kg A ....... anhydrous. TP33 Chromosulfuric acid........ 8 UN2240 I 8........ A3, A6, A7, B4, None......... 201....... 243....... 0.5 L 2.5 L B 40, 66, B6, N34, T10, 74, 89, TP2, TP12, TP13 90 Chromyl chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chromium oxychloride. Cigar and cigarette ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... lighters, charged with fuel, see Lighters or Lighter refills containing flammable gas.. Coal briquettes, hot....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Coal gas, compressed....... 2.3 UN1023 ....... 2.3, 2.1. 3 None......... 302....... 314, 315.. Forbidden Forbidden D 40 Coal tar distillates, 3 UN1136 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... flammable. ........................... ........... ................. III 3........#
Passage 123B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP29 Coal tar dye, corrosive, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquid, n.o.s, see Dyes, liquid or solid, n.o.s. or Dye intermediates, liquid or solid, corrosive, n.o.s.. Coating solution (includes 3 UN1139 I 3........ T11, TP1, TP8, 150.......... 201....... 243....... 1 L 30 L E ....... surface treatments or TP27 coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining). ........................... ........... ................. II 3........ 149, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Cobalt naphthenates, powder 4.1 UN2001 III 4.1...... A19, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Cobalt resinate, 4.1 UN1318 III 4.1...... A1, A19, IB6, 151.......... 213....... 240....... 25 kg 100 kg A ....... precipitated. T1, TP33 Coke, hot.................. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Collodion, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrocellulose etc. D G Combustible liquid, n.o.s.. Comb liq NA1993 III None..... IB3, T1, T4, TP1 150.......... 203....... 241....... 60 L 220 L A ....... G Components, explosive 1.2B UN0382 II 1.2B..... 101 None......... 62........ None...... Forbidden Forbidden 11 ....... train, n.o.s.. G Components, explosive 1.4B UN0383 II 1.4B..... 101 None......... 62........ None...... Forbidden 75 kg 06 ....... train, n.o.s.. G Components, explosive 1.4S UN0384 II 1.4S..... 101 None......... 62........ None...... 25 kg 100 kg 05 ....... train, n.o.s.. G Components, explosive 1.1B UN0461 II 1.1B..... 101 None......... 62........ None...... Forbidden Forbidden 11 ....... train, n.o.s.. Composition B, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexolite, etc. D G Compounds, cleaning liquid. 8 NA1#
Passage 124760 I 8........ A7, B10, T14, None......... 201....... 243....... 0.5 L 2.5 L B 40 TP2, TP27 ........................... ........... ................. II 8........ B2, IB2, N37, 154.......... 202....... 242....... 1 L 30 L B 40 T11, TP2, TP27 ........................... ........... ................. III 8........ IB3, N37, T7, 154.......... 203....... 241....... 5 L 60 L A 40 TP1, TP28 D G Compounds, cleaning liquid. 3 NA1993 I 3........ T11, TP1 150.......... 201....... 243....... 1 L 30 L E ....... ........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 D G Compounds, tree killing, 8 NA1760 I 8........ A7, B10, T14, None......... 201....... 243....... 0.5 L 2.5 L B 40 liquid or Compounds, weed TP2, TP27 killing, liquid. ........................... ........... ................. II 8........ B2, IB2, N37, 154.......... 202....... 242....... 1 L 30 L B 40 T11, TP2, TP27 ........................... ........... ................. III 8........ IB3, N37, T7, 154.......... 203....... 241....... 5 L 60 L A 40 TP1, TP28 D G Compounds, tree killing, 3 NA1993 I 3........ T11, TP1 150.......... 201....... 243....... 1 L 30 L E ....... liquid or Compounds, weed killing, liquid. ........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 D G Compounds, tree killing, 6.1 NA2810 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid or Compounds, weed TP27 killing, liquid.#
Passage 125........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 G Compressed gas, flammable, 2.1 UN1954 ....... 2.1...... ................ 306.......... 302, 305.. 314, 315.. Forbidden 150 kg D 40 n.o.s.. G Compressed gas, n.o.s...... 2.2 UN1956 ....... 2.2...... ................ 306, 307..... 302, 305.. 314, 315.. 75 kg 150 kg A ....... G Compressed gas, oxidizing, 2.2 UN3156 ....... 2.2, 5.1. A14 306.......... 302....... 314, 315.. 75 kg 150 kg D ....... n.o.s.. G I Compressed gas, toxic, 2.3 UN3304 ....... 2.3, 8... 1 None......... 192....... 245....... Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone A. G I Compressed gas, toxic, 2.3 UN3304 ....... 2.3, 8... 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone B. G I Compressed gas, toxic, 2.3 UN3304 ....... 2.3, 8... 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone C. G I Compressed gas, toxic, 2.3 UN3304 ....... 2.3, 8... 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone D. G I Compressed gas, toxic, 2.3 UN3305 ....... 2.3, 2.1, 1 None......... 192....... 245....... Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone A. G I Compressed gas, toxic, 2.3 UN3305 ....... 2.3, 2.1, 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone B. G I Compressed gas, toxic, 2.3 UN3305 ....... 2.3, 2.1, 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone C. G I Compressed gas, toxic, 2.3 UN3305 ....... 2.3, 2.1, 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone D. G Compressed gas, toxic, 2.3 UN1953 ....... 2.3, 2.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 flammable, n.o.s. Inhalation hazard Zone A. G Compressed gas, toxic, 2.3 UN1953 ....... 2.3, 2.1. 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. In#
Passage 126halation hazard Zone B. G Compressed gas, toxic, 2.3 UN1953 ....... 2.3, 2.1. 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. Inhalation Hazard Zone C. G Compressed gas, toxic, 2.3 UN1953 ....... 2.3, 2.1. 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. Inhalation Hazard Zone D. G Compressed gas, toxic, 2.3 UN1955 ....... 2.3...... 1 None......... 192....... 245....... Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone A. G Compressed gas, toxic, 2.3 UN1955 ....... 2.3...... 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone B. G Compressed gas, toxic, 2.3 UN1955 ....... 2.3...... 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone C. G Compressed gas, toxic, 2.3 UN1955 ....... 2.3...... 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone D. G I Compressed gas, toxic, 2.3 UN3306 ....... 2.3, 5.1, 1 None......... 192....... 244....... Forbidden Forbidden D 40, 89, oxdizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone A. G I Compressed gas, toxic, 2.3 UN3306 ....... 2.3, 5.1, 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone B. G I Compressed gas, toxic, 2.3 UN3306 ....... 2.3, 5.1, 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone C. G I Compressed gas, toxic, 2.3 UN3306 ....... 2.3, 5.1, 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone D. G Compressed gas, toxic, 2.3 UN3303 ....... 2.3, 5.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone A. G Compressed gas, toxic, 2.3 UN3303 ....... 2.3, 5.1. 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone B. G Compressed gas, toxic, 2.3 UN3303 ....... 2.3, 5.1. 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone C. G Compressed gas, toxic, 2.3 UN3303 ....... 2.3, 5.1. 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone D.#
Passage 127D Consumer commodity......... ORM-D ................. ....... None..... ................ 156, 306..... 156, 306.. None...... 30 kg gross 30 kg gross A ....... Contrivances, water- 1.2L UN0248 II 1.2L..... 101 None......... 62........ None...... Forbidden Forbidden 08 8E, activated, with burster, 14E, expelling charge or 15E, propelling charge. 17E Contrivances, water- 1.3L UN0249 II 1.3L..... 101 None......... 62........ None...... Forbidden Forbidden 08 8E, activated, with burster, 14E, expelling charge or 15E, propelling charge. 17E Copper acetoarsenite....... 6.1 UN1585 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Copper acetylide........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Copper amine azide......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Copper arsenite............ 6.1 UN1586 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Copper based pesticides, 3 UN2776 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Copper based pesticides, 6.1 UN3010 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Copper based pesticides, 6.1 UN3009 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP2, TP28 Copper based p#
Passage 128esticides, 6.1 UN2775 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Copper chlorate............ 5.1 UN2721 II 5.1...... A1, IB8, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 IP4, T3, TP33 Copper chloride............ 8 UN2802 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Copper cyanide............. 6.1 UN1587 II 6.1...... IB8, IP2, IP4, 153.......... 204....... 242....... 25 kg 100 kg A 52 T3, TP33 Copper selenate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Copper selenite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Copper tetramine nitrate... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... A W Copra...................... 4.2 UN1363 III 4.2...... IB8, IP3, IP7 None......... 213....... 241....... Forbidden Forbidden A 13, 19, 48, 119 Cord, detonating, flexible. 1.1D UN0065 II 1.1D..... 102 63(a)........ 62........ None...... Forbidden Forbidden 07 ....... Cord, detonating, flexible. 1.4D UN0289 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Cord detonating or Fuse 1.2D UN0102 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... detonating metal clad. Cord, detonating or Fuse, 1.1D UN0290 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... detonating metal clad. Cord, detonating, mild 1.4D UN0104 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... effect or Fuse, detonating, mild effect metal clad. Cord, igniter.............. 1.4G UN0066 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Cordeau detona#
Passage 129nt fuse, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cord, detonating, etc; Cord, detonating, flexible. Cordite, see Powder, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... smokeless. G Corrosive liquid, acidic, 8 UN3264 I 8........ A6, B10, T14, None......... 201....... 243....... 0.5 L 2.5 L B 40 inorganic, n.o.s.. TP2, TP27 ........................... ........... ................. II 8........ A6, B2, IB2, 154.......... 202....... 242....... 1 L 30 L B 40 T11, TP2, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 40 TP28 G Corrosive liquid, acidic, 8 UN3265 I 8........ A6, B10, T14, None......... 201....... 243....... 0.5 L 2.5 L B 40 organic, n.o.s.. TP2, TP27 ........................... ........... ................. II 8........ B2, IB2, T11, 154.......... 202....... 242....... 1 L 30 L B 40 TP2, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 40 TP28 G Corrosive liquid, basic, 8 UN3266 I 8........ A6, T14, TP2, None......... 201....... 243....... 0.5 L 2.5 L B 40, 52 inorganic, n.o.s.. TP27 ........................... ........... ................. II 8........ B2, IB2, T11, 154.......... 202....... 242....... 1 L 30 L B 40, 52 TP2, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 40, 52 TP28#
Passage 130G Corrosive liquid, basic, 8 UN3267 I 8........ A6, B10, T14, None......... 201....... 243....... 0.5 L 2.5 L B 40, 52 organic, n.o.s.. TP2, TP27 ........................... ........... ................. II 8........ B2, IB2, T11, 154.......... 202....... 242....... 1 L 30 L B 40, 52 TP2, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 40, 52 TP28 G Corrosive liquid, self- 8 UN3301 I 8, 4.2... A6, B10 None......... 201....... 243....... 0.5 L 2.5 L D ....... heating, n.o.s.. ........................... ........... ................. II 8, 4.2... B2, IB1 154.......... 202....... 242....... 1 L 30 L D ....... G Corrosive liquids, 8 UN2920 I 8, 3..... A6, B10, T14, None......... 201....... 243....... 0.5 L 2.5 L C 25, 40 flammable, n.o.s.. TP2, TP27 ........................... ........... ................. II 8, 3..... B2, IB2, T11, None......... 202....... 243....... 1 L 30 L C 25, 40 TP2, TP27 G Corrosive liquids, n.o.s... 8 UN1760 I 8........ A6, A7, B10, None......... 201....... 243....... 0.5 L 2.5 L B 40 T14, TP2, TP27 ........................... ........... ................. II 8........ B2, IB2, T11, 154.......... 202....... 242....... 1 L 30 L B 40 TP2, TP27 ........................... ........... ................. III 8........ IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L A 40 TP28 G Corrosive liquids, 8 UN3093 I 8, 5.1... A6, A7 None......... 201....... 243....... Forbidden 2.5 L C 89 oxidizing, n.o.s.. ........................... ........... ................. II 8, 5.1... A6, A7, IB2 None......... 202....... 243....... 1 L 30 L C 89 G Corrosive liquids, toxic, 8 UN2922 I 8, 6.1... A7, A6, B10, None......... 201....... 243....... 0.5 L 2.5 L B 40 n.o.s.. T14, TP2, TP13, TP27 ........................... ........... ................. II 8, 6.1... B3, IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L B 40 ........................... ........... ................. III 8, 6.1... IB3, T7, TP1, 154.......... 203....... 241....... 5 L 60 L B 40 TP28 G Corrosive liquids, water- 8 UN3094 I 8, 4.3... A6, A7 None......... 201....... 243....... Forbidden 1 L E ....... reactive, n.o.s.. ........................... ........... ................. II 8, 4.3... A6, A7 None......... 202....... 243....... 1 L 5 L E ....... G Corrosive solid, acidic, 8 UN3260 I 8.#
Passage 131....... IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg B ....... inorganic, n.o.s.. TP33 ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg B ....... T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 G Corrosive solid, acidic, 8 UN3261 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg B ....... organic, n.o.s.. TP33 ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg B ....... T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 G Corrosive solid, basic, 8 UN3262 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg B 52 inorganic, n.o.s.. TP33 ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg B 52 T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 52 TP33 G Corrosive solid, basic, 8 UN3263 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg B 52 organic, n.o.s.. TP33 ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg B 52 T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 52 TP33 G Corrosive solids, 8 UN2921 I 8, 4.1... IB6, T6, TP33 None......... 211....... 242....... 1 kg 25 kg B 12, 25 flammable, n.o.s.. ........................... ........... ................. II 8, 4.1... IB8, IP2, IP4, None......... 212....... 242....... 15 kg 50 kg B 12, 25 T3, TP33 G Corrosive solids, n.o.s.... 8 UN1759 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg B ....... TP33 ........................... ........... ................. II 8........ 128, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A ....... IP4, T3, TP33 ........................... ........... ................. III 8........ 128, IB8, IP3, 154.......... 213....... 240....... 25#
Passage 132kg 100 kg A ....... T1, TP33 G Corrosive solids, 8 UN3084 I 8, 5.1... T6, TP33 None......... 211....... 242....... 1 kg 25 kg C ....... oxidizing, n.o.s.. ........................... ........... ................. II 8, 5.1... IB6, IP2, T3, None......... 212....... 242....... 15 kg 50 kg C ....... TP33 G Corrosive solids, self- 8 UN3095 I 8, 4.2... T6, TP33 None......... 211....... 243....... 1 kg 25 kg C ....... heating, n.o.s..#
Passage 133........................... ........... ................. II 8, 4.2... IB6, IP2, T3, None......... 212....... 242....... 15 kg 50 kg C ....... TP33 G Corrosive solids, toxic, 8 UN2923 I 8, 6.1... IB7, T6, TP33 None......... 211....... 242....... 1 kg 25 kg B 40 n.o.s.. ........................... ........... ................. II 8, 6.1... IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg B 40 T3, TP33 ........................... ........... ................. III 8, 6.1... IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg B 40, 95 TP33 G Corrosive solids, water- 8 UN3096 I 8, 4.3... IB4, IP1, T6, None......... 211....... 243....... 1 kg 25 kg D ....... reactive, n.o.s.. TP33 ........................... ........... ................. II 8, 4.3... IB6, IP2, T3, None......... 212....... 242....... 15 kg 50 kg D ....... TP33 D W Cotton..................... 9 NA1365 ....... 9........ 137, IB8, IP2, None......... None...... None...... No limit No limit A ....... IP4, W41 A W Cotton waste, oily......... 4.2 UN1364 III 4.2...... IB8, IP3, IP7 None......... 213....... None...... Forbidden Forbidden A 54 A I W Cotton, wet................ 4.2 UN1365 III 4.2...... IB8, IP3, IP7 None......... 204....... 241....... Forbidden Forbidden A ....... Coumarin derivative 3 UN3024 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Coumarin derivative 6.1 UN3026 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 pesticides, liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Coumarin derivative 6.1 UN3025 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 pesticides, liquid, toxic, TP27 flammable, flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ......................#
Passage 134..... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP1, TP28 Coumarin derivative 6.1 UN3027 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 pesticides, solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Cresols, liquid............ 6.1 UN2076 II 6.1, 8... IB2, IP2, IP4, 153.......... 202....... 243....... 1 L 30 L B ....... T7, TP2 Cresols, solid............. 6.1 UN3455 II 6.1, 8... IB8, IP2, IP4, 153.......... 212....... 242....... 15 kg 50 kg B ....... T3, TP33 Cresylic acid.............. 6.1 UN2022 II 6.1, 8... IB2, T7, TP2, 153.......... 202....... 243....... 1 L 30 L B ....... TP13 Crotonaldehyde, stabilized. 6.1 UN1143 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 40 B74, B77, T20, TP2, TP13, TP38, TP45 Crotonic acid liquid....... 8 UN2823 III 8........ IB8, T1 154.......... 203....... 241....... 5 L 60 L A 12 Crotonic acid, solid....... 8 UN2823 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 12 TP33 Crotonylene................ 3 UN1144 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E ....... Cupriethylenediamine 8 UN1761 II 8, 6.1... IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L A ....... solution. ........................... ........... ................. III 8, 6.1... IB3, T7, TP1, 154.......... 203....... 242....... 5 L 60 L A 95 TP28 Cutters, cable, explosive.. 1.4S UN0070 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Cyanide or cyanide ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures, dry, see Cyanides, inorganic, solid, n.o.s.. Cyanide solutions, n.o.s... 6.1 UN1935 I 6.1...... B37, T14, TP2, None......... 201....... 243....... 1 L 30 L B 40, 52 TP13, TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L A 40, 52 TP13, TP27 ........................... ........... ......#
Passage 135........... III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40, 52 TP13, TP28 Cyanides, inorganic, solid, 6.1 UN1588 I 6.1...... IB7, IP1, N74, None......... 211....... 242....... 5 kg 50 kg A 52 n.o.s.. N75, T6, TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 52 N74, N75, T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, N74, 153.......... 213....... 240....... 100 kg 200 kg A 52 N75, T1, TP33 Cyanogen................... 2.3 UN1026 ....... 2.3, 2.1. 2 None......... 304....... 245....... Forbidden Forbidden D 40 Cyanogen bromide........... 6.1 UN1889 I 6.1, 8... A6, A8, T6, TP33 None......... 211....... 242....... 1 kg 15 kg D 40 Cyanogen chloride, 2.3 UN1589 ....... 2.3, 8... 1 None......... 192....... 245....... Forbidden Forbidden D 40 stabilized. Cyanuric chloride.......... 8 UN2670 II 8........ IB8, IP2, IP4, None......... 212....... 240....... 15 kg 50 kg A 12, 40 T3, TP33#
Passage 136Cyanuric triazide.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cyclobutane................ 2.1 UN2601 ....... 2.1...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Cyclobutyl chloroformate... 6.1 UN2744 II 6.1, 8, 3 IB1, T7, TP2, 153.......... 202....... 243....... 1 L 30 L A 12, 13, TP13 21, 25, 40, 100 1,5,9-Cyclododecatriene.... 6.1 UN2518 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 40 Cycloheptane............... 3 UN2241 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Cycloheptatriene........... 3 UN2603 II 3, 6.1... IB2, T7, TP1, 150.......... 202....... 243....... 1 L 60 L E 40 TP13 Cycloheptene............... 3 UN2242 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Cyclohexane................ 3 UN1145 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Cyclohexanone.............. 3 UN1915 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Cyclohexene................ 3 UN2256 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Cyclohexenyltrichlorosilane 8 UN1762 II 8........ A7, B2, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Cyclohexyl acetate......... 3 UN2243 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Cyclohexyl isocyanate...... 6.1 UN2488 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Cyclohexyl mercaptan....... 3 UN3054 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 40, 95 Cyclohexylamine............ 8 UN2357 II 8, 3..... IB2, T7, TP2 None......... 202....... 243....... 1 L 30 L A 40 Cyclohexyltrichlorosilane.. 8 UN1763 II 8........ A7, B2, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Cyclonite and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... cyclotetramethylenetetrani tramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite and HMX mixtures, ...........#
Passage 137................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite and octogen ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cyclotrimethylenetrinitram ine, etc. Cyclooctadiene phosphines, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see 9- Phosphabicyclononanes. Cyclooctadienes............ 3 UN2520 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Cyclooctatetraene.......... 3 UN2358 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Cyclopentane............... 3 UN1146 II 3........ IB2, T7, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Cyclopentane, methyl, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methylcyclopentane. Cyclopentanol.............. 3 UN2244 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Cyclopentanone............. 3 UN2245 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Cyclopentene............... 3 UN2246 II 3........ IB2, IP8, T7, 150.......... 202....... 242....... 5 L 60 L E ....... TP2 Cyclopropane............... 2.1 UN1027 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Cyclotetramethylene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tetranitramine (dry or unphlegmatized) (HMX). Cyclotetramethylenetetranit 1.1D UN0484 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... ramine, desensitized or Octogen, desensitized or HMX, desensitized. Cyclotetramethylenetetranit 1.1D UN0226 II 1.1D..... ................ None.........#
Passage 13862........ None...... Forbidden Forbidden 10 ....... ramine, wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass. Cyclotrimethylenetrinitrami ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ne and cyclotetramethylenetetrani tramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclotrimethylenenitramine ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... and octogen, mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclotrimethylenetrinitrami ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ne and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclotrimethylenetrinitrami 1.1D UN0483 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... ne, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized. Cyclotrimethylenetrinitrami 1.1D UN0072 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... ne, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass. Cymenes.................... 3 UN2046 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Dangerous Goods in 9 UN3363 ....... ......... 136 None......... 222....... None...... No limit No limit A ....... Machinery or Dangerous Goods in Apparatus. Decaborane................. 4.1 UN1868 II 4.1, 6.1. A19, A20, IB6, None......... 212....... None...... Forbidden 50 kg A 74 IP2, T3, TP33 Decahydronaphthalene....... 3 UN1147 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... n-Decane................... 3 UN2247 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Deflagrating metal salts of 1.3C UN0132 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E aromatic nitroderivatives, n.o.s..#
Passage 139Delay electric igniter, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Igniters. Depth charges, see Charges, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... depth. G Desensitized explosive, 3 UN3379 I 3........ 164 None......... 201....... None...... Forbidden Forbidden D 36 liquid, n.o.s.. G Desensitized explosive, 4.1 UN3380 I 4.1...... 164 None......... 211....... None...... Forbidden Forbidden D 28, 36 solid, n.o.s.. Detonating relays, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Detonators, etc. Detonator assemblies, non- 1.1B UN0360 II 1.1B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... electric for blasting. Detonator assemblies, non- 1.4B UN0361 II 1.4B..... 103 63(f), 63(g). 62........ None...... Forbidden 75 kg 06 ....... electric, for blasting. Detonator, assemblies, non- 1.4S UN0500 II 1.4S..... ................ 63(f), 63(g). 62........ None...... 25 kg 100 kg 05 ....... electric for blasting. Detonators, electric, for 1.1B UN0030 II 1.1B..... ................ 63(f), 63(g). 62........ None...... Forbidden Forbidden 11 ....... blasting. Detonators, electric, for 1.4B UN0255 II 1.4B..... 103 63(f), 63(g). 62........ None...... Forbidden 75 kg 06 ....... blasting. Detonators, electric for 1.4S UN0456 II 1.4S..... ................ 63(f), 63(g). 62........ None...... 25 kg 100 kg 05 ....... blasting. Detonators for ammunition.. 1.1B UN0073 II 1.1B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... Detonators for ammunition.. 1.2B UN0364 II 1.2B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... Detonators for ammunition.. 1.4B UN0365 II 1.4B..... 103 None......... 62........ None...... Forbidden 75 kg 06 ....... Detonators for ammunition.. 1.4S UN0366 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Detonators, non-electric, 1.1B UN0029 II 1.1B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... for blasting. Detonators, non-electric, 1.4B UN0267 II 1.4B..... 103 6#
Passage 1403(f), 63(g). 62........ None...... Forbidden 75 kg 06 ....... for blasting. Detonators, non- 1.4S UN0455 II 1.4S..... ................ 63(f), 63(g). 62........ None...... 25 kg 100 kg 5 ....... electric,for blasting. Deuterium, compressed...... 2.1 UN1957 ....... 2.1...... ................ 306.......... 302....... None...... Forbidden 150 kg E 40 Devices, small, hydrocarbon 2.1 UN3150 ....... 2.1...... ................ 306.......... 304....... None...... Forbidden 150 kg B 40 gas powered or Hydrocarbon gas refills for small devices with release device. Di-n-amylamine............. 3 UN2841 III 3, 6.1... B1, IB3, T4, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Di-n-butyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxydicarbonate, with more than 52 percent in solution. Di-n-butylamine............ 8 UN2248 II 8, 3..... IB2, T7, TP2 None......... 202....... 243....... 1 L 30 L A ....... 2,2-Di-(tert-butylperoxy) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... butane, with more than 55 percent in solution. Di-(tert-butylperoxy) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... phthalate, with more than 55 percent in solution. 2,2-Di-(4,4-di-tert- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... butylperoxycyclohexyl) propane, with more than 42 percent with inert solid. Di-2,4-dichlorobenzoyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxide, with more than 75 percent with water. 1,2-Di- 3 UN2372 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... (dimethylamino)ethane. Di-2-ethylhexyl phosphoric ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... acid, see Diisooctyl acid phosphate. Di-(1-hydroxytetrazole) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). Di-(#
Passage 1411-naphthoyl) peroxide.. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... a,a'-Di-(nitroxy) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... methylether. Di-(beta-nitroxyethyl) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ammonium nitrate. Diacetone alcohol.......... 3 UN1148 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Diacetone alcohol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass. Diacetyl, see Butanedione.. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diacetyl peroxide, solid, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... or with more than 25 percent in solution. Diallylamine............... 3 UN2359 II 3, 6.1, 8 IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 21, 40, 100 Diallylether............... 3 UN2360 II 3, 6.1... IB2, N12, T7, 150.......... 202....... 243....... 1 L 60 L E 40 TP1, TP13 4,4'-Diaminodiphenyl 6.1 UN2651 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... methane. TP33 p-Diazidobenzene........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1,2-Diazidoethane.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1,1'-Diazoaminonaphthalene. Forbidden ................. ....... ......... ................ ............. .......... .......... ......#
Passage 142..... ........... .......... ....... Diazoaminotetrazole (dry).. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diazodinitrophenol (dry)... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diazodinitrophenol, wetted 1.1A UN0074 II 1.1A..... 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... with not less than 40 percent water or mixture of alcohol and water, by mass. Diazodiphenylmethane....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diazonium nitrates (dry)... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diazonium perchlorates Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). 1,3-Diazopropane........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dibenzyl peroxydicarbonate, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 87 percent with water. Dibenzyldichlorosilane..... 8 UN2434 II 8........ B2, IB2, T7, 154.......... 202....... 242....... 1 L 30 L C 40 TP2, TP13 Diborane................... 2.3 UN1911 ....... 2.3, 2.1. 1 None......... 302....... None...... Forbidden Forbidden D 40, 57 D Diborane mixtures.......... 2.1 NA1911 ....... 2.1...... 5 None......... 302....... 245....... Forbidden Forbidden D 40, 57 Dibromoacetylene........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1,2-Dibromobutan-3-one..... 6.1 UN2648 II 6.1...... IB2 153.......... 202....... 243....... 5 L 60 L B 40 Dibromochloropropane....... 6.1 UN2872 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... ........................... ........... ................. III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A .......#
Passage 143A Dibromodifluoromethane, 9 UN1941 III None..... T11, TP2 155.......... 203....... 241....... 100 L 220 L A 25 R12B2. 1,2-Dibromoethane, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethylene dibromide. Dibromomethane............. 6.1 UN2664 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Dibutyl ethers............. 3 UN1149 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Dibutylaminoethanol........ 6.1 UN2873 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... N,N'- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dichlorazodicarbonamidine (salts of) (dry). 1,1-Dichloro-1-nitroethane. 6.1 UN2650 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 12, 40, 74 D 3,5-Dichloro-2,4,6- 6.1 NA9264 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A 40 trifluoropyridine. B74, T20, TP4, TP12, TP13, TP38, TP45 Dichloroacetic acid........ 8 UN1764 II 8........ A3, A6, A7, B2, 154.......... 202....... 242....... 1 L 30 L A ....... IB2, N34, T8, TP2, TP12 1,3-Dichloroacetone........ 6.1 UN2649 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 12, 40 T3, TP33 Dichloroacetyl chloride.... 8 UN1765 II 8........ A3, A6, A7, B2, 154.......... 202....... 242....... 1 L 30 L D 40 B6, IB2, N34, T7, TP2 Dichloroacetylene.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... + Dichloroanilines, liquid... 6.1 UN1590 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 Dichloroanilines, solid.... 6.1 UN3442 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 + o-Dichlorobenzene.......... 6.1 UN1591 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... 2,2'-Dichlorodiethyl ether. 6.1 UN1916 II 6.1, 3... IB2, N33, N34, 153.......... 202....... 243....... 5 L 60 L A ....... T7, TP2 Dichlorodifluoromethane and 2.2 UN2602 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... difluoroethane azeot#
Passage 144ropic mixture or Refrigerant gas R 500 with approximately 74 percent dichlorodifluoromethane. Dichlorodifluoromethane or 2.2 UN1028 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 12. Dichlorodimethyl ether, 6.1 UN2249 I 6.1, 3... ................ None......... 201....... 243....... Forbidden Forbidden .......... 40 symmetrical. 1,1-Dichloroethane......... 3 UN2362 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 1,2-Dichloroethane, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethylene dichloride. Dichloroethyl sulfide...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1,2-Dichloroethylene....... 3 UN1150 II 3........ IB2, T7, TP2 150.......... 202....... 242....... 5 L 60 L B ....... Dichlorofluoromethane or 2.2 UN1029 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R21. Dichloroisocyanuric acid, 5.1 UN2465 II 5.1...... 28, IB8, IP4, 152.......... 212....... 240....... 5 kg 25 kg A 13 dry or Dichloroisocyanuric T3, TP33 acid salts. Dichloroisopropyl ether.... 6.1 UN2490 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L B ....... Dichloromethane............ 6.1 UN1593 III 6.1...... IB3, IP8, N36, 153.......... 203....... 241....... 60 L 220 L A ....... T7, TP2 Dichloropentanes........... 3 UN1152 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Dichlorophenyl isocyanates. 6.1 UN2250 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 25, 40, T3, TP33 48 Dichlorophenyltrichlorosila 8 UN1766 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 ne. N34, T7, TP2, TP13 1,2-Dichloropropane........ 3 UN1279 II 3........ IB2, N36, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1 1,3-Dichloropropanol-2..... 6.1 UN2750 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 12, 40 Dichloropropene and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... propylene dichloride mixture, see 1,2- Dichloropropane. Di#
Passage 145chloropropenes........... 3 UN2047 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Dichlorosilane............. 2.3 UN2189 ....... 2.3, 2.1, 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 17, 40 8. 1,2-Dichloro-1,1,2,2- 2.2 UN1958 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... tetrafluoroethane or Refrigerant gas R 114. Dichlorovinylchloroarsine.. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dicycloheptadiene, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Bicyclo [2,2,1] hepta-2,5- diene, stabilized. Dicyclohexylamine.......... 8 UN2565 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Dicyclohexylammonium 4.1 UN2687 III 4.1...... IB8, IP3, T1, 151.......... 213....... 240....... 25 kg 100 kg A 48 nitrite. TP33#
Passage 146Dicyclopentadiene.......... 3 UN2048 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Didymium nitrate........... 5.1 UN1465 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 D Diesel fuel................ 3 NA1993 III None..... 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 I Diesel fuel................ 3 UN1202 III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T2, TP1 Diethanol nitrosamine Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dinitrate (dry). Diethoxymethane............ 3 UN2373 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... 3,3-Diethoxypropene........ 3 UN2374 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Diethyl carbonate.......... 3 UN2366 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Diethyl cellosolve, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethylene glycol diethyl ether. Diethyl ether or Ethyl 3 UN1155 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E 40 ether. Diethyl ketone............. 3 UN1156 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Diethyl peroxydicarbonate, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with more than 27 percent in solution. Diethyl sulfate............ 6.1 UN1594 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L C ....... Diethyl sulfide............ 3 UN2375 II 3........ IB2, T7, TP1, None......... 202....... 243....... 5 L 60 L E ....... TP13 Diethylamine............... 3 UN1154 II 3, 8..... A3, IB2, N34, 150.......... 202....... 243....... 1 L 5 L E 40 T7, TP1 2-Diethylaminoethanol...... 8 UN2686 II 8, 3..... B2, IB2, T7, TP2 None......... 202....... 243....... 1 L 30 L A ....... 3-Diethyamino-propylamine.. 3 UN2684 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A ....... + N, N-Diethylaniline........ 6.1 UN2432 III 6.1...... IB3, T4, TP1 153.......... 2#
Passage 14703....... 241....... 60 L 220 L A ....... Diethylbenzene............. 3 UN2049 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Diethyldichlorosilane...... 8 UN1767 II 8, 3..... A7, B6, IB2, None......... 202....... 243....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Diethylene glycol dinitrate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diethyleneglycol dinitrate, 1.1D UN0075 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 13 21E desensitized with not less than 25 percent non- volatile water-insoluble phlegmatizer, by mass. Diethylenetriamine......... 8 UN2079 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 40, 52 N,N-Diethylethylenediamine. 8 UN2685 II 8, 3..... IB2, T7, TP2 None......... 202....... 243....... 1 L 30 L A ....... Diethylgold bromide........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diethylthiophosphoryl 8 UN2751 II 8........ B2, IB2, T7, TP2 None......... 212....... 240....... 15 kg 50 kg D 12, 40 chloride. Diethylzinc................ 4.2 UN1366 I 4.2, 4.3. B11, T21, TP2, None......... 181....... 244....... Forbidden Forbidden D 18 TP7 Difluorochloroethanes, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1-Chloro-1,1- difluoroethanes. 1,1-Difluoroethane or 2.1 UN1030 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Refrigerant gas R 152a. 1,1-Difluoroethylene or 2.1 UN1959 ....... 2.1...... ................ 306.......... 304....... None...... Forbidden 150 kg E 40 Refrigerant gas R 1132a. Difluoromethane or 2.1 UN3252 ....... 2.1...... T50 306.......... 302....... 314, 315.. Forbidden 150 kg D 40 Refrigerant gas R 32. Difluorophosphoric acid, 8 UN1768 II 8........ A6, A7, B2, IB2, None......... 202....... 242....... 1 L 30 L A 40 anhydrous. N5, N34, T8, TP2, TP12 2,3-Dihydropyran........... 3 UN2376 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... 1,8-Dihydroxy-2,4,5,7- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ....#
Passage 148....... .......... ....... tetranitroanthraquinone (chrysamminic acid). Diiodoacetylene............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Diisobutyl ketone.......... 3 UN1157 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Diisobutylamine............ 3 UN2361 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A ....... Diisobutylene, isomeric 3 UN2050 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... compounds. Diisooctyl acid phosphate.. 8 UN1902 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Diisopropyl ether.......... 3 UN1159 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E 40 Diisopropylamine........... 3 UN1158 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... Diisopropylbenzene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hydroperoxide, with more than 72 percent in solution. Diketene, stabilized....... 6.1 UN2521 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 26, 27, B74, T20, TP2, 40 TP13, TP38, TP45 1,2-Dimethoxyethane........ 3 UN2252 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... 1,1-Dimethoxyethane........ 3 UN2377 II 3........ IB2, T7, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Dimethyl carbonate......... 3 UN1161 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Dimethyl ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chlorothiophosphate, see Dimethyl thiophosphoryl chloride. 2,5-Dimethyl-2,5- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dihydroperoxy hexane, with more than 82 percent with water. Dimethyl disulfide......... 3 UN2381 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Dimethyl ether............. 2.1 UN1033 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Dimethyl-N-propylamine..... 3 UN22#
Passage 14966 II 3, 8..... IB2, T7, TP2, 150.......... 202....... 243....... 1 L 5 L B 40 TP13 Dimethyl sulfate........... 6.1 UN1595 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Dimethyl sulfide........... 3 UN1164 II 3........ IB2, IP8, T7, 150.......... 202....... 242....... 5 L 60 L E 40 TP2 Dimethyl thiophosphoryl 6.1 UN2267 II 6.1, 8... IB2, T7, TP2 153.......... 202....... 243....... 1 L 30 L B 25 chloride.#
Passage 150Dimethylamine, anhydrous... 2.1 UN1032 ....... 2.1...... T50 None......... 304....... 314, 315.. Forbidden 150 kg D 40 Dimethylamine solution..... 3 UN1160 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... 2-Dimethylaminoacetonitrile 3 UN2378 II 3, 6.1... IB2, T7, TP1 150.......... 202....... 243....... 1 L 60 L A 52, 40 2-Dimethylaminoethanol..... 8 UN2051 II 8, 3..... B2, IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L A ....... 2-Dimethylaminoethyl 6.1 UN3302 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L D 25 acrylate. 2-Dimethylaminoethyl 6.1 UN2522 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L B 40 methacrylate. N,N-Dimethylaniline........ 6.1 UN2253 II 6.1...... IB1, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... 2,3-Dimethylbutane......... 3 UN2457 II 3........ IB2, T7, TP1 150.......... 202....... 242....... 5 L 60 L E ....... 1,3-Dimethylbutylamine..... 3 UN2379 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... Dimethylcarbamoyl chloride. 8 UN2262 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 40 Dimethylcyclohexanes....... 3 UN2263 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... N,N-Dimethylcyclohexylamine 8 UN2264 II 8, 3..... B2, IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L A 40 Dimethyldichlorosilane..... 3 UN1162 II 3, 8..... B77, IB2, T7, None......... 202....... 243....... Forbidden Forbidden B 40 TP2, TP13 Dimethyldiethoxysilane..... 3 UN2380 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Dimethyldioxanes........... 3 UN2707 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... N,N-Dimethylformamide...... 3 UN2265 III 3........ B1, IB3, T2, TP2 150.......... 203....... 242....... 60 L 220 L A ....... Dimethylhexane Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dihydroperoxide (dry). Dimethylhydrazine, 6.1 UN2382 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40, 74 symmetrical. B74, B77, T20, TP2,#
Passage 151TP13, TP38, TP45 Dimethylhydrazine, 6.1 UN1163 I 6.1, 3, 8 2, B7, B9, B14, None......... 227....... 244....... Forbidden Forbidden D 21, 38, unsymmetrical. B32, B74, T20, 40, 100 TP2, TP13, TP38, TP45 2,2-Dimethylpropane........ 2.1 UN2044 ....... 2.1...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Dimethylzinc............... 4.2 UN1370 I 4.2, 4.3. B11, B16, T21, None......... 181....... 244....... Forbidden Forbidden D 18 TP2, TP7 Dinitro-o-cresol........... 6.1 UN1598 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 1,3-Dinitro-5,5-dimethyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hydantoin. Dinitro-7,8- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dimethylglycoluril (dry). 1,3-Dinitro-4,5- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dinitrosobenzene. 1,4-Dinitro-1,1,4,4- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tetramethylolbutanetetrani trate (dry). 2,4-Dinitro-1,3,5- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trimethylbenzene. Dinitroanilines............ 6.1 UN1596 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 91 T3, TP33 Dinitrobenzenes, liquid.... 6.1 UN1597 II 6.1...... 11, IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 91 ........................... ........... ................. III 6.1...... 11, IB3, T7, TP2 153.......... 203....... 241....... 60 L 220 L A 91 Dinitrobenzenes, solid..... 6.1 UN3443 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 91 T3, TP33 Dinitrochlorobenzene, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorodinitrobenzene. 1,2-Dinitroethane.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ...#
Passage 152.... 1,1-Dinitroethane (dry).... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dinitrogen tetroxide....... 2.3 UN1067 ....... 2.3, 5.1, 1, B7, B14, B45, None......... 336....... 314....... Forbidden Forbidden D 40, 89, 8. B46, B61, B66, 90 B67, B77, T50, TP21 Dinitroglycoluril or Dingu. 1.1D UN0489 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Dinitromethane............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dinitrophenol, dry or 1.1D UN0076 II 1.1D, 6.1 ................ None......... 62........ None...... Forbidden Forbidden 10 5E wetted with less than 15 percent water, by mass. Dinitrophenol solutions.... 6.1 UN1599 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 36 ........................... ........... ................. III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 36 Dinitrophenol, wetted with 4.1 UN1320 I 4.1, 6.1. 23, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28, 36 not less than 15 percent A20, N41 water, by mass. Dinitrophenolates alkali 1.3C UN0077 II 1.3C, 6.1 ................ None......... 62........ None...... Forbidden Forbidden 10 5E metals, dry or wetted with less than 15 percent water, by mass. Dinitrophenolates, wetted 4.1 UN1321 I 4.1, 6.1. 23, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28, 36 with not less than 15 A20, N41 percent water, by mass. Dinitropropylene glycol.... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... .......#
Passage 153Dinitroresorcinol, dry or 1.1D UN0078 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E wetted with less than 15 percent water, by mass. 2,4-Dinitroresorcinol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (heavy metal salts of) (dry). 4,6-Dinitroresorcinol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (heavy metal salts of) (dry). Dinitroresorcinol, wetted 4.1 UN1322 I 4.1...... 23, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28, 36 with not less than 15 A20, N41 percent water, by mass. 3,5-Dinitrosalicylic acid Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (lead salt) (dry). Dinitrosobenzene........... 1.3C UN0406 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Dinitrosobenzylamidine and Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... salts of (dry). 2,2-Dinitrostilbene........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dinitrotoluenes, liquid.... 6.1 UN2038 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Dinitrotoluenes, solid..... 6.1 UN3454 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Dinitrotoluenes, molten.... 6.1 UN1600 II 6.1...... T7, TP3 None......... 202....... 243....... Forbidden Forbidden C ....... 1,9-Dinitroxy Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... pentamethylene-2,4, 6,8- tetramine (dry). Dioxane.................... 3 UN1165 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Dioxolane.................. 3 UN1166 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Dipentene.................. 3 UN2052 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Diphenylamine chloroarsine. 6.1 UN1698 I 6.1..#
Passage 154.... T6, TP33 None......... 201....... None...... Forbidden Forbidden D 40 Diphenylchloroarsine, 6.1 UN1699 I 6.1...... A8, B14, B32, None......... 201....... 243....... Forbidden 30 L D 40 liquid. N33, N34, T14, TP2, TP13, TP27 Diphenyl-chloroarsine, 6.1 UN3450 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg D 40 solid. TP33 Diphenyldichlorosilane..... 8 UN1769 II 8........ A7, B2, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Diphenylmethyl bromide..... 8 UN1770 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg D 40 T3, TP33 Dipicryl sulfide, dry or 1.1D UN0401 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... wetted with less than 10 percent water, by mass. Dipicryl sulfide, wetted 4.1 UN2852 I 4.1...... 162, A2, N41, None......... 211....... None...... Forbidden 0.5 kg D 28 with not less than 10 N84 percent water, by mass. Dipicrylamine, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexanitrodiphenylamine. Dipropionyl peroxide, with Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... more than 28 percent in solution. Di-n-propyl ether.......... 3 UN2384 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Dipropyl ketone............ 3 UN2710 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Dipropylamine.............. 3 UN2383 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... G Disinfectant, liquid, 8 UN1903 I 8........ A6, A7, B10, None......... 201....... 243....... 0.5 L 2.5 L B ....... corrosive, n.o.s.. T14, TP2, TP27 G Disinfectants, liquid, 8 UN1903 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L B ....... corrosive n.o.s.. ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... G Disinfectants, liquid, 6.1 UN3142 I 6.1...... A4, T14, TP2, None......... 201....... 243....... 1 L 30 L A 40 toxic, n.o.s.. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243......#
Passage 155. 5 L 60 L A 40 TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 G Disinfectants, solid, 6.1 UN1601 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 toxic, n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Disodium trioxosilicate.... 8 UN3253 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 G Dispersant gases, n.o.s. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Refrigerant gases, n.o.s.. Divinyl ether, stabilized.. 3 UN1167 I 3........ A7, T11, TP2 None......... 201....... 243....... 1 L 30 L E 40 Dodecyltrichlorosilane..... 8 UN1771 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Dry ice, see Carbon ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dioxide, solid. G Dyes, liquid, corrosive, 8 UN2801 I 8........ 11, A6, B10, None......... 201....... 243....... 0.5 L 2.5 L A ....... n.o.s. or Dye T14, TP2, TP27 intermediates, liquid, corrosive, n.o.s.. ........................... ........... ................. II 8........ 11, B2, IB2, 154.......... 202....... 242....... 1 L 30 L A ....... T11, TP2, TP27 ........................... ........... ................. III 8........ 11, IB3, T7, 154.......... 203....... 241....... 5 L 60 L A ....... TP1, TP28 G Dyes, liquid, toxic, n.o.s. 6.1 UN1602 I 6.1...... ................ None......... 201....... 243....... 1 L 30 L A ....... or Dye intermediates, liquid, toxic, n.o.s.. ........................... ........... ................. II 6.1...... IB2 153.......... 202....... 243....... 5 L 60 L A ....... ........................... ........... ................. III 6.1...... IB3 153.......... 203....... 241....... 60 L 220 L A ....... G Dyes, solid, corrosive, 8 UN3147 I 8........ IB7, IP1, T6, None......... 211....... 242....... 1 kg 25 kg A ......#
Passage 156. n.o.s. or Dye TP33 intermediates, solid, corrosive, n.o.s.. ........................... ........... ................. II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... T3, TP33 ........................... ........... ................. III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33#
Passage 157G Dyes, solid, toxic, n.o.s. 6.1 UN3143 I 6.1...... A5, IB7, IP1, None......... 211....... 242....... 5 kg 50 kg A ....... or Dye intermediates, T6, TP33 solid, toxic, n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Dynamite, see Explosive, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... blasting, type A. Electrolyte (acid or ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... alkali) for batteries, see Battery fluid, acid or Battery fluid, alkali. Elevated temperature 3 UN3256 III 3........ IB1, T3, TP3, None......... None...... 247....... Forbidden Forbidden A ....... liquid, flammable, n.o.s., TP29 with flash point above 37.8 C, at or above its flash point. Elevated temperature 9 UN3257 III 9........ IB1, T3, TP3, None......... None...... 247....... Forbidden Forbidden A 85 liquid, n.o.s., at or TP29 above 100 C and below its flash point (including molten metals, molten salts, etc.). Elevated temperature solid, 9 UN3258 III 9........ ................ 247(h) (4)... None...... 247....... Forbidden Forbidden A 85 n.o.s., at or above 240 C, see Sec. 173.247(h)(4). Engines, internal 9 UN3166 ....... 9........ 135 220.......... 220....... 220....... Forbidden No limit A ....... combustion, flammable gas powered. Engines, internal 9 UN3166 ....... 9........ 135 220.......... 220....... 220....... No limit No limit A ....... combustion, flammable liquid powered. G Environmentally hazardous 9 UN3082 III 9........ 8, 146, IB3, T4, 155.......... 203....... 241....... No limit No limit A ....... substances, liquid, n.o.s.. TP1, TP29 G Environmentally hazardous 9 UN3077 III 9........ 8, 146, B54, 155.......... 213....... 240....... No limit No limit A ....... substances, solid, n.o.s.. IB8, IP3, N20, T1, TP33 Epibromohydrin............. 6.1 UN2558 I 6.1, 3... T14, TP2, TP13 None......... 201....... 243....... Forbidden Forbidden D 40 + Epichlorohydrin............ 6.1 UN2023 II 6.1, 3... IB2, T7, TP2, 153.......... 202......#
Passage 158. 243....... 5 L 60 L A 40 TP13 1,2-Epoxy-3-ethoxypropane.. 3 UN2752 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Esters, n.o.s.............. 3 UN3272 II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP29 Etching acid, liquid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... n.o.s., see Hydrofluoric acid, solution etc. Toxins, extracted from 6.1 UN3462 I 6.1...... 141, IB7, IP1, None......... 211....... 243....... 5 kg 50 kg B ....... living sources, solid, T6, TP33 n.o.s.. ........................... ........... ................. II 6.1...... 141, IB8, IP2, None......... 212....... 243....... 25 kg 100 kg B ....... IP4, T3, TP33 Ethane..................... 2.1 UN1035 ....... 2.1...... ................ 306.......... 304....... 302....... Forbidden 150 kg E 40 Toxins, extracted from 6.1 UN3462 III 6.1...... 141, IB8, IP3, 153.......... 213....... 241....... 100 kg 200 kg A ....... living sources, solid, T1, TP33 n.o.s.. D Ethane-Propane mixture, 2.1 NA1961 ....... 2.1...... T75, TP5 None......... 316....... 314, 315.. Forbidden Forbidden D 40 refrigerated liquid. Ethane, refrigerated liquid 2.1 UN1961 ....... 2.1...... T75, TP5 None......... None...... 315....... Forbidden Forbidden D 40 Ethanol amine dinitrate.... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethanol or Ethyl alcohol or 3 UN1170 II 3........ 24, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L A ....... Ethanol solutions or Ethyl alcohol solutions. ........................... ........... ................. III 3........ 24, B1, IB3, T2, 150.......... 203....... 242....... 60 L 220 L A ....... TP1 Ethanolamine or 8 UN2491 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Ethanolamine solutions. Ether, see Diethyl ether... ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethers, n.o.s.............. 3 UN3271 II 3........ IB2, T7, TP1, 150........#
Passage 159.. 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP29 Ethyl acetate.............. 3 UN1173 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Ethyl acrylate, stabilized. 3 UN1917 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B 40 TP13 Ethyl alcohol, see Ethanol. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethyl aldehyde, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Acetaldehyde. Ethyl amyl ketone.......... 3 UN2271 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... N-Ethylbenzyltoluidines, 6.1 UN3460 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... solid. TP33 N-Ethyl-N-benzylaniline.... 6.1 UN2274 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Ethyl borate............... 3 UN1176 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Ethyl bromide.............. 6.1 UN1891 II 6.1...... IB2, IP8, T7, 153.......... 202....... 243....... 5 L 60 L B 40, 85 TP2, TP13 Ethyl bromoacetate......... 6.1 UN1603 II 6.1, 3... IB2, T7, TP2 None......... 202....... 243....... Forbidden Forbidden D 40 Ethyl butyl ether.......... 3 UN1179 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Ethyl butyrate............. 3 UN1180 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A .......#
Passage 160Ethyl chloride............. 2.1 UN1037 ....... 2.1...... B77, T50 None......... 322....... 314, 315.. Forbidden 150 kg B 40 Ethyl chloroacetate........ 6.1 UN1181 II 6.1, 3... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Ethyl chloroformate........ 6.1 UN1182 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 21, 40, B74, N34, T20, 100 TP2, TP13, TP38, TP45 Ethyl 2-chloropropionate... 3 UN2935 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... + Ethyl chlorothioformate.... 8 UN2826 II 8, 6.1, 3 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A 40 B74, T20, TP2, TP38, TP45 Ethyl crotonate............ 3 UN1862 II 3........ IB2, T4, TP2 150.......... 202....... 242....... 5 L 60 L B ....... Ethyl ether, see Diethyl ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ether. Ethyl fluoride or 2.1 UN2453 ....... 2.1...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Refrigerant gas R161. Ethyl formate.............. 3 UN1190 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Ethyl hydroperoxide........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethyl isobutyrate.......... 3 UN2385 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... + Ethyl isocyanate........... 3 UN2481 I 3, 6.1... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40, 52 B72, T22, TP2, TP13, TP38, TP44 Ethyl lactate.............. 3 UN1192 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Ethyl mercaptan............ 3 UN2363 I 3........ A6, T11, TP2, None......... 201....... 243....... Forbidden 30 L E 95, 102 TP13 Ethyl methacrylate, 3 UN2277 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... stabilized. Ethyl methyl ether......... 2.1 UN1039 ....... 2.1...... ................ None......... 201....... 314, 315.. Forbidden 150 kg B 40 Ethyl methyl ketone or 3 UN1193 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyl ethyl ketone. Ethyl nitrite solutions.... 3 UN1194 I 3, 6.1...#
Passage 161................ None......... 201....... None...... Forbidden Forbidden E 40, 105 Ethyl orthoformate......... 3 UN2524 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Ethyl oxalate.............. 6.1 UN2525 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Ethyl perchlorate.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... D Ethyl phosphonothioic 6.1 NA2927 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 dichloride, anhydrous. B74, T20, TP4, TP12, TP13, TP38, TP45 D Ethyl phosphonous 6.1 NA2845 I 6.1, 4.2. 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 18 dichloride, anhydrous B74, T20, TP4, pyrophoric liquid. TP12, TP13, TP38, TP45 D Ethyl phosphorodichloridate 6.1 NA2927 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP4, TP12, TP13, TP38, TP45 Ethyl propionate........... 3 UN1195 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Ethyl propyl ether......... 3 UN2615 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Ethyl silicate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetraethyl silicate. Ethylacetylene, stabilized. 2.1 UN2452 ....... 2.1...... ................ None......... 304....... 314, 315.. Forbidden 150 kg B 40 Ethylamine................. 2.1 UN1036 ....... 2.1...... B77, T50 None......... 321....... 314, 315.. Forbidden 150 kg D 40 Ethylamine, aqueous 3 UN2270 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 solution with not less than 50 percent but not more than 70 percent ethylamine. N-Ethylaniline............. 6.1 UN2272 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 52, 74 2-Ethylaniline............. 6.1 UN2273 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 52, 74 Ethylbenzene............... 3 UN1175 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... N-Ethylbenzyltoluidines 6.1 UN2753 III 6.1...... IB3, T7, TP1 153.......... 203....... 241....... 60 L 220 L A ....... li#
Passage 162quid. 2-Ethylbutanol............. 3 UN2275 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 2-Ethylbutyl acetate....... 3 UN1177 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 2-Ethylbutyraldehyde....... 3 UN1178 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Ethyldichloroarsine........ 6.1 UN1892 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 Ethyldichlorosilane........ 4.3 UN1183 I 4.3, 8, 3 A2, A3, A7, N34, None......... 201....... 244....... Forbidden 1 L D 21, 28, T10, TP2, TP7, 40, 49, TP13 100 Ethylene, acetylene and 2.1 UN3138 ....... 2.1...... T75, TP5 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 57 propylene in mixture, refrigerated liquid with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene. Ethylene chlorohydrin...... 6.1 UN1135 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 Ethylene................... 2.1 UN1962 ....... 2.1...... ................ 306.......... 304....... 302....... Forbidden 150 kg E 40#
Passage 163Ethylene diamine Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diperchlorate. Ethylene dibromide......... 6.1 UN1605 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Ethylene dibromide and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... methyl bromide liquid mixtures, see Methyl bromide and ethylene dibromide, liquid mixtures. Ethylene dichloride........ 3 UN1184 II 3, 6.1... IB2, N36, T7, 150.......... 202....... 243....... 1 L 60 L B 40 TP1 Ethylene glycol diethyl 3 UN1153 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L A ....... ether. ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Ethylene glycol dinitrate.. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethylene glycol monoethyl 3 UN1171 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... ether. Ethylene glycol monoethyl 3 UN1172 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... ether acetate. Ethylene glycol monomethyl 3 UN1188 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... ether. Ethylene glycol monomethyl 3 UN1189 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... ether acetate. Ethylene oxide and carbon 2.3 UN3300 ....... 2.3, 2.1. 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40 dioxide mixture with more than 87 percent ethylene oxide. Ethylene oxide and carbon 2.1 UN1041 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 25 kg B 40 dioxide mixtures with more than 9 percent but not more than 87 percent ethylene oxide. Ethylene oxide and carbon 2.2 UN1952 ....... 2.2...... ................ 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... dioxide mixtures with not more than 9 percent ethylene oxide. Ethylene oxide and 2.2 UN3297 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... chlorotetrafluoroethane m#
Passage 164ixture with not more than 8.8 percent ethylene oxide. Ethylene oxide and 2.2 UN3070 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... dichlorodifluoromethane mixture, with not more than 12.5 percent ethylene oxide. Ethylene oxide and 2.2 UN3298 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... pentafluoroethane mixture with not more than 7.9 percent ethylene oxide. Ethylene oxide and 3 UN2983 I 3, 6.1... 5, A11, N4, N34, None......... 201....... 243....... Forbidden 30 L E 40 propylene oxide mixtures, T14, TP2, TP7, with not more than 30 TP13 percent ethylene oxide. Ethylene oxide and 2.2 UN3299 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide. Ethylene oxide or Ethylene 2.3 UN1040 ....... 2.3, 2.1. 4, T50, TP20 None......... 323....... 323....... Forbidden Forbidden D 40 oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C. Ethylene, refrigerated 2.1 UN1038 ....... 2.1...... T75, TP5 None......... 316....... 318, 319.. Forbidden Forbidden D 40 liquid (cryogenic liquid). Ethylenediamine............ 8 UN1604 II 8, 3..... IB2, T7, TP2 154.......... 202....... 243....... 1 L 30 L A 40 Ethyleneimine, stabilized.. 6.1 UN1185 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, B77, N25, N32, T22, TP2, TP13, TP38, TP44 Ethylhexaldehyde, see Octyl ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... aldehydes etc. 2-Ethylhexyl chloroformate. 6.1 UN2748 II 6.1, 8... IB2, T7, TP2, 153.......... 202....... 243....... 1 L 30 L A 12, 13, TP13 21, 25, 40, 100 2-Ethylhexylamine.......... 3 UN2276 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A 40 Ethylphenyldichlorosilane.. 8 UN2435 II 8........ A7, B2, IB2, None......... 202....... 242....... Forbidden 30 L C ....... N34, T7, TP2, TP13 1-Ethylpiperidine.......... 3 UN2386 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... N-Ethyltoluidines.......... 6.1 UN2754 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Ethyltrichlorosilane....... 3 UN1196 II 3, 8..... A7, IB1, N34, 150.......... 202....... 243....... 1 L 5 L B#
Passage 16540 T7, TP2, TP13 Etiologic agent, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Infectious substances, etc. Explosive articles, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Articles, explosive , n.o.s. etc. Explosive, blasting, type A 1.1D UN0081 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 21E, 29E Explosive, blasting, type B 1.1D UN0082 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 29E Explosive, blasting, type B 1.5D UN0331 II 1.5D..... 105, 106 None......... 62........ None...... Forbidden Forbidden 10 29E or Agent blasting, Type B. Explosive, blasting, type C 1.1D UN0083 II 1.1D..... 123 None......... 62........ None...... Forbidden Forbidden 10 22E Explosive, blasting, type D 1.1D UN0084 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Explosive, blasting, type E 1.1D UN0241 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 19E, 29E#
Passage 166Explosive, blasting, type E 1.5D UN0332 II 1.5D..... 105, 106 None......... 62........ None...... Forbidden Forbidden 10 29E or Agent blasting, Type E. Explosive, forbidden. See Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sec. 173.54. Explosive substances, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Substances, explosive, n.o.s. etc. Explosives, slurry, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Explosive, blasting, type E. Explosives, water gels, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Explosive, blasting, type E. Extracts, aromatic, liquid. 3 UN1169 II 3........ 149, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Extracts, flavoring, liquid 3 UN1197 II 3........ 149, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Fabric with animal or ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... vegetable oil, see Fibers or fabrics, etc. Ferric arsenate............ 6.1 UN1606 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Ferric arsenite............ 6.1 UN1607 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Ferric chloride, anhydrous. 8 UN1773 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Ferric chloride, solution.. 8 UN2582 III 8........ B15, IB3, T4, 154.......... 203....... 241....... 5 L 60 L A ....... TP1 Ferric nitrate............. 5.1 UN1466 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Ferrocerium................ 4.1 UN1323 II 4.#
Passage 1671...... 59, A19, IB8, 151.......... 212....... 240....... 15 kg 50 kg A ....... IP2, IP4, T3, TP33 Ferrosilicon with 30 4.3 UN1408 III 4.3, 6.1. A1, A19, B6, 151.......... 213....... 240....... 25 kg 100 kg A 13, 40, percent or more but less IB8, IP4, IP7, 52, 53, than 90 percent silicon. T1, TP33 85, 103 Ferrous arsenate........... 6.1 UN1608 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 D Ferrous chloride, solid.... 8 NA1759 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... T3, TP33 D Ferrous chloride, solution. 8 NA1760 II 8........ B3, IB2, T11, 154.......... 202....... 242....... 1 L 30 L B 40 TP2, TP27 Ferrous metal borings or 4.2 UN2793 III 4.2...... A1, A19, IB8, None......... 213....... 241....... 25 kg 100 kg A ....... Ferrous metal shavings or IP3, IP7 Ferrous metal turnings or Ferrous metal cuttings in a form liable to self- heating. Fertilizer ammoniating 2.2 UN1043 ....... 2.2...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 solution with free ammonia. A I W Fibers, animal or Fibers, 4.2 UN1372 III ......... ................ 151.......... 213....... 240....... Forbidden Forbidden A ....... vegetable burnt, wet or damp.. I W Fibers, vegetable, dry..... 4.1 UN3360 ....... 4.1...... 137 151.......... 213....... 240....... No Limit No Limit A ....... A W Fibers or Fabrics, animal 4.2 UN1373 III 4.2...... 137, IB8, IP3, None......... 213....... 241....... Forbidden Forbidden A ....... or vegetable or Synthetic, T1, TP33 n.o.s. with animal or vegetable oil. Fibers or Fabrics 4.1 UN1353 III 4.1...... A1, IB8, IP3 None......... 213....... 240....... 25 kg 100 kg D ....... impregnated with weakly nitrated nitrocellulose, n.o.s.. Films, nitrocellulose base, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... from which gelatine has been removed; film scrap, see Celluloid scrap. Films, nitrocellulose base, 4.1 UN1324 III 4.1...... ................ None......... 183....... None...... 25 kg 100 kg D 28 gelatine coated (except scrap). Fire extinguisher charges, 8 UN1774 II 8........ N41 154.......... 202....... None...... 1 L 30 L A ....... corrosive liquid. Fire extinguisher charges, ........... ................. ....... ......... ................ ...#
Passage 168.......... .......... .......... ........... ........... .......... ....... expelling, explosive, see Cartridges, power device. Fire extinguishers 2.2 UN1044 ....... 2.2...... 18, 110 309.......... 309....... None...... 75 kg 150 kg A ....... containing compressed or liquefied gas. Firelighters, solid with 4.1 UN2623 III 4.1...... A1, A19 None......... 213....... None...... 25 kg 100 kg A 52 flammable liquid. Fireworks.................. 1.1G UN0333 II 1.1G..... 108 None......... 62........ None...... Forbidden Forbidden 07 ....... Fireworks.................. 1.2G UN0334 II 1.2G..... 108 None......... 62........ None...... Forbidden Forbidden 07 ....... Fireworks.................. 1.3G UN0335 II 1.3G..... 108 None......... 62........ None...... Forbidden Forbidden 07 ....... Fireworks.................. 1.4G UN0336 II 1.4G..... 108 None......... 62........ None...... Forbidden 75 kg 06 ....... Fireworks.................. 1.4S UN0337 II 1.4S..... 108 None......... 62........ None...... 25 kg 100 kg 05 ....... First aid kits............. 9 UN3316 ....... 9........ 15 161.......... 161....... None...... 10 kg 10 kg A ....... W Fish meal, stabilized or 9 UN2216 III None..... 155, IB8, IP3, 155.......... 218....... 218....... No limit No limit B 88, Fish scrap, stabilized. T1, TP33 122, 128 Fish meal, unstablized or 4.2 UN1374 II 4.2...... 155, A1, A19, None......... 212....... 241....... 15 kg 50 kg B 18, 128 Fish scrap, unstabilized. IB8, IP2, IP4, T3, TP33 Fissile radioactive ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... materials, see Radioactive material, fissile, n.o.s.. Flammable compressed gas, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Compressed or Liquefied gas, flammable, etc. Flammable compressed gas ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (small receptacles not fitted with a dispersion device, not refillable), see Receptacles, etc. Flammable gas in lighters, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Lighters or lighter refills, cigarettes, contai#
Passage 169ning flammable gas. G Flammable liquid, toxic, 3 UN3286 I 3, 6.1, 8 T14, TP2, TP13, None......... 201....... 243....... Forbidden 2.5 L E 21, 40, corrosive, n.o.s.. TP27 100 ........................... ........... ................. II 3, 6.1, 8 IB2, T11, TP2, 150.......... 202....... 243....... 1 L 5 L B 21, 40, TP13, TP27 100 G Flammable liquids, 3 UN2924 I 3, 8..... T14, TP2 None......... 201....... 243....... 0.5 L 2.5 L E 40 corrosive, n.o.s.. ........................... ........... ................. II 3, 8..... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 5 L B 40 TP27 ........................... ........... ................. III 3, 8..... B1, IB3, T7, 150.......... 203....... 242....... 5 L 60 L A 40 TP1, TP28#
Passage 170G Flammable liquids, n.o.s... 3 UN1993 I 3........ T11, TP1, TP27 150.......... 201....... 243....... 1 L 30 L E ....... ........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 G Flammable liquids, toxic, 3 UN1992 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L E 40 n.o.s.. TP27 ........................... ........... ................. II 3, 6.1... IB2, T7, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13 ........................... ........... ................. III 3, 6.1... B1, IB3, T7, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP28 G Flammable solid, corrosive, 4.1 UN3180 II 4.1, 8... A1, IB6, IP2, 151.......... 212....... 242....... 15 kg 50 kg D 40 inorganic, n.o.s.. T3, TP33 ........................... ........... ................. III 4.1, 8... A1, IB6, T1, 151.......... 213....... 242....... 25 kg 100 kg D 40 TP33 G Flammable solid, inorganic, 4.1 UN3178 II 4.1...... A1, IB8, IP2, 151.......... 212....... 240....... 15 kg 50 kg B ....... n.o.s.. IP4, T3, TP33 ........................... ........... ................. III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg B ....... T1, TP33 G Flammable solid, organic, 4.1 UN3176 II 4.1...... IB1, T3, TP3, 151.......... 212....... 240....... Forbidden Forbidden C ....... molten, n.o.s.. TP26 ........................... ........... ................. III 4.1...... IB1, T1, TP3, 151.......... 213....... 240....... Forbidden Forbidden C ....... TP26 G Flammable solid, oxidizing, 4.1 UN3097 II 4.1, 5.1. 131 None......... 214....... 214....... Forbidden Forbidden E 40 n.o.s.. ........................... ........... ................. III 4.1, 5.1. 131, T1, TP33 None......... 214....... 214....... Forbidden Forbidden D 40 G Flammable solid, toxic, 4.1 UN3179 II 4.1, 6.1. A1, IB6, IP2, 151.......... 212....... 242....... 15 kg 50 kg B 40 inorganic, n.o.s.. T3, TP33 ........................... ........... ................. III 4.1, 6.1. A1, IB6, T1, 151.......... 213....... 242....... 25 kg 100 kg B 40 TP33 G Flammable solids, 4.1 UN2925 II 4.1, 8... A1, IB6, IP2, None......... 212...#
Passage 171.... 242....... 15 kg 50 kg D 40 corrosive, organic, n.o.s.. T3, TP33 ........................... ........... ................. III 4.1, 8... A1, IB6, T1, 151.......... 213....... 242....... 25 kg 100 kg D 40 TP33 G Flammable solids, organic, 4.1 UN1325 II 4.1...... A1, IB8, IP2, 151.......... 212....... 240....... 15 kg 50 kg B ....... n.o.s.. IP4, T3, TP33 ........................... ........... ................. III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg B ....... T1, TP33 G Flammable solids, toxic, 4.1 UN2926 II 4.1, 6.1. A1, IB6, IP2, 151.......... 212....... 242....... 15 kg 50 kg B 40 organic, n.o.s.. T3, TP33 ........................... ........... ................. III 4.1, 6.1. A1, IB6, T1, 151.......... 213....... 242....... 25 kg 100 kg B 40 TP33 Flares, aerial............. 1.3G UN0093 II 1.3G..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Flares, aerial............. 1.4G UN0403 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Flares, aerial............. 1.4S UN0404 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Flares, aerial............. 1.1G UN0420 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Flares, aerial............. 1.2G UN0421 II 1.2G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Flares, airplane, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Flares, aerial. Flares, signal, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cartridges, signal. Flares, surface............ 1.3G UN0092 II 1.3G..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Flares, surface............ 1.1G UN0418 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Flares, surface............ 1.2G UN0419 II 1.2G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Flares, water-activated, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... ....#
Passage 172...... ....... see Contrivances, water- activated, etc. Flash powder............... 1.1G UN0094 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 15 ....... Flash powder............... 1.3G UN0305 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 15 ....... Flue dusts, poisonous, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Arsenical dust. Fluoric acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrofluoric acid, etc. Fluorine, compressed....... 2.3 UN1045 ....... 2.3, 5.1, 1 None......... 302....... None...... Forbidden Forbidden D 40, 89, 8. 90 Fluoroacetic acid.......... 6.1 UN2642 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 1 kg 15 kg E ....... TP33 Fluoroanilines............. 6.1 UN2941 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Fluorobenzene.............. 3 UN2387 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B .......#
Passage 173Fluoroboric acid........... 8 UN1775 II 8........ A6, A7, B2, B15, 154.......... 202....... 242....... 1 L 30 L A ....... IB2, N3, N34, T7, TP2 Fluorophosphoric acid 8 UN1776 II 8........ A6, A7, B2, IB2, None......... 202....... 242....... 1 L 30 L A ....... anhydrous. N3, N34, T8, TP2, TP12 Fluorosilicates, n.o.s..... 6.1 UN2856 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Fluorosilicic acid......... 8 UN1778 II 8........ A6, A7, B2, B15, None......... 202....... 242....... 1 L 30 L A ....... IB2, N3, N34, T8, TP2, TP12 Fluorosulfonic acid........ 8 UN1777 I 8........ A3, A6, A7, A10, None......... 201....... 243....... 0.5 L 2.5 L D 40 B6, B10, N3, N36, T10, TP2, TP12 Fluorotoluenes............. 3 UN2388 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 Forbidden materials. See Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sec. 173.21. Formaldehyde, solutions, 3 UN1198 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A 40 flammable. Formaldehyde, solutions, 8 UN2209 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... with not less than 25 percent formaldehyde. Formalin, see Formaldehyde, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solutions. Formic acid................ 8 UN1779 II 8........ B2, B28, IB2, 154.......... 202....... 242....... 1 L 30 L A 40 T7, TP2 Fracturing devices, 1.1D UN0099 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... explosive, without detonators for oil wells. Fuel, aviation, turbine 3 UN1863 I 3........ 144, T11, TP1, 150.......... 201....... 243....... 1 L 30 L E ....... engine. TP8, TP28 ........................... ........... ................. II 3........ 144, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T2, TP1 D Fuel oil (No. 1, 2, 4, 5, 3 NA1993 III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... or 6). T4, TP1, TP29 Fuel system components ........... ........#
Passage 174......... ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (including fuel control units (FCU), carburetors, fuel lines, fuel pumps) see Dangerous Goods in Apparatus or Dangerous Goods in Machinery. Fulminate of mercury (dry). Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fulminate of mercury, wet, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Mercury fulminate, etc. Fulminating gold........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fulminating mercury........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fulminating platinum....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fulminating silver......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fulminic acid.............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fumaryl chloride........... 8 UN1780 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L C 8, 40 Fumigated lading, see Sec. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sec. 172.302(g), 173.9 and 176.76(h). Fumigated transport vehicle ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... or freight container see 173.9. Furaldehydes............... 6.1 UN1199 II 6.1, 3... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Furan...................... 3 UN2389 I 3........ T12, TP2, TP13 None......... 201....... 243....... 1 L 30 L E 40 Furfuryl alcohol........... 6.1 UN2874 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 52, 74 Furfurylamine..............#
Passage 1753 UN2526 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A 40 Fuse, detonating, metal ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... clad, see Cord, detonating, metal clad. Fuse, detonating, mild ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... effect, metal clad, see Cord, detonating, mild effect, metal clad. Fuse, igniter tubular metal 1.4G UN0103 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... clad. Fuse, non-detonating 1.3G UN0101 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... instantaneous or quickmatch. Fuse, safety............... 1.4S UN0105 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... D Fusee (railway or highway). 4.1 NA1325 II 4.1...... ................ None......... 184....... None...... 15 kg 50 kg B ....... Fusel oil.................. 3 UN1201 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Fuses, tracer, see Tracers ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... for ammunition. Fuzes, combination, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... percussion and time, see Fuzes, detonating (UN0257, UN0367); Fuzes, igniting (UN0317, UN0368). Fuzes, detonating.......... 1.1B UN0106 II 1.1B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... Fuzes, detonating.......... 1.2B UN0107 II 1.2B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... Fuzes, detonating.......... 1.4B UN0257 II 1.4B..... 116 None......... 62........ None...... Forbidden 75 kg 06 ....... Fuzes, detonating.......... 1.4S UN0367 II 1.4S..... 116 None......... 62........ None...... 25 kg 100 kg 05 ....... Fuzes, detonating, with 1.1D UN0408 II 1.1D..... ................ None......... 62........#
Passage 176None...... Forbidden Forbidden 07 ....... protective features. Fuzes, detonating, with 1.2D UN0409 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... protective features. Fuzes, detonating, with 1.4D UN0410 II 1.4D..... 116 None......... 62........ None...... Forbidden 75 kg 06 ....... protective features. Fuzes, igniting............ 1.3G UN0316 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Fuzes, igniting............ 1.4G UN0317 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Fuzes, igniting............ 1.4S UN0368 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Galactsan trinitrate....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Gallium.................... 8 UN2803 III 8........ T1, TP33 None......... 162....... 240....... 20 kg 20 kg B 48 Gas cartridges, (flammable) 2.1 UN2037 ....... 2.1...... ................ 306.......... 304....... None...... 1 kg 15 kg B 40 without a release device, non-refillable. Gas generator assemblies 2.2 ................. ....... 2.2...... ................ None......... 335....... None...... 75 kg 150 kg A ....... (aircraft), containing a non-flammable non-toxic gas and a propellant cartridge. D Gas identification set..... 2.3 NA9035 ....... 2.3...... 6 None......... 194....... None...... Forbidden Forbidden D ....... Gas oil.................... 3 UN1202 III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T2, TP1#
Passage 177G Gas, refrigerated liquid, 2.1 UN3312 ....... 2.1...... T75, TP5 None......... 316....... 318....... Forbidden Forbidden D 40 flammable, n.o.s. (cryogenic liquid). G Gas, refrigerated liquid, 2.2 UN3158 ....... 2.2...... T75, TP5 320.......... 316....... 318....... 50 kg 500 kg D ....... n.o.s. (cryogenic liquid). G Gas, refrigerated liquid, 2.2 UN3311 ....... 2.2, 5.1. T75, TP5, TP22 320.......... 316....... 318....... Forbidden Forbidden D ....... oxidizing, n.o.s. (cryogenic liquid). Gas sample, non- 2.1 UN3167 ....... 2.1...... ................ 306.......... 302, 304.. None...... 1 L 5 L D ....... pressurized, flammable, n.o.s., not refrigerated liquid. Gas sample, non- 2.3 UN3168 ....... 2.3, 2.1. 6 306.......... 302....... None...... Forbidden 1 L D ....... pressurized, toxic, flammable, n.o.s., not refrigerated liquid. Gas sample, non- 2.3 UN3169 ....... 2.3...... 6 306.......... 302, 304.. None...... Forbidden 1 L D ....... pressurized, toxic, n.o.s., not refrigerated liquid. D Gasohol gasoline mixed with 3 NA1203 II 3........ 144 150.......... 202....... 242....... 5 L 60 L E ....... ethyl alcohol, with not more than 20 percent alcohol. Gasoline................... 3 UN1203 II 3........ 139, B33, B101, 150.......... 202....... 242....... 5 L 60 L E ....... T8 Gasoline, casinghead, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Gasoline. Gelatine, blasting, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Explosive, blasting, type A. Gelatine dynamites, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Explosive, blasting, type A. Germane.................... 2.3 UN2192 ....... 2.3, 2.1. 2 None......... 302....... 245....... Forbidden Forbidden D 40 Glycerol-1,3-dinitrate..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Glycerol gluconate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitrate. Glycerol lactate trinitrate Forbidden ................. ....... .........#
Passage 178................ ............. .......... .......... ........... ........... .......... ....... Glycerol alpha- 6.1 UN2689 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... monochlorohydrin. Glyceryl trinitrate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitroglycerin, etc. Glycidaldehyde............. 3 UN2622 II 3, 6.1... IB2, IP8, T7, 150.......... 202....... 243....... 1 L 60 L A 40 TP1 Grenades, hand or rifle, 1.1D UN0284 II 1.1D..... ................ ............. 62........ None...... Forbidden Forbidden 07 ....... with bursting charge. Grenades, hand or rifle, 1.2D UN0285 II 1.2D..... ................ ............. 62........ None...... Forbidden Forbidden 07 ....... with bursting charge. Grenades, hand or rifle, 1.1F UN0292 II 1.1F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... with bursting charge. Grenades, hand or rifle, 1.2F UN0293 II 1.2F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... with bursting charge. Grenades, illuminating, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammunition, illuminating, etc. Grenades, practice, hand or 1.4S UN0110 II 1.4S..... ................ ............. 62........ None...... 25 kg 100 kg 05 ....... rifle. Grenades, practice, hand or 1.3G UN0318 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden 07 ....... rifle. Grenades, practice, hand or 1.2G UN0372 II 1.2G..... ................ ............. 62........ None...... Forbidden Forbidden 07 ....... rifle. Grenades practice Hand or 1.4G UN0452 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 06 ....... rifle. Grenades, smoke, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammunition, smoke, etc. Guanidine nitrate.......... 5.1 UN1467 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A 73 T1, TP33 Guanyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitrosamin#
Passage 179oguanylidene hydrazine (dry). Guanyl 1.1A UN0113 II 1.1A..... 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... nitrosaminoguanylidene hydrazine, wetted with not less than 30 percent water, by mass. Guanyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitrosaminoguanyltetrazene (dry). Guanyl 1.1A UN0114 II 1.1A..... 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... nitrosaminoguanyltetrazene , wetted or Tetrazene, wetted with not less than 30 percent water or mixture of alcohol and water, by mass. Gunpowder, compressed or ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Gunpowder in pellets, see Black powder (UN 0028). Gunpowder, granular or as a ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... meal, see Black powder (UN 0027). Hafnium powder, dry........ 4.2 UN2545 I 4.2...... ................ None......... 211....... 242....... Forbidden Forbidden D ....... ........................... ........... ................. II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg D ....... IP2, N34, T3, TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg D ....... TP33 Hafnium powder, wetted with 4.1 UN1326 II 4.1...... A6, A19, A20, None......... 212....... 241....... 15 kg 50 kg E 74 not less than 25 percent IB6, IP2, N34, water (a visible excess of T3, TP33 water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Hand signal device, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Signal devices, hand. Hazardous substances, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquid or solid, n.o.s., see Environmentally hazardous substances, etc. D G Hazardous waste, liquid, 9 NA3082 III 9........ IB3, T2, TP1 155.......... 203....... 241....... No li#
Passage 180mit No limit A ....... n.o.s.. D G Hazardous waste, solid, 9 NA3077 III 9........ B54, IB8, IP2, 155.......... 213....... 240....... No limit No limit A ....... n.o.s.. T1, TP33 Heating oil, light......... 3 UN1202 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Helium, compressed......... 2.2 UN1046 ....... 2.2...... ................ 306.......... 302....... 302, 314.. 75 kg 150 kg A 85 Helium-oxygen mixture, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Rare gases and oxygen mixtures. Helium, refrigerated liquid 2.2 UN1963 ....... 2.2...... T75, TP5 320.......... 316....... 318....... 50 kg 500 kg B ....... (cryogenic liquid). Heptafluoropropane or 2.2 UN3296 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 227. n-Heptaldehyde............. 3 UN3056 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A .......#
Passage 181Heptanes................... 3 UN1206 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... n-Heptene.................. 3 UN2278 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Hexachloroacetone.......... 6.1 UN2661 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L B 12, 40 Hexachlorobenzene.......... 6.1 UN2729 III 6.1...... B3, IB8, IP3, 153.......... 203....... 241....... 60 L 220 L A ....... T1, TP33 Hexachlorobutadiene........ 6.1 UN2279 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Hexachlorocyclopentadiene.. 6.1 UN2646 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, T20, TP2, TP13, TP38, TP45 Hexachlorophene............ 6.1 UN2875 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Hexadecyltrichlorosilane... 8 UN1781 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2 Hexadienes................. 3 UN2458 II 3........ IB2, T4, TP1 None......... 202....... 242....... 5 L 60 L B ....... Hexaethyl tetraphosphate 2.3 UN1612 ....... 2.3...... 3 None......... 334....... None...... Forbidden Forbidden D 40 and compressed gas mixtures. Hexaethyl tetraphosphate, 6.1 UN1611 II 6.1...... IB2, N76, T7, 153.......... 202....... 243....... 5 L 60 L E 40 liquid. TP2 Hexaethyl tetraphosphate, 6.1 UN1611 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg E 40 solid. N76 Hexafluoroacetone.......... 2.3 UN2420 ....... 2.3, 8... 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Hexafluoroacetone hydrate, 6.1 UN2552 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L B 40 liquid. Hexafluoroacetone hydrate, 6.1 UN3436 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 40 solid. T3, TP33 Hexafluoroethane, or 2.2 UN2193 ....... 2.2...... ................ 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 116. Hexafluorophosphoric acid.. 8 UN1782 II 8........ A6, A7, B2, IB2, None......... 202....... 242....... 1 L 30 L A ....... N3, N34, T8, TP2, TP12 Hexafluoropropylene 2.2 UN1858 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... compressed or Refrigerant gas R 1216. H#
Passage 182exaldehyde................ 3 UN1207 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Hexamethylene diisocyanate. 6.1 UN2281 II 6.1...... IB2, T7, TP2, 153.......... 202....... 243....... 5 L 60 L C 13, 40 TP13 Hexamethylene triperoxide Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diamine (dry). Hexamethylenediamine, solid 8 UN2280 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 12 TP33 Hexamethylenediamine 8 UN1783 II 8........ IB2, T7, TP2 None......... 202....... 242....... 1 L 30 L A ....... solution. ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Hexamethyleneimine......... 3 UN2493 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 Hexamethylenetetramine..... 4.1 UN1328 III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Hexamethylol benzene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hexanitrate. Hexanes.................... 3 UN1208 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... 2,2',4,4',6,6'- Hexanitro- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 3,3'-dihydroxyazobenzene (dry). Hexanitroazoxy benzene..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... N,N'-(hexanitrodiphenyl) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ethylene dinitramine (dry). Hexanitrodiphenyl urea..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 2,2',3',4,4',6- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexanitrodiphenylamine. Hexanitrodiphenylamine or 1.1D UN0079 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden#
Passage 18310 ....... Dipicrylamine or Hexyl. 2,3',4,4',6,6'- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexanitrodiphenylether. Hexanitroethane............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexanitrooxanilide......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexanitrostilbene.......... 1.1D UN0392 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Hexanoic acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Corrosive liquids, n.o.s.. Hexanols................... 3 UN2282 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 74 1-Hexene................... 3 UN2370 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Hexogen and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... cyclotetramethylenetetrani tramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Hexogen and HMX mixtures, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Hexogen and octogen ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Hexogen, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cyclotrimethylenetrinitram ine, etc. Hexolite, or Hexotol dry or 1.1D UN0118 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... wetted with less than 15 percent water, by mass. Hexotonal.................. 1.1D UN0393 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbid#
Passage 184den 10 ....... Hexyl, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hexanitrodiphenylamine. Hexyltrichlorosilane....... 8 UN1784 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 High explosives, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... individual explosives' entries. HMX, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cyclotetramethylenete tranitramine, etc. Hydrazine, anhydrous....... 8 UN2029 I 8, 3, 6.1 A3, A6, A7, A10, None......... 201....... 243....... Forbidden 2.5 L D 40, 125 B7, B16, B53#
Passage 185Hydrazine, aqueous solution 6.1 UN3293 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... with not more than 37 percent hydrazine, by mass. Hydrazine azide............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrazine chlorate......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrazine dicarbonic acid Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diazide. Hydrazine aqueous solution, 8 UN2030 I 8, 6.1... 151, B16, B53, None......... 201....... 243....... Forbidden 2.5 L D 40 with more than 37% T10, TP2, TP13 hydrazine, by mass. ........................... ........... ................. II 8, 6.1... B16, B53, IB2, None......... 202....... 243....... Forbidden 30 L D 40 T7, TP2, TP13 ........................... ........... ................. III 8, 6.1... B16, B53, IB3, 154.......... 203....... 241....... 5 L 60 L D 40 T4, TP1 Hydrazine perchlorate...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrazine selenate......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydriodic acid, anhydrous, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Hydrogen iodide, anhydrous. Hydriodic acid............. 8 UN1787 II 8........ A3, A6, B2, IB2, 154.......... 202....... 242....... 1 L 30 L C ....... N41, T7, TP2 ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L C 8 Hydrobromic acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... anhydrous, see Hydrogen bromide, anhydrous. Hydrobromic acid, with more 8 UN1788 II 8........ B2, B15, IB2, 154.......... 202....... 242....... Forbidden Forbidden C ....... than 49 percent N41, T7, TP2 hydrobromic acid. ........................... ...........#
Passage 186................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... Forbidden Forbidden C 8 Hydrobromic acid, with not 8 UN1788 II 8........ A3, A6, B2, B15, 154.......... 202....... 242....... 1 L 30 L C ....... more than 49 percent IB2, N41, T7, hydrobromic acid. TP2 ........................... ........... ................. III 8........ A3, IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L C 8 Hydrocarbon gas mixture, 2.1 UN1964 ....... 2.1...... ................ 306.......... 302....... 314, 315.. Forbidden 150 kg E 40 compressed, n.o.s.. Hydrocarbon gas mixture, 2.1 UN1965 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 liquefied, n.o.s.. Hydrocarbons, liquid, 3 UN3295 I 3........ 144, T11, TP1, 150.......... 201....... 243....... 1 L 30 L E ....... n.o.s.. TP8, TP28 ........................... ........... ................. II 3........ 144, IB2, T7, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8, TP28 ........................... ........... ................. III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 Hydrochloric acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... anhydrous, see Hydrogen chloride, anhydrous. Hydrochloric acid.......... 8 UN1789 II 8........ A3, A6, B3, B15, 154.......... 202....... 242....... 1 L 30 L C ....... IB2, N41, T8, TP2, TP12 ........................... ........... ................. III 8........ A3, IB3, T4, 154.......... 203....... 241....... 5 L 60 L C 8 TP1, TP12 Hydrocyanic acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... anhydrous, see Hydrogen cyanide etc. Hydrocyanic acid, aqueous 6.1 UN1613 I 6.1...... 2, B61, B65, None......... 195....... 244....... Forbidden Forbidden D 40 solutions or Hydrogen B77, B82, T20, cyanide, aqueous solutions TP2, TP13 with not more than 20 percent hydrogen cyanide. D Hydrocyanic acid, aqueous 6.1 NA1613 II 6.1...... IB1, T14, TP2, None......... 195....... 243....... Forbidden 5 L D 40 solutions with less than 5 TP13, TP27 percent hydrogen cyanide. Hydrocyanic acid, ........... ................. ....... ......... ................ ............. .......... .......... ....#
Passage 187....... ........... .......... ....... liquefied, see Hydrogen cyanide, etc. Hydrocyanic acid (prussic), Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... unstabilized. Hydrofluoric acid and 8 UN1786 I 8, 6.1... A6, A7, B15, None......... 201....... 243....... Forbidden 2.5 L D 40 Sulfuric acid mixtures. B23, N5, N34, T10, TP2, TP12, TP13 Hydrofluoric acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... anhydrous, see Hydrogen fluoride, anhydrous. Hydrofluoric acid, with 8 UN1790 I 8, 6.1... A6, A7, B4, B15, None......... 201....... 243....... 0.5 L 2.5 L D 12, 40 more than 60 percent B23, N5, N34, strength. T10, TP2, TP12, TP13 Hydrofluoric acid, with not 8 UN1790 II 8, 6.1... A6, A7, B15, 154.......... 202....... 243....... 1 L 30 L D 12, 40 more than 60 percent IB2, N5, N34, strength. T8, TP2, TP12 Hydrofluoroboric acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fluoroboric acid. Hydrofluorosilicic acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Fluorosilicic acid. Hydrogen and Methane 2.1 UN2034 ....... 2.1...... ................ 306.......... 302....... 302, 314, Forbidden 150 kg E 40, 57 mixtures, compressed. 315.#
Passage 188Hydrogen bromide, anhydrous 2.3 UN1048 ....... 2.3, 8... 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Hydrogen chloride, 2.3 UN1050 ....... 2.3, 8... 3 None......... 304....... None...... Forbidden Forbidden D 40 anhydrous. Hydrogen chloride, 2.3 UN2186 ....... 2.3, 8... 3, B6 None......... None...... 314, 315.. Forbidden Forbidden B 40 refrigerated liquid. Hydrogen, compressed....... 2.1 UN1049 ....... 2.1...... ................ 306.......... 302....... 302, 314.. Forbidden 150 kg E 40, 57 Hydrogen cyanide, solution 6.1 UN3294 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 in alcohol with not more B74, T20, TP2, than 45 percent hydrogen TP13, TP38, TP45 cyanide. Hydrogen cyanide, 6.1 UN1051 I 6.1, 3... 1, B35, B61, None......... 195....... 244....... Forbidden Forbidden D 40 stabilized with less than B65, B77, B82 3 percent water. Hydrogen cyanide, 6.1 UN1614 I 6.1...... 5 None......... 195....... None...... Forbidden Forbidden D 25, 40 stabilized, with less than 3 percent water and absorbed in a porous inert material. Hydrogen fluoride, 8 UN1052 I 8, 6.1... 3, B7, B46, B71, None......... 163....... 243....... Forbidden Forbidden D 40 anhydrous. B77, T10, TP2 Hydrogen in a metal hydride 2.1 UN3468 ....... 2.1...... 167 None......... 214....... None...... Forbidden Forbidden D ....... storage system. Hydrogen iodide, anhydrous. 2.3 UN2197 ....... 2.3...... 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Hydrogen iodide solution, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Hydriodic acid, solution. Hydrogen peroxide and 5.1 UN3149 II 5.1, 8... 145, A2, A3, A6, None......... 202....... 243....... 1 L 5 L D 25, 66, peroxyacetic acid B53, IB2, IP5, 75 mixtures, stabilized with T7, TP2, TP6, acids, water and not more TP24 than 5 percent peroxyacetic acid. Hydrogen peroxide, aqueous 5.1 UN2014 II 5.1, 8... 12, B53, B80, None......... 202....... 243....... Forbidden Forbidden D 25, 66, solutions with more than B81, B85, IB2, 75 40 percent but not more T7, TP2, TP6, than 60 percent hydrogen TP24, TP37 peroxide (stabilized as necessary). Hydrogen peroxide, aqueous 5.1 UN2014 II 5.1, 8... A2, A3, A6, B53, None......... 202....... 243....... 1 L 5 L D 25, 66, solutions with not less#
Passage 189IB2, IP5, T7, 75 than 20 percent but not TP2, TP6, TP24, more than 40 percent TP37 hydrogen peroxide (stabilized as necessary). Hydrogen peroxide, aqueous 5.1 UN2984 III 5.1...... A1, IB2, IP5, 152.......... 203....... 241....... 2.5 L 30 L B 25, 66, solutions with not less T4, TP1, TP6, 75 than 8 percent but less TP24, TP37 than 20 percent hydrogen peroxide (stabilized as necessary). Hydrogen peroxide, 5.1 UN2015 I 5.1, 8... 12, B53, B80, None......... 201....... 243....... Forbidden Forbidden D 25, 66, stabilized or Hydrogen B81, B85, T10, 75 peroxide aqueous TP2, TP6, TP24, solutions, stabilized with TP37 more than 60 percent hydrogen peroxide. Hydrogen, refrigerated 2.1 UN1966 ....... 2.1...... T75, TP5 None......... 316....... 318, 319.. Forbidden Forbidden D 40 liquid (cryogenic liquid). Hydrogen selenide, 2.3 UN2202 ....... 2.3, 2.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 anhydrous. Hydrogen sulfate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sulfuric acid. Hydrogen sulfide........... 2.3 UN1053 ....... 2.3, 2.1. 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Hydrogendifluorides, n.o.s. 8 UN1740 II 8........ IB8, IP2, IP4, None......... 212....... 240....... 15 kg 50 kg A 25, 40, N3, N34, T3, 52 TP33 ........................... ........... ................. III 8........ IB8, IP3, N3, 154.......... 213....... 240....... 25 kg 100 kg A 25, 40, N34, T1, TP33 52 Hydroquinone, solid........ 6.1 UN2662 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Hydroquinone solution...... 6.1 UN3435 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Hydrosilicofluoric acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Fluorosilicic acid. Hydroxyl amine iodide...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydroxylamine sulfate...... 8 UN2865 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Hypochlorite solutions..... 8 UN1791 II 8........ A7, B2, B15, 154.......... 202....... 242....... 1 L 30 L B#
Passage 19026 IB2, IP5, N34, T7, TP2, TP24 ........................... ........... ................. III 8........ IB3, N34, T4, 154.......... 203....... 241....... 5 L 60 L B 26 TP2, TP24 Hypochlorites, inorganic, 5.1 UN3212 II 5.1...... A9, IB8, IP2, 152.......... 212....... 240....... 5 kg 25 kg D 4, 48, n.o.s.. IP4, T3, TP33 52, 56, 58, 69, 106, 116 118 Hyponitrous acid........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Igniter fuse, metal clad, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Fuse, igniter, tubular, metal clad. Igniters................... 1.1G UN0121 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Igniters................... 1.2G UN0314 II 1.2G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Igniters................... 1.3G UN0315 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 .......#
Passage 191Igniters................... 1.4G UN0325 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Igniters................... 1.4S UN0454 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... 3,3'-Iminodipropylamine.... 8 UN2269 III 8........ IB3, T4, TP2 154.......... 203....... 241....... 5 L 60 L A ....... G Infectious substances, 6.2 UN2900 ....... 6.2...... A81, A82 134.......... 196....... None...... 50 mL or 50 4 L or 4 kg B 40 affecting animals only. g G Infectious substances, 6.2 UN2814 ....... 6.2...... A81, A82 134.......... 196....... None...... 50 mL or 50 4 L or 4 kg B 40 affecting humans. g Diagnostic specimen........ 6.2 ................. ....... ......... A82 134.......... 199....... None...... 4 L or 4 kg 4 L or 4 kg A 40 Inflammable, see Flammable. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Initiating explosives (dry) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Inositol hexanitrate (dry). Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... G Insecticide gases, n.o.s... 2.2 UN1968 ....... 2.2...... ................ 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... G Insecticide gases, 2.1 UN3354 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg D 40 flammable, n.o.s.. G Insecticide gases, toxic, 2.3 UN3355 ....... 2.3, 2.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 flammable, n.o.s. Inhalation hazard Zone A. G Insecticide gases, toxic, 2.3 UN3355 ....... 2.3, 2.1. 2, B9, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. Inhalation hazard Zone B. G Insecticide gases, toxic, 2.3 UN3355 ....... 2.3, 2.1. 3, B14 None......... 302, 305.. 314, 315.. Forbidden Forbidden D ....... flammable, n.o.s. Inhalation hazard Zone C. G Insecticide gases, toxic, 2.3 UN3355 ....... 2.3, 2.1. 4 None......... 302, 305.. 314, 315.. Forbidden Forbidden D ....... flammable, n.o.s. Inhalation hazard Zone D. G Insecticide gases, toxic, 2.3 UN1967 ....... 2.3...... 3 None......... 193, 334.. 245....... Forbidden Forbidden D 40 n#
Passage 192.o.s.. Inulin trinitrate (dry).... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Iodine azide (dry)......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Iodine monochloride........ 8 UN1792 II 8........ B6, IB8, IP2, None......... 212....... 240....... Forbidden 50 kg D 40, 66, IP4, N41, T7, 74, 89, TP2 90 Iodine pentafluoride....... 5.1 UN2495 I 5.1, 6.1, ................ None......... 205....... 243....... Forbidden Forbidden D 25, 40, 8. 52, 66, 90 2-Iodobutane............... 3 UN2390 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Iodomethylpropanes......... 3 UN2391 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Iodopropanes............... 3 UN2392 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Iodoxy compounds (dry)..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Iridium nitratopentamine Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... iridium nitrate. Iron chloride, see Ferric ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chloride. Iron oxide, spent, or Iron 4.2 UN1376 III 4.2...... B18, IB8, IP3, None......... 213....... 240....... Forbidden Forbidden E ....... sponge, spent obtained T1, TP33 from coal gas purification. Iron pentacarbonyl......... 6.1 UN1994 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, B77, T22, TP2, TP13, TP38, TP44 Iron sesquichloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ferric chloride. Irritating material, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tear gas substances, etc. Isobutane see also 2.1 UN1969 ....... 2.1...... 19, T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 P#
Passage 193etroleum gases, liquefied. Isobutanol or Isobutyl 3 UN1212 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... alcohol. Isobutyl acetate........... 3 UN1213 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isobutyl acrylate, 3 UN2527 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... stabilized. Isobutyl alcohol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Isobutanol. Isobutyl aldehyde, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Isobutyraldehyde. D Isobutyl chloroformate..... 6.1 NA2742 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... 1 L 30 L A 12, 13, B74, T20, TP4, 22, 25, TP12, TP13, 40, 48, TP38, TP45 100 Isobutyl formate........... 3 UN2393 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isobutyl isobutyrate....... 3 UN2528 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... + Isobutyl isocyanate........ 3 UN2486 I 3, 6.1... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP27 Isobutyl methacrylate, 3 UN2283 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... stabilized. Isobutyl propionate........ 3 UN2394 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L B .......#
Passage 194Isobutylamine.............. 3 UN1214 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 Isobutylene see also 2.1 UN1055 ....... 2.1...... 19, T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Petroleum gases, liquefied. Isobutyraldehyde or 3 UN2045 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E 40 Isobutyl aldehyde. Isobutyric acid............ 3 UN2529 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A ....... Isobutyronitrile........... 3 UN2284 II 3, 6.1... IB2, T7, TP2, 150.......... 202....... 243....... 1 L 60 L E 40 TP13 Isobutyryl chloride........ 3 UN2395 II 3, 8..... IB1, T7, TP2 150.......... 202....... 243....... 1 L 5 L C 40 G Isocyanates, flammable, 3 UN2478 II 3, 6.1... 5, A3, A7, IB2, 150.......... 202....... 243....... 1 L 60 L D 40 toxic, n.o.s. or T11, TP2, TP13, Isocyanate solutions, TP27 flammable, toxic, n.o.s. flash point less than 23 degrees C. ........................... ........... ................. III 3, 6.1... 5, A3, A7, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T7, TP1, TP13, TP28 G Isocyanates, toxic, 6.1 UN3080 II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 25, 40, flammable, n.o.s. or TP13, TP27 48 Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C. G Isocyanates, toxic, n.o.s. 6.1 UN2206 II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L E 25, 40, or Isocyanate solutions, TP13, TP27 48 toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C. ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L E 25, 40, TP13, TP28 48 Isocyanatobenzotrifluorides 6.1 UN2285 II 6.1, 3... 5, IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L D 25, 40, 48 Isoheptenes................ 3 UN2287 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isohexenes................. 3 UN2288 II 3........ IB2, IP8, T11, 150.......... 202....... 242....... 5 L 60 L E ....... TP1 Isooctane, see Octanes..... ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Is#
Passage 195ooctenes................. 3 UN1216 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isopentane, see Pentane.... ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Isopentanoic acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Corrosive liquids, n.o.s.. Isopentenes................ 3 UN2371 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E ....... Isophorone diisocyanate.... 6.1 UN2290 III 6.1...... IB3, T4, TP2 153.......... 203....... 241....... 60 L 220 L B 40 Isophoronediamine.......... 8 UN2289 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Isoprene, stabilized....... 3 UN1218 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E ....... Isopropanol or Isopropyl 3 UN1219 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... alcohol. Isopropenyl acetate........ 3 UN2403 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isopropenylbenzene......... 3 UN2303 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Isopropyl acetate.......... 3 UN1220 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isopropyl acid phosphate... 8 UN1793 III 8........ IB2, T4, TP1 154.......... 213....... 240....... 25 kg 100 kg A ....... Isopropyl alcohol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Isopropanol. Isopropyl butyrate......... 3 UN2405 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Isopropyl chloroacetate.... 3 UN2947 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Isopropyl chloroformate.... 6.1 UN2407 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 40 B74, B77, T20, TP2, TP13, TP38, TP44 Isopropyl 2- 3 UN2934 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... chloropropionate. Isopropyl isobutyrate...... 3 UN2406 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... + Iso#
Passage 196propyl isocyanate....... 3 UN2483 I 3, 6.1... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP38, TP44 Isopropyl mercaptan, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Propanethiols. Isopropyl nitrate.......... 3 UN1222 II 3........ IB99 150.......... 202....... None...... 5 L 60 L D ....... Isopropyl phosphoric acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Isopropyl acid phosphate. Isopropyl propionate....... 3 UN2409 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Isopropylamine............. 3 UN1221 I 3, 8..... T11, TP2 None......... 201....... 243....... 0.5 L 2.5 L E ....... Isopropylbenzene........... 3 UN1918 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Isopropylcumyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hydroperoxide, with more than 72 percent in solution. Isosorbide dinitrate 4.1 UN2907 II 4.1...... IB6, IP2, N85 None......... 212....... None...... 15 kg 50 kg E 28, 36 mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate. Isosorbide-5-mononitrate... 4.1 UN3251 III 4.1...... 66, IB8 151.......... 213....... 240....... Forbidden Forbidden D 12 Isothiocyanic acid......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Jet fuel, see Fuel ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... aviation, turbine engine. D Jet perforating guns, 1.1D NA0124 II 1.1D..... 55, 56 None......... 62........ None...... Forbidden Forbidden 07 ....... charged oil well, with detonator. D Jet perforating guns, 1.4D NA0494 II 1.4D..... 55, 56 None......... 62........ None...... Forbidden Forbidden 06 ....... charged oil well, with detonator. Jet perforating guns, 1.1D UN0124 II 1.1D..... 55 None......... 62........ None...... Forbidden Forbidden 07 ....... charged oil well, without detonator. Jet perforating guns#
Passage 197, 1.4D UN0494 II 1.4D..... 55, 114 None......... 62........ None...... Forbidden 300 kg 06 ....... charged, oil well, without detonator. Jet perforators, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Charges, shaped, etc. Jet tappers, without ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... detonator, see Charges, shaped, etc. Jet thrust igniters, for ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... rocket motors or Jato, see Igniters. Jet thrust unit (Jato), see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Rocket motors. Kerosene................... 3 UN1223 III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T2, TP2 G Ketones, liquid, n.o.s..... 3 UN1224 I 3........ T11, TP1, TP8, None......... 201....... 243....... 1 L 30 L E ....... TP27#
Passage 198........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8, TP28 ........................... ........... ................. III 3........ B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... TP1, TP29 Krypton, compressed........ 2.2 UN1056 ....... 2.2...... ................ 306.......... 302....... None...... 75 kg 150 kg A ....... Krypton, refrigerated 2.2 UN1970 ....... 2.2...... T75, TP5 320.......... None...... None...... 50 kg 500 kg B ....... liquid (cryogenic liquid). Lacquer base or lacquer ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chips, nitrocellulose, dry, see Nitrocellulose, etc. (UN 2557). Lacquer base or lacquer ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chips, plastic, wet with alcohol or solvent, see Nitrocellulose (UN2059, UN2555, UN2556, UN2557) or Paint etc.(UN1263). Lead acetate............... 6.1 UN1616 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Lead arsenates............. 6.1 UN1617 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Lead arsenites............. 6.1 UN1618 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Lead azide (dry)........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Lead azide, wetted with not 1.1A UN0129 II 1.1A..... 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... less than 20 percent water or mixture of alcohol and water, by mass. Lead compounds, soluble, 6.1 UN2291 III 6.1...... 138, IB8, IP3, 153.......... 213....... 240....... 100 kg 200 kg A ....... n.o.s.. T1, TP33 Lead cyanide............... 6.1 UN1620 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 52 T3, TP33 Lead dioxide............... 5.1 UN1872 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Lead dross, see Lead ........... ................. ....... ......... ................ ............. .......... ..........#
Passage 199........... ........... .......... ....... sulfate, with more than 3 percent free acid. Lead nitrate............... 5.1 UN1469 II 5.1, 6.1. IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A ....... T3, TP33 Lead nitroresorcinate (dry) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Lead perchlorate, solid.... 5.1 UN1470 II 5.1, 6.1. IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Lead perchlorate, solution. 5.1 UN3408 III 5.1, 6.1. IB2, T4, TP1 152.......... 203....... 242....... 2.5 L 30 L A 56, 58 ........................... ........... ................. II 5.1, 6.1. IB2, T4, TP1 152.......... 202....... 243....... 1 L 5 L A 56, 58 Lead peroxide, see Lead ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dioxide. Lead phosphite, dibasic.... 4.1 UN2989 II 4.1...... IB8, IP2, IP4, None......... 212....... 240....... 5 kg 25 kg B 34 T3, TP33 ........................... ........... ................. III 4.1...... IB8, IP3, T1, 151.......... 213....... 240....... 15 kg 50 kg B 34 TP33 Lead picrate (dry)......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Lead styphnate (dry)....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Lead styphnate, wetted or 1.1A UN0130 II 1.1A..... 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... Lead trinitroresorcinate, wetted with not less than 20 percent water or mixture of alcohol and water, by mass. Lead sulfate with more than 8 UN1794 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... 3 percent free acid. T3, TP33 Lead trinitroresorcinate, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Lead styphnate, etc. Life-saving appliances, not 9 UN3072 ....... None..... ................ None......... 219....... None...... No limit No limit A ....... self inflating containing dangerous goods as equipment. Life-saving appliances, 9 UN2990 ....... None..... .....#
Passage 200........... None......... 219....... None...... No limit No limit A ....... self inflating. Lighter replacement ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... cartridges containing liquefied petroleum gases (and similar devices, each not exceeding 65 grams), see Lighters or lighter refills etc. containing flammable gas. Lighters, fuse............. 1.4S UN0131 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Lighters or Lighter refills 2.1 UN1057 ....... 2.1...... N10 None......... 21, 308... None...... 1 kg 15 kg B 40 containing flammable gas. Lime, unslaked, see Calcium ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... oxide. G Liquefied gas, flammable, 2.1 UN3161 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg D 40 n.o.s.. G Liquefied gas, n.o.s....... 2.2 UN3163 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... G Liquefied gas, oxidizing, 2.2 UN3157 ....... 2.2, 5.1. A14 306.......... 304....... 314, 315.. 75 kg 150 kg D ....... n.o.s.. G I Liquefied gas, toxic, 2.3 UN3308 ....... 2.3, 8... 1 None......... 192....... 245....... Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone A. G I Liquefied gas, toxic, 2.3 UN3308 ....... 2.3, 8... 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone B. G I Liquefied gas, toxic, 2.3 UN3308 ....... 2.3, 8... 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone C.#
Passage 201G I Liquefied gas, toxic, 2.3 UN3308 ....... 2.3, 8... 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40 corrosive, n.o.s. Inhalation Hazard Zone D. G I Liquefied gas, toxic, 2.3 UN3309 ....... 2.3, 2.1, 1 None......... 192....... 245....... Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone A. G I Liquefied gas toxic, 2.3 UN3309 ....... 2.3, 2.1, 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone B. G I Liquefied gas, toxic, 2.3 UN3309 ....... 2.3, 2.1, 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone C. G I Liquefied gas, toxic, 2.3 UN3309 ....... 2.3, 2.1, 4 None......... 304....... 314, 315.. Forbidden Forbidden D 17, 40 flammable, corrosive, 8. n.o.s. Inhalation Hazard Zone D. G Liquefied gas, toxic, 2.3 UN3160 ....... 2.3, 2.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 flammable, n.o.s. Inhalation Hazard Zone A. G Liquefied gas, toxic, 2.3 UN3160 ....... 2.3, 2.1. 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. Inhalation Hazard Zone B. G Liquefied gas, toxic, 2.3 UN3160 ....... 2.3, 2.1. 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. Inhalation Hazard Zone C. G Liquefied gas, toxic, 2.3 UN3160 ....... 2.3, 2.1. 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40 flammable, n.o.s. Inhalation Hazard Zone D. G Liquefied gas, toxic, 2.3 UN3162 ....... 2.3...... 1 None......... 192....... 245....... Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone A. G Liquefied gas, toxic, 2.3 UN3162 ....... 2.3...... 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone B. G Liquefied gas, toxic, 2.3 UN3162 ....... 2.3...... 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone C. G Liquefied gas, toxic, 2.3 UN3162 ....... 2.3...... 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone D. G I Liquefied gas, toxic, 2.3 UN3310 ....... 2.3, 5.1, 1 None......... 192....... 245....... Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone A. G I Liquefied gas, toxic, 2.3 UN3310 ....... 2.3, 5.1, 2,#
Passage 202B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone B. G I Liquefied gas, toxic, 2.3 UN3310 ....... 2.3, 5.1, 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone C. G I Liquefied gas, toxic, 2.3 UN3310 ....... 2.3, 5.1, 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40, 89, oxidizing, corrosive, 8. 90 n.o.s. Inhalation Hazard Zone D. G Liquefied gas, toxic, 2.3 UN3307 ....... 2.3, 5.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone A. G Liquefied gas, toxic, 2.3 UN3307 ....... 2.3, 5.1. 2, B9, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone B. G Liquefied gas, toxic, 2.3 UN3307 ....... 2.3, 5.1. 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone C. G Liquefied gas, toxic, 2.3 UN3307 ....... 2.3, 5.1. 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40 oxidizing, n.o.s. Inhalation Hazard Zone D. Liquefied gases, non- 2.2 UN1058 ....... 2.2...... ................ 306.......... 304....... None...... 75 kg 150 kg A ....... flammable charged with nitrogen, carbon dioxide or air. Liquefied hydrocarbon gas, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Hydrocarbon gas mixture, liquefied, n.o.s.. Liquefied natural gas, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methane, etc. (UN 1972). Liquefied petroleum gas see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Petroleum gases, liquefied. Lithium.................... 4.3 UN1415 I 4.3...... A7, A19, IB4, None......... 211....... 244....... Forbidden 15 kg E 52 IP1, N45 Lithium acetylide ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ethylenediamine complex, see Water reactive solid etc. Lithium alkyls, liquid..... 4.2 UN2445 I 4.2, 4.3. B11, T21, TP2, None......... 181.......#
Passage 203244....... Forbidden Forbidden D ....... TP7 Lithium alkyls, solid...... 4.2 UN3433 I 4.2, 4.3. B11, T21, TP7, None......... 181....... 244....... Forbidden Forbidden D ....... TP33 Lithium aluminum hydride... 4.3 UN1410 I 4.3...... A19 None......... 211....... 242....... Forbidden 15 kg E 52 Lithium aluminum hydride, 4.3 UN1411 I 4.3, 3... A2, A3, A11, N34 None......... 201....... 244....... Forbidden 1 L D 40 ethereal. Lithium batteries, 9 UN3091 II 9........ 29, A54, A55 185.......... 185....... None...... 5 kg 5 kg A ....... contained in equipment. Lithium batteries packed 9 UN3091 II 9........ 29, A54, A55 185.......... 185....... None...... 5 kg gross 35 kg gross A ....... with equipment. Lithium battery............ 9 UN3090 II 9........ 29, A54, A55 185.......... 185....... None...... 5 kg gross 35 kg gross A ....... Lithium borohydride........ 4.3 UN1413 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E 52 Lithium ferrosilicon....... 4.3 UN2830 II 4.3...... A19, IB7, IP2, 151.......... 212....... 241....... 15 kg 50 kg E 40, 85, T3, TP33 103 Lithium hydride............ 4.3 UN1414 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E 52 Lithium hydride, fused 4.3 UN2805 II 4.3...... A8, A19, A20, 151.......... 212....... 241....... 15 kg 50 kg E 52 solid. IB4, T3, TP33 Lithium hydroxide.......... 8 UN2680 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... T3, TP33 Lithium hydroxide, solution 8 UN2679 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 29#
Passage 204........................... ........... ................. III 8........ IB3, T4, TP2 154.......... 203....... 241....... 5 L 60 L A 29, 96 Lithium hypochlorite, dry 5.1 UN1471 II 5.1...... A9, IB8, IP2, 152.......... 212....... 240....... 5 kg 25 kg A 4, 48, with more than 39% IP4, N34 52, 56, available chlorine (8.8% 58, 69, available oxygen) or 106, Lithium hypochlorite 116 mixtures, dry with more than 39% available chlorine (8.8% available oxygen). Lithium in cartridges, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Lithium. Lithium nitrate............ 5.1 UN2722 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Lithium nitride............ 4.3 UN2806 I 4.3...... A19, IB4, IP1, None......... 211....... 242....... Forbidden 15 kg E ....... N40 Lithium peroxide........... 5.1 UN1472 II 5.1...... A9, IB6, IP2, 152.......... 212....... None...... 5 kg 25 kg A 13, 52, N34, T3, TP33 66, 75 Lithium silicon............ 4.3 UN1417 II 4.3...... A19, A20, IB7, 151.......... 212....... 241....... 15 kg 50 kg A 85, 103 IP2, T3, TP33 LNG, see Methane etc. (UN ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1972). London purple.............. 6.1 UN1621 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 LPG, see Petroleum gases, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquefied. Lye, see Sodium hydroxide, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solutions. Magnesium alkyls........... 4.2 UN3053 I 4.2, 4.3. B11, T21, TP2, None......... 181....... 244....... Forbidden Forbidden D 18 TP7 Magnesium aluminum 4.3 UN1419 I 4.3, 6.1. A19, N34, N40 None......... 211....... 242....... Forbidden 15 kg E 40, 52, phosphide. 85 + Magnesium arsenate......... 6.1 UN1622 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Magnesium bisulfite ........... ................. ....... ......... ................ ............. .......... .......... ........... ......#
Passage 205..... .......... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Magnesium bromate.......... 5.1 UN1473 II 5.1...... A1, IB8, IP4, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 T3, TP33 Magnesium chlorate......... 5.1 UN2723 II 5.1...... IB8, IP2, IP4, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 T3, TP33 Magnesium diamide.......... 4.2 UN2004 II 4.2...... A8, A19, A20, None......... 212....... 241....... 15 kg 50 kg C ....... IB6, T3, TP33 Magnesium diphenyl......... 4.2 UN2005 I 4.2...... T21, TP7, TP33 None......... 187....... 244....... Forbidden Forbidden C ....... Magnesium dross, wet or hot Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Magnesium fluorosilicate... 6.1 UN2853 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Magnesium granules, coated, 4.3 UN2950 III 4.3...... A1, A19, IB8, 151.......... 213....... 240....... 25 kg 100 kg A 52 particle size not less IP4, T1, TP33 than 149 microns. Magnesium hydride.......... 4.3 UN2010 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E 52 Magnesium or Magnesium 4.1 UN1869 III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A 39, 52, alloys with more than 50 T1, TP33 53, 74, percent magnesium in 101 pellets, turnings or ribbons. Magnesium nitrate.......... 5.1 UN1474 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Magnesium perchlorate...... 5.1 UN1475 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Magnesium peroxide......... 5.1 UN1476 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 13, 52, TP33 66, 75 Magnesium phosphide........ 4.3 UN2011 I 4.3, 6.1. A19, N40 None......... 211....... None...... Forbidden 15 kg E 40, 52, 85 Magnesium, powder or 4.3 UN1418 I 4.3, 4.2. A19, B56 None......... 211....... 244....... Forbidden 15 kg A 39, 52 Magnesium alloys, powder. ........................... ........... ................. II 4.3, 4.2. A19, B56, IB5, None......... 212....... 241....... 15 kg 50 kg A 39, 52 IP2, T3, TP33 ........................... ........... ................. III 4.3, 4.2. A19, B56, IB8, None......... 213....... 241....... 25 kg 100 kg A 39, 52 IP4, T1, TP33 Mag#
Passage 206nesium scrap, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Magnesium, etc. (UN 1869). Magnesium silicide......... 4.3 UN2624 II 4.3...... A19, A20, IB7, 151.......... 212....... 241....... 15 kg 50 kg B 85, 103 IP2, T3, TP33 Magnetized material, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sec. 173.21. Maleic anhydride........... 8 UN2215 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Maleic anhydride, molten... 8 UN2215 III 8........ T4, TP3 None......... 213....... 240....... Forbidden Forbidden A .......#
Passage 207Malononitrile.............. 6.1 UN2647 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 12 T3, TP33 Mancozeb (manganese ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ethylenebisdithiocarbamate complex with zinc) see Maneb. Maneb or Maneb preparations 4.2 UN2210 III 4.2, 4.3. 57, A1, A19, None......... 213....... 242....... 25 kg 100 kg A 34 with not less than 60 IB6, T1, TP33 percent maneb. Maneb stabilized or Maneb 4.3 UN2968 III 4.3...... 54, A1, A19, 151.......... 213....... 242....... 25 kg 100 kg B 34, 52 preparations, stabilized IB8, IP4, T1, against self-heating. TP33 Manganese nitrate.......... 5.1 UN2724 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Manganese resinate......... 4.1 UN1330 III 4.1...... A1, IB6, T1, 151.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Mannitan tetranitrate...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mannitol hexanitrate (dry). Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mannitol hexanitrate, 1.1D UN0133 II 1.1D..... 121 None......... 62........ None...... Forbidden Forbidden 10 ....... wetted or Nitromannite, wetted with not less than 40 percent water, or mixture of alcohol and water, by mass. Marine pollutants, liquid ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... or solid, n.o.s., see Environmentally hazardous substances, liquid or solid, n.o.s.. Matches, block, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Matches, 'strike anywhere'. Matches, fusee............. 4.1 UN2254 III 4.1...... ................ 186.......... 186....... None...... Forbidden Forbidden A ....... Matches, safety (book, card 4.1 UN1944 III 4.1...... ................ 186.......... 186....... None...... 25 kg 100 kg A ....... or strike on box). Matches, strike anywhere... 4.1 UN1331 III 4.1...... ................ 186.......... 186....... None...... Forbidden Forbidden#
Passage 208B ....... Matches, wax, Vesta........ 4.1 UN1945 III 4.1...... ................ 186.......... 186....... None...... 25 kg 100 kg B ....... Matting acid, see Sulfuric ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... acid. Medicine, liquid, 3 UN3248 II 3, 6.1... 36, IB2 150.......... 202....... None...... 1 L 5 L B 40 flammable, toxic, n.o.s.. ........................... ........... ................. III 3, 6.1... 36, IB3 150.......... 203....... None...... 5 L 5 L A ....... Medicine, liquid, toxic, 6.1 UN1851 II 6.1...... 36 153.......... 202....... 243....... 5 L 5 L C 40 n.o.s.. ........................... ........... ................. III 6.1...... 36 153.......... 203....... 241....... 5 L 5 L C 40 Medicine, solid, toxic, 6.1 UN3249 II 6.1...... 36, T3, TP33 153.......... 212....... None...... 5 kg 5 kg C 40 n.o.s.. ........................... ........... ................. III 6.1...... 36, T1, TP33 153.......... 213....... None...... 5 kg 5 kg C 40 Memtetrahydrophthalic ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... anhydride, see Corrosive liquids, n.o.s.. Mercaptans, liquid, 3 UN3336 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E 95 flammable, n.o.s. or Mercaptan mixture, liquid, flammable, n.o.s.. ........................... ........... ................. II 3........ IB2, T7, TP1, 150.......... 202....... 242....... 5 L 60 L B 95 TP8, TP28 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 203....... 241....... 60 L 220 L B 95 T4, TP1, TP29 Mercaptans, liquid, 3 UN1228 II 3, 6.1... IB2, T11, TP2, None......... 202....... 243....... Forbidden 60 L B 40, 95 flammable, toxic, n.o.s. TP27 or Mercaptan mixtures, liquid, flammable, toxic, n.o.s.. ........................... ........... ................. III 3, 6.1... A6, B1, IB3, T7, 150.......... 203....... 242....... 5 L 220 L A 40, 95 TP1, TP28 Mercaptans, liquid, toxic, 6.1 UN3071 II 6.1, 3... A6, IB2, T11, 153.......... 202....... 243....... 5 L 60 L C 40, 121 flammable, n.o.s. or TP2, TP13, TP27 Mercaptan mixtures, liquid, toxic, flammable, n.o.s., flash point not less than 23 degrees C. 5-Mercaptotetrazol-1-acetic 1.4C UN0448 II 1.4C..... ....#
Passage 209............ None......... 62........ None...... Forbidden 75 kg 09 ....... acid. Mercuric arsenate.......... 6.1 UN1623 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercuric chloride.......... 6.1 UN1624 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercuric compounds, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercury compounds, etc. Mercuric nitrate........... 6.1 UN1625 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... N73, T3, TP33 + Mercuric potassium cyanide. 6.1 UN1626 I 6.1...... IB7, IP1, N74, None......... 211....... 242....... 5 kg 50 kg A 52 N75, T6, TP33 Mercuric sulfocyanate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercury thiocyanate. Mercurol, see Mercury ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nucleate. Mercurous azide............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercurous compounds, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercury compounds, etc. Mercurous nitrate.......... 6.1 UN1627 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 A W Mercury.................... 8 UN2809 III 8........ ................ 164.......... 164....... 240....... 35 kg 35 kg B 40, 97 Mercury acetate............ 6.1 UN1629 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury acetylide.......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercury ammonium chloride.. 6.1 UN1630 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury based pesticides, 3 UN2778 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP#
Passage 21027 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Mercury based pesticides, 6.1 UN3012 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Mercury based pesticides, 6.1 UN3011 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C.#
Passage 211........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... IB3, T7, TP2, 153.......... 203....... 242....... 60 L 220 L A 40 TP28 Mercury based pesticides, 6.1 UN2777 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Mercury benzoate........... 6.1 UN1631 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury bromides........... 6.1 UN1634 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury compounds, liquid, 6.1 UN2024 I 6.1...... ................ None......... 201....... 243....... 1 L 30 L B 40 n.o.s.. ........................... ........... ................. II 6.1...... IB2 153.......... 202....... 243....... 5 L 60 L B 40 ........................... ........... ................. III 6.1...... IB3 153.......... 203....... 241....... 60 L 220 L B 40 Mercury compounds, solid, 6.1 UN2025 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A ....... n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 A Mercury contained in 8 UN2809 III 8........ ................ None......... 164....... None...... No limit No limit B 40, 97 manufactured articles. Mercury cyanide............ 6.1 UN1636 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 52 N74, N75, T3, TP33 Mercury fulminate, wetted 1.1A UN0135 II 1.1A..... 111, 117 None......... 62........ None...... Forbidden Forbidden 12 ....... with not less than 20 percent water, or mixture of alcohol and water, by mass. Mercury gluconate.......... 6.1 UN1637 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242.....#
Passage 212.. 25 kg 100 kg A ....... T3, TP33 Mercury iodide............. 6.1 UN1638 II 6.1...... IB2, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury iodide aquabasic Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ammonobasic (Iodide of Millon's base). Mercury nitride............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercury nucleate........... 6.1 UN1639 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury oleate............. 6.1 UN1640 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury oxide.............. 6.1 UN1641 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury oxycyanide......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mercury oxycyanide, 6.1 UN1642 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 52, 91 desensitized. T3, TP33 Mercury potassium iodide... 6.1 UN1643 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury salicylate......... 6.1 UN1644 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 + Mercury sulfates........... 6.1 UN1645 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mercury thiocyanate........ 6.1 UN1646 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Mesityl oxide.............. 3 UN1229 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... G Metal carbonyls, liquid, 6.1 UN3281 I 6.1...... 5, T14, TP2, None......... 201....... 243....... 1 L 30 L B 40 n.o.s.. TP13, TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 G Metal carbonyls, solid, 6.1 UN3466 I 6.1...... IB7, IP#
Passage 2131, T6, None......... 211....... 242....... 5 kg 50 kg D 40 n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg B 40 TP33#
Passage 214Metal catalyst, dry........ 4.2 UN2881 I 4.2...... N34, T21, TP7, None......... 187....... None...... Forbidden Forbidden C ....... TP33 ........................... ........... ................. II 4.2...... IB6, IP2, N34, None......... 187....... 242....... Forbidden 50 kg C ....... T3, TP33 ........................... ........... ................. III 4.2...... IB8, IP3, N34, None......... 187....... 241....... 25 kg 100 kg C ....... T1, TP33 Metal catalyst, wetted with 4.2 UN1378 II 4.2...... A2, A8, IB1, None......... 212....... None...... Forbidden 50 kg C ....... a visible excess of liquid. N34, T3, TP33 Metal hydrides, flammable, 4.1 UN3182 II 4.1...... A1, IB4, T3, 151.......... 212....... 240....... 15 kg 50 kg E ....... n.o.s.. TP33 ........................... ........... ................. III 4.1...... A1, IB4, T1, 151.......... 213....... 240....... 25 kg 100 kg E ....... TP33 Metal hydrides, water 4.3 UN1409 I 4.3...... A19, N34, N40 None......... 211....... 242....... Forbidden 15 kg D 52 reactive, n.o.s.. ........................... ........... ................. II 4.3...... A19, IB4, N34, 151.......... 212....... 242....... 15 kg 50 kg D 52 N40, T3, TP33 Metal powder, self-heating, 4.2 UN3189 II 4.2...... IB6, IP2, T3, None......... 212....... 241....... 15 kg 50 kg C ....... n.o.s.. TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg C ....... TP33 Metal powders, flammable, 4.1 UN3089 II 4.1...... IB8, IP2, IP4, 151.......... 212....... 240....... 15 kg 50 kg B ....... n.o.s.. T3, TP33 ........................... ........... ................. III 4.1...... IB6, T1, TP33 151.......... 213....... 240....... 25 kg 100 kg B ....... Metal salts of methyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitramine (dry). G Metal salts of organic 4.1 UN3181 II 4.1...... A1, IB8, IP2, 151.......... 212....... 240....... 15 kg 50 kg B 40 compounds, flammable, IP4, T3, TP33 n.o.s.. ........................... ........... ................. III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg B 40 T1, TP33 Metaldehyde................ 4.1 UN1332 III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 G Metallic sub#
Passage 215stance, water- 4.3 UN3208 I 4.3...... A7, IB4 None......... 211....... 242....... Forbidden 15 kg E 40 reactive, n.o.s.. ........................... ........... ................. II 4.3...... A7, IB7, IP2, 151.......... 212....... 242....... 15 kg 50 kg E 40 T3, TP33 ........................... ........... ................. III 4.3...... A7, IB8, IP4, 151.......... 213....... 241....... 25 kg 100 kg E 40 T1, TP33 G Metallic substance, water- 4.3 UN3209 I 4.3, 4.2. A7 None......... 211....... 242....... Forbidden 15 kg E 40 reactive, self-heating, n.o.s.. ........................... ........... ................. II 4.3, 4.2. A7, IB5, IP2, None......... 212....... 242....... 15 kg 50 kg E 40 T3, TP33 ........................... ........... ................. III 4.3, 4.2. A7, IB8, IP4, None......... 213....... 242....... 25 kg 100 kg E 40 T1, TP33 Methacrylaldehyde, 3 UN2396 II 3, 6.1... 45, IB2, T7, 150.......... 202....... 243....... 1 L 60 L E 40 stabilized. TP1, TP13 Methacrylic acid, 8 UN2531 II 8........ IB2, T7, TP1, 154.......... 202....... 242....... 1 L 30 L C 40 stabilized. TP18, TP30 + Methacrylonitrile, 3 UN3079 I 3, 6.1... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 12, 40, stabilized. B74, T20, TP2, 48 TP13, TP38, TP45 Methallyl alcohol.......... 3 UN2614 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Methane and hydrogen, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures, see Hydrogen and methane, mixtures, etc. Methane, compressed or 2.1 UN1971 ....... 2.1...... ................ 306.......... 302....... 302....... Forbidden 150 kg E 40 Natural gas, compressed (with high methane content). Methane, refrigerated 2.1 UN1972 ....... 2.1...... T75, TP5 None......... None...... 318....... Forbidden Forbidden D 40 liquid (cryogenic liquid) or Natural gas, refrigerated liquid (cryogenic liquid), with high methane content). Methanesulfonyl chloride... 6.1 UN3246 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP2, TP12, TP13, TP38, TP45 + I Methanol................... 3 UN1230 II 3, 6.1... IB2, T7, TP2 150.......... 202....... 242....... 1 L 60 L B 40 D Methanol................... 3 UN1230 II 3........ IB2, T7, TP2 150.......... 20#
Passage 2162....... 242....... 1 L 60 L B 40 Methazoic acid............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 4-Methoxy-4-methylpentan-2- 3 UN2293 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... one. 1-Methoxy-2-propanol....... 3 UN3092 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... + Methoxymethyl isocyanate... 3 UN2605 I 3, 6.1... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP38, TP44 Methyl acetate............. 3 UN1231 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyl acetylene and 2.1 UN1060 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 propadiene mixtures, stabilized. Methyl acrylate, stabilized 3 UN1919 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP13 Methyl alcohol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methanol. Methyl allyl chloride...... 3 UN2554 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L E ....... TP13 Methyl amyl ketone, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Amyl methyl ketone.#
Passage 217Methyl bromide............. 2.3 UN1062 ....... 2.3...... 3, B14, T50 None......... 193....... 314, 315.. Forbidden Forbidden D 40 Methyl bromide and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chloropicrin mixtures with more than 2 percent chloropicrin, see Chloropicrin and methyl bromide mixtures. Methyl bromide and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chloropicrin mixtures with not more than 2 percent chloropicrin, see Methyl bromide. Methyl bromide and ethylene 6.1 UN1647 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden C 40 dibromide mixtures, liquid. B74, N65, T20, TP2, TP13, TP38, TP44 Methyl bromoacetate........ 6.1 UN2643 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L D 40 2-Methlybutanal............ 3 UN3371 II ......... 3IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... 2-Methyl-1-butene.......... 3 UN2459 I 3........ T11, TP2 None......... 201....... 243....... 1 L 30 L E ....... 2-Methyl-2-butene.......... 3 UN2460 II 3........ IB2, IP8, T7, None......... 202....... 242....... 5 L 60 L E ....... TP1 3-Methyl-1-butene.......... 3 UN2561 I 3........ T11, TP2 None......... 201....... 243....... 1 L 30 L E ....... Methyl tert-butyl ether.... 3 UN2398 II 3........ IB2, T7, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Methyl butyrate............ 3 UN1237 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyl chloride, or 2.1 UN1063 ....... 2.1...... T50 306.......... 304....... 314, 315.. 5 kg 100 kg D 40 Refrigerant gas R 40. Methyl chloride and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chloropicrin mixtures, see Chloropicrin and methyl chloride mixtures. Methyl chloride and 2.1 UN1912 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg D 40 methylene chloride mixtures. Methyl chloroacetate....... 6.1 UN2295 I 6.1, 3... T14, TP2, TP13 None......... 201....... 243....... 1 L 30 L D ....... Methyl chlorocarbonate, see ........... ................. ....... ......... ................ ............. .........#
Passage 218. .......... ........... ........... .......... ....... Methyl chloroformate. Methyl chloroform, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1,1,1-Trichloroethane. Methyl chloroformate....... 6.1 UN1238 I 6.1, 3, 8 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 21, 40, B72, N34, T22, 100 TP2, TP13, TP38, TP44 Methyl chloromethyl ether.. 6.1 UN1239 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, T22, TP2, TP38, TP44 Methyl 2-chloropropionate.. 3 UN2933 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Methyl dichloroacetate..... 6.1 UN2299 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Methyl ethyl ether, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethyl methyl ether. Methyl ethyl ketone, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethyl methyl ketone. Methyl ethyl ketone Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxide, in solution with more than 9 percent by mass active oxygen. 2-Methyl-5-ethylpyridine... 6.1 UN2300 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Methyl fluoride, or 2.1 UN2454 ....... 2.1...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Refrigerant gas R 41. Methyl formate............. 3 UN1243 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E ....... 2-Methyl-2-heptanethiol.... 6.1 UN3023 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40, 102 B74, T20, TP2, TP13, TP38, TP45 Methyl iodide.............. 6.1 UN2644 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A 12, 40 B74, T20, TP2, TP13, TP38, TP45 Methyl isobutyl carbinol... 3 UN2053 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Methyl isobutyl ketone..... 3 UN1245 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60#
Passage 219L B ....... Methyl isobutyl ketone Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... peroxide, in solution with more than 9 percent by mass active oxygen. Methyl isocyanate.......... 6.1 UN2480 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40, 52 B72, T22, TP2, TP13, TP38, TP44 Methyl isopropenyl ketone, 3 UN1246 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... stabilized. Methyl isothiocyanate...... 6.1 UN2477 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A ....... B74, T20, TP2, TP13, TP38, TP45 Methyl isovalerate......... 3 UN2400 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyl magnesium bromide, 4.3 UN1928 I 4.3, 3... ................ None......... 201....... 243....... Forbidden 1 L D ....... in ethyl ether. Methyl mercaptan........... 2.3 UN1064 ....... 2.3, 2.1. 3, B7, B9, B14, None......... 304....... 314, 315.. Forbidden Forbidden D 40 T50#
Passage 220Methyl ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mercaptopropionaldehyde, see Thia-4-pentanal. Methyl methacrylate 3 UN1247 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 monomer, stabilized. Methyl nitramine (dry)..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methyl nitrate............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methyl nitrite............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methyl norbornene ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dicarboxylic anhydride, see Corrosive liquids, n.o.s.. Methyl orthosilicate....... 6.1 UN2606 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden E 40 B74, T20, TP2, TP13, TP38, TP45 D Methyl phosphonic 6.1 NA9206 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden C ....... dichloride. B74, N34, N43, T20, TP4, TP12, TP13, TP38, TP45 Methyl phosphonothioic ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dichloride, anhydrous, see Corrosive liquid, n.o.s.. D Methyl phosphonous 6.1 NA2845 I 6.1, 4.2. 2, B9, B14, B16, None......... 227....... 244....... Forbidden Forbidden D 18 dichloride, pyrophoric B32, B74, T20, liquid. TP4, TP12, TP13, TP38, TP45 Methyl picric acid (heavy Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... metal salts of). Methyl propionate.......... 3 UN1248 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyl propyl ether........ 3 UN2612 II 3........ IB2, IP8, T7, 150.......... 202....... 242....... 5 L 60 L E 40 TP2 Methyl propyl ketone....... 3 UN1249 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyl sulfate, see ........... ................#
Passage 221. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dimethyl sulfate. Methyl sulfide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dimethyl sulfide. Methyl trichloroacetate.... 6.1 UN2533 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Methyl trimethylol methane Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitrate. Methyl vinyl ketone, 6.1 UN1251 I 6.1, 3, 8 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden B 40 stabilized. B72, T22, TP2, TP13, TP38, TP44 Methylal................... 3 UN1234 II 3........ IB2, IP8, T7, None......... 202....... 242....... 5 L 60 L E ....... TP2 Methylamine, anhydrous..... 2.1 UN1061 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Methylamine, aqueous 3 UN1235 II 3, 8..... B1, IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L E 135 solution. Methylamine dinitramine and Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dry salts thereof. Methylamine nitroform...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Methylamine perchlorate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). Methylamyl acetate......... 3 UN1233 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... N-Methylaniline............ 6.1 UN2294 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... alpha-Methylbenzyl alcohol, 6.1 UN2937 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... liquid. alpha-Methylbenzyl alcohol, 6.1 UN3438 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... solid. TP33 3-Methylbutan-2-one........ 3 UN2397 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... N-Methylbutylamine......... 3 UN2945 II 3, 8..... IB2, T7, TP1 150.......... 202....#
Passage 222... 243....... 1 L 5 L B 40 Methylchlorosilane......... 2.3 UN2534 ....... 2.3, 2.1, 2, B9, B14, N34 None......... 226....... 314, 315.. Forbidden Forbidden D 17, 40 8. Methylcyclohexane.......... 3 UN2296 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methylcyclohexanols, 3 UN2617 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... flammable. Methylcyclohexanone........ 3 UN2297 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Methylcyclopentane......... 3 UN2298 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... D Methyldichloroarsine....... 6.1 NA1556 I 6.1...... 2, T20, TP4, None......... 192....... None...... Forbidden Forbidden D 40 TP12, TP13, TP38, TP45 Methyldichlorosilane....... 4.3 UN1242 I 4.3, 8, 3 A2, A3, A7, B6, None......... 201....... 243....... Forbidden 1 L D 21, 28, B77, N34, T10, 40, 49, TP2, TP7, TP13 100 Methylene chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dichloromethane. Methylene glycol dinitrate. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 2-Methylfuran.............. 3 UN2301 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... a-Methylglucoside Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tetranitrate. a-Methylglycerol trinitrate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 5-Methylhexan-2-one........ 3 UN2302 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Methylhydrazine............ 6.1 UN1244 I 6.1, 3, 8 1, B7, B9, B14, None......... 226....... 244....... Forbidden Forbidden D 21, 40, B30, B72, B77, 49, 100 N34, T22, TP2, TP13, TP38, TP44 4-Methylmorpholine or n- 3 UN2535 II 3, 8..... B6, IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 methylmorpholine. Methylpentadienes.......... 3 UN2461 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L E ....... 2-Methylpentan-2-ol........ 3 UN2560 II#
Passage 223I 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Methylpentanes, see Hexanes ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... .......#
Passage 224Methylphenyldichlorosilane. 8 UN2437 II 8........ IB2, T7, TP2, 154.......... 202....... 242....... 1 L 30 L C 40 TP13 1-Methylpiperidine......... 3 UN2399 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B ....... Methyltetrahydrofuran...... 3 UN2536 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Methyltrichlorosilane...... 3 UN1250 I 3, 8..... A7, B6, B77, None......... 201....... 243....... Forbidden 2.5 L B 40 N34, T11, TP2, TP13 alpha-Methylvaleraldehyde.. 3 UN2367 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Mine rescue equipment ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... containing carbon dioxide, see Carbon dioxide. Mines with bursting charge. 1.1F UN0136 II 1.1F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... Mines with bursting charge. 1.1D UN0137 II 1.1D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Mines with bursting charge. 1.2D UN0138 II 1.2D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... Mines with bursting charge. 1.2F UN0294 II 1.2F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... Mixed acid, see Nitrating ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... acid, mixtures etc. Mobility aids, see Battery ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... powered equipment or Battery powered vehicle'. D Model rocket motor......... 1.4C NA0276 II 1.4C..... 51 None......... 62........ None...... Forbidden 75 kg 06 ....... D Model rocket motor......... 1.4S NA0323 II 1.4S..... 51 None......... 62........ None...... 25 kg 100 kg 05 ....... Molybdenum pentachloride... 8 UN2508 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg C 40 TP33 Monochloroacetone Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (unstabilized). Monochloroethylene, see ........... ................. ....... ......... .....#
Passage 225........... ............. .......... .......... ........... ........... .......... ....... Vinyl chloride, stabilized. Monoethanolamine, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethanolamine, solutions. Monoethylamine, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ethylamine. Morpholine................. 8 UN2054 I 8, 3..... A6, T10, TP2 None......... 201....... 243....... 0.5 L 2.5 L A ....... Morpholine, aqueous, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixture, see Corrosive liquids, n.o.s.. Motor fuel anti-knock ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... compounds see Motor fuel anti-knock mixtures. + Motor fuel anti-knock 6.1 UN1649 I 6.1, 3... 14, 151, B9, None......... 201....... 244....... Forbidden 30 L D 25, 40 mixtures. B90, T14, TP2, TP13 Motor spirit, see Gasoline. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Muriatic acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrochloric acid. Musk xylene, see 5-tert- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Butyl-2,4,6-trinitro-m- xylene. Naphtha see Petroleum ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... distillates n.o.s.. Naphthalene, crude or 4.1 UN1334 III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A ....... Naphthalene, refined. T1, TP33 Naphthalene diozonide...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... beta-Naphthylamine......... 6.1 UN1650 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 beta-Naphthylamine, solid.. 6.#
Passage 2261 UN1650 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 beta-Naphthylamine solution 6.1 UN3411 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... ........................... ........... ................. III 6.1...... IB2, T7, TP2 153.......... 203....... 241....... 60 L 220 L A ....... alpha-Naphthylamine........ 6.1 UN2077 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Naphthalene, molten........ 4.1 UN2304 III 4.1...... IB1, T1, TP3 151.......... 213....... 241....... Forbidden Forbidden C ....... Naphthylamineperchlorate... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Naphthylthiourea........... 6.1 UN1651 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Naphthylurea............... 6.1 UN1652 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Natural gases (with high ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... methane content), see Methane, etc. (UN 1971, UN 1972). Neohexane, see Hexanes..... ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Neon, compressed........... 2.2 UN1065 ....... 2.2...... ................ 306.......... 302....... 302....... 75 kg 150 kg A ....... Neon, refrigerated liquid 2.2 UN1913 ....... 2.2...... T75, TP5 320.......... 316....... None...... 50 kg 500 kg B ....... (cryogenic liquid). New explosive or explosive ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... device, see Sec. Sec. 173.51 and 173.56. Nickel carbonyl............ 6.1 UN1259 I 6.1, 3... 1 None......... 198....... None...... Forbidden Forbidden D 18, 40 Nickel cyanide............. 6.1 UN1653 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 52 N74, N75, T3, TP33 Nickel nitrate............. 5.1 UN2725 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Nickel nitrite............. 5.1 UN2726 III 5.1.....#
Passage 227. A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 T1, TP33 Nickel picrate............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nicotine................... 6.1 UN1654 II 6.1...... IB2 153.......... 202....... 243....... 5 L 60 L A .......#
Passage 228Nicotine compounds, liquid, 6.1 UN3144 I 6.1...... A4 None......... 201....... 243....... 1 L 30 L B 40 n.o.s. or Nicotine preparations, liquid, n.o.s.. ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L B 40 TP28 Nicotine compounds, solid, 6.1 UN1655 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... n.o.s. or Nicotine TP33 preparations, solid, n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Nicotine hydrochloride 6.1 UN1656 II 6.1...... IB2 153.......... 202....... 243....... 5 L 60 L A ....... liquid or solution. ........................... ........... ................. III 6.1...... IB3 153.......... 203....... 241....... 60 L 220 L A ....... Nicotine hydrochloride, 6.1 UN3444 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... solid. T3, TP33 Nicotine salicylate........ 6.1 UN1657 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Nicotine sulfate solution.. 6.1 UN1658 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... ........................... ........... ................. III 6.1...... IB3, T7, TP2 153.......... 203....... 241....... 60 L 220 L A ....... Nicotine sulphate, solid... 6.1 UN3445 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Nicotine tartrate.......... 6.1 UN1659 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Nitrated paper (unstable).. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrates, inorganic, 5.1 UN3218 II 5.1...... 58, IB2, T4, TP1 152.......... 202....... 242....... 1 L 5 L B 56, 58, aqueous solution, n.o.s.. 133 ........................... ........... ................. III 5.1...... 58, IB2, T4, TP1 152.......... 2#
Passage 22903....... 241....... 2.5 L 30 L B 56, 58, 133 Nitrates, inorganic, n.o.s. 5.1 UN1477 II 5.1...... IB8, IP2, IP4, 152.......... 212....... 240....... 5 kg 25 kg A 56, 58 T3, TP33 ........................... ........... ................. III 5.1...... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 TP33 Nitrates of diazonium Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... compounds. Nitrating acid mixtures, 8 UN1826 I 8, 5.1... A7, T10, TP2, None......... 158....... 243....... Forbidden 2.5 L D 40, 66 spent with more than 50 TP12, TP13 percent nitric acid. Nitrating acid mixtures 8 UN1826 II 8........ A7, B2, IB2, T8, None......... 158....... 242....... Forbidden 30 L D 40 spent with not more than TP2, TP12 50 percent nitric acid. Nitrating acid mixtures 8 UN1796 I 8, 5.1... A7, T10, TP2, None......... 158....... 243....... Forbidden 2.5 L D 40, 66 with more than 50 percent TP12, TP13 nitric acid. Nitrating acid mixtures 8 UN1796 II 8........ A7, B2, IB2, T8, None......... 158....... 242....... Forbidden 30 L D 40 with not more than 50 TP2, TP12, TP13 percent nitric acid. Nitric acid other than red 8 UN2031 I 8, 5.1... A3, B47, B53, None......... 158....... 243....... Forbidden 2.5 L D 44, 66, fuming, with more than 70 T10, TP2, TP12, 89, 90, percent nitric acid. TP13 110, 111 Nitric acid other than red 8 UN2031 II 8........ A6, B2, B47, None......... 158....... 242....... Forbidden 30 L D 44, 66, fuming, with not more than B53, IB2, T8, 89, 90, 70 percent nitric acid. TP2, TP12 110, 111 + Nitric acid, red fuming.... 8 UN2032 I 8, 5.1, 2, B9, B32, B74, None......... 227....... 244....... Forbidden Forbidden D 40, 66, 6.1. T20, TP2, TP12, 74, 89, TP13, TP38, TP45 90 Nitric oxide, compressed... 2.3 UN1660 ....... 2.3, 5.1, 1, B37, B46, None......... 337....... None...... Forbidden Forbidden D 40, 89, 8. B50, B60, B77 90 Nitric oxide and dinitrogen 2.3 UN1975 ....... 2.3, 5.1, 1, B7, B9, B14, None......... 337....... None...... Forbidden Forbidden D 40, 89, tetroxide mixtures or 8. B45, B46, B61, 90 Nitric oxide and nitrogen B66, B67, B77 dioxide mixtures. G Nitriles, flammable, toxic, 3 UN3273 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L E 40, 52 n.o.s.. TP27 ........................... ........... ..............#
Passage 230... II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40, 52 TP13, TP27 G Nitriles, toxic, flammable, 6.1 UN3275 I 6.1, 3... 5, T14, TP2, None......... 201....... 243....... 1 L 30 L B 40, 52 n.o.s.. TP13, TP27 ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40, 52 TP13, TP27 G Nitriles, toxic, liquid, 6.1 UN3276 I 6.1...... 5, T14, TP2, None......... 201....... 243....... 1 L 30 L B 52 n.o.s.. TP13, TP27 G Nitriles, toxic, solid, 6.1 UN3439 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg D 52 n.o.s.. TP33 G Nitriles, toxic, liquid, 6.1 UN3276 II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 52 n.o.s.. TP27 G Nitriles, toxic, solid, 6.1 UN3439 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 52 n.o.s.. T3, TP33#
Passage 231G Nitriles, toxic, liquid, 6.1 UN3276 III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A 52 n.o.s.. TP28 G Nitriles, toxic, solid, 6.1 UN3439 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 n.o.s.. TP33 Nitrites, inorganic, 5.1 UN3219 II 5.1...... IB1, T4, TP1 152.......... 202....... 242....... 1 L 5 L B 46, 56, aqueous solution, n.o.s.. 58, 133 ........................... ........... ................. III 5.1...... IB2, T4, TP1 152.......... 203....... 241....... 2.5 L 30 L B 46, 56, 58, 133 Nitrites, inorganic, n.o.s. 5.1 UN2627 II 5.1...... 33, IB8, IP4, 152.......... 212....... None...... 5 kg 25 kg A 46, 56, T3, TP33 58, 133 3-Nitro-4- 6.1 UN2307 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 chlorobenzotrifluoride. 6-Nitro-4-diazotoluene-3- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... sulfonic acid (dry). Nitro isobutane triol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitrate. N-Nitro-N-methylglycolamide Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitrate. 2-Nitro-2-methylpropanol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitrate. Nitro urea................. 1.1D UN0147 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... N-Nitroaniline............. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... + Nitroanilines (o-; m-; p-;) 6.1 UN1661 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Nitroanisole, liquid....... 6.1 UN2730 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Nitroanisoles, solid....... 6.1 UN3458 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 + Nitrobenzene............... 6.1 UN1662 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 m-Nitrobenzene diazonium Forbidden .......#
Passage 232.......... ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... perchlorate. Nitrobenzenesulfonic acid.. 8 UN2305 II 8........ B2, B4, IB8, 154.......... 202....... 242....... 1 L 30 L A ....... IP2, IP4, T3, TP33 Nitrobenzol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrobenzene. 5-Nitrobenzotriazol........ 1.1D UN0385 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Nitrobenzotrifluorides, 6.1 UN2306 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 liquid. Nitrobenzotrifluorides, 6.1 UN3431 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 solid. T3, TP33 Nitrobromobenzenes, liquid. 6.1 UN2732 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Nitrobromobenzenes, solid.. 6.1 UN3459 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Nitrocellulose, dry or 1.1D UN0340 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 13 27E wetted with less than 25 percent water (or alcohol), by mass. Nitrocellulose membrane 4.1 UN3270 II 4.1...... 43, A1 151.......... 212....... 240....... 1 kg 15 kg D ....... filters, with not more than 12.6% nitrogen, by dry mass. Nitrocellulose, plasticized 1.3C UN0343 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... with not less than 18 percent plasticizing substance, by mass. Nitrocellulose, solution, 3 UN2059 I 3........ T11, TP1, TP8, None......... 201....... 243....... 1 L 30 L E ....... flammable with not more TP27 than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose. ........................... ........... ................. II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Nitrocellulose, unmodified 1.1D UN0341 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 13 27E or plasticized with less than 18 percent plasticizing substance, by mass. Nitrocellulose, wetted#
Passage 233with 1.3C UN0342 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... not less than 25 percent alcohol, by mass. Nitrocellulose with alcohol 4.1 UN2556 II 4.1...... ................ 151.......... 212....... None...... 1 kg 15 kg D 28 with not less than 25 percent alcohol by mass, and with not more than 12.6 percent nitrogen, by dry mass. Nitrocellulose, with not 4.1 UN2557 II 4.1...... 44 151.......... 212....... None...... 1 kg 15 kg D 28 more than 12.6 percent nitrogen, by dry mass, or Nitrocellulose mixture with pigment or Nitrocellulose mixture with plasticizer or Nitrocellulose mixture with pigment and plasticizer. Nitrocellulose with water 4.1 UN2555 II 4.1...... ................ 151.......... 212....... None...... 15 kg 50 kg E 28 with not less than 25 percent water, by mass. Nitrochlorobenzene, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chloronitrobenzenes etc. Nitrocresols, solid........ 6.1 UN2446 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Nitrocresols, liquid....... 6.1 UN3434 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Nitroethane................ 3 UN2842 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Nitroethyl nitrate......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitroethylene polymer...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrogen, compressed....... 2.2 UN1066 ....... 2.2...... ................ 306.......... 302....... 314, 315.. 75 kg 150 kg A ....... Nitrogen dioxide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dinitrogen tetroxide. Nitrogen fertilizer ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Fertilizer ammoniating solution etc. Nitrogen, mixtures with ........... ................. ....... ......... ................ ............. ..........#
Passage 234.......... ........... ........... .......... ....... rare gases, see Rare gases and nitrogen mixtures. Nitrogen peroxide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dinitrogen tetroxide. Nitrogen, refrigerated 2.2 UN1977 ....... 2.2...... T75, TP5 320.......... 316....... 318....... 50 kg 500 kg D ....... liquid cryogenic liquid.#
Passage 235Nitrogen tetroxide and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitric oxide mixtures, see Nitric oxide and nitrogen tetroxide mixtures. Nitrogen tetroxide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dinitrogen tetroxide. Nitrogen trichloride....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrogen trifluoride....... 2.2 UN2451 ....... 2.2, 5.1. ................ None......... 302....... None...... 75 kg 150 kg D 40 Nitrogen triiodide......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrogen triiodide Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... monoamine. Nitrogen trioxide.......... 2.3 UN2421 ....... 2.3, 5.1, 1 None......... 336....... 245....... Forbidden Forbidden D 40, 89, 8. 90 Nitroglycerin, desensitized 1.1D UN0143 II 1.1D, 6.1 125 None......... 62........ None...... Forbidden Forbidden 13 21E with not less than 40 percent non-volatile water insoluble phlegmatizer, by mass. Nitroglycerin, liquid, not Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... desensitized. Nitroglycerin mixture, 3 UN3343 ....... 3........ 129 None......... 214....... None...... Forbidden Forbidden D ....... desensitized, liquid, flammable, n.o.s. with not more than 30 percent nitroglycerin, by mass. Nitroglycerin mixture, 3 UN3357 II 3........ 142 None......... 202....... 243....... 5 L 60 L E ....... desensitized, liquid, n.o.s. with not more than 30% nitroglycerin, by mass. Nitroglycerin mixture, 4.1 UN3319 II 4.1...... 118 None......... None...... None...... Forbidden 0.5 kg E ....... desensitized, solid, n.o.s. with more than 2 percent but not more than 10 percent nitroglycerin, by mass. Nitroglycerin, solution in 3 UN3064 II 3........ N8 None......... 202....... None...... Forbidden 5 L E ....... alcohol, with more than 1 percent but not more than 5 percent nitroglycerin. Nitroglycer#
Passage 236in, solution in 1.1D UN0144 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 21E alcohol, with more than 1 percent but not more than 10 percent nitrogylcerin. Nitroglycerin solution in 3 UN1204 II 3........ IB2, N34 150.......... 202....... None...... 5 L 60 L B ....... alcohol with not more than 1 percent nitroglycerin. Nitroguanidine nitrate..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitroguanidine or Picrite, 1.1D UN0282 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... dry or wetted with less than 20 percent water, by mass. Nitroguanidine, wetted or 4.1 UN1336 I 4.1...... 23, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28 Picrite, wetted with not A20, N41 less than 20 percent water, by mass. 1-Nitrohydantoin........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrohydrochloric acid..... 8 UN1798 I 8........ A3, B10, N41, None......... 201....... 243....... Forbidden 2.5 L D 40, 66, T10, TP2, TP12, 74, 89, TP13 90 Nitromannite (dry)......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitromannite, wetted, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Mannitol hexanitrate, etc. Nitromethane............... 3 UN1261 II 3........ ................ 150.......... 202....... None...... Forbidden 60 L A ....... Nitromuriatic acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrohydrochloric acid. Nitronaphthalene........... 4.1 UN2538 III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 4-Nitrophenylhydrazine, 4.1 UN3376 I 4.1...... 164, A8, A19, None......... 211....... None...... Forbidden 15 kg E 36 with not less than 30% A20, N41 water, by mass. + Nitrophenols (o-; m-; p-;). 6.1 UN1663 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 m-Nitrophenyldinitro Forbidden ..........#
Passage 237....... ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... methane. Nitropropanes.............. 3 UN2608 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... p-Nitrosodimethylaniline... 4.2 UN1369 II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg D 34 IP2, N34, T3, TP33 Nitrostarch, dry or wetted 1.1D UN0146 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... with less than 20 percent water, by mass. Nitrostarch, wetted with 4.1 UN1337 I 4.1...... 23, A8, A19, None......... 211....... None...... 1 kg 15 kg D 28 not less than 20 percent A20, N41 water, by mass. Nitrosugars (dry).......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitrosyl chloride.......... 2.3 UN1069 ....... 2.3, 8... 3, B14 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Nitrosylsulfuric acid, 8 UN2308 II 8........ A3, A6, A7, B2, 154.......... 202....... 242....... 1 L 30 L D 40, 66, liquid. IB2, N34, T8, 74, 89, TP2, TP12 90 Nitrosylsulphuric acid, 8 UN3456 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg D 40, 66, solid. T3, TP33 74, 89, 90 Nitrotoluenes, liquid...... 6.1 UN1664 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Nitrotoluenes, solid....... 6.1 UN3446 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Nitrotoluidines (mono)..... 6.1 UN2660 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Nitrotriazolone or NTO..... 1.1D UN0490 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Nitrous oxide and carbon ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dioxide mixtures, see Carbon dioxide and nitrous oxide mixtures. Nitrous oxide.............. 2.2 UN1070 ....... 2.2, 5.1. A14 306.......... 304....... 314, 315.. 75 kg 150 kg A 40 Nitrous oxide, refrigerated 2.2 UN2201 ....... 2.2, 5.1. B6, T75, TP5, None......... 304....... 314, 315.. Forbidden Forbidden B 40 liquid. TP22 Nitroxylenes, liquid....... 6.1 UN1665 II 6.1.#
Passage 238..... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Nitroxylenes, solid........ 6.1 UN3447 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Nitroxylol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitroxylenes. Nonanes.................... 3 UN1920 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Non-flammable gas, n.o.s., ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Compressed gas, etc. or Liquefied gas, etc.#
Passage 239Nonliquefied gases, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Compressed gases, etc. Nonliquefied hydrocarbon ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... gas, see Hydrocarbon gas mixture, compressed, n.o.s.. Nonyltrichlorosilane....... 8 UN1799 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Nordhausen acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sulfuric acid, fuming etc. 2,5-Norbornadiene, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... stabilized, see Bicyclo 2,2,1 hepta-2,5-diene, stabilized. Octadecyltrichlorosilane... 8 UN1800 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Octadiene.................. 3 UN2309 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... 1,7-Octadine-3,5-diyne-1,8- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dimethoxy-9-octadecynoic acid. Octafluorobut-2-ene or 2.2 UN2422 ....... 2.2...... ................ None......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 1318. Octafluorocyclobutane, or 2.2 UN1976 ....... 2.2...... T50 None......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas RC 318. Octafluoropropaneor 2.2 UN2424 ....... 2.2...... T50 None......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 218. Octanes.................... 3 UN1262 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Octogen, etc. see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cyclotetramethylene tetranitramine, etc.. Octolite or Octol, dry or 1.1D UN0266 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... wetted with less than 15 percent water, by mass. Octonal.................... 1.#
Passage 2401D UN0496 ....... 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Octyl aldehydes............ 3 UN1191 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Octyltrichlorosilane....... 8 UN1801 II 8........ A7, B2, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Oil gas, compressed........ 2.3 UN1071 ....... 2.3, 2.1. 6 None......... 304....... 314, 315.. Forbidden 25 kg D 40 Oleum, see Sulfuric acid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... fuming. Organic peroxide type A, Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquid or solid. G Organic peroxide type B, 5.2 UN3101 II 5.2, 1... 53 152.......... 225....... None...... Forbidden Forbidden D 12, 40, liquid. 52, 53 G Organic peroxide type B, 5.2 UN3111 II 5.2, 1... 53 None......... 225....... None...... Forbidden Forbidden D 2, 40, liquid, temperature 52, 53 controlled. G Organic peroxide type B, 5.2 UN3102 II 5.2, 1... 53 152.......... 225....... None...... Forbidden Forbidden D 12, 40, solid. 52, 53 G Organic peroxide type B, 5.2 UN3112 II 5.2, 1... 53 None......... 225....... None...... Forbidden Forbidden D 2, 40, solid, temperature 52, 53 controlled. G Organic peroxide type C, 5.2 UN3103 II 5.2...... ................ 152.......... 225....... None...... 5 L 10 L D 12, 40, liquid. 52, 53 G Organic peroxide type C, 5.2 UN3113 II 5.2...... ................ None......... 225....... None...... Forbidden Forbidden D 2, 40, liquid, temperature 52, 53 controlled. G Organic peroxide type C, 5.2 UN3104 II 5.2...... ................ 152.......... 225....... None...... 5 kg 10 kg D 12, 40, solid. 52, 53 G Organic peroxide type C, 5.2 UN3114 II 5.2...... ................ None......... 225....... None...... Forbidden Forbidden D 2, 40, solid, temperature 52, 53 controlled. G Organic peroxide type D, 5.2 UN3105 II 5.2...... ................ 152.......... 225....... None...... 5 L 10 L D 12, 40, liquid. 52, 53 G Organic peroxide type D, 5.2 UN3115 II 5.2...... ................ None......... 225....... None...... Forbidden Forbidden D 2, 40, liquid, temperature 52, 53 controlled. G Organic peroxide type D, 5.#
Passage 2412 UN3106 II 5.2...... ................ 152.......... 225....... None...... 5 kg 10 kg D 12, 40, solid. 52, 53 G Organic peroxide type D, 5.2 UN3116 II 5.2...... ................ None......... 225....... None...... Forbidden Forbidden D 2, 40, solid, temperature 52, 53 controlled. G Organic peroxide type E, 5.2 UN3107 II 5.2...... ................ 152.......... 225....... None...... 10 L 25 L D 12, 40, liquid. 52, 53 G Organic peroxide type E, 5.2 UN3117 II 5.2...... ................ None......... 225....... None...... Forbidden Forbidden D 2, 40, liquid, temperature 52, 53 controlled. G Organic peroxide type E, 5.2 UN3108 II 5.2...... ................ 152.......... 225....... None...... 10 kg 25 kg D 12, 40, solid. 52, 53 G Organic peroxide type E, 5.2 UN3118 II 5.2...... ................ None......... 225....... None...... Forbidden Forbidden D 2, 40, solid, temperature 52, 53 controlled. G Organic peroxide type F, 5.2 UN3109 II 5.2...... IP5 152.......... 225....... 225....... 10 L 25 L D 12, 40, liquid. 52, 53#
Passage 242G Organic peroxide type F, 5.2 UN3119 II 5.2...... IP5 None......... 225....... 225....... Forbidden Forbidden D 2, 40, liquid, temperature 52, 53 controlled. G Organic peroxide type F, 5.2 UN3110 II 5.2...... TP33 152.......... 225....... 225....... 10 kg 25 kg D 12, 40, solid. 52, 53 G Organic peroxide type F, 5.2 UN3120 II 5.2...... TP33 None......... 225....... 225....... Forbidden Forbidden D 2, 52, solid, temperature 53 controlled. D Organic phosphate, mixed 2.3 NA1955 ....... 2.3...... 3 None......... 334....... None...... Forbidden Forbidden D 40 with compressed gas or Organic phosphate compound, mixed with compressed gas or Organic phosphorus compound, mixed with compressed gas. Organic pigments, self- 4.2 UN3313 II 4.2...... IB8, IP2, IP4, None......... 212....... 241....... 15 kg 50 kg C ....... heating. T3, TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg C ....... TP33 G Organoarsenic compound, 6.1 UN3280 I 6.1...... 5, T14, TP2, None......... 211....... 242....... 5 kg 50 kg B ....... liquid, n.o.s.. TP13, TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 212....... 242....... 25 kg 100 kg B ....... TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP28 G Organoarsenic compound, 6.1 UN3465 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... solid, n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Organochlorine pesticides 3 UN2762 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Organochlorine pesticides, 6.1 UN2996 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... .............#
Passage 243.... II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Organochlorine pesticides, 6.1 UN2995 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP2, TP28 Organochlorine pesticides, 6.1 UN2761 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 G Organometallic compound, 6.1 UN3282 I 6.1...... T14, TP2, TP13, None......... 211....... 242....... 5 kg 50 kg B ....... toxic, liquid, n.o.s.. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 212....... 242....... 25 kg 100 kg B ....... TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP28 G Organometallic compound, 6.1 UN3467 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... toxic, solid, n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 G Organometallic substance, 4.2 UN3392 I 4.2...... B11, T21, TP2, None......... 181....... 244....... Forbidden Forbidden D 143 liquid, pyrophoric. TP7 G Organometallic substance, 4.2 UN3394 I 4.2, 4.3. B11, T21, TP2, None......... 181....... 244....... Forbidden Forbidden D ....... liquid, pyrophoric, water- TP7 reactive. G Organometallic subst#
Passage 244ance, 4.3 UN3398 I 4.3...... T13, TP2, TP7 None......... 201....... 244....... Forbidden Forbidden E 40, 52 liquid, water-reactive. ........................... ........... ................. II 4.3...... IB1, T7, TP2, None......... 202....... 243....... 1 L 5 L E 40, 52 TP7 ........................... ........... ................. III 4.3...... IB2, T7, TP2, None......... 203....... 242....... 5 L 60 L E 40, 52 TP7 G Organometallic substance, 4.3 UN3399 I 4.3, 3... T13, TP2, TP7 None......... 201....... 244....... Forbidden Fobidden E 40, 52 liquid, water-reactive, flammable. ........................... ........... ................. II 4.3, 3... IB1, T7, TP2, None......... 202....... 243....... Forbidden Forbidden E 40, 52 TP7 ........................... ........... ................. III 4.3, 3... IB2, T7, TP2, None......... 203....... 242....... Forbidden Forbidden E 40, 52 TP7 G Organometallic substance, 4.2 UN3391 I 4.2...... T21, TP7, TP33 None......... 181....... 244....... Forbidden Forbidden D ....... solid, pyrophoric. G Organometallic substance, 4.2 UN3393 I 4.2, 4.3. B11, T21, TP7, None......... 181....... 244....... Forbidden Forbidden D 52 solid, pyrophoric, water- TP33 reactive.#
Passage 245G Organometallic substance, 4.2 UN3400 II 4.2...... IB6, T3, TP33 None......... 212....... 242....... 15 kg 50 kg C ....... solid, self-heating. ........................... ........... ................. III 4.2...... IB8, T1, TP33 None......... 203....... 242....... 25 kg 100 kg C ....... G Organometallic substance, 4.3 UN3395 I 4.3...... N40, T9, TP7, None......... 211....... 242....... Forbidden Forbidden E 40, 52 solid, water-reactive. TP33 ........................... ........... ................. II 4.3...... IB4, T3, TP33 151.......... 212....... 242....... 15 kg 50 kg E 40, 52 ........................... ........... ................. III 4.3...... IB6, T1, TP33 151.......... 213....... 241....... 25 kg 100 kg E 40, 52 G Organometallic substance, 4.3 UN3396 I 4.3, 4.1. N40, T9, TP7, None......... 211....... 242....... Forbidden Forbidden E 40, 52 solid, water-reactive, TP33 flammable. ........................... ........... ................. II 4.3, 4.1. IB4, T3, TP33 151.......... 212....... 242....... 15 kg 50 kg E 40, 52 ........................... ........... ................. III 4.3, 4.1. IB6, T1, TP33 151.......... 213....... 241....... 25 kg 100 kg E 40, 52 G Organometallic substance, 4.3 UN3397 I 4.3, 4.2. N40, T9, TP7, None......... 211....... 242....... Forbidden Forbidden E 40, 52 solid, water-reactive, TP33 self-heating. ........................... ........... ................. II 4.3, 4.2. IB4, T3, TP33 None......... 212....... 242....... 15 kg 50 kg E 40, 52 ........................... ........... ................. III 4.3, 4.2. IB6, T1, TP33 None......... 213....... 241....... 25 kg 100 kg E 40, 52 Organophosphorus compound, 6.1 UN3279 I 6.1, 3... 5, T14, TP2, None......... 201....... 243....... 1 L 30 L B 40 toxic, flammable, n.o.s.. TP13, TP27 ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 G Organophosphorus compound, 6.1 UN3278 I 6.1...... 5, T14, TP2, None......... 201....... 243....... 1 L 30 L B ....... toxic, liquid, n.o.s.. TP13, TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B ....... TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A ....... TP28 G Organo#
Passage 246phosphorus compound, 6.1 UN3464 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... toxic, solid, n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Organophosphorus 3 UN2784 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Organophosphorus 6.1 UN3018 I 6.1...... N76, T14, TP2, None......... 201....... 243....... 1 L 30 L B 40 pesticides, liquid, toxic. TP13, TP27 ........................... ........... ................. II 6.1...... IB2, N76, T11, 153.......... 202....... 243....... 5 L 60 L B 40 TP2, TP13, TP27 ........................... ........... ................. III 6.1...... IB3, N76, T7, 153.......... 203....... 241....... 60 L 220 L A 40 TP2, TP28 Organophosphorus 6.1 UN3017 I 6.1, 3... N76, T14, TP2, None......... 201....... 243....... 1 L 30 L B 40 pesticides, liquid, toxic, TP13, TP27 flammable, flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, N76, T11, 153.......... 202....... 243....... 5 L 60 L B 40 TP2, TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, N76, 153.......... 203....... 242....... 60 L 220 L A 40 T7, TP2, TP28 Organophosphorus 6.1 UN2783 I 6.1...... IB7, IP1, N77, None......... 211....... 242....... 5 kg 50 kg A 40 pesticides, solid, toxic. T6, TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 N77, T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, N77, 153.......... 213....... 240....... 100 kg 200 kg A 40 T1, TP33 Organotin compounds, 6.1 UN2788 I 6.1...... A3, N33, N34, None......... 201....... 243....... 1 L 30 L B 40 liquid, n.o.s.. T14, TP2, TP13, TP27 ........................... ........... ................. II 6.1...... A3, IB2, N33,#
Passage 247153.......... 202....... 243....... 5 L 60 L A 40 N34, T11, TP2, TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28#
Passage 248Organotin compounds, solid, 6.1 UN3146 I 6.1...... A5, IB7, IP1, None......... 211....... 242....... 5 kg 50 kg B 40 n.o.s.. T6, TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Organotin pesticides, 3 UN2787 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Organotin pesticides, 6.1 UN3020 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Organotin pesticides, 6.1 UN3019 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP2, TP28 Organotin pesticides, 6.1 UN2786 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Orthonitroaniline, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitroanilines etc. Osmium tetroxide........... 6.1 UN2471 I 6.1...... A8, IB7, IP1, None......... 211....... 242....... 5 kg 50 kg B 40 N33, N34, T6, TP3#
Passage 2493 D G Other regulated substances, 9 NA3082 III 9........ IB3, T2, TP1 155.......... 203....... 241....... No limit No limit A ....... liquid, n.o.s.. D G Other regulated substances, 9 NA3077 III 9........ B54, IB8, IP2, 155.......... 213....... 240....... No limit No limit A ....... solid, n.o.s.. T1, TP33 G Oxidizing liquid, 5.1 UN3098 I 5.1, 8... A6 None......... 201....... 244....... Forbidden 2.5 L D 13, 56, corrosive, n.o.s.. 58, 106, 138 ........................... ........... ................. II 5.1, 8... IB1 None......... 202....... 243....... 1 L 5 L B 34, 56, 58, 106, 138 ........................... ........... ................. III 5.1, 8... IB2 152.......... 203....... 242....... 2.5 L 30 L B 34, 56, 58, 106, 138 G Oxidizing liquid, n.o.s.... 5.1 UN3139 I 5.1...... 127, A2, A6 None......... 201....... 243....... Forbidden 2.5 L D 56, 58, 106, 138 ........................... ........... ................. II 5.1...... 127, A2, IB2 152.......... 202....... 242....... 1 L 5 L B 56, 58, 106, 138 ........................... ........... ................. III 5.1...... 127, A2, IB2 152.......... 203....... 241....... 2.5 L 30 L B 56, 58, 106, 138 G Oxidizing liquid, toxic, 5.1 UN3099 I 5.1, 6.1. A6 None......... 201....... 244....... Forbidden 2.5 L D 56, 58, n.o.s.. 106, 138 ........................... ........... ................. II 5.1, 6.1. IB1 152.......... 202....... 243....... 1 L 5 L B 56, 58, 95, 106, 138 ........................... ........... ................. III 5.1, 6.1. IB2 152.......... 203....... 242....... 2.5 L 30 L B 56, 58, 95, 106, 138 G Oxidizing solid, corrosive, 5.1 UN3085 I 5.1, 8... ................ None......... 211....... 242....... 1 kg 15 kg D 13, 56, n.o.s.. 58, 106, 138 ........................... ........... ................. II 5.1, 8... IB6, IP2, T3, None......... 212....... 242....... 5 kg 25 kg B 13, 34, TP33 56, 58, 106, 138#
Passage 250........................... ........... ................. III 5.1, 8... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg B 13, 34, TP33 56, 58, 106, 138 G Oxidizing solid, flammable, 5.1 UN3137 I 5.1, 4.1. ................ None......... 214....... 214....... Forbidden Forbidden .......... ....... n.o.s.. G Oxidizing solid, n.o.s..... 5.1 UN1479 I 5.1...... IB5, IP1 None......... 211....... 242....... 1 kg 15 kg D 56, 58, 106, 138 ........................... ........... ................. II 5.1...... IB8, IP2, IP4, 152.......... 212....... 240....... 5 kg 25 kg B 56, 58, T3, TP33 106, 138 ........................... ........... ................. III 5.1...... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg B 56, 58, TP33 106, 138 G Oxidizing solid, self- 5.1 UN3100 I 5.1, 4.2. ................ None......... 214....... 214....... Forbidden Forbidden .......... ....... heating, n.o.s.. ........................... ........... ................. II 5.1, 4.2. ................ None......... 214....... 214....... Forbidden Forbidden .......... ....... G Oxidizing solid, toxic, 5.1 UN3087 I 5.1, 6.1. ................ None......... 211....... 242....... 1 kg 15 kg D 56, 58, n.o.s.. 106, 138 ........................... ........... ................. II 5.1, 6.1. IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg B 56, 58, TP33 95, 106, 138 ........................... ........... ................. III 5.1, 6.1. IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg B 56, 58, TP33 95, 106, 138 G Oxidizing solid, water- 5.1 UN3121 ....... 5.1, 4.3. ................ None......... 214....... 214....... Forbidden Forbidden .......... ....... reactive, n.o.s.. Oxygen and carbon dioxide ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures, see Carbon dioxide and oxygen mixtures. Oxygen, compressed......... 2.2 UN1072 ....... 2.2, 5.1. A14, A52 306.......... 302....... 314, 315.. 75 kg 150 kg A ....... Oxygen difluoride, 2.3 UN2190 ....... 2.3, 5.1, 1 None......... 304....... None...... Forbidden Forbidden D 13, 40, compressed. 8. 89, 90 Oxygen generator, chemical 5.1 UN3356 II 5.1...... 60, A51 None......... 212....... None...... Forbidden 25 kg gross D 56, 58, (including when contained 69, 106 in associated equipment, e.g., passenger#
Passage 251service units (PSUs), portable breathing equipment (PBE), etc).. + Oxygen generator, chemical, 9 NA3356 III 9........ 61 None......... 213....... None...... Forbidden Forbidden A ....... spent. Oxygen, mixtures with rare ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... gases, see Rare gases and oxygen mixtures. Oxygen, refrigerated liquid 2.2 UN1073 ....... 2.2, 5.1. T75, TP5, TP22 320.......... 316....... 318....... Forbidden Forbidden D ....... (cryogenic liquid). Paint including paint, 3 UN1263 I 3........ T11, TP1, TP8 150.......... 201....... 243....... 1 L 30 L E ....... lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base. ........................... ........... ................. II 3........ 149, B52, IB2, 150.......... 173....... 242....... 5 L 60 L B ....... T4, TP1, TP8 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 173....... 242....... 60 L 220 L A ....... T2, TP1 Paint or Paint related 8 UN3066 II 8........ B2, IB2, T7, TP2 154.......... 173....... 242....... 1 L 30 L A ....... material. ........................... ........... ................. III 8........ B52, IB3, T4, 154.......... 173....... 241....... 5 L 60 L A ....... TP1 Paint related material 3 UN1263 I 3........ T11, TP1, TP8 150.......... 201....... 243....... 1 L 30 L E ....... including paint thinning, drying, removing, or reducing compound. ........................... ........... ................. II 3........ 149, B52, IB2, 150.......... 173....... 242....... 5 L 60 L B ....... T4, TP1, TP8 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 173....... 242....... 60 L 220 L A ....... T2, TP1 Paper, unsaturated oil 4.2 UN1379 III 4.2...... IB8, IP3 None......... 213....... 241....... Forbidden Forbidden A ....... treated incompletely dried (including carbon paper). Paraformaldehyde........... 4.1 UN2213 III 4.1...... A1, IB8, IP3, 151.......... 213....... 240....... 25 kg 100 kg A ....... T1, TP33 Paraldehyde................ 3 UN1264 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Paranitroaniline, solid, ........... ................. ....... ......... ................ ............. .......... ........#
Passage 252.. ........... ........... .......... ....... see Nitroanilines etc. D Parathion and compressed 2.3 NA1967 ....... 2.3...... 3 None......... 334....... 245....... Forbidden Forbidden E 40 gas mixture. Paris green, solid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Copper acetoarsenite.#
Passage 253A W PCB, see Polychlorinated ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... biphenyls. + Pentaborane................ 4.2 UN1380 I 4.2, 6.1. 1 None......... 205....... 245....... Forbidden Forbidden D ....... Pentachloroethane.......... 6.1 UN1669 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 Pentachlorophenol.......... 6.1 UN3155 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Pentaerythrite tetranitrate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... (dry). Pentaerythrite tetranitrate 4.1 UN3344 II 4.1...... 118, N85 None......... 214....... None...... Forbidden Forbidden E ....... mixture, desensitized, solid, n.o.s. with more than 10 percent but not more than 20 percent PETN, by mass. Pentaerythrite tetranitrate 1.1D UN0411 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... or Pentaerythritol tetranitrate or PETN, with not less than 7 percent wax by mass. Pentaerythrite 1.1D UN0150 II 1.1D..... 121 None......... 62........ None...... Forbidden Forbidden 10 ....... tetranitrate, wetted or Pentaerythritol tetranitrate, wetted, or PETN, wetted with not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pentaerythritol tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass. Pentaerythritol ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tetranitrate, see Pentaerythrite tetranitrate, etc. Pentafluoroethane or 2.2 UN3220 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 125. Pentamethylheptane......... 3 UN2286 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Pentane-2,4-dione.......... 3 UN2310 III 3, 6.1... B1, IB3, T4, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Pentanes................... 3 UN1265 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E ....... ........................... ........... ................. II 3........ IB2, IP8, T4, 150.......... 202....... 242....... 5 L 60 L#
Passage 254E ....... TP1 Pentanitroaniline (dry).... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Pentanols.................. 3 UN1105 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP29 ........................... ........... ................. III 3........ B1, B3, IB3, T2, 150.......... 203....... 242....... 60 L 220 L A ....... TP1 1-Pentene (n-amylene)...... 3 UN1108 I 3........ T11, TP2 150.......... 201....... 243....... 1 L 30 L E ....... 1-Pentol................... 8 UN2705 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L B 26, 27 Pentolite, dry or wetted 1.1D UN0151 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... with less than 15 percent water, by mass. Pepper spray, see Aerosols, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... etc. or Self-defense spray, non-pressurized. Perchlorates, inorganic, 5.1 UN3211 II 5.1...... IB2, T4, TP1 152.......... 202....... 242....... 1 L 5 L B 56, 58, aqueous solution, n.o.s.. 133 ........................... ........... ................. III 5.1...... IB2, T4, TP1 152.......... 202....... 241....... 2.5 L 30 L B 56, 58, 69, 133 Perchlorates, inorganic, 5.1 UN1481 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 n.o.s.. TP33 ........................... ........... ................. III 5.1...... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 TP33 Perchloric acid, with more Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... than 72 percent acid by mass. Perchloric acid with more 5.1 UN1873 I 5.1, 8... A2, A3, N41, None......... 201....... 243....... Forbidden 2.5 L D 66 than 50 percent but not T10, TP1, TP12 more than 72 percent acid, by mass. Perchloric acid with not 8 UN1802 II 8, 5.1... IB2, N41, T7, None......... 202....... 243....... Forbidden 30 L C 66 more than 50 percent acid TP2 by mass. Perchloroethylene, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetrachloroethylene. P#
Passage 255erchloromethyl mercaptan.. 6.1 UN1670 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, N34, T20, TP2, TP13, TP38, TP45 Perchloryl fluoride........ 2.3 UN3083 ....... 2.3, 5.1. 2, B9, B14 None......... 302....... 314, 315.. Forbidden Forbidden D 40 Percussion caps, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Primers, cap type. Perfluoro-2-butene, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Octafluorobut-2-ene. Perfluoro(ethyl vinyl 2.1 UN3154 ....... 2.1...... ................ 306.......... 302, 304, 314, 315.. Forbidden 150 kg E 40 ether). 305. Perfluoro(methyl vinyl 2.1 UN3153 ....... 2.1...... T50 306.......... 302, 304, 314, 315.. Forbidden 150 kg E 40 ether). 305. Perfumery products with 3 UN1266 II 3........ 149, IB2, T4, 150.......... 202....... 242....... 15 L 60 L B ....... flammable solvents. TP1, TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Permanganates, inorganic, 5.1 UN3214 II 5.1...... 26, IB2, T4, TP1 152.......... 202....... 242....... 1 L 5 L D 56, 58, aqueous solution, n.o.s.. 133, 138 Permanganates, inorganic, 5.1 UN1482 II 5.1...... 26, A30, IB6, 152.......... 212....... 242....... 5 kg 25 kg D 56, 58, n.o.s.. IP2, T3, TP33 138 ........................... ........... ................. III 5.1...... 26, A30, IB8, 152.......... 213....... 240....... 25 kg 100 kg D 56, 58, IP3, T1, TP33 138 Peroxides, inorganic, 5.1 UN1483 II 5.1...... A7, A20, IB6, None......... 212....... 242....... 5 kg 25 kg A 13, 52, n.o.s.. IP2, N34, T3, 66, 75 TP33 ........................... ........... ................. III 5.1...... A7, A20, IB8, 152.......... 213....... 240....... 25 kg 100 kg A 13, 52, IP3, N34, T1, 66, 75 TP33 Peroxyacetic acid, with Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... more than 43 percent and with more than 6 percent hydrogen peroxide.#
Passage 256Persulfates, inorganic, 5.1 UN3216 III 5.1...... IB2, T4, TP1, 152.......... 203....... 241....... 2.5 L 30 L A 56, 133 aqueous solution, n.o.s.. TP29 Persulfates, inorganic, 5.1 UN3215 III 5.1...... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 n.o.s.. TP33 G Pesticides, liquid, 3 UN3021 I 3, 6.1... B5, T14, TP2, None......... 201....... 243....... Forbidden 30 L B ....... flammable, toxic, flash TP13, TP27 point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B ....... TP13, TP27 G Pesticides, liquid, toxic, 6.1 UN2903 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 flammable, n.o.s. flash TP27 point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, TP2 153.......... 203....... 242....... 60 L 220 L A 40 G Pesticides, liquid, toxic, 6.1 UN2902 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 n.o.s.. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 G Pesticides, solid, toxic, 6.1 UN2588 I 6.1...... IB7, T6, TP33 None......... 211....... 242....... 5 kg 50 kg A 40 n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 PETN, see Pentaerythrite ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tetranitrate. PETN/TNT, see Pentolite, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... etc. Petrol, see Gasoline....... ........... ................. ....... ......... ................ ............. ......#
Passage 257.... .......... ........... ........... .......... ....... Petroleum crude oil........ 3 UN1267 I 3........ 144, T11, TP1, 150.......... 201....... 243....... 1 L 30 L E ....... TP8 ........................... ........... ................. II 3........ 144, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T2, TP1 Petroleum distillates, 3 UN1268 I 3........ 144, T11, TP1, 150.......... 201....... 243....... 1 L 30 L E ....... n.o.s. or Petroleum TP8 products, n.o.s.. ........................... ........... ................. II 3........ 144, IB2, T7, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8, TP28 ........................... ........... ................. III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 Petroleum gases, liquefied 2.1 UN1075 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 or Liquefied petroleum gas. D Petroleum oil.............. 3 NA1270 I 3........ 144, T11, TP1 None......... 201....... 243....... 1 L 30 L E ....... ........................... ........... ................. II 3........ 144, IB2, T7, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8, TP28 ........................... ........... ................. III 3........ 144, B1, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T4, TP1, TP29 Phenacyl bromide........... 6.1 UN2645 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B 40 T3, TP33 + Phenetidines............... 6.1 UN2311 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Phenol, molten............. 6.1 UN2312 II 6.1...... B14, T7, TP3 None......... 202....... 243....... Forbidden Forbidden B 40 + Phenol, solid.............. 6.1 UN1671 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... N78, T3, TP33 Phenol solutions........... 6.1 UN2821 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... ........................... ........... ................. III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Phenolsulfonic acid, liquid 8 UN1803 II 8........ B2, IB2, N41, 154.......... 202......#
Passage 258. 242....... 1 L 30 L C 14 T7, TP2 Phenoxyacetic acid 3 UN3346 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 derivative pesticide, TP27 liquid, flammable, toxic flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Phenoxyacetic acid 6.1 UN3348 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 derivative pesticide, TP27 liquid, toxic. ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP27#
Passage 259........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Phenoxyacetic acid 6.1 UN3347 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 derivative pesticide, TP27 liquid, toxic, flammable, flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Phenoxyacetic acid 6.1 UN3345 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 derivative pesticide, TP33 solid, toxic. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Phenyl chloroformate....... 6.1 UN2746 II 6.1, 8... IB2, T7, TP2, 153.......... 202....... 243....... 1 L 30 L A 12, 13, TP13 21, 25, 40, 100 Phenyl isocyanate.......... 6.1 UN2487 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, B77, N33, N34, T20, TP2, TP13, TP38, TP45 Phenyl mercaptan........... 6.1 UN2337 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 40, 52 B74, B77, T20, TP2, TP13, TP38, TP45 Phenyl phosphorus 8 UN2798 II 8........ B2, B15, IB2, 154.......... 202....... 242....... Forbidden 30 L B 40 dichloride. T7, TP2 Phenyl phosphorus 8 UN2799 II 8........ B2, B15, IB2, 154.......... 202....... 242....... Forbidden 30 L B 40 thiodichloride. T7, TP2 Phenylacetonitrile, liquid. 6.1 UN2470 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 52 Phenylacetyl chloride...... 8 UN2577 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L C 40 Phenylcarbylamine chloride. 6.1 UN1672 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, T20, TP2, TP13, TP38, TP45 m-Phenylene Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diaminediperchlorate#
Passage 260(dry). + Phenylenediamines (o-; m-; 6.1 UN1673 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... p-;). TP33 Phenylhydrazine............ 6.1 UN2572 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 Phenylmercuric acetate..... 6.1 UN1674 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Phenylmercuric compounds, 6.1 UN2026 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A ....... n.o.s.. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Phenylmercuric hydroxide... 6.1 UN1894 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Phenylmercuric nitrate..... 6.1 UN1895 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Phenyltrichlorosilane...... 8 UN1804 II 8........ A7, B6, IB2, None......... 202....... 242....... Forbidden 30 L C 40 N34, T7, TP2 Phosgene................... 2.3 UN1076 ....... 2.3, 8... 1, B7, B46 None......... 192....... 314....... Forbidden Forbidden D 40 9-Phosphabicyclononanes or 4.2 UN2940 II 4.2...... A19, IB6, IP2, None......... 212....... 241....... 15 kg 50 kg A ....... Cyclooctadiene phosphines. T3, TP33 Phosphine.................. 2.3 UN2199 ....... 2.3, 2.1. 1 None......... 192....... 245....... Forbidden Forbidden D 40 Phosphoric acid solution... 8 UN1805 III 8........ A7, IB3, N34, 154.......... 203....... 241....... 5 L 60 L A ....... T4, TP1 Phosphoric acid, solid..... 8 UN3453 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Phosphoric acid ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... triethyleneimine, see Tris- (1-aziridiyl)phosphine oxide, solution. Phosphoric anhydride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosphorus pentoxide. Phosphorous acid........... 8 UN2834 III 8........ IB8, IP3, T1, 154.........#
Passage 261. 213....... 240....... 25 kg 100 kg A 48 TP33 Phosphorus, amorphous...... 4.1 UN1338 III 4.1...... A1, A19, B1, B9, None......... 213....... 243....... 25 kg 100 kg A 74 B26, IB8, IP3, T1, TP33 Phosphorus bromide, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosphorus tribromide. Phosphorus chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosphorus trichloride. Phosphorus heptasulfide, 4.1 UN1339 II 4.1...... A20, IB4, N34, None......... 212....... 240....... 15 kg 50 kg B 74 free from yellow or white T3, TP33 phosphorus.#
Passage 262Phosphorus oxybromide...... 8 UN1939 II 8........ B8, IB8, IP2, None......... 212....... 240....... Forbidden 50 kg C 12, 40 IP4, N41, N43, T3, TP33 Phosphorus oxybromide, 8 UN2576 II 8........ B2, B8, IB1, None......... 202....... 242....... Forbidden Forbidden C 40 molten. N41, N43, T7, TP3, TP13 + Phosphorus oxychloride..... 8 UN1810 II 8, 6.1... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden C 40 B74, B77, N34, T20, TP2, TP38, TP45 Phosphorus pentabromide.... 8 UN2691 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... Forbidden 50 kg B 12, 40, IP4, N34, T3, 53, 55 TP33 Phosphorus pentachloride... 8 UN1806 II 8........ A7, IB8, IP2, None......... 212....... 240....... Forbidden 50 kg C 40, 44, IP4, N34, T3, 89, TP33 100, 141 Phosphorus................. 2.3 UN2198 ....... 2.3, 8... 2, B9, B14 None......... 302, 304.. 314, 315.. Forbidden Forbidden D 40 Phosphorus pentasulfide, 4.3 UN1340 II 4.3, 4.1. A20, B59, IB4, 151.......... 212....... 242....... 15 kg 50 kg B 74 free from yellow or white T3, TP33 phosphorus. Phosphorus pentoxide....... 8 UN1807 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A ....... IP4, N34, T3, TP33 Phosphorus sesquisulfide, 4.1 UN1341 II 4.1...... A20, IB4, N34, None......... 212....... 240....... 15 kg 50 kg B 74 free from yellow or white T3, TP33 phosphorus. Phosphorus tribromide...... 8 UN1808 II 8........ A3, A6, A7, B2, None......... 202....... 242....... Forbidden 30 L C 40 B25, IB2, N34, N43, T7, TP2 Phosphorus trichloride..... 6.1 UN1809 I 6.1, 8... 2, B9, B14, B15, None......... 227....... 244....... Forbidden Forbidden C 40 B32, B74, B77, N34, T20, TP2, TP13, TP38, TP45 Phosphorus trioxide........ 8 UN2578 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 12 TP33 Phosphorus trisulfide, free 4.1 UN1343 II 4.1...... A20, IB4, N34, None......... 212....... 240....... 15 kg 50 kg B 74 from yellow or white T3, TP33 phosphorus. Phosphorus, white dry or 4.2 UN1381 I 4.2, 6.1. B9, B26, N34, None......... 188....... 243....... Forbidden Forbidden E ....... Phosphorus, white, under T9, TP3, TP31 water or Phosphorus white, in solution or Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution. Phosphorus white, molten... 4.2 UN2447 I 4.2, 6.1. B9, B26, N34, None......... 188....... 243....... Forbidden#
Passage 263Forbidden D ....... T21, TP3, TP7, TP26 Phosphorus (white or red) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... and a chlorate, mixtures of. Phosphoryl chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosphorus oxychloride. Phthalic anhydride with 8 UN2214 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... more than .05 percent TP33 maleic anhydride. Picolines.................. 3 UN2313 III 3........ B1, IB3, T4, TP1 150.......... 203....... 242....... 60 L 220 L A 40 Picric acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitrophenol, etc. Picrite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Nitroguanidine, etc. Picryl chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitrochlorobenzene. Pine oil................... 3 UN1272 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... alpha-Pinene............... 3 UN2368 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Piperazine................. 8 UN2579 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 12, 52 TP33 Piperidine................. 8 UN2401 I 8, 3..... A10, T10, TP2 None......... 201....... 243....... 0.5 L 2.5 L B 52 Pivaloyl chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trimethylacetyl chloride. Plastic molding compound in 9 UN3314 III 9........ 32, IB8, IP3, 155.......... 221....... 221....... 100 kg 200 kg A 85, 87 dough, sheet or extruded IP7 rope form evolving flammable vapor. Plastic solvent, n.o.s., ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Flammable liquids, n.o.s.. Plastics, nitrocellulose- 4.2 UN2006 III 4.2...... .........#
Passage 264....... None......... 213....... None...... Forbidden Forbidden C ....... based, self-heating, n.o.s.. Poisonous gases, n.o.s., ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Compressed or liquefied gases, flammable or toxic, n.o.s.. Polyalkylamines, n.o.s., ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Amines, etc. Polychlorinated biphenyls, 9 UN2315 II 9........ 9, 81, 140, IB3, 155.......... 202....... 241....... 100 L 220 L A 95 liquid. T4, TP1 Polychlorinated biphenyls, 9 UN3432 II 9........ 9, 81, 140, IB8, 155.......... 212....... 240....... 100 kg 200 kg A 95 solid. T3, TP33#
Passage 265Polyester resin kit........ 3 UN3269 ....... 3........ 40, 149 152.......... 225....... None...... 5 kg 5 kg B ....... Polyhalogenated biphenyls, 9 UN3151 II 9........ IB2 155.......... 204....... 241....... 100 L 220 L A 95 liquid or Polyhalogenated terphenyls liquid. Polyhalogenated biphenyls, 9 UN3152 II 9........ IB8, IP2, IP4, 155.......... 204....... 241....... 100 kg 200 kg A 95 solid or Polyhalogenated T3, TP33 terphenyls, solid. Polymeric beads, 9 UN2211 III 9........ 32, IB8, IP3, 155.......... 221....... 221....... 100 kg 200 kg A 85, 87 expandable, evolving IP7, T1, TP33 flammable vapor. Potassium.................. 4.3 UN2257 I 4.3...... A7, A19, A20, None......... 211....... 244....... Forbidden 15 kg D 52 B27, IB4, IP1, N6, N34, T9, TP7, TP33 Potassium arsenate......... 6.1 UN1677 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Potassium arsenite......... 6.1 UN1678 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Potassium bisulfite ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Bisulfites, aqueous solutions, n.o.s.. Potassium borohydride...... 4.3 UN1870 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E 52 Potassium bromate.......... 5.1 UN1484 II 5.1...... IB8, IP4, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Potassium carbonyl......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Potassium chlorate......... 5.1 UN1485 II 5.1...... A9, IB8, IP4, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 N34, T3, TP33 Potassium chlorate, aqueous 5.1 UN2427 II 5.1...... A2, IB2, T4, TP1 152.......... 202....... 241....... 1 L 5 L B 56, 58, solution. 133 ........................... ........... ................. III 5.1...... A2, IB2, T4, TP1 152.......... 203....... 241....... 2.5 L 30 L B 56, 58, 69, 133 Potassium chlorate mixed ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... with mineral oil, see Explosive, blasting, type C. Potassium cuprocyanide..... 6.1 UN1679 II 6.1...... IB8, IP2, IP4, 153.......... 212.#
Passage 266...... 242....... 25 kg 100 kg A 52 T3, TP33 Potassium cyanide, solid... 6.1 UN1680 I 6.1...... B69, B77, IB7, None......... 211....... 242....... 5 kg 50 kg B 52 IP1, N74, N75, T6, TP33 Potassium cyanide solution. 6.1 UN3413 I 6.1...... B69, B77, N74, None......... 201....... 243....... 1 L 30 L B 52 N75, T14, TP2, TP13 ........................... ........... ................. II 6.1...... B69, B77, IB2, 153.......... 202....... 243....... 5 L 60 L B 52 N74, N75, T11, TP2, TP13, TP27 ........................... ........... ................. III 6.1...... B69, B77, IB3, 153.......... 203....... 241....... 60 L 220 L A 52 N74, N75, T7, TP2, TP13, TP28 Potassium dichloro ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... isocyanurate or Potassium dichloro-s-triazinetrione, see Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts etc. Potassium dithionite or 4.2 UN1929 II 4.2...... A8, A19, A20, None......... 212....... 241....... 15 kg 50 kg E 13 Potassium hydrosulfite. IB6, IP2, T3, TP33 Potassium fluoride, solid.. 6.1 UN1812 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Potassium fluoride solution 6.1 UN3422 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 52 Potassium fluoroacetate.... 6.1 UN2628 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg E ....... TP33 Potassium fluorosilicate... 6.1 UN2655 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Potassium hydrate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Potassium hydroxide, solid. Potassium hydrogen ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... fluoride, see Potassium hydrogen difluoride. Potassium hydrogen fluoride ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Corrosive liquid, n.o.s.. Potassium hydrogen sulfate. 8 UN2509 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A ....... IP4, N34, T3, TP33 Potassium 8 UN1811 II 8, 6.1... IB8, IP#
Passage 2672, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 25, 40, hydrogendifluoride solid. N3, N34, T3, 52 TP33 Potassium 8 UN3421 II 8, 6.1... IB2, N3, N34, 154.......... 202....... 243....... 1 L 30 L A 25, 40, hydrogendifluoride T7, TP2 52 solution. ........................... ........... ................. III 8, 6.1... IB3, N3, N34, 154.......... 203....... 241....... 5 L 60 L A 40, 52 T4, TP1 Potassium hydrosulfite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Potassium dithionite. Potassium hydroxide, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquid, see Potassium hydroxide solution. Potassium hydroxide, solid. 8 UN1813 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... T3, TP33 Potassium hydroxide, 8 UN1814 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A ....... solution. ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Potassium hypochlorite, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Hypochlorite solutions, etc. Potassium, metal alloys, 4.3 UN1420 I 4.3...... A7, A19, A20, None......... 201....... 244....... Forbidden 1 L E 40, 52 liquid. B27#
Passage 268Potassium, metal alloys, 4.3 UN3404 I 4.3...... A19, A20, B27, None......... 211....... 244....... Forbidden 15 kg D ....... solid. IB4, IP1, T9, TP7, TP33 Potassium metal, liquid ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... alloy, see Alkali metal alloys, liquid, n.o.s.. Potassium metavanadate..... 6.1 UN2864 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Potassium monoxide......... 8 UN2033 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 29 T3, TP33 Potassium nitrate.......... 5.1 UN1486 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Potassium nitrate and 5.1 UN1487 II 5.1...... B78, IB8, IP4, 152.......... 212....... 240....... 5 kg 25 kg A 56, 58 sodium nitrite mixtures. T3, TP33 Potassium nitrite.......... 5.1 UN1488 II 5.1...... IB8, IP4, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Potassium perchlorate...... 5.1 UN1489 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Potassium permanganate..... 5.1 UN1490 II 5.1...... IB8, IP4, T3, 152.......... 212....... 240....... 5 kg 25 kg D 56, 58, TP33 138 Potassium peroxide......... 5.1 UN1491 I 5.1...... A20, IB6, IP1, None......... 211....... None...... Forbidden 15 kg B 13, 52, N34 66, 75 Potassium persulfate....... 5.1 UN1492 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 IP3, T1, TP33 Potassium phosphide........ 4.3 UN2012 I 4.3, 6.1. A19, N40 None......... 211....... None...... Forbidden 15 kg E 40, 52, 85 Potassium selenate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Potassium selenite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Potassium sodium alloys, 4.3 UN3403 I 4.3...... A19, B27, N34, None......... 211....... 244....... Forbidden 15 kg D 52 solid. N40, T9, TP7, TP33 Potassium sodium alloys, 4.3 UN3404 I 4.3...... A19, B27, N34, None......... 211....... 244....... Forbidden 15 kg D 52 solid. N40, T9, TP7, TP33 Potassium#
Passage 269sodium alloys, 4.3 UN1422 I 4.3...... A7, A19, B27, None......... 201....... 244....... Forbidden 1 L E 40, 52 liquid. N34, N40, T9, TP3, TP7, TP31 Potassium sulfide, 4.2 UN1382 II 4.2...... A19, A20, B16, None......... 212....... 241....... 15 kg 50 kg A 52 anhydrous or Potassium IB6, IP2, N34, sulfide with less than 30 T3, TP33 percent water of crystallization. Potassium sulfide, hydrated 8 UN1847 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 52 with not less than 30 T3, TP33 percent water of crystallization. Potassium superoxide....... 5.1 UN2466 I 5.1...... A20, IB6, IP1 None......... 211....... None...... Forbidden 15 kg B 13, 52, 66, 75 Powder cake, wetted or 1.1C UN0433 II 1.1C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Powder paste, wetted with not less than 17 percent alcohol by mass. Powder cake, wetted or 1.3C UN0159 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Powder paste, wetted with not less than 25 percent water, by mass. Powder paste, see Powder ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... cake, etc. Powder, smokeless.......... 1.1C UN0160 II 1.1C..... ................ None......... 62........ None...... Forbidden Forbidden .......... 26E Powder, smokeless.......... 1.3C UN0161 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden .......... 26E Power device, explosive, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Cartridges, power device. Primers, cap type.......... 1.4S UN0044 II None..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Primers, cap type.......... 1.1B UN0377 II 1.1B..... ................ None......... 62........ None...... Forbidden Forbidden 11 ....... Primers, cap type.......... 1.4B UN0378 II 1.4B..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Primers, small arms, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Primers, cap type. Primers, tubular........... 1.3G UN0319 II 1.3G..... ................#
Passage 270None......... 62........ None...... Forbidden Forbidden 07 ....... Primers, tubular........... 1.4G UN0320 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Primers, tubular........... 1.4S UN0376 II None..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Printing ink, flammable or 3 UN1210 I 3........ T11, TP1, TP8 150.......... 173....... 243....... 1 L 30 L E ....... Printing ink related material (including printing ink thinning or reducing compound), flammable. ........................... ........... ................. II 3........ 149, IB2, T4, 150.......... 173....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 173....... 242....... 60 L 220 L A ....... Projectiles, illuminating, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Ammunition, illuminating, etc. Projectiles, inert with 1.4S UN0345 II 1.4S..... ................ ............. 62........ None...... 25 kg 100 kg 01 ....... tracer. Projectiles, inert, with 1.3G UN0424 II 1.3G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... tracer. Projectiles, inert, with 1.4G UN0425 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... tracer. Projectiles, with burster 1.2D UN0346 II 1.2D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... or expelling charge.#
Passage 271Projectiles, with burster 1.4D UN0347 II 1.4D..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... or expelling charge. Projectiles, with burster 1.2F UN0426 II 1.2F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... or expelling charge. Projectiles, with burster 1.4F UN0427 II 1.4F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... or expelling charge. Projectiles, with burster 1.2G UN0434 II 1.2G..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... or expelling charge. Projectiles, with burster 1.4G UN0435 II 1.4G..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... or expelling charge. Projectiles, with bursting 1.1F UN0167 II 1.1F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... charge. Projectiles, with bursting 1.1D UN0168 II 1.1D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... charge. Projectiles, with bursting 1.2D UN0169 II 1.2D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... charge. Projectiles, with bursting 1.2F UN0324 II 1.2F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... charge. Projectiles, with bursting 1.4D UN0344 II 1.4D..... ................ ............. 62........ None...... Forbidden 75 kg 02 ....... charge. Propadiene, stabilized..... 2.1 UN2200 ....... 2.1...... ................ None......... 304....... 314, 315.. Forbidden 150 kg B 40 Propadiene mixed with ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... methyl acetylene, see Methyl acetylene and propadiene mixtures, stabilized. Propane see also Petroleum 2.1 UN1978 ....... 2.1...... 19, T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 gases, liquefied. Propanethiols.............. 3 UN2402 II 3........ A6, IB2, T4, 150.......... 202....... 242....... 5 L 60 L E 95, 102 TP1, TP13 n-Propanol or Propyl 3 UN1274 II 3........ B1, IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... alcohol, normal. ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A#
Passage 272....... Propellant, liquid......... 1.3C UN0495 II 1.3C..... 37 None......... 62........ None...... Forbidden Forbidden 10 ....... Propellant, liquid......... 1.1C UN0497 II 1.1C..... 37 None......... 62........ None...... Forbidden Forbidden 10 ....... Propellant, solid.......... 1.1C UN0498 II 1.1C..... ................ None......... 62........ None...... Forbidden Forbidden .......... 26E Propellant, solid.......... 1.3C UN0499 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden .......... 26E Propellant, solid.......... 1.4C UN0501 ....... 1.4C..... ................ None......... 62........ None...... Forbidden Forbidden A 24E Propionaldehyde............ 3 UN1275 II 3........ IB2, T7, TP1 150.......... 202....... 242....... 5 L 60 L E ....... Propionic acid............. 8 UN1848 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Propionic anhydride........ 8 UN2496 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Propionitrile.............. 3 UN2404 II 3, 6.1... IB2, T7, TP1, None......... 202....... 243....... Forbidden 60 L E 40 TP13 Propionyl chloride......... 3 UN1815 II 3, 8..... IB1, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 n-Propyl acetate........... 3 UN1276 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Propyl alcohol, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Propanol. n-Propyl benzene........... 3 UN2364 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... n-Propyl chloroformate..... 6.1 UN2740 I 6.1, 3, 8 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 21, 40, B74, B77, N34, 100 T20, TP2, TP13, TP38, TP44 Propyl chloride see 1- ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chloropropane. Propyl formates............ 3 UN1281 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... n-Propyl isocyanate........ 6.1 UN2482 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 B72, T22, TP2, TP13, TP38, TP44 Propyl mercaptan, see ........... ................. ....... ......... ......#
Passage 273.......... ............. .......... .......... ........... ........... .......... ....... Propanethiols. n-Propyl nitrate........... 3 UN1865 II 3........ IB99 150.......... 202....... None...... 5 L 60 L D 44, 89, 90, 100 Propylamine................ 3 UN1277 II 3, 8..... A7, IB2, N34, 150.......... 202....... 243....... 1 L 5 L E 40 T7, TP1 Propylene see also 2.1 UN1077 ....... 2.1...... 19, T50 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Petroleum gases, liquefied. Propylene chlorohydrin..... 6.1 UN2611 II 6.1, 3... IB2, T7, TP2, 153.......... 202....... 243....... 5 L 60 L A 12, 40, TP13 48 Propylene oxide............ 3 UN1280 I 3........ A3, N34, T11, None......... 201....... 243....... 1 L 30 L E 40 TP2, TP7 Propylene tetramer......... 3 UN2850 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 1,2-Propylenediamine....... 8 UN2258 II 8, 3..... A3, A6, IB2, None......... 202....... 243....... 1 L 30 L A 40 N34, T7, TP2 Propyleneimine, stabilized. 3 UN1921 I 3, 6.1... A3, N34, T14, None......... 201....... 243....... 1 L 30 L B 40 TP2, TP13 Propyltrichlorosilane...... 8 UN1816 II 8, 3..... A7, B2, B6, IB2, None......... 202....... 243....... Forbidden 30 L C 40 N34, T7, TP2, TP13 Prussic acid, see Hydrogen ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... cyanide. Pyrethroid pesticide, 3 UN3350 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Pyrethroid pesticide, 6.1 UN3352 I 6.1...... T14, TP2, TP13, None......... 211....... 242....... 1 L 30 L A 40 liquid toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 212....... 242....... 5 L 60 L A 40 TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 213....... 240....... 60 L 220 L A 40 TP28 Pyrethroid pesticide, 6.1 UN3351 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C.#
Passage 274........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L B 40 TP28 Pyrethroid pesticide, 6.1 UN3349 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Pyridine................... 3 UN1282 II 3........ IB2, T4, TP2 None......... 202....... 242....... 5 L 60 L B 21, 100 Pyridine perchlorate....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... G Pyrophoric liquid, 4.2 UN3194 I 4.2...... ................ None......... 181....... 244....... Forbidden Forbidden D 18 inorganic, n.o.s.. G Pyrophoric liquids, 4.2 UN2845 I 4.2...... B11, T22, TP2, None......... 181....... 244....... Forbidden Forbidden D 18 organic, n.o.s.. TP7 G Pyrophoric metals, n.o.s., 4.2 UN1383 I 4.2...... B11, T21, TP7, None......... 187....... 242....... Forbidden Forbidden D ....... or Pyrophoric alloys, TP33 n.o.s.. G Pyrophoric solid, 4.2 UN3200 I 4.2...... T21, TP7, TP33 None......... 187....... 242....... Forbidden Forbidden D ....... inorganic, n.o.s.. G Pyrophoric solids, organic, 4.2 UN2846 I 4.2...... ................ None......... 187....... 242....... Forbidden Forbidden D ....... n.o.s.. Pyrosulfuryl chloride...... 8 UN1817 II 8........ B2, IB2, T8, 154.......... 202....... 242....... 1 L 30 L C 40 TP2, TP12 Pyroxylin solution or ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solvent, see Nitrocellulose. Pyrrolidine................ 3 UN1922 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 Quebrachitol pentanitrate.. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Quicklime, see Calcium ........... ................. ......#
Passage 275. ......... ................ ............. .......... .......... ........... ........... .......... ....... oxide. Quinoline.................. 6.1 UN2656 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 12 R 12, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dichlorodifluoromethane. R 12B1, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorodifluorobromomethane. R 13, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorotrifluoromethane. R 13B1, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Bromotrifluoromethane. R 14, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetrafluoromethane. R 21, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dichlorofluoromethane. R 22, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorodifluoromethane. R 114, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dichlorotetrafluoroethane. R 115, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chloropentafluoroethane. R 116, see Hexafluoroethane ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... R 124, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorotetrafluoroethane. R 133a, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorotrifluoroethane. R 152a, see Difluoroethane#
Passage 276. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... R 500, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Dichlorodifluoromethane and difluorethane, etc. R 502, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorodifluoromethane and chloropentafluoroethane mixture, etc. R 503, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Chlorotrifluoromethane and trifluoromethane, etc. Radioactive material, 7 UN2909 ....... None..... ................ 422, 426..... 422, 426.. 422, 426.. ........... ........... A ....... excepted package-articles manufactured from natural uranium or depleted uranium or natural thorium. Radioactive material, 7 UN2908 ....... Empty.... ................ 422, 428..... 422, 428.. 422, 428.. ........... ........... A ....... excepted package-empty packaging. Radioactive material, 7 UN2911 ....... None..... ................ 422, 424..... 422, 424.. .......... ........... ........... A ....... excepted package- instruments or articles. Radioactive material, 7 UN2910 ....... None..... ................ 421, 422..... 421, 422.. 421, 422.. ........... ........... A ....... excepted package-limited quantity of material. Radioactive material, low 7 UN2912 ....... 7........ A56, T5, TP4, W7 421, 422, 428 427....... 427....... ........... ........... A 95, 129 specific activity (LSA-I) non fissile or fissile- excepted. Radioactive material, low 7 UN3321 ....... 7........ A56, T5, TP4, W7 421, 422, 428 427....... 427....... ........... ........... A 95, 129 specific activity (LSA-II) non fissile or fissile- excepted. Radioactive material, low 7 UN3322 ....... 7........ A56, T5, TP4, W7 421, 422, 428 427....... 427....... ........... ........... A 95, 129 specific activity (LSA- III) non fissile or fissile excepted. Radioactive material, 7 UN2913 ....... 7........ A56 421, 422, 428 427....... 427....... ........... ........... A 95 surface contaminated objects (SCO-I or SCO-II) non fissile or fissile- excepted. Radioactive material, 7 UN2919 ....... 7........ A56, 139#
Passage 277............. .......... .......... ........... ........... A 95, 105 transported under special arrangement, non fissile or fissile excepted. Radioactive material, 7 UN3331 ....... 7........ A56, 139 ............. .......... .......... ........... ........... A 95, 105 transported under special arrangement, fissile.#
Passage 278Radioactive material, Type 7 UN3327 ....... 7........ A56, W7, W8 453.......... 417....... 417....... ........... ........... A 95, A package, fissile non- 105, special form. 131 Radioactive material, Type 7 UN2915 ....... 7........ A56, W7, W8 ............. 415....... 415....... ........... ........... A 95, 130 A package non-special form, non fissile or fissile-excepted. Radioactive material, Type 7 UN3332 ....... 7........ A56, W7, W8 ............. 415, 476.. 415, 476.. ........... ........... A 95 A package, special form non fissile or fissile- excepted. Radioactive material, Type 7 UN3333 ....... 7........ A56, W7, W8 453.......... 417, 476.. 417, 476.. ........... ........... A 95, 105 A package, special form, fissile. Radioactive material, Type 7 UN3329 ....... 7........ A56 453.......... 417....... 417....... ........... ........... A 95, 105 B(M) package, fissile. Radioactive material, Type 7 UN2917 ....... 7........ A56 ............. 416....... 416....... ........... ........... A 95, 105 B(M) package non fissile or fissile-excepted. Radioactive material, Type 7 UN3328 ....... 7........ A56 453.......... 417....... 417....... ........... ........... A 95, 105 B(U) package, fissile. Radioactive material, Type 7 UN2916 ....... 7........ A56 ............. 416....... 416....... ........... ........... A 95, 105 B(U) package non fissile or fissile-excepted. Radioactive material, 7 UN2978 ....... 7, 8..... ................ 423.......... 420, 427.. 420, 427.. ........... ........... A 95, 132 uranium hexafluoride non fissile or fissile- excepted. I Radioactive material, 7 UN2977 ....... 7, 8..... ................ 453.......... 417, 420.. 417, 420.. ........... ........... A 95, 132 uranium hexafluoride, fissile. A W Rags, oily................. 4.2 UN1856 III 4.2...... ................ 151.......... 213....... 240....... Forbidden Forbidden A ....... Railway torpedo, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Signals, railway track, explosive. Rare gases and nitrogen 2.2 UN1981 ....... 2.2...... ................ 306.......... 302....... None...... 75 kg 150 kg A ....... mixtures, compressed. Rare gases and oxygen 2.2 UN1980 ....... 2.2...... 79 306.......... 302....... None...... 75 kg 150 kg A ....... mixtures, compressed. Rare gases mixtures, 2.2 UN19#
Passage 27979 ....... 2.2...... ................ 306.......... 302....... None...... 75 kg 150 kg A ....... compressed. RC 318, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Octafluorocyclobutane. RDX and ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... cyclotetramethylenetetrani tramine, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized. RDX and HMX mixtures, 1.1D UN0391 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... wetted with not less than 15 percent water by mass or RDX and HMX mixtures, desensitized with not less than 10 percent phlegmatizer by mass. RDX and Octogen mixtures, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. RDX, see Cyclotrimethylene ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitramine, etc. Receptacles, small, 2.1 UN2037 ....... 2.1...... ................ 306.......... 304....... None...... 1 kg 15 kg B 40 containing gas (gas cartridges) flammable, without release device, not refillable and not exceeding 1 L capacity. Receptacles, small, 2.2 UN2037 ....... 2.2...... ................ 306.......... 304....... None...... 1 kg 15 kg B 40 containing gas (gas cartridges) non-flammable, without release device, not refillable and not exceeding 1 L capacity. ........................... ........... ................. ....... 2.2, 5.1. A14 306.......... 304....... None...... 1 kg 15 kg B 40 Red phosphorus, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Phosphorus, amorphous. Refrigerant gas R 404A..... 2.2 UN3337 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 407A..... 2.2 UN3338 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 407B..... 2.2 UN3339 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ...#
Passage 280.... Refrigerant gas R 407C..... 2.2 UN3340 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... G Refrigerant gases, n.o.s... 2.2 UN1078 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... D Refrigerant gases, n.o.s. 2.1 NA1954 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg D 40 or Dispersant gases, n.o.s.. Refrigerating machines, 2.1 UN3358 ....... 2.1...... ................ 306.......... 306....... 306....... Forbidden Forbidden C 40 containing flammable, non- toxic, liquefied gas. Refrigerating machines, 2.2 UN2857 ....... 2.2...... A53 306, 307..... 306....... 306, 307.. 450 kg 450 kg A ....... containing non-flammable, non-toxic, or ammonia solution (UN2672). Regulated medical waste.... 6.2 UN3291 II 6.2...... A13 134.......... 197....... 197....... No limit No limit A 40 Release devices, explosive. 1.4S UN0173 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Resin solution, flammable.. 3 UN1866 I 3........ B52, T11, TP1, 150.......... 201....... 243....... 1 L 30 L E ....... TP8, TP28 ........................... ........... ................. II 3........ 149, B52, IB2, 150.......... 173....... 242....... 5 L 60 L B ....... T4, TP1, TP8 ........................... ........... ................. III 3........ B1, B52, IB3, 150.......... 173....... 242....... 60 L 220 L A ....... T2, TP1 Resorcinol................. 6.1 UN2876 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Rifle grenade, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Grenades, hand or rifle, etc. Rifle powder, see Powder, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... smokeless (UN 0160). Rivets, explosive.......... 1.4S UN0174 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Road asphalt or tar liquid, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Tars, liquid, etc. Rocket motors.............. 1.3C UN0186 II 1.3C..... 109 None......... 62........ None...... Forbidden 220 kg 03 .......#
Passage 281Rocket motors.............. 1.1C UN0280 II 1.1C..... 109 None......... 62........ None...... Forbidden Forbidden 03 ....... Rocket motors.............. 1.2C UN0281 II 1.2C..... 109 None......... 62........ None...... Forbidden Forbidden 03 ....... Rocket motors, liquid 1.2J UN0395 II 1.2J..... 109 None......... 62........ None...... Forbidden Forbidden 04 23E fueled. Rocket motors, liquid 1.3J UN0396 II 1.3J..... 109 None......... 62........ None...... Forbidden Forbidden 04 23E fueled. Rocket motors with 1.3L UN0250 II 1.3L..... 109 None......... 62........ None...... Forbidden Forbidden 08 8E, hypergolic liquids with or 14E, without an expelling 15E charge. Rocket motors with 1.2L UN0322 II 1.2L..... 109 None......... 62........ None...... Forbidden Forbidden 08 8E, hypergolic liquids with or 14E, without an expelling 15E charge.#
Passage 282Rockets, line-throwing..... 1.2G UN0238 II 1.2G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Rockets, line-throwing..... 1.3G UN0240 II 1.3G..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Rockets, line-throwing..... 1.4G UN0453 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Rockets, liquid fueled with 1.1J UN0397 II 1.1J..... ................ None......... 62........ None...... Forbidden Forbidden 04 23E bursting charge. Rockets, liquid fueled with 1.2J UN0398 II 1.2J..... ................ None......... 62........ None...... Forbidden Forbidden 04 23E bursting charge. Rockets, with bursting 1.1F UN0180 II 1.1F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... charge. Rockets, with bursting 1.1E UN0181 II 1.1E..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... charge. Rockets, with bursting 1.2E UN0182 II 1.2E..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... charge. Rockets, with bursting 1.2F UN0295 II 1.2F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... charge. Rockets, with expelling 1.2C UN0436 II 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... charge. Rockets, with expelling 1.3C UN0437 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... charge. Rockets, with expelling 1.4C UN0438 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 02 ....... charge. Rockets, with inert head... 1.3C UN0183 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... Rockets, with inert head... 1.2C UN0502 ....... 1.2C..... ................ None......... 62........ None...... Forbidden Forbidden B 1E, 5E Rosin oil.................. 3 UN1286 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Rubber solution............ 3 UN1287 II 3........ 149, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 Rubber scrap or shoddy, 4.1 UN1345 II 4.1...... I#
Passage 283B8, IP2, IP4, 151.......... 212....... 240....... 15 kg 50 kg A ....... powdered or granulated, T3, TP33 not exceeding 840 microns and rubber contend exceeding 45%. Rubber solution............ 3 UN1287 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Rubidium................... 4.3 UN1423 I 4.3...... 22, A7, A19, None......... 211....... 242....... Forbidden 15 kg D 52 IB4, IP1, N34, N40, N45 Rubidium hydroxide......... 8 UN2678 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 29 T3, TP33 Rubidium hydroxide solution 8 UN2677 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 29 ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A 29 Safety fuse, see Fuse, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... safety. Sand acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fluorosilicic acid. Seed cake, containing 4.2 UN1386 III None..... IB8, IP3, IP7, None......... 213....... 241....... Forbidden Forbidden A 13 vegetable oil solvent N7 extractions and expelled seeds, with not more than 10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined. I Seed cake with more than 4.2 UN1386 III None..... IB8, IP3, IP7, None......... 213....... 241....... Forbidden Forbidden E 13 1.5 percent oil and not N7 more than 11 percent moisture. I Seed cake with not more 4.2 UN2217 III None..... IB8, IP3, IP7, None......... 213....... 241....... Forbidden Forbidden A 13 than 1.5 percent oil and N7 not more than 11 percent moisture. Selenates or Selenites..... 6.1 UN2630 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg E ....... TP33 Selenic acid............... 8 UN1905 I 8........ IB7, IP1, N34, None......... 211....... 242....... Forbidden 25 kg A ....... T6, TP33 Selenium compound, solid, 6.1 UN3283 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... n.o.s.. TP33 Selenium compound, liquid, 6.1 UN3440 I 6.1...... T14, TP2, TP27 None......... 201....... 243....... 1 L 30 L B ....... n.o.s#
Passage 284.. Selenium compound, solid, 6.1 UN3283 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... n.o.s.. T3, TP33 Selenium compound, liquid, 6.1 UN3440 II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B ....... n.o.s.. TP27 Selenium compound, solid, 6.1 UN3283 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... n.o.s.. TP33 Selenium compound, liquid, 6.1 UN3440 III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A ....... n.o.s.. TP28 Selenium disulfide......... 6.1 UN2657 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Selenium hexafluoride...... 2.3 UN2194 ....... 2.3, 8... 1 None......... 302....... None...... Forbidden Forbidden D 40 Selenium nitride........... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenium oxychloride....... 8 UN2879 I 8, 6.1... A3, A6, A7, N34, None......... 201....... 243....... 0.5 L 2.5 L E 40 T10, TP2, TP12, TP13 Self-defense spray, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... aerosol, see Aerosols, etc. + A D Self-defense spray, non- 9 NA3334 III 9........ A37 155.......... 203....... None...... No limit No limit A ....... pressurized. G Self-heating liquid, 4.2 UN3188 II 4.2, 8... IB2 None......... 202....... 243....... 1 L 5 L C ....... corrosive, inorganic, n.o.s.. ........................... ........... ................. III 4.2, 8... IB2 None......... 203....... 241....... 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3185 II 4.2, 8... IB2 None......... 202....... 243....... 1 L 5 L C ....... corrosive, organic, n.o.s.. ........................... ........... ................. III 4.2, 8... IB2 None......... 203....... 241....... 5 L 60 L C ....... G Self-heating liquid, 4.2 UN3186 II 4.2...... IB2 None......... 202....... 242....... 1 L 5 L C ....... inorganic, n.o.s.. ........................... ........... ................. III 4.2...... IB2 None......... 203....... 241....... 5 L 60 L C .......#
Passage 285G Self-heating liquid, 4.2 UN3183 II 4.2...... IB2 None......... 202....... 242....... 1 L 5 L C ....... organic, n.o.s.. ........................... ........... ................. III 4.2...... IB2 None......... 203....... 241....... 5 L 60 L C ....... G Self-heating liquid, toxic, 4.2 UN3187 II 4.2, 6.1. IB2 None......... 202....... 243....... 1 L 5 L C ....... inorganic, n.o.s.. ........................... ........... ................. III 4.2, 6.1. IB2 None......... 203....... 241....... 5 L 60 L C ....... G Self-heating liquid, toxic, 4.2 UN3184 II 4.2, 6.1. IB2 None......... 202....... 243....... 1 L 5 L C ....... organic, n.o.s.. ........................... ........... ................. III 4.2, 6.1. IB2 None......... 203....... 241....... 5 L 60 L C ....... G Self-heating solid, 4.2 UN3192 II 4.2, 8... IB5, IP2, T3, None......... 212....... 242....... 15 kg 50 kg C ....... corrosive, inorganic, TP33 n.o.s.. ........................... ........... ................. III 4.2, 8... IB8, IP3, T1, None......... 213....... 242....... 25 kg 100 kg C ....... TP33 G Self-heating, solid, 4.2 UN3126 II 4.2, 8... IB5, IP2, T3, None......... 212....... 242....... 15 kg 50 kg C ....... corrosive, organic, n.o.s.. TP33 ........................... ........... ................. III 4.2, 8... IB8, IP3, T1, None......... 213....... 242....... 25 kg 100 kg C ....... TP33 G Self-heating solid, 4.2 UN3190 II 4.2...... IB6, IP2, T3, None......... 212....... 241....... 15 kg 50 kg C ....... inorganic, n.o.s.. TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg C ....... TP33 G Self-heating, solid, 4.2 UN3088 II 4.2...... IB6, IP2, T3, None......... 212....... 241....... 15 kg 50 kg C ....... organic, n.o.s.. TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg C ....... TP33 G Self-heating, solid, 4.2 UN3127 ....... 4.2, 5.1. ................ None......... 214....... 214....... Forbidden Forbidden .......... ....... oxidizing, n.o.s.. G Self-heating solid, toxic, 4.2 UN3191 II 4.2, 6.1. IB5, IP2, T3, None......... 212....... 242....... 15 kg 50 kg C ....... inorganic, n.o.s.. TP33 ........................... ........... ................. III 4.2, 6.1. IB8, IP3, T1, None......... 213....... 242....... 25#
Passage 286kg 100 kg C ....... TP33 G Self-heating, solid, toxic, 4.2 UN3128 II 4.2, 6.1. IB5, IP2, T3, None......... 212....... 242....... 15 kg 50 kg C ....... organic, n.o.s.. TP33 ........................... ........... ................. III 4.2, 6.1. IB8, IP3, T1, None......... 213....... 242....... 25 kg 100 kg C ....... TP33 Self-propelled vehicle, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Engines or Batteries etc. G Self-reactive liquid type B 4.1 UN3221 II 4.1...... 53 None......... 224....... None...... Forbidden Forbidden D 52, 53 G Self-reactive liquid type 4.1 UN3231 II 4.1...... 53 None......... 224....... None...... Forbidden Forbidden D 2, 52, B, temperature controlled. 53 G Self-reactive liquid type C 4.1 UN3223 II 4.1...... ................ None......... 224....... None...... 5 L 10 L D 52, 53 G Self-reactive liquid type 4.1 UN3233 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, C, temperature controlled. 53 G Self-reactive liquid type D 4.1 UN3225 II 4.1...... ................ None......... 224....... None...... 5 L 10 L D 52, 53 G Self-reactive liquid type 4.1 UN3235 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, D, temperature controlled. 53 G Self-reactive liquid type E 4.1 UN3227 II 4.1...... ................ None......... 224....... None...... 10 L 25 L D 52, 53 G Self-reactive liquid type 4.1 UN3237 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, E, temperature controlled. 53 G Self-reactive liquid type F 4.1 UN3229 II 4.1...... T23 None......... 224....... None...... 10 L 25 L D 52, 53 G Self-reactive liquid type 4.1 UN3239 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, F, temperature controlled. 53 G Self-reactive solid type B. 4.1 UN3222 II 4.1...... 53 None......... 224....... None...... Forbidden Forbidden D 52, 53 G Self-reactive solid type B, 4.1 UN3232 II 4.1...... 53 None......... 224....... None...... Forbidden Forbidden D 2, 52, temperature controlled. 53 G Self-reactive solid type C. 4.1 UN3224 II 4.1...... ................ None......... 224....... None...... 5 kg 10 kg D 52, 53 G Self-reactive solid type C, 4.1 UN3234 II 4.1...... ..........#
Passage 287...... None......... 224....... None...... Forbidden Forbidden D 2, 52, temperature controlled. 53 G Self-reactive solid type D. 4.1 UN3226 II 4.1...... ................ None......... 224....... None...... 5 kg 10 kg D 52, 53 G Self-reactive solid type D, 4.1 UN3236 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, temperature controlled. 53 G Self-reactive solid type E. 4.1 UN3228 II 4.1...... ................ None......... 224....... None...... 10 kg 25 kg D 52, 53 G Self-reactive solid type E, 4.1 UN3238 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, temperature controlled. 53 G Self-reactive solid type F. 4.1 UN3230 II 4.1...... ................ None......... 224....... None...... 10 kg 25 kg D 52, 53 G Self-reactive solid type F, 4.1 UN3240 II 4.1...... ................ None......... 224....... None...... Forbidden Forbidden D 2, 52, temperature controlled. 53 Shale oil.................. 3 UN1288 I 3........ T11, TP1, TP8, None......... 201....... 243....... 1 L 30 L B ....... TP27 ........................... ........... ................. II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Shaped charges, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Charges, shaped, etc. Signal devices, hand....... 1.4G UN0191 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Signal devices, hand....... 1.4S UN0373 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 .......#
Passage 288Signals, distress, ship.... 1.1G UN0194 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Signals, distress, ship.... 1.3G UN0195 II 1.3G..... ................ None......... 62........ None...... Forbidden 75 kg 07 ....... Signals, highway, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Signal devices, hand. Signals, railway track, 1.1G UN0192 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... explosive. Signals, railway track, 1.4S UN0193 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... explosive. Signals, railway track, 1.3G UN0492 ....... 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... explosive. Signals, railway track, 1.4G UN0493 ....... 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... explosive. Signals, ship distress, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... water-activated, see Contrivances, water- activated, etc. Signals, smoke............. 1.1G UN0196 II 1.1G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Signals, smoke............. 1.4G UN0197 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Signals, smoke............. 1.2G UN0313 II 1.2G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Signals, smoke............. 1.3G UN0487 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Silane..................... 2.1 UN2203 ....... 2.1...... ................ None......... 302....... None...... Forbidden Forbidden E 40, 57, 104 Silicofluoric acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Fluorosilicic acid. Silicon chloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silicon tetrachloride. Silicon powder, amorphous.. 4.1 UN1346 III 4.1...... A1, IB8, IP3, None.....#
Passage 289.... 213....... 240....... 25 kg 100 kg A 74 T1, TP33 Silicon tetrachloride...... 8 UN1818 II 8........ A3, A6, B2, B6, 154.......... 202....... 242....... 1 L 30 L C 40 IB2, T7, TP2, TP7 Silicon tetrafluoride...... 2.3 UN1859 ....... 2.3, 8... 2 None......... 302....... None...... Forbidden Forbidden D 40 Silver acetylide (dry)..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silver arsenite............ 6.1 UN1683 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Silver azide (dry)......... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silver chlorite (dry)...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silver cyanide............. 6.1 UN1684 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40, 52 T3, TP33 Silver fulminate (dry)..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silver nitrate............. 5.1 UN1493 II 5.1...... IB8, IP4, T3, 152.......... 212....... 242....... 5 kg 25 kg A ....... TP33 Silver oxalate (dry)....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silver picrate (dry)....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Silver picrate, wetted with 4.1 UN1347 I 4.1...... 23 None......... 211....... None...... Forbidden Forbidden D 28, 36 not less than 30 percent water, by mass. Sludge, acid............... 8 UN1906 II 8........ A3, A7, B2, IB2, None......... 202....... 242....... Forbidden 30 L C 14 N34, T8, TP2, TP12, TP28 D Smokeless powder for small 4.1 NA3178 I 4.1...... 16 None......... 171....... None...... Forbidden 7.3 kg A ....... arms (100 pounds or less). Soda lime with more than 4 8 UN1907 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... percent sodium hydroxide. TP33 Sodium..................... 4.3 UN1428 I 4.3...... A7, A8, A19, None#
Passage 290......... 211....... 244....... Forbidden 15 kg D 52 A20, B9, B48, B68, IB4, IP1, N34, T9, TP7, TP33, TP46 Sodium aluminate, solid.... 8 UN2812 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 Sodium aluminate, solution. 8 UN1819 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A ....... ........................... ........... ................. III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Sodium aluminum hydride.... 4.3 UN2835 II 4.3...... A8, A19, A20, 151.......... 212....... 242....... Forbidden 50 kg E 52 IB4, T3, TP33 Sodium ammonium vanadate... 6.1 UN2863 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Sodium arsanilate.......... 6.1 UN2473 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Sodium arsenate............ 6.1 UN1685 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Sodium arsenite, aqueous 6.1 UN1686 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... solutions. ........................... ........... ................. III 6.1...... IB3, T4, TP2 153.......... 203....... 241....... 60 L 220 L A ....... Sodium arsenite, solid..... 6.1 UN2027 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Sodium azide............... 6.1 UN1687 II 6.1...... IB8, IP2, IP4 153.......... 212....... 242....... 25 kg 100 kg A 36, 52, 91 Sodium bifluoride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sodium hydrogendifluoride.#
Passage 291Sodium bisulfite, solution, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Bisulfites, aqueous solutions, n.o.s.. Sodium borohydride......... 4.3 UN1426 I 4.3...... N40 None......... 211....... 242....... Forbidden 15 kg E 52 Sodium borohydride and 8 UN3320 II 8........ B2, IB2, N34, 154.......... 202....... 242....... 1 L 30 L A 52 sodium hydroxide solution, T7, TP2 with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass. ........................... ........... ................. III 8........ B2, IB3, N34, 154.......... 203....... 241....... 5 L 60 L A 52 T4, TP2 Sodium bromate............. 5.1 UN1494 II 5.1...... IB8, IP4, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Sodium cacodylate.......... 6.1 UN1688 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 52 T3, TP33 Sodium carbonate 5.1 UN3378 II 5.1...... IB8, IP2, IP4, 152.......... 212....... 240....... 5 kg 25 kg A 13, 48, peroxyhydrate. T3, TP33 75 ........................... ........... ................. III 5.1...... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg A 13, 48, TP33 75 Sodium chlorate............ 5.1 UN1495 II 5.1...... A9, IB8, IP4, 152.......... 212....... 240....... 5 kg 25 kg A 56, 58 N34, T3, TP33 Sodium chlorate, aqueous 5.1 UN2428 II 5.1...... A2, IB2, T4, TP1 152.......... 202....... 241....... 1 L 5 L B 56, 58, solution. 133 ........................... ........... ................. III 5.1...... A2, IB2, T4, TP1 152.......... 203....... 241....... 2.5 L 30 L B 56, 58, 69, 133 Sodium chlorate mixed with ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dinitrotoluene, see Explosive blasting, type C. Sodium chlorite............ 5.1 UN1496 II 5.1...... A9, IB8, IP2, None......... 212....... 242....... 5 kg 25 kg A 56, 58 IP4, N34, T3, TP33 Sodium chloroacetate....... 6.1 UN2659 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Sodium cuprocyanide, solid. 6.1 UN2316 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 52 TP33 Sodium cuprocyanide, 6.1 UN2317 I 6.1...... T14, TP2, TP13 None......... 201....... 243......#
Passage 292. 1 L 30 L B 40, 52 solution. Sodium cyanide, solid...... 6.1 UN1689 I 6.1...... B69, B77, IB7, None......... 211....... 242....... 5 kg 50 kg B 52 N74, N75, T6, TP33 Sodium cyanide solution.... 6.1 UN3414 I 6.1...... B69, B77, N74, None......... 201....... 243....... 1 L 30 L B 52 N75, T14, TP2, TP13 ........................... ........... ................. II 6.1...... B69, B77, IB2, 153.......... 202....... 243....... 5 L 60 L B 52 N74, N75, T11, TP2, TP13, TP27 ........................... ........... ................. III 6.1...... B69, B77, IB3, 153.......... 203....... 241....... 60 L 220 L A 52 N74, N75, T7, TP2, TP13, TP28 Sodium dichloroisocyanurate ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... or Sodium dichloro-s- triazinetrione, see Dichloroisocyanuric acid etc. Sodium dinitro-o-cresolate, 1.3C UN0234 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E dry or wetted with less than 15 percent water, by mass. Sodium dinitro-o-cresolate, 4.1 UN3369 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 wetted with not less than N41, N84 10% water, by mass. Sodium dinitro-o-cresolate, 4.1 UN1348 I 4.1, 6.1. 23, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28, 36 wetted with not less than A20, N41 15 percent water, by mass. Sodium dithionite or Sodium 4.2 UN1384 II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg E 13 hydrosulfite. IP2, T3, TP33 Sodium fluoride, solid..... 6.1 UN1690 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Sodium fluoride solution... 6.1 UN3415 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A 52 Sodium fluoroacetate....... 6.1 UN2629 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg E ....... TP33 Sodium fluorosilicate...... 6.1 UN2674 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Sodium hydrate, see Sodium ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hydroxide, solid. Sodium hydride............. 4.3 UN1427 I 4.3...... A19, N40 None......... 211....... 242....... Forbidden 15 kg E 52 Sodium hydrogendifl#
Passage 293uoride.. 8 UN2439 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 12, 25, N3, N34, T3, 40, 52 TP33 Sodium hydrosulfide, with 4.2 UN2318 II 4.2...... A7, A19, A20, None......... 212....... 241....... 15 kg 50 kg A ....... less than 25 percent water IB6, IP2, T3, of crystallization. TP33 Sodium hydrosulfide with 8 UN2949 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A 52 not less than 25 percent IP4, T7, TP2 water of crystallization. Sodium hydrosulfite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sodium dithionite. Sodium hydroxide, solid.... 8 UN1823 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... T3, TP33 Sodium hydroxide solution.. 8 UN1824 II 8........ B2, IB2, N34, 154.......... 202....... 242....... 1 L 30 L A ....... T7, TP2 ........................... ........... ................. III 8........ IB3, N34, T4, 154.......... 203....... 241....... 5 L 60 L A ....... TP1 Sodium hypochlorite, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... solution, see Hypochlorite solutions etc. Sodium metal, liquid alloy, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Alkali metal alloys, liquid, n.o.s..#
Passage 294Sodium methylate........... 4.2 UN1431 II 4.2, 8... A7, A19, IB5, None......... 212....... 242....... 15 kg 50 kg B ....... IP2, T3, TP33 Sodium methylate solutions 3 UN1289 II 3, 8..... IB2, T7, TP1, 150.......... 202....... 243....... 1 L 5 L B ....... in alcohol. TP8 ........................... ........... ................. III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A ....... Sodium monoxide............ 8 UN1825 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A ....... T3, TP33 Sodium nitrate............. 5.1 UN1498 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Sodium nitrate and 5.1 UN1499 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... potassium nitrate mixtures. IP3, T1, TP33 Sodium nitrite............. 5.1 UN1500 III 5.1, 6.1. A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 IP3, T1, TP33 Sodium pentachlorophenate.. 6.1 UN2567 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Sodium perborate 5.1 UN3377 III 5.1...... IB8, IP3, T1, 152.......... 213....... 240....... 25 kg 100 kg A 13, 48, monohydrate. TP33 75 Sodium perchlorate......... 5.1 UN1502 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Sodium permanganate........ 5.1 UN1503 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg D 56, 58, TP33 138 Sodium peroxide............ 5.1 UN1504 I 5.1...... A20, IB5, IP1, None......... 211....... None...... Forbidden 15 kg B 13, 52, N34 66, 75 Sodium peroxoborate, 5.1 UN3247 II 5.1...... IB8, IP4, T3, 152.......... 212....... 240....... 5 kg 25 kg A 13, 25 anhydrous. TP33 Sodium persulfate.......... 5.1 UN1505 III 5.1...... A1, IB8, IP3, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 T1, TP33 Sodium phosphide........... 4.3 UN1432 I 4.3, 6.1. A19, N40 None......... 211....... None...... Forbidden 15 kg E 40, 52, 85 Sodium picramate, dry or 1.3C UN0235 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E wetted with less than 20 percent water, by mass. Sodium picramate, wetted 4.1 UN1349 I 4.1...... 23, A8, A19, N41 None......... 211....... None...... Forbidden 15 kg E 28, 36 with not less than 20 percent water, by mass. Sodium#
Passage 295picryl peroxide..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sodium potassium alloys, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Potassium sodium alloys. Sodium selenate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Sodium sulfide, anhydrous 4.2 UN1385 II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg A 52 or Sodium sulfide with IP2, N34, T3, less than 30 percent water TP33 of crystallization. Sodium sulfide, hydrated 8 UN1849 II 8........ IB8, IP2, IP4, 154.......... 212....... 240....... 15 kg 50 kg A 26 with not less than 30 T3, TP33 percent water. Sodium superoxide.......... 5.1 UN2547 I 5.1...... A20, IB6, IP1, None......... 211....... None...... Forbidden 15 kg E 13, 52, N34 66, 75 Sodium tetranitride........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... G Solids containing corrosive 8 UN3244 II 8........ 49, IB5, T3, 154.......... 212....... 240....... 15 kg 50 kg B 40 liquid, n.o.s.. TP33 G Solids containing flammable 4.1 UN3175 II 4.1...... 47, IB6, IP2, 151.......... 212....... 240....... 15 kg 50 kg B ....... liquid, n.o.s.. T3, TP33 G Solids containing toxic 6.1 UN3243 II 6.1...... 48, IB2, T2, 153.......... 212....... 240....... 25 kg 100 kg B 40 liquid, n.o.s.. TP33 Sounding devices, explosive 1.2F UN0204 II 1.2F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... Sounding devices, explosive 1.1F UN0296 II 1.1F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... Sounding devices, explosive 1.1D UN0374 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Sounding devices, explosive 1.2D UN0375 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Spirits of salt, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrochloric acid. Squibs, see#
Passage 296Igniters etc... ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Stannic chloride, anhydrous 8 UN1827 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L C ....... Stannic chloride 8 UN2440 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... pentahydrate. TP33 Stannic phosphide.......... 4.3 UN1433 I 4.3, 6.1. A19, N40 None......... 211....... 242....... Forbidden 15 kg E 40, 52, 85 Steel swarf, see Ferrous ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... metal borings, etc. Stibine.................... 2.3 UN2676 ....... 2.3, 2.1. 1 None......... 304....... None...... Forbidden Forbidden D 40 Storage batteries, wet, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Batteries, wet etc. Strontium arsenite......... 6.1 UN1691 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33#
Passage 297Strontium chlorate......... 5.1 UN1506 II 5.1...... A1, A9, IB8, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 IP2, IP4, N34, T3, TP33 Strontium nitrate.......... 5.1 UN1507 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Strontium perchlorate...... 5.1 UN1508 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Strontium peroxide......... 5.1 UN1509 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 13, 52, TP33 66, 75 Strontium phosphide........ 4.3 UN2013 I 4.3, 6.1. A19, N40 None......... 211....... None...... Forbidden 15 kg E 40, 52, 85 Strychnine or Strychnine 6.1 UN1692 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 salts. TP33 Styphnic acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitroresorcinol, etc. Styrene monomer, stabilized 3 UN2055 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... G Substances, explosive, 1.1L UN0357 II 1.1L..... 101 None......... 62........ None...... Forbidden Forbidden .......... 8E, n.o.s.. 14E, 15E, 17E G Substances, explosive, 1.2L UN0358 II 1.2L..... 101 None......... 62........ None...... Forbidden Forbidden .......... 8E, n.o.s.. 14E, 15E, 17E G Substances, explosive, 1.3L UN0359 II 1.3L..... 101 None......... 62........ None...... Forbidden Forbidden .......... 8E, n.o.s.. 14E, 15E, 17E G Substances, explosive, 1.1A UN0473 II 1.1A..... 101, 111 None......... 62........ None...... Forbidden Forbidden 12 ....... n.o.s.. G Substances, explosive, 1.1C UN0474 II 1.1C..... 101 None......... 62........ None...... Forbidden Forbidden 10 ....... n.o.s.. G Substances, explosive, 1.1D UN0475 II 1.1D..... 101 None......... 62........ None...... Forbidden Forbidden 10 ....... n.o.s.. G Substances, explosive, 1.1G UN0476 II 1.1G..... 101 None......... 62........ None...... Forbidden Forbidden 08 ....... n.o.s.. G Substances, explosive, 1.3C UN0477 II 1.3C..... 101 None......... 62........ None...... Forbidden Forbidden 10 ....... n.o.s.. G Substances, explosive, 1.3G UN0478 II 1.3G..... 101 None......... 62........ None...... Forbidden Forbidden 08 ....... n.o.s.. G Substances, explosive, 1.4C UN0479 II 1.4C..... 101 None......... 6#
Passage 2982........ None...... Forbidden 75 kg 09 ....... n.o.s.. G Substances, explosive, 1.4D UN0480 II 1.4D..... 101 None......... 62........ None...... Forbidden 75 kg 09 ....... n.o.s.. G Substances, explosive, 1.4S UN0481 II 1.4S..... 101 None......... 62........ None...... 25 kg 75 kg 05 ....... n.o.s.. G Substances, explosive, 1.4G UN0485 II 1.4G..... 101 None......... 62........ None...... Forbidden 75 kg 08 ....... n.o.s.. G Substances, explosive, very 1.5D UN0482 II 1.5D..... 101 None......... 62........ None...... Forbidden Forbidden 10 ....... insensitive, n.o.s., or Substances, EVI, n.o.s.. Substituted nitrophenol 3 UN2780 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 pesticides, liquid, TP27 flammable, toxic, flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Substituted nitrophenol 6.1 UN3014 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 pesticides, liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Substituted nitrophenol 6.1 UN3013 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 pesticides, liquid, toxic, TP27 flammable, flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... B1, IB3, T7, 153.......... 203....... 242....... 60 L 220 L A 40 TP2, TP28 Substituted nitrophenol 6.1 UN2779 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 pesticides, solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Sucrose octanitrate (dry).. Forbidden ................. ....... ......... ................#
Passage 299............. .......... .......... ........... ........... .......... ....... Sulfamic acid.............. 8 UN2967 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 D Sulfur..................... 9 NA1350 III 9........ 10, IB8, IP2 None......... None...... 240....... No limit No limit A 19, 74 I Sulfur..................... 4.1 UN1350 III 4.1...... 30, IB8, IP3, None......... None...... 240....... No limit No limit A 19, 74 T1, TP33 Sulfur and chlorate, loose Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... mixtures of. Sulfur chlorides........... 8 UN1828 I 8........ 5, A3, A7, A10, None......... 201....... 243....... Forbidden 2.5 L C 40 B10, B77, N34, T20, TP2, TP12 Sulfur dichloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sulfur chlorides. Sulfur dioxide............. 2.3 UN1079 ....... 2.3, 8... 3, B14, T50, None......... 304....... 314, 315.. Forbidden Forbidden D 40 TP19 Sulfur dioxide solution, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Sulfurous acid.#
Passage 300Sulfur hexafluoride........ 2.2 UN1080 ....... 2.2...... ................ 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... D Sulfur, molten............. 9 NA2448 III 9........ 30, IB3, T1, TP3 None......... 213....... 247....... Forbidden Forbidden C 61 I Sulfur, molten............. 4.1 UN2448 III 4.1...... 30, IB1, T1, TP3 None......... 213....... 247....... Forbidden Forbidden C 61 Sulfur tetrafluoride....... 2.3 UN2418 ....... 2.3, 8... 1 None......... 302....... 245....... Forbidden Forbidden D 40, 52 + Sulfur trioxide, stabilized 8 UN1829 I 8, 6.1... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden A 40 B49, B74, B77, N34, T20, TP4, TP12, TP13, TP25, TP26, TP38, TP45 Sulfuretted hydrogen, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrogen sulfide. Sulfuric acid, fuming with 8 UN1831 I 8........ B84, N34, T20, None......... 201....... 243....... Forbidden 2.5 L C 14, 40 less than 30 percent free TP2, TP12, TP13 sulfur trioxide. + Sulfuric acid, fuming with 8 UN1831 I 8, 6.1... 2, A3, A6, A7, None......... 227....... 244....... Forbidden Forbidden C 14, 40 30 percent or more free B9, B14, B32, sulfur trioxide. B74, B77, B84, N34, T20, TP2, TP12, TP13 Sulfuric acid, spent....... 8 UN1832 II 8........ A3, A7, B2, B83, None......... 202....... 242....... Forbidden 30 L C 14 B84, IB2, N34, T8, TP2, TP12 Sulfuric acid with more 8 UN1830 II 8........ A3, A7, B3, B83, 154.......... 202....... 242....... 1 L 30 L C 14 than 51 percent acid. B84, IB2, N34, T8, TP2, TP12 Sulfuric acid with not more 8 UN2796 II 8........ A3, A7, B2, B15, 154.......... 202....... 242....... 1 L 30 L B ....... than 51% acid. IB2, N6, N34, T8, TP2, TP12 Sulfuric and hydrofluoric ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... acid mixtures, see Hydrofluoric and sulfuric acid mixtures. Sulfuric anhydride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Sulfur trioxide, stabilized. Sulfurous acid............. 8 UN1833 II 8........ B3, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L B 40 + Sulfuryl chloride.......... 8 UN1834 I 8, 6.1... 1, B6, B9, B#
Passage 30110, None......... 226....... 244....... Forbidden Forbidden C 40 B14, B30, B74, B77, N34, T22, TP2, TP12, TP38, TP44 Sulfuryl fluoride.......... 2.3 UN2191 ....... 2.3...... 4 None......... 304....... 314, 315.. Forbidden Forbidden D 40 Tars, liquid including road 3 UN1999 II 3........ 149, B13, IB2, 150.......... 202....... 242....... 5 L 60 L B ....... asphalt and oils, bitumen T3, TP3, TP29 and cut backs. ........................... ........... ................. III 3........ B1, B13, IB3, 150.......... 203....... 242....... 60 L 220 L A ....... T1, TP3 Tear gas candles........... 6.1 UN1700 II 6.1, 4.1. ................ None......... 340....... None...... Forbidden 50 kg D 40 Tear gas cartridges, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Ammunition, tear- producing, etc. D Tear gas devices with more 6.1 NA1693 I 6.1...... ................ None......... 340....... None...... Forbidden Forbidden D 40 than 2 percent tear gas substances, by mass. ........................... ........... ................. II 6.1...... ................ None......... 340....... None...... Forbidden Forbidden D 40 Tear gas devices, with not ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... more than 2 percent tear gas substances, by mass, see Aerosols, etc. Tear gas grenades, see Tear ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... gas candles. G Tear gas substances, 6.1 UN1693 I 6.1...... ................ None......... 201....... None...... Forbidden Forbidden D 40 liquid, n.o.s.. ........................... ........... ................. II 6.1...... IB2 None......... 202....... None...... Forbidden 5 L D 40 G Tear gas substance, solid, 6.1 UN3448 I 6.1...... T6, TP33 None......... 211....... 242....... Forbidden Forbidden D 40 n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, None......... 212....... 242....... Forbidden 25 kg D 40 T3, TP33 Tellurium compound, n.o.s.. 6.1 UN3284 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... TP33 ........................... ........... ................. II 6.1...... IB8, IP2,#
Passage 302IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Tellurium hexafluoride..... 2.3 UN2195 ....... 2.3, 8... 1 None......... 302....... None...... Forbidden Forbidden D 40 Terpene hydrocarbons, 3 UN2319 III 3........ B1, IB3, T4, 150.......... 203....... 242....... 60 L 220 L A ....... n.o.s.. TP1, TP29 Terpinolene................ 3 UN2541 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A .......#
Passage 303Tetraazido benzene quinone. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetrabromoethane........... 6.1 UN2504 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... 1,1,2,2-Tetrachloroethane.. 6.1 UN1702 II 6.1...... IB2, N36, T7, 153.......... 202....... 243....... 5 L 60 L A 40 TP2 Tetrachloroethylene........ 6.1 UN1897 III 6.1...... IB3, N36, T4, 153.......... 203....... 241....... 60 L 220 L A 40 TP1 Tetraethyl 6.1 UN1704 II 6.1...... IB2, T7, TP2 153.......... 212....... 242....... 25 kg 100 kg D 40 dithiopyrophosphate. Tetraethyl silicate........ 3 UN1292 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Tetraethylammonium Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... perchlorate (dry). Tetraethylenepentamine..... 8 UN2320 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... 1,1,1,2-Tetrafluoroethane 2.2 UN3159 ....... 2.2...... T50 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... or Refrigerant gas R 134a. Tetrafluoroethylene, 2.1 UN1081 ....... 2.1...... ................ 306.......... 304....... None...... Forbidden 150 kg E 40 stabilized. Tetrafluoromethane or 2.2 UN1982 ....... 2.2...... ................ None......... 302....... None...... 75 kg 150 kg A ....... Refrigerant gas R 14. 1,2,3,6- 3 UN2498 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Tetrahydrobenzaldehyde. Tetrahydrofuran............ 3 UN2056 II 3........ IB2, T4, TP1 None......... 202....... 242....... 5 L 60 L B ....... Tetrahydrofurfurylamine.... 3 UN2943 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Tetrahydrophthalic 8 UN2698 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... anhydrides with more than TP33 0.05 percent of maleic anhydride. 1,2,3,6-Tetrahydropyridine. 3 UN2410 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Tetrahydrothiophene........ 3 UN2412 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Tetramethylammonium 8 UN3423 II 8........ B2, IB8, IP2, 154.......... 213....... 240....... 15 kg#
Passage 30450 kg A 52 hydroxide, solid. IP4, T3, TP33 Tetramethylammonium 8 UN1835 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L A 52 hydroxide solution. ........................... ........... ................. III 8........ B2, IB3, T7, TP2 154.......... 203....... 241....... 5 L 60 L A 52 Tetramethylene diperoxide Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dicarbamide. Tetramethylsilane.......... 3 UN2749 I 3........ A7, T14, TP2 None......... 201....... 243....... Forbidden 30 L D ....... Tetranitro diglycerin...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetranitroaniline.......... 1.1D UN0207 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... + Tetranitromethane.......... 5.1 UN1510 I 5.1, 6.1. 2, B9, B14, B32, None......... 227....... None...... Forbidden Forbidden D 40, 66 B74, T20, TP2, TP13, TP38, TP44 2,3,4,6-Tetranitrophenol... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 2,3,4,6-Tetranitrophenyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... methyl nitramine. 2,3,4,6- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetranitrophenylnitramine. Tetranitroresorcinol (dry). Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 2,3,5,6-Tetranitroso-1,4- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dinitrobenzene. 2,3,5,6-Tetranitroso Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitrobenzene (dry). Tetrapropylorthotitanate... 3 UN2413 III 3........ B1, IB3, T4, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Tetrazene, see Guanyl ........... ................. ....... ......... ................ ............. .......... ...#
Passage 305....... ........... ........... .......... ....... nitrosaminoguanyltetrazene. Tetrazine (dry)............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetrazol-1-acetic acid..... 1.4C UN0407 II 1.4C..... ................ None......... 62........ None...... Forbidden 75 kg 09 ....... 1H-Tetrazole............... 1.1D UN0504 ....... 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden B 1E, 5E Tetrazolyl azide (dry)..... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tetryl, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitrophenylmethylnitram ine. A I W Textile waste, wet......... 4.2 UN1857 III 4.2...... ................ 151.......... 213....... 240....... Forbidden Forbidden A ....... Thallium chlorate.......... 5.1 UN2573 II 5.1, 6.1. IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 TP33 Thallium compounds, n.o.s.. 6.1 UN1707 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Thallium nitrate........... 6.1 UN2727 II 6.1, 5.1. IB6, IP2, T3, 153.......... 212....... 242....... 5 kg 25 kg A ....... TP33 4-Thiapentanal............. 6.1 UN2785 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L D 25, 49 Thioacetic acid............ 3 UN2436 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Thiocarbamate pesticide, 3 UN2772 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP13, 150.......... 202....... 243....... 1 L 60 L B 40 TP27 Thiocarbamate pesticide, 6.1 UN3005 I 6.1, 3... T14, TP2, TP13 None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... IB3, T7, TP2, 153......#
Passage 306.... 203....... 242....... 60 L 220 L A 40 TP28 Thiocarbamate pesticide, 6.1 UN3006 I 6.1...... T14, TP2, TP13 None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Thiocarbamate pesticides, 6.1 UN2771 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 solid, toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33#
Passage 307Thiocarbonylchloride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Thiophosgene. Thioglycol................. 6.1 UN2966 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Thioglycolic acid.......... 8 UN1940 II 8........ A7, B2, IB2, 154.......... 202....... 242....... 1 L 30 L A ....... N34, T7, TP2 Thiolactic acid............ 6.1 UN2936 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Thionyl chloride........... 8 UN1836 I 8........ B6, B10, N34, None......... 201....... 243....... Forbidden Forbidden C 40 T10, TP2, TP12, TP13 Thiophene.................. 3 UN2414 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B 40 + Thiophosgene............... 6.1 UN2474 II 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden B 40, 52 B74, N33, N34, T20, TP2, TP38, TP45 Thiophosphoryl chloride.... 8 UN1837 II 8........ A3, A7, B2, B8, None......... 202....... 242....... Forbidden 30 L C 40 B25, IB2, N34, T7, TP2 Thiourea dioxide........... 4.2 UN3341 II 4.2...... IB6, IP2, T3, None......... 212....... 241....... 15 kg 50 kg D ....... TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg D ....... TP33 Tin chloride, fuming, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Stannic chloride, anhydrous. Tin perchloride or Tin ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... tetrachloride, see Stannic chloride, anhydrous. Tinctures, medicinal....... 3 UN1293 II 3........ IB2, T4, TP1, 150.......... 202....... 242....... 5 L 60 L B ....... TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Tinning flux, see Zinc ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... chloride. Titanium disulphide........ 4.2 UN3174 III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg A ....... TP33#
Passage 308Titanium hydride........... 4.1 UN1871 II 4.1...... A19, A20, IB4, None......... 212....... 241....... 15 kg 50 kg E ....... N34, T3, TP33 Titanium powder, dry....... 4.2 UN2546 I 4.2...... ................ None......... 211....... 242....... Forbidden Forbidden D ....... ........................... ........... ................. II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg D ....... IP2, N5, N34, T3, TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg D ....... TP33 Titanium powder, wetted 4.1 UN1352 II 4.1...... A19, A20, IB6, None......... 212....... 240....... 15 kg 50 kg E 74 with not less than 25 IP2, N34, T3, percent water (a visible TP33 excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Titanium sponge granules or 4.1 UN2878 III 4.1...... A1, IB8, IP3, None......... 213....... 240....... 25 kg 100 kg D 74 Titanium sponge powders. T1, TP33 + Titanium tetrachloride..... 8 UN1838 II 8, 6.1... 2, B7, B9, B14, None......... 227....... 244....... Forbidden Forbidden C 40 B32, B74, B77, T20, TP2, TP13, TP38, TP45 Titanium trichloride 8 UN2869 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A 40 mixtures. IP4, N34, T3, TP33 ........................... ........... ................. III 8........ A7, IB8, IP3, 154.......... 213....... 240....... 25 kg 100 kg A 40 N34, T1, TP33 Titanium trichloride, 4.2 UN2441 I 4.2, 8... N34 None......... 181....... 244....... Forbidden Forbidden D 40 pyrophoric or Titanium trichloride mixtures, pyrophoric. TNT mixed with aluminum, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Tritonal. TNT, see Trinitrotoluene, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... etc. Toluene.................... 3 UN1294 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... + Toluene diisocyanate....... 6.1 UN2078 II 6.1...... IB2, T7, TP2, 153.......... 202....... 243....... 5 L 60 L D 25, 40 TP13 Toluene sulfonic acid, see ........... ................. ....... ......... ......#
Passage 309.......... ............. .......... .......... ........... ........... .......... ....... Alkyl, or Aryl sulfonic acid etc. + Toluidines, liquid......... 6.1 UN1708 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Toluidines, solid.......... 6.1 UN3451 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 2,4-Toluylenediamine, solid 6.1 UN1709 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... or 2,4-Toluenediamine, TP33 solid. 2,4-Toluylenediamine 6.1 UN3418 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... solution or 2,4- Toluenediamine solution. Torpedoes, liquid fueled, 1.3J UN0450 II 1.3J..... ................ ............. 62........ None...... Forbidden Forbidden 04 23E with inert head. Torpedoes, liquid fueled, 1.1J UN0449 II 1.1J..... ................ ............. 62........ None...... Forbidden Forbidden 04 23E with or without bursting charge. Torpedoes with bursting 1.1E UN0329 II 1.1E..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... charge.#
Passage 310Torpedoes with bursting 1.1F UN0330 II 1.1F..... ................ ............. 62........ None...... Forbidden Forbidden 08 ....... charge. Torpedoes with bursting 1.1D UN0451 II 1.1D..... ................ ............. 62........ None...... Forbidden Forbidden 03 ....... charge. G Toxic by inhalation liquid, 6.1 UN3381 I 6.1...... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 n.o.s. with an inhalation B72, T22, TP2, toxicity lower than or TP13, TP27, equal to 200 ml/m3 and TP38, TP44 saturated vapor concentration greater than or equal to 500 LC50. G Toxic by inhalation liquid, 6.1 UN3382 I 6.1...... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 n.o.s. with an inhalation B74, T20, TP2, toxicity toxicity lower TP13, TP27, than or equal to 1000 ml/ TP38, TP4527, m3 and saturated vapor TP38, TP4513 concentration greater than or equal to 10 LC50. G Toxic by inhalation liquid, 6.1 UN3383 I 6.1, 3... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 flammable, n.o.s. with an B72, T22, TP2, inhalation toxicity lower TP13, TP27, than or equal to 200 ml/m3 TP38, TP44 and saturated vapor concentration greater than or equal to 500 LC50. G Toxic by inhalation liquid, 6.1 UN3384 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 flammable, n.o.s. with an B74, T20, TP2, inhalation toxicity lower TP13, TP27, than or equal to 1000 ml/ TP38, TP45 m3 and saturated vapor concentration greater than or equal to 10 LC50. G Toxic by inhalation liquid, 6.1 UN3385 I 6.1, 4.3. 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 water-reactive, n.o.s. B72, T22, TP2, with an inhalation TP13, TP38, TP44 toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50. G Toxic by inhalation liquid, 6.1 UN3386 I 6.1, 4.3. 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 water-reactive, n.o.s. B74, T20, TP2, with an inhalation TP13, TP38, TP44 toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50. G Toxic by inhalation liquid, 6.1 UN3387 I 6.1, 5.1. 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 oxidizing, n.o.s. with an B72, T22, TP2, inhalation toxicity lower TP13, TP38, TP4#
Passage 3114 than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50. G Toxic by inhalation liquid, 6.1 UN3388 I 6.1, 5.1. 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 oxidizing, n.o.s. with an T20, TP2, TP13, inhalation toxicity lower TP38, TP44 than or equal to 1000 ml/ m3 and saturated vapor concentration greater than or equal to 10 LC50. G Toxic by inhalation liquid, 6.1 UN3389 I 6.1, 8... 1, B9, B14, B30, None......... 226....... 244....... Forbidden Forbidden D 40 corrosive, n.o.s. with an B72, T22, TP2, inhalation toxicity lower TP13, TP27, than or equal to 200 ml/m3 TP38, TP44 and saturated vapor concentration greater than or equal to 500 LC50. G Toxic by inhalation liquid, 6.1 UN3390 I 6.1, 8... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 corrosive, n.o.s. with an B74, T20, TP2, inhalation toxicity lower TP13, TP27, than or equal to 1000 ml/ TP38, TP45 m3 and saturated vapor concentration greater than or equal to 10 LC50. G Toxic liquid, corrosive, 6.1 UN3289 I 6.1, 8... T14, TP2, TP13, None......... 201....... 243....... 0.5 L 2.5 L A ....... inorganic, n.o.s.. TP27 G Toxins, extracted from 6.1 UN3172 II 6.1...... 141, IB2 None......... 202....... 243....... 5 L 60 L B 40 living sources, liquid, n.o.s.. ........................... ........... ................. III 6.1...... 141, IB3 153.......... 203....... 241....... 60 L 220 L B 40 G Toxic liquid, corrosive, 6.1 UN3289 II 6.1, 8... IB2, T11, TP2, 153.......... 202....... 243....... 1 L 30 L A ....... inorganic, n.o.s.. TP27 G Toxic liquid, inorganic, 6.1 UN3287 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L A ....... n.o.s.. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L A ....... TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A ....... TP28 G Toxic liquids, corrosive, 6.1 UN2927 I 6.1, 8... T14, TP2, TP13, None......... 201....... 243....... 0.5 L 2.5 L B 40 organic, n.o.s.. TP27 ........................... ........... ................. II 6.1, 8... IB2, T11, TP2, 153.......... 202....... 243....... 1 L 30 L B 40 TP27 G Toxic liquids, flammable, 6.1 UN2929 I 6.1, 3... T14, TP2, TP13, None......... 20#
Passage 3121....... 243....... 1 L 30 L B 40 organic, n.o.s.. TP27 ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 G Toxic, liquids, organic, 6.1 UN2810 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 n.o.s.. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP1, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 G Toxic liquids, oxidizing, 6.1 UN3122 I 6.1, 5.1. A4 None......... 201....... 243....... Forbidden 2.5 L C ....... n.o.s.. ........................... ........... ................. II 6.1, 5.1. IB2 153.......... 202....... 243....... 1 L 5 L C ....... G Toxic liquids, water- 6.1 UN3123 I 6.1, 4.3. A4 None......... 201....... 243....... Forbidden 1 L E 40 reactive, n.o.s..#
Passage 313........................... ........... ................. II 6.1, 4.3. IB2 None......... 202....... 243....... 1 L 5 L E 40 G Toxic solid, corrosive, 6.1 UN3290 I 6.1, 8... IB7, T6, TP33 None......... 211....... 242....... 1 kg 25 kg A ....... inorganic, n.o.s.. ........................... ........... ................. II 6.1, 8... IB6, IP2, T3, 153.......... 212....... 242....... 15 kg 50 kg A ....... TP33 G Toxic solid, inorganic, 6.1 UN3288 I 6.1...... IB7, T6, TP33 None......... 211....... 242....... 5 kg 50 kg A ....... n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 G Toxic solids, corrosive, 6.1 UN2928 I 6.1, 8... IB7, T6, TP33 None......... 211....... 242....... 1 kg 25 kg B 40 organic, n.o.s.. ........................... ........... ................. II 6.1, 8... IB6, IP2, T3, 153.......... 212....... 242....... 15 kg 50 kg B 40 TP33 G Toxic solids, flammable, 6.1 UN2930 I 6.1, 4.1. IB6, T6, TP33 None......... 211....... 242....... 1 kg 15 kg B ....... organic, n.o.s.. ........................... ........... ................. II 6.1, 4.1. IB8, IP2, IP4, 153.......... 212....... 242....... 15 kg 50 kg B ....... T3, TP33 G Toxic solids, organic, 6.1 UN2811 I 6.1...... IB7, T6, TP33 None......... 211....... 242....... 5 kg 50 kg B ....... n.o.s.. ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 G Toxic solids, oxidizing, 6.1 UN3086 I 6.1, 5.1. T6, TP33 None......... 211....... 242....... 1 kg 15 kg C ....... n.o.s.. ........................... ........... ................. II 6.1, 5.1. IB6, IP2, T3, 153.......... 212....... 242....... 15 kg 50 kg C ....... TP33 G Toxic solids, self-heating, 6.1 UN3124 I 6.1, 4.2. A5, T6, TP33 None......... 211....... 242....... 5 kg 15 kg D 40 n.o.s.. ........................... ........... ................. II 6.1, 4.2. IB6, IP2, T3, None......... 212....... 242....... 15 kg 50 kg D 40 TP33 G Toxic solids,#
Passage 314water- 6.1 UN3125 I 6.1, 4.3. A5, T6, TP33 None......... 211....... 242....... 5 kg 15 kg D 40 reactive, n.o.s.. ........................... ........... ................. II 6.1, 4.3. IB6, IP2, T3, 153.......... 212....... 242....... 15 kg 50 kg D 40 TP33 D Toy Caps................... 1.4S NA0337 II 1.4S..... ................ None......... 62........ None...... 25 kg 100 kg 05 ....... Tracers for ammunition..... 1.3G UN0212 II 1.3G..... ................ None......... 62........ None...... Forbidden Forbidden 07 ....... Tracers for ammunition..... 1.4G UN0306 II 1.4G..... ................ None......... 62........ None...... Forbidden 75 kg 06 ....... Tractors, see Vehicle, etc. ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Tri-(b-nitroxyethyl) Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... ammonium nitrate. Triallyl borate............ 6.1 UN2609 III 6.1...... IB3 153.......... 203....... 241....... 60 L 220 L A 13 Triallylamine.............. 3 UN2610 III 3, 8..... B1, IB3, T4, TP1 None......... 203....... 242....... 5 L 60 L A 40 Triazine pesticides, 3 UN2764 I 3, 6.1... T14, TP2, TP13, None......... 201....... 243....... Forbidden 30 L B 40 liquid, flammable, toxic, TP27 flash point less than 23 degrees C. ........................... ........... ................. II 3, 6.1... IB2, T11, TP2, 150.......... 202....... 243....... 1 L 60 L B 40 TP13, TP27 Triazine pesticides, 6.1 UN2998 I 6.1...... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic. TP27 ........................... ........... ................. II 6.1...... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1...... IB3, T7, TP2, 153.......... 203....... 241....... 60 L 220 L A 40 TP28 Triazine pesticides, 6.1 UN2997 I 6.1, 3... T14, TP2, TP13, None......... 201....... 243....... 1 L 30 L B 40 liquid, toxic, flammable, TP27 flash point not less than 23 degrees C. ........................... ........... ................. II 6.1, 3... IB2, T11, TP2, 153.......... 202....... 243....... 5 L 60 L B 40 TP13, TP27 ........................... ........... ................. III 6.1, 3... IB3, T7, TP2,#
Passage 315153.......... 203....... 242....... 60 L 220 L A 40 TP28 Triazine pesticides, solid, 6.1 UN2763 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 40 toxic. TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A 40 T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 TP33 Tributylamine.............. 6.1 UN2542 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Tributylphosphane.......... 4.2 UN3254 I 4.2...... T21, TP7, TP33 None......... 211....... 242....... Forbidden Forbidden D 136#
Passage 316Trichloro-s-triazinetrione ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dry, with more than 39 percent available chlorine, see Trichloroisocyanuric acid, dry. Trichloroacetic acid....... 8 UN1839 II 8........ A7, IB8, IP2, 154.......... 212....... 240....... 15 kg 50 kg A ....... IP4, N34, T3, TP33 Trichloroacetic acid, 8 UN2564 II 8........ A3, A6, A7, B2, 154.......... 202....... 242....... 1 L 30 L B ....... solution. IB2, N34, T7, TP2 ........................... ........... ................. III 8........ A3, A6, A7, IB3, 154.......... 203....... 241....... 5 L 60 L B 8 N34, T4, TP1 + Trichloroacetyl chloride... 8 UN2442 II 8, 6.1... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden D 40 B74, N34, T20, TP2, TP38, TP45 Trichlorobenzenes, liquid.. 6.1 UN2321 III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Trichlorobutene............ 6.1 UN2322 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 25, 40 1,1,1-Trichloroethane...... 6.1 UN2831 III 6.1...... IB3, N36, T4, 153.......... 203....... 241....... 60 L 220 L A 40 TP1 Trichloroethylene.......... 6.1 UN1710 III 6.1...... IB3, N36, T4, 153.......... 203....... 241....... 60 L 220 L A 40 TP1 Trichloroisocyanuric acid, 5.1 UN2468 II 5.1...... IB8, IP4, T3, 152.......... 212....... 240....... 5 kg 25 kg A 13 dry. TP33 Trichloromethyl perchlorate Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trichlorosilane............ 4.3 UN1295 I 4.3, 3, 8 N34, T14, TP2, None......... 201....... 244....... Forbidden Forbidden D 21, 28, TP7, TP13 40, 49, 100 Tricresyl phosphate with 6.1 UN2574 II 6.1...... A3, IB2, N33, 153.......... 202....... 243....... 5 L 60 L A ....... more than 3 percent ortho N34, T7, TP2 isomer. Triethyl phosphite......... 3 UN2323 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Triethylamine.............. 3 UN1296 II 3, 8..... IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40 Triethylenetetramine....... 8 UN2259 II 8........ B2, IB2, T7, TP2 154.......... 202....... 242....... 1 L 30 L B 40, 52 Trifluoroacetic acid....... 8 UN2699 I 8........ A3, A6, A7, B4, None......... 201..#
Passage 317..... 243....... 0.5 L 2.5 L B 12, 40 N3, N34, N36, T10, TP2, TP12 Trifluoroacetyl chloride... 2.3 UN3057 ....... 2.3, 8... 2, B7, B9, B14, None......... 304....... 314, 315.. Forbidden Forbidden D 40 T50, TP21 Trifluorochloroethylene, 2.3 UN1082 ....... 2.3, 2.1. 3, B14, T50 None......... 304....... 314, 315.. Forbidden Forbidden D 40 stabilized. Trifluoromethane or 2.2 UN1984 ....... 2.2...... ................ 306.......... 304....... 314, 315.. 75 kg 150 kg A ....... Refrigerant gas R 23. 1,1,1-Trifluoroethane or 2.1 UN2035 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Refrigerant gas, R 143a. Trifluoromethane, 2.2 UN3136 ....... 2.2...... T75, TP5 306.......... None...... 314, 315.. 50 kg 500 kg D ....... refrigerated liquid. 2-Trifluoromethylaniline... 6.1 UN2942 III 6.1...... IB3 153.......... 203....... 241....... 60 L 220 L A ....... 3-Trifluoromethylaniline... 6.1 UN2948 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A 40 Triformoxime trinitrate.... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Triisobutylene............. 3 UN2324 III 3........ B1, IB3, T4, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Triisopropyl borate........ 3 UN2616 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L A ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... D Trimethoxysilane........... 6.1 NA9269 I 6.1, 3... 2, B9, B14, B32, None......... 227....... 244....... Forbidden Forbidden E 40 B74, T20, TP4, TP12, TP13, TP38, TP45 Trimethyl borate........... 3 UN2416 II 3........ IB2, T7, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Trimethyl phosphite........ 3 UN2329 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... 1,3,5-Trimethyl-2,4,6- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitrobenzene. Trimethylacetyl chloride... 6.1 UN2438 I 6.1, 8, 3 2, B3, B9, B14, None......... 227....... 244....... Forbidden Forbidden D 25, 40 B32, B74, N34, T20, TP2, TP13, TP38, TP45 Trimethylamine, anhydrous.. 2.1 UN1083 ....... 2.1...... T50 306......#
Passage 318.... 304....... 314, 315.. Forbidden 150 kg B 40 Trimethylamine, aqueous 3 UN1297 I 3, 8..... T11, TP1 None......... 201....... 243....... 0.5 L 2.5 L D 40, 135 solutions with not more than 50 percent trimethylamine by mass. ........................... ........... ................. II 3, 8..... B1, IB2, T7, TP1 150.......... 202....... 243....... 1 L 5 L B 40, 41 ........................... ........... ................. III 3, 8..... B1, IB3, T7, TP1 150.......... 203....... 242....... 5 L 60 L A 40, 41 1,3,5-Trimethylbenzene..... 3 UN2325 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Trimethylchlorosilane...... 3 UN1298 II 3, 8..... A3, A7, B77, 150.......... 202....... 243....... 1 L 5 L E 40 IB2, N34, T7, TP2, TP13 Trimethylcyclohexylamine... 8 UN2326 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Trimethylene glycol Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diperchlorate. Trimethylhexamethylene 6.1 UN2328 III 6.1...... IB3, T4, TP2, 153.......... 203....... 241....... 60 L 220 L B ....... diisocyanate. TP13 Trimethylhexamethylenediami 8 UN2327 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... nes. Trimethylol nitromethane Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... trinitrate. Trinitro-meta-cresol....... 1.1D UN0216 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E#
Passage 3192,4,6-Trinitro-1,3- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diazobenzene. 2,4,6-Trinitro-1,3,5- Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... triazido benzene (dry). Trinitroacetic acid........ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitroacetonitrile....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitroamine cobalt....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitroaniline or 1.1D UN0153 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Picramide. Trinitroanisole............ 1.1D UN0213 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Trinitrobenzene (picryl 4.1 UN3365 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 chloride), wetted, with N41, N84 not less than 10% water by mass. Trinitrobenzene, wetted, 4.1 UN3367 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 with not less than 10% N41, N84 water, by mass. Trinitrobenzene, dry or 1.1D UN0214 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... wetted with less than 30 percent water, by mass. Trinitrobenzene, wetted 4.1 UN1354 I 4.1...... 23, A2, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 28 with not less than 30 N41 percent water, by mass. Trinitrobenzenesulfonic 1.1D UN0386 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E acid. Trinitrobenzoic acid, dry 1.1D UN0215 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... or wetted with less than 30 percent water, by mass. Trinitrobenzoic acid, 4.1 UN3368 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 wetted with not less than N41, N84 10% water by mass. Trinitrobenzoic acid, 4.1 UN1355 I 4.1...... 23, A2, A8, A19, N#
Passage 320one......... 211....... None...... 0.5 kg 0.5 kg E 28 wetted with not less than N41 30 percent water, by mass. Trinitrochlorobenzene or 1.1D UN0155 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Picryl chloride. Trinitroethanol............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitroethylnitrate....... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitrofluorenone......... 1.1D UN0387 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Trinitromethane............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... 1,3,5-Trinitronaphthalene.. Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Trinitronaphthalene........ 1.1D UN0217 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Trinitrophenetole.......... 1.1D UN0218 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Trinitrophenol (picric 4.1 UN3364 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 acid), wetted, with not N41, N84 less than 10 percent water by mass. Trinitrophenol or Picric 1.1D UN0154 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E acid, dry or wetted with less than 30 percent water, by mass. Trinitrophenol, wetted with 4.1 UN1344 I 4.1...... 23, A8, A19, N41 None......... 211....... None...... 1 kg 15 kg E 28, 36 not less than 30 percent water, by mass. 2,4,6-Trinitrophenyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... guanidine (dry). 2,4,6-Trinitrophenyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitramine. 2,4,6-Trinitrophenyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .........#
Passage 321. ....... trimethylol methyl nitramine trinitrate (dry). Trinitrophenylmethylnitrami 1.1D UN0208 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... ne or Tetryl. Trinitroresorcinol or 1.1D UN0219 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass. Trinitroresorcinol, wetted 1.1D UN0394 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass. 2,4,6-Trinitroso-3-methyl Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitraminoanisole. Trinitrotetramine cobalt Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... nitrate. Trinitrotoluene and 1.1D UN0388 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Trinitrobenzene mixtures or TNT and trinitrobenzene mixtures or TNT and hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures. Trinitrotoluene mixtures 1.1D UN0389 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... containing Trinitrobenzene and Hexanitrostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene. Trinitrotoluene or TNT, dry 1.1D UN0209 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... or wetted with less than 30 percent water, by mass. Trinitrotoluene (TNT), 4.1 UN3366 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 wetted, with not less than N41, N84 10 percent water by mass. Trinitrotoluene, wetted 4.1 UN1356 I 4.1...... 23, A2, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 28 with not less than 30 N41 percent water, by mass. Tripropylamine............. 3 UN2260 III 3, 8..... B1, IB3, T4, TP1 150.......... 203....... 242....... 5 L 60 L A 40 Tripropylene............... 3 UN2057 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3....#
Passage 322.... B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Tris-(1- 6.1 UN2501 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... aziridinyl)phosphine oxide, solution. ........................... ........... ................. III 6.1...... IB3, T4, TP1 153.......... 203....... 241....... 60 L 220 L A ....... Tris, bis-bifluoroamino Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... diethoxy propane (TVOPA). Tritonal................... 1.1D UN0390 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 10 ....... Tungsten hexafluoride...... 2.3 UN2196 ....... 2.3, 8... 2 None......... 338....... None...... Forbidden Forbidden D 40 Turpentine................. 3 UN1299 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Turpentine substitute...... 3 UN1300 I 3........ T11, TP1, TP8, None......... 201....... 243....... 1 L 30 L B ....... TP27 ........................... ........... ................. II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Undecane................... 3 UN2330 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A .......#
Passage 323Urea hydrogen peroxide..... 5.1 UN1511 III 5.1, 8... A1, A7, A29, 152.......... 213....... 240....... 25 kg 100 kg A 13 IB8, IP3, T1, TP33 Urea nitrate, dry or wetted 1.1D UN0220 II 1.1D..... 119 None......... 62........ None...... Forbidden Forbidden 10 ....... with less than 20 percent water, by mass. Urea nitrate, wetted, with 4.1 UN3370 I 4.1...... 162, A8, A19, None......... 211....... None...... 0.5 kg 0.5 kg E 36 not less than 10 percent N41, N84 water by mass. Urea nitrate, wetted with 4.1 UN1357 I 4.1...... 23, 39, A8, A19, None......... 211....... None...... 1 kg 15 kg E 28, 36 not less than 20 percent N41 water, by mass. Urea peroxide, see Urea ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... hydrogen peroxide. Valeraldehyde.............. 3 UN2058 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Valeric acid, see Corrosive ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... liquids, n.o.s.. Valeryl chloride........... 8 UN2502 II 8, 3..... A3, A6, A7, B2, 154.......... 202....... 243....... 1 L 30 L C 40 IB2, N34, T7, TP2 Vanadium compound, n.o.s... 6.1 UN3285 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg B ....... TP33 ........................... ........... ................. II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg B ....... T3, TP33 ........................... ........... ................. III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A ....... TP33 Vanadium oxytrichloride.... 8 UN2443 II 8........ A3, A6, A7, B2, 154.......... 202....... 242....... Forbidden 30 L C 40 B16, IB2, N34, T7, TP2 Vanadium pentoxide, non- 6.1 UN2862 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 40 fused form. TP33 Vanadium tetrachloride..... 8 UN2444 I 8........ A3, A6, A7, B4, None......... 201....... 243....... Forbidden 2.5 L C 40 N34, T10, TP2 Vanadium trichloride....... 8 UN2475 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A 40 TP33 Vanadyl sulfate............ 6.1 UN2931 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Vehicle, flammable gas 9#
Passage 324UN3166 ....... 9........ 135, 157 220.......... 220....... 220....... Forbidden No limit A ....... powered. Vehicle, flammable liquid 9 UN3166 ....... 9........ 135, 157 220.......... 220....... 220....... No limit No limit A ....... powered. Very signal cartridge, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Cartridges, signal. Vinyl acetate, stabilized.. 3 UN1301 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Vinyl bromide, stabilized.. 2.1 UN1085 ....... 2.1...... T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Vinyl butyrate, stabilized. 3 UN2838 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... Vinyl chloride, stabilized. 2.1 UN1086 ....... 2.1...... 21, B44, T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 Vinyl chloroacetate........ 6.1 UN2589 II 6.1, 3... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Vinyl ethyl ether, 3 UN1302 I 3........ A3, T11, TP2 None......... 201....... 243....... 1 L 30 L D ....... stabilized. Vinyl fluoride, stabilized. 2.1 UN1860 ....... 2.1...... ................ 306.......... 304....... 314, 315.. Forbidden 150 kg E 40 Vinyl isobutyl ether, 3 UN1304 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... stabilized. Vinyl methyl ether, 2.1 UN1087 ....... 2.1...... B44, T50 306.......... 304....... 314, 315.. Forbidden 150 kg B 40 stabilized. Vinyl nitrate polymer...... Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Vinylidene chloride, 3 UN1303 I 3........ T12, TP2, TP7 150.......... 201....... 243....... 1 L 30 L E 40 stabilized. Vinylpyridines, stabilized. 6.1 UN3073 II 6.1, 3, 8 IB1, T7, TP2, 153.......... 202....... 243....... 1 L 30 L B 40 TP13 Vinyltoluenes, stabilized.. 3 UN2618 III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Vinyltrichlorosilane, 3 UN1305 I 3, 8..... A3, A7, B6, N34, None......... 201....... 243....... Forbidden 2.5 L B 40 stabilized. T11, TP2, TP13 Warheads, rocket with 1.4D UN0370 II 1.4D..... ................ None......... 62........ None...... Forbidden 75 kg 02 ....... burster or expelling charge. Warheads, rocket with 1.#
Passage 3254F UN0371 II 1.4F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... burster or expelling charge. Warheads, rocket with 1.1D UN0286 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... bursting charge. Warheads, rocket with 1.2D UN0287 II 1.2D..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... bursting charge. Warheads, rocket with 1.1F UN0369 II 1.1F..... ................ None......... 62........ None...... Forbidden Forbidden 08 ....... bursting charge. Warheads, torpedo with 1.1D UN0221 II 1.1D..... ................ None......... 62........ None...... Forbidden Forbidden 03 ....... bursting charge. G Water-reactive liquid, 4.3 UN3129 I 4.3, 8... ................ None......... 201....... 243....... Forbidden 1 L D ....... corrosive, n.o.s.. ........................... ........... ................. II 4.3, 8... IB1 None......... 202....... 243....... 1 L 5 L E 85 ........................... ........... ................. III 4.3, 8... IB2 None......... 203....... 242....... 5 L 60 L E ....... G Water-reactive liquid, 4.3 UN3148 I 4.3...... ................ None......... 201....... 244....... Forbidden 1 L E 40 n.o.s.. ........................... ........... ................. II 4.3...... IB1 None......... 202....... 243....... 1 L 5 L E 40 ........................... ........... ................. III 4.3...... IB2 None......... 203....... 242....... 5 L 60 L E 40 G Water-reactive liquid, 4.3 UN3130 I 4.3, 6.1. A4 None......... 201....... 243....... Forbidden 1 L D ....... toxic, n.o.s.. ........................... ........... ................. II 4.3, 6.1. IB1 None......... 202....... 243....... 1 L 5 L E 85 ........................... ........... ................. III 4.3, 6.1. IB2 None......... 203....... 242....... 5 L 60 L E 85 G Water-reactive solid, 4.3 UN3131 I 4.3, 8... IB4, IP1, N40 None......... 211....... 242....... Forbidden 15 kg D ....... corrosive, n.o.s.. ........................... ........... ................. II 4.3, 8... IB6, IP2, T3, 151.......... 212....... 242....... 15 kg 50 kg E 85 TP33 ........................... ........... ................. III 4.3, 8... IB8, IP4, T1, 151.......... 213....... 241....... 25 kg 100 kg E 85 TP33#
Passage 326G Water-reactive solid, 4.3 UN3132 I 4.3, 4.1. IB4, N40 None......... 211....... 242....... Forbidden 15 kg D ....... flammable, n.o.s.. ........................... ........... ................. II 4.3, 4.1. IB4, T3, TP33 151.......... 212....... 242....... 15 kg 50 kg E ....... ........................... ........... ................. III 4.3, 4.1. IB6, T1, TP33 151.......... 213....... 241....... 25 kg 100 kg E ....... G Water-reactive solid, 4.3 UN2813 I 4.3...... IB4, N40 None......... 211....... 242....... Forbidden 15 kg E 40 n.o.s.. ........................... ........... ................. II 4.3...... IB7, IP2, T3, 151.......... 212....... 242....... 15 kg 50 kg E 40 TP33 ........................... ........... ................. III 4.3...... IB8, IP4, T1, 151.......... 213....... 241....... 25 kg 100 kg E 40 TP33 G Water-reactive, solid, 4.3 UN3133 II 4.3, 5.1. ................ None......... 214....... 214....... Forbidden Forbidden E 40 oxidizing, n.o.s.. ........................... ........... ................. III 4.3, 5.1. ................ None......... 214....... 214....... Forbidden Forbidden E 40 G Water-reactive solid, self- 4.3 UN3135 I 4.3, 4.2. N40 None......... 211....... 242....... Forbidden 15 kg E ....... heating, n.o.s.. ........................... ........... ................. II 4.3, 4.2. IB5, IP2, T3, None......... 212....... 242....... 15 kg 50 kg E ....... TP33 ........................... ........... ................. III 4.3, 4.2. IB8, IP4, T1, None......... 213....... 241....... 25 kg 100 kg E ....... TP33 G Water-reactive solid, 4.3 UN3134 I 4.3, 6.1. A8, IB4, IP1, None......... 211....... 242....... Forbidden 15 kg D ....... toxic, n.o.s.. N40 ........................... ........... ................. II 4.3, 6.1. IB5, IP2, T3, 151.......... 212....... 242....... 15 kg 50 kg E 85 TP33 ........................... ........... ................. III 4.3, 6.1. IB8, IP4, T1, 151.......... 213....... 241....... 25 kg 100 kg E 85 TP33 Wheel chair, electric, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Battery powered vehicle or Battery powered equipment. White acid, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Hydrofluoric acid. I#
Passage 327White asbestos (chrysotile, 9 UN2590 III 9........ 156, IB8, IP2, 155.......... 216....... 240....... 200 kg 200 kg A 34, 40 actinolite, anthophyllite, IP3, T1, TP33 tremolite). Wood preservatives, liquid. 3 UN1306 II 3........ 149, IB2, T4, 150.......... 202....... 242....... 5 L 60 L B ....... TP1, TP8 ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A 40 A I W Wool waste, wet............ 4.2 UN1387 III 4.2...... ................ 151.......... 213....... 240....... Forbidden Forbidden A ....... Xanthates.................. 4.2 UN3342 II 4.2...... IB6, IP2, T3, None......... 212....... 241....... 15 kg 50 kg D 40 TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg D 40 TP33 Xenon...................... 2.2 UN2036 ....... 2.2...... ................ 306.......... 302....... None...... 75 kg 150 kg A ....... Xenon, refrigerated liquid 2.2 UN2591 ....... 2.2...... T75, TP5 320.......... None...... None...... 50 kg 500 kg B ....... (cryogenic liquids). Xylenes.................... 3 UN1307 II 3........ IB2, T4, TP1 150.......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB3, T2, TP1 150.......... 203....... 242....... 60 L 220 L A ....... Xylenols, solid............ 6.1 UN2261 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Xylenols, liquid........... 6.1 UN3430 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Xylidines, liquid.......... 6.1 UN1711 II 6.1...... IB2, T7, TP2 153.......... 202....... 243....... 5 L 60 L A ....... Xylidines, solid........... 6.1 UN3452 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... T3, TP33 Xylyl bromide, liquid...... 6.1 UN1701 II 6.1...... A3, A6, A7, IB2, None......... 340....... None...... Forbidden 60 L D 40 N33, T7, TP2, TP13 Xylyl bromide, solid....... 6.1 UN3417 II 6.1...... A3, A6, A7, IB8, None......... 340....... None...... Forbidden 100 kg B 40 IP2, IP4, N33, T3, TP33 p-Xylyl diazide............ Forbidden ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Zinc ammonium nitrite....#
Passage 328.. 5.1 UN1512 II 5.1...... IB8, IP4, T3, None......... 212....... 242....... 5 kg 25 kg E ....... TP33 Zinc arsenate or Zinc 6.1 UN1712 II 6.1...... IB8, IP2, IP4, 153.......... 212....... 242....... 25 kg 100 kg A ....... arsenite or Zinc arsenate T3, TP33 and zinc arsenite mixtures. Zinc ashes................. 4.3 UN1435 III 4.3...... A1, A19, IB8, 151.......... 213....... 241....... 25 kg 100 kg A ....... IP4, T1, TP33 Zinc bisulfite solution, ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... see Bisulfites, aqueous solutions, n.o.s.. Zinc bromate............... 5.1 UN2469 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A 56, 58 IP3, T1, TP33#
Passage 329Zinc chlorate.............. 5.1 UN1513 II 5.1...... A9, IB8, IP2, 152.......... 212....... 242....... 5 kg 25 kg A 56, 58 IP4, N34, T3, TP33 Zinc chloride, anhydrous... 8 UN2331 III 8........ IB8, IP3, T1, None......... 213....... 240....... 25 kg 100 kg A ....... TP33 Zinc chloride, solution.... 8 UN1840 III 8........ IB3, T4, TP1 154.......... 203....... 241....... 5 L 60 L A ....... Zinc cyanide............... 6.1 UN1713 I 6.1...... IB7, IP1, T6, None......... 211....... 242....... 5 kg 50 kg A 52 TP33 Zinc dithionite or Zinc 9 UN1931 III None..... IB8, IP3, T1, 155.......... 204....... 240....... 100 kg 200 kg A 49 hydrosulfite. TP33 Zinc ethyl, see Diethylzinc ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Zinc fluorosilicate........ 6.1 UN2855 III 6.1...... IB8, IP3, T1, 153.......... 213....... 240....... 100 kg 200 kg A 52 TP33 Zinc hydrosulfite, see Zinc ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... dithionite. Zinc muriate solution, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Zinc chloride, solution. Zinc nitrate............... 5.1 UN1514 II 5.1...... IB8, IP4, T3, 152.......... 212....... 240....... 5 kg 25 kg A ....... TP33 Zinc permanganate.......... 5.1 UN1515 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg D 56, 58, TP33 138 Zinc peroxide.............. 5.1 UN1516 II 5.1...... IB6, IP2, T3, 152.......... 212....... 242....... 5 kg 25 kg A 13, 52, TP33 66, 75 Zinc phosphide............. 4.3 UN1714 I 4.3, 6.1. A19, N40 None......... 211....... None...... Forbidden 15 kg E 40, 52, 85 Zinc powder or Zinc dust... 4.3 UN1436 I 4.3, 4.2. A19, IB4, IP1, None......... 211....... 242....... Forbidden 15 kg A 52, 53 N40 ........................... ........... ................. II 4.3, 4.2. A19, IB7, IP2, None......... 212....... 242....... 15 kg 50 kg A 52, 53 T3, TP33 ........................... ........... ................. III 4.3, 4.2. IB8, IP4, T1, None......... 213....... 242....... 25 kg 100 kg A 52, 53 TP33 Zinc resinate.............. 4.1 UN2714 III 4.1...... A1, IB6, T1, 151.......... 213....... 240....... 25 kg 100 kg A ......#
Passage 330. TP33 Zinc selenate, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Zinc selenite, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Selenates or Selenites. Zinc silicofluoride, see ........... ................. ....... ......... ................ ............. .......... .......... ........... ........... .......... ....... Zinc fluorosilicate. Zirconium, dry, coiled 4.1 UN2858 III 4.1...... A1 151.......... 213....... 240....... 25 kg 100 kg A ....... wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns). Zirconium, dry, finished 4.2 UN2009 III 4.2...... A1, A19 None......... 213....... 240....... 25 kg 100 kg D ....... sheets, strip or coiled wire. Zirconium hydride.......... 4.1 UN1437 II 4.1...... A19, A20, IB4, None......... 212....... 240....... 15 kg 50 kg E ....... N34, T3, TP33 Zirconium nitrate.......... 5.1 UN2728 III 5.1...... A1, A29, IB8, 152.......... 213....... 240....... 25 kg 100 kg A ....... IP3, T1, TP33 Zirconium picramate, dry or 1.3C UN0236 II 1.3C..... ................ None......... 62........ None...... Forbidden Forbidden 10 5E wetted with less than 20 percent water, by mass. Zirconium picramate, wetted 4.1 UN1517 I 4.1...... 23, N41 None......... 211....... None...... 1 kg 15 kg D 28, 36 with not less than 20 percent water, by mass. Zirconium powder, dry...... 4.2 UN2008 I 4.2...... T21, TP7, TP33 None......... 211....... 242....... Forbidden Forbidden D ....... ........................... ........... ................. II 4.2...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg D ....... IP2, N5, N34, T3, TP33 ........................... ........... ................. III 4.2...... IB8, IP3, T1, None......... 213....... 241....... 25 kg 100 kg D ....... TP33 Zirconium powder, wetted 4.1 UN1358 II 4.1...... A19, A20, IB6, None......... 212....... 241....... 15 kg 50 kg E 74 with not less than 25 IP2, N34, T3, percent water (a visible TP33 excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Zirconium scrap............ 4.2 UN1932 III 4.2...... IB8, IP3, N34#
Passage 331, None......... 213....... 240....... Forbidden Forbidden D ....... T1, TP33 Zirconium suspended in a 3 UN1308 I 3........ ................ None......... 201....... 243....... Forbidden Forbidden B ....... liquid. ........................... ........... ................. II 3........ IB2 None......... 202....... 242....... 5 L 60 L B ....... ........................... ........... ................. III 3........ B1, IB2 150.......... 203....... 242....... 60 L 220 L B ....... Zirconium tetrachloride.... 8 UN2503 III 8........ IB8, IP3, T1, 154.......... 213....... 240....... 25 kg 100 kg A ....... TP33 * * * * * 10. In Appendix B to Sec. 172.101, the List of Marine Pollutants is amended by removing three entries, revising one entry and adding one entry in appropriate alphabetical order to read as follows: Appendix B to Sec. 172.101--List of Marine Pollutants List of Marine Pollutants ------------------------------------------------------------------------ S, M, P Marine Pollutant ------------------------------------------------------------------------ (1) (2) ------------------------------------------------------------------------ [Remove:]........................... Isoamyl mercaptan Pentanethiols Tetrachlorophenol [Revise:] PP.............................. 2, 6-Di-tert-Butylphenol [Add:] * * * * * ------------------------------------------------------------------------ 11. In Sec. 172.102: a. Paragraphs (b)(3), (b)(4) and (b)(8) are revised and a new paragraph (b)(9) is added. b. In paragraph (c)(1), Special Provisions 47, 135, and 137 are revised; Special Provisions 163, 164, 165, 166, 167, 170 and 171 are added; and Special Provision 143 and 153 are removed. c. In paragraph (c)(2), Special Provision A11 is revised and a new Special Provision A14 is added. d. The introductory text of paragraph (c)(3) is revised; in paragraph (c)(3) Special Provision B69 is revised and paragraph (c)(4) is revised. e. Paragraphs (c)(7)(viii) and (c)(8) are redesignated as paragraphs (c)(8) and (c)(9) respectively, the introductory paragraph of (c)(8) is revised, a new paragraph (c)(8)(ii) is added, Special Provisions TP3 and TP6 are revised and a new Special Provision TP32 is added. f. Paragraph (c)(7) is revised. The additions and revisions read as follows:#
Passage 332* * * * * (b) * * * (3) A code containing the letter ``B'' refers to a special provision that applies only to bulk packaging requirements. Unless otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs. (4) A code containing the letters ``IB'' or ``IP'' refers to a special provision that applies only to transportation in IBCs. * * * * * (8) A code containing the letters ``TP'' refers to a special provision for UN portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. (9) A code containing the letter ``W'' refers to a special provision that applies only to transportation by water. (c) * * * (1) * * *#
Passage 333* * * * * 47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Except when the liquids are fully absorbed in solid material contained in sealed bags, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed into a solid material are not subject to this subchapter provided there is no free liquid in the packet. * * * * * 135 The entries ``Vehicle, flammable gas powered'' or ``Vehicle, flammable liquid powered,'' as appropriate, must be used when internal combustion engines are installed in a vehicle. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. * * * * * 137 Cotton, dry; flax, dry; and sisal, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, ``Cotton Bales--Dimensions and Density'' (IBR, see Sec. 171.7 of this subchapter) to a density of not less than 360 kg/m \3\ (22.1 lb/ft \3\) for cotton, 400 kg/m \3\ (24.97 lb/ft \3\) for flax and 620 kg/m \3\ (38.71 lb/ft \3\) for sisal and transported in a freight container or closed transport vehicle. * * * * * 163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see Sec. 171.7 of this subchapter). 164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter). The material must be packaged so that the percentage of diluent does not fall below that stated in the approval, at any time during transportation. 165 These substances are susceptible to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). During the course of transportation, packages containing these substances m#
Passage 334ust be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas. 166 When transported in non-friable tablet form calcium hypochlorite, dry or hydrated, may be transported as a Packing Group III material. 167 These storage systems shall always be considered as containing hydrogen. 170 Air must be eliminated from the vapor space by nitrogen or other means. 171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in Sec. 173.127. * * * * * (2) ``A'' codes. These provisions apply only to transportation by aircraft: * * * * * A11 Only specification cylinders constructed of metals which are compatible with the hazardous material may be used. * * * * * A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with Sec. 173.306 of this subchapter when transported aboard an aircraft. * * * * * (3) ``B'' codes. These provisions apply only to bulk packagings. Unless otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs: * * * * * B69 Dry sodium cyanide or potassium cyanide may be shipped in sift- proof weather-resistant metal covered hopper cars, covered motor vehicles, portable tanks or non-specification bins. Bins must be approved by the Associate Administrator. * * * * * (4) Table 1 and Table 2--IB Codes and IP Special IBC Packing Provisions. These provisions apply only to transportation in IBCs. When no IBC code is assigned in the Sec. 172.101 Table for a specific proper shipping name, or in Sec. 173.225(e) for Type F organic peroxides, an IBC may not be used unless authorized by the Associate Administrator. The letter ``Z'' shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in Sec. 178.702(a)(2) of this subchapter to specify the material used for the outer packaging. Tables 1 and 2 follow:#
Passage 335Table 1.--IB Codes (IBC Codes) ------------------------------------------------------------------------ IBC code Authorized IBCs ------------------------------------------------------------------------ IB1................... Authorized IBCs: Metal (31A, 31B and 31N). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. IB2................... Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized. IB3................... Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 [deg]C (1.1 bar at 122 [deg]F), or 130 kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 3 for UN2672). IB4................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N). IB5................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1). IB6................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport. IB7................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F). Additional Requirement: Liners of wooden IBCs must be sift-proof. IB8................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible#
Passage 336(13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IB9................... IBCs are only authorized if approved by the Associate Administrator. ------------------------------------------------------------------------ Table 2.--IP Codes ------------------------------------------------------------------------ ------------------------------------------------------------------------ IP1................... IBCs must be packed in closed freight containers or a closed transport vehicle. IP2................... When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. IP3................... Flexible IBCs must be sift-proof and water- resistant or must be fitted with a sift-proof and water-resistant liner. IP4................... Flexible, fiberboard or wooden IBCs must be sift- proof and water-resistant or be fitted with a sift-proof and water-resistant liner. IP5................... IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. IP6................... Non-specification bulk bins are authorized. IP7................... For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter. IP8................... Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in Sec. 178.814 of this subchapter at a test pressure that is not less than 1.5 times the vapor pressure of the contents at 55 [deg]C (131 [deg]F). IP13.................. Transportation by vessel in IBCs is prohibited. IP14.................. Air shall be eliminated from the vapor space by nitrogen or other means. IP20.................. Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. ------------------------------------------------------------------------#
Passage 337* * * * * (7) ``T'' codes. (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. Liquefied compressed gases are assigned to portable tank instruction T50. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75. (ii) The following table specifies the portable tank requirements applicable to ``T'' Codes T1 through T22. Column 1 specifies the ``T'' Code. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by Sec. 180.605 of this subchapter must be conducted. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of Sec. 178.275(g)(3) of this subchapter for the pressure relief devices. When the word ``Normal'' is indicated, Sec. 178.275(g)(3) of this subchapter does not apply. Column 5 references the applicable requirements for bottom openings in part 178 of this subchapter or references ``Prohibited'' which means bottom openings are prohibited. The table follows:#
Passage 338Table of Portable Tank T Codes T1-T22 [Portable tank codes T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.] ---------------------------------------------------------------------------------------------------------------- Minimum Minimum shell thickness Portable tank test (in mm-reference steel) Pressure-relief Bottom opening instruction (1) pressure (See Sec. 178.274(d)) requirements (See Sec. requirements (See Sec. (bar) (2) (3) 178.275(g)) (4) 178.275(d)) (5) ---------------------------------------------------------------------------------------------------------------- T1................... 1.5 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(2) T2................... 1.5 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(3) T3................... 2.65 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(2) T4................... 2.65 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(3) T5................... 2.65 Sec. 178.274(d)(2)..... Sec. 178.275(g)(3).... Prohibited T6................... 4 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(2) T7................... 4 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(3) T8................... 4 Sec. 178.274(d)(2)..... Normal.................. Prohibited T9................... 4 6 mm..................... Normal.................. Prohibited T10.................. 4 6 mm..................... Sec. 178.275(g)(3).... Prohibited T11.................. 6 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(3) T12.................. 6 Sec. 178.274(d)(2)..... Sec. 178.275(g)(3).... Sec. 178.275(d)(3) T13.................. 6 6 mm..................... Normal.................. Prohibited T14.................. 6 6 mm..................... Sec. 178.275(g)(3).... Prohibited T15.................. 10 Sec. 178.274(d)(2)..... Normal.................. Sec. 178.275(d)(3) T16.................. 10 Sec. 178.274(d)(2)..... Sec. 178.275(g)(3).... Sec. 178.275(d)(3) T17.................. 10 6 mm..................... Normal.................. Sec. 178.275(d)(3) T18.................. 10 6 mm..................... Sec. 178.275(g)(3).... Sec. 178.275(d)(3) T19.................. 10 6 mm..................... Sec. 178.275(g)(3).... Prohibited T20.................. 10 8 mm.............#
Passage 339........ Sec. 178.275(g)(3).... Prohibited T21.................. 10 10 mm.................... Normal.................. Prohibited T22.................. 10 10 mm.................... Sec. 178.275(g)(3).... Prohibited ----------------------------------------------------------------------------------------------------------------#
Passage 340(iii) T50. When portable tank instruction T50 is referenced in Column (7) of the Sec. 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of Sec. 173.313 of this subchapter. (iv) T75. When portable tank instruction T75 is referenced in Column (7) of the Sec. 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of Sec. 178.277 of this subchapter. (v) UN and IM portable tank codes/special provisions. When a specific portable tank instruction is specified by a ``T'' Code in Column (7) of the Sec. 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the ``T'' Code. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and (D) With regard to bottom openings-- (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or (3) When no bottom openings are authorized, the alternative portable tank must not have bottom openings. (vi) Except when an organic peroxide is authorized under Sec. 173.225(g), if a hazardous material is not assigned a portable tank ``T'' Code or TP9 is referenced in Column (7) of the Sec. 172.101 Table, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. (8) ``TP'' codes. (i) These provisions apply to the transportation of hazardous materials in UN Specification portable tanks. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that#
Passage 341are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the Sec. 172.101 Table. (ii) The following is a list of the portable tank special provisions: * * * * * * * * * * TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: [GRAPHIC] [TIFF OMITTED] TP22JN04.000 df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively. * * * * * TP6 The tank must be equipped with pressure release devices which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see Sec. 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. * * * * * TP32 Portable tanks may be used subject to the following conditions: (a) Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; (b) The suitability for transport in tanks must be demonstrated using test 8 (d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see Sec. 171.7 of this subchapter) or an alternative means approved by the Associate Administrator. * * * * * 12. In Sec. 172.202, paragraph (a)(5)(i) is revised to read as follows: Sec. 172.202 Description of hazardous material on shipping papers.#
Passage 342(a) * * * (5) * * * (i) For Class I materials, the quantity must be the net explosive mass. For an explosive that is an article, such as Cartridges, small arms, the quantity must be the net mass of the article. * * * * * 13. In Sec. 172.203, paragraphs (f), (m)(2) and (o)(3) are revised and a new paragraph (i)(3) is added to read as follows: Sec. 172.203 Additional description requirements. * * * * * (f) Transportation by air. A statement indicating that the shipment is within the limitations prescribed for either passenger and cargo aircraft or cargo aircraft only must be entered on the shipping paper. * * * * * (i) * * * (3) For a hazardous material consigned under an ``n.o.s.'' entry not included in the segregation groups listed in section 3.1.4 of the IMDG Code but belonging, in the opinion of the consignor, to one of these groups, the appropriate segregation group must be shown in association with the basic description. When no segregation group is applicable, there is no requirement to indicate that condition. (m) * * * (2) For materials that are poisonous by inhalation (see Sec. 171.8 of this subchapter), the words ``Poison-Inhalation Hazard'' or ``Toxic- Inhalation Hazard'' and the words ``Zone A'', ``Zone B'', ``Zone C'', or ``Zone D'', for gases or ``Zone A'' or ``Zone B'' for liquids, as appropriate, must be entered on the shipping description. The word ``Poison'' or ``Toxic'' or the phrase ``Poison-Inhalation Hazard'' or ``Toxic Inhalation Hazard'' need not be repeated if it otherwise appears in the shipping description. * * * * * (o) * * * (3) The word ``SAMPLE'' must be included in association with the basic description when a sample of a Division 4.1 (self-reactive) material (see Sec. 173.224(c)(3) of this subchapter) or Division 5.2 (organic peroxide) material (see Sec. 173.225(b)(2) of this subchapter) is offered for transportation. 14. In Sec. 172.204, paragraph (c)(3) is revised to read as follows:#
Passage 343* * * * * (c) * * * (3) Additional certification requirements. Effective October 1, 2006, each person who offers a hazardous material for transportation by air must add to the certification required in this section the following statement: ``I declare that all of the applicable air transport requirements have been met.'' Each person who offers any package or overpack of hazardous materials for transport by air must ensure that: (a) The articles or substances are not prohibited for transport by air (see the Sec. 172.101 Table); (b) The articles or substances are properly classed, marked and labeled and otherwise in a condition for transport as required by this subchapter; (c) The articles or substances are packaged in accordance with all the applicable air transport requirements, including appropriate types of packaging that conform to the packing requirements and the ``A'' Special Provisions in Sec. 172.102; inner packaging and maximum quantity per package limits; the compatibility requirements (see, for example, Sec. 173.24 of this subchapter); and requirements for closure for both inner and outer packagings, absorbent materials, and pressure differential in Sec. 173.27 of this subchapter. Other requirements may also apply. For example, single packagings may be prohibited, inner packaging may need to be packed in intermediate packagings, and certain materials may be required to be transported in packagings meeting a more stringent performance level. * * * * * 15. A new Sec. 172.317 is added to read as follows: Sec. 172.317 Keep away from heat handling mark. (a) General. For transportation by aircraft, each package containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the KEEP AWAY FROM HEAT handling mark specified in this section. (b) Location and design. The marking must be a rectangle measuring at least 105 mm (4.1 inches) in height by 74 mm (2.9 inches) in width. Markings with not less than half this dimension are permissible where the dimensions of the package can only bear a smaller mark. (c) KEEP AWAY FROM HEAT handling mark. The KEEP AWAY FROM HEAT handling mark must conform to the following: (1) Except for size, the KEEP AWAY FROM HEAT handling mark must appear as follows:#
Passage 344(2) The symbol, letters and border must be black and the background white, except for the starburst which must be red. (3) The KEEP AWAY FROM HEAT handling marking required by paragraph (a) of this section must be durable, legible and displayed on a background of contrasting color. PART 173--SHIPPERS--GENERAL REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS 17. The authority citation for part 173 continues to read as follows: Authority: 49 U.S.C. 5101-5127, 44701; 49 CFR 1.45, 1.53. 18. In Sec. 173.3, paragraph (c) introductory text is revised to read as follows: * * * * * (c) Salvage drums. Packages of hazardous materials that are damaged, defective, found to be not conforming to the requirements of this subchapter after having been placed in transportation, or found leaking, and hazardous materials that have spilled or leaked may be placed in a metal or plastic removable head salvage drum that is compatible with the lading and shipped for repackaging or disposal under the following conditions: * * * * * 19. In Sec. 173.24, paragraphs (g) and (i) are revised to read as follows: Sec. 173.24 General requirements for packagings and packages.#
Passage 345* * * * * (g) Venting. Venting of packagings, to reduce internal pressure which may develop by the evolution of gas from the contents, is permitted only when-- (1) Transportation by aircraft is not involved; (2) Except as otherwise provided in this subchapter, the evolved gases are not poisonous, likely to create a flammable mixture with air or be an asphyxiant under normal conditions of transportation; (3) The packaging is designed so as to preclude an unintentional release of hazardous materials from the receptacle; (4) For bulk packagings, other than IBCs, venting is authorized for the specific hazardous material by a special provision in the Sec. 172.101 table or by the applicable bulk packaging specification in part 178 of this subchapter; and (5) Intermediate bulk packagings (IBCs) may be vented when required to reduce internal pressure that may develop by the evolution of gas subject to the requirements of paragraph (g)(1) through (g)(3) of this section. The IBC must be of a type that has successfully passed (with the vent in place) the applicable design qualification tests with no release of hazardous material. * * * * * (i) Air transportation. Packages offered or intended for transportation by aircraft are subject to requirements additional to those of other modes of transport (e.g., quantity limitations, requirements for absorbent material, pressure differential requirements appropriate closure procedures, and specific packaging requirements) and must conform to the general requirements for transportation by aircraft in Sec. 173.27. 20. In Sec. 173.25, paragraphs (a)(2) and (a)(4) are revised to read as follows: Sec. 173.25 Authorized packagings and overpacks.#
Passage 346(a) * * * * * * * * (2) The overpack is marked with the proper shipping and identification number, when applicable, and is labeled as required by this subchapter for each hazardous material contained therein, unless marking and labels representative of each hazardous material in the overpack are visible. * * * * * (4) The overpack is marked with the word ``OVERPACK.'' Alternatively, until October 1, 2007, the overpack is marked with a statement indicating that the ``inside (inner) packages comply with prescribed specifications'' when specification packagings are required, unless specification markings on the inside packages are visible. * * * * * 21. In Sec. 173.27, paragraph (i) is revised to read as follows: Sec. 173.27 General requirements for transportation by aircraft. * * * * * (i) Effective October 1, 2006, each person who offers a hazardous material for transportation by aircraft must include the certification statement specified in Sec. 172.204(c)(3). 22. In Sec. 173.28, paragraph (c)(2) is revised to read as follows: Sec. 173.28 Reuse, reconditioning and remanufacture of packagings. * * * * * (c) * * * (1) * * * (2) For the purpose of this subchapter, reconditioning of a non- bulk packaging other than a metal drum includes: * * * * * 23. In Sec. 173.115, a new paragraph (k) is added to read as follows: Sec. 173.115 Class 2, Division 2.1, 2.2 and 2.3--Definitions.#
Passage 347* * * * * (k) The following applies to aerosols (see Sec. 171.8 of this subchapter): (1) An aerosols must be assigned to Division 2.1 if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more; (2) An aerosol must be assigned to Division 2.2 if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g. (3) Aerosols not meeting the provisions of (a) or (b) above must be classed in accordance with the appropriate tests of the UN Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter). (4) Division 2.3 gases may not be transported in an aerosol container. (5) When the contents are classified as Division 6.1 or Class 8, PG III, the aerosol must be assigned a subsidiary hazard of Division 6.1 or Class 8. (6) Substances of Division 6.1 or Class 8 Packing Group I and Packing Group II may not be transported in an aerosol container. (7) Flammable components are Class 3 flammable liquids, Class 4.1 flammable solids, or Division 2.2 flammable gases. The chemical heat of combustion must be determined in accordance with the UN Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter). 24. In Sec. 173.128, paragraph (d)(1) is revised to read as follows: Sec. 173.128 Class 5, Division 5.2--Definitions and types. * * * * * (d) Approvals. (1) An organic peroxide must be approved, in writing, by the Associate Administrator, before being offered for transportation or transported, including assignment of a generic type and shipping description, except for-- (i) An organic peroxide which is identified by technical name in the Organic Peroxides Table in Sec. 173.225(c); (ii) A mixture of organic peroxides prepared according to Sec. 173.225(b); or (iii) An organic peroxide which may be shipped as a sample under the provisions of Sec. 173.225(b). * * * * * 25. In 173.132, paragraph (b)(1) is revised to read as follows: 173.132 Class 6, Division 6.1--Definitions.#
Passage 348* * * * * (b) * * * (1) LD50 (median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50% of young adult albino rats when administered by the oral route. The LD50 value is expressed in terms of mass of test substance per mass of test animal (mg/kg). * * * * * 26. In Sec. 173.136, paragraph (d) is added to read as follows: * * * * * (d) Steel or aluminum corrosion test data produced no later than September 30, 2005, using the procedures of Sec. 173.137(c)(2), in effect on September 30, 2004 (see 49 CFR 173.137 revised as of October 1, 2003), for appropriate steel or aluminum types may be used for classification and assignment of packing group for Class 8 materials corrosive to steel or aluminum. 27. In Sec. 173.137, paragraph (c)(2) is revised to read as follows: Sec. 173.137 Class 8--Assignment of packing group. * * * * * (c) * * * * * * * * (2) That do not cause full thickness destruction of intact skin tissue but exhibit a corrosion on steel or aluminum surfaces exceeding 6.25 mm (0.25 inch) a year at a test temperature of 55 [deg]C (130 [deg]F). The corrosion must be determined in accordance with the UN Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter). 28. In Sec. 173.150, paragraph (a), the introductory text of paragraph (b), paragraph (b)(2) and paragraph (c) are revised to read as follows: Sec. 173.150 Exceptions for Class 3 (flammable) and combustible liquids.#
Passage 349(a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted only if this section is referenced for the specific hazardous material in the Sec. Sec. 172.101 Table of this subchapter. (b) Limited quantities. Limited quantities of flammable liquids and combustible liquids are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized: * * * * * (2) For flammable liquids in Packing Group II, inner packagings not over 1.0 L (0.3 gallons) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) net capacity each, packed in a strong outer packaging. * * * * * (c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section and is a ''consumer commodity'' as defined in 171.8 of this subchapter, may be renamed ''Consumer commodity'' and reclassed as ORM-D material. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in Sec. 173.156. * * * * * 29. In 173.151, paragraphs (b) and (c), and the introductory text of paragraph (d) are revised to read as follows: * * * * * (b) Limited quantities of Division 4.1. Limited quantities of flammable solids#
Passage 350(Division 4.1) in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized: (1) For flammable solids in Packing Group II, inner packagings not over 1.0 kg (2.2 pounds) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 0.5 kg (1.1 pounds) net capacity each, packed in a strong outer packaging. (2) For flammable solids in Packing Group III, inner packagings not over 5.0 kg (11 pounds) net capacity each, packed in a strong outer packaging. (c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and charcoal briquettes in packagings not exceeding 30 kg (66 pounds) gross weight, may be renamed ``Consumer commodity'' and reclassed as ORM-D material if the material is a ``consumer commodity'' as defined in 171.8 of this subchapter. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft, and are eligible for the exceptions provided in Sec. 173.156. (d) Limited quantities of Division 4.3. Limited quantities of dangerous when wet (Division 4.3) solids in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addi#
Passage 351tion, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized: * * * * * 30. In Sec. 173.152, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows: Sec. 173.152 Exceptions for Division 5.1 (oxidizers) and Division 5.2 (organic peroxides).#
Passage 352* * * * * (b) Limited quantities. Limited quantities of oxidizers (Division 5.1) in Packing Group II and III and organic peroxides are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized: (1) For oxidizers in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging. * * * * * (c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a ``consumer commodity'' as defined in Sec. 171.8 of this subchapter, may be renamed ''Consumer commodity'' and reclassed as ORM- D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in Sec. 173.156. 31. In Sec. 173.153, paragraph (b), and paragraph (c)(1) are revised to read as follows: Sec. 173.153 Exceptions for Division 6.1 (poisonous materials).#
Passage 353* * * * * (b) Limited quantities. The exceptions in this paragraph do not apply to poison-by-inhalation materials. Limited quantities of poisonous materials (Division 6.1) in Packing Group II and III are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized: (1) For poisonous materials in Packing Group II, inner packagings not over 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids, packed in a strong outer packaging. (2) For poisonous materials in Packing Group III, inner packagings not over 4 L (1.0 gallon) each for liquids or 5.0 kg (11 pounds) each for solids, packed in a strong outer packaging. (c) * * * (1) A limited quantity of poisonous material in Packing Group III which conforms to the provisions of paragraph (b) of this section, and is a ''consumer commodity'' as defined in Sec. 171.8 of this subchapter, may be renamed ``Consumer commodity'' and reclassed as ORM- D. * * * * * 32. In Sec. 173.154, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows: Sec. 173.154 Exceptions for Class 8 (corrosive materials). * * * * * (b) Limited quantities. Limited quantities of corrosive materials (Class 8) in Packing Group II and III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds)#
Passage 354gross weight. The following combination packagings are authorized: (1) For corrosive materials in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging. * * * * * (c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a ''consumer commodity'' as defined in Sec. 171.8 of this subchapter, may be renamed ''Consumer commodity'' and reclassed as ORM- D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in Sec. 173.156. * * * * * 33. In Section 173.185, paragraphs (c)(3) and (e)(6) are revised to read as follows: Sec. 173.185 Lithium batteries and cells.#
Passage 355* * * * * (c) * * * (3) Each cell or battery is of the type proven to be non-dangerous by testing in accordance with Tests in the UN Manual of Tests and Criteria (IBR; see Sec. 171.7 of this subchapter). Such testing must be carried out on each type of cell or battery prior to the initial transport of that type. A cell or battery and equipment containing a cell or battery which was first transported prior to [INSERT EFFECTIVE DATE OF RULE] and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested; * * * * * (e) * * * (6) Each cell or battery is of the type proven to meet the lithium battery requirements in the UN Manual of Tests and Criteria (IBR; see Sec. 171.7 of this subchapter). A cell or battery and equipment containing a cell or battery which was first transported prior to [INSERT EFFECTIVE DATE OF RULE] and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested; * * * * * 34. In Sec. 173.186, paragraph (e) is revised to read as follows: * * * * * (e) Packagings. Strike-anywhere matches must be tightly packed in securely closed chipboard, fiberboard, wooden, or metal inner packagings to prevent accidental ignition under conditions normally incident to transportation. Each inner packaging may contain no more than 700 strike-anywhere matches and must be packed in outer steel drums (1A2), aluminum drums (1B2), steel jerricans (3A2), wooden (4C1, 4C2), plywood (4D), reconstituted wood (4F) or fiberboard (4G) boxes, plywood (1D) or fiber (1G) drums. Gross weight of fiberboard boxes (4G) must not exceed 30 kg (66 pounds). Gross weight of other outer packagings must not exceed 45 kg (100 pounds). 35. In Sec. 173.187, a new paragraph (f) is added to read as follows: Sec. 173.187 Pyrophoric solids, metals or alloys, n.o.s. * * * * * (f) In specification cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT. 36. In Sec. 173.211, paragraph (c) is revised to read as follows: Sec. 173.211 Non-bulk packagings for solid hazardous materials in Packing Group I.#
Passage 356* * * * * (c) Except for transportation by passenger aircraft, the following single packagings are authorized: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plastic drum: 1H1 or 1H2 Fiber drum: 1G Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box with liner: 4A Aluminum box with liner: 4B Natural wood box, sift proof: 4C2 Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1 Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2 Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2 Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT 37. In Sec. 173.212, paragraph (c) is revised to read as follows: Sec. 173.212 Non-bulk packagings for solid hazardous materials in Packing Group III. * * * * * (c) Except for transportation by passenger aircraft, the following single packagings are authorized: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Plywood drum: 1D Plastic drum: 1H1 or 1H2 Fiber drum: 1G Metal drum other than steel or aluminum: 1N1 or 1N2 Wooden barrel: 2C1 or 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Steel box with liner: 4A Aluminum box: 4B Aluminum box with liner: 4B Natural wood box: 4C1 Natural wood box, sift proof: 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2 Bag, woven plastic: 5H1, 5H2 or 5H3 Bag, plastic film: 5H4 Bag, textile: 5L1, 5L2 or 5L3 Bag, paper, multiwall, water resistant: 5M2 Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1 Plastic receptacle in steel aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB1, 6PC or 6PG2 Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2 Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT#
Passage 35738. In Sec. 173.213, paragraph (c) is revised to read as follows: Sec. 173.213 Non-bulk packagings for solid hazardous materials in Packing Group III. (c) The following single packagings are authorized: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Plywood drum: 1D Plastic drum: 1H1 or 1H2 Fiber drum: 1G Metal drum other than steel or aluminum: 1N1 or 1N2 Wooden barrel: 2C1 or 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Steel box with liner: 4A Aluminum box: 4B Aluminum box with liner: 4B Natural wood box: 4C1 Natural wood box, sift proof: 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2 Bag, woven plastic: 5H1, 5H2 or 5H3 Bag, plastic film: 5H4 Bag, textile: 5L1, 5L2 or 5L3 Bag, paper, multiwall, water resistant: 5M2 Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1 Plastic receptacle in steel aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB1, 6PC or 6PG2 Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2 Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT 39. Section 173.219 is revised to read as follows:#
Passage 358(a) A life-saving appliance, self-inflating or non-self-inflating, containing small quantities of hazardous materials that are required as part of the life-saving appliance must conform to the requirements of this section. Packagings must conform to the general packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter. The appliances must be packed, so that they cannot be accidentally activated and, except for life vests, the hazardous materials must be in inner packagings packed so as to prevent movement. The hazardous materials must be an integral part of the appliance and in quantities that do not exceed those appropriate for the actual appliance when in use. (b) Life saving appliances may contain: (1) Division 2.2 compressed gases, including oxygen. However, oxygen generators are not permitted; (2) Signal devices (Class 1), which may include smoke and illumination signal flares; (3) Electric storage batteries and lithium batteries (Life saving appliances containing lithium batteries must be transported in accordance with Sec. 173.185.); (4) First aid or repair kits conforming to the applicable material and quantity limitations of Sec. 173.161 of this subchapter; (5) Strike-anywhere matches; (6) For self-inflating life saving appliances only, cartridges power device of Division 1.4S, for purposes of the self-inflating mechanism provided that the quantity of explosives per appliance does not exceed 3.2 g; or (7) Limited quantities of other hazardous materials. (c) Hazardous materials in life saving appliances must be packaged as follows: (1) Division 2.2 compressed gases must be packaged in cylinders in accordance with the requirements of this subchapter; (2) Signal devices (Class 1) must be in packagings that prevent them from being inadvertently activated; (3) Strike-anywhere matches must be cushioned to prevent movement or friction in a metal or composition receptacle with a screw-type closure in a manner that prevents them from being inadvertently activated; (4) Limited quantities of other hazardous materials must be packaged in accordance with the requirements of this subchapter; and (5) For other than transportation by aircraft, life saving appliances containing no hazardous materials other than carbon dioxide cylinders with a capacity not exceeding 100 cm\3\ are not subject to the provis#
Passage 359ions of this subchapter provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg. 40. In Sec. 173.220, paragraph (b)(2) is revised to read as follows: Sec. 173.220 Internal combustion engines, self-propelled vehicles, mechanical equipment containing internal combustion engines, and battery powered vehicles or equipment. * * * * * (b) * * * (2) Flammable liquefied or compressed gas fuel. (i) For transportation by motor vehicle, rail car or vessel, fuel tanks and fuel systems containing flammable liquefied or compressed gas fuel must be securely closed. For transportation by vessel, the requirements of Sec. Sec. 176.78(k) and 176.905 of this subchapter apply. (ii) For transportation by aircraft: (A) Flammable gas-powered vehicles, machines, equipment or cylinders containing the flammable gas must be completely emptied of flammable gas. Lines from vessels to gas regulators, and gas regulators themselves, must also be drained of all traces of flammable gas. To ensure that these conditions are met, gas shut-off valves must be left open and connections of lines to gas regulators must be left disconnected upon delivery of the vehicle to the operator. Shut-off valves must be closed and lines reconnected at gas regulators before loading the vehicle aboard the aircraft; or alternatively (B) Flammable gas powered vehicles, machines or equipment, which have cylinders (fuel tanks) that are equipped with electrically operated valves, may be transported under the following conditions: (1) The valves must be in the closed position and in the case of electrically operated valves, power to those valves must be disconnected; (2) After closing the valves, the vehicle, equipment or machinery must be operated until it stops from lack of fuel before being loaded aboard the aircraft; (3) In no part of the system between the pressure receptacle and the shut off valve shall the pressure exceed more than 5% of the maximum allowable working pressure of the system; and (4) There must not be any residual liquefied gas in the system, including the fuel tank. 41. In Sec. 173.224, paragraph (b) (4) is revised to read as follows: Sec. 173.224 Packaging and control and emergency temperatures for self-reactive materials.#
Passage 360* * * * * (b) * * * (4) Packing method. Column 4 specifies the highest packing method which is authorized for the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in Sec. 173.225(d) defines the packing methods. Bulk packagings for Type F self-reactive substances are authorized by Sec. 173.225(f) for IBCs and Sec. 173.225(h) for bulk packagings other than IBCs. Additional bulk packagings are authorized if approved by the Associate Administrator. * * * * * 42. Section 173.225 is revised to read as follows: Sec. 173.225 Packaging requirements and other provisions for organic peroxides.#
Passage 361(a) General. When the Sec. 172.101 table specifies that an organic peroxide must be packaged under this section, the organic peroxide must be packaged and offered for transportation in accordance with the provisions of this section. Each packaging must conform to the general requirements of subpart B of part 173 and to the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. No used material, other than production residues or regrind from the same production process, may be used in plastic packagings. Organic peroxides that require temperature control are subject to the provisions of Sec. 173.21(f). When an IBC or bulk packaging is authorized and meets the requirements of paragraph (f) or (h) of this section, respectively, lower control temperatures than those specified for non-bulk packaging may be required. An organic peroxide not identified in paragraph (c), (e), or (g) of this section by technical name or formulation of identified organic peroxides must conform to the provisions of paragraph (c) of Sec. 173.128. (b) New organic peroxides, formulations and samples. (1) Except as provided for samples in paragraph (b)(2) of this section, no person may offer for transportation an organic peroxide that is not identified by technical name in the Organic Peroxides Table, Organic Peroxide IBC Table, or the Organic Peroxide Portable Tank Table of this section, or a formulation of one or more organic peroxides that are identified by technical name in one of those tables, unless the organic peroxide is assigned a generic type and shipping description and is approved by the Associate Administrator under the provisions of Sec. 173.128(d) of this subchapter. (2) Samples. Samples of new organic peroxides or new formulations of organic peroxides identified in the Organic Peroxides Table in paragraph (c) of this section, for which complete test data are not available, and that are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for organic peroxide Type C, packaged and offered for transportation, under the following conditions: (i) Data available to the person offering the material for transportation must indicate that the sample wou#
Passage 362ld pose a level of hazard no greater than that of an organic peroxide Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation; (ii) The sample must be packaged in accordance with packing method OP2, for a liquid or solid, respectively; (iii) Packages of the organic peroxide may be offered for transportation and transported in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and (iv) One of the following shipping descriptions must be assigned: (A) Organic peroxide Type C, liquid, 5.2, UN 3103; (B) Organic peroxide Type C, solid, 5.2, UN 3104; (C) Organic peroxide Type C, liquid, temperature controlled, 5.2, UN 3113; or (D) Organic peroxide Type C, solid, temperature controlled, 5.2, UN 3114. (3) Mixtures. Mixtures of organic peroxides individually identified in the Organic Peroxides Table in paragraph (c) of this section may be classified as the same type of organic peroxide as that of the most dangerous component and be transported under the conditions for transportation given for this type. If the stable components form a thermally less stable mixture, the SADT of the mixture must be determined and the new control and emergency temperature derived under the provisions of Sec. 173.21(f). (c) Organic peroxides table. The following Organic Peroxides Table specifies by technical name those organic peroxides that are authorized for transportation and not subject to the approval provisions of Sec. 173.128 of this part. An organic peroxide identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the table. The column headings of the Organic Peroxides Table are as follows: (1) Technical name. The first column specifies the technical name. (2) ID number. The second column specifies the identification (ID) number which is used to identify the proper shipping name in the Sec. 172.101 table. The word ``EXEMPT'' appearing in the column denotes that the material is not regulated as an organic peroxide. (3) Concentration of organic peroxide. The third column specifies concentration (mass percent) limitations, if any, in mixtures or solutions for the organic peroxide. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the low#
Passage 363er and upper limits (i.e., ``53-100'' means from, and including, 53 % to, and including 100 %). See introductory paragraph of Sec. 172.203(k) of this subchapter for additional description requirements for an organic peroxide that may qualify for more than one generic listing, depending on its concentration. (4) Concentration of diluents. The fourth column specifies the type and concentration (mass percent) of diluent or inert solid, when required. Other types and concentrations of diluents may be used if approved by the Associate Administrator. (i) The required mass percent of ``Diluent type A'' is specified in column 4a. A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150 [deg] C at atmospheric pressure. Type A diluents may be used for desensitizing all organic peroxides. (ii) The required mass percent of ``Diluent type B'' is specified in column 4b. A diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point, at atmospheric pressure, of less than 150 [deg]C (302 [deg]F) but at least 60 [deg]C (140 [deg]F), and a flash point greater than 5 [deg]C (41 [deg]F). Type B diluents may be used for desensitizing all organic peroxides, when specified in the organic peroxide tables, provided that the boiling point is at least 60 [deg]C (140 [deg]F) above the SADT of the peroxide in a 50 kg (110 lbs) package. A type A diluent may be used to replace a type B diluent in equal concentration. (iii) The required mass percent of ``Inert solid'' is specified in column 4c. An inert solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic peroxide. (5) Concentration of water. Column 5 specifies, in mass percent, the minimum amount of water, if any, which must be in formulation. (6) Packing method. Column 6 specifies the highest packing method (largest packaging capacity) authorized for the organic peroxide. Lower numbered packing methods (smaller packaging capacities) are also authorized. For example, if OP3 is specified, then OP2 and OP1 are also authorized. The Table of Packing Methods in paragraph (d) of this section defines the non-bulk packing methods. (7) Temperatures. Column 7a specifies the control temperature. Column 7b specifies the emergency#
Passage 364only when temperature controls are required. (See Sec. 173.21(f)). (8) Notes. Column 8 specifies other applicable provisions, as set forth in notes following the table.#
Passage 365Organic Peroxide Table -------------------------------------------------------------------------------------------------------------------------------------------------------- Diluent (mass %) Temperature ([deg]C) Technical name ID number Concentration --------------------------- Water (mass Packing ---------------------- Notes (mass %) A B I %) method Control Emergency (1) (2)......... (3).............. (4a)... (4b)... (4c)... (5)......... (6)......... (7a).... (7b)...... (8) ------------------------------ Acetyl acetone peroxide...... UN3105...... =48... ....... ....... >=8......... OP7......... ........ .......... 2 Acetyl acetone peroxide [as a UN3106...... =12........ OP4......... -10..... 0......... ........... peroxide. Acetyl cyclohexanesulfonyl UN3115...... =68... ....... ............ OP7......... -10..... 0......... ........... peroxide. tert-Amyl hydroperoxide...... UN3107...... =6.... ....... ....... >=6......... OP8......... ........ .......... ........... tert-Amyl peroxyacetate...... UN3105...... =38... ....... ....... ............ OP7......... ........ .......... ........... tert-Amyl peroxybenzoate..... UN3103...... =23... ....... ....... ............ OP5......... ........ .......... ........... carbonate. tert-Amyl peroxyneodecanoate. UN3115...... =23... ....... ............ OP7......... 0....... +10....... ........... tert-Amyl peroxypivalate..... UN3113...... =23... ....... ............ OP5......... +10..... +15....... ........... tert-Amyl peroxy-3,5,5- UN3101...... 42-100.......... ....... ....... ....... ............ OP8......... ........ .......... 1 tert-Butyl cumyl peroxide.... UN3108...... =48... ............ OP8......... ........ .......... 1 n-Butyl-4,4-di-(tert- UN3103...... >52-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... butylperoxy)valerate. n-Butyl-4,4-di-(tert- UN3108...... =48... ............ OP8......... ........ .......... ........... butylperoxy)valerate. tert-Butyl hydroperoxide..... UN3103...... >79-90........... ....... ....... ....... >=10........ OP5......... ........ .......... 13 tert-Butyl hydroperoxide..... UN3105...... =20... ....... ....... ............ OP7......... ........ .......... 4, 13 tert-Butyl hydroperoxide..... UN3107...... 14......... OP8......... ........ .......... 13, 16 tert-Butyl hydroperoxide..... UN3109...... =28........ OP8......... .......#
Passage 366. .......... 13 tert-Butyl hydroperoxide UN3103...... 9........... ....... ....... ....... >=7......... OP5......... ........ .......... 13 [and] Di-tert-butylperoxide. tert-Butyl monoperoxymaleate. UN3102...... >52-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... tert-Butyl monoperoxymaleate. UN3103...... =48... ....... ....... ............ OP6......... ........ .......... ........... tert-Butyl monoperoxymaleate. UN3108...... =48... ............ OP8......... ........ .......... ........... tert-Butyl monoperoxymaleate UN3108...... 52-77........... >=23... ....... ....... ............ OP5......... ........ .......... ........... tert-Butyl peroxyacetate..... UN3103...... >32-52........... >=48... ....... ....... ............ OP6......... ........ .......... ........... tert-Butyl peroxyacetate..... UN3109...... =68... ....... ............ OP8......... ........ .......... ........... tert-Butyl peroxybenzoate.... UN3103...... >77-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... tert-Butyl peroxybenzoate.... UN3105...... >52-77........... >=23... ....... ....... ............ OP7......... ........ .......... 1 tert-Butyl peroxybenzoate.... UN3106...... =48... ....... ....... ............ OP7......... ........ .......... ........... fumarate. tert-Butyl peroxycrotonate... UN3105...... =23... ....... ....... ............ OP7......... ........ .......... ........... tert-Butyl UN3113...... 52-100.......... ....... ....... ....... ............ OP6......... +20..... +25....... ........... ethylhexanoate. tert-Butyl peroxy-2- UN3117...... >32-52........... ....... >=48... ....... ............ OP8......... +30..... +35....... ........... ethylhexanoate. tert-Butyl peroxy-2- UN3118...... =48... ............ OP8......... +20..... +25....... ........... ethylhexanoate. tert-Butyl peroxy-2- UN3119...... =68... ....... ............ OP8......... +40..... +45....... ........... ethylhexanoate. tert-Butyl peroxy-2- UN3106...... =14... ....... >=60... ............ OP7......... ........ .......... ........... ethylhexanoate [and] 2,2-di- (tert-Butylperoxy)butane. tert-Butyl peroxy-2- UN3115...... =33... ....... ............ OP7......... +35..... +40....... ........... ethylhexanoate [and] 2,2-di- (tert-Butylperoxy)butane. tert-Butyl peroxy-2- UN3105...... 52-77........... ....... >=23#
Passage 367... ....... ............ OP5......... +15..... +20....... ........... tert-Butyl peroxyisobutyrate. UN3115...... =48... ....... ............ OP7......... +15..... +20....... ........... tert-Butylperoxy UN3103...... =23... ....... ....... ............ OP5......... ........ .......... ........... isopropylcarbonate. 1-(2-tert-Butylperoxy UN3105...... =23... ....... ....... ............ OP7......... ........ .......... ........... isopropyl)-3- isopropenylbenzene. 1-(2-tert-Butylperoxy UN3108...... =58... ............ OP8......... ........ .......... ........... isopropyl)-3- isopropenylbenzene. tert-Butyl peroxy-2- UN3103...... 77-100.......... ....... ....... ....... ............ OP7......... -5...... +5........ ........... tert-Butyl peroxyneodecanoate UN3115...... =23... ....... ............ OP7......... 0....... +10....... ........... tert-Butyl peroxyneodecanoate UN3119...... =68... ....... ....... ............ OP8......... 0....... +10....... ...........#
Passage 368tert-Butyl UN3115...... =23... ....... ....... ............ OP7......... 0....... +10....... ........... peroxyneoheptanoate. tert-Butyl UN3117...... 67-77........... >=23... ....... ....... ............ OP5......... 0....... +10....... ........... tert-Butyl peroxypivalate.... UN3115...... =33... ....... ............ OP7......... 0....... +10....... 29 tert-Butyl peroxypivalate.... UN3115...... >27-67........... ....... >=33... ....... ............ OP7......... 0....... +10....... ........... tert-Butyl peroxypivalate.... UN3119...... =73... ....... ............ OP8......... +30..... +35....... ........... tert-Butylperoxy UN3106...... 32-100.......... ....... ....... ....... ............ OP7......... ........ .......... ........... trimethylhexanoate. tert-Butyl peroxy-3,5,5- UN3109...... =68... ....... ............ OP8......... ........ .......... ........... trimethylhexanoate. 3-Chloroperoxybenzoic acid... UN3102...... >57-86........... ....... ....... >=14... ............ OP1......... ........ .......... ........... 3-Chloroperoxybenzoic acid... UN3106...... =3.... >=40........ OP7......... ........ .......... ........... 3-Chloroperoxybenzoic acid... UN3106...... =6.... >=17........ OP7......... ........ .......... ........... Cumyl hydroperoxide.......... UN3107...... >90-98........... =10... ....... ....... ............ OP8......... ........ .......... 13, 15 Cumyl peroxyneodecanoate..... UN3115...... =23... ....... ............ OP7......... -10..... 0......... ........... Cumyl peroxyneodecanoate [as UN3119...... =23... ....... ....... ............ OP7......... -10..... 0......... ........... Cumyl peroxypivalate......... UN3115...... =23... ....... ............ OP7......... -5...... +5........ ........... Cyclohexanone peroxide(s).... UN3104...... =9......... OP6......... ........ .......... 13 Cyclohexanone peroxide(s).... UN3105...... =28... ....... ....... ............ OP7......... ........ .......... 5 Cyclohexanone peroxide(s) [as UN3106...... =68... ............ Exempt...... ........ .......... ........... Diacetone alcohol peroxides.. UN3115...... =26... ....... >=8......... OP7......... +40..... +45....... 5 Diacetyl peroxide............ UN3115...... =73... ....... ............ OP7......... +20..... +25....... 8,13 Di-tert-amyl peroxide........ UN3107...... =18... ....... ....... ............ OP6......... ........ .......... ........... am#
Passage 369ylperoxy)cyclohexane. Dibenzoyl peroxide........... UN3102...... >51-100.......... ....... ....... 77-94........... ....... ....... ....... >=6......... OP4......... ........ .......... 3 Dibenzoyl peroxide........... UN3104...... =23........ OP6......... ........ .......... ........... Dibenzoyl peroxide........... UN3106...... =28... >=10........ OP7......... ........ .......... ........... Dibenzoyl peroxide [as a UN3106...... >52-62........... ....... ....... ....... ............ OP7......... ........ .......... 21 paste]. Dibenzoyl peroxide........... UN3106...... >35-52........... ....... ....... >=48... ............ OP7......... ........ .......... ........... Dibenzoyl peroxide........... UN3107...... >36-42........... >=18... ....... ....... =15........ OP8......... ........ .......... ........... paste]. Dibenzoyl peroxide [as a UN3108...... =65... ............ Exempt...... ........ .......... ........... Di-(4-tert- UN3114...... 52-100.......... ....... ....... ....... ............ OP8......... ........ .......... ........... Di-tert-butyl peroxide....... UN3109...... =48... ....... ............ OP8......... ........ .......... 24 Di-tert-butyl peroxyazelate.. UN3105...... =48... ....... ....... ............ OP7......... ........ .......... ........... 2,2-Di-(tert- UN3103...... =48... ....... ....... ............ OP6......... ........ .......... ........... butylperoxy)butane. 1,6-Di-(tert- UN3103...... =28... ....... ....... ............ OP5......... ........ .......... ........... butylperoxycarbonyloxy)hexan e. 1,1-Di-(tert- UN3101...... >80-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... butylperoxy)cyclohexane. 1,1-Di-(tert- UN3103...... >52-80........... >=20... ....... ....... ............ OP5......... ........ .......... ........... butylperoxy)cyclohexane. 1,1-Di-(tert- UN3105...... =48... ....... ....... ............ OP7......... ........ .......... 29 butylperoxy)cyclohexane. 1,1-Di-(tert- UN3105...... >42-52........... >=48... ....... ....... ............ OP7......... ........ .......... ........... butylperoxy)cyclohexane. 1,1-Di-(tert- UN3106...... =13... ....... >=45... ............ OP7......... ........ .......... ........... butylperoxy)cyclohexane. 1,1-Di-(tert- UN3107...... =25... ....... ....... ............ OP8......... ........ .......... 22 butylperoxy)cyclohexane. 1,1-Di-(ter#
Passage 370t- UN3109...... =58... ....... ....... ............ OP8......... ........ .......... ........... butylperoxy)cyclohexane. 1,1-Di-(tert- UN3109...... =25... >=50... ....... ............ OP8......... ........ .......... 29 butylperoxy)cyclohexane. 1,1-Di-(tert- UN3109...... =13... >=74... ....... ............ OP8......... ........ .......... ........... butylperoxy)cyclohexane. Di-n-butyl peroxydicarbonate. UN3115...... >27-52........... ....... >=48... ....... ............ OP7......... -15..... -5........ ........... Di-n-butyl peroxydicarbonate. UN3117...... =73... ....... ............ OP8......... -10..... 0......... ........... Di-n-butyl peroxydicarbonate UN3118...... <=42............. ....... ....... ....... ............ OP8......... -15..... -5........ ........... [as a stable dispersion in water (frozen)].#
Passage 371Di-sec-butyl UN3113...... >52-100.......... ....... ....... ....... ............ OP4......... -20..... -10....... 6 peroxydicarbonate. Di-sec-butyl UN3115...... =48... ....... ............ OP7......... -15..... -5........ ........... peroxydicarbonate. Di-(2-tert- UN3106...... >42-100.......... ....... ....... =58... ............ Exempt...... ........ .......... ........... butylperoxyisopropyl)benzene (s). Di-(tert- UN3105...... >42-52........... >=48... ....... ....... ............ OP7......... ........ .......... ........... butylperoxy)phthalate. Di-(tert- UN3106...... =58... ....... ....... ............ OP8......... ........ .......... ........... butylperoxy)phthalate. 2,2-Di-(tert- UN3105...... =48... ....... ....... ............ OP7......... ........ .......... ........... butylperoxy)propane. 2,2-Di-(tert- UN3106...... =13... ....... >=45... ............ OP7......... ........ .......... ........... butylperoxy)propane. 1,1-Di-(tert-butylperoxy)- UN3101...... >90-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... 3,3,5-trimethylcyclohexane. 1,1-Di-(tert-butylperoxy)- UN3103...... >57-90........... >=10... ....... ....... ............ OP5......... ........ .......... ........... 3,3,5-trimethylcyclohexane. 1,1-Di-(tert-butylperoxy)- UN3103...... =23... ....... ............ OP5......... ........ .......... ........... 3,3,5-trimethylcyclohexane. 1,1-Di-(tert-butylperoxy)- UN3110...... =43... ............ OP8......... ........ .......... ........... 3,3,5-trimethylcyclohexane. 1,1-Di-(tert-butylperoxy)- UN3107...... =43... ....... ....... ............ OP8......... ........ .......... ........... 3,3,5-trimethylcyclohexane. 1,1-Di-(tert-butylperoxy)- UN3107...... =26... >=42... ....... ............ OP8......... ........ .......... ........... 3,3,5-trimethylcyclohexane. Dicetyl peroxydicarbonate.... UN3116...... =23........ OP5......... ........ .......... ........... Di-4-chlorobenzoyl peroxide UN3106...... =68... ............ Exempt...... ........ .......... ........... Dicumyl peroxide............. UN3110...... >52-100.......... ....... ....... =48... ............ Exempt...... ........ .......... ........... Dicyclohexyl UN3112...... >91-100.......... ....... ....... ....... ............ OP3......... +10..... +15....... ........... peroxydicarbonate. Dicyclohexyl UN3114...... =9......... OP5......... +10...#
Passage 372.. +15....... ........... peroxydicarbonate. Dicyclohexyl UN3119...... =58... ............ OP7......... ........ .......... ........... butylperoxy)cyclohexyl)propa ne. 2,2-Di-(4,4-di(tert- UN3107...... =75... ....... ............ OP8......... ........ .......... 29 butylperoxy)cyclohexyl)propa ne. 2,2-Di-(4,4-di(tert- UN3107...... =78... ....... ............ OP8......... ........ .......... ........... butylperoxy)cyclohexyl)propa ne. Di-2,4-dichlorobenzoyl UN3102...... =23........ OP5......... ........ .......... ........... peroxide. Di-2,4-dichlorobenzoyl UN3106...... =48... ....... ............ OP7......... -10..... 0......... ........... peroxydicarbonate. Di-(2-ethylhexyl) UN3113...... >77-100.......... ....... ....... ....... ............ OP5......... -20..... -10....... ........... peroxydicarbonate. Di-(2-ethylhexyl) UN3115...... =23... ....... ............ OP7......... -15..... -5........ ........... peroxydicarbonate. Di-(2-ethylhexyl) UN3117...... =73... ............ OP5......... ........ .......... ........... Di-(1- UN3106...... 32-52........... ....... >=48... ....... ............ OP5......... -20..... -10....... ........... Diisobutyryl peroxide........ UN3115...... =68... ....... ............ OP7......... -20..... -10....... ........... Diisopropylbenzene UN3106...... =5.... ....... ....... >=5......... OP7......... ........ .......... 17 dihydroperoxide. Diisopropyl peroxydicarbonate UN3112...... >52-100.......... ....... ....... ....... ............ OP2......... -15..... -5........ ........... Diisopropyl peroxydicarbonate UN3115...... =48... ....... ............ OP7......... -20..... -10....... ........... Diisopropyl peroxydicarbonate UN3115...... =72... ....... ....... ............ OP7......... -15..... -5........ ........... Dilauroyl peroxide........... UN3106...... <=100............ ....... ....... ....... ............ OP7......... ........ .......... ...........#
Passage 373Dilauroyl peroxide [as a UN3109...... =48... ....... ............ OP7......... -5...... +5........ ........... peroxydicarbonate. Di-(2-methylbenzoyl)peroxide. UN3112...... =13........ OP5......... +30..... +35....... ........... Di-(4-methylbenzoyl)peroxide UN3106...... =58... ....... ............ OP7......... +30..... +40....... ........... + Benzoyl (3-methylbenzoyl) peroxide + Dibenzoyl peroxide. 2,5-Dimethyl-2,5-di- UN3102...... >82-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... (benzoylperoxy)hexane. 2,5-Dimethyl-2,5-di- UN3106...... =18... ............ OP7......... ........ .......... ........... (benzoylperoxy)hexane. 2,5-Dimethyl-2,5-di- UN3104...... =18........ OP5......... ........ .......... ........... (benzoylperoxy)hexane. 2,5-Dimethyl-2,5-di-(tert- UN3105...... >52-100.......... ....... ....... ....... ............ OP7......... ........ .......... ........... butylperoxy)hexane. 2,5-Dimethyl-2,5-di-(tert- UN3108...... =23... ............ OP8......... ........ .......... ........... butylperoxy)hexane. 2,5-Dimethyl-2,5-di-(tert- UN3109...... =48... ....... ....... ............ OP8......... ........ .......... ........... butylperoxy)hexane. 2,5-Dimethyl-2,5-di-(tert- UN3108...... 86-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... butylperoxy)hexyne-3. 2,5-Dimethyl-2,5-di-(tert- UN3103...... >52-86........... >=14... ....... ....... ............ OP5......... ........ .......... ........... butylperoxy)hexyne-3. 2,5-Dimethyl-2,5-di-(tert- UN3106...... =48... ............ OP7......... ........ .......... ........... butylperoxy)hexyne-3. 2,5-Dimethyl-2,5-di-(2- UN3113...... =18........ OP6......... ........ .......... ........... dihydroperoxyhexane. 2,5-Dimethyl-2,5-di-(3,5,5- UN3105...... =23... ....... ....... ............ OP7......... ........ .......... ........... trimethylhexanoylperoxy)hexa ne. 1,1-Dimethyl-3- UN3117...... =48... ....... ....... ............ OP8......... 0....... +10....... ........... hydroxybutylperoxyneoheptano ate. Dimyristyl peroxydicarbonate. UN3116...... =48... ....... ....... ............ OP7......... -10..... 0......... ........... neodecanoylperoxyisopropyl)b enzene. Di-n-nonanoyl peroxide....... UN3116...... 85-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... phenoxyeth#
Passage 374yl)peroxydicarbona te. Di-(2- UN3106...... =15........ OP7......... ........ .......... ........... phenoxyethyl)peroxydicarbona te. Dipropionyl peroxide......... UN3117...... =73... ....... ............ OP8......... +15..... +20....... ........... Di-n-propyl peroxydicarbonate UN3113...... =23... ....... ............ OP5......... -20..... -10....... ........... Disuccinic acid peroxide..... UN3102...... >72-100.......... ....... ....... ....... ............ OP4......... ........ .......... 18 Disuccinic acid peroxide..... UN3116...... =28........ OP7......... +10..... +15....... ........... Di-(3,5,5- UN3115...... >38-82........... >=18... ....... ....... ............ OP7......... 0....... +10....... ........... trimethylhexanoyl)peroxide. Di-(3,5,5- UN3119...... =62... ....... ....... ............ OP8......... +20..... +25....... ........... trimethylhexanoyl)peroxide. Ethyl 3,3-di-(tert- UN3105...... =33... ....... ....... ............ OP7......... ........ .......... ........... amylperoxy)butyrate. Ethyl 3,3-di-(tert- UN3103...... >77-100.......... ....... ....... ....... ............ OP5......... ........ .......... ........... butylperoxy)butyrate. Ethyl 3,3-di-(tert- UN3105...... =23... ....... ....... ............ OP7......... ........ .......... ........... butylperoxy)butyrate. Ethyl 3,3-di-(tert- UN3106...... =48... ............ OP7......... ........ .......... ........... butylperoxy)butyrate. 1-(2-ethylhexanoylperoxy)-1,3- UN3115...... =45... >=10... ....... ............ OP7......... -20..... -10....... ........... Dimethylbutyl peroxypivalate. tert-Hexyl peroxyneodecanoate UN3115...... =29... ....... ....... ............ OP7......... 0....... +10....... ........... tert-Hexyl peroxypivalate.... UN3115...... =28... ....... ............ OP7......... +10..... +15....... ........... Isopropylcumyl hydroperoxide. UN3109...... =28... ....... ....... ............ OP8......... ........ .......... 13 p-Menthyl hydroperoxide...... UN3105...... > 72-100......... ....... ....... ....... ............ OP7......... ........ .......... 13 p-Menthyl hydroperoxide...... UN3109...... =28... ....... ....... ............ OP8......... ........ .......... ...........#
Passage 375Methylcyclohexanone UN3115...... =33... ....... ............ OP7......... +35..... +40....... ........... peroxide(s). Methyl ethyl ketone UN3101...... =48... ....... ....... ............ OP5......... ........ .......... 5, 13, 29 peroxide(s). Methyl ethyl ketone UN3105...... =55... ....... ....... ............ OP7......... ........ .......... 5, 29 peroxide(s). Methyl ethyl ketone UN3107...... =60... ....... ....... ............ OP8......... ........ .......... 5, 29 peroxide(s). Methyl isobutyl ketone UN3105...... =19... ....... ....... ............ OP7......... ........ .......... 5, 23 peroxide(s). Organic peroxide, liquid, UN3103...... ................. ....... ....... ....... ............ OP2......... ........ .......... 12 sample. Organic peroxide, liquid, UN3113...... ................. ....... ....... ....... ............ OP2......... ........ .......... 12 sample, temperature controlled. Organic peroxide, solid, UN3104...... ................. ....... ....... ....... ............ OP2......... ........ .......... 12 sample. Organic peroxide, solid, UN3114...... ................. ....... ....... ....... ............ OP2......... ........ .......... 12 sample, temperature controlled. Peroxyacetic acid, type D, UN3105...... =15........ OP8......... ........ .......... 13, 20, 28, peracetic acid [with not 29 more than 7% hydrogen peroxide]. Peroxyacetic acid or Exempt...... =60........ Exempt...... ........ .......... 28, 29 peracetic acid [with not more than 20% hydrogen peroxide]. Peroxyacetic acid or UN3109...... 56-100.......... ....... ....... ....... ............ OP7......... ........ .......... 13 Pinanyl hydroperoxide........ UN3109...... =44... ....... ....... ............ OP8......... ........ .......... ........... Polyether poly-tert- UN3107...... =23... ....... ............ OP8......... ........ .......... ........... butylperoxycarbonate. Tetrahydronaphthyl UN3106...... =28... ....... ............ OP7......... -5...... +5........ ........... peroxyneodecanoate. 1,1,3,3-Tetramethylbutyl UN3119...... =23... ....... ....... ............ OP7......... 0....... +10....... ........... peroxypivalate. 3,6,9-Triethyl-3,6,9- UN3105...... =58... ....... ....... ............ OP7......... ........ .......... 26 trimethyl- 1,4,7- triperoxonane. ----------------------------------------------------------------------------------------------------------------#
Passage 376---------------------------------------- Notes: 1. For domestic shipments, OP8 is authorized. 2. Available oxygen must be =8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene. 18. Addition of water to this organic peroxide will decrease its thermal stability. 19. [Reserved] 20. Mixtures with hydrogen peroxide, water and acid(s). 21. With diluent type A, with or without water. 22. With >=36% diluent type A by mass, and in addition ethylbenzene. 23. With >=19% diluent type A by mass, and in addition methyl isobutyl ketone. 24. Diluent type B with boiling point >100 C. 25. No ``Corrosive'' subsidiary risk label is required for concentrations below 56%. 26. Available oxygen must be <=7.6%. 27. Formulations derived from distillation of peroxyacetic acid originating from peroxyacetic acid in a concentration of not more than 41% with water, total active oxygen less than or equal to 9.5% (peroxyacetic acid plus hydrogen peroxide). 28. For the purposes of this section, the names ``Peroxyacetic acid'' and ``Peracetic acid'' are synonymous. 29. For international transportation, shipments of this material must be accompanied by a Competent Authority approval from the Associate Administrator. (d) Packing Method Table. Packagings for organic peroxides and self-reactive substances are listed in the Maximum Quantity per Packing Method Table. The packing methods are designated OP1 to OP8. The quantities specified for each packing method represent the maximum that is authorized. (1) The following types of packagings are authorized: (i) Drums: 1A1, 1A2, 1B1, 1B2, 1D, 1G, 1H1, 1H2; (ii) Jerricans: 3A1, 3A2, 3B1, 3B2, 3H1, 3H2; (iii) Boxes: 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2, 4A, 4B; or (iv) Composite packagings with a plastic inner receptacle: 6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1, 6HH2. (2) Metal packaging (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8. (3) In combination packagings, glass receptacles are used only as inner packagings with a maximum content of 0.5 kg for solids or 0.5 L for liquids. (4) The maximum quantity per packaging or package for Packing Methods OP1-OP8 must be as follows:#
Passage 377Maximum Quantity per Packaging/Package for Packing Methods OP1 to OP8 ---------------------------------------------------------------------------------------------------------------- Packing Method Maximum Quantity ----------------------------------------------------------------------- OP1 OP2 OP3 OP4 \1\ OP5 OP6 OP7 OP8 ---------------------------------------------------------------------------------------------------------------- Solids and combination packagings 0.5 0.5/10 5 5 25 50 50 \2\ 400 (liquid and solid) (kg)................ Liquids (L)............................. 0.5 ....... 5 ....... 30 60 60 \3\ 225 ---------------------------------------------------------------------------------------------------------------- \1\ If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package. \2\ 60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg. \3\ 60 L for jerricans. (e) Organic Peroxide IBC Table. The following Organic Peroxide IBC Table specifies, by technical name, those organic peroxides that are authorized for transportation in certain IBCs and not subject to the approval provisions of Sec. 173.128 of this part. Additional requirements for authorized IBCs are found in paragraph (f) of this section.#
Passage 378Organic Peroxide IBC Table ---------------------------------------------------------------------------------------------------------------- Maximum UN No. Organic peroxide Type of IBC quantity Control Emergency (litres) temperature temperature ---------------------------------------------------------------------------------------------------------------- 3109 ORGANIC PEROXIDE, TYPE F, LIQUID ---------------- tert-Butyl hydroperoxide, 31A.............. 1250 not more than 72% with water. tert-Butyl peroxyacetate, 31A.............. 1250 not more than 32% in 31HA1............ 1000......... diluent type A. tert-Butyl peroxy-3,5,5- 31A.............. 1250 trimethylhexanoate, not 31HA1............ 1000......... more than 32% in diluent type A. Cumyl hydroperoxide, not 31HA1............ 1250 more than 90% in diluent type A. Dibenzoyl peroxide, not 31H1............. 1000 more than 42% as a stable dispersion. Di-tert-butyl peroxide, 31A.............. 1250 not more than 52% in 31HA1............ 1000......... diluent type B. 1,1-Di-(tert-butylperoxy) 31H1............. 1000 cyclohexane, not more than 42% in diluent type A. Dicumyl peroxide, less 31A.............. 1250 than or equal to 100%. 31HA1............ 1000......... Dilauroyl peroxide, not 31HA1............ 1000 more than 42%, stable dispersion, in water. Isopropyl cumyl 31HA1............ 1250 hydroperoxide, not more than 72% in diluent type A. p-Menthyl hydroperoxide, 31HA1............ 1250 not more than 72% in diluent type A. Peroxyacetic acid, 31H1............. 1500 stabilized, not more 31HA1............ 1500......... than 17%. 31A.............. 1500......... Peroxyacetic acid, with 31A.............. 1500 not more than 26% 31HA1............ 1500......... hydrogen peroxide. Peroxyacetic acid, type 31A.............. 1500 F, stabilized. 31HA1............ 1500......... ---------------- 3110 ORGANIC PEROXIDE TYPE F, SOLID ---------------- Dicumyl peroxide, less 31A.............. 2000 than or equal to 100%. 31H1............. 31HA1............ ---------------- 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED ---------------- tert-Butyl peroxy-2- 31HA1............ 1000 +30 [deg]C...... +35 [deg]C ethylhexanoate, not more 31A.............. 1250......... than 32% in diluent type B. tert-Butyl 31A.............. 1250 0 [deg]C........ +10 [deg]C peroxyneodecanoate, not more than 32% in diluent type A. tert-Butyl#
Passage 37931A.............. 1250 -5 [deg]C....... +5 [deg]C peroxyneodecanoate, not more than 42% stable dispersion, in water. tert-Butyl 31HA1............ 1000......... +10 [deg]C...... +15 [deg]C peroxypivalate, not more 31A.............. 1250......... than 27% in diluent type B. Cumyl peroxyneodecanoate, 31A.............. 1250......... -15 [deg]C...... -5 [deg]C not more than 52%, stable dispersion, in water. Dicyclohexylperoxydicarbo 31A.............. 1250......... +10 [deg]C...... +15 [deg]C nate, not more than 42% as a stable dispersion, in water. Di-(4-tert- 31HA1............ 1000......... +30 [deg]C...... +35 [deg]C butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water. Dicetyl 31HA1............ 1000......... +30 [deg]C...... +35 [deg]C peroxydicarbonate, not more than 42%, stable dispersion, in water. Di-(2-ethylhexyl) 31A.............. 1250......... -20 [deg]C...... -10 [deg]C peroxydicarbonate, not more than 52%, stable dispersion, in water. Dimyristyl 31HA1............ 1000......... +15 [deg]C...... +20 [deg]C peroxydicarbonate, not more than 42%, stable dispersion, in water. Di-(3,5,5- 31HA1............ 1000......... +10 [deg]C...... +15 [deg]C trimethylhexanoyl) 31A.............. 1250......... peroxide, not more than 38% in diluent type A. Di-(3,5,5- 31A.............. 1250......... +10 [deg]C...... +15 [deg]C trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water. 1,1,3,3-Tetramethylbutyl 31A.............. 1250......... -5 [deg]C....... +5 [deg]C peroxyneodecanoate, not more than 52%, stable dispersion, in water. ----------------------------------------------------------------------------------------------------------------#
Passage 380(f) IBCs. IBCs are authorized subject to the conditions and limitations of this section if the IBC type is authorized according to paragraph (e) of this section, as applicable, and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group II performance level. The additional requirements in paragraphs (h)(5)(i) and (h)(5)(ii) of this section also apply. Type F organic peroxides or self-reactive substances are not authorized for transportation in IBCs other than those specified, unless approved by the Associate Administrator. (i) IBCs shall be provided with a device to allow venting during transportation. The inlet to the pressure relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation. (ii) To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (h)(3)(v) of this section. The control and emergency temperatures specified in the Organic Peroxide IBC Table are based on a non-insulated IBC. (g) Organic Peroxide Portable Tank Table. The following Organic Peroxide Portable Tank Table provides certain portable tank requirements and identifies, by technical name, those organic peroxides that are authorized for transportation in the bulk packagings listed in paragraph (h). Organic peroxides listed in this table, provided they meet the specific packaging requirements found in paragraph (h), are not subject to the approval provisions of Sec. 173.128 of this part.#
Passage 381Organic Peroxide Portable Tank Table ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Minimum test UN No. Hazardous material pressure Minimum shell thickness (mm- Bottom opening requirements Pressure-relief Filling limits Control Emergency (bar) reference steel) See . . . See . . . requirements See . . . temperature temperature ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ 3109 ORGANIC PEROXIDE, TYPE F, LIQUID ------------------- tert-Butyl more 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than hydroperoxide, not 90% at 59[deg]F more than 72% with (15[deg]C). water. * Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water. Cumyl hydro-peroxide, 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than not more than 90% in 90% at 59[deg]F diluent type A. (15[deg]C). Di-tert-butyl 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than peroxide, not more 90% at 59[deg]F than 32% in diluent (15[deg]C). type A. Dicumyl peroxide, less 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than than or equal to 100% 90% at 59[deg]F in diluent type B. (15[deg]C). Isopropyl cumyl hydro- 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than peroxide, not more 90% at 59[deg]F than 72% in diluent (15[deg]C). type A. p-Menthyl hydro- 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than peroxide, not more 90% at 59[deg]F than 72% in diluent (15[deg]C). type A. Pinanyl hydro- 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than peroxide, not more 90% at 59[deg]F than 56% in diluent (15[deg]C). type A. ------------------- 3110 ORGANIC PEROXIDE, TYPE F, SOLID ------------------- Dicumyl peroxide less 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275#
Passage 382(g)(1)....... Not more than than or equal to 100% 90% at 59[deg]F with inert solids * (15[deg]C). Maximum quantity per portable tank 2,000 kg. ------------------- 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED ------------------- tert-Butyl 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than +30[deg]C.... +35[deg]C peroxyacetate, not 90% at 59[deg]F more than 32% in (15[deg]C). diluent type B. tert-Butyl peroxy-2- 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than +15[deg]C.... +20[deg]C ethylhexanoate, not 90% at 59[deg]F more than 32% in (15[deg]C). diluent type B. tert-Butyl 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than +5[deg]C..... +10[deg]C peroxypivalate, not 90% at 59[deg]F more than 27% in (15[deg]C). diluent type B. tert-Butyl peroxy- 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than +35[deg]C.... +40[deg]C 3,5,5-trimethyl- 90% at 59[deg]F hexanoate, not more (15[deg]C). than 32% in diluent type B. Di-(3,5,5-trimethyl- 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than +0[deg]C..... +5[deg]C hexanoyl) peroxide, 90% at 59[deg]F not more than 38% in (15[deg]C). diluent type A. Peroxyacetic acid, 4............ Sec. 178.274(d)(2)....... Sec. 178.275(d)(3)....... Sec. 178.275(g)(1)....... Not more than +30[deg]C.... +35[deg]C distilled, 90% at 59[deg]F stabilized, not more (15[deg]C). than 41%. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------#
Passage 383(h) Bulk packagings other than IBCs. The following bulk packagings are authorized, subject to the conditions and limitations of this section, if the organic peroxide is listed in the Organic Peroxide Portable Tank Table and bulk packagings are authorized and the bulk packaging conforms to the requirements of this subchapter: (1) Rail cars. Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 fusion-weld tank car tanks are authorized. DOT 103W, 111A60F1 and 111A60W1 tank car tanks must have bottom outlets effectively sealed from inside. Gauging devices are required on DOT 103W tank car tanks. Riveted tank car tanks are not authorized. (2) Cargo tanks. Specification MC 307, MC 310, MC 311, MC 312, DOT 407, and DOT 412 cargo tank motor vehicles with a tank design pressure of at least 172 kPa (25 psig) are authorized. (3) Portable tanks. The following requirements apply to portable tanks intended for the transport of Type F organic peroxides or Type F self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of paragraph (g) of this section. Type F organic peroxide or self-reactive substance formulations other than those indicated in the Organic Peroxide Portable Tank Table may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply: (i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4 bar). (ii) The portable tank must be fitted with temperature-sensing devices. (iii) The portable tank must be fitted with pressure relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell. (iv) The pressure relief devices must consist of reclosing devices fitted to prevent significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 [deg]C (122 [deg]F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The pressure relief devices must not allow liquid to escape in the event the portable tank is overturned in#
Passage 384a loaded condition. (v)(A) The emergency-relief devices may be of the reclosing or frangible types, or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula: [GRAPHIC] [TIFF OMITTED] TP22JN04.001 Where: q = heat absorption (W) A = wetted area (m\2\) F = insulation factor (-) (B) Insulation factor (F) in the formula in paragraph (h)(3)(v)(A) of this section equals 1 for non-insulated vessels and for insulated vessels F is calculated using the following formula: U = K/L = heat transfer coefficient of the insulation (W·m-\2\); K-\1\); where K = heat conductivity of insulation layer (W[middot]m-\1\);K-\1\), and L = thickness of insulation layer (m). TPO = temperature of material at relieving conditions (K).#
Passage 385(vi) The start-to-discharge pressure of emergency-relief devices must be higher than that specified for the pressure relief devices in paragraph (h)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank. Note to Paragraph (h)(3)(vi): An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter). A second example of a test method for venting sizing is given in the American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2). (vii) For insulated portable tanks, the capacity and setting of emergency-relief devices must be determined assuming a loss of insulation from 1% of the surface area. (viii) Vacuum-relief devices and reclosing devices on portable tanks used for flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided. (ix) Service equipment such as devices and external piping must be designed and constructed so that no hazardous material remains in them after filling the portable tank. (x) Portable tanks may be either insulated or protected by a sun- shield. If the SADT of the hazardous material in the portable tank is 55 [deg]C (131 [deg]F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal. (xi) The degree of filling must not exceed 90% at 15 [deg]C (59 [deg]F). (xii) DOT 57 metal portable tanks are authorized only for tert- butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s)), dicumyl peroxide and mixtures of two or more of these peroxides. DOT 57 portable tanks must conform to the venting requirements of paragraph (f) of this section. These portable tanks are not subject to the requirements of paragraphs (h)(3)(ii) and (h)(3)(iv) of this section. These portable tanks are not subject to any other requirements of paragraph (h) of this section. (4) For tertiary butyl hydroperoxide (TBHP), each tank car, cargo tank or portable tank must contain 7.6 cm (3.0 inches) low density polyethylene (PE) saddles having a melt index of at least 0.2#
Passage 386grams per 10 minutes (for example see, ASTM D1238, condition E) as part of the lading, with a ratio of PE to TBHP over a range of 0.008 to 0.012 by mass. Alternatively, plastic or metal containers equipped with fusible plugs having a melting point between 69 [deg]C (156 [deg]F) and 71 [deg]C (160 [deg]F) and filled with a sufficient quantity of water to dilute the TBHP to 65% or less by mass may be used. The PE saddles must be visually inspected after each trip and, at a minimum, once every 12 months, and replaced when discoloration, fracture, severe deformation, or other indication of change is noted. 43. Section 173.226 is revised to read as follows: Sec. 173.226 Materials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A. Division 6.1, Packing Group I, Zone A poisonous by inhalation (see Sec. 173.133) must be packed in non-bulk packagings in accordance with the following paragraphs: (a) In seamless specification cylinders conforming to the requirements of Sec. 173.40. (b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 drums further packed in a 1A2 or 1H2 drum. Both inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package#
Passage 387intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. All outer drums, even those tested to contain inner packaging or as single packagings for solids, must withstand a hydrostatic test pressure of 100 kPa (15 psig). The outer drum must have a minimum thickness of 1.35 mm (0.053 inch) for a 1A2 outer drum or 6.3 mm (0.248 inch) for a 1H2 outer drum. In addition, the inner drum must-- (1) Be capable of satisfactorily withstanding the hydrostatic pressure test in Sec. 178.605 of this subchapter at a test pressure of 300 kPa (45 psig); (2) Satisfactorily withstand the leakproofness test in Sec. 178.604 of this subchapter using an internal air pressure of at least twice the vapor pressure at 55 [deg]C (131 [deg]F) of the material to be packaged; (3) Have screw-type closures that are-- (i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque; (ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and (iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig). (4) Have a minimum thickness as follows: (i) For a 1A1 or 1N1 drum, 1.3 mm (0.051 inch); (ii) For a 1B1 drum, 3.9 mm (0.154 inch); (iii) For a 1H1 drum, 3.16 mm (0.124 inch); and (iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and the outer steel drum shall be 0.96 mm (0.0378 inch). (5) Be isolated from the outer drum by a shock-mitigating, non- reactive material, which completely surrounds the inner packaging on all sides. (c) In combination packagings, consisting of an inner packaging system and an outer packaging, as follows: (1) Outer packagings: Steel drum: 1A2 Aluminum drum: 1B2 Metal drum, other than steel or aluminum: 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H2 Solid plastic box: 4H2#
Passage 388(2) Inner packaging system. The inner packaging system consists of two packagings: (i) an impact-resistant receptacle of glass, earthenware, plastic or metal securely cushioned with a non-reactive, absorbent material, and (A) Capacity of each inner receptacle may not exceed 4 L (1 gallon). (B) An inner receptacle that has a closure must have a closure which is physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation. (ii) Packed within a leak-tight packaging of metal or plastic. (iii) This combination packaging in turn is packed within the outer packaging. (A) The total amount of liquid contained in the outer packaging may not exceed 16 L (4 gallons). (iv) the inner packaging system must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level when subjected to the following tests: (A) 178.603--Drop Test (B) 178.604--Leakproofness Test (C) 178.605--Hydrostatic Pressure Test (v) The inner packaging system must meet the above tests without the benefit of the outer packaging. (vi) The leakproofness and hydrostatic pressure test may be conducted on either the inner receptacle or the outer packaging of the inner packaging system. (vii) In addition to the requirements in 173.226(b), the outer package must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level as applicable for the type of package being used. (d) If approved by the Associate Administrator, 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, palletizes the drums, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery. (e) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with 173.28 using a minimum test pressure as indicated in paragraph (b)(2) of this section. 44. Section 173.227 is revised to read as follows:#
Passage 389Sec. 173.227 Materials poisonous by inhalation. Division 6.1, Packing Group I, Hazard Zone B. (a) In packagings as authorized in Sec. 173.226 and seamless and welded specification cylinders conforming to the requirements of Sec. 173.40. (b) 1A1, 1B1, 1N1 or 1H1 drum or 6HA1 composite further packed in a 1A2 or 1H2 drum. Both the inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drum must have a minimum thickness of 1.35 mm (0.053 inches) for a 1A2 outer drum or 6.30 mm (0.248 inches) for a 1H2 outer drum. Outer 1A2 and 1H2 drums must withstand a hydrostatic test pressure of 100 kPa (15 psig). Capacity of the inner drum may not exceed 220 liters. In addition, the inner drum must conform to all of the following requirements: (1) Satisfactorily withstand the leakproofness test in Sec. 178.604 of this subchapter using an internal air pressure of at least two times the vapor pressure at 55 [deg]C (131 [deg]F) of the material to be packaged. (2) Have screw closures that are-- (i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque; (ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and (iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig). (3) Have a minimum thickness as follows: (i) For a 1A1 drum, 0.69 mm (0.027 inch); (ii) For a 1B1 drum, 2.79 mm (0.110 inch); (iii) For a 1H1 drum, 1.14 mm (0.045 inch); or (iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0625 inch), the outer steel drum shall be 0.70 mm (0.027 inch). (4) Be isolated from the outer drum by a shock-mitigating, non- reactive material which completely surrounds the inner packaging on all sides.#
Passage 390(5) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with 173.28 using a minimum test pressure as indicated in paragraph (b)(1) of this section. (c) 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery. 45. In Sec. 173.249, paragraph (c) is revised to read as follows: * * * * * (c) UN portable tanks conforming to tank code T22 (see Sec. 172.102 of this subchapter) or specification IM 101 portable tanks conforming with paragraphs (d) through (f) of this section. The total quantity in one tank may not be less than 88% nor more than 92% of the volume of the tank. * * * * * 46. In Sec. 173.306, paragraphs (i) and (j) are removed and a new paragraph (i) is added to read as follows: Sec. 173.306 Limited quantities of compressed gases. * * * * * (i) Aerosols with a capacity of less than 50 ml. Aerosols, as defined in Sec. 171.8 of this subchapter, with a capacity not exceeding 50 ml and with a pressure not exceeding 970 kPa (141 psig) at 55 [deg]C (131 [deg]F), containing no hazardous materials other than a Division 2.2 gas, are not subject to the requirements of this subchapter. * * * * * 47. In Sec. 173.307, paragraph (a)(5) is removed. 48. Section 173.313 is added to read as follows: Sec. 173.313 UN Portable Tank Table for Liquefied Compressed Gases.#
Passage 391The UN Portable Tank Table for Liquefied Compressed Gases is referenced in Sec. 172.102(c)(7)(iii) of this subchapter for portable tanks that are used to transport liquefied compressed gases. The table applies to each liquefied compressed gas that is identified with Special Provision T50 in Column (7) of the Sec. 172.101 Table. In addition to providing the UN identification number and proper shipping name, the table provides maximum allowable working pressures, bottom opening requirements, pressure relief device requirements, and degree of filling requirements for liquefied compressed gas permitted for transportation in a T50 portable tank. In the minimum test pressure column, ``small'' means a portable tank with a diameter of 1.5 meters or less when measured at the widest part of the shell, ``sunshield'' means a portable tank with a shield covering at least the upper third of the shell, ``bare'' means no sunshield or insulation is provided, and ``insulated'' means a complete cladding of sufficient thickness of insulating material necessary to provide a minimum conductance of not more than 0.67 w/m\2\/k. In the pressure relief requirements column, the word ``Normal'' denotes that a frangible disc as specified in Sec. 178.276(e)(3) of this subchapter is not required.#
Passage 392UN Portable Tank Table for Liquefied Compressed Gases ---------------------------------------------------------------------------------------------------------------- Minimum design Non-refrigerated pressure (MAWP) Pressure relief UN No. liquefied (bar) Small; Bare; Openings below requirements (See Maximum filling compressed gases Sunshield; liquid level Sec. density (kg/l) Insulated 178.276(e)) ---------------------------------------------------------------------------------------------------------------- 1005......... Ammonia, anhydrous 29.0, 25.7, 22.0, Allowed........... Sec. 0.53 19.7. 178.276(e)(3). 1009......... Bromotrifluorometh 38.0, 34.0, 30.0, Allowed........... Normal........... 1.13 ane or 27.5. Refrigerant gas R 13B1. 1010......... Butadienes, 7.5, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.55 stabilized. 1011......... Butane............ 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.51 1012......... Butylene.......... 8.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.53 1017......... Chlorine.......... 19.0, 17.0, 15.0, Not Allowed....... Sec. 1.25 13.5. 178.276(e)(3). 1018......... Chlorodifluorometh 26.0, 24.0, 21.0, Allowed........... Normal........... 1.03 ane or 19.0. Refrigerant gas R 22. 1020......... Chloropentafluoroe 23.0, 20.0, 18.0, Allowed........... Normal........... 1.06 thane or 16.0. Refrigerant gas R 115. 1021......... 1-Chloro-1,2,2,2- 10.3, 9.8, 7.9, Allowed........... Normal........... 1.2 tetrafluoroethane 7.0. or Refrigerant gas R 124. 1027......... Cyclopropane...... 18.0, 16.0, 14.5, Allowed........... Normal........... 0.53 13.0. 1028......... Dichlorodifluorome 16.0, 15.0, 13.0, Allowed........... Normal........... 1.15 thane or 11.5. Refrigerant gas R 12. 1029......... Dichlorofluorometh 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 1.23 ane or Refrigerant gas R 21. 1030......... 1,1-Difluoroethane 16.0, 14.0, 12.4, Allowed........... Normal........... 0.79 or Refrigerant 11.0. gas R 152a. 1032......... Dimethylamine, 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.59 anhydrous. 1033......... Dimethyl ether.... 15.5, 13.8, 12.0, Allowed........... Normal........... 0.58 10.6. 1036......... Ethylamine........ 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.61 1037......... Ethyl chloride.... 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.8 1040...#
Passage 393...... Ethylene oxide Only authorized in Not Allowed....... Sec. 0.78 with nitrogen up 10 bar insulated 178.276(e)(3). to a total portable tanks--. pressure of 1MPa (10 bar) at 50 [deg]C. 1041......... Ethylene oxide and See MAWP Allowed........... Normal........... See Sec. carbon dioxide definition in 173.32(f) mixture with more Sec. 178.276(a). than 9% but not more than 87% ethylene oxide. 1055......... Isobutylene....... 8.1, 7.0, 7.0. 7.0 Allowed........... Normal........... 0.52 1060......... Methyl acetylene 28.0, 24.5, 22.0, Allowed........... Normal........... 0.43 and propadiene 20.0. mixture, stabilized. 1061......... Methylamine, 10.8, 9.6, 7.8, Allowed........... Normal........... 0.58 anhydrous. 7.0.#
Passage 3941062......... Methyl bromide.... 7.0, 7.0, 7.0, 7.0 Not Allowed....... Sec. 1.51 178.276(e)(3). 1063......... Methyl chloride or 14.5, 12.7, 11.3, Allowed........... Normal........... 0.81 Refrigerant gas R 10.0. 40. 1064......... Methyl mercaptan.. 7.0, 7.0, 7.0, 7.0 Not Allowed....... Sec. 0.78 178.276(e)(3). 1067......... Dinitrogen 7.0, 7.0, 7.0, 7.0 Not Allowed....... Sec. 1.3 tetroxide. 178.276(e)(3). 1075......... Petroleum gas, See MAWP Allowed........... Normal........... See Sec. liquefied. definition in 173.32(f) Sec. 178.276(a). 1077......... Propylene......... 28.0, 24.5, 22.0, Allowed........... Normal........... 0.43 20.0. 1078......... Refrigerant gas, See MAWP Allowed........... Normal........... See Sec. n.o.s. definition in 173.32(f) Sec. 178.276(a). 1079......... Sulphur dioxide... 11.6, 10.3, 8.5, Not Allowed....... Sec. 1.23 7.6. 178.276(e)(3). 1082......... Trifluorochloroeth 17.0, 15.0, 13.1, Not Allowed....... Sec. 1.13 ylene, stabilized 11.6. 178.276(e)(3). or Refrigerant gas R 1113. 1083......... Trimethylamine, 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.56 anhydrous. 1085......... Vinyl bromide, 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 1.37 stabilized. 1086......... Vinyl chloride, 10.6, 9.3, 8.0, Allowed........... Normal........... 0.81 stabilized. 7.0. 1087......... Vinyl methyl 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 0.67 ether, stabilized. 1581......... Chloropicrin and 7.0, 7.0, 7.0, 7.0 Not Allowed....... Sec. 1.51 methyl bromide 178.276(e)(3). mixture. 1582......... Chloropicrin and 19.2, 16.9, 15.1, Not Allowed....... Sec. 0.81 methyl chloride 13.1. 178.276(e)(3). mixture. 1858......... Hexafluoropropylen 19.2, 16.9, 15.1, Allowed........... Normal........... 1.11 e compressed or 13.1. Refrigerant gas R 1216. 1912......... Methyl chloride 15.2, 13.0, 11.6, Allowed........... Normal........... 0.811954 and methylene 10.1. cloride mixture. NA 1954...... Insecticide gases, See MAWP Allowed........... Normal........... Sec. 173.32(f) flammable, n.o.s.. definition in Sec. 178.276(a). 1958......... 1, 2-Dichloro-1, 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 1.3 1, 2,2- tetrafluoroethane or Refrigerant. 1965......... Hydrocarbon gas, See MAWP Allowed........... Normal........... See Sec. mixture definition in 173.32(f) liquefied, n.o.s. Sec. 178.276(a). 1969......... Iso#
Passage 395butane......... 8.5, 7.5, 7.0, 7.0 Allowed........... Normal........... 0.49 1973......... Chlorodifluorometh 28.3, 25.3, 22.8, Allowed........... Normal........... 1.05 ane and 20.3. chloropentafluoro ethane mixture with fixed boiling point, with approximately 49% chlorodifluoromet hane or Refrigerant gas R 502. 1974......... Chlorodifluorobrom 7.4, 7.0, 7.0, 7.0 Allowed........... Normal........... 1.61 omethane or Refrigerant gas R 12B1. 1976......... Octafluorocyclobut 8.8, 7.8, 7.0, 7.0 Allowed........... Normal........... 1.34 ane or Refrigerant gas RC 318. 1978......... Propane........... 22.5, 20.4, 18.0, Allowed........... Normal........... 0.42 16.5. 1983......... 1-Chloro-2, 2, 2- 7.0, 7.0, 7.0, 7.0 Allowed........... Normal........... 1.18 trifluoroethane or Refrigerant gas R 133a. 2035......... 1, 1, 1- 31.0, 27.5, 24.2, Allowed........... Normal........... 0.76 Trifluoroethane 21.8. compressed or Refrigerant gas R 143a. 2424......... Octafluoropropane 23.1, 20.8, 18.6, Allowed........... Normal........... 1.07 or Refrigerant 16.6. gas R 218. 2517......... 1-Chloro-1, 1- 8.9, 7.8, 7.0, 7.0 Allowed........... Normal........... 0.99 difluoroethane or Refrigerant gas R 142b. 2602......... Dichlorodifluorome 20.0, 18.0, 16.0, Allowed........... Normal........... 1.01 thane and 14.5. difluoroethane azeotropic mixture with approximately 74% dichlorodifluorom ethane or Refrigerant gas R 500. 3057......... Trifluoroacetyl 14.6, 12.9, 11.3, Not Allowed....... Sec. 1.17 chloride. 9.9. 178.276(e)(3). 3070......... Ethylene oxide and 14.0, 12.0, 11.0, Allowed........... Sec. 1.09 dichlorodifluorom 9.0. 178.276(e)(3). ethane mixture with not more than 12.5% ethylene oxide. 3153......... Pefluoro (methyl 14.3, 13.4, 11.2, Allowed........... Normal........... 1.14 vinyl ether). 10.2. 3159......... 1,1,1, 2- 17.7, 15.7, 13.8, Allowed........... Normal........... 1.04 Tetrafluoroethane 12.1. or Refrigerant gas R 134a. 3161......... Liquefied gas, See MAWP Allowed........... Normal........... Sec. 173.32(f) flammable, n.o.s.. definition in Sec. 178.276(a). 3163......... Liquefied gas, See MAWP Allowed........... Normal........... Sec. 173.32(f) n.o.s. definition in Sec. 178.276(a). 3220......... Pentafluoroethane 34.4, 30.8, 27.5, Allowed........... Normal........... 0.95 or Refrigerant. 24.5.#
Passage 3963252......... Difluoromethane or 43.0, 39.0, 34.4, Allowed........... Normal........... 0.78 Refrigerant gas R 30.5. 32. 3296......... Heptafluoropropane 16.0, 14.0, 12.5, Allowed........... Normal........... 1.2 or Refrigerant 11.0. gas R 227. 3297......... Ethylene oxide and 8.1, 7.0, 7.0, 7.0 Allowed........... Normal........... 1.16 chlorotetrafluoro ethane mixture, with not more than 8.8% ethylene oxide. 3298......... Ethylene oxide and 25.9, 23.4, 20.9, Allowed........... Normal........... 1.02 pentafluoroethane 18.6. mixture, with not more than 7.9% ethylene oxide. 3299......... Ethylene oxide and 16.7, 14.7, 12.9, Allowed........... Normal........... 1.03 tetrafluoroethane 11.2. mixture, with not more than 5.6% ethylene oxide. 3318......... Ammonia solution, See MAWP Allowed........... Sec. 173.32(f) relative density definition in 178.276(e)(3). less than 0.880 178.276(a). at 15 [deg]C in water, with more than 50% ammonia. 3337......... Refrigerant gas R 31.6, 28.3, 25.3, Allowed........... Normal........... 0.84 404A. 22.5. 3338......... Refrigerant gas R 31.3, 28.1, 25.1, Allowed........... Normal........... 0.95 407A. 22.4. 3339......... Refrigerant gas R 33.0, 29.6, 26.5, Allowed........... Normal........... 0.95 4078. 23.6. 3340......... Refrigerant gas R 29.9, 26.8, 23.9, Allowed........... Normal........... 0.95 407C. 21.3. ---------------------------------------------------------------------------------------------------------------- 49. In Sec. 173.315, paragraph (a) introductory text is revised to read as follows: Sec. 173.315 Compressed gases in cargo tanks and portable tanks.#
Passage 397(a) Liquefied compressed gases that are transported in UN portable tanks must be loaded and offered for transportation in accordance with the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313. A liquefied compressed gas offered for transportation in a cargo tank motor vehicle or a portable tank must be prepared in accordance with this section, Sec. Sec. 173.32 and 173.33 and subpart E or subpart G of part 180 of this subchapter, as applicable. For cryogenic liquids, see Sec. 173.318. For marking requirements, see Sec. Sec. 172.326 and 172.328 of this subchapter. Except for UN portable tanks, a liquefied compressed gas must be loaded and offered for transportation in accordance with the following table: * * * * * 50. In Sec. 173.323, paragraph (b) is revised to read as follows:#
Passage 398* * * * * (b) Ethylene oxide must be packaged in one of the following: (1) In hermetically sealed glass or metal inner packagings suitably cushioned in an outer package authorized by Sec. 173.201(b). The maximum quantity permitted in any glass inner packaging is 100 g (3.5 ounces), and the maximum quantity permitted in any metal inner packaging is 340 g (12 ounces). After filling, each inner packaging shall be determined to be leak-tight by placing the inner packaging in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapour pressure of ethylene oxide at 55 [deg]C is achieved. The total quantity in any outer packaging shall not exceed 2.5 kg. Each completed package must be capable of passing all Packing Group I performance tests. (2) In specification cylinders, as authorized for any compressed gas except acetylene. Pressurizing valves and insulation are required for cylinders over 4 L (1 gallon) capacity. Eductor tubes must be provided for cylinders over 19 L (5 gallons) capacity. Cylinders must be seamless or welded steel (not brazed) with a nominal capacity of no more than 115 L (30 gallons) and may not be liquid full below 82 [deg]C (180 [deg]F). Before each refilling, each cylinder must be tested for leakage at no less than 103.4 kPa (15 psig) pressure. In addition, each cylinder must be equipped with a fusible type relief device with yield temperature of 69 [deg]C to 77 [deg]C (157 [deg]F to 170 [deg]F). The capacity of the relief device and the effectiveness of the insulation must be such that the charged cylinder will not explode when tested by the method described in CGA Pamphlet C-14 or other equivalent method. (3) In 1A1 steel drums of no more than 231 L (61 gallons) and meeting Packing Group I performance standards. The drum must be lagged of all welded construction with the inner shell having a minimum thickness of 1.7 mm (0.068 inches) and the outer shell having a minimum thickness of 2.4 mm (0.095 inches). Drums must be capable of withstanding a hydrostatic test pressure of 690 kPa (100 psig). Lagging must be of sufficient thickness so that the drum, when filled with ethylene oxide and equipped with the required pressure relief device, will not rupture when exposed to fire. The drum may not be liquid full below 85 [deg]C (185 [deg]F), and must be marked ``THIS END UP'' on#
Passage 399the top head. Before each refilling, each drum must be tested for leakage at no less than 103 kPa (15 psig) pressure. Each drum must be equipped with a fusible type relief device with yield temperature of 69 [deg]C to 77 [deg]C (157 [deg]F to 170 [deg]F), and the capacity of the relief device must be such that the filled drum is capable of passing, without rupture, the test method described in CGA Pamphlet C-14 or other equivalent method. * * * * * 51. The authority citation for part 175 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 52. In Sec. 175.10, paragraphs (a)(4)(i), (a)(4)(iii), and (a)(18) are revised to read as follows: (a) * * * (4) * * * (i) Non-radioactive medicinal and toilet articles (including aerosols) may be carried in checked or carry-on baggage. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release; * * * * * (iii) Other aerosols in Division 2.2 with no subsidiary risk may be carried in checked baggage only. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release; * * * * * (18) Compressed gas cylinders of Division 2.2 worn by passengers for the operation of mechanical limbs and spare cylinders of a similar size for the same purpose in sufficient quantities to ensure an adequate supply for the duration of the journey. * * * * * 53. Section 175.85 is revised by adding new paragraph (j) to read as follows: * * * * * (j) A package bearing a KEEP AWAY FROM HEAT handling marking must be protected from direct sunshine and stored in a cool and ventilated place, away from sources of heat. 54. The authority citation for part 176 continues to read as follows:#
Passage 400Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 55. In Sec. 176.2, the following revisions are made: a. The definitions for ``Explosive article'', ``Explosive substance'' and ``Magazine'' are revised. b. The term ``Transport unit'' is revised to read ``Cargo transport unit''. c. In the definition ``In containers or the like'', the term ``transport unit'' is removed and the term ``cargo transport unit'' is added in its place. The revisions and additions read as follows: * * * * * Cargo transport unit means a transport vehicle, a freight container or a portable tank. A closed cargo transport unit means a cargo transport unit in which the contents are totally enclosed by permanent structures. An open cargo transport unit means a cargo transport unit that is not a closed cargo transport unit. Cargo transport units with fabric sides or tops are not closed cargo transport units for the purposes of this part. * * * * * Explosive article means an article or device which contains one or more explosive substances. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code. * * * * * Explosive substance means a solid or liquid material, or a mixture of materials, which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to its surroundings. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code. * * * * * In containers or the like means in any clean, substantial, weatherproof box structure which can be secured to the vessel's structure, including a portable magazine or a closed cargo transport unit. Whenever this stowage is specified, stowage in deckhouses, mast lockers and oversized weatherproof packages (overpacks) is also acceptable. * * * * * Magazine means an enclosure designed to protect certain goods of Class 1 (explosive) materials from damage by other cargo and adverse weather conditions during loading, unloading, and when in transit; and to prevent unauthorized access. A magazine may be a fixed structure or compartment in the vessel, a closed freight container, a closed transport vehicle, or a portable magazine. Magazines may be positioned in any part of the ship conforming with the relevant provisions for Class 1 (explosive) materials contained in Subpart G of this part provided that mag#
Passage 401azines which are fixed structures are sited so that their doors, where fitted, are easily accessible. * * * * * 56. Section 176.27 is revised to read as follows: (a) A carrier may not transport a hazardous material by vessel unless a certificate prepared in accordance with Sec. 172.204 of this subchapter has been received. (b) In the case of an import or export shipment of hazardous materials that will not be transported by rail, highway, or air, the shipper may certify on the bill of lading or other shipping paper that the hazardous material is properly classed, described, marked, packaged, and labeled according to part 172 of this subchapter or in accordance with the requirements of the IMDG Code (IBR, see Sec. 171.7 of this subchapter). See Sec. 171.12 of this subchapter. (c)(1) A person responsible for packing or loading a freight container or transport vehicle with packages of hazardous materials for transportation by a manned vessel in ocean or coastwise service, must provide the vessel operator, at the time the shipment is offered for transportation by vessel, with a signed container packing certificate stating, at a minimum, that-- (i) The freight container or transport vehicle is serviceable for the materials loaded therein, contains no incompatible goods, and is properly marked, labeled or placarded, as applicable; and (ii) When the freight container or transport vehicle contains packages, those packages have been inspected prior to loading, are properly marked, labeled or placarded, as applicable; are not damaged; and are properly secured. (2) The certification may appear on a shipping paper or on a separate document as a statement, such as ``It is declared that the packing of the container has been carried out in accordance with the applicable provisions [of 49 CFR], [of the IMDG Code], or [of 49 CFR and the IMDG Code].'' 57. In Sec. 176.63, paragraph (e) is revised to read as follows:#
Passage 402* * * * * (e) Closed cargo transport unit, for the purpose of stowage of Class 1 (explosive) materials on board a vessel, means a unit which fully encloses the contents by permanent structures and can be secured to the ship's structure, and includes a magazine. Cargo transport units with fabric sides or tops are not closed cargo transport units. Where this stowage is specified, stowage in small compartments such as deck- houses and mast lockers are acceptable alternatives. The floor of any closed cargo transport unit or compartment shall either be constructed of wood, close-boarded or so arranged that goods are stowed on sparred gratings, wooden pallets or dunnage. Provided that the necessary additional specifications are met, a closed cargo transport unit may be used for type ``A'' or ``C'' class 1 stowage or as a magazine.'' * * * * * 58. In Sec. 176.76, paragraphs (h) and (i) are revised to read as follows: Sec. 176.76 Transport vehicles, freight containers, and portable tanks containing hazardous materials.#
Passage 403* * * * * (h) A fumigated cargo transport unit may only be transported on board a vessel subject to the following conditions and limitations: (1) The fumigated cargo transport unit may be placed on board a vessel only if at least 24 hours have elapsed since the unit was last fumigated; (2) The fumigated cargo transport unit is accompanied by a document showing the date of fumigation and the type and amount of fumigant used; (3) Prior to loading, the master is informed of the intended placement of the fumigated cargo transport unit on board the vessel and the information provided on the accompanying document; (4) Equipment that is capable of detecting the fumigant and instructions for the equipment's use is provided on the vessel; (5) The fumigated cargo transport unit must be stowed at least 5 m from any opening to accommodation spaces; (6) Fumigated cargo transport units may only be transported on deck on vessels carrying more than 25 passengers; and (7) Fumigants may not be added to cargo transport units while on board a vessel. (i) A cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 [deg]C transported on deck must be stowed ``away from'' possible sources of ignition. In the case of container ships, a distance equivalent to one container space athwartships away from possible sources of ignition applied in any direction will satisfy this requirement. 59. In Sec. 176.83: a. Paragraphs (a)(5), (d), (e), (f)(1), (f)(3), (g)(1), (g)(2), (g)(3) and (l) are revised; b. The headings to paragraphs (g) and (f) and the title to Table 176.83(g) are revised; and c. A new paragraph (m) is added. The revisions and additions read as follows:#
Passage 404* * * * * (a) * * * (5) Whenever hazardous materials are stowed together, whether or not in a cargo transport unit, the segregation of such hazardous materials from others must always be in accordance with the most restrictive requirements for any of the hazardous materials concerned. * * * * * (d) Segregation in cargo transport units: Two hazardous materials for which any segregation is required may not be stowed in the same cargo transport unit. (e) Segregation of hazardous materials stowed as breakbulk cargo from those packed in cargo transport units: (1) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in open cargo transport units in accordance with paragraph (c) of this section. (2) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in closed cargo transport units in accordance with paragraph (c) of this section, except that: (i) Where ``away from'' is required, no segregation between packages and the closed cargo transport units is required; and (ii) Where ``separated from'' is required, the segregation between the packages and the closed cargo transport units may be the same as for ``away from''. (f) Segregation of cargo transport units on board container vessels: (1) Except for hatchless container ships, this paragraph applies to segregation of cargo transport units that are carried on board container vessels, or on other types of vessels, provided these cargo spaces are properly fitted for permanent stowage of containers during transport. * * * * * (3) Segregation Table: Table Sec. 176.83(f) sets forth the general requirements for segregation between cargo transport units on board container vessels. * * * * * (g) Segregation of cargo transport units on board trailerships and trainships: (1) The requirements of this paragraph apply to the segregation of cargo transport units which are carried on board trailerships and trainships or in ``roll-on/roll-off'' cargo spaces. (2) For trailerships and trainships which have spaces suitable for breakbulk cargo, containers, or any other method of stowage, the appropriate paragraph of this section applies to the relevant cargo space. (3) Segregation Table. Table Sec. 176.83(g) sets forth the general requirements for segregation between transport units on board trailerships and trainships. TABLE 176.83(g).--SEGREGATION OF CARGO TRANSPORT U#
Passage 405NITS ON BOARD TRAILERSHIPS AND TRAINSHIPS * * * * * (l) Segregation of containers on board hatchless (open-top) container ships: (1) This paragraph applies to the segregation of cargo transport units that are transported on board hatchless container ships provided that the cargo spaces are properly fitted to give permanent stowage of the cargo transport units during transport. (2) For container ships that have both hatchless container spaces and other spaces suitable for breakbulk cargo, conventional container stowage, or any other method of stowage, the appropriate requirements of this section apply to the relevant cargo space. (3) Segregation Table: Table Sec. 176.83(l)(3) sets forth the general requirements for segregation of cargo transport units on board hatchless container ships. (4) In Table Sec. 176.83(l)(3), a container space means a distance of not less than 6 m (20 feet) fore and aft or not less than 2.5 m (8 feet) athwartship. BILLING CODE 4910-60-P#
Passage 406(m) Provisions for segregation groups: (1) For the purpose of segregation, materials having certain similar chemical properties have been grouped together in segregation groups. The segregation groups ( such as ``acids'', ``chlorates'', ``permanganates'') and the entries allocated to each of these groups include the substances identified in section 3.1.4 of the IMDG Code. When column (10B) of the Sec. 172.101 Table refers to a numbered stowage provision set forth in Sec. 176.84(b) such as ``Stow ``away from'' acids'', that particular stowage/segregation requirement applies to all the materials allocated to the respective segregation group. (2) Not all hazardous materials falling within a segregation group are listed by name in the regulations. These materials are shipped under ``n.o.s.'' entries. Although these ``n.o.s.'' entries are not listed themselves in the above groups, the shipper must decide whether allocation under a segregation group is appropriate. Mixtures, solutions or preparations containing hazardous materials falling within a segregation group and shipped under an ``n.o.s.'' entry are also considered to fall within that segregation group. (3) The segregation groups described above do not address materials which fall outside the classification criteria of the hazardous materials regulations although it is recognized that some non-hazardous materials have certain chemical properties similar to hazardous materials listed in the segregation groups. A shipper or the person responsible for packing the materials into a cargo transport unit who does have knowledge of the chemical properties of such non-hazardous materials may identify a relevant segregation group and apply the segregation requirements for that segregation group. 60. In Sec. 176.84, paragraph (a) is revised, in paragraph (b), Table of provisions, eleven new entries are added in appropriate numerical order and in paragraph (c)(2), three notes in the Provisions for the stowage of Class 1 (explosive) materials table are revised to read as follows: Sec. 176.84 Other requirements for stowage and segregation for cargo vessels and passenger vessels.#
Passage 407(a) General. When Column 10B of the Sec. 172.101 Table refers to a numbered or alpha-numeric stowage provision for water shipments, the meaning and requirements of that provision are set forth in this section. Terms in quotation marks are defined in Sec. 176.83. Other terms used in the table in this section such as ``acids'', ``chlorates'' and ``permanganates'' indicate different chemical groups referred to here as segregation groups. Materials falling within a segregation group are considered to have certain similar chemical properties and, although not exhaustive in nature, the materials belonging to each group include those substances identified in section 3.1.4 of the IMDG Code as set forth in Sec. 176.83(m). (b) * * * ------------------------------------------------------------------------ Code Provisions ------------------------------------------------------------------------ * * * * * 133.................................... Stow ``separated from'' sulfur. 134.................................... Stow ``separated from'' UN2716. 135.................................... Stow ``Separated from'' mercury and mercury compounds. 136.................................... Stow ``Separated from'' carbon tetrachloride. 137.................................... For arsenic sulphides, Stow ``separated from'' acids. 138.................................... Stow ``Separated from'' peroxides. 139.................................... Stow ``Separated from'' mercury salts. 140.................................... Stow ``Separated from'' UN3052 and UN3461. 141.................................... Stow ``away from'' radioactive materials. 142.................................... Packages in cargo transport units must be stowed so as to allow for adequate air circulation throughout the cargo. 143.................................... Prohibited on any vessel carrying explosives (except explosives in Division 1.4, Compatibility group S). * * * * * ------------------------------------------------------------------------ ------------------------------------------------------------------------ Note Provision ------------------------------------------------------------------------ * * * * * 19E.................................... ``Away from'' explosives containing chlorates or perchlorates.#
Passage 408* * * * * 22E.................................... ``Away from'' ammonium compounds and explosives containing ammonium compounds or salts. 23E.................................... ``Separated from'' Division 1.4 and ``separated longitudinally by an intervening complete compartment or hold from'' Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J. * * * * * ------------------------------------------------------------------------ * * * * * 61. In Sec. 176.116, paragraph (c) is revised and a new paragraph (f) is added to read as follows: Sec. 176.116 General stowage conditions for Class 1 (explosive) materials. * * * * * (c) Security: All compartments, magazines, and cargo transport units containing Class 1 (explosive) materials must be locked or suitably secured in order to prevent unauthorized access. * * * * * (f) Under deck stowage of Class 1 (explosive) materials allocated stowage categories 09 and 10: (1) These Class 1 (explosive) materials must not be stowed in the same compartment or hold with other cargo that is readily combustible (such as items packaged in straw). (2) The position of stowage of these Class 1 (explosive) materials must be such as to maintain direct access to the hatchway by not overstowing with other cargo except for other Class 1 (explosive) materials. (3) In all cases, all cargo within the compartment or hold, including Class 1 (explosive) materials stowed in cargo transport units, must be secured so as to eliminate the possibility of significant movement. Where an entire deck is used as a magazine, the stowage must be so arranged that the Class 1 (explosive) materials stowed therein must be removed from the ship before working any cargo in any decks above or below the space in the same hold. 62. Section 176.122 is removed and reserved. 63. Section 176.124 is removed and reserved. 64. Section 176.128 is revised to read as follows: Sec. 176.128 Magazine stowage types ``A'', ``C'' and Special Stowage.#
Passage 409(a) The stowage arrangements of Class 1 (explosive) substances and certain articles are subject to varying levels of containment, (except for compatibility group S substances), when stowed below deck. The levels are dependent on the hazard presented and the nature of the particular explosives involved. Columns (10A) and (10B) of the Hazardous Materials Table specify the stowage applicable to each substance or article. The different levels of containment are defined below as ``A'', ``C'' and ``Special''. (b) Magazine stowage type ``A''. Magazine stowage type A is required for those substances that must be kept clear of steelwork. (c) Magazine stowage type ``C''. Magazine stowage type C is required for those substances in compatibility group A. (d) Special Stowage. Special Stowage is required for Explosive substances, n.o.s. in compatibility groups G or L, and for articles in compatibility groups G, H, L and K, which are particularly hazardous. 65. Section 176.132 is removed and reserved. 66. Section 176.133 is revised to read as follows: The construction requirements for magazine stowage type C are the same as for a closed cargo transport unit in Sec. 176.63(e). In addition, the magazine must be located as near as practicable to the centerline of the vessel and must not be closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less. 67. Section 176.136 is revised to read as follows:#
Passage 410(a) Special stowage is required for certain articles presenting both explosive and chemical hazards, such as smoke or lachrymatory (compatibility group G or H), toxic (compatibility group K), or substances and articles which present a special risk (compatibility group L). Except as permitted in paragraph (c) of this section, Class 1 (explosive) materials requiring special stowage must be stowed on deck unless such stowage is impracticable and the COTP authorizes special stowage below deck. Where on deck stowage is recommended and an alternative stowage below deck is permitted by the COTP, the stowage must always be subject to special stowage. (b) Class 1 (explosive) materials for which special stowage is required must be stowed as far away as practicable from living, accommodation, and working areas, and may not be overstowed. Closed cargo transport units in which such Class 1 (explosive) materials are stowed may not be located closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less. (c) Class 1 (explosive) materials in compatibility groups G and H may be transported in steel magazines or in freight containers. If a freight container is used for this purpose, the floor of the freight container must be leakproof; for example, an all-metal container may be used and a fillet of cement or other material worked across the bottom of the door opening. (d) Class 1 (explosive) materials stowed in one compartment may not be of more than one compatibility group, except the COTP may allow Class 1 (explosive) materials of compatibility groups G and H in separate steel magazines to be stowed in the same compartment, not less than 3 m (10 feet) apart. (e) Class 1 (explosive) materials in compatibility groups K and L must be stowed in a steel magazine regardless of the stowage position in the vessel. 68. In Sec. 176.138, paragraph (a) is revised to read as follows: (a) [Reserved] * * * * * 69. In Sec. 176.142, paragraph (a) is revised to read as follows: Sec. 176.142 Hazardous materials of extreme flammability. (a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials:#
Passage 411Carbon disulfide.................................... UN1131 Class 3 Diethylzinc......................................... UN1366 Division 4.2 Dimethylzinc........................................ UN1370 Division 4.2 Magnesium alkys..................................... UN3053 Division 4.2 Methyl phosphonous di-chloride, pyrophoric liquid... NA2845 Division 6.1 Nickel carbonyl..................................... UN1259 Division 6.1 Pyrophoric liquid, inorganic, n.o.s................. UN3194 Division 4.2 Pyrophoric liquid, organic, n.o.s................... UN2845 Division 4.2 Organometallic substance, liquid, pyrophoric........ UN3392 Division 4.2 Organometallic substance, liquid, pyrophoric, water- UN3394 Division 4.2 reactive.. * * * * * 70. In Sec. 176.144, paragraphs (a), (b), (c) and (e) are revised to read as follows: Sec. 176.144 Segregation of Class 1 (explosive) materials. (a) Except as provided in Sec. 176.145 of this subchapter, stowage of Class 1 (explosive) materials within the same compartment, magazine, or cargo transport unit is subject to provisions contained in table 176.144(a).#
Passage 412Table 176.144(a).--Authorized Mixed Stowage for Explosives [An ``X'' indicates that explosives in the two different compatibility groups reflected by the location of the ``X'' may not be stowed in the same compartment, magazine, or cargo transport unit] -------------------------------------------------------------------------------------------------------------------------------------------------------- Compatibility groups A B C D E F G H J K L N S -------------------------------------------------------------------------------------------------------------------------------------------------------- A............................................................ ..... X X X X X X X X X X X X B............................................................ X ..... X X X X X X X X X X C............................................................ X X ..... ..... ..... X 1 X X X X D............................................................ X X ..... ..... ..... X 1 X X X X E............................................................ X X ..... ..... ..... X 1 X X X X F............................................................ X X X X X ..... X X X X X X G............................................................ X X 1 1 1 X ..... X X X X X H............................................................ X X X X X X X ..... X X X X J............................................................ X X X X X X X X ..... X X X K............................................................ X X X X X X X X X ..... X X L............................................................ X X X X X X X X X X 2 X X N............................................................ X X X ..... ..... X X X X X X#
Passage 413S............................................................ X ..... ..... ..... ..... ..... ..... ..... ..... ..... X -------------------------------------------------------------------------------------------------------------------------------------------------------- Notes: 1. Explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of compatibility groups C, D, and E, provided no explosive substances are carried in the same compartment, magazine or cargo transport unit. 2. Explosives in compatibility group L may only be stowed in the same compartment, magazine or cargo transport unit with identical explosives within compatibility group L. 3. Different types of articles of Division 1.6, compatibility group N, may only be transported together when it is proven that there is no additional risk of sympathetic detonation between the articles. Otherwise they must be treated as division 1.1. 4. When articles of compatibility group N are transported with articles or substances of compatibility groups C, D or E, the goods of compatibility group N must be treated as compatibility group D. 5. When articles of compatibility group N are transported together with articles or substances of compatibility group S, the entire load must be treated as compatibility group N. 6. Any combination of articles in compatibility groups C, D and E must be treated as compatibility group E. Any combination of substances in compatibility groups C and D must be treated as the most appropriate compatibility group shown in Table 2 of Sec. 173.52 taking into account the predominant characteristics of the combined load. This overall classification code must be displayed on any label or placard on a unit load or cargo transport unit as prescribed in subpart E (Labeling) and subpart F (Placarding).#
Passage 414(b) Where Class 1 (explosive) materials of different compatibility groups are allowed to be stowed in the same compartment, magazine, or cargo transport unit, the stowage arrangements must conform to the most stringent requirements for the entire load. (c) Where a mixed load of Class 1 (explosive) materials of different hazard divisions and/or stowage arrangements is carried within a compartment, magazine, or cargo transport unit, the entire load must be treated as belonging to the hazard division having the greatest hazard. (For example, if a load of Division 1.1 (explosive) materials is mixed with Division 1.3 (explosive) materials, the load is treated as a Division 1.1 (explosive) material as defined in Sec. 173.50(b) of this subchapter and the stowage must conform to the most stringent requirements for the entire load). * * * * * (e) Segregation on deck: When Class 1 (explosive) materials in different compatibility groups are carried on deck, they must be stored not less than 6 m (20 feet) apart unless they are allowed under Table 176.144(a) to be stowed in the same compartment, magazine, or cargo transport unit. * * * * * 71. In Sec. 176.146, paragraph (d)(1) is revised to read as follows: Sec. 176.146 Segregation from non-hazardous materials. * * * * * (d) In order to avoid contamination: (1) An explosive substance or article which has a secondary POISON hazard label must be stowed ``separated from'' all foodstuffs, except when such materials are stowed in separate closed cargo transport units, the requirements for ``away from'' segregation apply. * * * * * 72. The undesignated center heading before Sec. 176.168 is revised to read ``CARGO TRANSPORT UNITS AND SHIPBORNE BARGES''. 73. In Sec. 176.170, a new paragraph (b) is added to read as follows: Sec. 176.170 Transport of Class 1 (explosive) materials in freight containers. * * * * * (b) Freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, must not be stowed in the outermost row of containers. * * * * * 74. In Sec. 176.174, paragraphs (a) and (b) are revised to read as follows: Sec. 176.174 Transport of Class 1 (explosive) materials in shipborne barges.#
Passage 415(a) Fixed magazines may be built within a shipboard barge. Freight containers may be used as magazines within a barge. (b) Shipborne barges may be used for the carriage of all types of Class 1 (explosive) materials. When carrying Class 1 (explosive) materials requiring special stowage, the following requirements apply: (1) Class 1 (explosive) materials in compatibility group G or H must be stowed in freight containers. (2) Class 1 (explosive) materials in compatibility group K or L must be stowed in steel magazines. * * * * * 75. In Sec. 176.600, in paragraph (a), in the last sentence, the wording ``closed transport units'' is removed and the wording ``closed cargo transport units'' is added in its place. 76. The authority citation for part 178 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 77. In Sec. 178.274, paragraph (f)(1)(v) is revised to read as follows: Sec. 178.274 Specifications for UN portable tanks. * * * * * (f) * * * (1) * * * (v) The rated flow capacity of the spring loaded pressure relief devices, frangible disc or fusible elements in standard cubic meters of air per second (m\3\/s). For spring loaded pressure relief device the rated flow capacity shall be determined according to ISO 4126-1 (IBR, see Sec. 171.1 of this subchapter); and * * * * * 78. In Sec. 178.275, paragraph (i)(2) is revised to read as follows: Sec. 178.275 Specification for UN Portable Tanks intended for the transportation of liquid and solid hazardous materials. * * * * * (i) * * * (2) The combined delivery capacity of the pressure relief system (taking into account the reduction of the flow when the portable tank is fitted with frangible-discs preceding spring-loaded pressure-relief devices or when the spring-loaded pressure-relief devices are provided with a device to prevent the passage of the flame), in condition of complete fire engulfment of the portable tank must be sufficient to limit the pressure in the shell to 20% above the start to discharge pressure limiting device (pressure relief device). The total required capacity of the relief devices may be determined using the formula in paragraph (i)(2)(i)(A) of this section or the table in paragraph (i)(2)(iii) of this section. * * * * * 79. In Sec. 178.276, paragraphs (a)(4)(ii)(A), (d), and (e)(3) are revised to read as follows:#
Passage 416Sec. 178.276 Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of non- refrigerated liquefied compressed gases. * * * * * (a) * * * (4) * * * (ii) * * * (A) Not less than the pressure specified for each liquefied compressed gas listed in the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313; and * * * * * (d) Bottom openings. Bottom openings are prohibited on portable tanks when the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313 of this subchapter indicates that bottom openings are not allowed. In this case, there may be no openings located below the liquid level of the shell when it is filled to its maximum permissible filling limit. (e) * * * (3) A portable tank intended for the transportation of certain liquefied compressed gases identified in the UN Portable Tank Table for Liquefied Compressed Gases in Sec. 173.313 of this subchapter must have a pressure relief device which conforms to the requirements of this subchapter. Unless a portable tank, in dedicated service, is fitted with a relief device constructed of materials compatible with the hazardous material, the relief device must be comprised of a frangible disc preceded by a reclosing device. The space between the frangible disc and the device must be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement must facilitate the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible disc must rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device. * * * * * 80. In Sec. 178.602, paragraph (b) is revised to read as follows: Sec. 178.602 Preparation of packagings and packages for testing.#
Passage 417* * * * * (b) For the drop and stacking test, inner and single-unit receptacles other than bags must be filled to not less than 95% of maximum capacity (see Sec. 171.8 of this subchapter) in the case of solids and not less than 98% of maximum in the case of liquids. Bags shall be filled to the maximum mass at which they may be used. The material to be transported in the packagings may be replaced by a non- hazardous material, except for chemical compatibility testing or where this would invalidate the results of the tests. * * * * * 81. In Sec. 178.603, paragraphs (c)(1) and (e)(2) are revised to read as follows: * * * * * (c) Special preparation of test samples for the drop test. (1) Testing of plastic drums, plastic jerricans, plastic boxes other than expanded polystyrene boxes, composite packagings (plastic material), and combination packagings with plastic inner packagings other than plastic bags intended to contain solids or articles must be carried out when the temperature of the test sample and its contents has been reduced to -18 [deg]C (0 [deg]F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti- freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at -18 [deg]C (0 [deg]F) or lower are considered acceptable test liquids. Test samples prepared in this way are not required to be conditioned in accordance with Sec. 178.602(d). * * * * * (e) * * * * * * * * (2) For liquids in single packagings and for inner packagings of combination packagings, if the test is performed with water: * * * * * 82. In Sec. 178.810, paragraph (b)(3) is revised to read as follows: * * * * * (b) Special preparation for the drop test. * * * * * (3) Rigid plastic IBCs and composite IBCs with plastic inner receptacles must be conditioned for testing by reducing the temperature of the packaging and its contents to -18 [deg]C (0 [deg]F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at -18 [deg]C (0 [deg]F) or lower are considered acceptable test liquids. IBCs conditioned in this way are not required to be conditioned in accordance with Sec. 178.802. * * * * * PART 180--CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS#
Passage 41883. The authority citation for part 180 continues to read as follows: Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53. 84. In Sec. 180.350, paragraph (c) is revised to read as follows: Sec. 180.350 Applicability and definitions. * * * * * (c) Routine maintenance of IBCs is the routine performance on: (1) Metal, rigid plastic or composite IBCs of operations such as: (i) Cleaning; (ii) Removal and reinstallation or replacement of body closures (including associated gaskets), or of service equipment conforming to the original manufacturer's specifications provided that the leaktightness of the IBC is verified; or (iii) Restoration of structural equipment not directly performing a hazardous material containment or discharge pressure retention function so as to conform to the design type (for example, the straightening of legs or lifting attachments), provided the containment function of the IBC is not affected. (2) Plastics or textile flexible IBCs of operations, such as: (i) Cleaning; or (ii) Replacement of non-integral components, such as non-integral liners and closure ties, with components conforming to the original manufacturer's specification; provided that these operations do not adversely affect the containment function of the flexible IBC or alter the design type. 85. In Sec. 180.352, paragraph (d)(1)(iv) is revised and a new paragraph (d)(1)(v) is added to read as follow: Sec. 180.352 Requirements for retest and inspection of IBCs. * * * * * (d) * * * (1) * * * (iv) Except for routine maintenance of metal, rigid plastics and composite IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing the routine maintenance shall durably mark the IBC near the manufacturer's UN design type marking to show the following: (A) The County in which the routine maintenance was carried out; and (B) The name or authorized symbol of the party performing the routine maintenance. (v) Retests and inspections performed in accordance with paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the requirements for the 2.5 and five year periodic tests and inspections required by paragraph (b) of this section, as applicable. * * * * *#
Passage 419Issued in Washington, DC on May 26, 2004, under authority delegated in 49 CFR part 106. Frits Wybenga, Deputy Associate Administrator for Hazardous Materials Safety. [FR Doc. 04-12411 Filed 6-21-04; 8:45 am] BILLING CODE 4910-60-P#
This material provides agency context. It does not replace binding regulatory text, and its legal effect depends on the underlying authority and facts.