Guide 153: Substances - Toxic and/or Corrosive (Combustible)

ERG 2024 Guide 153, page 1GUIDE 153 Substances - Toxic and/or Corrosive (Combustible) POTENTIAL HAZARDS HEALTH • TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death. • Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears). • Contact with molten substance may cause severe burns to skin and eyes. • Avoid any skin contact. • Fire may produce irritating, corrosive and/or toxic gases. • Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination. • • • • • • • FIRE OR EXPLOSION Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Corrosives in contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. PUBLIC SAFETY CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Keep unauthorized personnel away. Stay upwind, uphill and/or upstream. Ventilate closed spaces before entering, but only if properly trained and equipped. • • • • PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. • Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. EVACUATION Immediate precautionary measure • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Spill • • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances. For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary. Fire • If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. Page 236 ERG 2024#

ERG 2024 Guide 153, page 2Substances - Toxic and/or Corrosive (Combustible) GUIDE 153 EMERGENCY RESPONSE FIRE Small Fire • Dry chemical, CO2 or water spray. Large Fire • Dry chemical, CO2, alcohol-resistant foam or water spray. • If it can be done safely, move undamaged containers away from the area around the fire. • • Dike runoff from fire control for later disposal. Fire Involving Tanks, Rail Tank Cars or Highway Tanks Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. • Do not get water inside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks in direct contact with flames. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Prevent entry into waterways, sewers, basements or confined areas. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. • DO NOT GET WATER INSIDE CONTAINERS. FIRST AID Refer to the “General First Aid” section. Specific First Aid: • For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required. • Removal of solidified molten material from skin requires medical assistance. In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section. ERG 2024 Page 237#