Guidanceguidance
02-0084
US Liquids of Georgia Solvent Division — Hazardous Materials Safety Interpretation
Current as of source date Government source
RegulusPipeline researchRegulusPipeline research02-0084
Page 1• U.S. Department of Transportation 400 Seventh St., S.W. Research and Washington, D.C. 20590 special Programs Administratior JUL 10 2002 Ms. Joan Van Matre US Liquids of Georgia Solvent Division Ref. No.: 02-0084 1184 Logan Circle Atlanta, GA 30318 Dear Ms. Van Matre: This responds to your March 18, 2002 letter requesting clarification on shipping paper documentation and placarding under the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180). Specifically, you ask the correct shipping description and proper placard required for your non-bulk and bulk shipments of combustible plate wash solvent. According to your letter, you ship a plate wash solvent that you have classed as a "Combustible liquid" in 55-gallon drums and in 275-gallon totes. The shipping papers attached with your letter are not in compliance with the HMR. The basic shipping description (the proper shipping name, hazard class number, UN identification number, and packing group number) is incorrect. Regarding the sequence.of information, the type of packaging, e.g., "drums, (55 gal)" may be entered before or after the basic • description. Any additional information concerning the material must be placed after the basic description required by § 172.202(a). In addition, "plate wash solvent" is not a proper shipping name or proper technical name. Generic shipping paper entries such as "Combustible liquid, n.o.s.", requires a technical name or chemical name of the ingredient that makes the material combustible. A technical name is a recognized chemical name or microbiological name currently used in scientific and technical handbooks, journals, and texts. Generic descriptions are authorized for use as a technical names provided they readily identify the general chemical group, or microbiological group. Examples of acceptable generic chemical descriptions are organic phosphate compounds, petroleum aliphatic hydrocarbons and tertiary amines. Trade names may not be used as technical names. The following is an example of a proper shipping description for a "Combustible liquid, n.o.s." material: 1 tote, Combustible liquid, n.o.s. (proper technical name), NA 1993, 400 Ibs. In response to your placarding question, if you meet provisions in § 173.150(f), the non-bulk (55-gallon drum) shipment of the plate wash solvent is not subject to the HMR, including shipping paper, marking, labeling, and placarding, unless it is a hazardous waste, hazardous substance, or marine pollutant.#
Page 2However, the bulk (tote) shipment of the plate wash solvent is subject to the HMR as stated in § 173.150(f) and must be properly described on the shipping paper, marked, packaged, and placarded. Each bulk package must be marked with the UN identification number as specified in §§ 172.302 and 172.322. In accordance with § 172.504(a), each bulk packaging, freight container, unit load device, transport vehicle, or rail car containing any quantity of a hazardous must be placarded on each side and each end with the type of placards specified in tables 1 or 2 of this subpart. In addition, under § 172.514(c), a tote or portable tank having a capacity of less than 3,785 L (1,000 gallons) may be placarded on only two opposite sides or, alternatively, may be labeled instead of placarded. For your information, there is no combustible label authorized in the HMR. A placard on a tote may be used to meet vehicle placarding if it is visible on all four sides; however, if the bulk package is inside a freight container or transport vehicle and the placards are not visible, the motor vehicle must be placarded on all four sides and the UN identification number displayed. I hope this answers your inquiry. Sincerely, Delmer F. Billings Chief, Standards Development Office of Hazardous Materials Standards#
Page 3• ° Boothe : §172.101. §172.544 March 18, 2002 Proper Shipping Name Mr. Ed Mazzullo The Hazardous Materials Information Center Placarding Dear Mr. Mazzullo, 0Z-0084 We need your help in clarifying the correct shipping papers and truck placarding for the plate wash solvent that we sbip. I am faxing you the following: Our standard shipping Bill of Lading (for 1 - 55 gallon drum/275 gallon tote/24 - 55 gallon drums) The MSDS for two of the solvents that we ship We need information in writing please for the following: • For a 275 gallon tote sbipment - correct shipping papers and correct truck placard • For a 55 gallon drum (each drum weighs 400 Ibs.) - correct shipping papers and truck placard if any required • For 20 - 55 gallon drums or more - correct shipping papers and truck placard if any • required Also, we need to know if a common carrier is carrying 20 - 55 gallon drums and the trailer naa combustible placarding, and he had the snipping papers completed as we are sending you for plate wash solvent, was he in violation for having the combustible placards on the trailer? He had a DOT officer pull him over on Friday and he was given a ticket for having the combustible placard on his trailer. The officer said it was not supposed to be placarded at all since it was drums not bulk (tote). We do put 2 combustible labels on the 275 gallon totes for shipment and we have been giving the fried are diverte com busine ford fries tale we more than 2200 Ibs in 55 gallon drums but we do not put the combustible labels on the 55 gallon drums. Please fax your response to my attention at 404-605-0095 and please mail the original to: Joan VaniMatre US Liquids of Georgla Solvent Division 1184 Logan Circle Atlanta, Georgia 30318 If you have any questions, please call me at 404-605-0085. Thank You for your assistance. 20 394d 9600909605#
Page 4STRAIGHT BILL OF LADING PAGE BOL MAT ORIGINAL-NOT NEGOTIABLE 1 OF 1 I DATE $376 • TERMS March 18, 2002 #PRO: 000-000000-00 * CARRIEA Prepalo SECT JSCH'- USF Hollana 2 2 норі TANLEANO PU DATE PU TIME SHIPPER CONSIGNEE Us Liquids 1184 Logan Circle, N.w. Tru-Color 3803 Ford Circle Atlanta GA 30318 Cincinnati OH 45227 BILL TO OR REMITTO •. ISSUING OFFICE OR AGENT GENERAL COMMENTS PLEASE DO NOT BREAK PALLETS! • HOT RUSH / NON-HAZIPLEASE DO NOT BREAK •. PIECES IN DESCRIPTION SUBJECT TO CORRECTION WEIGHT LBS RATE CHARGES CLASS 1 Drums, DRUM(S) (55/GAL) 400 Purchase Order latewash Solvent IT#101720-3 • TOTALS 400 • • • • • REMIT C.O.D. TO COD AMT: $ C.O.D. FEE PREPAID Subject to Seclion 7 of conditione, it this shipment is 10 COLLECT ADDRESS slanor, the consianor shall sion the following stalament: De dellversa to the consignse without recourse on the con NOTE - Where the rate to dependent on value, shippars are requirad to state The carior shall not make delivery of this enfoment CHARGES TOTAL pacifically in writing the agreed or declared value of tha property The screed or doclared valua of the property Is hereby specifically stated by the without payment of Ireloht and all other lawful charges. =hipper to ba not exceading. UNLESS MARKEO COLLECT FAEIGHT CHARGES ARE PREPAJO $ (Signature ol Consignon CHECK BOX IF COLLECT marked, concigned, and desined a nacals abovo which sald carrer (ihe word canfer bain undered throughoul thie contacles meaning any person or corporation in poscocion of property under the contract, egita to cany tolts usual RECEIVE, sudid to the classication and lenta in eradi on the dale of this lesun of thie Sit of Lading. The procery described alove in apparent good order, except as noted (contente and condion of contenta of package a unknown). Disco of delvery al aRia destinellon, d on la routa, ononico to delve lo another cameron ina roula to asta dealinallon. Mis mutuaty sarced as to esch carrar of ail or any of said property, over all or any portion of sala routa to dosinasior nd es to each party at any lima interested in sil or any said property, that every service to da penomad hamunder shall to cubjact to al the bil ol isco lem and conartons in governing classificason on tha dato of shipmer SHIPPER Til is to coral at are above are acoite are prosie casino cecio. acted Marked and apolo and are in proper color or last econo a lot role to an o US Liquide Usf Holland PER PER DATE • Mark with or ROll appropriato to designare Hazardous Materials or Hazardous Subetances a dolined in the department of Transportation Regulatons govarning the bransporation o hazardove malarials The ưso of this column ie an optional method for identllying hazardous materisis on bille of lading por Section 172.201 (a) (1) (Ill) of Thie 49, Code of Fedenal Reguistong, Also, when shipping hazardous matorials. the shipper's certification stalement prescribed in Saclion 172.204 (e) of the Fodoral Regulatione must be Indicated on the blll of lading, unless a spocito exosption from this requremont is provided In the Reculations for a particular mataris. E0 394d SaINDITSA S600909500 2007/8T/E0#
Page 5STRAIGHT BILL OF LADING PAGE OF BOL. NEA. • ORIGINAL-NOT NEGOTIABLE 1 * DATE 3376 * TERMS • March 18, 2002 CARRIER Prepaid PRO 000006000-00 SEC 7 AACT - ARA Cooper Transportation PU DATE PUTIME :: 341, DOOR: SHIPPER CONSIGNEE US Liquids 1184 Logan Atlanta circle, N.w. GA 30318 BILL TO OR REMIT TO ISSUING OFFICE OR AGENT • GENERAL COMMENTS PIECES IN DESCRIPTION EJECT TO CORRECTIO NEIGHT LBS RATE CHARGES CLASS 1 X Tots eins, TOTE(S) (275/921) 2000 Platewash Solvent IT#101720-3 Datest 501Vn, No 1593, • Purchase Order # III Emergency #1-800-366-9880 - • TOTALS 2000 : • REMIT C.O.D. TO COD AMT: $ C.O.D. FEE PREPAID ADDRESS bo dollverad to tha constones without recourse on the con- Sublectto Sucion 7 of condione, Il lhit ehipmantie to 7 COLLECT $ ecifically in wriling the agrand or declared value of the proper OTE - Whor the rate is depandant on value, shippers are requred to fie signor, the consonor shall sign the following statement: The carrer shall not mako dollvory of hit shipment CHARGES TOTAL $ chipper to be not excesaing. The agreed or declared value of the property is hareby epocificalty staled by ine without pRyment of froighl and all other lawtul charpas. FREIGHT CHARGES ARE PREPAID UNLESS MARKED COLLECT $ per. (Signalure of Consignor) CHECK BOX IF COLLECT marked, consignad, and doeáned as indicaled abave which cald asiar the word carrier being understood throughoul the con rect a meaning any peacon of corporaton in pottestion of property under the contraco agreed to carry lo Hs UsUAl A data den to de a ding, the property decod above in apparent good order, exco, as nold (contante and condilion of conlante of packagoe unknown), placo of delivary as daid daatinallon, lt on lta roulo, america la dared to another cater on the route lo sald destinalton, it is mutuay agrod as to nach care of at or any of gad property, over all of any portion of aid roule to destina for and se to each party al any ume interested in all or any said proparty, that query service lo be penormod harunder what be subiect to all the bit of sacing lemns and condisone in gerarning discrification on tha date of ehioment at to triproper case, dacord, packagod, marked and lab sid and are in proper condian for transportaton, scarding to the colcable regula kone of the Decertmant of Transportation Shipper hereby confes that hor is lamiber wih fil the thi of leding toms and conditions in the governing cla mallication and the said ter and condon at hereby agiced to by the chipper and accected or him eif and his 155 one SHIPPER CARRIER PER US • Liquids ARA Cooper Transportation PER DATE • Mark with "X*or Rolf appropriate to designato Hazardous Matoriale or Hazardou Substances as delinad in the deparimont of mansportation Regulations govoming the transportation of hazardous malories. the shippors contilleation atatement prescribad In Section 172,204 (R) of lic Fadoral Regulations must be Indicated on the bill of lading, unlose a specile exceplion from sis requiramant le provided in the The uao of this columnle an opllonal method for identlfying hazardous matorials on bite of lading por Section 172.201 (a) (1) (ill) of Tillo 49, Code of Federal Regulatons. Also, when shipping hazardous matarialg. 39Vd SAINDITSN 900909-01 09: 200/0#
Page 6STRAIGHT BILL OF LADING PAGE ORIGINAL-NOT NEGOTIABLE OF 1 DATE 8376 : TERMS March 18; 2002 * CARRIER Prepaid SPR0000-000000~ỌQ SEC 7) GATF - R&L CarrisTE PU DATE PU TIME DOOR •3. 9326) SHIPPER US Liquid= CONSIGNEE : Atlanta 1184 Logan Circie, N.W GA 3031$ MA BILL TO OR REMITTO ISSUING OFFICE OR AGENT GENERAL COMMENTS PLEASE 00 NOT BREAK PALLETS! • HOT RUSH / NON-HAZIPLEASE DO NOT BREAK PIECES IN H DESCRIPTION RATE CHARGES CLASS 24 Xorums, DRUMS) (55/GAL) $600 Purchase Order # Platowash Solvent IT#101720~3 5= Combustible Liquids, • • NOs, Platewash Solvent, NA1993, Emergency# 1-800-355-9850 • 24 TOTALS 3600 • TO REMIT C.O.D. COD AMT: $ C.O.D. FEE PREPAID AODRESS da deliverad lo the consigne without secourse on the con Subjeci to Secilen 7 of conditions, i this shipment is to COLLECT $ epecifically in writing the agreed or declared value of the property. NOTE • Whore the rata is dopondent on valuo, chippere aro roquirad to elato sionor, the consignor shall sign the following etalamant The camer chall not make delivery of thie shipment TOTAL shipper lo ba nal oxceeding. The agreed or declared value of the property is hereby specifically stated by the without payment of freight and all other iawlul charges. CHARGES $ FREIGHT CHARGES ARE PREPAID $ CHECK BOX IF COLLECT UNLESS MARKED COLLECT RECEIVED, sutject to the darelicallons and laritle in offoct on tha date of thic leave of inle Bal of Lading, tha preparty doccriced above In apparent good order, axcop: as noted (comtams and condition of contexis ol packages unknama). per (Signature of Consignor) markod, concigned, and ductined de indicated above Which taid carrier fihe word eater being undere ood throughout the cotact el meaning ay perton or cotporation in possession of property under the contact syrdes to carry to he vevo. a deter eat de at te er to deto cat role to old denalton it te mutualy agreed a to each cater of all or any of aal proparty, over all or any porson ol sela roule to destinata. and ae to each party at any me interested in all or any sald property, that every serie to be partormed morounder shall bo subjeci lo at tha bill al isting deems and condilans in governing diascifies ion on ho data ol stipment to can that hoove named material are property classed, described, packaged, marked and lad bed and are in proper conchion for tansportalan, according to the coplesble regulsdone of the Dopartmont of Transportation. Shipper hardy certies mat nor camillar wan a the bik of lading terms and conctions in the governing clascificaton and the cold terms and condions ate hereby somed to by the hipper and accepled for himsolf and his astigns "SHIPPER CARRIER US Liquids Rel Carriers PER PER DATE Mark with "*" or "RO" it appropriato lo designate Hezardous Materiale or Hazardous Subetances as defined In the department of Transportsdon Regulations govarrung tha Iransportalion of hazardous maleriale. the shipper's conilication atatemant precaribad in Saction 172.204 (a) of the Fodoral Roguialians mutt be indiasied on the bill of lading, unless a apecitic exception from this requirement is provided in the The use of this column is an optional mathed for identlying hazardous materials on bble of lading per Soction 172.201 (e) (1) (Itl) of Tile 49, Code of Federal Regulations. Also, when shipping hazardous malariale, Regulallons for a partleular material, 90 394d SAINDITSO S0090950 ES bE 200/1/80#
Page 7MSDS Number: P000197 http://www.dupont.com/masds/60_65_g0000197html : COU POND customers and is intended only for their use. Information in this format is provided as a gervice to our at their own discretion and risk. requirements and may not meet regulatory requirements in other The MSDS format adheres to U.s. standards and regulatory locations.. believes to be reliable. This information is based upon technical information DuPont knowledge and experience are gained. Please return to this •It is subject to revision as additional website for the most current version. • "OPTISOL" IN-LINE SOLUTION CONTAINING "CYREL" FLEXOGRAPHIC PLATE MATERIAL P0000197 Revised 15-MAR-2000 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification cyrel Optisol, Cyrel are registered trademarks of DuPont. Product Use "Cyrel" Flexographic Printing Plates are considered articles by OSHA (CER1910.1200)• However, unexposed plates contair naterial that may cause skin irritation of allergic skin рEо80» » солей» от покровс ра настоло суте. This MSDS is applicable only to spent solutions (before • Plates with Company Identification MANUFACTURER/DISTRIBUTOR DuPont "Cyrel" Packaging Graphios • 10f8 90 SHINDI TO 9600909506 07/07/2000 10:50 AM і#
Page 8MSDS Number: P0000197 http://www.duponr.com/nasds/60_65_p0000197.btml : Products Chintnut Run Plaza, Budding 702 19880-0702 PHONE NUMBERS Product Information Medical Emergency Transport Emergency : 800-424-9300 (CHEMTREC : 800-345-9999 - press 1 : 800-441-3637 COMPOSITION/INFORMATION ON INGREDIENTS Components Material CAS Number Heptyl Acetates 70914-20-4 90438-79-2 15-70 Unexposed "Cyrel" Flexographic Printing Plate -5-30 material (contains synthetic rubber and 10-95 Components (Remazks) Material 1s not known to contain Ioxic Chemicals under Section 313 OF 1986 and 40 CFR part 372. of Title III of the Superfund Amendments and Reauthorization Act HAZARDS IDENTIFICATION Potential Health Effects INHALATION lungs with cough, difficulty breathing or shortness of breath. Short-term overexposure may cause: Irritation of nose, throat, and Central nervous system depression with dizziness, confusion, effects such as headache, nausea and weakness. coordination, drowsiness or unconsciousness. Non-specific The distinctive odor of "Cyrel Optisol" In-Line Solution disagreeable to some individuals. which is said to be noticeable at 0.1 to 2.0 ppm may be SKIN CONTACT Short-term overexposure may cause: Irritation with itching, 20f8 403940 9608909580 19:12020 07/07/2000 10:50 AM#
Page 9MSDS Number: P0000197 http:/www.dupont.com/msds/60_65_p0000197.htonl burning, redness, swelling of rash. Repeated and/os prolonged exposure may cause: Skin sensitization with allergic tashes. EYE CONTACT pain or blurred vision. Contact with liquid may cause: Severe eye irritation with tearing, cause eye irritation with tearing, pain or blurred vision. Contact with the vapor or aerogol may INGESTION Che major ingestion hazard is aspiration (liquid entering the pneumonia". ungs during ingestion or vomiting) which may result in "chemica. after exposure, depending on how much chemical entered the lungs. Carcinogenicity Information dona to or grego than it are 120e b al, 0, OStA 02 ACCH as a carcinogen. FIRST AID MEASURES First Aid INHALATION. artificial respiration. If breathing is difficult, give oxygen. If inhaled, remove to fresh air. If not breathing, give SKIN CONTACT Wash contaminated clothing before reuse. In oase of contact, immediately wash skin with soap and water. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call' a physician. INGESTION If swallowed, do not induce vomiting. of water. Never give anything by mouth to an unconscious person. Inmediately give 2 glasses Call a physician. Notes to Physicians measures as needed. No antidote or specific treatment regimens known. Use supportive 3 of8 80 390d 9600909080 ES: 2032781/e6 AM#
Page 10MSDS Number: P0000197 http://www.dupont.com/msds/60_65_p0000197.html : FIRE FIGHTING MEASURES Flammable Properties Flashpoint: >141 E and <200 F Extinguishing Media Water Spray, Foam, Dry Chemical. Fire Fighting Instructions breathing apparatus. Keep personnel removed and upwind of fire. Wear self-contained tank/container with water pray protective equipment. cool ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) Initial Containment Remove source of heat, electricity. Dike spill. sparks, flame, impact, friction or Prevent material from entering sewers, wateiways, or low areas. Spill Clean Up soak up with noncombustible absorbent materials. HANDLING AND STORAGE Handling (Personnel) close than poor ate and contact yes in o Clothing pIlot to rouse. • ants 50 JOVd SaInDITSn 9600909500 19:1 200Z/ 07/07/2000 10:50 AM#
Page 11MSDS Nuruber: P0000197 http://www.duponz.com/msds/60_65_p0000197.html : Handling (Physical Aspects) Peep nay from heat, sparke and flames. Ground container when Storage container tightly closed. store in a well ventilated place. Store in a cool place. Kee! BOODROO EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Use sufficient ventilation to keep employee exposure below Iecommended limits. Personal Protective Equipment EYE/FACE PROPECTION Dear coverall chemical splash goggles and face shield when spraying materials. posalbility exists for eye and face contact due to splashing ox RESPIRATORY PROTECTION Limits, a NIOSH approved respirator should be selected based on Where airborne concentrations are expected to exceed exposure he form and concentration of the contaminant in air and in accordance with OSHA Respiratory Protection Standard CER 1910.134. PROTECTIVE CLOTHING Wear impervious clothing, such as gloves, apron, boots, or whole bodysuit as appropriate. Exposure Guidelines Exposure Limits • MATERIAL "OPTISOI" IN-LINE SOLUTION CONTAINING "CYREL" FLEXOGRAPHIC PLATE TIV PEL (OSHA) (ACGIH) : None Establishec : None Established PHYSICAL AND CHEMICAL PROPERTIES Physical Data Color Form : Varies from Láquid to semi-solid • sof8 0I 3940 SCINDITSO 9600909780 2007/8I/E0 07/07/2000 10:50 AM#
Page 12MSDS Number: P0000197 http://www.dupont.cora/msds/60_65_p0000197.html odor : : Slight odor STABILITY AND REACTIVITY отстаю- Chemical stability Stable at normal temperatures and storage conditions. Incompatibility with Other Materials Incompatible or can react with strong oxidizers, strong acids, bases. Polymerization Polymerization will not occur. TOXICOLOGICAL INFORMATION Animal Data For toxicity information, contact "Cyrel" Packaging Graphios Products at 1-800-345-9999. ECOLOGICAL INFORMATION Ecotoxicological Information Fordinto at 1-0-015-99 Crel" Packaging Graphics For information, DISPOSAL CONSIDERATIONS Waste Disposal • accordance with applicable Federal, State/Provincial, and Local Treatment, storage, transportation, and disposal must be in regulations. Do not flush to surface water or sanitary sewer 60f8 IT 394d SaInDITSn 9600909505#
Page 13• MSDS Nunber: POQ00197 http://www.duponr.com/msda/60_65_p0000197.html system. Flexographic Printing Plate material with "Cyrel Opti5ol" spent solutions and/or stillbottom wastes containing "Cyrel" In-line Solution have been analyzed by the Toxioity organies and are below all regulatory levels currently Characteristic Leachate Procedure (ICLP) for metals and 11sted by the Environmental Protection Agency (EPA). Flexographic Printing Plate material with "Cyrel OptiSol" Spent solutions and/or stillbottom wastes containing "Cyrel" In-Line Solution do not meet the Federal definition of a 19 the recommended disposal method. DO NOT landfill. RCRA hazardous waste. Incineration in an approved facility has banned liquids from landfills. stillbottom wastes containing "Cyxel" Flexographic Printing Spent solutions and/or meet the EPA requirements. Plate material with "Cyrel OptiSol" In-Line Solution may not REGULATORY INFORMATION ТІКОГТ 111E3083 U.S. Federal Regulations ISCA Inventory Status : In compliance with ISCA Inventory requirements for commexoial purposes. TITLE III HAZARD CLASSIFICATIONS SECIIONS 311, 312 Chronic : Yes : Yes Pressure OTHER INFORMATION Additional Information For additional Material Safety Data Sheets, contact your DuPont dealer or the DuPont marketing service center which serves your axea. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use ir combination with any other material or in any process. Responsibility for MSDS: Prodit "Cyre!" Packaging Graphica Address : Chestnut Run Plaza - 702 7 018 2 3940 SCINDITSA 9600909580 ES:+T 200Z/8T/E0 07/07/2000 10:50 AM#
Page 14MSDS Number: P0000197 http://www.dupont.com/msds/60_65_p0000197.homl : Telephone : 800-345-9999 (Prese 1) Wilmington, DE 19880-0702 End of MSDS • 8o18 ET SAINDITSN S600909500 2782/81/880 AM#
Page 15Mac Dermid! Flex-Light® GRAPHICARTS Letterflex@ Systems 5210 Phillip Lee Drive Atlanta, GA 30336 24 Hour Emergency Chemtrec: 800-424-9300 MATERIAL SAFETY DATA SHEET PRODUCT IDENTIFICATION TRADE NAME: Solvito eD SYNONYMS: NA • II. HAZARDOUS COMPONENIS Components CAS # OSHA ACGIH PEL Petroleum Hydrocarbon* NE NE Aliphatic Alcohol* 50 50 ppm (skin) 50 ppm (skin) * The specific chemical identity is a Trade Secret and is therefore not for these compounds. being disclosed in the MSDS. Potential hazard information is not being withheld. The MSDS includes health hazard information physician or other health-related personnel. The specific chemical identity will be provided upon request by a NA = Not Applicable NE = Not Established III. PHYSICAL DATA BOILING POINI: 353-390°F at 760mm Hg MELTING POINT: Liquid at room temperature SPECIFIC GRAVITY (H2O=1): 0.87 @ 60ºF VAPOR PRESSURE: 1 mm @ 100°F VAPOR DENSITY (AIR=1): 4.0 SOLUBILITY IN H2O: Less than 0.1% 77F 8 VOLATILES BY VOLUME: 100 EVAPORATION RATE: 0.1 (Butyl Acetate = 1) SCINDITO 9600909000 ES T 2007/8T/80#
Page 16: SOLVITO OD PAGE 2 Of 5 APPEARANCE AND ODOR: Clear, colorless liquid; aromatic hydrocarbon odor. VOC'S: 1008 WEIGHT: 7.3 Pounds per Gallon IV. FIRE AND EXPLOSION DATA FLASH POINT: 145°F minimum, Pensky-Martens Closed Cup NEPA 704: Health 2 Flanmability 2 Reactivity O AUTO IGNITION TEMPERATURE: ~802°F EXPLOSIVE LIMITS IN AIR: Lower Explosion Limit: "1.88 Upper Explosion Limit: "11.7% EXTINGUISHING MEDIA: Carbon Dioxide, foam, water spray, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Use self-contained breathing apparatus. exposed to heat, sparks or open flame. UNUSUAL FIRE AND EXPLOSION HAZARD: Combustible liquid. May ignite if and other decomposition products of' undetermined hazard. Could generate oxides of Carbon vapor) and can be dangerous. EMPIY CONTAINER WARNING; Empty containers retain residue (liquid and/or DRILL, GRIND OR EXPOSE SUCH CONTAINERS IO HEAT, DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION AS THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. V. REACTIVITY DATA STABILITY: Product is stable. INCOMPATABLITY: Sulfuric acid, strong oxidizing agents, inorganic acids, halogens, aldehydes, acid anhydrides, alkylene oxides, monomers and HAZARDOUS DECOMPOSITION PRODUCTS: In case of fire, flammable hydrocarbons. • HAZARDOUS POLYMERIZATION: Will not occur. ST 39Vd SaINDITSN 9600509000 ES:DT 2802/87/EB#
Page 17SOLVIT® QD PAGE 3 OF 5 •. VI. HEALTH HAZARD DATA EXPOSURE LIMITS: None established for mixture. TOXICIIY DATA: Irritating to rabbits in a primary dermal irritation study. No skin sensitization was observed in guinea pigs (Buehler). CARCINOGENICTY: NTP? See below IARC Monographs? No OSHA Regulated? No PRIMARY ROUTE (S) OF EXPOSURE: Eye contact, skin contact, inhalation. EFFECTS OF OVEREXPOSURE: ACUTE: Eye contact causes severe irritation. promptly, eye injury will occur which may result in permanent If not removed under normal conditions, Skin contact causes irritation. Although not present to the eyes and the respiratory tract and may cause headaches, high vapor concentrations are irritating effects. dizziness, unconsciousness and other central nervous system These effects are temporary and reversible. report states that lifetime inhalation exposure to naphthalene CHRONIC: This product contains 0.38 Naphthalene. An NIP draft resulted in increases in tumors of the nose in rats. In a previous study, lifetime inhalation exposure increased lung tumors in female mice. The relevance of these findings to humans is not known. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Asthma, bronchitis, emphysema and any other respiratory disorders. VII. SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS: Use local and mechanical exhaust to minimize exposure to vapors or mists. 50 ppm alcohol. RECOMMENDED OCCUPATIONAL EXPOSURE LIMITS: 100 pom total hydrocarbons, PERSONAL PROTECTIVE EQUIPMENT: approved air purifying respirator equipped with NIOSH approved organic vapor cartridges is recommended. Use must comply with the OSHA standard for respiratory protection (29 CFR 1910.134) including appropriate fit testing and training. EYE: Chemical splash goggles. SAINDITSO 600909580 E9:0 200z/8/60#
Page 18SOLVIT® OD PAGE 4 OF 5 GLOVES: Impervious nitrile or butyl rubber. • VIII. FIRSI AID PROCEDURES EYE CONTACT: If the material gets in the eyes, immediately wash the eyes with upper eyelids. Continue for 15 minutes. Get medical attention copious amounts of water, occasionally lifting the lower and immediately. SKIN CONTACT: If the material gets on the skin, immediately wash the area with INGESTION: If the material has been swallowed, do not induce vomiting. Get medical attention immediately. INHALATION: If dizziness, coughing, experienced, remove to fresh air. irritation or tightness in the chest i is difficult. Get medical attention immediately. Administer oxygen if breathin IX: SPILL OR LEAK PROCEDURES STEPS IO BE TAKEN IN CASE MATERIAL IS SPILLED: Evacuate area of all non-essential personnel. Remove all sources apron or lab coat and respirator. Ventilate confined spaces. Contain spill with absorbent wear gloves, goggies, material such as sand or earth. socks to prevent sewer runoff. Absorb spill with absorbent such as sawdust. Using non-sparking tools, shovel into salvage Do not use combustible materials container. WASTE DISPOSAL METHOD: Waste liquid can be incinerated or used for fuel blending- Naste products may be hazardous due to ignitability. Comply witi federal, state and local regulations • LT 39Vd SaInDITSn 9600909501 89: 200z/81/80#
Page 19SOLVIT® OD PAGE 5 Of 5 X. SPECIAL PRECAUTIONS Store in a cool, well-ventilated area away from flammable materials and sources of heat, sparks or flame. Use with electrically grounded Practice good housekeeping and vigorous personal hygiene to minimize contact with material. This product is for industrial use only. Do not reuse container. XI. REGULATORY COMMENTS DOT CLASSIFICATION: Not regulated for non-bulk packaging. For bulk packaging: Combustible liquid, n.o.s.; Combustible liquid; NA 1993; PG III ISCA STATUS: All components are on the ISCA Chemical Substance Inventory. SARA TITLE II: This product contains no chemicals on the EPA's list of Toxic Release Chemicals under Section 313 above regulated thresholds. 1990 CAA Amendments HAP's: This product contains 0.38 Naphthalene, CAS# 91-20-3. XII. PREPARATION INFORMATION PREPARED BY: Linda Weglewski, Regulatory Affairs Manager ADDRESS: 5210 Phillip Lee Drive Atlanta, GA 30336 TELEPHONE: (404) 696-4565 DATE: April 4, 2001 SUPERSEDES: December 20, 2000 The data included herein are presented according to practices current at the time of preparation hereol, are made available solely ior the consideration, investigation and verification of the original recipients hereof and do not constitute a representation or warranty for which responsibility of a recipient of this data to remain currently MacDermid Graphic Arts assumes responsibility. informed on chemical hazard information, safety program and to comply with all national, federal, local laws and regulations applicable to safety, occupational health, right to know and environmental protection. 8T 390d SAINDI ISN 9600909503 E9:t[ 2000#
This material provides agency context. It does not replace binding regulatory text, and its legal effect depends on the underlying authority and facts.