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03-0191
Page 1MAY 26 2004 Washington, D.C. 20590 400 Seventh St., S.W. Research and ecial Progran dministratio Ms. Alicia M. Shaban Regulatory Chemist Ref. No. 03-0191 Environment, Health & Safety Ondeo Nalco Company Ondeo Nalco Center IL 60563-1198 Dear Ms. Shaban: This responds to your letter regarding the determination of under the Hazardous Materials Regulations (HMR; 49 CFR Parts 171- proper shipping names for corrosive liquid mixtures and solutions appropriate to use the acidic/basic and organic/inorganic 180). Specifically, you are requesting whether it is more UN3267) or the "Corrosive liquid, n.o.s." proper shipping name corrosive liquid descriptions (Identification Numbers UN3264- (UN1760) under various scenarios. responding. Your scenarios are paraphrased and answered as I apologize for the delay in 01. A mixture or solution is neither significantly acidic or basic (pH 7). The hazardous constituent of the mixture or solution is a basic organic component. shipping name be "Corrosive liquid, basic, organic, n.o.s." Should the proper (UN1760)? (UN3267) or the more generic "Corrosive liquids, n.o.s." A1. Assuming the pH neutral mixture or solution meets the determining whether a mixture or solution is definition of a regulated corrosive material, when acidic/basic or based on the hazardous constituent (s) of the mixture or organic/inorganic, a shipper must make that determination solution. describes the constituent (s) must be used. The proper shipping name that most appropriately The most describe would be "Corrosive appropriate description for the mixture or solution you (UN3267) . liquid, basic, organic, n.o.s." 173-136 030191#
Page 2Q2. A mixture or solution contains organic non-hazardous constituents and an inorganic hazardous component or, alternatively, inorganic non-hazardous constituents and an organic hazardous component. What criteria should be used to determine the proper shipping name under this scenario? A2. Use of the terms "organic" or "inorganic" is based on the hazardous constituents in the mixture or solution, not the mixture or solution as a whole. 23. A mixture or solution contains inorganic non-hazardous constituents and the corrosive component is an amine. corrosive, n.o.s." (UN2735) or the more generic "Corrosive Should the proper shipping name be, "Amines, liquid, liquids, n.o.s." (UN1760)? A3. The most appropriate description for the mixture or n.o.s." (UN2735) . solution you describe would be "Amines, liquid, corrosive, should be supplemented with the qualifying word "mixture" or In addition, the proper shipping name "solution" as specified in § 172.101 (c) (10). I trust this satisfies your inquiry. Please contact us if we can be of further assistance. Sincerely, Director Edward T. Mazzul Office of Hazardous Materials Standards#
Page 308/01/03 FRI 10:13 FAX 630 305 2986 ENVIRN HLTH SFTY 0002 ONDEO Nalco Stevens 3173.136 July 31, 2003 Mr. Edward T. Mazzullo Definition U.S. DOT/RSPA (DHM-10) Directory, Office of Hazardous Materials Standards 400 7* Street S.W. 03-8191 Fax: 202-366-3012 Washington, D.C. 20590-0001 Subject: 49CFR173.136 Selection of UN ID number for corrosive liquids mecting definition in Ondeo Nalco Company Naperville, IL 60563-1198 Ondeo Nalco Center Tel: 630-305-1000 Fax: 630-305-2900 Dear Mr. Mazzullo: Please confirm applicability of choosing various UN ID numbers for corrosive liquids. We and 3267, versus UN1760. These issues do not seem to be specifically defined in the D.O.T., cannot find any definitive explanation for use of the newer, more specific UN3264, 3265, 3266, significantly acidic or basic, regardless of whether the technical component is an acid or base. For First, we would like an opinion about using UN1760 specifically when pH is not either nother example to consider: If the corrosive components are amines, is the more specific prop lipping name for UN2735 preferred, or if non-hazardous inorganic components are preser swea#
Page 408/01/03 FRI 10:14 FAX 630 305 2986 ENVIRN HITH SFTY 7003 ONDEO Nalco July 31, 2003 Thank you for your prompt response. Yours Truly, Alicial fabor Dana M. Hall Regulatory Chemist Alicia M. Shaban Dana M. Hall Regulatory Chemist 630-305-2658 Environment, Health & Safety Environment Health & Safety Ondea Natco Company Naperville, IL 60563-1198 Ondeo Nalco Center Tel: 630-305-1000 Fax: 630-305-2900 sVez#
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