49 CFR 173.226
Materials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A.
Division 6.1, Packing Group I, materials that are poisonous by inhalation and that fall within the boundaries of Hazard Zone A in the graph found in § 173.133 must be packed in non-bulk packagings in accordance with the following paragraphs:
(a) In seamless specification cylinders conforming to the requirements of § 173.40. However, a welded cylinder filled before October 1, 2002, may be transported for reprocessing or disposal of the cylinder's contents until December 31, 2003.
(b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 drums further packed in a 1A2 or 1H2 drum. Both inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drum must have a minimum thickness of 1.35 mm (0.053 inch) for a 1A2 outer drum or 6.30 mm (0.248 inch) for a 1H2 outer drum. Outer 1A2 and 1H2 drums must withstand a hydrostatic test pressure of 100 kPa (15 psig). Capacity of the inner drum may not exceed 220 L (58 gallons). In addition, the inner drum must—
(1) Be capable of satisfactorily withstanding the hydrostatic pressure test in § 178.605 of this subchapter at a test pressure of 550 kPa (80 psig);
(2) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an internal air pressure of at least twice the vapor pressure at 55 °C (131 °F) of the material to be packaged;
(3) Have screw-type closures that are—
(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a device that is capable of measuring torque;
(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and
(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).
(4) Have a minimum thickness as follows:
(i) If the capacity of the inner drum is less than or equal to 120 L (32 gallons), the minimum thickness of the inner drum is—
(A) For a 1A1 or 1N1 drum, 1.3 mm (0.051 inch);
(B) For a 1B1 drum, 3.9 mm (0.154 inch);
(C) For a 1H1 drum, 3.16 mm (0.124 inch); and
(D) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and the outer steel drum shall be 0.96 mm (0.0378 inch).
(ii) If the capacity of the inner drum is greater than 120 L (32 gallons), the thickness of the inner drum is—
(A) For a 1A1 or 1N1 drum, 1.7 mm (0.067 inch);
(B) For a 1B1 drum, 4.7 mm (0.185 inch);
(C) For a 1H1 drum, 3.16 mm (0.124 inch); and
(D) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and the outer steel drum shall be 1.08 mm (0.043 inch); and
(5) Be isolated from the outer drum by a shock-mitigating, non-reactive material.
(c) In combination packagings, consisting of an inner packaging system and an outer packaging, as follows:
(1) Outer packagings:
Steel drum: 1A2 Aluminum drum: 1B2 Metal drum, other than steel or aluminum: 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H2 Wooden barrel: 2C2 Steel jerrican: 3A2 Plastic jerrican: 3H2 Aluminum jerrican: 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H2 Solid plastic box: 4H2
(2) Inner packaging system. The inner packaging system consists of two packagings: an impact-resistant receptacle of glass, earthenware, plastic or metal securely cushioned with a non-reactive, absorbent material and packed within a leak-tight packaging of metal or plastic. This combination packaging in turn is packed within the outer packaging. Capacity of each inner receptacle may not exceed 4 L (1 gallon). An inner receptacle that has a closure must have a closure which is physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation. Both the inner packaging system and the outer packaging must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level. The inner packaging system must meet these tests without the benefit of the outer packaging. The total amount of liquid contained in the outer packaging may not exceed 16 L (4 gallons).
[Amdt. 173-224, 55 FR 52643, Dec. 21, 1990, as amended at 56 FR 66274, Dec. 20, 1991; Amdt. 173-236, 58 FR 50236, Sept. 24, 1993; Amdt. 173-138, 59 FR 49134, Sept. 26, 1994; Amdt. 173-241, 59 FR 67517, Dec. 29, 1994; Amdt 173-261, 62 FR 24741, May 6, 1997; 66 FR 45380, Aug. 28, 2001; 67 FR 61289, Sept. 30, 2002; 68 FR 24660, May 8, 2003]